Abstract: The present disclosure provides high-grade ethanol production systems and methods that increase energy efficiency as compared to typical systems and methods by minimizing undesired acetal formation. The provided ethanol production method may include a low boilers removal distillation column and/or a stripper column constructed to simultaneously remove at least a portion of the acetaldehyde and at least a portion of the acetal from a feed stream in the presence of water. In some aspects, a low boilers removal process may be followed by a water removal process, which may be followed by a high boilers removal process. Acidity (e.g., carbon dioxide) may also be removed from a feed stream prior to or during the low boilers removal process. By minimizing acetal production, the provided method minimizes the amount of energy that is required to remove acetal when producing high-grade ethanol.

Abstract: A membrane distillation (MD) system includes a sweep gas MD (SGMD) module and a knockout chamber. The MD module includes a feed inlet, a feed outlet, a condensing media inlet, and a condensing media outlet. The condensing media is sweep gas. The knockout chamber is positioned after the feed outlet. The knockout chamber includes a liquid inlet, a liquid outlet, and a vapor outlet. Direct gas phase stripping within the SGMD module leads to additional water evaporation at the knockout chamber and contributes to enhanced water or VOCs removal of the MD system.

Abstract: A carbon molecular sieve (CMS) membrane may advantageously be made by pyrolyzing a membrane precursor composition comprised of a carbon forming polymer (e.g., polyimide) blended with a polyvinylidene chloride copolymer (PVDC), the polyvinylidene chloride copolymer being the reaction product of at least 60% to 97% by weight of vinylidene chloride and at least one other comonomer and the carbon forming polymer to polyvinylidene chloride copolymer has a weight ratio of greater than 1 to 99. The membrane precursor composition may be formed by dissolving the carbon forming polymer and PVDC in a solvent to form a dope solution. The dope solution may be shaped, for example, into an asymmetric hollow fiber. The asymmetric hollow fiber may be heated to a temperature to dehydrochorinate the PVDC and then subsequently heated in a non-oxidizing atmosphere to carbonize the polymers of the shaped membrane to form the CMS membrane.

Abstract: A conditioning system for a filter module is disclosed. The conditioning system may generally include an inlet, a heat exchanger, a magnetically levitated pump, a channel provided to bypass the heat exchanger, a controller, an outlet, and a base. The system may have components lined with corrosion-resistant materials. A method of conditioning a filter module is also disclosed. The method may generally include measuring TOC in a source of ultrapure water, heating the ultrapure water, rinsing a filter module with the heated water, flushing the filter module with ambient temperature water, and repeating the rinsing with heated water and flushing with ambient temperature water. A method of facilitating conditioning of the filter module is also disclosed. The method may generally include providing a portable filter module conditioning system and providing instructions for installation or use.

Abstract: Novel copolymers that are fluoropolymers including a first repeat unit that is fluorinated and cyclic and a second repeat unit from a trifluorovinyl methylene ether monomer having sulfur or sulfone functionality in the pendant group are disclosed. The copolymers have relatively high gas permeability as a result of a cyclic repeat unit in the copolymer backbone and ionomers from oxidation of the sulfur containing functionality are particularity useful in the cathode structure of a proton exchange membrane fuel cell.

Abstract: A dual-layer membrane and a method for preparing thereof. By adding a modifying monomer containing an active group and a characteristic group to a dope solution or spinning solution during the preparation of the dual-layer membrane, the grafting reaction occurs between the active group of the monomer and the polymer in the dope solution or spinning solution, and the intermolecular interaction with other polymers is enhanced by the characteristic group of the monomer, to improve the miscibility between the polymers. The method is suitable for preparing both a dual-layer flat sheet membrane and a dual-layer hollow fiber membrane, and can realize the preparation of a dual-layer membrane with an interpenetrated structure at the interface under mild preparation conditions.

Abstract: The present disclosure relates to an organic compound having the following structure, and an organic light emitting diode (OLED) and an organic light emitting device including the organic compound. Applying the organic compound into an emissive layer makes the OLED and the organic light emitting device lower their driving voltage, improves their luminous efficiency and color purity.

Abstract: A reverse osmosis system for a seawater desalination system is provided.

