And Liquid Testing Or Volume Measuring Patents (Class 210/662)
  • Publication number: 20070227976
    Abstract: The present invention realizes an ion exchange apparatus capable of enhancing the reliability of regeneration operation. Further, the present invention realizes an ion exchange apparatus capable of simplifying the construction of a salt water supply device. The ion exchange apparatus includes a resin bed housing part (2) in which an ion exchange resin bed (5) is housed; a flow passage control valve (3) for switching between a water service operation and a regeneration operation; and a salt water tank (40) for reserving salt water to be used in regeneration, the flow passage control valve (3) being connected to the salt water tank (40) through a salt water supply line (31), in which the salt water supply line (31) is provided with a flow detecting unit (48) for detecting a flow rate in a direction of supplying salt water and a flow rate in a direction of supplying refill water.
    Type: Application
    Filed: March 23, 2007
    Publication date: October 4, 2007
    Inventors: Hideo Furukawa, Hajime Abe, Makoto Hato, Hironao Kato, Kazutaka Baba
  • Patent number: 7273555
    Abstract: A process for continuous countercurrent ion exchange comprises piping a contaminated feed stream into a closed loop ion exchange contactor. The contactor is an ion exchange bed that has three or more reaction segments. The segments are comprised of at least an adsorption segment for treating the contaminated feed stream, a regeneration segment for stripping the contaminant ions from the resin bed, and a pulse segment for advancing the resin bed. Simultaneously, the feed stream is moved through the contactor in the same direction as the regeneration stream. Measuring the quality of this treated feed stream after it exits the contactor monitors the treatment capacity of the resin bed. In response to this quality measurement, the regenerated resin bed is advanced in the pulse segment of the contactor. The spent brine is recycled back to the contactor until the final effluent brine is highly concentrated. After the resin stops advancing, the feed stream and regeneration stream resume flow.
    Type: Grant
    Filed: May 30, 2003
    Date of Patent: September 25, 2007
    Assignee: Severn Trent Services, Inc.
    Inventor: Richard S. Dennis
  • Patent number: 7264837
    Abstract: The deacidification of citrus juice with ion exchange resin is described. Maintaining a high acid condition of the juice is achieved by passing the juice through regenerated resin that is preconditioned with an aqueous food-grade acid, preferably citric acid. Additionally or optionally, an early bed volume or multiple early bed volumes of juice flow are at a rapid flow rate. The products obtained also are described, and they may be any deacidified citrus juice or juice blend where the pH of the juice does not rise above that of an acid food pH for the juice during deacidification. In preferred embodiments, the juice product is orange juice. In another preferred embodiment, the conditioning process is used to provide a deacidified citrus juice product while avoiding raising the pH of any portion of the juice to 4.6 or above so as to control microbial growth of the juice.
    Type: Grant
    Filed: April 2, 2003
    Date of Patent: September 4, 2007
    Assignee: Tropicana Products, Inc.
    Inventors: Yongsoo Chung, Osvaldo A. Chu, Marcelo Perez Alvarez
  • Patent number: 7247242
    Abstract: Methods for removing arsenic from water by addition of inexpensive and commonly available magnesium oxide, magnesium hydroxide, calcium oxide, or calcium hydroxide to the water. The hydroxide has a strong chemical affinity for arsenic and rapidly adsorbs arsenic, even in the presence of carbonate in the water. Simple and commercially available mechanical methods for removal of magnesium hydroxide particles with adsorbed arsenic from drinking water can be used, including filtration, dissolved air flotation, vortex separation, or centrifugal separation. A method for continuous removal of arsenic from water is provided. Also provided is a method for concentrating arsenic in a water sample to facilitate quantification of arsenic, by means of magnesium or calcium hydroxide adsorption.
    Type: Grant
    Filed: October 25, 2001
    Date of Patent: July 24, 2007
    Assignee: Sandia Corporation
    Inventors: Robert C. Moore, D. Richard Anderson
  • Patent number: 7238735
    Abstract: A process for producing an aqueous dispersion of purified polytetrafluoroethylene (PTFE), comprising passing a crude aqueous dispersion of PTFE comprising from 10 to 50 mass % of PTFE fine particles having an average particle diameter of from 0.1 to 0.5 ?m, from 0.05 to 1.0 mass %, based on PTFE, of a fluorine-containing carboxylic acid salt (APFO) and from 2 to 20 mass %, based on PTFE, of a nonionic surfactant through a column packed with a weak basic AER upward at a linear velocity of 0.1 to 2 mm/sec with a contact time of 0.2 to 4 hours to reduce the APFO concentration. The process can increase the absorption of APFO by the anion exchange resin, prevents agglomeration of PTFE during passage and makes it easy to elute the absorbed APFO.
    Type: Grant
    Filed: November 21, 2005
    Date of Patent: July 3, 2007
    Assignee: Asahi Glass Company, Limited
    Inventors: Jun Hoshikawa, Shinya Higuchi, Yasuhiko Matsuoka
  • Patent number: 7192526
    Abstract: Method of optimizing the operation of a unit intended for separation of the components of a feed (xylenes) by simulated countercurrent in hybrid operating mode. The method allows to minimize the solvent ratio and to maximize the capacity of the separation unit while keeping product specifications such as purity and yield constant. It has been verified that these two objectives cannot be reached simultaneously and it is recommended to operate with a minimum solvent ratio while guaranteeing a high capacity compatible with stable operation of the separation unit. These optimization objectives are reached while keeping good stability around the optimum point thus defined, by using a known operation control process such as the one described in patent EP-875,268 for example.
