Acrylic Patents (Class 210/733)
  • Patent number: 10155849
    Abstract: There is disclosed certain hyperbranched polyester amides with end groups selected from: esters or amides of betaine-type end groups useful in various end uses such as a flocculent.
    Type: Grant
    Filed: June 20, 2014
    Date of Patent: December 18, 2018
    Assignee: DSM IP ASSETS B.V.
    Inventors: Henricus Johannes Arts, Thomas Dikken, Remco Dinkelberg
  • Patent number: 9533891
    Abstract: A washing method of red mud that is produced when an alumina-containing ore having a goethite to hematite mass ratio of 60/40 (goethite/hematite) or more in the iron component thereof is heat-treated with an alkaline solution at a temperature of 110° C. to 160° C. to obtain an aluminate liquor, including: mixing the red mud with a diluting fluid to obtain suspension that has an aluminum concentration of 95 g/L or less in terms of Al2O3; adding a flocculant to the suspension, wherein, the flocculant includes a polymer having a repeating unit derived from (meth)acrylic acid or a salt thereof and being substantially free from a repeating unit derived from vinylhydroxamic acid compound or a salt thereof; and settling and separating the red mud so as to wash the red mud.
    Type: Grant
    Filed: April 5, 2013
    Date of Patent: January 3, 2017
    Assignee: SHOWA DENKO K.K.
    Inventor: Yu Akama
  • Publication number: 20150053623
    Abstract: Flowable liquid suspensions are described comprising blends of particulate water soluble high molecular weight polymer flocculants. The polymer flocculants can include polyethylene oxide, polyacrylamide, polyDadmac, Dadmac-acrylamide copolymers, copolymers thereof and combinations thereof. The suspension allows the use of fine powders while reducing potential air quality and safety issues. The suspensions generally settle when mixing is stopped, but a uniform dispersion results when the suspensions are mixed, and the mixed suspensions can be delivered for use. The flocculant suspensions can be used for waste water purification, fiber dewatering, and the like.
    Type: Application
    Filed: August 22, 2013
    Publication date: February 26, 2015
    Inventors: Jason Holt, Malcolm Barry Lindler
  • Publication number: 20140284519
    Abstract: The invention relates to a process for the purification of water and/or dewatering of sludges and/or sediments, to the use of a surface-treated calcium carbonate for water purification and/or dewatering of sludges and/or sediments, as well as to the use of a surface-treated calcium carbonate for reducing the amount of polymeric flocculation aids in water and/or sludges and/or sediments and to a composite material comprising a surface-treated calcium carbonate and impurities originated from different sources obtainable by said process.
    Type: Application
    Filed: October 30, 2012
    Publication date: September 25, 2014
    Inventors: Daniel E. Gerard, Hans-Georg Hartan, Joachim Schoelkopf, Michael Skovby, Patrick A.C. Gane
  • Publication number: 20140238943
    Abstract: A method for treating a suspension of mineral particles in water, such as mineral tailings, includes the step of contacting the suspension of mineral particles in water with a specific water-soluble polymer. This polymer is preferably a water-soluble polymer having an anionicity of between 10 to 55 mol %, and more preferably 20 to 50 mol %. Furthermore, this polymer has preferably a molecular weight between 15 and 40 million daltons, and more preferably between 18 and 30 million. The method involves adding the specific polymer into a thickener containing the tailings to treat, and/or during transport of the suspension to a deposition area for dewatering and solidification, or to the tailings to treat followed by a mechanical treatment such as centrifugation, screw press and filtration.
    Type: Application
    Filed: February 22, 2013
    Publication date: August 28, 2014
    Inventors: Cedrick Favero, Scott Ramey, Trong Dang-Vu
  • Patent number: 8728326
    Abstract: The invention relates to a polymer comprising structural units of formula and formula wherein R1, R2, R5 and R6 are independently hydrogen, a methyl group, or —COOH, only one of R1 and R2 or R5 and R6 is —COOH; R3 and R7 are independently hydrogen, or a methyl group; R4 is —COOH, —CONH2 or —OH, when R4 is —OH, R1, R2 and R3 are respectively hydrogen; and R8 is —COO, —CONH, or —O—, when R8 is —O—, R5, R6 and R7 are respectively hydrogen. Methods for preparing and using the polymer are also described herein.
    Type: Grant
    Filed: March 29, 2011
    Date of Patent: May 20, 2014
    Assignee: General Electric Company
    Inventors: Wenqing Peng, Yangang Liang, Shengxia Liu, Larry Neil Lewis, Robert James Perry, Stephen Robert Vasconcellos, Su Lu, Guixi Zhang
  • Patent number: 8721896
    Abstract: The disclosure relates generally to the use of low molecular weight polymers to aggregate mineral components in aqueous mineral slurries to release and separate individual components of the slurry, which may then be recovered from the slurry.
