Of Iron Or Manganese Material Patents (Class 210/722)
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Patent number: 11649180Abstract: A treatment for a large body of water to make the water suitable for recreational purposes is disclosed. A sedimentation zone and a dissipation zone are designated in the water body. A disinfection method based on a CT index and a flocculant composition are utilized in the sedimentation zone to aid in the settling of different microorganisms and/or contaminants. Also, the water in the sedimentation zone is minimally disturbed to facilitate the sedimentation process. A permanent chlorine residual is maintained in the dissipation zone by adding an efficient amount of a chlorine disinfectant such that at least a 0.5 mg/L free chlorine level is maintained in the water volume. Water is injected into the dissipation zone by means of one or more inlet nozzles. Along with natural currents produced by winds and water temperature differences, a water dissipation pattern from within the dissipation zone into the sedimentation zone is generated.Type: GrantFiled: February 16, 2021Date of Patent: May 16, 2023Assignee: CRYSTAL LAGOONS TECHNOLOGIES, INC.Inventor: Fernando Benjamin Fischmann
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Patent number: 11319232Abstract: Disclosed is a method for preparing a solid material including manganese, the method including the following steps: a. bringing into contact an aqueous effluent including manganese, for example at least 5 mg/L, typically at least 5 to 50 mg/L, and preferably 7 to 25 mg/L of manganese, with an oxidizing agent, manganese, preferably at a temperature between 10° C. and 50° C., and obtaining an oxidized aqueous solution; b. adding a base to the oxidized aqueous solution obtained at the end of step a) until a pH of between 8 and 12, preferably greater than 9, and preferably from 9 to 10.5, and obtaining a solution including a precipitate; c. filtration of the solution obtained at the end of step b); and d. obtaining a solid material including manganese, and especially manganese (IV) and/or Mn (III).Type: GrantFiled: March 30, 2018Date of Patent: May 3, 2022Assignee: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUEInventor: Claude Grison
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Patent number: 10919788Abstract: Embodiments of this invention provide an integrated system for clean energy generation and storage and RO desalination. The integrated system includes a first subsystem that stores hydraulic energy. The integrated system further includes a second subsystem that desalinates water. The integration system also includes a penstock that facilitates flow of the water between the first subsystem and the second subsystem. The integrated subsystem may also incorporate solar and/or wind power generation plants as a power source for the integrated system.Type: GrantFiled: December 29, 2017Date of Patent: February 16, 2021Assignee: Oceanus Power & Water, LLCInventors: Neal Aronson, Sandra Walker, Jose Alberto Garcia Guerrero, Joan Leal Jeldrez, Mark Allen
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Patent number: 10047974Abstract: An automatically flushing water heater maintenance system may be provided, the system including a water heater and a water heater controller. The water heater may include an inlet, an outlet, and a flush outlet having a first control valve in flow communication therewith. The first control valve may be configured to control a flow of water and sediment through the flush outlet out of the water heater. The water heater controller may be configured to communicate with the first control valve by transmitting a first control signal to the first control valve, the first control signal configured to cause the first control valve to open or close as part of an automatic flushing process. As a result of the flushing, the useful life of the water heater may be extended, and/or water heater leakage alleviated. Insurance discounts may be provided based upon using the automatic water heater flushing functionality.Type: GrantFiled: February 29, 2016Date of Patent: August 14, 2018Assignee: STATE FARM MUTUAL AUTOMOBILE INSURANCE COMPANYInventors: Jeffrey A. Riblet, Melinda T. Magerkurth
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Patent number: 9580312Abstract: The invention relates to a continuous method for producing acetylenes and syngas by partially oxidizing hydrocarbons with oxygen. A first feed stream (1) containing one or more hydrocarbons and a second feed stream (2) containing oxygen are —mixed in a ratio of the mass flows of the second feed stream (2) to the first feed stream (1) corresponding to an oxygen number of less than or equal to 0.31, said streams being heated separately from each other, —and fed to a combustion chamber (FR) via a burner block (BR), the partial oxidation of the hydrocarbons being carried out in said combustion chamber, —thereby obtaining a first cracked gas stream Ig. The invention is characterized in that —the first cracked gas stream Ig is precooled to a temperature ranging from 100 to 1000° C.Type: GrantFiled: January 15, 2014Date of Patent: February 28, 2017Assignee: BASF SEInventors: Maximilian Vicari, Christian Weichert, Dirk Grossschmidt, Michael Russ, Kai Rainer Ehrhardt, Horst Neuhauser, Michael L. Hayes