    Type: Grant
    Filed: July 23, 2003
    Date of Patent: March 20, 2007
    Assignee: Institut Francais du Petrole
    Inventors: Nicolas Couenne, Luc Wolff
  • Patent number: 6926835
    Abstract: Sampling pipes 21 and 22 are inserted, separated from outlet openings, into first and second water softeners 4 and 11. Raw water flows through first water softener 4, and raw water does not flow through second water softener 11. Once the hardness component concentration of the treatment water sampled by sampling pipe 21 reaches a specified concentration, the watercourse selection of valves 2 and 6 and valves 9 and 13 are switched, causing raw water to flow through second water softener 11. First water softener 4 is regenerated by salt water from a salt water chamber 14. The resulting water softening device prevents the leaking of hardness components, even with there is a fluctuation in the water quality of the raw water or when there is performance deterioration in the ion exchange resin.
    Type: Grant
    Filed: July 19, 2001
    Date of Patent: August 9, 2005
    Assignee: Kurita Water Industries, Ltd.
    Inventors: Hiroshi Iizuka, Akikazu Yamamoto, Tutomu Kurokawa
  • Patent number: 6911152
    Abstract: Disclosed herein are a high-sensitivity method and apparatus for monitoring the concentration or inflow of impurities in circulating water of a circulating water system, which can remarkably improve the measurement sensitivity by converting carbonate ions of low conductivity into chlorine or sulfate ions of increased conductivity, and which can measure the inflow of air or organic substances and the amount of inflow in a simple and efficient manner in real-time. The method of the present invention comprises the steps of: increasing a content of strong acids in sample water and thus increasing equivalent conductivity of the impurities, by utilizing cation exchange resin together with anion exchange resin, in which cations of the sample water are adsorbed on the cation exchange resin to form strong acids while weakly acidic anions of low dissociation degree in the sample water are adsorbed on the anion exchange resin to form strong acids; and measuring the increased conductivity of the impurities.
    Type: Grant
    Filed: September 5, 2002
    Date of Patent: June 28, 2005
    Assignee: Korea Electric Power Corporation
    Inventors: Woo-young Kim, Tae-won Lee, Jeom-in Baek, Yu-chan Yoon, Seung-min Lee
  • Patent number: 6884356
    Abstract: Methods and apparatus (50) are disclosed for accurately measuring low concentrations of boron in deionized water utilizing the chemical reaction of boric acid with a polyol by injecting very small plugs of concentrated polyol into streams of boron containing and non-boron containing water samples to produce an ionized acids product, and then measuring the conductivity difference (delta conductivity), corrected for interfering or extraneous factors which can effect conductivity, between such boron containing and non-boron containing samples using a conductivity and temperature detector (23).
    Type: Grant
    Filed: August 4, 2001
    Date of Patent: April 26, 2005
    Assignee: Sievers Instruments, Inc.
    Inventors: Paul P. Kosenka, Kevin J. O'Neill, Richard D. Godec
  • Patent number: 6814872
    Abstract: Regeneration controller and method for controlling regeneration of a water softener are provided. The controller includes a water meter configured to output a signal indicative of the volume of influent water received by the water softener. A water-hardness indicator, such as a conductivity meter or ion-selective electrode, is configured to output a signal indicative of a degree of hardness of the influent water. A processor is coupled to receive the respective signals from the water meter and the hardness indicator. The processor is further configured to calculate a value indicative of the total level of hardness removed by the water softener. A comparator is coupled to receive a signal indicative of the quantity of resin capacity of the water softener. The comparator is further configured to receive the value indicative of total hardness to issue a regeneration command based on comparing the resin capacity relative to the value of total hardness.
    Type: Grant
    Filed: December 3, 2002
    Date of Patent: November 9, 2004
    Assignee: General Electric Company
    Inventor: James Rulon Young Rawson
  • Patent number: 6790362
    Abstract: The present invention provides a controller for a water softener having an ion exchange resin capable of receiving hard water ions from hard water during a softening step and releasing the hard water ions during a regeneration step. The controller includes a processor programmed to cause termination of the softening step and initiate the regeneration step when both a first and a second condition are met. The first condition is met when the resin is saturated with hard water ions, and the second condition is met when current demand for soft water is at or below a prescribed flow rate.
    Type: Grant
    Filed: January 11, 2002
    Date of Patent: September 14, 2004
    Assignee: Culligan International Company
    Inventors: Lance FitzGerald, John N. VanNewenhizen
  • Patent number: 6767468
    Abstract: A process for removing uranium/vanadium-based contaminants from groundwater using a primary in-ground treatment media and a pretreatment media that chemically adjusts the groundwater contaminant to provide for optimum treatment by the primary treatment media.