    Type: Grant
    Filed: January 23, 2013
    Date of Patent: May 13, 2014
    Assignee: Sortwell & Co.
    Inventor: Edwin T. Sortwell
  • Patent number: 8663496
    Abstract: The invention relates to a double-layered compacted solid water-purification product, comprising at least one first layer and at least one second layer, characterized in that the first layer comprises at least one flocculating system and at least one dispersion system, the second layer comprises at least one disinfectant which liberates free chlorine on contact with water and at least one excipient for the disinfectant, whereby said excipient releases the disinfectant into the water at a controlled rate such that the combination of excipient and disinfectant releases 0.1 to 100 mg/l of free chlorine per hour. The invention further relates to the method for production of such a product.
    Type: Grant
    Filed: July 18, 2005
    Date of Patent: March 4, 2014
    Assignee: Eurotab
    Inventors: Paul Branlard, Philippe Desmarescaux, Murielle Moneron
  • Patent number: 8562838
    Abstract: Provided is a method for treating sludge from the mining or mineral industry, including before above-ground spreading, contacting the sludge with a flocculating agent that is a water-soluble, organic polymer having a molecular weight of from 5,000,000 to 25,000,000 g/mol and an anionicity of from 10 to 40 mol %, to produce contacted sludge, wherein the water-soluble organic polymer includes at least one anionic monomer having a carboxylic function or having a sulfonic acid function, at least one non-ionic monomer, and optionally one or more cationic monomers, where the flocculating agent is branched, and has from 0.02 to 2 mol % hydrophobic monomers.
    Type: Grant
    Filed: October 20, 2009
    Date of Patent: October 22, 2013
    Assignee: SNF S.A.S.
    Inventors: Frédéric Poncet, Nicolas Gaillard
  • Patent number: 8557125
    Abstract: A coagulant composition includes chitosan, methacryloyloxyethyltrimethyl ammonium methyl sulfate and a redox initiator. A coagulant, method for making the coagulant and clarifying wastewater is also provided.
    Type: Grant
    Filed: June 7, 2010
    Date of Patent: October 15, 2013
    Assignee: General Electric Company
    Inventors: Seethalakshmi Suresh, Stephen Robert Vasconcellos, Narain Madhavan, Baraka Kawawa
  • Publication number: 20130220922
    Abstract: The invention concerns an online method and system for monitoring properties of an aqueous stream of an industrial process. The method comprises providing an initial aqueous stream originating from said process, the aqueous stream containing solid matter exhibiting a first settling behavior; adding modifying agent to the initial aqueous stream at an addition rate sufficient to provide a modified aqueous stream containing solid matter exhibiting a second settling behavior different from the first settling behavior; conducting a sample of the initial aqueous stream or modified aqueous stream, any combination stream comprising the modified aqueous stream or any substream of the modified aqueous stream batchwise from a sampling point to a settling vessel having a volume; and measuring the settling behavior of the solid matter in the sample locally in the settling vessel as a function of time.
    Type: Application
    Filed: July 19, 2011
    Publication date: August 29, 2013
    Applicant: KEMIRA OYJ
    Inventors: Iiris Joensuu, Marjatta Piironen, Eija Saari, Jukka-Pekka Sirviö, Seppo Tuomivaara
  • Patent number: 8506822
    Abstract: A process of concentrating an aqueous suspension of solid particles comprising the steps of adding at least one organic polymeric flocculant to the suspension thereby forming flocculated solids in which the flocculated solids are allowed form a layer of solids and thereby forming a more concentrated suspension in which the process comprises the addition of an effective amount of an agent that is selected from the group consisting of free radical agents, oxidizing agents, enzymes and radiation, in which the agent is applied to the suspension prior to or substantially simultaneously with adding the organic polymeric flocculant and/or the organic polymeric flocculant is added to the suspension in a vessel and the agent is applied to the suspension in the same vessel. The process is particularly suitable for solids liquid separation in which the flocculated solids are allowed to settle by sedimentation in a gravity thickener.
    Type: Grant
    Filed: December 8, 2011
    Date of Patent: August 13, 2013
    Assignee: BASF SE
    Inventors: Gillian Moody, Anthony Allen, Stephen Adkins, Brian Dymond, Paul Stocks
  • Publication number: 20130186838
    Abstract: The disclosure relates generally to the use of polymers to assist in aggregating mineral components in aqueous mineral slurries to release and separate individual components of the slurry, which may then be recovered from the slurry.