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Patent number: 9181115Abstract: Embodiments of the invention provide a method and system for providing a regeneration stage in a water treatment system. The method can include entering a first air bleed state to allow pressurized, deoxygenated air to exit the water treatment system, entering a second air bleed state to equalize a first air pressure of remaining deoxygenated air inside the water treatment system with a second air pressure outside the water treatment system, entering a backwash state to expel remaining deoxygenated air and particulates from inside the water treatment system, and entering an air draw state to allow oxygenated air to enter the water treatment system.Type: GrantFiled: January 6, 2014Date of Patent: November 10, 2015Assignee: PENTAIR RESIDENTIAL FILTRATION, LLCInventors: Andrew Tischendorf, Michael P. Lindfors, Kyle Paull
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Patent number: 9056789Abstract: The present invention provides a method of producing a granular product, the method comprising providing waste stone wool product of which at least 90% is in coherent form having minimum dimension at least 50 mm and which has a content of at least 10% water, by weight of the waste stone wool product; producing a base material from the stone wool by reducing the coherent stone wool to particulate form such that at least 80% by weight of the base material is in the form of particles having size not more than 40 mm, and has water content not more than 50 wt % based on the particulate base material; forming the particulate base material into granules, wherein at least 80% by weight of the granules have size not more than 40 mm, and subjecting the granules to sintering at a temperature in the range 900 to 1050° C. to form a granular product wherein at least 80% by weight of the granular product is in the form of granules having size not more than 40 mm, and during the operation of the method no binder is added.Type: GrantFiled: June 16, 2010Date of Patent: June 16, 2015Assignee: ROCKWELL INTERNATIONAL A/SInventor: Jean Marie Wilhelmus Cuypers
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Patent number: 8894865Abstract: This invention relates generally to processes for extracting iron and/or calcium from geothermal brines.Type: GrantFiled: November 14, 2012Date of Patent: November 25, 2014Assignee: Berkshire Hathaway Energy CompanyInventors: John L. Featherstone, George Furmanski
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Patent number: 8889010Abstract: A method for treating low barium frac water includes contacting a frac water stream with a radium selective complexing resin to produce a low radium stream, passing the low radium stream through a thermal brine concentrator to produce a concentrated brine; and passing the concentrated brine through a thermal crystallizer to yield road salt.Type: GrantFiled: July 25, 2011Date of Patent: November 18, 2014Assignee: General Electric CompanyInventors: James Manio Silva, Hope Matis, William Leonard Kostedt, IV
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Patent number: 8851293Abstract: A mined ore processing apparatus to process mined ores, such as oil sands ore, into granular material is disclosed. An ore processor bed receives the ore to be processed. The ore processor bed has a frame supporting several rotating elements each separately driven to provide independent rotation rate and direction from the other. The ore processing bed is operable as a sizing device to decimate mined ore supply into granular material and separating it from rocks and other large lump mineral materials found in situ. The ore processing bed may be oriented to provide an upward inclination, which, when combined with alternating rotating element rotation directions, provides a crushing action to the ore material to crush larger rock. Alternately, a rock crusher is also provided to disintegrate oversized materials.Type: GrantFiled: March 9, 2012Date of Patent: October 7, 2014Assignee: Suncor Energy, Inc.Inventors: Brad Bjornson, Doug Cox, Paul MacDougall, Garth Booker
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Patent number: 8790516Abstract: The invention relates to a method for removing arsenic as scorodite from solutions that contain iron and arsenic. In accordance with the method, arsenic is first precipitated as ferric arsenate and subsequently processed hydrothermally into crystalline scorodite.Type: GrantFiled: February 19, 2010Date of Patent: July 29, 2014Assignee: Outotec OyjInventors: Mikko Ruonala, Jaakko Leppinen, Ville Miettinen
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Publication number: 20140144845Abstract: Embodiments of the invention provide a method and system for providing a regeneration stage in a water treatment system. The method can include entering a first air bleed state to allow pressurized, deoxygenated air to exit the water treatment system, entering a second air bleed state to equalize a first air pressure of remaining deoxygenated air inside the water treatment system with a second air pressure outside the water treatment system, entering a backwash state to expel remaining deoxygenated air and particulates from inside the water treatment system, and entering an air draw state to allow oxygenated air to enter the water treatment system.Type: ApplicationFiled: January 6, 2014Publication date: May 29, 2014Applicant: Pentair Residential Filtration, LLCInventors: Andrew Tischendorf, Michael M. Lindfors, Kyle Paull
