Phosphorus Containing Patents (Class 210/906)

Cross-Reference Art Collections

Phosphate slimes (Class 210/907)
  • Patent number: 5447637
    Abstract: Phossy water is a toxic liquid waste that is generated when elemental phosphorus is manufactured, stored, or processed into phosphorus-containing products. Elemental phosphorus may be present as a solution, as colloidal particles, and as settleable particles.The primary objects of the invention are as follows:1. To provide a process for the disposal of phossy water stored at the TVA National Fertilizer and Environmental Research Center.2. To provide a process for the recovery of phossy water that will be generated when hazardous wastes stored at the TVA National Fertilizer and Environmental Research Center are recycled.Phossy water can be disposed of by using it to quench and granulate molten slag at electric furnaces used to manufacture elemental phosphorus. The elemental phosphorus content of the phossy water is limited to about 2 parts per million.
    Type: Grant
    Filed: September 21, 1994
    Date of Patent: September 5, 1995
    Inventor: James C. Barber
  • Patent number: 5430226
    Abstract: A method for regenerating a spent solvent generated from a nuclear fuel cycle and containing a higher hydrocarbon (n-dodecane), tributyl phosphate and degradation products thereof. The spent solvent is brought into contact with a methanol/water mixture having a water concentration of 100 to 750 g/l and the resulting mixture is subjected to phase separation to form a non-methanol/water phase and a methanol/water phase. The degradation products such as DBP in the spent solvent selectively migrate into the methanol/water phase and n-dodecane and TBP can be recovered as the non-methanol/water phase.
    Type: Grant
    Filed: June 30, 1992
    Date of Patent: July 4, 1995
    Assignee: Doryokuro Kakunenryo Kaithatsu Jigyodan
    Inventors: Jin Ohuchi, Isao Kondoh, Takashi Okada
  • Patent number: 5415778
    Abstract: A method and related product for purification of waste water, especially of water polluted with phosphorus, nitrogen, heavy metals, and chlorinated solvents. The purification process consists of:a) adding two liquid mixtures in sequence to the waste water;b) letting the pollutants react with the two mixtures;c) subsequently removing the sludge that forms.One of the two liquid mixtures in question is a liquid mixture of two acids that may be extracted from lignite, leonardite and fossils of vegetal origin like peat.
    Type: Grant
    Filed: February 28, 1994
    Date of Patent: May 16, 1995
    Assignee: HydroGeo North America L.L.C.
    Inventors: Roberto Zanin, Gaetano Boetti
  • Patent number: 5407572
    Abstract: A tertiary treatment unit is provided that has a first filtration unit operatively connected to an influent for filtering solids therefrom to form an effluent, a second filtration unit operatively connected to the first filtration unit to receive the effluent and to filter finer solids and bacteria and viruses from the effluent, a supply tank operatively connected to the effluent to provide chemicals that are mixed into the effluent, and a reactor that receives the effluent and removes nitrogen and some phosphorous therefrom to form a treated effluent. The treatment unit further has a first adsorption unit that receives the treated effluent and adsorbs additional nitrogen, BOD, TSS and certain chemicals from the treated effluent, and a second adsorption unit that receives the partially adsorbed treated effluent from the first adsorption unit and adsorbs additional phosphorous from the treated effluent to form the final effluent.
    Type: Grant
    Filed: January 11, 1993
    Date of Patent: April 18, 1995
    Assignee: Step Three, Inc.
    Inventors: John P. McGuire, Lirong Li
  • Patent number: 5403488
    Abstract: The present invention provides a process for the regulation of the activa sludge step of a clarification plant by control of the decomposition efficiency of the activated sludge, wherein an activated sludge sample is incubated under precisely defined conditions, which are optimised with regard to the pH value, the temperature and the salt concentration, with the substrate or substrates of interest above the saturation range and, in the initial phase, the decrease of the substrate or the increase of a decomposition product is determined kinetically as a measure of the decomposition efficiency for this substrate and the measured value determined is used as regulating value for the control of the clarification plant.
