Abstract: A method is provided for separating an inert solid substantially inorganic fraction comprising sand or soil from a tarry or oily organic matter in a feedstock. The feedstock may be contaminated soil or tarry waste. The feedstock is combined with pulverized coal and water. The ratio (oil or tar to dry weight of coal) of about 1.0:10 to about 4.0:10 at a temperature in the range of 60.degree.-95.degree. C. The mixture is agitated, the coarse particles are removed, and up to about 0.10% by weight (based on weight of coal) of a frothing agent is added. The mixture is then subjected to flotation, and the froth is removed from the mixture.

Abstract: There is disclosed a method for treatment of an oil slick resulting from an oil spill on a body of water. The oil slick is treated with a granular elastomeric gum comprising a block copolymer of ethylene/butylene and styrene. The treatment material has a low density, typically from 14 to about 15 pounds per cubic foot and will absorb oil and form a dry solid which has a non-tacky and non-oily surface. The copolymer granular elastomeric gum is broadcast on the surface of an oil slick in proportions from about 0.2 to about 1 part per weight part of oil. The wave action on the body of water is generally sufficiently turbulent to admix the absorbent with the oil of the oil slick, resulting in the formation of floating solids which are dry to the touch and which have a non-oily, non-tacky surface. These solids can be readily recovered from the water or from a shoreline after they have washed ashore.

Abstract: Degradable particulate absorbent materials, together with processes for manufacture thereof, wherein the absorbent materials: (i) have, in most forms of the invention, only on the order of 0% to 10%, by weight, of inorganic solids or "fillers", and in all forms have less than 30% inorganic solids by weight; (ii) are not in pellet form; (iii) are characterized by an open porous fiber structure having relatively low bulk densities on the order of not more than 13 lbs./ft..sup.3 and preferably only from about 6 to about 10 lbs./ft..sup.

Abstract: Highly concentrated and toxic petroleum-based and synthetic fuels wastewaters such as oil shale retort water are treated in a unit treatment process by electrolysis in a reactor containing oleophilic, ionized, open-celled polyurethane foams and subjected to mixing and laminar flow conditions at an average detention time of six hours. Both the polyurethane foams and the foam regenerate solution are re-used. The treatment is a cost-effective process for waste-waters which are not treatable, or are not cost-effectively treatable, by conventional process series.

Abstract: A method for cleaning oil-contaminated water in a bathing or swimming area comprising circulating absorbers of open-cell cross-linked polyolefin foam on the surface of said oil-contaminated water, the contaminating oil being removed by said absorbers.

Abstract: This invention relates to a process for removing a solute from a solution. The process comprises maintaining the solution at reflux conditions to produce a vapor which evolves from the reaction solution. At least a portion of the vapor is removed from the zone and is contacted, outside of the reaction zone, with a solid removal agent which is specific for capturing to itself that portion of the vapor which was the solute to be removed and originally present in the reaction solution. After such capture, the remaining vapor is condensed and returned to the reaction zone. In another embodiment, the solute is removed from the solution by first maintaining the solution at reflux conditions in a zone to produce a vapor which evolves from the solution. At least a portion of that vapor is removed from the zone and condensed. The resultant condensate is contacted, outside of the reaction zone, with a solid removal agent which is specific for capturing unto itself the solute from the condensate.

Abstract: A method of removing oil from a surface contaminated with oil comprises spreading elongated mat (A) of nonwoven cotton fiber on the surface of the oil to absorb the oil. The mat is prepared by forming cotton fibers into at least a first nonwoven fiber web (30) and a second nonwoven fiber web (32). A composite is formed by arranging the first and second fiber webs together with a scrim (34) intermediate the first and second fiber webs. The composite is delivered to a needle punch machine (54) and the first and second fiber webs are needle punched into the scrim. The mat is formed in a continuous length greater than its width. The cotton waste fibers are short and are needle punched and compacted into the scrim. Compacted interlocked mat (A) has sufficient strength to facilitate feeding of the mat longitudinally onto the oil (14) and surface, and pulling longitudinally from the surface after absorbing oil through an oil removal device (24) from said mat.

Abstract: Oil contaminated ground water is purified by immersing one pump into the oil layer in the underground formation and another pump into the water layer in the underground formation and pumping the oil and water into, respectively, an oil storage tank and an oil/water separator. The water being pumped into the oil/water separator contains small amounts of emulsified oil which is separated from the water in the separator and forwarded to the oil storage tank. The water from the separator is passed through a series of filters to remove any trace amounts of oil present in the water so that the oil level in the purified water does not exceed 0.9 parts per billion.