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Patent number: 8728325Abstract: Advanced oxidation process namely ozonation and Fenton's (hydrogen peroxide/Fe:2+) were utilized to degrade kinetic hydrate inhibitor (KHI). The oxidized solution after scavenging oxygen can be successfully disposed to the injection well. This facilitates use of KHI more frequently and in higher concentrations for future projects oil & gas operations. It also offers an alternative that competes efficiently with thermodynamic hydrate inhibitor (THI) or complements THI.Type: GrantFiled: March 1, 2012Date of Patent: May 20, 2014Assignee: ConocoPhillips CompanyInventors: Altaf Hussain, Isik Riza Turkmen, Joel Minier Matar, Samir Gharfeh, Samer Adham
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Publication number: 20140054233Abstract: This invention relates to a method for selective removal of silica and silicon containing compounds from solutions that include silica and silicon containing compounds, including geothermal brines.Type: ApplicationFiled: October 24, 2013Publication date: February 27, 2014Applicant: Simbol Inc.Inventor: Stephen Harrison
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Patent number: 8623217Abstract: Embodiments of the invention provide a method and system for providing a regeneration stage in a water treatment system. The method can include entering a first air bleed state to allow pressurized, deoxygenated air to exit the water treatment system, entering a second air bleed state to equalize a first air pressure of remaining deoxygenated air inside the water treatment system with a second air pressure outside the water treatment system, entering a backwash state to expel remaining deoxygenated air and particulates from inside the water treatment system, and entering an air draw state to allow oxygenated air to enter the water treatment system.Type: GrantFiled: July 26, 2013Date of Patent: January 7, 2014Assignee: Pentair Residential Filtration, LLCInventors: Andrew Tischendorf, Michael M. Lindfors, Kyle Paull
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Publication number: 20130319951Abstract: Sulfate anions and divalent metal ions in water are removed by treating sulfate-containing water, at a pH of 11-12.5, with aluminum chloride and calcium chloride, optionally together with lime, to form solid ettringite and similar crystalline species. Sulfate is removed as part of the ettringite or ettringite-like materials, but calcium content can be reduced at the same time even though calcium chloride is used as an additive to the treated water. Lime may be used also as a supplemental source of calcium and to help raise the pH. Iron may also be removed by oxidation in a variation of the process. In well treatment, divalent metal ions in flowback fluids can reduce the amount of calcium otherwise necessary to form the solid materials, thus further facilitating recycling of the fluid.Type: ApplicationFiled: May 31, 2012Publication date: December 5, 2013Inventors: Kevin Smith, Jeffrey Snider, Jimmy Poindexter
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Patent number: 8597521Abstract: This invention relates to a method for selective removal of silica and silicon containing compounds from solutions that include silica and silicon containing compounds, including geothermal brines.Type: GrantFiled: June 24, 2010Date of Patent: December 3, 2013Assignee: Simbol Inc.Inventor: Stephen Harrison
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Publication number: 20130284678Abstract: An apparatus and methods for measuring the concentration of an additive are disclosed. The apparatus comprises a treatment stream (1) and a dosing stream (2). An additive is added to the dosing stream using a metering device (3). In some embodiments, the dosing stream is mixed after adding the additive using a first mixing device (4). Downstream from the metering device and the mixing device, the concentration of the additive in the dosing stream is measured using a monitor flow cell (5). In some embodiments, the dosing stream and treatment stream are combined (6) and mixed using a second mixing device (7). The concentration of the additive in the treatment stream can be calculated as a function of the volumetric flow rate ratio of the dosing stream to the treatment stream and the measured concentration of the additive in the dosing stream.Type: ApplicationFiled: December 14, 2011Publication date: October 31, 2013Applicant: FERRATE TREATMENT TECHNOLOGIES, LLCInventors: Luke J. Daly, Craig S. Alig
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Publication number: 20130213896Abstract: Disclosed are methods for treating and coating a ferrous metal substrate, such as cold rolled steel, hot rolled steel, and electrogalvanized steel. These methods include contacting the ferrous metal substrate with an aqueous pretreatment composition comprising: (a) a Group IIIB and/or IVB metal compound; (b) phosphate ions; and (c) water. Also disclosed are off-shift methods of removing iron from the pretreatment bath.Type: ApplicationFiled: March 6, 2013Publication date: August 22, 2013Applicant: PPG Industries Ohio, Inc.Inventor: PPG Industries Ohio, Inc.
