Passing Through Membrane In Vapor Phase Patents (Class 210/640)
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Patent number: 11260348Abstract: A dehydration method is a dehydration method for selectively separating water from a mixture that contains water, using a zeolite membrane having an AFX structure, and the method includes a step of supplying the mixture to a supply side space of the zeolite membrane having an AFX structure, and a step of making a pressure difference between the supply side space and a permeation side space of the zeolite membrane having an AFX structure.Type: GrantFiled: December 4, 2019Date of Patent: March 1, 2022Assignee: NGK Insulators, Ltd.Inventors: Kenichi Noda, Makoto Miyahara, Katsuya Shimizu, Takeshi Hagio
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Patent number: 11235284Abstract: This document describes systems and methods for treating and recovering water from feed solutions using a membrane module that has a plurality of hollow fiber membranes encapsulated in a collection chamber and an expansion chamber that is connected to the outlet of the membrane module.Type: GrantFiled: October 25, 2018Date of Patent: February 1, 2022Assignee: MEMSIFT INNOVATIONS PTE. LTD.Inventor: James Selvaraj Antony Prince
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Patent number: 11193873Abstract: Provided is a method of calculating a tortuous hydraulic diameter of a porous medium for laminar flow and turbulent flow considering a geometric feature and a friction loss feature. A method of calculating a tortuous hydraulic diameter of a porous medium, according to an embodiment of the present invention, includes providing porosity and a specific surface area of a porous medium, calculating a hydraulic diameter of the porous medium by using the porosity and the specific surface area, calculating tortuosity of the porous medium, and calculating a tortuous hydraulic diameter corresponding to a function of tortuosity, by using the hydraulic diameter and the tortuosity of the porous medium.Type: GrantFiled: September 29, 2017Date of Patent: December 7, 2021Assignee: KOREA GAS CORPORATIONInventor: Chang Hoon Shin
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Patent number: 11112377Abstract: Disclosed are devices for determining an analyte concentration (e.g., glucose). The devices comprise a sensor configured to generate a signal associated with a concentration of an analyte and a sensing membrane located over the sensor. The sensing membrane comprises an enzyme layer, wherein the enzyme layer comprises an enzyme and a polymer comprising polyurethane and/or polyurea segments and one or more zwitterionic repeating units. The enzyme layer protects the enzyme and prevents it from leaching from the sensing membrane into a host or deactivating.Type: GrantFiled: December 29, 2016Date of Patent: September 7, 2021Assignee: DexCom, Inc.Inventors: Shanger Wang, Ted Tang Lee, Jiong Zou
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Patent number: 11111473Abstract: A method for producing products, advantageously solvents, is by fermentation, advantageously multi-stage fermentation. The fermentation is complemented with pervaporation as in situ product recovery technology, combined with a multistage condensation of the permeate. The condensates are separately introduced in the downstream processing to recover the produced products, advantageously solvents. The method for producing products, advantageously solvents, by fermentation is simplified and has an overall improved energy efficiency. A related system uses method for producing products, advantageously solvents, is by fermentation.Type: GrantFiled: July 19, 2017Date of Patent: September 7, 2021Assignee: VITO NV (VLAAMSE INSTELLING VOOR TECHNOLOGISCH ONDERZOEK NV)Inventors: Wouter Van Hecke, Helene De Wever, Lambertus Bouwman
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Patent number: 11041665Abstract: Methods and systems are provided for heat transfer from a process fluid, such as humid air, to liquid droplets that are generated by contact of a heat transfer surface with the process fluid. The heat transfer surface rapidly ejects liquid droplets, which may then be coalesced and removed, thereby cooling the process fluid. Enhanced methods of condensate collection are described.Type: GrantFiled: November 27, 2018Date of Patent: June 22, 2021Assignee: Nelumbo Inc.Inventors: Lance R. Brockway, David C. Walther
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Patent number: 10982987Abstract: Device for metering powder, in particular in clean-rooms, which includes a vessel containing powder and a sealing head with a septum for the vessel, wherein the sealing head is connectable powder-tight with the vessel and the septum powder-tight with the sealing head and the device further includes a vessel holder, which serves to hold the sealing head of the vessel, and the vessel with its opening points downwards, so that the powder can flow out of the vessel, wherein a gap is provided between the sealing head and a holding bowl of the vessel holder, in which a gas flow between the holding bowl and the sealing head can be created. The invention also relates to a use of the device and a metered addition method.Type: GrantFiled: March 6, 2020Date of Patent: April 20, 2021Assignee: ANCOSYS GMBHInventors: Juerg Stahl, Irene Popova, Christian Rueckl