    Type: Application
    Filed: July 19, 2011
    Publication date: July 25, 2013
    Applicant: SORTWELL & CO.
    Inventor: Edwin T. Sortwell
  • Publication number: 20130153510
    Abstract: The invention relates to a method and system for treating an aqueous stream having a first flow rate and containing solid matter exhibiting first settling properties, the method comprising adding a modifying agent to the aqueous stream at an addition rate sufficient to change the first settling properties of the aqueous stream to obtain a modified aqueous stream having solid matter exhibiting second settling properties different from the first settling properties; taking batchwise samples of the modified aqueous stream to a settling vessel having a volume; determining a settling property of the solid matter of the samples in the settling vessel; and conducting the modified aqueous stream to a separation unit in which solid matter is separated from the modified aqueous stream. The invention provides a convenient way of monitoring and/or controlling aqueous streams conducted for example to purification processes.
    Type: Application
    Filed: July 19, 2011
    Publication date: June 20, 2013
    Applicant: KEMIRA OYJ
    Inventors: Kaj Jansson, Iiris Joensuu, Marjatta Piironen, Jukka-Pekka Sirviö, Tapio Yrjänäinen
  • Patent number: 8361342
    Abstract: The present invention relates to a compacted solid product for water purification comprising:—at least a first layer comprising at least a coagulant/flocculant system comprising at least one polyvalent inorganic salt, at least one water-soluble cationic polymer and at least one high-molecular-weight anionic polymer,—at least a second layer comprising at least one disinfectant that releases active chlorine on contact with water, characterized in that said coagulant/flocculant system moreover comprises a sodium alginate. The invention also relates to the method for preparing such a product.
    Type: Grant
    Filed: October 4, 2007
    Date of Patent: January 29, 2013
    Assignee: Eurotab
    Inventors: Paul Branlard, Gilles Rubinstenn
  • Patent number: 8211389
    Abstract: Uses for a composition comprising a polymer derived from at least two monomers: acrylic-x and an alkylamine, wherein said polymer is modified to contain a functional group capable of scavenging one or more compositions containing one or more metals are disclosed. These polymers have many uses in various mediums, including wastewater systems.
    Type: Grant
    Filed: April 6, 2010
    Date of Patent: July 3, 2012
    Assignee: Nalco Company
    Inventors: Paul J. Zinn, Jitendra T. Shah, William J. Andrews
  • Publication number: 20120103916
    Abstract: The suspended solids content of a process stream in a process for digesting bauxite ore to produce alumina is reduced by contacting the stream with silicon-containing polymers.
    Type: Application
    Filed: January 5, 2012
    Publication date: May 3, 2012
    Applicant: CYTEC TECHNOLOGY CORP.
    Inventors: Matthew J. Davis, Qi Dai, Haunn-Lin Tony Chen, Matthew Taylor
  • Patent number: 8147703
    Abstract: The invention relates to a method for processing sludge, comprising the addition of a lime-based basic agent to a sludge having a first pH value in order to raise the pH to a second value higher than the first one, adding at least one anionic organic flocculating agent that is active at said second pH value, flocculating the sludge, and separating the flocculated sludge between dehydrated sludge and a liquid phase, wherein the sludge to be dehydrated has a first above-mentioned pH value lower than 9, while the lime-based basic agent induces said pH raise to said above-mentioned second value within less than 5 minutes. The invention also relates to a composition for implementing said processing.
    Type: Grant
    Filed: November 13, 2007
    Date of Patent: April 3, 2012
    Assignee: S.A. Lhoist Recherche et Developpement
    Inventor: Marc Joseph Henri Remy
  • Patent number: 8097167
    Abstract: The present invention relates to a process of concentrating an aqueous suspension of solid particles comprising the steps of adding at least one organic polymeric flocculant to the suspension thereby forming flocculated solids in which the flocculated solids are allowed form a layer of solids and thereby forming a more concentrated suspension in which the process comprises the addition of an effective amount of an agent that is selected from the group consisting of free radical agents, oxidising agents, enzymes and radiation, in which the agent is applied to the suspension prior to or substantially simultaneously with adding the organic polymeric flocculant and/or the organic polymeric flocculant is added to the suspension in a vessel and the agent is applied to the suspension in the same vessel. The process is particularly suitable for solids liquid separation in which the flocculated solids are allowed to settle by sedimentation in a gravity thickener.