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Patent number: 8512571Abstract: The present invention is a method and system for treating iron-contaminated water (e.g., mine drainage) using an innovative treatment approach identified herein as the Activated Iron Solids (AIS) Process. The AIS process is capable of oxidizing and removing iron as iron oxides from iron-contaminated waters (such as, mining-related discharge, groundwater, surface water and industrial waste streams) producing a clean effluent. The AIS process is performed in a single or multiple tank system in which high concentrations of AIS are suspended through mechanical mixing to maintain a catalytic surface chemistry environment that increases iron removal thousands times faster than would naturally occur and hundreds times faster than existing arts (e.g., aerobic pond passive treatment). The AIS process can utilize inexpensive alkaline material (such as, pulverized limestone) where initial mine drainage alkalinity (mg/L as CaCO3) to ferrous iron (mg/L) ratio is less than approximately 1.7.Type: GrantFiled: September 12, 2008Date of Patent: August 20, 2013Inventor: Jonathan M. Dietz
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Patent number: 8465701Abstract: Provided is a catalyst material comprising aggregates of nanoneedles of mainly R-type manganese dioxide and having a mesoporous structure. With this, water can be oxidatively decomposed under visible light at room temperature to produce oxygen gas, proton and electron. Also provided is a catalyst material comprising aggregates of nanoparticles of mainly hydrogenated manganese dioxide. With this, acetic acid or an inorganic substance can be synthesized from carbon dioxide gas.Type: GrantFiled: March 25, 2008Date of Patent: June 18, 2013Assignee: Kyoto UniversityInventor: Hideki Koyanaka
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Publication number: 20130140243Abstract: A method of purifying raw water comprises the steps of supplying the raw water to a generally vertical, open-ended inlet cylinder (23) in a reservoir (20), exposing the water in the inlet cylinder (23) to air for accomplishing oxidizing of matter, such as iron, manganese, and hydrogen sulphide in the water and/or agitation of the water, allowing the oxidized matter to fall down by gravity to the bottom of the reservoir (20), allowing the purified water to flow upwards past the inlet cylinder (23) and through a distribution disc (24) in the reservoir (20), and removing the purified water from the upper part of the reservoir (20).Type: ApplicationFiled: May 4, 2011Publication date: June 6, 2013Inventor: Bert Gustafsson
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Patent number: 8430164Abstract: The invention relates to a method for producing steam comprising the successive steps of: providing feedwater containing carbonate and/or sulfate ions; adding a crystallizing reagent able to react with carbonate and/or sulfate ions to the feedwater, in order to produce carbonate and/or sulfate crystals; filtering the feedwater with a ceramic membrane to produce a permeate stream; supplying the permeate stream to a boiler; and generating steam in the boiler. The invention also relates to an installation adapted for implementing said method, as well as to a process for extracting hydrocarbons from a subterranean formation using the abovementioned method for producing steam.Type: GrantFiled: July 2, 2010Date of Patent: April 30, 2013Assignee: Total S.A.Inventor: Annie Audibert-Hayet
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Publication number: 20130068697Abstract: This invention relates generally to processes for extracting iron and/or calcium from geothermal brines.Type: ApplicationFiled: November 14, 2012Publication date: March 21, 2013Applicant: Midamerican Energy Holdings CompanyInventor: Midamerican Energy Holdings Company
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Patent number: 8361327Abstract: The present invention relates to an agricultural water-recycling system comprising an iron (Fe)-ionizing module and a method of recycling agricultural water using the same, and more particularly to an agricultural water-recycling system comprising an iron (Fe)-ionizing module and a method of recycling agricultural water using the same, in which phosphorus (P) contained in effluent from a sewage treatment plant is removed by using the iron (Fe)-ionizing module comprising an iron (Fe)-ionizing electrode consisting of an iron plate serving as a cathode and a titanium plate serving as an anode and an electrode-washing device. According to the present invention, an effluent treatment process of a sewage treatment plant and an electrode washing process needed for iron ionization can be simultaneously performed, the iron ionization is controlled depending on the concentration of phosphorus contained in the effluent, thereby improving effluent treatment efficiency.Type: GrantFiled: January 29, 2010Date of Patent: January 29, 2013Assignees: Korea Rural Community Corporation, Blue Environment N Tech Co., Ltd., Kyungpook National University Industry-Academic Cooperation FoundationInventors: Kwang Ya Lee, Hae Do Kim, Jong Hwa Son, Min Hong, Kyung Sook Choi
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Publication number: 20130001173Abstract: The wastewater treatment method is to obtain demanganized wastewater, through a step wherein an acid or an alkali is added to sulfuric acid acidified wastewater to adjust pH to not less than 4.0 and not more than 6.0, whereby the sulfuric acid acidified wastewater is separated into a dealuminized solution and an aluminum precipitate; a step wherein a slurrying solution is added to the aluminum precipitate to form a slurry, then an alkali is added to adjust pH to not less than 9.0 and not more than 9.5, whereby an pH-adjusted aluminum precipitate slurry is formed; a step wherein an alkali is added to the dealuminized solution to adjust pH to not less than 8.0 and not more than 9.0; and others.Type: ApplicationFiled: January 6, 2011Publication date: January 3, 2013Applicant: Sumitomo Mental Mining Co., Ltd.Inventors: Hiroshi Kobayashi, Tatsuya Higaki, Hirofumi Shoji, Norihisa Toki, Keiji Kudo, Hiroyuki Mitsui, Osamu Nakai