    Type: Grant
    Filed: July 31, 2002
    Date of Patent: July 27, 2004
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Donald R. Metzler, Stanley Morrison
  • Patent number: 6762057
    Abstract: A sample separation apparatus including a porous, or rough, capillary column. The porous capillary column includes a matrix which defines pores, and may be formed from a material such as porous silicon. Alternatively, the capillary column may have a rough surface of hemispherical grain silicon. The capillary column is defined in a surface of a substrate, such as silicon. The sample separation apparatus may include a stationary phase or a capture substrate disposed on the surfaces thereof. The sample separation apparatus may also include a detector positioned proximate the capillary column. A variation of the sample separation apparatus includes an electrode proximate each end of the capillary column. The sample separation apparatus may be employed to effect various types of chromatographic separation, electrophoretic separation, and analyte identification.
    Type: Grant
    Filed: November 18, 1999
    Date of Patent: July 13, 2004
    Assignee: Micron Technology, Inc.
    Inventor: Terry L. Gilton
  • Patent number: 6746609
    Abstract: A process for treating cooling tower water in a system which includes a recirculated evaporative cooling water stream and a source of make-up water. A side stream is taken off of the source of make-up water and the side stream is directed to either a strong acid cation exchange resin unit and/or to a weak acid cation exchange resin unit, after which it is returned to the make-up water line. The pH of saturation is determined for the recirculated evaporative cooling water as is the pH. Depending upon the difference between the pH and the pH of saturation, the side stream of the make-up water is opened or closed and directed to one or both of the cation exchange units.
    Type: Grant
    Filed: August 21, 2002
    Date of Patent: June 8, 2004
    Inventor: Berile B. Stander
  • Publication number: 20040104175
    Abstract: Regeneration controller and method for controlling regeneration of a water softener are provided. The controller includes a water meter configured to output a signal indicative of the volume of influent water received by the water softener. A water-hardness indicator, such as a conductivity meter or ion-selective electrode, is configured to output a signal indicative of a degree of hardness of the influent water. A processor is coupled to receive the respective signals from the water meter and the hardness indicator. The processor is further configured to calculate a value indicative of the total level of hardness removed by the water softener. A comparator is coupled to receive a signal indicative of the quantity of resin capacity of the water softener. The comparator is further configured to receive the value indicative of total hardness to issue a regeneration command based on comparing the resin capacity relative to the value of total hardness.
    Type: Application
    Filed: December 3, 2002
    Publication date: June 3, 2004
    Applicant: General Electric Company
    Inventor: James Rulon Young Rawson
  • Patent number: 6736976
    Abstract: A fluid treatment device for reducing the level of a chemical compound in a fluid. The device comprises: a fluid inlet; a fluid outlet; a flow-through fluid treatment zone having comprising: a radiation source, an adsorbent and a photocatalyst. The fluid treatment zone is reversibly operable between: (i) a first mode in which the fluid flows in a first direction and at least a portion of the chemical compound is adsorbed on the adsorbent; and (ii) a second mode in which the fluid flows in a second direction different from the first direction in which the absorbed chemical compound is exposed to radiation from the radiation resulting in photooxidation of the chemical compound.
    Type: Grant
    Filed: April 19, 2001
    Date of Patent: May 18, 2004
    Inventors: Apostolos Kantzas, Cooper H. Langford, Amit Bhargava, Alex Starosud
  • Patent number: 6706193
    Abstract: Fluorinated emulsifiers can be recovered from an aqueous phase containing small amounts of fluoropolymer particles by treating the aqueous phase with a small amount of a nonionic surface-active agent, bringing the aqueous phase adjusted in this way into contact with an anionic exchanger resin, and liberating the adsorbed emulsifier from the exchanger resin. The finely divided fluoropolymer can be precipitated quantitatively in the untreated aqueous phase or the eluate using flocculating agents.
    Type: Grant
    Filed: December 11, 2001
    Date of Patent: March 16, 2004
    Assignee: 3M Innovative Properties Company
    Inventors: Georg Burkard, Klaus Hintzer, Gernot Löhr
  • Publication number: 20040035795
    Abstract: A process for treating cooling tower water in a system which includes a recirculated evaporative cooling water stream and a source of make-up water. A side stream is taken off of the source of make-up water and the side stream is directed to either a strong acid cation exchange resin unit and/or to a weak acid cation exchange resin unit, after which it is returned to the make-up water line. The pH of saturation is determined for the recirculated evaporative cooling water as is the pH. Depending upon the difference between the pH and the pH of saturation, the side stream of the make-up water is opened or closed and directed to one or both of the cation exchange units.
    Type: Application
    Filed: August 21, 2002
    Publication date: February 26, 2004
    Inventor: Berile B. Stander
  • Patent number: 6696301
    Abstract: The present invention provides a highly sensitive and practical method for the determination of and the separation of 5-hydroxycreatinine from a sample of bodily fluid. The method of the present invention is useful as a method for the testing of renal dysfunction, such as uremia, chronic nephritis and closure of the urinary tract, etc. A separation solvent of pH 4.1 to 4.6 is used in a high performance liquid chromatography step that is carried out using a strongly acidic cation-exchange resin, such as a styrene-divinylbenzene resin. The determination sensitivity is a concentration of only about 0.02 &mgr;M, whereby 5-hydroxycreatinine in blood of healthy persons can be determined for the first time. Moreover, only one separation solvent, such as a citrate, need be used and the cycle time for analysis is only about 14 minutes per measurement. Thus, a practitioner using one set of HPLC equipment is able to carry out about 100 determinations per day.
    Type: Grant
    Filed: October 2, 2001
    Date of Patent: February 24, 2004
    Assignee: Nippon Zoki Pharmaceutical Co., Ltd.