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Patent number: 10888824Abstract: The present invention is directed to a method for treating a surface of a filled microporous membrane. The microporous membrane includes a polyolefinic matrix, inorganic filler distributed throughout the matrix, and a network of interconnecting pores throughout the membrane. The method includes sequentially (1) contacting at least one surface of the membrane with a treatment composition of a silane-functional polyamine compound having at least one alkoxy silane group, such that the silane-functional polyamine compound is in intimate contact with the filler present in the matrix; and (2) subjecting the membrane of (1) to conditions sufficient to effect a condensation reaction between the inorganic filler and the silane-functional polyamine compound. Treated membranes also are provided.Type: GrantFiled: November 16, 2016Date of Patent: January 12, 2021Assignee: PPG Industries Ohio, Inc.Inventors: Qunhui Guo, James C. Peters, Luciano M. Parrinello, Linda K. Anderson
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Patent number: 10875795Abstract: The present disclosure is in the field of chemical sciences. The present disclosure relates to a process for removal of anion from aqueous solution. The process involves removal of sulphate ion from aqueous solution using cation and organic solvent that enables precipitation of the sulphate ion from the aqueous solution. The process is simple, efficient, cost-effective, ecofriendly, enables recovery of sulphate ions, calcium ions as calcium sulphate with high purity and also enables the recovery of organic solvent in the range of about 88% to about 99%.Type: GrantFiled: January 9, 2017Date of Patent: December 29, 2020Assignee: RELIANCE INDUSTRIES LIMITEDInventors: Chintansinh Dharmendrasinh Chudasama, Sumeet Kumar Sharma, Kalpana Gopalakrishnan, Nagesh Sharma, Raksh Vir Jasra
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Patent number: 10780402Abstract: A method of manufacturing a membrane can include forming the membrane from a dissolved polymer in the presence of a functionalizing agent; and exposing the functionalizing agent to a nanoparticle to form a modified membrane.Type: GrantFiled: April 12, 2013Date of Patent: September 22, 2020Assignee: KING ABDULLAH UNIVERSITY OF SCIENCE AND TECHNOLOGYInventors: Suzana Nunes, Iran D. Charry Prada
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Patent number: 10704451Abstract: In one embodiment, there is provided a heat exchanger for equipment, having: at least one phase change material; and at least one heat exchange interface for heat exchange between the phase change material and a fluid flowing within, into and/or from a replaceable fluid container for the equipment, the replaceable fluid container having at least one fluid port adapted to couple to a fluid circulation system of the equipment when the replaceable container is coupled to a dock.Type: GrantFiled: December 16, 2016Date of Patent: July 7, 2020Assignee: Castrol LimitedInventor: Timothy Hugh Lake
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Patent number: 10702830Abstract: A thermal water purification system and a related method including distilling units consecutively flowed through by raw feed liquid, each having a boiling liquid section and a vapor section, and including a heat exchanger cavity adapted to transfer thermal energy to the raw feed liquid before entering the boiling liquid section of a first distilling unit. Heat exchanger tubes in fluidic communication with the heat exchanger cavity extend through the boiling liquid section of the first distilling unit to transfer thermal energy from a medium in the tubes to cause the raw feed liquid to boil. Preheating tubes extend through the vapor section of each distilling unit to heat the raw feed liquid before entering the boiling sections using thermal energy from vapor condensing against external surfaces of the preheating tubes, which produces the distillate liquid that flows through a discharge port and a conduit supplying a storage tank.Type: GrantFiled: March 15, 2017Date of Patent: July 7, 2020Assignee: Ecole Polytechnique Federale de Lausanne (EPFL)Inventors: Chin Lee Ong, John R. Thome
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Patent number: 10697412Abstract: The present application is directed to systems and methods for on-board fuel separation. The system includes: a source fuel tank for liquid fuel; a pump; and a membrane module. The membrane module includes a hydrophilic membrane, a retentate channel, and a permeate channel. The retentate and permeate channels are on opposing sides of the membrane. The membrane module receives fuel from the source fuel tank and separates the liquid fuel into a high octane fraction that collects in the retentate channel and a low octane fraction that diffuses through the membrane to the permeate channel. The system further includes a low octane fuel tank for receiving at least a portion of the low octane fraction, a high octane fuel tank for receiving at least a portion of the high octane fraction, and an engine configured to selectively receive at least a portion of the low and high octane fractions.Type: GrantFiled: February 14, 2018Date of Patent: June 30, 2020Assignee: Saudi Arabian Oil CompanyInventors: Esam Z. Hamad, Husain A. Baaqel