Abstract: A porous water-treating material comprising cut porous strands each comprising a resinous matrix material which consists essentially of a thermoplastic polymer material or a mixture thereof with an inorganic particulate material. Each strand having a number of pores connected to each other and an irregularly rugged peripheral surface which has a ratio in diameter of a circumscribed circle to an inscribed circle in any cross-sectional profile from 1.10:1 to 5.00:1 and a ratio of the distance between circumscribed lines to that between inscribed lines in any side projection profile of from 1.10:1 to 3.00:1. The cut porous strands are prepared by melt-extruding a resinous mixture of the resinous matrix material with a blowing agent at a temperature higher than the melting point of the thermoplastic polymer material and the thermally decomposing point of the blowing material so as to cause the strands to have a number of pores and an irregularly rugged peripheral surface thereof.

Abstract: A method and apparatus for separating an oil phase from an aqueous phase by means of a rotating drum apparatus containing one or more compartments, each being partially filled with oleophilic free bodies. When containing two or more compartments, they are separated by an apertured baffle. The interior surfaces of the drum are oleophilic and the portion of the drum sidewall, where the mixture is removed is apertured. Due to the oleophilic free bodies and interior oleophilic surfaces, the aqueous phase velocity through the drum is faster than the oil phase which adheres to the oleophilic surfaces causing an in situ buildup and agglomeration of oil phase in the drum. The mixture exiting the apertured drum sidewall is partitioned by the tumbling free bodies, oleophilic drum surfaces and drum rotation such that aqueous phase leaves the drum between the 6 and 9 o'clock positions of counter clockwise rotation where free body concentration is minimal.

Abstract: To protect shores against oil pollutants, a web-like oil-retaining textile, is lowered into the water in parallel with the shore and the textile is drawn up on the shore over a strip of land which is in danger of getting polluted in such a manner that a longitudinal edge of the textile remains in the water. The oil which is thrown towards the shore by the waves adheres to the textile and is thereby prevented from contacting the strip of land.One longitudinal edge of the textile is provided with a heavy foot rope and the other longitudinal edge is provided with floats and cords for drawing the textile up on the shore. The textile may be a needled fibrous felt having a width of 4 to 8 meters, the width being comparable to that of the strip of land to be protected.

Abstract: A process for absorbing oil and a particulate oil-absorbing composition are provided, which composition in dust form displays a low explosion hazard and a low flammability, but which after absorption of oil is flammable and entirely consumed when burned, the particles comprising as the major component at least 50% by weight hydrophobic cellulose pulp fibers blended with at least 30% up to 50% of an inorganic cellulose paper pulp filler.

Abstract: A mixture containing dispersed phase and continuous aqueous phase, with particulate solids being part of either or both phases, is separated by passing it one or more times through apertures in an endless oleophilic conveyor belt in a separation zone wherein bitumen phase adheres to the belt and bitumen adhering to the belt is conveyed to one or more bitumen treatment zones and to a recovery zone where bitumen is removed from the belt. The end rolls of the belt are not immersed in a water bath; however, portions of the belt, while in the separation, treatment and recovery zones, may be partly or completely in an aqueous environment. More than one set of separation, treatment and recovery zones may be used on the same endless belt conveyor. Also, a mixture containing dispersed aqueous phase and continuous bitumen or oil phase, and possibly gas, is deposited onto an apertured oleophilic endless belt conveyor and is treated in one or more treatment zones and is then removed from the belt.

Abstract: A process is provided for the absorption of organic liquids, particularly oil, using hydrophobic fibrous material prepared by impregnating fibrous material comprising cellulose fibers with a liquid resinous material selected from the group consisting of acrylate prepolymers and polymers, alkyd prepolymers and polymers, and polyester prepolymers and polymers in an amount to provide in the impregnated fibrous material from about 0.5 to about 30% by weight polyacrylate, polyalkyd or polyester, and then heating the impregnated fibrous material to convert the polymer or prepolymer by chemical reaction into a hydrophobic polymer rendering the fibrous material hydrophobic.

Abstract: Granular media are featured which cleanse oil from oil-in-water emulsions. These media comprise a glass or filter sand substrate. The substrate is treated with at least one trialkoxysilane wherein the alkoxy moiety comprises from 1 to 2 carbons. The granular media are backwashable to refresh their lipophilic properties.