    Inventors: Ko Nakamura, Katsumi Kawano
  • Publication number: 20040020858
    Abstract: The invention concerns a method for controlling a nanofiltration or reverse osmosis module system designed for treating a supply fluid or for detecting living micro-organism leaks, each module comprising nanofiltration or reverse osmosis membranes and joints connecting said membranes, including steps which consist in: selecting in the supply fluid a dissolved compound present in significant amount but normally highly retained by the membranes; measuring the concentration value of said compound in a downstream zone of a module of said system; comparing said measured value with a reference value; and recognising the existence of a fault in said zone of the system when said measured value is higher than the reference value.
    Type: Application
    Filed: June 16, 2003
    Publication date: February 5, 2004
    Inventors: Claire Ventresque, Valerie Gisclon-Lallemand, Guy Bablon, Gerard Chagneau
  • Patent number: 6652754
    Abstract: A process for determining by simulation the optimum stabilization conditions of a simulated moving bed (SMB) separation system allows to obtain set values for the purity of an extracted constituent and for the efficiency. In order to determine the optimum flow rates, a single simulation is carried out, which includes a succession of stages intended for rectification of the fluid flow rates during limited time intervals (T), including each, after each time interval, comparison of the respective purity degrees and efficiencies obtained, resulting from situations stemming from simulations over a time interval (&Dgr;t) where rectifications are applied to at least one flow rate, with those of a reference situation resulting from a simulation over the same time interval but without flow rate rectification, followed by a selection of flow rates aimed to minimize the quantity of impurities in the extract and the quantity of constituent in the raffinate.
    Type: Grant
    Filed: November 21, 2000
    Date of Patent: November 25, 2003
    Assignee: Institut Francais du Petrole
    Inventor: Didier Pavone
  • Patent number: 6652755
    Abstract: A simulated moving bed separation system is provided, in which a fluid circulation flow path can be washed for a short time. This system is provided with a circulation flow path having two or more packed beds connected in series and endlessly to each other, with desorbing-charging inlet, extract draw-out port, feedstock introducing port and raffinate draw-out port arranged in this order in the direction of flow of a circulation liquid, which are allowed to intermittently shift in the direction while being kept in this order, and with packed bed-washing pipes, valves and pumps. A desorbing liquid is introduced through the desorbing liquid introducing port into the circulation flow path. An extract rich in a strongly adsorptive constituent to be separated is drawn out through the extract draw-out port.
    Type: Grant
    Filed: April 1, 2002
    Date of Patent: November 25, 2003
    Assignee: Daicel Chemical Industries, Ltd.
    Inventor: Hirokazu Ikeda
  • Patent number: 6602421
    Abstract: A method for purifying contaminated water involves passing contaminated water through a porous bed of steel slag. The steel slag can be used to remove various contaminants or reduce the concentration of such contaminants, such as heavy metals (for example, hexavalent chromium), chlorinated organic compounds, and certain inorganic anions. The method preferably involves placing an underground barrier of a porous bed of steel slag in a flow path of contaminated groundwater then allowing contaminated groundwater to pass through the barrier to purify the contaminated groundwater. The slag particles may be used as produced with no further grinding necessary, although the slag may be passed through a sieve or sieves to obtain a set of slag particles having a median diameter of about ⅛ inch to 1 inch, and preferably between about ¼ inch to ⅜ inch. Due to the inherent permeability of slag, no additive need be mixed with the slag.
    Type: Grant
    Filed: July 1, 1999
    Date of Patent: August 5, 2003
    Inventor: James S. Smith
  • Publication number: 20030141246
    Abstract: The resist stripping waste liquid regenerating apparatus of the invention regenerates a resist stripping waste liquid to obtain a resist stripping regenerated liquid. The apparatus is provided with a membrane separating apparatus which employs a membrane with a molecular weight cutoff of 100-1500 to separate a resist stripping waste liquid into a concentrated liquid and a permeating liquid, an adjusting tank which stores the permeating liquid and adjusts the concentration of an alkanolamine and organic solvent, means for supplying the alkanolamine to the adjusting tank, and means for supplying the organic solvent to the adjusting tank. This construction adequately reduces the resist concentration of the permeating liquid since the resist in the resist stripping waste liquid cannot permeate the membrane. It is thereby possible to lessen the need for dilution of the resist concentration and thus satisfactorily reduce the amount of alkanolamine and organic solvent supplied to the adjusting tank.
    Type: Application
    Filed: November 27, 2002
    Publication date: July 31, 2003
    Inventors: Shu Ogawa, Yasuyuki Kobayakawa, Yoshiya Kitagawa, Makoto Kikukawa, Takayuki Kaneyasu
  • Publication number: 20030080063
    Abstract: Disclosed herein are a high-sensitivity method and apparatus for monitoring the concentration or inflow of impurities in circulating water of a circulating water system, which can remarkably improve the measurement sensitivity by converting carbonate ions of low conductivity into chlorine or sulfate ions of increased conductivity, and which can measure the inflow of air or organic substances and the amount of inflow in a simple and efficient manner in real-time. The method of the present invention comprises the steps of: increasing a content of strong acids in sample water and thus increasing equivalent conductivity of the impurities, by utilizing cation exchange resin together with anion exchange resin, in which cations of the sample water are adsorbed on the cation exchange resin to form strong acids while weakly acidic anions of low dissociation degree in the sample water are adsorbed on the anion exchange resin to form strong acids; and measuring the increased conductivity of the impurities.