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Patent number: 10596525Abstract: A composition of five parts by mass of chitosan and one part graphene oxide is suspended in water. The composition may be used to form filtration layers of any size or shape and may be reinforced by additional layers. The composition may be used to construct a large filtration apparatus of any size or shape and may be used to form highly resilient, antimicrobial structures and surfaces for a variety of applications.Type: GrantFiled: August 7, 2017Date of Patent: March 24, 2020Assignee: UNITED STATES OF AMERICA AS REPRESENTED BY THE SECRETARY OF THE ARMYInventors: Victor F Medina, Christopher S Griggs, Jose Mattei-Sosa, Brooke Petery, Luke Gurtowski
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Patent number: 10583395Abstract: The present disclosure is directed to a forward osmosis system/process utilized primarily in conjunction with a subsurface irrigation system/process. Saline wastewater or naturally saline water is treated using forward osmosis membranes that draw at least partially purified water from the wastewater into an osmotic draw solution (draw solution). The resulting diluted osmotic draw solution is then circulated through the subsurface irrigation system including one or more tubular membranes that reject the draw solution while permitting water in the diluted draw solution to pass through.Type: GrantFiled: July 20, 2018Date of Patent: March 10, 2020Assignee: KC Harvey Environmental, LLCInventors: Jonathan A. Brant, Kevin Harvey
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Patent number: 10577257Abstract: A method and system for effectively desalinating a feed stream is provided. In one embodiment, a feed stream is desalinated by a Brine Forward (BF) desalination system, which comprises an enabling de-scaling step combined with a plurality of multi-stage flash (MSF) trains arranged in series, wherein the de-scaling step is conducted within a MSF first train at a top temperature. With the aid of the de-scaling step, the system obviates or reduces many of the well known disadvantages of the desalination practice along with their expenditures and environmental burdens. The elimination of otherwise intractable substantial operating and silent environmental costs of such disadvantages, in itself, may over defray the de-scaling step's cost and with greater benefits to the overall system's performance and distillate production. Furthermore, all of the products from the de-scaling step are commercially viable, and if desirable or necessary, all of the de-scaling step's additives are also recyclable.Type: GrantFiled: May 6, 2019Date of Patent: March 3, 2020Inventor: Mansour S. Bader
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Patent number: 10577269Abstract: A system and method for effectively desalinating a feed stream is provided. In one embodiment, a feed stream is desalinated by a Brine Forward (BF) desalination system comprising an enabling de-scaling step combined with a plurality of trains arranged in series and alternated in pairs of opposing feed evaporation modes, wherein each pair comprises a leading backward fed multi-effect train and a following forward fed multi-effect train. This system is structured on the grounds of simplicity and homogeneity, without using scale inhibitors and restricting top brine temperature. This system is a close approximation of efficient regenerative heating and brine cascading; the energy extracted to heat the feed is only slightly hotter than the feed it is heating without complex feed heating setups; and the brine extracted after evaporating vapor in the train is used to evaporate vapor in the next train, yet reject brine is readily reusable in other applications.Type: GrantFiled: April 20, 2019Date of Patent: March 3, 2020Inventor: Mansour S. Bader
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Patent number: 10569223Abstract: Membrane distillation (MD) systems include at least two MD modules arranged in series, each of at least two MD modules including a condensing media inlet operable to receive a condensing media and a condensing media outlet, a feed inlet operable to receive a feed media and a feed outlet, and a first heating element positioned and operable to heat a feed prior to or upon introduction of the feed to a first of the at least two MD modules, wherein a stream exiting the feed outlet of the first of the at least two MD modules is introduced to the second of the at least two MD modules. Other MD systems include at least two MD modules arranged in parallel.Type: GrantFiled: June 20, 2017Date of Patent: February 25, 2020Inventors: Somenath Mitra, Sagar Roy