    Type: Grant
    Filed: January 24, 1994
    Date of Patent: April 4, 1995
    Assignee: Orpegen Medizinisch-Molekular-Biologische Forschungsgesellschaft mbH
    Inventors: Andreas Volsch, Werner Nader
  • Patent number: 5397473
    Abstract: A biological treatment method for water containing nitrogen and phosphorus is provided. Treatment is carried out by contacting the water with one or more substituted or unsubstituted hydrocarbon compounds each having from 1 to 6 carbon atoms in the presence of methanotrophs and/or aerobic heterotrophic bacteria under process conditions effective to reduce soluble nitrogen and soluble phosphorus levels in the water each to below about 1 mg/L.
    Type: Grant
    Filed: August 27, 1993
    Date of Patent: March 14, 1995
    Assignee: Cornell Research Foundation, Inc.
    Inventor: William J. Jewell
  • Patent number: 5393427
    Abstract: A process and installation for the removal of organic matter, phosphate ions and nitrogenous compounds from sewage wastewater. The installation comprises a raw sewage feed line 12 shown feeding into a primary separation basin 14. The primary separation basin 14 has an overflow flow line 16, discharging separated effluent to an attached growth fermentation vessel or fermenter 18. The fermenter 18 is filled with solid supports 20 with sufficient voids therebetween to allow the effluent to pass through the supports 20 and to allow for the growth of fermenting bacteria (not shown) on the supports 20. The supports 20 are shown diagrammatically in the drawings, and can be in the form of rotating discs, hanging or suspended ropes which move as the liquid is passed through the system, a fluidized bed in which the solids are kept in suspension by upward movement of the liquid, rings, slats or plates. The liquid effluent then passes out of the fermenter 18, through flow line 26, for further processing.
    Type: Grant
    Filed: April 8, 1993
    Date of Patent: February 28, 1995
    Inventor: James L. Barnard
  • Patent number: 5380438
    Abstract: Wastewater is treated by promoting the presence and growth of BPR organisms, which have the ability to absorb and retain an amount of phosphorus in excess of the amount required by the BPR organisms for metabolism and cell growth. In the process, a mixture of influent wastewater (10) and activated sludge (14) containing BPR organisms is first subjected to a period of incubation in an anoxic zone (20) followed by a period of incubation in an anaerobic zone (30). Volatile fatty acids (VFA's) (16) are added in the anaerobic zone (30). The mixture is then subjected to an aerobic zone (41). The wastewater mixture (46) leaving the aerobic zone is clarified in a clarifier (50), causing activated sludge to settle. The activated sludge contains BPR organisms which are engorged with phosphorus absorbed from the wastewater. The clarified wastewater (52) becomes effluent from the system. The activated sludge (54) is removed from the clarifier (50).
    Type: Grant
    Filed: August 17, 1993
    Date of Patent: January 10, 1995
    Assignee: City of Atlanta
    Inventor: Philip W. Nungesser
  • Patent number: 5376275
    Abstract: An activated sludge treatment process is disclosed wherein a sewage sludge component is fermented for a period of at least 15 days to form soluble carbonaceous substrates, the fermented sludge component is contacted with influent sewage to form a conditioned sewage, and the conditioned sewage is supplied to the activated sludge plant.
    Type: Grant
    Filed: January 24, 1992
    Date of Patent: December 27, 1994
    Assignee: Commonwealth Scientific and Industrial Research Organisation
    Inventor: William G. Raper
  • Patent number: 5372720
    Abstract: A method of reducing nitrogen, phosphor, and excessive biological oxygen demand (BOD) in wastewater supplied to and passing through a granular filter bed activated with bacteria includes in the flow direction of the wastewater through the bed simultaneously precipitation of phosphorous, denitrification and reduction of the excessive BOD in a single process step. The reduction of excess BOD is produced by blowing in an oxygen-containing gas, preferably air. Immediately before the wastewater enters the filter bed a precipitation/flocculation agent may be added for precipitation of phosphor.
    Type: Grant
    Filed: March 8, 1993
    Date of Patent: December 13, 1994
    Assignee: Nordic Water Products AB
    Inventor: Kurt A. Jonsson
  • Patent number: 5368741
    Abstract: Aqueous phosphorus wastes from the electric furnace production of phosphors and containing heavy metal bearing particulates are treated with lime whereby the phosphorus is converted into useful phosphorus compounds and the heavy metals rendered sufficiently non-leachable to permit their release into the environment. The treatment is conducted above about 60.degree. C. at a pH of between about 11.0 to 12.5.