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Patent number: 8313653Abstract: This invention relates generally to processes for extracting iron and/or calcium from geothermal brines.Type: GrantFiled: August 11, 2010Date of Patent: November 20, 2012Assignee: Midamerican Energy Holdings CompanyInventors: John L. Featherstone, George Furmanski
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Patent number: 8282835Abstract: The invention provides a method of efficiently removing selenium from water. The method involves: adding an oxidant to the liquid, adjusting the liquid's pH to below 7.5, adding ferric salt in an amount such that less than a quarter of selenium in the liquid precipitates and adding a poly dithiocarbamate material to the liquid in an amount such that the amount of poly dithiocarbamate material (in ppm) is greater than the amount of ferric salt (in ppm). This method removes far more selenium than previous methods, and does it using a smaller amount of expensive chemicals. Moreover this method makes it far more likely to achieve cost effective compliance with the ever-increasing environmental standards for selenium in water.Type: GrantFiled: March 10, 2010Date of Patent: October 9, 2012Assignee: Nalco CompanyInventors: Daniel E. Schwarz, Jitendra T. Shah
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Patent number: 8211314Abstract: The present disclosure describes using the naturally present dissolved chemicals as precipitants from local water sources to form an adsorbent and a process of purifying the water using natural resources. The adsorbent may be processed at the right pH and temperature to purify and remove heavy metals from waste water. Once the heavy metals are removed the concentration of the heavy metals are estimated in the reusable water. The local authority acceptable level heavy metal containing reusable water is reclaimed for non-human consumption. This disclosure enables to conserve water and provide a cheap and an effective method to decontaminate industrial waste water.Type: GrantFiled: March 6, 2012Date of Patent: July 3, 2012Assignee: King Abdulaziz City for Science and Technology “KACST”Inventor: Saad A Al-Jlil
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Publication number: 20120118831Abstract: The present invention provides reagents that may be useful for treating wastes such as impure aqueous materials including wastewater to remove a significant proportion of the heavy metals that may be contained therein. The reagents include a calcium aluminosilicate (CAS) source and may include one or more of the following elements as an oxide: calcium oxide, aluminum oxide, silicon oxide, iron oxide, magnesium oxide, sodium oxide, potassium oxide, and sulfate. Further, the reagent comprises lime either as CaO or Ca(OH)2. In addition, the invention provides methods for treating wastes such as impure aqueous materials to remove a significant proportion of the heavy metals contained therein.Type: ApplicationFiled: January 20, 2012Publication date: May 17, 2012Inventors: Raymond T. Hemmings, Bruce J. Cornelius
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Patent number: 8147702Abstract: The present disclosure describes using the naturally present dissolved chemicals as precipitants from local water sources to form an adsorbent. The adsorbent may be collected and used at the right pH and temperature to purify and remove heavy metals from waste water. Once the heavy metals are removed the concentration of the heavy metals are estimated in the reusable water. The local authority acceptable level heavy metal containing reusable water is reclaimed for non-human consumption. This disclosure enables to conserve water and provide a cheap and an effective method to decontaminate industrial waste water.Type: GrantFiled: April 21, 2011Date of Patent: April 3, 2012Assignee: King Abdulaziz City for Science and Technology (KACST)Inventor: Saad A Al-Jlil
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Publication number: 20120031850Abstract: Sulfate anions and divalent metal ions, such as magnesium, strontium and barium, in water are removed by treating the water with polyaluminum chloride, usually together with lime, to form ettringite and similar crystalline species which are readily removable by settling, filtration and the like. Iron is also removed by oxidation in a variation of the process. The process is particularly useful for treating aqueous solutions used in well treatment, where flowback fluids can provide some of the divalent metal ions necessary to form the ettringite-like materials, thus reducing the amount of lime otherwise necessary and further facilitating recycling of the fluid.Type: ApplicationFiled: August 3, 2011Publication date: February 9, 2012Inventors: Kevin Smith, Jeffrey Snider, Jimmy Poindexter
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Patent number: 8034158Abstract: There are provided a method of manufacturing an Fe/Ni-containing material having a low content of sulfur (S) from an Fe/Ni/SO4-containing liquid waste, a ferronickel mass using the Fe/Ni-containing material, and a method of manufacturing the ferronickel mass. The method of manufacturing an Fe/Ni-containing material from an Fe/Ni-containing liquid waste includes: removing SO4 from an Fe/Ni/SO4-containing liquid waste by adding an SO4 neutralizing agent to the liquid waste so that pH of the liquid waste can be maintained to a pH level of 0.5 to 2.5; precipitating Fe and Ni in the form of hydroxide [(Ni,Fe)(OH)] by adding NaOH to the SO4-free solution; washing the precipitate with water; and manufacturing an Ni/Fe-containing material by filtering and drying the washed Ni/Fe-containing sludge.Type: GrantFiled: May 15, 2008Date of Patent: October 11, 2011Assignee: Research Institute of Industrial Science & TechnologyInventor: Jae Young Lee