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Patent number: 10478778Abstract: A composite membrane for selectively separating (e.g., pervaporating) a first fluid (e.g., first liquid such as a high octane compound) from a mixture comprising the first fluid (e.g., first liquid such as a high octane compound) and a second fluid (e.g., second liquid such as gasoline). The composite membrane includes a porous substrate comprising opposite first and second major surfaces, and a plurality of pores. A pore-filling polymer is disposed in at least some of the pores so as to form a layer having a thickness within the porous substrate. The composite membrane further includes at least one of: (a) an ionic liquid mixed with the pore-filling polymer; or (b) an amorphous fluorochemical film disposed on the composite membrane.Type: GrantFiled: July 1, 2016Date of Patent: November 19, 2019Assignee: 3M Innovative Properties CompanyInventors: Jinsheng Zhou, Ryan C. Shirk, David Scott Seitz, Moses M. David
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Patent number: 10472306Abstract: The present invention relates to a combined C3/C4 splitter with a membrane system. More specifically, the present invention relates to a combined C3/C4 splitter column to separate highly pure propylene product from a liquefied petroleum gas stream, which eliminates a C3 splitter having over 120 trays and the additional equipment that a C3 splitter requires.Type: GrantFiled: June 29, 2018Date of Patent: November 12, 2019Inventors: Stanley J. Frey, Chunqing Liu, Trung Pham
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Patent number: 10471368Abstract: The present invention relates to a combined C3/C4 splitter with a membrane system. More specifically, the present invention relates to a combined C3/C4 splitter column to separate highly pure propylene product from a liquefied petroleum gas stream, which eliminates a C3 splitter having over 120 trays and the additional equipment that a C3 splitter requires.Type: GrantFiled: June 29, 2018Date of Patent: November 12, 2019Inventors: Stanley J. Frey, Chunqing Liu, Trung Pham
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Patent number: 10456722Abstract: A system for use in a gas turbine engine fuel supply has an internal fuel filter having an internal bore and an external surface. A chamber within the internal bore of the fuel filter for receives a fuel and allows fuel to pass radially outwardly across the fuel filter. An oxygen removal unit is outwardly of the external surface of the fuel filter, such that fuel passes through the fuel filter, encounters the oxygen removal unit such that oxygen can be removed from the fuel, an outlet port for removed oxygen, and a separate outlet port for fuel having passed over the fuel filter and the oxygen removal unit.Type: GrantFiled: August 25, 2017Date of Patent: October 29, 2019Assignee: Hamilton Sundstrand CorporationInventor: Gerald P. Dyer
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Patent number: 10450212Abstract: There is provided herein a system and method for de-toxifying and de-scaling source water. In some embodiments, source water will be mixed with either an aluminum source or an iron source to separate endotoxins from acidic proteins and convert the naturally present bicarbonate in source water to carbon dioxide. Endotoxins and carbon dioxide will then be removed from source water by a stage of hydrophobic membranes to produce de-toxified and de-carbonated source water. Calcium hydroxide will be mixed with the de-toxified and de-carbonated source water to form precipitates comprising foulants and sulfate. A recoverable and reusable amine solvent will also be used to induce efficient precipitation. Possible reuse applications for the treated source water by the inventive methods that minimize excessive uses of potable water may include hydro-fracturing of shale and sand formations and heavy oil recovery by steam injection.Type: GrantFiled: June 12, 2017Date of Patent: October 22, 2019Inventor: Mansour S. Bader
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Patent number: 10427957Abstract: Separation processes using osmotically driven membrane systems are disclosed generally involving the extraction of solvent from a first solution to concentrate solute by using a second concentrated solution to draw the solvent from the first solution across a semi-permeable membrane.Type: GrantFiled: July 14, 2017Date of Patent: October 1, 2019Assignee: OASYS WATER LLCInventors: Nathan T. Hancock, Marek S. Nowosielski-Slepowron
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Patent number: 10414667Abstract: A process for the recovery of sodium sulfate from water, in particular from water deriving from a silica manufacturing process.Type: GrantFiled: June 1, 2016Date of Patent: September 17, 2019Assignee: RHODIA OPERATIONSInventors: Dominique Horbez, Enrico Drioli
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Patent number: 10390500Abstract: Presented herein are membranes for use in separating solids including salts from water. One application of such membranes is in a sub-surface irrigation system that that utilizes a saline or tainted water as a feed source. In various embodiments, the membranes operate on a solution diffusion principle. In other embodiments the membranes operate on an ultrafiltration principle and/or a solution diffusion principle. In any embodiment, the membranes operate similar to pervaporation membranes suitable for non-pressure driven systems. The membranes are designed to provide increased flux rate while separating solids such as salts from water.Type: GrantFiled: October 10, 2016Date of Patent: August 27, 2019Assignee: KC HARVEY ENVIRONMENTAL, LLCInventors: Jonathan A. Brant, Kevin Harvey
