Abstract: Provided herein are methods and compositions for reducing the level of a cyanotoxin in cyanotoxin contaminated-water. The electrolytic destruction methods can include contacting the contaminated water with an electrochemical cell in the presence of a magnesium salt and applying an electrical current to the water for a time and in an amount sufficient to oxidize the cyanotoxin. The methods are useful for treatment of lake water, reservoir water, pond water, river water, or irrigation water and any water that serves as a source of drinking water.

Abstract: A sterilizing system according to the present invention includes a water supply apparatus provided with a filter unit having a plurality of filters, a water tank storing water purified by the filter unit, a water cock and water tank connection passages, and a sterilizer to sterilize the water supply apparatus, wherein the sterilizer comprises a sterilizing water generator, a circulation pump, a circulation passage, a rinsing water supply passage, a first drain passage and a first drain valve.

Abstract: A system for treating wastewater is disclosed that includes an array of interconnected reactor tubes. Each reactor tube comprises an outer cathode and an inner anode. The inner anode is positioned within the outer cathode. A voltage differential is applied across the inner anodes and the outer cathodes as wastewater flows between the inner anodes and outer cathodes. As the wastewater flows through the reactor tubes, the water is treated. The voltage differential can cause contaminants in the wastewater to flocculate. The flocculated contaminants can then be removed from the wastewater. The voltage differential can also generate chlorine based elements that treat the water removing ammonia and controlling microorganisms. The inner anode and the outer cathode can comprise mixed metal oxide materials or non-donating conductive materials.

Abstract: A low energy water treatment system and method is provided. The system has at least one electrodialysis device that produces partially treated water and a brine byproduct, a softener, and at least one electrodeionization device. The partially treated water stream can be softened by the softener to reduce the likelihood of scale formation and to reduce energy consumption in the electrodeionization device, which produces water having target properties. At least a portion of the energy used by the electrodeionization device can be generated by concentration differences between the brine and seawater streams introduced into compartments thereof. The brine stream can also be used to regenerate the softener.

Abstract: Methods and compositions for improving water quality by reducing chlorine demand, decreasing disinfection by-products and controlling deposits in water systems include adding low concentrations of supplemental oxidants, for example, RE-Ox® to the systems.

Abstract: A system for treating wastewater is disclosed that includes a series of interconnected reactor tubes. Each reactor tube comprises an outer cathode and an inner anode. The inner anode is positioned within the outer cathode. A voltage differential is applied across the inner anodes and the outer cathodes as wastewater flows between the inner anodes and outer cathodes. As the wastewater flows through the reactor tubes, chlorine based elements are generated to treat the wastewater. The system can include an injector to add chloride salts into the wastewater to generate chlorine based elements. The system can also include a feedback path to divert a portion of the wastewater with chlorine based elements back to the influent wastewater so that the chlorine based elements are mixed with the influent wastewater. The inner anode and the outer cathode can comprise non-donating conductive materials.

Abstract: A point of use electrolysis system can be used to generate oxidizing species within liquid retained by a point of use discharge nozzle, helping to prevent pathogens from growing and multiplying in the nozzle. In one example, a system includes a point of use discharge nozzle having an inlet and an outlet and electrodes. The electrodes are configured to electrochemically generate an oxidizing species within the point of use discharge nozzle. According to the example, the point of use discharge nozzle is configured to trap liquid from a liquid source, when liquid ceases flowing through the point of use discharge nozzle, thereby providing a trapped liquid. Further, the electrodes are configured to generate the oxidizing species within the trapped liquid.

Abstract: A salt water chlorinator (30) for a swimming pool includes an electrolysis cell having two anodes (98) and a cathode (94). Two scrapers (102), each of which is of titanium and includes scraping portions in the form of ribs (106) in contact with the opposite surfaces of the cathode, are reciprocated relative to the cathode (94) to remove scale deposits from the cathode (94). The scrapers (102) are mounted in a frame (110) and their scraping ribs (106) are curved such that the ribs (106) are self-biased against the cathode surfaces. A mechanism for reciprocating the scrapers (102) includes two solenoid coils (116) which act on cores (114) in a stem (112) of the frame (110). A control circuit for the electrolysis cell is contained in a housing (86) which is attached to a housing (82) for the electrolysis cell. The control circuit includes a flow sensor for sensing salt-water flow through the electrolysis cell.