    Type: Grant
    Filed: January 4, 2007
    Date of Patent: January 17, 2012
    Assignee: BASF SE
    Inventors: Gillian Moody, Anthony Allen, Stephen Adkins, Brian Dymond, Paul Stocks
  • Publication number: 20110155671
    Abstract: The present invention relates to a process of concentrating an aqueous suspension of solid particles comprising the steps of adding at least one organic polymeric flocculant to the suspension thereby forming flocculated solids in which the flocculated solids are allowed form a layer of solids and thereby forming a more concentrated suspension in which the process comprises the addition of an effective amount of an agent that is selected from the group consisting of free radical agents, oxidising agents, enzymes and radiation, in which the agent is applied to the suspension prior to or substantially simultaneously with adding the organic polymeric flocculant and/or the organic polymeric flocculant is added to the suspension in a vessel and the agent is applied to the suspension in the same vessel. The process is particularly suitable for solids liquid separation in which the flocculated solids are allowed to settle by sedimentation in a gravity thickener.
    Type: Application
    Filed: January 4, 2007
    Publication date: June 30, 2011
    Applicant: CIBA CORPORATION
    Inventors: Gillian Moody, Anthony Allen, Stephen Adkins, Brian Dynond, Paul Stocks
  • Patent number: 7875188
    Abstract: A process in which a suspension comprising dispersed particulate material in an aqueous medium is transferred as a fluid to a deposition area, then allowed to stand and rigidify, and in which rigidification is improved whilst retaining the fluidity of the suspension during transfer, by combining with the suspension during transfer a rigidifying amount of a treatment system which comprises i) a water-soluble synthetic polymer and ii) a water-soluble natural or seminatural polymer. Improved rigidification can be achieved, including dose efficiency especially in regard to the amount of synthetic polymer required. In addition improvements in the clarity of liquor released from the suspension can be achieved.
    Type: Grant
    Filed: May 4, 2007
    Date of Patent: January 25, 2011
    Assignee: BASF SE
    Inventors: Brian Dymond, John Lamperd, Angela Beveridge
  • Patent number: 7736515
    Abstract: There is provided a method for highly treating distillation waste generated in the process of separating a distilled alcoholic material after alcoholic fermentation of starchy materials. The method includes the steps of adding sodium polyacrylate to the distillation waste from the starchy materials, then adding chitosan to treat the distillation waste, and further adding sodium polyacrylate to the waste. Furthermore, solid-liquid separation is then carried out. A liquid material thus separated is brought into contact with a reverse osmosis membrane.
    Type: Grant
    Filed: January 17, 2008
    Date of Patent: June 15, 2010
    Assignees: Mitsubishi Gas Chemical Company, Inc., Dia Aqua Solutions Co., Inc.
    Inventors: Hiroshi Takamiya, Shoichiro Kajiwara, Koji Hirukawa, Kimihisa Iwashiro
  • Publication number: 20100108616
    Abstract: The invention relates to a dispersing agent composition and to a process for treating liquid slurries of bentonite particles, optionally comprising contaminating solids, in order to remove any contaminating solids and/or the bentonite particles, wherein said dispersing agent composition is added to said slurry causing contaminating solids and/or the bentonite particles to settle without flocculation.
    Type: Application
    Filed: January 24, 2008
    Publication date: May 6, 2010
    Applicant: GEO Grounding Engineering Operations
    Inventors: Arnaud R. W. Bostyn, Jorge Capitao-Mor Da Costa E Silva
  • Patent number: 7674382
    Abstract: A method of cleaning a fouled and/or scaled UF or MF membrane with a solution containing one or more thermo-responsive polymers is disclosed. More specifically, the method comprises: (a) treating the membrane in a membrane separation system with a solution containing one or more TRP, wherein said TRP is soluble in said solution and at least an effective amount of said TRP diffuses into a foulant layer that is present on the surface and/or in pores of said membrane; (b) making insoluble said TRP diffused into said foulant layer; (c) optionally rinsing the membrane; (d) optionally backwashing the membrane with air and/or liquid between the steps (b) and (c); and (e) optionally backwashing the membrane with air and/or liquid after the membrane is rinsed in step (c).
    Type: Grant
    Filed: May 3, 2007
    Date of Patent: March 9, 2010
    Assignee: Nalco Company
    Inventor: Deepak A. Musale
  • Patent number: 7662289
    Abstract: A method of cleaning a fouled or a scaled RO or NF membrane surface with a solution containing one or more thermo-responsive polymers is disclosed. More specifically, the method comprises: treating the membrane surface in a membrane separation system with a solution containing one or more TRP, wherein said TRP is soluble in said solution and at least an effective amount of said TRP diffuses into a foulant layer on said membrane surface; making insoluble said TRP diffused into said foulant layer; optionally, rinsing the membrane.