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Publication number: 20110220571Abstract: The present disclosure describes using the naturally present dissolved chemicals as precipitants from local water sources to form an adsorbent. The adsorbent may be collected and used at the right pH and temperature to purify and remove heavy metals from waste water. Once the heavy metals are removed the concentration of the heavy metals are estimated in the reusable water. The local authority acceptable level heavy metal containing reusable water is reclaimed for non-human consumption. This disclosure enables to conserve water and provide a cheap and an effective method to decontaminate industrial waste water.Type: ApplicationFiled: April 21, 2011Publication date: September 15, 2011Applicant: King Abdulaziz City for Organization Name Science and Technology "KACST"Inventor: Saad A. Al-Jlil
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Publication number: 20110198297Abstract: A water filtration system (2) and method includes a conduit network (4) configured to transport a treatment stream of water. An air compressor (10) is in fluid communication with the conduit network (4) configured to inject compressed air into the treatment stream (2) oxidizing a first portion of the dissolved iron. At least one closed pressure contact vessel (6) is in fluid communication with the conduit network (4). At least one filter tank (14) is in fluid communication with the at least one closed pressure contact vessel (6) having a first filtering media (16) adapted to adjust the pH of the treatment stream for oxidation of a second portion of the dissolved iron. At least one polishing filter tank (18) is in fluid communication with the at least one filter tank (14) having a second filtering media (22) adapted to catalyze the oxidation of any residual dissolved iron.Type: ApplicationFiled: September 29, 2009Publication date: August 18, 2011Inventor: Michael Ubri
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Publication number: 20110163042Abstract: A removal method of manganese in which manganese is removed by precipitating manganese selectively from sulfuric acid waste water containing aluminum, magnesium and manganese with inhibiting the precipitation of magnesium. The removal method of manganese from waste water in which manganese is removed by precipitating manganese selectively from the sulfuric acid waste water containing aluminum, magnesium and manganese with inhibiting the precipitation of magnesium, characterized in that said waste water is subjected to the following steps (1) and (2). (1) First, aluminum in said waste water is removed. (2) Subsequently, neutralizing agent is added into the wastewater after removing aluminum, then pH of the waste water is adjusted at 8.0 to 9.0, and oxygen gas is blown.Type: ApplicationFiled: February 23, 2010Publication date: July 7, 2011Applicant: SUMITOMO METAL MINING CO., LTD.Inventors: Hiroshi Kobayashi, Norihisa Toki, Hirofumi Shoji, Keiji Kudo, Tatsuya Higaki
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Patent number: 7678281Abstract: A method of reclaiming a well completion brine solution containing metal impurities by introducing to the brine solution an organic chelant of the formula: and may be either a neutral compound, a corresponding salt, or a corresponding quaternary salt, wherein: D is F-A (Y3)u(Y4)v; R is independently selected from Cp or CpC(O); Cp is a C1-C36, preferably a C8-C36, hydrocarbyl group, optionally substituted with one or more substituents selected the group consisting of halogen, hydroxyl, sulfate, CH2CO2Z or —(CH2)nPO(OZ)2 groups; each A is independently selected from —N and —P; Y1 is independently selected from J, —[(F)-A(J)]w Y6 and R; J, R1, Y2, Y3, Y4, Y5 and Y6 are independently selected from the group consisting of —H, R, —(F)nCO2Z and —(CH2)nPO(OZ)2; each F is independently selected from a C1-C12 hydrocarbyl group, optionally substituted with one or more substituents selected from the group consisting of halogen, hydroxyl, sulfate, CH2CO2Z or —(CH2)nPO(OZ)2 groups; Z is —H, a balanced organic counteType: GrantFiled: February 2, 2007Date of Patent: March 16, 2010Assignee: BJ Services CompanyInventors: Paul H. Javora, Qi Qu
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Patent number: 7674384Abstract: A method of reclaiming a well completion brine solution by using an organic chelant that is capable of discriminating between (i) iron and non-zinc heavy metals; and (ii) calcium and zinc. The chelant contains a functional group selected from the group —CO2H or —PO(R21)R20 or a salt or ester thereof, —C(O)—, —OE, —SE, —N?C(R2)R3, EO—N?C(R2)R3, —N(R2)R3, and —N(C(O)R1)R2 group optionally substituted with a —COOH or —PO(R21)R20 or a salt or ester thereof, —SE or —OE group, wherein R2 and R3 are independently selected from E or forms, with nitrogen, phosphorous, oxygen or sulfur, a heterocyclic ring; E is R1 or —H; R1 is a C1-C30 alkyl or aralkyl group or a derivative thereof and R20 and R21 are independently selected from —OH, —OR1 and R1.Type: GrantFiled: February 2, 2007Date of Patent: March 9, 2010Assignee: BJ Services CompanyInventors: Paul H. Javora, Qi Qu
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Publication number: 20100051555Abstract: An arsenic removal process where arsenic 3 is oxidized to arsenic 5 where the water is passed upflow through a bed of manganese dioxide (MnO2) at a sufficient flow rate such that the MnO2 bed is fluidized whereby precipitating or precipitated iron and/or manganese and/or any other suspended solids will pass through the bed. The suspended matter is then removed by passing the water through disposable or reusable filters. The oxidized arsenic is then removed by passing the water through applicable arsenic removal media.Type: ApplicationFiled: August 27, 2009Publication date: March 4, 2010Inventor: Frank S. Craft, SR.