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Patent number: 10392329Abstract: A method and a device for condensing a water-soluble organic matter, which can collect a highly concentrated water-soluble organic matter, save energy, and reduce cost of the device by reducing a membrane area. According to the present invention, the permeability ratio of a vapor-permeation separation membrane disposed at least immediately before a final outlet on a non-permeation side in the separation membrane device is lower than those of the other vapor-permeation separation membranes while a hybrid process combining distillation by the distillation column with membrane separation by the separation membrane devices including a plurality of vapor-permeation separation membranes is used and energy saving performance is maintained. Therefore, a highly concentrated and condensed component of a water-soluble organic matter is obtained.Type: GrantFiled: April 30, 2014Date of Patent: August 27, 2019Assignees: WASEDA UNIVERSITY, MITSUBISHI CHEMICAL CORPORATION, HITACHI ZOSEN CORPORATION, CHIYODA CORPORATIONInventors: Masahiko Matsukata, Kenichi Kawazuishi, Kenichi Mimura
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Patent number: 10377696Abstract: An apparatus for separating dimethyl carbonate using pervaporation includes: an atmospheric distillation column and a high pressure distillation column distilling a mixture containing dimethyl carbonate and methanol and separating dimethyl carbonate from the mixture; and a pervaporation membrane module disposed between the atmospheric distillation column and the high pressure distillation column and allowing for permeation of the methanol to separate the methanol from the mixture, thereby reducing heat consumption and a process cost as compared to the case of only using an existing pressure swing distillation method.Type: GrantFiled: December 24, 2015Date of Patent: August 13, 2019Assignees: POSCO, NEDERLANDSE ORGANISATIE VOOR TOEGEPAST-NATUURWETENSCHAPPELIJK ONDERZOEK TNO, RESEARCH INSTITUTE OF INDUSTRIAL SCIENCE & TECHNOLOGYInventors: Joon-Hyun Baik, Jaap Ferdinand Vente, Anatolie Motelica
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Patent number: 10359012Abstract: An internal combustion engine includes, in addition to an LPL-EGR system, two water vapor separation film modules for fresh air and for EGR gas. One module 34 is connected to a pressure reducing pump 40 through a suction passage 38. Other module 36 is connected to a pressure reducing pump 44 through a suction passage 42. A condenser 54 that condenses water vapor that flows through the suction passage 38 is provided in the suction passage 38. A water tank 56 that temporarily accumulates condensed water that is discharged from the condenser 54 is provided on a downstream side relative to the condenser 54. The water tank 56 is connected to injectors 60 that inject water from the water tank 56 into intake ports of respective cylinders or into respective cylinders.Type: GrantFiled: May 10, 2017Date of Patent: July 23, 2019Assignee: Toyota Jidosha Kabushiki KaishaInventor: Kazuki Kikuchi
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Patent number: 10308529Abstract: The present invention relates to a desalination apparatus and a desalination method using the same. In one specific embodiment, the desalination apparatus comprises: a forward osmosis unit having a draw-solution part into which seawater flows, and a raw water part into which raw water flows, and having an osmosis membrane, formed between the draw solution part and the raw water part, so as to respectively generate first treated water and first concentrated water; a capacitive deionization unit, which is connected to the draw solution part through a first inflow passage, and into which the first treated water of the draw solution part flows so as to generate second treated water; and an electrodialysis unit, which is connected to the raw water part through a second inflow passage, and into which the first concentrated water of the raw water part flows so as to generate third treated water.Type: GrantFiled: June 23, 2016Date of Patent: June 4, 2019Assignee: Korea Electric Power CorporationInventors: Pill Yang Park, Jae Bong Lee, Seok Won Yoon, Ki Hyoung Kim, Kyu Il Kim
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Patent number: 10252923Abstract: Water treatment systems including electrically-driven and pressure-driven separation apparatus configured to produce a first treated water suitable for use as irrigation water and a second treated water suitable for use as potable water from one of brackish water and seawater and methods of operation of same.Type: GrantFiled: August 30, 2012Date of Patent: April 9, 2019Assignee: Evoqua Water Technologies LLCInventors: Gary C. Ganzi, Evgeniya Freydina, Anil D. Jha, Li-Shiang Liang, Frederick C. Wilkins