Abstract: Methods, systems and compositions for producing at least one light-boiling, volatile, organic product using at least a portion of one or more carbon containing substances from a non-biosynthetic process in a biosynthetic process are provided. These methods, systems and compositions are useful in reducing waste treatment load of carbon containing chemical process waste streams.

Abstract: An apparatus and method for recovering heat and water vapor from a waste gas stream. A waste gas passageway directs waste gas over a plurality of membrane tubes extending across the waste gas passageway. Each of the membrane tubes includes an internal passage separated from the waste gas passageway by a porous membrane. A water supply inlet manifold is connected to each of the plurality of membrane tubes, and configured to introduce water into the internal passages of the membrane tubes. A vacuum source is connected to the water side of the apparatus, and configured to adjust a pressure within the internal passages of the membrane tubes. The water within the internal passages receives heat and water vapor from the waste gas stream across the porous membrane.

Abstract: An apparatus and system for separating a liquid from a mixed gas stream includes a porous graphite foam support comprising graphite foam with pores having a first pore size and a membrane support surface. A porous condensation membrane layer is provided on the membrane support surface, and interlocked with the pores of the graphite foam. The condensation membrane layer includes capillary condensation pores having a second pore size that is less than the first pore size. A mixed gas stream passageway is in fluid communication with the condensation membrane layer. A liquid collection assembly collects condensed liquid from the condensation pores and the graphite foam support pores. A gas inlet is provided for flowing the mixed gas stream into the mixed gas stream passageway. A gas outlet is provided for exhausting gas from the mixed gas stream passageway. A method for separating a liquid from a mixed gas stream is also disclosed.

Abstract: A filter assembly including a filtration medium comprising a nanofiber, having a three-dimensional network structure, and having a fiber web layer comprising a hydrophilic coating layer that covers at least a part of the outer surface of the nanofiber; and a first support body that supports the filtration medium, which is provided on both surfaces thereof, and has a channel formed therein. Accordingly, the filtration medium has excellent chemical resistance and improved hydrophilicity such that the flow rate can increase substantially. In addition, the improved hydrophilicity is maintained for a long period of time such that the utilization period can be extended substantially. Furthermore, any change in the pore structure of the filtration medium during the hydrophilicity endowing process is minimized such that the initially designed physical characteristics of the filtration medium can be fully exhibited.

Abstract: The present application concerns a microfluidic cassette for synthesizing a radiotracer including a microfluidic circuit in a support card that includes at least one intake for supply by a vial, at least one isotope port, at least one reaction chamber, at least one mixing chamber, at least one formulation chamber, and at least one connection for a syringe, linked together by capillaries. Also disclosed is a method for synthesizing a radiotracer in such a cassette.

Abstract: Provided is a filtration method that includes a cleaning step and involves the use of a porous membrane, wherein the filtration method offers exceptional resistance to cleaning solutions (chemicals) (chemical liquid resistance) and exceptional filtration performance, and has a long service life. A filtration method includes the following steps: a filtration step in which a liquid to be processed that contains a material to be filtered is passed through a porous membrane configured from a resin having a three-dimensional mesh structure, and a filtrate is separated from the material to be filtered; and a cleaning step in which the porous membrane has a cleaning solution passed therethrough or is immersed in the cleaning solution so that the interior of the porous membrane is cleaned.

Abstract: A process and system to control the final product quality in a system for separating olefins and paraffins in a membrane system. A small finishing membrane stage is added to an existing membrane system that takes a slip stream from the product, purifies it to a very high concentration of propylene and blends it back into the product stream.

Abstract: Embodiments provide methods and structures for purification or volume reduction of a brine by an advanced vacuum distillation process (AVMD) to achieve higher flux by passage of vapors through an AVMD distillation unit. In one example, brine is circulated in a tank. The tank may include one or more membrane pouches that are submerged in the circulating brine or placed above the water level of the hot circulating brine. In other embodiments the membrane pouches are outside of the tank that includes the hot circulating brine but still in communication with it. The circulating brine is heated, allowing creation of water vapor. Using a vacuum, the water vapor is drawn through the membrane, where it may be condensed and subjected to further beneficial use. This process can concentrate to levels to generate crystals or solids, which can be separated and utilized.