Abstract: A method for the removal of liquid or solid impurities from an impurities-containing liquid mixture wherein the impurities immiscible or occasionally miscible with the liquid medium are emulsified or finely suspended in the liquid medium, which comprises kneading the impurities-containing liquid mixture with a viscoelastic material having an affinity with said impurities and having substantially no affinity with said liquid medium, and thereby having the viscoelastic material take up the impurities and separating out the purified liquid medium. According to this method, various liquid wastes can be purified, and noble resources can be recovered from the wastes and re-used, and the separated liquid medium, particularly aqueous medium which is not useful can be thrown away without encountering problems of environmental pollution.

Abstract: A variable density fluid is provided comprising a multiplicity of polymer micro-particles or polymer microfilaments added to a suspending liquid. By varying the density, shape, size, and material of construction of the added micro-particles or microfilaments, the physical properties of the composite liquid suspension, such as density, viscosity and compressibility, are controllable. In one specific embodiment, the polymer micro-particles can be used to selectively remove a liquid from a mixture of liquids, such as oil from sea water for example.

Abstract: For separating oil from aqueous or solvent dispersions the dispersion is passed through a porous flat-shaped textile article which comprises at least partly of oleophilic fibres each having a titer below 1 dtex. The flat-shaped textile article is preferably a three dimensional article, and can have a pile and possibly also a substrate comprising of extremely fine oleophilic artificial fibres. The pile threads and eventually also the threads of the substrate are split by means of a swelling agent into many extremely fine oleophilic fibres having a low titer. The small and very small oil drops in the dispersion are withheld on the extremely fine oleophilic fibres and coalesce to larger oil droplets or oil drops which rise to the surface of the liquid due to their lower density than the liquid. The oil can be easily removed from the surface of the liquid.

Abstract: A mixture containing a dispersed bitumen, oil or hydrocarbon phase and a continuous aqueous phase is passed for treatment through a rotating horizontal tumbler, containing oleophilic free bodies, for the purpose of increasing the particle size of the dispersed phase and facilitating subsequent separation of the phases of the mixture. Alternately, a mixture containing a dispersed aqueous phase and a continuous bitumen, oil or hydrocarbon phase is passed for treatment through a rotating horizontal tumbler, containing hydrophilic and oleophilic free bodies, for the purpose of increasing the particle size of the dispersed phase and facilitating subsequent separation of the phases of the mixture.

Abstract: An oil and water mixture containing a dispersed phase and a continuous phase is passed for treatment through a rotating horizontal tumbler containing free bodies and a hydrocarbon diluent for the purpose of facilitating subsequent separation of the phases of the mixture. The free bodies tumbling with the mixture in the drum have affinity for the dispersed phase particles, and the hydrocarbon diluent reduces the viscosity of the oil phase thereby causing an increase in the particle size of the dispersed phase of the mixture. Some mixtures that may be treated include effluent streams from a hot-water oil sands extraction plant, oil-in-water emulsions from processes that use enhanced oil well recovery and bitumen froth.

Abstract: A method for the removal of hormones from whole human serum which comprises: contacting, at a pressure higher than 1 psi the serum with a composite sheet, the composite sheet comprising a matrix of self-bonding fibers having interdispersed therein carbon particles, such that better than 90% of the carbon particles have an average diameter less than about 50 microns; and recovering a whole human serum having substantially undetectable amounts of hormones. The method is particularly useful for the removal of thyroid hormones.

Abstract: Method for removing a liquid floating on water, for example oil, particularly crude oil on sea water, with a water-resistant synthetic resin foam formed in situ in the region of the water surface to be cleaned, a mixture containing a solvent-free liquid epoxy resin, 5-15%, by weight, based on the epoxy resin, of a resin hardening agent on the basis of an alkylphenol and a biphenol as well as a methylalkyl ketone and 20-30%, by weight, of an accelerator being cured with a di- or polyamine around the liquid to be removed and, optionally, also around the center thereof.

Abstract: A liquid-absorbing textile product which is in the form of a double-layer fabric wherein the two layers are interwoven by pile threads of a hydrophobic and oleophilic synthetic material. The resulting product is very manageable and capable of absorbing considerable quantities of oil despite its low weight.

Abstract: Bags or booms of porous material filled with an oil adsorbant, particulate polyisocyanurate synthetic foam material are used to enclose and adsorb oil spilled on water or hard surfaces.