    Type: Grant
    Filed: October 12, 1993
    Date of Patent: November 29, 1994
    Assignee: FMC Corporation
    Inventors: Theodore F. Munday, Jay R. Brummer, Paul J. Beck
  • Patent number: 5344562
    Abstract: A modified activated sludge system is provided wherein wastewater is treated to reduce BOD, nitrogen, and/or phosphorus. The disclosed system features a zone sequence nitrification/denitrification, with nitrification induced by recycling mixed liquor that contains a significant concentration of oxygen and nitrifying bacteria. With a further modification, the main treatment zones of the treatment system are split into two or more parallel treatment trains that are either high-loaded with BOD or low-loaded with BOD. The high-loaded sections facilitate the sludge generation and BOD removal, while the low-loaded sections are operated for nitrification and to enhance the growth of nitrifying bacteria. The parallel treatment zones combine and pass into a final denitrification zone. Phosphorus removal is achieved with phosphate release in a reverse flow regime to the main treatment, and phosphate retention primarily in aerated treatment zones in the main stream of the process.
    Type: Grant
    Filed: March 3, 1993
    Date of Patent: September 6, 1994
    Inventors: Gunter Lorenz, Jurgen Lorenz
  • Patent number: 5342522
    Abstract: The invention relates to a method for the treatment of (raw) sewage in a package plant consisting of three bioreactors in series. The treatment is being carried out using three types of biomass.In a first step phosphate is removed by biological means and, at the same time, the chemical and biological oxygen demand is lowered in a highly loaded active sludge system, in a second step a nitrification is carried out, ammonium being converted to nitrate, and in a third step a denitrification is carried out using a carbon source. In the denitrification step acidified surplus sludge from the P-removing step can also be used instead of an external carbon source. The nitrifying and denitrifying bioreactors are both fixed film processes. The thickness of the biofilm on the support material in the nitrifying bioreactor can be influenced by adjusting the aeration system or by adjusting the hydraulic loading.
    Type: Grant
    Filed: November 16, 1992
    Date of Patent: August 30, 1994
    Assignee: Tauw Milieu B.V.
    Inventors: Eric H. Marsman, Garardus J. F. M. Vlekke, Leonardus G. C. M. Urlings, Berend A. H. Reitsma
  • Patent number: 5304308
    Abstract: In an intermittent aeration activated sludge process in which aeration and agitation is repeated alternately, a first aeration tank and a second aeration tank are connected to each other and an ORP meter is applied to each tank. In the first aeration tank, the sum of an aeration period and a denitrification period of an agitation step is controlled to a predetermined period T.sub.gs based on a time when a bending point appeared on an ORP curve in a previous cycle. In the second aeration tank, the sum of an aeration period and an agitation period is controlled to a predetermined period T.sub.ds longer than T.sub.gs based on a time when an ORP measured value reached a predetermined value in a previous cycle. Operations of the first and second aeration tanks are simultaneously transferred from the agitation to the aeration based on detection of the predetermined ORP value. As a result, a necessary anaerobic condition period is secured in the first aeration tank.
    Type: Grant
    Filed: April 27, 1993
    Date of Patent: April 19, 1994
    Assignees: Fuji Electric Co., Ltd., Unitika Ltd.
    Inventors: Kazushi Tsumura, Yasuji Yamamoto, Kosei Sasaki, Shigeru Hatsumata
  • Patent number: 5296147
    Abstract: The invention relates to a method for processing manure, fermented liquid manure being subjected to nitrification in a first step and to denitrification in a subsequent step, an aerated reactor which contains active sludge rich in nitrifying bacteria being used in the nitrification step and acid-neutralizing chemicals being added to said reactor if necessary and a continuously fed upflow sludge bed (USB) reactor which contains a very compact biomass which is capable of converting nitrate to nitrogen gas and to which an organic substrate is added being used in the denitrification step, the loading of the reactor being controlled to obtain an optimum nitrification and denitrification and this is obtained on the basis of one or more of the following data:the incoming nitrogen load;the information from the WAZU respiration meter;the pH in the nitrification reactor, the criterion for which is that the pH is in the range limited by 6 and 8.
    Type: Grant
    Filed: June 1, 1993
    Date of Patent: March 22, 1994
    Assignee: Ecotechniek B.V.