Abstract: The present disclosure provides processes and systems for heat integration in ethanol production. In one embodiment, a feed mixture is distilled with one or more distillation units to remove at least a portion of the water, and form a distillation unit bottom stream, a vaporous overhead stream, and a fusel oil stream. Molecular sieve units are regenerated by vacuum or a combination of vacuum and optionally a portion of the product stream to form one or more regenerate streams. A feed tank is configured to receive at least one selected from a condensed portion of the regenerate streams and a portion of a vaporous depressure stream, to form a feed stream. The energy contained in the depressure vapor is recovered by the depressure vapor contacting the feed tank and heating up at least one stream forwarded into the feed tank.

Abstract: Devices and techniques may improve the permeate productivity in membrane distillation separation by modifying the feed and/or coolant sides of a membrane distillation module depending on the membrane distillation configuration. The bubbling of a carrier gas through the feed liquid in the feed liquid side of the module can increase the turbulent dissipation rate and/or enhance mass transfer across the membrane pores.

Abstract: In some embodiments, the present disclosure pertains to systems and methods for distilling a fluid by exposing the fluid to a porous membrane that includes a surface capable of generating heat. In some embodiments, the heat generated at the surface propagates the distilling of the fluid by converting the fluid to a vapor that flows through the porous membrane and condenses to a distillate. In some embodiments, the surface capable of generating heat is associated with a photo-thermal composition that generates the heat at the surface by converting light energy from a light source to thermal energy. In some embodiments, the photo-thermal composition includes, without limitation, noble metals, semiconducting materials, dielectric materials, carbon-based materials, composite materials, nanocomposite materials, nanoparticles, hydrophilic materials, polymers, fibers, meshes, fiber meshes, hydrogels, hydrogel meshes, nanomaterials, and combinations thereof.

Abstract: A dehydration method is a dehydration method for selectively separating water from a mixture that contains water, using a zeolite membrane having an AFX structure, and the method includes a step of supplying the mixture to a supply side space of the zeolite membrane having an AFX structure, and a step of making a pressure difference between the supply side space and a permeation side space of the zeolite membrane having an AFX structure.

Abstract: This document describes systems and methods for treating and recovering water from feed solutions using a membrane module that has a plurality of hollow fiber membranes encapsulated in a collection chamber and an expansion chamber that is connected to the outlet of the membrane module.

Abstract: Provided is a method of calculating a tortuous hydraulic diameter of a porous medium for laminar flow and turbulent flow considering a geometric feature and a friction loss feature. A method of calculating a tortuous hydraulic diameter of a porous medium, according to an embodiment of the present invention, includes providing porosity and a specific surface area of a porous medium, calculating a hydraulic diameter of the porous medium by using the porosity and the specific surface area, calculating tortuosity of the porous medium, and calculating a tortuous hydraulic diameter corresponding to a function of tortuosity, by using the hydraulic diameter and the tortuosity of the porous medium.

Abstract: A method for producing products, advantageously solvents, is by fermentation, advantageously multi-stage fermentation. The fermentation is complemented with pervaporation as in situ product recovery technology, combined with a multistage condensation of the permeate. The condensates are separately introduced in the downstream processing to recover the produced products, advantageously solvents. The method for producing products, advantageously solvents, by fermentation is simplified and has an overall improved energy efficiency. A related system uses method for producing products, advantageously solvents, is by fermentation.

Abstract: Disclosed are devices for determining an analyte concentration (e.g., glucose). The devices comprise a sensor configured to generate a signal associated with a concentration of an analyte and a sensing membrane located over the sensor. The sensing membrane comprises an enzyme layer, wherein the enzyme layer comprises an enzyme and a polymer comprising polyurethane and/or polyurea segments and one or more zwitterionic repeating units. The enzyme layer protects the enzyme and prevents it from leaching from the sensing membrane into a host or deactivating.

Abstract: Methods and systems are provided for heat transfer from a process fluid, such as humid air, to liquid droplets that are generated by contact of a heat transfer surface with the process fluid. The heat transfer surface rapidly ejects liquid droplets, which may then be coalesced and removed, thereby cooling the process fluid. Enhanced methods of condensate collection are described.