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Patent number: 10227433Abstract: A variety of polycycloalkyl polynorbornene monomers and polymers derived therefrom are disclosed and claimed. The polymers and copolymers as disclosed herein are useful for forming pervaporation membranes, among other uses.Type: GrantFiled: September 6, 2016Date of Patent: March 12, 2019Assignee: PROMERUS, LLCInventors: Andrew Bell, Leah Langsdorf, Oleksandr Burtovyy
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Patent number: 10179310Abstract: A natural-gas purification apparatus includes: a compressor that adjusts the pressure of natural gas, and a separation device that separates natural-gas liquid and carbon dioxide from the natural gas after the pressure adjustment by the compressor through a natural-gas-liquid separation membrane and a carbon-dioxide separation membrane.Type: GrantFiled: March 31, 2017Date of Patent: January 15, 2019Assignee: MITSUBISHI HEAVY INDUSTRIES, LTD.Inventors: Wataru Matsubara, Masayuki Eda, Shintaro Honjo, Susumu Okino, Hiromi Nakatani, Masaki Yushima
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Patent number: 10174404Abstract: Nanofiltration can be used to improve a hydrometallurgical process in which valuable metal is extracted from ore or tailings by leaching with a suitable lixiviant. The process requires at least two nanofiltration subsystems in which raffinate from a solvent extraction process is treated in a nanofiltration subsystem, after which permeate therefrom is combined with a pregnant solution stream and is treated in a second nanofiltration subsystem. This arrangement can lead to advantages in the amount of lixiviant recovered, in the raw materials required, in the effluent produced, in the size of plant, and in overall cost.Type: GrantFiled: August 14, 2013Date of Patent: January 8, 2019Assignee: Chemetics Inc.Inventors: Siamak Lashkari, Felix Mok, Ganapathy Ramasubbu, Anthony Mumba
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Patent number: 10143971Abstract: A system for crystallizing a material that is dissolved in a solvent includes: a crystallization device through which a solution that is to be concentrated flows, the solution including the solvent containing the material to be crystallized and dissolved in the solvent, and a liquid having a lower temperature than the solution to be concentrated. The system includes at least one flow channel guiding the solution to be concentrated and at least one flow channel guiding the liquid, where the inner space of each respective flow channel guiding the liquid is delimited at least in part by a membrane wall that is permeable for the vaporous solvent, where a vapor pressure difference enables the solvent to pass from the solution to be concentrated across the membrane wall.Type: GrantFiled: January 9, 2014Date of Patent: December 4, 2018Assignee: Major Bravo LimitedInventor: Wolfgang Heinzl
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Patent number: 10054022Abstract: An exhaust after-treatment system for treating an exhaust produced by an engine. The exhaust after-treatment system includes an exhaust passage, at least one catalytic exhaust after-treatment component in communication with the exhaust passage for treating the exhaust, and a water-removal device in communication with the exhaust passage that receives a portion of the exhaust therein at a location positioned upstream from the catalytic exhaust after-treatment component. The water-removal device is defined by a housing that includes a water-removal membrane that separates water from the portion of the exhaust to provide a permeate that is enriched with water, and to produce a retentate that is water depleted that facilitates the treating of the exhaust by the catalytic exhaust after-treatment component.Type: GrantFiled: February 23, 2016Date of Patent: August 21, 2018Assignee: Tenneco Automotive Operating Company Inc.Inventor: Michael C. Bradford
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Patent number: 9981848Abstract: An enrichment apparatus and process for enriching a hydrogen sulfide concentration in an acid gas stream to create a hydrogen sulfide rich stream for feed to a Claus. The enrichment apparatus comprises a hydrocarbon selective separation unit operable to separate the acid gas stream into a hydrocarbon rich stream and a purified acid gas stream, wherein the acid gas stream comprises hydrogen sulfide, carbon dioxide, and hydrocarbons, a hydrogen sulfide selective separation unit operable to separate the purified acid gas stream to create the hydrogen sulfide rich stream and a hydrogen sulfide lean stream, the hydrogen sulfide rich stream having a concentration of hydrogen sulfide, and the Claus unit operable to recover sulfur from the carbon dioxide lean stream. The enrichment apparatus can include a carbon dioxide selective separation unit in fluid communication with the hydrogen sulfide selective separation unit, operable to separate the hydrogen sulfide rich stream.Type: GrantFiled: January 30, 2017Date of Patent: May 29, 2018Assignee: SAUDI ARABIAN OIL COMPANYInventors: Jean-Pierre R. Ballaguet, Milind M. Vaidya, Sebastien A. Duval, Aadesh Harale, Anwar H. Khawajah, Veera Venkata R. Tammana