Abstract: Process and apparatus to remove colloids and nitrogen compounds from contaminated water by coagulating the colloids and separating them from the water. The water is then continuously oxidized with chlorine electrolytically to destroy the nitrogen compounds.

Abstract: Chlorine dioxide generation systems and methods are disclosed. One or more reactants, such as sodium hypochlorite, may be electrolytically generated on-site for delivery to a reaction column. Low concentration reactants may be used to generate chlorine dioxide as part of a mixed oxy-chloro product stream containing free available chlorine. In at least one embodiment, an optical analyzer may be positioned along a reactant feed line to measure a concentration of reactant supplied to a reaction column. A controller may adjust a flow rate of the reactant in response to information provided by the optical analyzer. The controller may also perform pH control within the system. In some embodiments, the chlorine dioxide generator may be incorporated in an all-liquid water disinfection system.

Abstract: A process for disinfecting a treatment fluid is disclosed, including the step of admixing an aqueous solution comprising two or more oxidants generated via electrolysis of a salt solution with a treatment fluid. The mixed oxidants may be generated on site, using a containerized system.

Abstract: This disclosure includes a device for producing sodium hypochlorite or hypochlorous acid for water treatment, the device including: a cylinder for storing salt in solid form, adapted for being fed directly via a pressurized water pipe, and including one or more tubes that form one or more electrolytic chambers; one or more electrolytic cells received in the electrolytic chambers; the tubes of the cylinders being perforated to allow the contacting of the electrolytic cells with the salt-saturated water while preventing the electrolytic cells from being short-circuited by the solid salt. This produces sodium hypochlorite or hypochlorous acid from salt-saturated water in a cylinder, connected directly to the pipe of the water to be treated without the latter being loaded with salt.

Abstract: A process for removing silicon compounds from aqueous NaCl brine includes, first, adjusting a weak brine to a pH value of less than 3 with hydrochloric acid. Iron(III) chloride or other trivalent iron ions are added to the acidified weak brine, the obtained weak brine is then continuously fed to a stirred dissolution vessel which contains undissolved salt in addition to brine. Fresh salt is charged batch-wise and intermittently to the dissolution vessel to produce strong brine. The obtained strong brine is fed to a stirred buffer vessel, the pH value in this buffer vessel being maintained at a level ranging from 5 to 8. A strong-brine flow is continuously withdrawn from the buffer vessel and filtered, and the filtrate containing the added iron and silicon is discharged. Also a system for carrying out this process is disclosed.

Abstract: Provided are methods and systems for continuously producing low concentrations of chlorine dioxide from dilute solutions of sodium chlorite. The low concentrations of chlorine dioxide produced allow for reduced exposure risk with direct application of the chlorine dioxide stream. The incorporation of a suitable chlorine dioxide detector permits continuous monitoring and control of chlorine dioxide production ensuring that the process stays within regulatory guidelines. Pretreatment of reaction water is preferred for achieving suitable conversion rates of the low concentrations of chlorite to chlorine dioxide.

Abstract: Embodiments of the present invention relate to a system and method for efficient removal of sulfur oxides (SOx), nitrogen oxides (NOx) and particulate matter (PM) contained in an exhaust gas generated from fuel combustion and efficient treatment of water containing microorganisms (e.g. ballast water).

Abstract: Methods and compositions for improving water quality by reducing chlorine demand, decreasing disinfection by-products and controlling deposits in water systems include adding low concentrations of supplemental oxidants, for example, RE-Ox® to the systems.

Abstract: Devices for receiving fluid such as water are described. Principally (although not necessarily exclusively) designed for use as chlorinators, the devices may divert water flowing in conduits into the devices for treatment and subsequent return to the flow stream. A device may connect to a pipe without tools and require only one hole to be formed in a pipe wall.

Abstract: A stabilized mixed oxidant solution may be produced by flowing a starting solution (e.g., salt brine, hypochlorous acid, and/or sodium hypochlorite) through a flow-through electrochemical module including first and second passages separated by an ion permeable membrane while electric power is applied between an anode and cathode in electrical communication with the first and second passages, respectively. An initially acidic anolyte solution received from the first (anode) passage is stabilized by elevating pH to yield a stabilized mixed oxidant solution. Methods of using the mixed oxidant solution are further provided.

Abstract: A chlorine based biofouling control subsystem is utilized to facilitate shipboard water management systems such as ballast water management that employ filters. The biofouling control system can serve as a subsystem to promote antifouling and reduce the filter clogging due to biofouling, which improves the efficiency and effectiveness of the ballast water treatment management system. An antifouling agent of the biofouling control system breaks up the dense colonies of marine organisms being filtered or treated by the main water management systems.