Abstract: Device for metering powder, in particular in clean-rooms, which includes a vessel containing powder and a sealing head with a septum for the vessel, wherein the sealing head is connectable powder-tight with the vessel and the septum powder-tight with the sealing head and the device further includes a vessel holder, which serves to hold the sealing head of the vessel, and the vessel with its opening points downwards, so that the powder can flow out of the vessel, wherein a gap is provided between the sealing head and a holding bowl of the vessel holder, in which a gas flow between the holding bowl and the sealing head can be created. The invention also relates to a use of the device and a metered addition method.

Abstract: The present invention is directed to a method for treating a surface of a filled microporous membrane. The microporous membrane includes a polyolefinic matrix, inorganic filler distributed throughout the matrix, and a network of interconnecting pores throughout the membrane. The method includes sequentially (1) contacting at least one surface of the membrane with a treatment composition of a silane-functional polyamine compound having at least one alkoxy silane group, such that the silane-functional polyamine compound is in intimate contact with the filler present in the matrix; and (2) subjecting the membrane of (1) to conditions sufficient to effect a condensation reaction between the inorganic filler and the silane-functional polyamine compound. Treated membranes also are provided.

Abstract: The present disclosure is in the field of chemical sciences. The present disclosure relates to a process for removal of anion from aqueous solution. The process involves removal of sulphate ion from aqueous solution using cation and organic solvent that enables precipitation of the sulphate ion from the aqueous solution. The process is simple, efficient, cost-effective, ecofriendly, enables recovery of sulphate ions, calcium ions as calcium sulphate with high purity and also enables the recovery of organic solvent in the range of about 88% to about 99%.

Abstract: A method of manufacturing a membrane can include forming the membrane from a dissolved polymer in the presence of a functionalizing agent; and exposing the functionalizing agent to a nanoparticle to form a modified membrane.

Abstract: In one embodiment, there is provided a heat exchanger for equipment, having: at least one phase change material; and at least one heat exchange interface for heat exchange between the phase change material and a fluid flowing within, into and/or from a replaceable fluid container for the equipment, the replaceable fluid container having at least one fluid port adapted to couple to a fluid circulation system of the equipment when the replaceable container is coupled to a dock.

Abstract: A thermal water purification system and a related method including distilling units consecutively flowed through by raw feed liquid, each having a boiling liquid section and a vapor section, and including a heat exchanger cavity adapted to transfer thermal energy to the raw feed liquid before entering the boiling liquid section of a first distilling unit. Heat exchanger tubes in fluidic communication with the heat exchanger cavity extend through the boiling liquid section of the first distilling unit to transfer thermal energy from a medium in the tubes to cause the raw feed liquid to boil. Preheating tubes extend through the vapor section of each distilling unit to heat the raw feed liquid before entering the boiling sections using thermal energy from vapor condensing against external surfaces of the preheating tubes, which produces the distillate liquid that flows through a discharge port and a conduit supplying a storage tank.

Abstract: The present application is directed to systems and methods for on-board fuel separation. The system includes: a source fuel tank for liquid fuel; a pump; and a membrane module. The membrane module includes a hydrophilic membrane, a retentate channel, and a permeate channel. The retentate and permeate channels are on opposing sides of the membrane. The membrane module receives fuel from the source fuel tank and separates the liquid fuel into a high octane fraction that collects in the retentate channel and a low octane fraction that diffuses through the membrane to the permeate channel. The system further includes a low octane fuel tank for receiving at least a portion of the low octane fraction, a high octane fuel tank for receiving at least a portion of the high octane fraction, and an engine configured to selectively receive at least a portion of the low and high octane fractions.

Abstract: A composition of five parts by mass of chitosan and one part graphene oxide is suspended in water. The composition may be used to form filtration layers of any size or shape and may be reinforced by additional layers. The composition may be used to construct a large filtration apparatus of any size or shape and may be used to form highly resilient, antimicrobial structures and surfaces for a variety of applications.