    Type: Application
    Filed: September 5, 2002
    Publication date: May 1, 2003
    Inventors: Woo-Young Kim, Tae-won Lee, Jeom-in Baek, Yu-chan Yoon, Seung-min Lee
  • Patent number: 6548307
    Abstract: This invention provides a RP-HPLC method, for the determination of logPoct values, which combines ease of operation and high accuracy, and which has been shown to work for a set of 36 molecules largely comprised of drugs. The general features of the method are: i) compound sparing (≦1 mL of a 30-50 &mgr;g/mL solution needed), ii) rapid determinations (20 minutes on average), iii) low sensitivity to impurities, iv) wide lipophilicity range (6 logPoct units), v) good accuracy, vi) excellent reproducibility. A linear free energy relationship (LFER) analysis, based on solvation parameters, shows that the method encodes the same information obtained from a shake-flask logPoct determination. The value generated via this method is referred to as ElogPoct.
    Type: Grant
    Filed: February 13, 2001
    Date of Patent: April 15, 2003
    Assignee: Pfizer Inc.
    Inventors: Franco Lombardo, Marina Y. Shalaeva, Karl A. Tupper
  • Patent number: 6541273
    Abstract: Methods and apparatus are disclosed which are useful for detecting the presence of various pesticides, including aryl pyrazoles such as fipronil. Pesticide residues are extracted from a variety of samples, including soil and/or water samples using techniques well known to those of skill in the art. The samples are then concentrated, and transferred to an solid phase extraction cartridge. The SPE cartridge includes activated charcoal, silica gel, magnesium-silica gel and an amino-functional silica sorbent, or suitable equivalents thereof. After cleanup, the eluate containing the analyte of interest can be concentrated to a standard sample size and the amount of pesticide residues quantitated. In a preferred embodiment, the column chromatography materials are assembled in a solid phase extraction cartridge with frits between the chromatography materials. This facilitates the use of the cartridge in standard automated analytical equipment, for example, robotic equipment.
    Type: Grant
    Filed: November 9, 2000
    Date of Patent: April 1, 2003
    Assignee: Aventis CropScience, S.A.
    Inventor: Robert S. Plaisance
  • Publication number: 20030052060
    Abstract: A water softening apparatus (10) comprises a regeneration tank (12) and a brine tank (14). An ion exchange resin (26) is located within the regeneration tank (12) and salt (38) is located within the brine tank (14). Water mixes with the salt (38) in the brine tank (14) to form a brine solution. A tube (56) is connected with the brine tank (14) and receives a flow of brine solution from the brine tank (14). A sensor (86) is mounted in the tube (56) for sensing the conductivity of the brine solution as the brine solution flows through the tube (56). The sensor (86) generates a signal indicative of the conductivity of the brine solution. The conductivity of the brine solution is indicative of an amount of salt in the brine solution.
    Type: Application
    Filed: September 20, 2001
    Publication date: March 20, 2003
    Inventor: Paul A. Teel
  • Patent number: 6531063
    Abstract: A septic system and method for the removal of nitrogen contaminants, such as nitrates and ammonia, from a wastewater effluent. The system comprises one or more zeolite tanks which contain a regenerable, granulated zeolite material to receive wastewater effluent from a septic tank and to capture the nitrogen contaminants to provide a treated, decontaminated effluent to flow out of the tank into a leach field. The system includes a secondary treatment.tank to reduce suspended solids and the biological oxygen demand (BOD) of the wastewater effluent prior to introduction into the zeolite tank. The system also includes an ion sensor to monitor the ammonium ion concentration in the system and to signal the need to regenerate the zeolite tank with saline water.
    Type: Grant
    Filed: May 5, 2000
    Date of Patent: March 11, 2003
    Inventor: Jane Anne Rose
  • Patent number: 6531064
    Abstract: A system for remediating groundwater contaminated with radionuclides, consisting of an underground bed of crushed zeolites. Distribution pipes convey contaminated groundwater to the zeolite bed by means of a pump, which draws the contaminated water through wells from an underground plume of released waste mixed with groundwater. The radionuclides in the water undergo capture with the zeolite minerals and lock into the zeolite crystal lattice. After the contaminated water passes through the zeolite bed, it is collected by a series of collection pipes and conveyed to a sampling station, where it can be determined whether the water has been decontaminated sufficiently to discharge it by piping to a river outfall or back to the ground. When functioning, the system contains the released contaminants on the waste site and prevents further spread and migration of the contaminated water by means of the cone of depression created by the pumping well.
    Type: Grant
    Filed: April 4, 2000
    Date of Patent: March 11, 2003
    Inventor: Jane Anne Rose
  • Patent number: 6524863
    Abstract: Methods for calculating Log P values for organic compounds are disclosed. The methods allow identification of compounds in a library with a desired Log P value. The method can be used to minimize the number of compounds in a given combinatorial or lead generation library which need to be further characterized and/or assayed. The Log P value is preferably obtained while the purity of the compounds is being determined. Preferably, the Log P value is correlated to the retention time on an HPLC column, such that the retention time equals the Log P value.
    Type: Grant
    Filed: July 26, 2000
    Date of Patent: February 25, 2003
    Assignee: Scynexis Chemistry & Automation, Inc.