Abstract: Control systems for use of electrolysis solutions for automated recirculating or single-pass cleaning systems, such as clean-in-place (CIP) applications are disclosed. Control systems and methods for using automated chlorine output solutions for various cleaning applications are measurable over broad pH ranges. The control systems generate consistent and predictable electrolytic solutions and include a measurement system that identifies chlorine oxyanion concentration across broad ranges of pH, overcoming the sensitivity of chlorine monitors to pH and permitting use of the control systems to control cleaning systems.

Abstract: A composition for disinfection treatment of swimming pool water by electrochlorination, composition including an alkali chloride and a metasilicate and optionally a chlorine stabilizing agent, for stabilizing against ultraviolet radiation, the use of a composition of this type, and a method involving a composition of this type.

Abstract: A method for chlorination of drinking water, comprising providing a main water stream flowing through a main water pipe at a volumetric flow rate of not less than 30 m3/hour, splitting off a portion of said main water stream to form a side water stream flowing through a side pipe, passing said side water stream through a plurality of electrolysis modules at a linear velocity of not less than 0.35 m/s, wherein each electrolysis module comprises at least one anode and one cathode, electrolyzing the side water stream, and directing the resultant electrolyzed side water stream, which contains free chlorine, back to the main stream. An apparatus for carrying out the method is also disclosed.

Abstract: Methods and compositions for improving water quality by reducing chlorine demand, decreasing disinfection by-products and controlling deposits in drinking water distribution systems include adding low concentrations of supplemental oxidants, for example, RE-Ox® to the systems.

Abstract: Methods and compositions for improving water quality by reducing chlorine demand, decreasing disinfection by-products and controlling deposits in drinking water distribution systems include adding low concentrations of supplemental oxidants, for example, RE-Ox® to the systems.

Abstract: A water purification apparatus is provided. The apparatus includes a casing and an electrode array. The casing has an outer surface, a substantially annular inner surface, and a water flow passage chamber surrounded by the substantially annular inner surface, the water flow passage chamber providing an outer annulus region and an inner central region. The electrode array features at least four electrodes in adjacent relationship to one another and circumferentially spaced apart from another about the outer annulus region, each electrode having a respective first planar surface and a respective second planar surface facing and substantially parallel to the respective second planar surface and the respective first planar surface of the adjacent electrodes on opposite sides thereof.

Abstract: A chlorine treatment apparatus includes a housing with a cavity containing a chlorine generator for chlorinating a liquid such as water and at least three openings to the cavity. The chlorine generator may be an electrolytic cell. Some embodiments may include one or more plugs for closing the openings. The plugs may be keyed to operate with only certain of the openings. Yet other embodiments may include sensors for monitoring various aspects of the liquid such as temperature, salinity, flow rate, and chlorine concentration.

Abstract: A method for electrolytically generating a biocide having an electron deficient carrier fluid and chlorine dioxide, including providing a carrier fluid; providing a pair of electrodes interposed by a semi-permeable membrane within a vessel for creating a first passageway and a second passageway, an anode electrode of the pair of electrodes disposed in the first passageway, cathode electrode of the pair of electrodes disposed in the second passageway; flowing the carrier fluid through the vessel; applying an electric potential to the pair of electrodes to produce an oxidative acidic fluid, a reductive alkaline fluid, and anodic gases in the container; removing the fluids and gases from the vessel; mixing a portion of the anodic gases with the reductive alkaline fluid to produce a hypochlorite solution; and mixing a chlorite brine with the hypochlorite solution, followed by the introduction of additional oxidative acidic fluid to release the biocide.

Abstract: Methods and compositions for improving water quality by reducing chlorine demand, decreasing disinfection by-products and controlling deposits in drinking water distribution systems include adding low concentrations of supplemental oxidants, for example, RE-Ox® to the systems.

Abstract: The invention relate to the addition of mixture of non-halide salts to the water of above-ground swimming pools to allow sterilisation by in-situ electrochlorination with a modest sodium chloride content. A limitation of sodium chloride concentration in above-ground pools is necessary to prevent corrosion of the relevant steel supporting structure. The salt mixture additive contains sodium bisulphate and other salts of low toxicity.