Abstract: The present disclosure is directed to a forward osmosis system/process utilized primarily in conjunction with a subsurface irrigation system/process. Saline wastewater or naturally saline water is treated using forward osmosis membranes that draw at least partially purified water from the wastewater into an osmotic draw solution (draw solution). The resulting diluted osmotic draw solution is then circulated through the subsurface irrigation system including one or more tubular membranes that reject the draw solution while permitting water in the diluted draw solution to pass through.

Abstract: A system and method for effectively desalinating a feed stream is provided. In one embodiment, a feed stream is desalinated by a Brine Forward (BF) desalination system comprising an enabling de-scaling step combined with a plurality of trains arranged in series and alternated in pairs of opposing feed evaporation modes, wherein each pair comprises a leading backward fed multi-effect train and a following forward fed multi-effect train. This system is structured on the grounds of simplicity and homogeneity, without using scale inhibitors and restricting top brine temperature. This system is a close approximation of efficient regenerative heating and brine cascading; the energy extracted to heat the feed is only slightly hotter than the feed it is heating without complex feed heating setups; and the brine extracted after evaporating vapor in the train is used to evaporate vapor in the next train, yet reject brine is readily reusable in other applications.

Abstract: A method and system for effectively desalinating a feed stream is provided. In one embodiment, a feed stream is desalinated by a Brine Forward (BF) desalination system, which comprises an enabling de-scaling step combined with a plurality of multi-stage flash (MSF) trains arranged in series, wherein the de-scaling step is conducted within a MSF first train at a top temperature. With the aid of the de-scaling step, the system obviates or reduces many of the well known disadvantages of the desalination practice along with their expenditures and environmental burdens. The elimination of otherwise intractable substantial operating and silent environmental costs of such disadvantages, in itself, may over defray the de-scaling step's cost and with greater benefits to the overall system's performance and distillate production. Furthermore, all of the products from the de-scaling step are commercially viable, and if desirable or necessary, all of the de-scaling step's additives are also recyclable.

Abstract: Membrane distillation (MD) systems include at least two MD modules arranged in series, each of at least two MD modules including a condensing media inlet operable to receive a condensing media and a condensing media outlet, a feed inlet operable to receive a feed media and a feed outlet, and a first heating element positioned and operable to heat a feed prior to or upon introduction of the feed to a first of the at least two MD modules, wherein a stream exiting the feed outlet of the first of the at least two MD modules is introduced to the second of the at least two MD modules. Other MD systems include at least two MD modules arranged in parallel.

Abstract: A composite membrane for selectively separating (e.g., pervaporating) a first fluid (e.g., first liquid such as a high octane compound) from a mixture comprising the first fluid (e.g., first liquid such as a high octane compound) and a second fluid (e.g., second liquid such as gasoline). The composite membrane includes a porous substrate comprising opposite first and second major surfaces, and a plurality of pores. A pore-filling polymer is disposed in at least some of the pores so as to form a layer having a thickness within the porous substrate. The composite membrane further includes at least one of: (a) an ionic liquid mixed with the pore-filling polymer; or (b) an amorphous fluorochemical film disposed on the composite membrane.

Abstract: The present invention relates to a combined C3/C4 splitter with a membrane system. More specifically, the present invention relates to a combined C3/C4 splitter column to separate highly pure propylene product from a liquefied petroleum gas stream, which eliminates a C3 splitter having over 120 trays and the additional equipment that a C3 splitter requires.

Abstract: The present invention relates to a combined C3/C4 splitter with a membrane system. More specifically, the present invention relates to a combined C3/C4 splitter column to separate highly pure propylene product from a liquefied petroleum gas stream, which eliminates a C3 splitter having over 120 trays and the additional equipment that a C3 splitter requires.

Abstract: A system for use in a gas turbine engine fuel supply has an internal fuel filter having an internal bore and an external surface. A chamber within the internal bore of the fuel filter for receives a fuel and allows fuel to pass radially outwardly across the fuel filter. An oxygen removal unit is outwardly of the external surface of the fuel filter, such that fuel passes through the fuel filter, encounters the oxygen removal unit such that oxygen can be removed from the fuel, an outlet port for removed oxygen, and a separate outlet port for fuel having passed over the fuel filter and the oxygen removal unit.