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Patent number: 9975084Abstract: A process for separating components or a fluid mixture using membranes comprising a selective layer made from copolymers of an amorphous per fluorinated dioxolane and a fluorovinyl monomer. The resulting membranes have superior selectivity performance for certain fluid components of interest while maintaining fast permeance compared to membranes prepared using conventional perfluoropolymers, such as Teflon® AF, Hyflon® AD, and Cytop®.Type: GrantFiled: May 30, 2017Date of Patent: May 22, 2018Assignees: Membrane Technology and Research, Inc., New York UniversityInventors: Timothy C Merkel, Hao Zhang, Zhenjie He, Johannes G Wijmans, Yoshiyuki Okamoto
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Patent number: 9944576Abstract: The present invention provides a method for selectively separating a straight-chain conjugated diene with high purity from a mixture containing the straight-chain conjugated diene and at least one type of straight-chain olefin. The method involves separating the straight-chain conjugated diene from the mixture containing the straight-chain conjugated diene and the straight-chain olefin using a zeolite membrane composite. The composite contains a porous support and a zeolite layer formed on the surface and in the fine pores of the support, and the zeolite contains an alkali metal cation.Type: GrantFiled: September 30, 2015Date of Patent: April 17, 2018Assignees: WASEDA UNIVERSITY, JXTG Nippon Oil & Energy CorporationInventors: Masahiko Matsukata, Motomu Sakai, Yasuhito Sasaki, Tatsuo Hamamatsu, Nobuhiro Kimura
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Patent number: 9834315Abstract: An aircraft fuel deoxygenation system includes a boost pump, a contactor-separator, and a centrifuge-separator pump. The boost pump is adapted to receive fuel from a fuel source and inert gas from an inert gas source, and is configured to mix the fuel and inert gas and supply a fuel/gas mixture. The contactor-separator is coupled to receive the fuel/gas mixture and is configured to remove oxygen from the fuel and thereby generate and supply deoxygenated fuel with entrained purge gas and separated purge gas. The centrifuge-separator pump is coupled to receive the deoxygenated fuel with entrained purge gas and is configured to separate and remove the entrained purge gas from the deoxygenated fuel and supply the deoxygenated fuel and additional purge gas.Type: GrantFiled: December 15, 2014Date of Patent: December 5, 2017Assignee: HONEYWELL INTERNATIONAL INC.Inventors: Charles Lo, Eric Blumer, Dan Laboda, Alexander Bershitsky
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Patent number: 9783467Abstract: A process for treating an effluent gas stream arising from a manufacturing operation that produces an olefin or an olefin derivative to recover unreacted olefin. The process involves compressing the effluent gas stream, which comprises an olefin, a paraffin, and a third gas, to produce a first compressed stream, then directing the first compressed stream to a membrane separation pretreatment step. The permeate stream withdrawn from this step is enriched in olefin and is sent to a second compressor, which produces a second compressed stream that is then cooled and condensed. The condensation step produces a liquid condensate and an uncondensed gas stream. The uncondensed gas stream undergoes a second membrane separation step to produce another olefin-enriched permeate stream, which is recirculated within the process prior to the second compression step, and an olefin-depleted residue stream, which may be purged from the process.Type: GrantFiled: November 2, 2016Date of Patent: October 10, 2017Assignee: Membrane Technology and Research, Inc.Inventor: Paul Su
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Patent number: 9770678Abstract: Described is a method for vacuum degassing of a liquid such as a solvent for a liquid chromatography system. The method includes modulating application of a vacuum to a fluid channel of a degasser so that each volume of a liquid drawn from the degasser experiences a residence time that is equal to the residence times of the other volumes. The residence time is determined as a time that the volume resides in the fluid channel under application of the vacuum and to a magnitude of the applied vacuum. The method is advantageous for use with liquid chromatography systems where differences in the diffusion rates of solvents into the degasser vacuum can otherwise introduce error into the composition gradient of a mobile phase.Type: GrantFiled: April 15, 2015Date of Patent: September 26, 2017Assignee: WATERS TECHNOLOGIES CORPORATIONInventors: Michael R. Jackson, Christopher Seith, Steven J. Ciavarini, Kara O'Donnell, John Angelosanto, John Leason
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Patent number: 9758458Abstract: Provided are a method of and a device for purifying isopropyl alcohol. Water may be effectively removed from a feed including water and isopropyl alcohol while consuming a minimum amount of energy, and therefore, a high-purity isopropyl alcohol may be obtained.Type: GrantFiled: August 20, 2014Date of Patent: September 12, 2017Assignee: LG CHEM, LTD.Inventors: Jong Suh Park, Sung Kyu Lee, Joon Ho Shin, Jong Ku Lee