    Inventor: Jaleh Abedi
  • Patent number: 6521131
    Abstract: The disclosed invention relates to a method of disposing of mercury-containing wastewater containing mercury-complexing materials, comprising the steps of treating wastewater containing mercury ions with a strong oxidizing agent in a reaction chamber to produce pretreated wastewater by removing an effluent stream of pretreated wastewater from the reaction chamber; and passing the effluent stream of pretreated wastewater through a column packed with a mercury-selective adsorbent material to produce an effluent stream of wastewater having a reduced mercury content. The adsorbent material is a porous resin having immobilized mercury-selective chelating groups bound thereto. A particularly preferred adsorbent material is a crosslinked styrene-divinylbenzene copolymer having immobilized dithiocarbamate groups bound thereto.
    Type: Grant
    Filed: July 15, 1999
    Date of Patent: February 18, 2003
    Assignee: SolmeteX, Inc.
    Inventors: Richard A. Hamilton, Scott P. Fulton, Ted M. Shields
  • Publication number: 20030024863
    Abstract: The apparatus and methods of the present invention enable efficient and appropriate treatment of Urban Water Runoff, so that the treated Urban water Runoff can be can be introduced into public waterways without contaminating such waterways. The system apparatus utilizes adsorptive Organoclay media, mechanical filtration and ultraviolet sterilization. The methods and apparatus of the present invention remove contaminants from Urban Water Runoff to a level which enable the resulting effluent to meet appropriate standards for introducing the treated Urban water Runoff in to public waterways. The method and apparatus of water treatment of the present invention does not utilize chlorine containing compounds which, when combined with organic compounds can produce THM's that can become problematic when re-introduced to the downstream environment. The systems of the present invention can be made sufficiently compact so as to enable their use in remote locations.
    Type: Application
    Filed: March 29, 2002
    Publication date: February 6, 2003
    Inventors: Guy Timothy Gannon, Joseph Charles Gannon
  • Publication number: 20030010716
    Abstract: Systems and processes are provided that are useful for separating components from feed streams containing multiple components. Systems and processes of the present invention are based on simulated moving bed technology.
    Type: Application
    Filed: November 15, 2001
    Publication date: January 16, 2003
    Applicant: Purdue Research Foundation
    Inventor: Phillip C. Wankat
  • Patent number: 6498040
    Abstract: A high-performance liquid chromatography apparatus and a process for conversion of mobile phase, enabling a trace amount of sample for NMR analysis to be efficiently separated and prepared, includes steps of separating a target ingredient from the sample by the high-performance liquid chromatography, trapping the target ingredient in a trapping column using a different mobile phase, replacing water by deuterium oxide and eluting this target ingredient from the trapping column using deuterated solvent other than deuterium oxide.
    Type: Grant
    Filed: February 10, 2000
    Date of Patent: December 24, 2002
    Assignee: Eisai Co., Ltd.
    Inventors: Yumi Yokoyama, Naoya Kishi, Masayuki Tanaka, Naoki Asakawa
  • Patent number: 6495371
    Abstract: For anion analysis, the method includes: (a) flowing an aqueous liquid sample stream containing anions to be detected and cation hydroxide through a separator bed, (b) flowing the aqueous effluent from the separator bed through a flow-through suppressor, (c) flowing the effluent liquid from the suppressor past a detector, (d) recycling said liquid effluent from the detector through a cathode chamber proximate to the suppressor bed and separated by a first barrier, and (e) applying an electrical potential between the cathode and the anode. Water is electrolyzed at the anode to cause cations on the cation exchange resin to electromigrate toward the barrier and to be transported across the barrier toward the cathode while water in the cathode chamber is electrolyzed to generate hydroxide ions which combine with the transported cations to form cation hydroxide in the cathode chamber.
    Type: Grant
    Filed: June 8, 2001
    Date of Patent: December 17, 2002
    Assignee: Dionex Corporation
    Inventors: Hamish Small, Yan Liu, John M. Riviello, Nebojsa Avdalovic, Kannan Srinivasan
  • Patent number: 6482325
    Abstract: Abrasive components and clear fluids are separated from an aqueous chemical mechanical slurry used for planarization of semiconductor materials, to permit the reuse of the clear liquid effluent in non-process applications as well as for gray water for irrigation, process cooling water, or as make-up water for a reverse osmosis system, or safe disposal in the industrial waste stream, as desired. A solids detection device determines the concentration of abrasive solids in the aqueous waste effluent stream, and a diverter valve receives and diverts the entire aqueous waste effluent stream to at least one reuse water collection tank when the abrasive solids concentration is below a desired threshold, and diverts the entire aqueous waste effluent stream to at least one concentrate water collection tank when the abrasive solids concentration is greater than or equal to the threshold. With the additional use of ion exchange, the resulting water stream can be reused in high purity water applications.
    Type: Grant
    Filed: March 19, 2001
    Date of Patent: November 19, 2002
    Assignee: Linica Group, Ltd.