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Patent number: 7641801Abstract: A method and system of removing or decreasing waste liquor manganese concentration to less than about 1 mg/L total manganese without the precipitation of significant amounts of magnesium. The method and system include steps for treating the waste liquor using three separate circuits in which in the first circuit, manganese is reduced, for example, from about 2 g/L to <500 mg/L using pH adjustment with a suitable neutralizing agent; and in the second circuit, the final target manganese level is achieved by oxidative precipitation using a suitable oxidizing agent. Part of the precipitated manganese product, e.g., MnO2, is recycled to the oxidative precipitation circuit as seed and the balance proceeds to a third circuit wherein the precipitated manganese product is re-dissolved, and then recycled to the first neutralization circuit. In the first neutralization circuit and the second oxidative precipitation circuit, the process conditions are selected to minimize the precipitation of magnesium, e.g., Mg(OH)2.Type: GrantFiled: February 28, 2007Date of Patent: January 5, 2010Assignee: Vale Inco LimitedInventors: Mohamed Buarzaiga, Eric Devuyst, Julian Edwards, Joe Paventi
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Publication number: 20090255678Abstract: Systems and methods for treating aqueous fluids and their associated methods of use are disclosed. In one embodiment, a method comprises providing an untreated aqueous fluid with a first concentration of a contaminant. The method further comprises chemically treating the aqueous fluid to precipitate at least a portion of the contaminant. The method further comprises mechanically treating the aqueous fluid to remove at least some of the precipitated contaminant from the aqueous fluid, and to produce a treated water with a second concentration of the contaminant, wherein mechanically treating the aqueous fluid comprises flowing the aqueous fluid through a centrifuge. The method further comprises placing the treated water in a first well bore of the well treatment operation.Type: ApplicationFiled: June 12, 2009Publication date: October 15, 2009Inventors: Randy Rosine, Johanna Haggstrom, Michael McCabe
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Publication number: 20090242489Abstract: A process and apparatus for removing elements is described herein.Type: ApplicationFiled: March 28, 2008Publication date: October 1, 2009Applicant: Global Materials Technologies, Inc.Inventors: Terrence P. Kane, Raymond Joseph Lovett
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Publication number: 20090184056Abstract: Oilfield completion, drilling, produced, flowback, and workover fluids containing iron are treated to remove the iron by passing them through a cavitation device together with an oxidizing agent and with the addition of lime. The cavitation device intimately mixes the oxidizing agent with the fluid while increasing the temperature of the fluid, thus promoting the oxidation reaction. Lime contributes to an increase in pH while promoting the formation of floc. Ferric hydrate and other solids or colloidal iron are removed in a filter capable of removing particles as small as 0.5 micron. The system may be enhanced by the addition of a bed of activated carbon capable of catalyzing the oxidation reaction.Type: ApplicationFiled: January 22, 2009Publication date: July 23, 2009Inventors: Kevin W. Smith, Harry D. Smith, JR.