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Patent number: 9744499Abstract: Reverse osmosis membranes made by interfacial polymerization of a monomer in a nonpolar (e.g. organic) phase together with a monomer in a polar (e.g. aqueous) phase on a porous support membrane. Interfacial polymerization process is disclosed for preparing a highly permeable RO membrane, comprising: contacting on a porous support membrane, a) a first solution containing 1,3-diaminobenzene, and b) a second solution containing trimesoyl chloride, wherein at least one of solutions a) and b) contains nanoparticles when said solutions are first contacted, and recovering a highly permeable RO membrane.Type: GrantFiled: October 8, 2015Date of Patent: August 29, 2017Assignee: LG NANOH2O, INC.Inventors: Christopher James Kurth, Jeffrey Alan Koehler, Meijuan Zhou, Brett Anderson Holmberg, Robert Leon Burk
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Patent number: 9724650Abstract: Disclosed are copolymers which are useful in hydrophilically modifying porous fluoropolymer supports. An example of the copolymers is: Also disclosed are a method of preparing such copolymers, a method of modifying porous fluoropolymer surfaces, and hydrophilic fluoropolymer porous membranes prepared therefrom. Also disclosed is a method of filtering fluids by the use of the hydrophilic fluoropolymer porous membranes.Type: GrantFiled: March 31, 2015Date of Patent: August 8, 2017Assignee: Pall CorporationInventors: Khaled Abdel-Hakim Helmy Aamer, Jian Qiu, Hassan Ait-Haddou
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Patent number: 9649603Abstract: Disclosed are copolymers suitable for hydrophilically modifying the surface of fluoropolymer membranes. An example of the copolymers is: Also disclosed are a method of preparing the copolymers, a method of hydrophilically modifying porous fluoropolymer supports, hydrophilic porous fluoropolymer membranes prepared from the copolymers, and a method of filtering fluids by the use of the hydrophilic porous fluoropolymer membranes.Type: GrantFiled: March 31, 2015Date of Patent: May 16, 2017Assignee: Pall CorporationInventors: Hassan Ait-Haddou, Khaled Abdel-Hakim Helmy Aamer, Jian Qiu, Frank Okezie Onyemauwa, Marcin Stasiak
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Patent number: 9643131Abstract: Disclosed are hydrophilic porous PTFE membranes comprising PTFE and an amphiphilic copolymer, for example, a copolymer of the formula: wherein m and n are as described herein. Also disclosed are a method of preparing hydrophilic porous PTFE membranes and a method of filtering fluids through such membranes.Type: GrantFiled: July 31, 2015Date of Patent: May 9, 2017Assignee: Pall CorporationInventors: Khaled Abdel-Hakim Helmy Aamer, Hassan Ait-Haddou, Marcin Stasiak, Amarnauth Singh
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Patent number: 9636641Abstract: Disclosed are polymers suitable for hydrophilically modifying the surface of porous fluoropolymer supports, for example, a copolymer of the formula: Also disclosed are a method of preparing the polymers, a method of hydrophilically modifying porous fluoropolymer supports, hydrophilic fluoropolymer porous membranes prepared from the polymers, and a method of filtering fluids through the porous membranes.Type: GrantFiled: March 31, 2015Date of Patent: May 2, 2017Assignee: Pall CorporationInventors: Khaled Abdel-Hakim Helmy Aamer, Jian Qiu, Hassan Ait-Haddou
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Patent number: 9587112Abstract: According to the present invention, an aromatic polysulfone resin is offered which is suitable as film material, especially in porous membranes. The aromatic polysulfone resin of the present invention has a reduced viscosity of 0.55-0.65 dL/g, and preferably 0.58-0.62 dL/g, number average molecular weight (Mn) of 22000 or more, and preferably 23500 or more, and a value of the ratio of weight average molecular weight (Mw) relative to number average molecular weight (Mn) of 2.54 or less, and preferably 2.50 or less.Type: GrantFiled: September 14, 2010Date of Patent: March 7, 2017Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Yusaku Kohinata, Hiroshi Harada
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Patent number: 9403102Abstract: A heat exchange system may include a first heat exchange circuit and a second heat exchange circuit. The first heat exchange circuit may circulate a first working fluid sequentially through a first heat exchanger, a second heat exchanger and a membrane contactor. The second heat exchange circuit may direct a second working fluid sequentially through the first heat exchanger and the membrane contactor, where the second working fluid includes solute and solvent. The first heat exchanger and the membrane contactor may transfer heat energy from the second working fluid to the first working fluid, and the second heat exchanger may transfer heat energy from the first working fluid to a third working fluid. The membrane contactor may extract a portion of the solvent from the second working fluid.Type: GrantFiled: February 13, 2012Date of Patent: August 2, 2016Assignee: United Technologies CorporationInventors: Hailing Wu, Zidu Ma