    Type: Grant
    Filed: January 16, 2007
    Date of Patent: February 16, 2010
    Assignee: Nalco Company
    Inventors: Deepak A. Musale, E. H. Kelle Zeiher
  • Patent number: 7608191
    Abstract: A process of separating suspended solids from a fermentation liquor by subjecting the liquor to a solids-liquid separation stage, wherein the fermentation liquor is produced in a fermentation process for the production of a fermentation product, and which liquor comprises lignin, wherein the solids-liquid separation stage is assisted by a treatment system, characterized in that the treatment system comprises an anionic polymer, with the proviso that the treatment system and does not include a cationic polymer having an intrinsic viscosity (IV) of at least 4 dl/g.
    Type: Grant
    Filed: January 20, 2005
    Date of Patent: October 27, 2009
    Assignee: Ciba Specialty Chemicals Water Treatments Ltd.
    Inventors: Jonathan Hughes, Rajesh Mistry, Kenneth Charles Symes
  • Patent number: 7575625
    Abstract: A solid is separated from a gas scrubber by collecting a solids burden not collected at a solids-collection device of a flue gas desulfurization system by adding at least one flocculant, flocculation aid or mixtures thereof, while using a separating device; wherein te flue-gas desulfurization system contains at least one absorption device disposed downstream from said solids-collection device.
    Type: Grant
    Filed: September 15, 2005
    Date of Patent: August 18, 2009
    Assignee: Ashland Licensing and Intellectual Property LLC
    Inventors: Frank Seida, Peter Graf
  • Patent number: 7566469
    Abstract: A method of dewatering corn stillage solids comprising adding to the solids an effective coagulating and flocculating amount of an anionic copolymer comprising acrylic acid sodium salt, methacrylic acid sodium salt or 2-acrylamido-2-methyl-1-propanesulfonic acid sodium salt to form a mixture of water and coagulated and flocculated solids; and separating the water from the coagulated and flocculated solids using a dewatering device.
    Type: Grant
    Filed: October 13, 2003
    Date of Patent: July 28, 2009
    Assignee: Nalco Company
    Inventor: David W. Scheimann
  • Patent number: 7560032
    Abstract: A high molecular weight, water-soluble polymer comprising pendant salicylic acid groups and having a weight average molecular weight of at least about 2,000,000 daltons and use of the polymer for clarifying red mud-containing liquors generated in the Bayer process for the recovery of alumina from bauxite.
    Type: Grant
    Filed: August 17, 2006
    Date of Patent: July 14, 2009
    Assignee: Nalco Company
    Inventors: Murat Quadir, Everett C. Phillips, Larry E. Brammer, Jr., Robert P. Mahoney, John D. Kildea, Manian Ramesh, John T. Malito
  • Patent number: 7413681
    Abstract: A process for partial oxidation of a hydrocarbon gas or liquid, involving the steps of partial oxidation and removal of soot by forming a slurry having water and carbon from the gaseous oxidation product, and separating part of the water from the slurry to obtain a soot composition having less water, wherein the separation is performed by means of a decanter centrifuge.
    Type: Grant
    Filed: March 28, 2002
    Date of Patent: August 19, 2008
    Assignee: Shell Oil Company
    Inventors: Gerard Grootveld, Franciscus Johanna Arnoldus Martens
  • Patent number: 7381332
    Abstract: This invention relates to a method of achieving a solid-liquid separation of an oil-based mud comprising the step of contacting said oil-based mud with a water-in-oil emulsion comprising a polymer derived from at least one water-soluble monomer, where the polymer is not dissolved prior to contact with the oil-based mud, mixing the water-in-oil emulsion and the oil-based mud and separating the solid phase from the liquid phase in the oil-based mud. In addition, this invention also relates to a composition comprising an oil-based mud with a water-in-oil emulsion comprising a polymer derived from at least one water-soluble monomer, wherein the polymer is not dissolved prior to contact with the oil-based mud.
    Type: Grant
    Filed: July 16, 2004
    Date of Patent: June 3, 2008
    Assignee: Kemira Oyj
    Inventors: Jorge Eduardo Adams Pena, Henry M. Masias, Sun-Yi Huang, Raymond S. Farinato
  • Patent number: 7338608
    Abstract: This invention relates to a method of achieving a solid-liquid separation of an oil-based mud comprising the step of contacting said oil-based mud with a water-in-oil emulsion comprising a polymer derived from at least one water-soluble monomer, where the polymer is not dissolved prior to contact with the oil-based mud, mixing the water-in-oil emulsion and the oil-based mud and separating the solid phase from the liquid phase in the oil-based mud. In addition, this invention also relates to a composition comprising an oil-based mud with a water-in-oil emulsion comprising a polymer derived from at least one water-soluble monomer, wherein the polymer is not dissolved prior to contact with the oil-based mud.