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Publication number: 20090084733Abstract: The present invention is a method and system for treating iron-contaminated water (e.g., mine drainage) using an innovative treatment approach identified herein as the Activated Iron Solids (AIS) Process. The AIS process is capable of oxidizing and removing iron as iron oxides from iron-contaminated waters (such as, mining-related discharge, groundwater, surface water and industrial waste streams) producing a clean effluent. The AIS process is performed in a single or multiple tank system in which high concentrations of AIS are suspended through mechanical mixing to maintain a catalytic surface chemistry environment that increases iron removal thousands times faster than would naturally occur and hundreds times faster than existing arts (e.g., aerobic pond passive treatment). The AIS process can utilize inexpensive alkaline material (such as, pulverized limestone) where initial mine drainage alkalinity (mg/L as CaCO3) to ferrous iron (mg/L) ratio is less than approximately 1.7.Type: ApplicationFiled: September 12, 2008Publication date: April 2, 2009Inventor: Jonathan M. Dietz
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Publication number: 20090020482Abstract: A method and a device for purifying water from contaminant trace species, especially arsenic, by co-precipitating trace species during oxidation and precipitation of iron compounds with subsequent separation. The co-precipitation is improved by contacting the water with an iron-containing material prior to oxidation to increase the iron content of the water. Arsenic and other trace species harmful to health may be removed from water effectively and in a simple manner, thus being able to comply with the more restrictive limits of arsenic in drinking water.Type: ApplicationFiled: May 11, 2006Publication date: January 22, 2009Applicant: MICRODROP ACQUA ApSInventor: Finn Lebech
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Publication number: 20080314839Abstract: Iron composite particles for purifying soil or ground water, comprise ?-Fe and magnetite, and having a ratio of a diffraction intensity D110 of (110) plane of ?-Fe to a sum of a diffraction intensity D311 of (311) plane of magnetite and the diffraction intensity D110 (D110/(D311+D110)) of 0.30 to as measured from X-ray diffraction spectrum of the iron composite particles, an Al content of 0.10 to 1.50% by weight and an S content of 3500 to 7000 ppm; a process for producing the iron composite particles; a purifying agent containing the iron composite particles; a process for producing the purifying agent; and a method for purifying soil or ground water.Type: ApplicationFiled: August 13, 2008Publication date: December 25, 2008Applicant: TODA KOGYO CORPORATIONInventors: Masayuki Uegami, Junichi Kawano, Koji Kakuya, Tomoko Okita, Kenji Okinaka
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Patent number: 7459086Abstract: A method for treating water to produce potable water is described herein. The inventive method enables the efficient removal of iron, manganese, and arsenic without the addition of powerful oxidants and without requiring a complex procedure for preparing the filtering material. The described method treats the water by passing the water through at least one bed of filter material, where the filter material comprises an association of manganese dioxide grains and at least one iron-based divided material in the hydroxide, oxide, or metallic state. The association may comprise a mixture of the iron-based divided material and the manganese dioxide grains. Alternatively, the association may comprise a superposition of layers of the iron-based divided material and the manganese dioxide grains.Type: GrantFiled: April 30, 2003Date of Patent: December 2, 2008Assignee: OTV SA S.A.Inventor: Abdelkader Gaid
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Publication number: 20080185345Abstract: There is a method of capturing, removing or collecting the particulate matter from a fluid containing a toxic liquid reaction and particulate matter produced from the reaction. The method includes partly or completely disposing a screen into the toxic fluid. Mixing the toxic fluid allowing the particulate matter to contact the screen. Moving the screen to capture the particulate matter on the screen. Removing the particulate matter from the screen by washing or scraping. There is also a cleaning apparatus to capture, remove or collect particulate matter from a toxic fluid. A cleaning apparatus contains at least a screen and a structure securing the screen. The cleaning apparatus can optionally include a scraping or washing means, a drive means, a flow inducer and a housing structure.Type: ApplicationFiled: April 3, 2008Publication date: August 7, 2008Inventor: Melvin C. Stanley
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Publication number: 20080179256Abstract: Disclosed are systems and methods for removing oxidizable metals from a liquid without the use of chemicals. This aeration technology maximizes the surface area-to-volume ratio of oxygen in the gas used. A system may comprise a dissolved oxygen addition device configured to receive the liquid and comprising a substrate with pores. A compressed gas source is connected to the device and configured to inject compressed gas containing oxygen through the substrate and into the liquid. Sub-micron sized bubbles are created on the substrate when the gas passes through the pores and expands in the liquid. The bubbles are removed from the substrate by passing liquid media while they have buoyancy insufficient to overcome a surface tension between the substrate and the bubbles. The bubbles then diffuse into the liquid to oxidize soluble oxidizable metals in the liquid media to create oxidized insoluble metal particles.Type: ApplicationFiled: January 23, 2008Publication date: July 31, 2008Applicant: PURIFICS ENVIRONMENTAL TECHNOLOGIES, INC.Inventors: Brian E. Butters, Anthony L. Powell
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Patent number: 7378022Abstract: A biological system for removing selenium from waste water comprises a first immobilized cell bioreactor (ICB) and a selenide removal module. The first ICB comprises a chamber having a substrate housed therein and situated to contact the waste water flowing therethrough during use. Anaerobic microorganisms are supported on the substrate, and comprise selenium respiring bacteria capable of reducing selenates and selenites to insoluble elemental selenium and/or sulfate reducing bacteria capable of reducing selenates and selenites to insoluble elemental selenium or to soluble selenides. The selenide removal module includes metallic or oxidized iron compounds capable of chemically reacting with selenide or sulfide compounds in the waste water to form iron selenide or iron sulfide precipitates.Type: GrantFiled: June 6, 2006Date of Patent: May 27, 2008Assignee: Honeywell International Inc.Inventors: Francis S. Lupton, William G. Sheridan