    Inventors: Gary L. Corlett, Edward T. Ferri, Jr., J. Tobin Geatz
  • Patent number: 6475390
    Abstract: A separation process is described for separation of a nutrient from divalent ions of an aqueous solution. The aqueous solution is contacted with an ion exchange resin that includes monovalent ions until the concentration of divalent ions in the aqueous solution has been depleted and an eluate is collected. The eluate is then subjected to a process, preferably a nanofiltration membrane process, capable of separating monovalent ions to obtain a permeate fraction including monovalent ions and a retentate fraction including the nutrient. The retentate fraction is then separated into fractions with at least one fraction including a major portion of the nutrient. The ion exchange resin is then regenerated by contacting it with a solution including the permeate fraction until a major portion of the divalent ions have been replaced by monovalent ions.
    Type: Grant
    Filed: April 14, 2000
    Date of Patent: November 5, 2002
    Assignees: University of Western Sydney, Commonwealth Scientific and Industrial Research Organization, Dairy Research and Development Corporation
    Inventors: Rosalie Joyce Durham, James Arthur Hourigan, Robert Walter Sleigh, Robert Leonard Johnson
  • Patent number: 6471870
    Abstract: A method for optimizing the operation of a simulated moving bed (LMS) type (closed or open) separation loop consisting of the interconnection in series of beds containing an adsorbent solid phase, divided into several zones, four for example, delimited by fluid injection and draw-off points (F, El, Ex, R). The optimization sought is obtained by selecting initial values to be imposed on operating variables (internal liquid and solid flows, permutation period, etc.) of a simulated moving bed (LMS) from internal flow rates of a true moving bed (LMV), knowing the flow rate of the feedstock (F) injected in the loop and the concentrations of the various constituents of this feedstock. The invention has an application for optimizing aromatic hydrocarbon or optical isomer separation loops.
    Type: Grant
    Filed: June 16, 1998
    Date of Patent: October 29, 2002
    Assignees: Novasep, Institut Francais du Petrole
    Inventors: Roger-Marc Nicoud, Michel Bailly
  • Patent number: 6461858
    Abstract: An enzyme is immobilized on a solid support and can react selectively with one enantiomer in an enantiomeric mixture. A methods of using the enzyme immobilized solid support in conjunct with a separating means to separate enantiomeric mixtures is described. An apparatus for separating an enantiomeric mixture using an enzyme immobilized on a solid support is also described.
    Type: Grant
    Filed: January 26, 1999
    Date of Patent: October 8, 2002
    Assignee: Pharm-Eco Laboratories, Inc.
    Inventors: Richard L. Gabriel, David A. Swanson
  • Patent number: 6451210
    Abstract: In a method for treating a contaminated fluid stream, a characteristic of a flow of the composition to a carbon adsorption zone is sensed. The sensing is remotely monitored to determine a treatment for the contaminated fluid stream. The contaminated fluid stream is then treated according to the monitoring. A system for treating a contaminated fluid stream comprises a sensor that senses a characteristic of a flow of a contaminated fluid stream prior to treatment and a monitor to receive information concerning the characteristic from the sensor and to consequently control the carbon adsorption zone to treat the contaminated fluid stream. The monitor is situated at a location remote from the carbon adsorption zone.
    Type: Grant
    Filed: November 20, 2000
    Date of Patent: September 17, 2002
    Assignee: General Electric Company
    Inventors: Timothy Mark Sivavec, Patricia Denise Mackenzie, Joseph James Salvo, Sunita Singh Baghel
  • Patent number: 6447685
    Abstract: The invention relates to an apparatus for separating water-containing solvent mixtures having two or more phases, using one or two gravitational separators (4, 16) and to the use of this apparatus, and also to a process for separating water-containing solvent mixtures having two or more phases. Using the novel apparatus it is possible to separate even small-density-difference solvent mixtures having two or more phases. To this end, a coalescence separator (1) has been provided upstream of the first gravitational separator (4).
    Type: Grant
    Filed: June 9, 2000
    Date of Patent: September 10, 2002
    Assignee: Satec U.S.A. LLC
    Inventors: Hans-Udo Saal, Ralf-Matthias Saal
  • Patent number: 6444127
    Abstract: A highly versatile drive arrangement that drives a linearly reciprocating piston of a water conditioning unit control valve without imparting any significant side loads on the support structure for the piston's drive rod or the associated seals. The drive arrangement includes a reversible electric motor and a motion converter, such as a lead screw arrangement, that converts the rotary motion of the electric motor's pinion or other output element to reciprocating linear motion of the piston. The reversible motor can be controlled, based on signals from a motion monitor such as an encoder, to drive the piston to any desired position within the piston upon command. This, in turn, permits the operation of the water conditioning unit to be optimized for prevailing conditions and permits the control valve's operation to be altered if, e.g., the piston becomes stuck or encounters an obstruction.
    Type: Grant
    Filed: September 21, 2000
    Date of Patent: September 3, 2002
    Assignee: Clack Corportion
    Inventors: Don Vaughan, Richard W. Wilder, Robert A. Clack
  • Publication number: 20020108905
    Abstract: A simulated moving bed separation system is provided, in which a fluid circulation flow path can be washed for a short time. This system is provided with a circulation flow path having two or more packed beds connected in series and endlessly to each other, with desorbing-charging inlet, extract draw-out port, feedstock introducing port and raffinate draw-out port arranged in this order in the direction of flow of a circulation liquid, which are allowed to intermittently shift in the direction while being kept in this order, and with packed bed-washing pipes, valves and pumps. A desorbing liquid is introduced through the desorbing liquid introducing port into the circulation flow path. An extract rich in a strongly adsorptive constituent to be separated is drawn out through the extract draw-out port.