Abstract: Treatment of high yield wood pulp which has ether extractives of greater than about 3.0% at temperatures of about 105.degree. C. or higher for at least about 16 hours followed by fluffing of the heat treated pulp results in a relatively inexpensive absorbent for oil spills and the like. The oil is readily recovered from the absorbent or the oil and absorbent may be burned as fuel without separation.

Abstract: A mass of net-like material of oleophilic, hydrophobic netting material is formed from strips of netting secured into a loose mass. Oil contacting the mass is sorbed by the strands and tends to bridge the openings in the net-like material to increase the short term oil pick up capacity.

Abstract: The present invention is directed to a process for separating oil from water in a mixture containing oil and water, as well as to means for performing the separation process. Specifically, the process involves:(a) feeding said mixture to a heated hold-up tank via an inlet located at a lower level of said tank, said tank having a residence time sufficient to permit separation of oil and water and formation of a water-in-oil emulsion which rises to float atop of said water, said tank being heated to a temperature within the range of about 160.degree. F. to about 180.degree. F.

Abstract: The system comprises a flexible line provided with means for collecting products scattered at the water bottom by circulating the flexible line in contact with these products. On the rising portion of the path followed by the flexible line, the collecting means are passed through a tubular casing for simultaneously protecting the surrounding water against pollution from products released, while hoisting the products to the surface.

Abstract: Water containing traces of oil is cleaned by passing the oil containing water through a foraminous body, the foraminous body having a coating on the surface thereof of an oil-imbibing, oil-swellable latex polymer in a quantity sufficient to blind the foraminous body when the latex is oil swollen.

Abstract: A process for separating hydrophobic organic liquids from water comprising passing a mixture of water and hydrophobic organic liquids through a column-like vessel which is filled with a hydrophobic, preferably open-celled, polyurethane foam, said foam having a high absorption capacity, permits high flow-through velocities even as the foam becomes covered and saturated with the hydrophobic organic liquids, is reversibly deformable, and can be reused.

Abstract: An oil recovery apparatus and method, particularly for removing oil and grease from the discharge of dishwashing machines or the like, provides a small size assembly employing the same principle as in U.S. Pat. No. 4,051,024. This apparatus and method employs single rotating discs of plastic or plastic coated material and each disk has a pair of scraper blades arranged to scrape opposite sides of the rotating blade. Exterior of the container for the oil recovery apparatus is at least one filter basket adapted to receive the flow into the strainer container of large particles of food and other waste such as cigarette butts and the like. Each filter is disposed for the ready cleaning of accumulated matter from the basket. There is shown plural filters, valve controlls, auxiliary heating and disc support means to be more fully described.

Abstract: A method and apparatus are provided for removing oil from the surface of water by means of one or a multiplicity of discs which are provided with either or a combination of oil-absorbent bristles and oil-absorbent materials disposed on the flat surfaces of the disc, the disc being disposed partially in the oil and partially in a vapor space thereabove, rotating the discs to cycle the bristles and/or oil-absorbent material alternately from the oil on the water to the vapor space thereabove, allowing the oil to adhere or absorb into the bristles or absorbent material and then removing the oil from the bristles and/or oil-absorbent material while the bristles and/or oil-absorbent material are in the vapor space.

Abstract: An improved process for removing oil from oily waste water streams, particularly from aqueous refinery streams wherein the oil is present as a stable oil-in-water emulsion, which comprises passing the stream through a filter bed of particulate, unprocessed PVC or its copolymers mixed with a granular, inert and preferably porous filler material such as particles of coke or carbon. The improvement substantially increases bed life and has unexpectedly resulted in higher oil-absorption capacity of the filter bed.

Abstract: A granular polyurethane cellular medium for absorbing water-borne, water insoluble hydrocarbons, method for its preparation and production system. The granular medium is formed by prereacting polyisocyanate or a prepolymer with a linear monohydric alcohol to form a prepolymer. This prepolymer subsequently is reacted with a polyol and blowing agent within a flexible sheet bun mold. Following molding of the bun within the flexible sheet, the bun is transferred to a comminution stage within a predetermined time period whereupon it is granulated. The material is fabricable at low cost and under a broad range of environmental conditions permitting flexibility in selecting the site for production of the material. The material exhibits an unusually high affinity for the water-borne contaminant hydrocarbons, does not absorb water and lends itself to low-cost production procedures.

Abstract: A method for separating water-immiscible oils and oil-like substances from mixtures including said oils in an aqueous medium which comprises contacting the mixture with an oleophilic fibrous web comprising large numbers of interconnected, interstitial spaces for reception and retention of the oil to the exclusion of water.