    Type: Grant
    Filed: September 30, 2003
    Date of Patent: March 4, 2008
    Assignee: Kemira Oyj
    Inventors: Jorge Adams, Henry Masias, Sun-Yi Huang, Raymond Farinato
  • Patent number: 7250462
    Abstract: The invention relates to an amphoteric water-soluble polymer dispersion containing polymer particles with particle diameters of 100 ?m or smaller and produced by dispersion-copolymerization of a monomer mixture comprising a methacrylate monomer containing a quaternary ammonium salt group, an acrylate monomer containing a quaternary ammonium salt group, an anionic monomer, and a (meth)acrylamide in respectively ratios specified in an aqueous salt solution in the presence of a polymer dispersant soluble in the aqueous salt solution and the invention also relates to a dewatering agent for organic sludge, a pretreatment agent or yield improver for paper making raw materials, and/or a drainage properties-enhancing agent using the amphoteric water-soluble polymer.
    Type: Grant
    Filed: May 28, 2002
    Date of Patent: July 31, 2007
    Assignee: Hymo Corporation
    Inventors: Isamu Kubota, Hiroyuki Koshio
  • Patent number: 7138472
    Abstract: A high molecular weight, water-soluble polymer comprising pendant salicylic acid groups and having a weight average molecular weight of at least about 2,000,000 daltons and use of the polymer for clarifying red mud-containing liquors generated in the Bayer process for the recovery of alumina from bauxite.
    Type: Grant
    Filed: February 24, 2003
    Date of Patent: November 21, 2006
    Assignee: Nalco Company
    Inventors: Murat Quadir, Everett C. Phillips, Larry E. Brammer, Jr., Robert P. Mahoney, John D. Kildea, Manian Ramesh, John T. Malito
  • Patent number: 6926832
    Abstract: A method of conditioning mixed liquor in a membrane biological reactor comprising adding to the mixed liquor an effective coagulating and flocculating amount of one or more water soluble cationic, amphoteric or zwitterionic polymers, or combination thereof and methods of reducing membrane fouling, enhancing membrane flux and reducing sludge production.
    Type: Grant
    Filed: December 26, 2002
    Date of Patent: August 9, 2005
    Assignee: Nalco Company
    Inventors: John H. Collins, Kristine S. Salmen, Deepak A. Musale, Seong-Hoon Yoon, William J. Ward
  • Patent number: 6784267
    Abstract: A water-soluble, cationic polymer comprising from about 1 to about 65 mole percent of one or more cationic monomers, from about 99 to about 35 mole percent of one or more nonionic monomers and from about 1 to about 1000 ppm, based on the total monomer content, of one or more hyperbranched monomers wherein the hyperbranched monomer contains from about 2 to about 20 allyl, vinyl, or acrylic end groups and method of dewatering sludge is disclosed.
    Type: Grant
    Filed: July 25, 2002
    Date of Patent: August 31, 2004
    Assignee: Nalco Company
    Inventors: William J. Ward, Ananthasubramanian Sivakumar
  • Patent number: 6736981
    Abstract: The use is described of particulate, water-insoluble and scarcely swellable polymers of ethylenically unsaturated monomers, which polymers contain, copolymerized, at least 20% by weight, based on the total weight of the monomers, of at least one &agr;,&bgr;-monoethylenically unsaturated monocarboxylic acid having from 3 to 6 carbons as filter aid for filtering aqueous liquids. Subject-matter of the invention are also water-insoluble, scarcely swellable polymers (popcorn polymers) that contain, copolymerized, &agr;,&bgr;-monoethylenically unsaturated carboxylic acids and styrene or styrene derivatives, and also a process for their preparation.
    Type: Grant
    Filed: February 19, 2002
    Date of Patent: May 18, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Marcos Gomez, Tilman C Rock, Helmut Meffert, Axel Sanner
  • Patent number: 6726845
    Abstract: The claimed invention is a method for separating Bayer process red mud from a Bayer process liquor which comprises adding to a Bayer process liquor containing red mud an effective amount of a water soluble synthetic flocculant, dextran and starch combination. The flocculant is added anywhere in the slurry containing the red mud suspended in Bayer process liquor, or in a liquor slurry containing bauxite prior to or during digestion. Once the flocculant combination is added, it is mixed sequentially with the Bayer process liquor and the red mud contained in the Bayer process liquor is removed by sedimentation, centrifugation or filtration.