Abstract: The invention is directed to an apparatus and methods of its use to generate chlorine dioxide. The apparatus comprises three cation exchange resin chambers in fluidic communication to convert chlorite salt into chlorine dioxide. Unlike previous converters, the invention utilizes an novel method of acidifying some of the chlorite to produce a more effective process. The invention can achieve a 100% theoretical yield which is s significant improvement over the 80% theoretical yield in previous attempts using non-acidifying chemistry. The method also avoids the need for expensive catalysts.

Abstract: An amperometric sensor includes a first electrode, a second electrode and a reference electrode. The sensor further includes a switch to selectably electrically connect the first electrode as a working electrode and to electrically connecting the second electrode as an auxiliary electrode during a first time interval. During a second time interval, the switch electrically connects the first electrode as the auxiliary electrode and electrically connects the second electrode as the working electrode. The switching of the two electrodes is repeated continuously as amperometric measurements are performed. Preferably, the sensor includes an ultrasonic transducer proximate the working electrode and the auxiliary electrode to clean the electrodes.

Abstract: A method of sanitizing water contained in a spa is provided which comprises installing a chlorine generating cell including a diamond electrode in a filter compartment of the spa, employing a resin-filled calcium remover bag to reduce the hardness of the water, adding salt to the water; and operating the chlorine generating cell to generate chlorine and other sanitizing agents for sanitizing the water.

Abstract: Disclosed herein is an improved electrolytic cell. The cell includes at least one pair of electrodes, an anode and a cathode. In general the anode includes at least one dimension, which is substantially greater than the cathode. In an exemplary embodiment, the length and the width of the anode are greater than the length and width of the cathode. In a first embodiment of a multi-cell chlorine generator, unequal dimension electrodes are stacked together. In a second embodiment of such a generator, the electrodes are of equal dimensions. In another exemplary embodiment of the improved electrolytic cell in accordance with this invention, the cathode forms a U-shaped member and the anode of at least one dimension being greater is located there between. Another embodiment of the chlorine generator includes at least two cells having the U-shaped cathode. In a first exemplary of embodiment of such a chlorine generator, the electrode are parallel to one another.

Abstract: The invention relates to an electrolysis method that uses iron particles and an aqueous solution containing sodium hypochlorite. The method is characterised in that said method uses direct current, the iron particles form the anode (46) and the sodium hypochlorite concentration of the aqueous solution is at least 1 g/L. The invention further relates to a method and to a plant for the pretreatment of raw water for producing water that can then be easily treated in order to produce drinkable water or a so-called technical water that cannot be consumed but that can be used for household, agricultural or industrial applications such as cleaning, washing, laundry, flushing, garden watering or irrigation.

Abstract: Methods and apparatus for efficient implementation and control of water treatment bypass loops combining ozone and chlorine injection are disclosed. Combined use of ozone and chlorine exploits high oxidation potential of ozone while retaining longer lived residual effectiveness of chlorine for high efficacy against contaminants, particularly biological and organic. Embodiments including automated monitoring and control of chlorine concentrations in presence of high oxidation potentials from ozone are disclosed, as is an inexpensive circuit for using a signal from a redox sensor for controlling output from an electrolysis cell. Also disclosed is a multipurpose enclosure that may be used, with different inserts, to implement an electrolysis cell, an ultraviolet ozone generator, an advanced oxidation unit, or an erosion feeder for adding dissolved salt to water for use in an electrolysis cell.

Abstract: An integrated process separates salts from salty waters and electrolyzes the salts to produce chlorine products such as chlorine, hypochlorites, chlorates and/or caustic soda.

Abstract: A method of sanitizing water contained in a spa is provided which comprises installing a chlorine generating cell including a diamond electrode in a filter compartment of the spa, employing a resin-filled calcium remover bag to reduce the hardness of the water, adding salt to the water; and operating the chlorine generating cell to generate chlorine and other sanitizing agents for sanitizing the water.

Abstract: The present invention relates to the technical filed of electrochemical elimination or reduction of microbial impurities of liquids. The liquids treated may inter alia include wastewater, industrial process water and water intended for human consumption.

Abstract: Suspect contaminated water is sanitized by treating it to produce a clean water stream and a waste water stream. A portion of the waste water stream is electrolyzed to provide a solution containing hypochlorite ions, a quantity of which is mixed with the suspect water in sufficient quantity to sanitize the suspect water and maintain sufficient residual chlorine to prevent re-contamination.