    Type: Application
    Filed: April 1, 2002
    Publication date: August 15, 2002
    Applicant: Daicel Chemical Industries, Ltd.
    Inventor: Hirokazu Ikeda
  • Publication number: 20020108908
    Abstract: An affinity matrix for use in affinity based molecular pull down and immunoprecipitation procedures. The affinity matrix comprises a polymeric support, a dye attached to a fraction of the polymeric support to enable optical detection of the polymeric support, and an affinity ligand other than the dye attached to a fraction of the polymeric support for the capture of a molecule.
    Type: Application
    Filed: January 31, 2002
    Publication date: August 15, 2002
    Applicant: Sigma-Aldrich Co.
    Inventors: Edward B. Watson, Kenneth E. Heuermann, John G. Dapron
  • Patent number: 6398966
    Abstract: Apparatus in fluid communication with a water leg portion of a hydrocarbon-contaminated water, e.g., a water leg portion of an offshore drilling or production platform sump tank for conveying water, separated from oil, into contact with organophilic media canisters such that the hydrocarbons and other organic materials commingled with the sump tank water will be adsorbed onto the organophilic media and detected by the embedded probe in selected canisters. The canisters are provided in a plurality of stacks and are in fluid communication with a header disposed at the bottom of the vessel housing the various stacks of canisters. Solids that do not pass through the canisters are accumulated at the bottom of the vessel and easily drained through a drain port. The water will pass through the media and will be conveyed back to the ocean water without contamination.
    Type: Grant
    Filed: August 9, 2001
    Date of Patent: June 4, 2002
    Assignee: AMCOL International Corporation
    Inventors: Jeffrey J. Smith, Jerald W. Darlington, Jr., Michael R. Johnson, John Occhipinti, Elmo Robichaux, Michael A. Berger
  • Publication number: 20020040874
    Abstract: A fluid treatment device for reducing the level of a chemical compound in a fluid. The device comprises: a fluid inlet; a fluid outlet; a flow-through fluid treatment zone having comprising: a radiation source, an adsorbent and a photocatalyst. The fluid treatment zone is reversibly operable between: (i) a first mode in which the fluid flows in a first direction and at least a portion of the chemical compound is adsorbed on the adsorbent; and (ii) a second mode in which the fluid flows in a second direction different from the first direction in which the adsorbed chemical compound is exposed to radiation from the radiation resulting in photooxidation of the chemical compound.
    Type: Application
    Filed: April 19, 2001
    Publication date: April 11, 2002
    Inventors: Apostolos Kantzas, Cooper H. Langford, Amit Bhargava, Alex Starosud
  • Patent number: 6361696
    Abstract: A method for the decontamination of fluid (liquid or supercritical) carbon dioxide fluid, especially of hydrocarbon contaminants, down to ≦100 ppb concentration are described. The critical component is a high silica zeolite, preferably a high silica Y-type zeolite, ZSM-5 or a high silica mordenite, which in a variety of physical forms is capable of decontaminating such fluid CO2 to ≦100 ppb, ≦10-50 ppb, or ˜1 ppb, without being detrimentally affected by the supercritical operating environment. The high silica zeolite may be produced by the removal of alumina from a natural or synthetic zeolite while retaining the desirable zeolite structure, to a silica:alumina ratio of from 20-2000:1. Preferably the zeolite is disposed in separate quantities in at least two vessels, which operate alternately. A portion of the purified product from the operating vessel is directed to the other vessel and there used to remove accumulated contaminants from that vessel's zeolite.
    Type: Grant
    Filed: January 19, 2000
    Date of Patent: March 26, 2002
    Assignee: Aeronex, Inc.
    Inventors: Jeffrey J. Spiegelman, Daniel Alvarez, Jr., Peter K. Shogren, Joshua T. Cook
  • Publication number: 20020030014
    Abstract: Lactam liquid media of reaction which comprise at least one lactam final product, notably &egr;-caprolactam, are treated and purified to convert impurities contained therein into harmless species or species easily removed downstream, by hydrogenating such liquid media of reaction in the presence of a hydrogenation catalyst and during which hydrogenation the liquid media of reaction have effective lactam-purifying amounts of ammonia dissolved therein.
    Type: Application
    Filed: May 21, 2001
    Publication date: March 14, 2002
    Inventor: Philippe Leconte
  • Patent number: 6348153
    Abstract: A process and apparatus for treating the heavy hydrogen isotope content of the contaminated water by contacting the contaminated water with a molecular separation material including a support medium carrying a plurality of hydration sites having associated waters of hydration, whereby a portion of the waters of hydration are replaced with heavy hydrogen isotope water molecules from the contaminated water. The hydrogen isotope water molecule content of the contaminated water is thus decreased. The molecular separation material is preferably a polymer, such as a polystyrene/divinyl benzene cross-linked polymer, having hydration sites with associated waters of hydration. Preferred hydration sites are obtained by reacting the polymer, which has been sulfonated or phosphonated to create reactive sites, with a salt of, for example, aluminum, sodium, magnesium, copper, zinc, cobalt, iron, nickel, manganese, potassium and chromium.
    Type: Grant
    Filed: March 24, 1999
    Date of Patent: February 19, 2002
    Inventors: James A. Patterson, Louis E. Furlong, Martin J. Gruber