    Type: Grant
    Filed: February 15, 2001
    Date of Patent: April 27, 2004
    Assignee: Ondeo Nalco Company
    Inventors: Scott Barham, James Morton Tippett
  • Patent number: 6723249
    Abstract: A method for reducing the toxicity of onium compounds, such as ammonium compounds and phosphonium compounds, by the use of certain additives is described. Suitable additives include, but are not necessarily limited to, carboxylic acids (e.g. naphthenic acids), sulfonic acids, organophosphonic acids, phenolic compounds, ether sulfates, phosphoric acid esters, sulfonated fatty acids, sulfated fatty acids, oligocarboxylic acids, and mixtures thereof, and alkali metal salts of these compounds and amine salts of these compounds.
    Type: Grant
    Filed: December 18, 2001
    Date of Patent: April 20, 2004
    Assignee: Baker Hughes Incorporated
    Inventors: Gordon T. Rivers, Hartley H. Downs
  • Patent number: 6716357
    Abstract: A method of removing phosphoric acid contained in wastewater which comprises comprehensively immobilizing calcium or a compound thereof with a solid polymer optionally together with magnetite and contacting the calcium-containing polymer with the wastewater to react the phosphoric acid contained in the wastewater with the calcium and thereby yield calcium apatite.
    Type: Grant
    Filed: October 31, 2001
    Date of Patent: April 6, 2004
    Assignee: Japan Science and Technology Corporation
    Inventors: Takaaki Maekawa, Kazuo Fujita
  • Patent number: 6669852
    Abstract: In order to provide a method for effectively separating red mud generated during alumina-extraction treatment of an alumina ore containing goethite as an iron component, the alumina ore containing goethite as an iron component is treated with an alkaline solution at 110-160° C., to thereby take up alumina components through extraction, and a settling aid formed of a water-soluble polymer including, as an effective component, a copolymer containing, as a monomer component, a vinylhydroxamic acid compound or a salt thereof (A) and having an average molecular weight of at least 2,000 is added to the resultant extract, to thereby settle the red mud for separation thereof.
    Type: Grant
    Filed: October 30, 2001
    Date of Patent: December 30, 2003
    Assignee: Showa Denko Kabushiki Kaisha
    Inventors: Isao Ishikawa, Haruo Washikita, Yasuo Kawai, Koyuki Mesuda
  • Patent number: 6617421
    Abstract: The present invention is a method of producing substantially dry water insoluble polymers from poly alkyl esters of vinylic monomers for use in a method for the clarification of red mud-containing liquors generated in the Bayer process for the recovery of alumina from bauxite ore. The polymers can be either homopolymers, copolymers or terpolymers. Preferably, the dried emulsion polymers are high molecular weight polymers of poly(methyl acrylate), poly(methyl acrylate/acrylic acid), poly(vinyl acetate/acrylic acid/methyl acrylate), poly(t-butyl methacrylate/acrylic acid/methyl acrylate) and poly(t-butyl acrylate/acrylic acid/methyl acrylate).
    Type: Grant
    Filed: January 29, 2002
    Date of Patent: September 9, 2003
    Assignee: Ondeo Nalco Company
    Inventors: Everett C. Phillips, Ronald J. Allain
  • Patent number: 6610209
    Abstract: A method for clarifying food processing waste water containing suspended solids comprising (iii) adding to the waste water with an effective amount of at least one vinylamine polymer having a molecular weight of at least 10,000, wherein the polymer is prepared by first polymerizing N-vinylformamide and, optionally, vinyl acetate to form a vinylformamide polymer or a vinylformamide/vinylacetate copolymer and then subjecting the vinyl formamide polymer or vinylformamide/vinylacetate copolymer to acid or base hydrolysis to form a vinylamine/vinylformaide copolymer, a vinylamine homopolymer or a up vinylamine/vinylalcohol copolymer; (ii) coagulating and flocculating the suspended solids; and (iii) separating the coagulated and flocculated suspended solids from the wastewater.
    Type: Grant
    Filed: July 5, 2001
    Date of Patent: August 26, 2003
    Assignee: Ondeo Nalco Company
    Inventors: Anthony G. Sommese, Daniel K. Chung
  • Patent number: 6518459
    Abstract: A filtering means containing gelatinous and solid materials is cleaned without dismantling the filtering means by contacting the gelatinous material inside the filtering means with a solvent, thereby physically degrading the gelatinous material such that the degraded gelatinous material can pass through the filtering means.