Abstract: There is provided herein a system and method for de-toxifying and de-scaling source water. In some embodiments, source water will be mixed with either an aluminum source or an iron source to separate endotoxins from acidic proteins and convert the naturally present bicarbonate in source water to carbon dioxide. Endotoxins and carbon dioxide will then be removed from source water by a stage of hydrophobic membranes to produce de-toxified and de-carbonated source water. Calcium hydroxide will be mixed with the de-toxified and de-carbonated source water to form precipitates comprising foulants and sulfate. A recoverable and reusable amine solvent will also be used to induce efficient precipitation. Possible reuse applications for the treated source water by the inventive methods that minimize excessive uses of potable water may include hydro-fracturing of shale and sand formations and heavy oil recovery by steam injection.

Abstract: Separation processes using osmotically driven membrane systems are disclosed generally involving the extraction of solvent from a first solution to concentrate solute by using a second concentrated solution to draw the solvent from the first solution across a semi-permeable membrane.

Abstract: A process for the recovery of sodium sulfate from water, in particular from water deriving from a silica manufacturing process.

Abstract: A method and a device for condensing a water-soluble organic matter, which can collect a highly concentrated water-soluble organic matter, save energy, and reduce cost of the device by reducing a membrane area. According to the present invention, the permeability ratio of a vapor-permeation separation membrane disposed at least immediately before a final outlet on a non-permeation side in the separation membrane device is lower than those of the other vapor-permeation separation membranes while a hybrid process combining distillation by the distillation column with membrane separation by the separation membrane devices including a plurality of vapor-permeation separation membranes is used and energy saving performance is maintained. Therefore, a highly concentrated and condensed component of a water-soluble organic matter is obtained.

Abstract: Presented herein are membranes for use in separating solids including salts from water. One application of such membranes is in a sub-surface irrigation system that that utilizes a saline or tainted water as a feed source. In various embodiments, the membranes operate on a solution diffusion principle. In other embodiments the membranes operate on an ultrafiltration principle and/or a solution diffusion principle. In any embodiment, the membranes operate similar to pervaporation membranes suitable for non-pressure driven systems. The membranes are designed to provide increased flux rate while separating solids such as salts from water.

Abstract: An apparatus for separating dimethyl carbonate using pervaporation includes: an atmospheric distillation column and a high pressure distillation column distilling a mixture containing dimethyl carbonate and methanol and separating dimethyl carbonate from the mixture; and a pervaporation membrane module disposed between the atmospheric distillation column and the high pressure distillation column and allowing for permeation of the methanol to separate the methanol from the mixture, thereby reducing heat consumption and a process cost as compared to the case of only using an existing pressure swing distillation method.

Abstract: An internal combustion engine includes, in addition to an LPL-EGR system, two water vapor separation film modules for fresh air and for EGR gas. One module 34 is connected to a pressure reducing pump 40 through a suction passage 38. Other module 36 is connected to a pressure reducing pump 44 through a suction passage 42. A condenser 54 that condenses water vapor that flows through the suction passage 38 is provided in the suction passage 38. A water tank 56 that temporarily accumulates condensed water that is discharged from the condenser 54 is provided on a downstream side relative to the condenser 54. The water tank 56 is connected to injectors 60 that inject water from the water tank 56 into intake ports of respective cylinders or into respective cylinders.

Abstract: The present invention relates to a desalination apparatus and a desalination method using the same. In one specific embodiment, the desalination apparatus comprises: a forward osmosis unit having a draw-solution part into which seawater flows, and a raw water part into which raw water flows, and having an osmosis membrane, formed between the draw solution part and the raw water part, so as to respectively generate first treated water and first concentrated water; a capacitive deionization unit, which is connected to the draw solution part through a first inflow passage, and into which the first treated water of the draw solution part flows so as to generate second treated water; and an electrodialysis unit, which is connected to the raw water part through a second inflow passage, and into which the first concentrated water of the raw water part flows so as to generate third treated water.

Abstract: Water treatment systems including electrically-driven and pressure-driven separation apparatus configured to produce a first treated water suitable for use as irrigation water and a second treated water suitable for use as potable water from one of brackish water and seawater and methods of operation of same.