Abstract: A chlorine treatment apparatus includes a housing with a cavity containing a chlorine generator for chlorinating a liquid such as water and at least three openings to the cavity. The chlorine generator may be an electrolytic cell. Some embodiments may include one or more plugs for closing the openings. The plugs may be keyed to operate with only certain of the openings. Yet other embodiments may include sensors for monitoring various aspects of the liquid such as temperature, salinity, flow rate, and chlorine concentration.

Abstract: Provided are methods and systems for continuously producing low concentrations of chlorine dioxide from dilute solutions of sodium chlorite. The low concentrations of chlorine dioxide produced allow for reduced exposure risk with direct application of the chlorine dioxide stream. The incorporation of a suitable chlorine dioxide detector permits continuous monitoring and control of chlorine dioxide production ensuring that the process stays within regulatory guidelines. Pretreatment of reaction water is preferred for achieving suitable conversion rates of the low concentrations of chlorite to chlorine dioxide.

Abstract: A low energy water treatment system and method is provided. The system has at least one electrodialysis device that produces partially treated water and a brine byproduct, a softener, and at least one electrodeionization device. The partially treated water stream can be softened by the softener to reduce the likelihood of scale formation and to reduce energy consumption in the electrodeionization device, which produces water having target properties. At least a portion of the energy used by the electrodeionization device can be generated by concentration differences between the brine and seawater streams introduced into compartments thereof. The brine stream can also be used to regenerate the softener.

Abstract: A device (10) for producing a biocidal solution has a sealed and replaceable reservoir (16) with a low volume capacity which contains pre-prepared aqueous salt solution (18) with a pre-determined concentration, an electrolytic cell (20) for electrochemically treating the salt solution (18), a pump (28) for delivering a flow of accurately measured volumes of the salt solution (18) to the electrolytic cell (20), a restrictor valve (36) for controlling further the flow rate of the salt solution (18) to a cathode chamber (24) of the electrolytic cell (20), an electrical circuit (46) for connecting the pump (28) and the electrolytic cell (20) to a mains supply source (48) and including a power pack (50) for providing a substantially constant direct current of (7) to (12) amps to the electrolytic cell (20) and an operator-controlled switch (52) for completing the electrical circuit (46) when the switch (52) is operated to produce a biocidal solution (12) having a predetermined level of available free chlorine and p

Abstract: A process for removing target ion(s) from a for-treatment water containing the target ion(s) is provided. Also provided is a method for improving the efficiency of an electrochemical cell for target ion(s) destruction.

Abstract: The invention discloses a process to implement and maintain water bodies larger than 15,000 m3 for recreational use, such as lakes or artificial lagoons, with excellent color, transparency and cleanness properties at low cost, which comprises the following steps: a.—providing a structure able to contain a large water body larger than 15,000 m3; b.—feeding the structure of step (a) with inlet water having iron and manganese levels lower than 1.5 ppm and turbidity lower than 5 NTU; c.—measuring water pH, ideally it should be within a range lower than 7.8; d.—adding an oxidizing agent to the water contained in the structure of step (a), with which a 600 mV minimal ORP is controlled in water for a minimal period of 4 hours and in maximal cycles of 48 hours; e.—adding a flocculating agent in concentrations within 0.

Abstract: A device for removing mineral deposits from the electrode of a pool chlorinator cell, which has a housing with liquid inlet and outlet ports and in which the electrode is submerged, has: (a) a container having an opening, with this opening being affixed proximate an aperture that is placed in the housing, (b) an ultrasonic membrane which covers the aperture, (c) an ultrasonic transducer mounted in the container and coupled to the membrane in such a manner so as to cause specified, ultrasonic vibrations in the membrane and throughout the liquid contained in the housing, and (d) a frequency modulated power source that drives the transducer. In a preferred embodiment, this device is powered such that the energy projected to the electrodes is in range of 100 to 200 watts and the flux of energy supplied to the membrane is in the range of 4 to 25 watts per square inch of membrane surface area.

Abstract: A treatment method of organic compounds included in waste water, comprising the steps of: supplying waste water to an adsorber 2 filled with an adsorbent 3 therein for adsorbing the organic compounds in the waste water by the adsorbent 3 in the adsorber 2, supplying a current between an anode 9 and a cathode 8 in water including an electrolyte in an electrolyzer 6 for electrolyzing the water including an electrolyte, and supplying an electrolyte resulting from electrolysis in the electrolyzer 6 to the adsorbent 3 in the adsorber 2 for contacting the electrolyte with the adsorbent 3, so that the organic compounds adsorbed by the adsorbent 3 are desorbed or decomposed.