    Type: Grant
    Filed: July 26, 2001
    Date of Patent: February 11, 2003
    Assignee: Phillips Petroleum Company
    Inventor: Brooks D. Bennett
  • Publication number: 20020096477
    Abstract: Process for treating liquid manure, comprising the introduction of homogenized liquid manure into a tank, into which are introduced some polymers/copolymers that bring about an interchange to produce the flocculation of colloidal substances and solids in suspension, which are then separated off with the aid of filters. The flocculation is carried out by feeding the liquid manure in at a constant flow rate and introducing the reagent at the same time in the form of a tertiary or quaternary polymer/copolymer, stirring the mixture for a time of between 5 and 15 minutes and then eliminating the suspended solids by flotation, involving the coalescence of the colloidal particles.
    Type: Application
    Filed: May 30, 2001
    Publication date: July 25, 2002
    Inventor: Jesus Martinez Almela
  • Patent number: 6372882
    Abstract: The present invention is a method of producing substantially dry water insoluble polymers from poly alkyl esters of vinylic monomers for use in a method for the clarification of red mud-containing liquors generated in the Bayer process for the recovery of alumina from bauxite ore. The polymers can be either homopolymers, copolymers or terpolymers. Preferably, the dried emulsion polymers are high molecular weight polymers of poly(methyl acrylate), poly(methyl acrylate/acrylic acid), poly(vinyl acetate/acrylic acid/methyl acrylate), poly(t-butyl methacrylate/acrylic acid/methyl acrylate) and poly(t-butyl acrylate/acrylic acid/methyl acrylate).
    Type: Grant
    Filed: April 3, 2000
    Date of Patent: April 16, 2002
    Assignee: Nalco Chemical Company
    Inventors: Everett C. Phillips, Ronald J. Allain
  • Patent number: 6358364
    Abstract: The invention comprises a borosilicate retention aid composition and a method for improving the production of paper by addition of the borosilicate. The borosilicate may be utilized in conjunction with a high molecular weight synthetic flocculant and/or starch, with or without the addition of a cationic coagulant. The borosilicate material is preferably a colloidal borosilicate. Methods for the preparation of the borosilicate material are disclosed.
    Type: Grant
    Filed: April 22, 2001
    Date of Patent: March 19, 2002
    Assignee: Nalco Chemical Company
    Inventors: Bruce A. Keiser, James E. Whitten
  • Patent number: 6319409
    Abstract: A process for treating waste water containing cutting oil is disclosed, which includes the steps of adding a cationic organic compound to waste water containing used cutting oil to coagulate water-insoluble matter in the water and to thereby form coagulated particles, adding an anionic organic polymer to cause those particles to grow into flocculated flocs, and separating the flocculated flocs. The process of the invention can treat waste water containing used cutting oil in an industrially beneficial way without producing a large amount of sludge.
    Type: Grant
    Filed: September 10, 1999
    Date of Patent: November 20, 2001
    Assignee: Fuji Jukogyo Kabushiki Kaisha
    Inventors: Yoshio Saitou, Masanori Kakemizu
  • Patent number: 6280631
    Abstract: The present invention provides a method for conditioning food processing waste prior to mechanical dewatering with the use of environmentally friendly coagulants and flocculants. The method of the present invention comprises treating these waste waters with an effective amount of a vinylamine polymer including from about 1 to about 100 mole percent vinylamine and from about 1 to about 99 mole percent of at least one monomer selected from the group consisting of amidine, vinylformamide, vinyl alcohol, vinyl acetate, vinyl pyrrolidinone and the esters, amides, nitriles and salts of acrylic acid and methacrytic acid. In an embodiment, the method of the present invention includes the further step of adding an effective amount of at least one flocculant to the food processing waste. The flocculent effectively agglomerates a portion of the colloidal organic solids into suspended solids.
    Type: Grant
    Filed: December 27, 1994
    Date of Patent: August 28, 2001
    Assignee: Nalco Chemical Company
    Inventors: Anthony G. Sommese, Daniel K. Chung
  • Patent number: 6261461
    Abstract: A polymer electrolyte which contains an inorganic pigment, having a sulfonated polystyrene resin as a principal ingredient, and is soluble to water.
    Type: Grant
    Filed: November 22, 1999
    Date of Patent: July 17, 2001
    Assignee: Sony Corporation
    Inventors: Yasuhito Inagaki, Tsutomu Noguchi, Haruo Watanabe, Miyuki Kuromiya