    Inventors: Iman W. Koster, Abraham Klapwijk
  • Patent number: 5296151
    Abstract: A process is provided for the precipitation of phosphates from phosphate-comprising waters which utilizes iron hydroxide of the formula Fe.sub.2 O.sub.3.nH.sub.2 O wherein n=0.5-3.0. The iron hydroxide is prepared from natural or technical muds comprising iron in a process which involves dissolving with mineral acid and precipitation with a base. Other metal hydroxides are used together with the iron hydroxide.
    Type: Grant
    Filed: September 2, 1992
    Date of Patent: March 22, 1994
    Assignee: Industrie Automation Sondertechnik GmbH & Co.
    Inventors: German Muller, Siegfried Riethmayer
  • Patent number: 5294348
    Abstract: A method for removing ammonia, or ammonia and phosphates from industrial agricultural or household effluents by causing precipitation as magnesium ammonium phosphate by means of a liquid reagent containing magnesium and phosphate ions and an acid. The effluents have more than 1 gle of ammoniacal nitrogen and the pH is adjusted to between 9 and 11 after addition of the liquid reagent.
    Type: Grant
    Filed: July 22, 1992
    Date of Patent: March 15, 1994
    Assignee: Societe Nationale Elf Aquitaine
    Inventors: Patrick Horny, Alain Ladousse
  • Patent number: 5290451
    Abstract: The invention relates to a method for processing manure, liquid manure and/or Kjeldahl-N containing waste water being subjected to a nitrification in an aerated reactor containing active sludge and to a denitrification in a high rate recirculation denitrification reactor (13) containing a very compact biomass capable of converting nitrate to nitrogen gas. The loading of the nitrification reactor (9) being controlled to obtain an optimal nitrification and denitrification, the effluent from the nitrification reactor (9) partially being passed to the denitrification reactor (13), adding a source of carbon to the effluent to be passed to the recirculation denitrification reactor (13) and passing another portion of the effluent stream from the nitrification reactor (9) to a separation step (19) to separate a sludge, the effluent from separation step (19) being passed to a discharge line denitrification reactor (37) under the addition of a carbon source if desired.
    Type: Grant
    Filed: April 3, 1992
    Date of Patent: March 1, 1994
    Assignee: Ecotechniek B.V.
    Inventors: Iman W. Koster, Abraham Klapwijk
  • Patent number: 5288405
    Abstract: A wastewater treatment system incorporates three interconnected, but separately controlled, processes to enhance biological phosphorus removal. The first process is a mainstream biological treatment process utilizing aerobic and solids separation zones and the provision of return activated sludge. The next is a first sidestream process for anoxic/anaerobic "selection" of desirable BPR organisms. Finally, a second sidestream process serves to ferment organic material in some of the return activated sludge to produce food utilized in the first sidestream selection process. The system permits the three processes to be separated from each other by creating two sidestreams, allowing all three processes to be controlled separately and optimized in satisfying their own specific goals.
    Type: Grant
    Filed: January 27, 1993
    Date of Patent: February 22, 1994
    Assignee: Piedmont Olsen Hensley, Inc.
    Inventor: James C. Lamb, III
  • Patent number: 5275722
    Abstract: An oxidation ditch wastewater treatment and denitrification system is provided, comprising an oxidation ditch, including a central channel, having an inlet end, an outlet end, a bottom and two sidewalls; an aeration channel, having an inlet end fluidly connected to the outlet end of the central channel, an outlet end fluidly connected to the inlet end of the central channel, a bottom and two sidewalls; and a denitrification channel, having an inlet end fluidly connected to the outlet end of the central channel, an outlet end fluidly connected to the inlet end of the central channel, a bottom and two sidewalls; an aerator, positioned in the aeration channel; and at least one circulation device, positioned in the oxidation ditch and adapted to circulate wastewater from the inlet end of the central channel to the outlet end of the central channel, from the inlet end of the aeration channel to the outlet end of the aeration channel, and from the inlet end of the denitrification channel to the outlet end of the de
    Type: Grant
    Filed: February 25, 1992
    Date of Patent: January 4, 1994
    Inventor: Harold J. Beard
  • Patent number: 5273661
    Abstract: A method for treating waste water such as that from an industrial processing facility comprising the separation of the waste water into a dilute waste stream and a concentrated waste stream. The concentrated waste stream is treated chemically to enhance precipitation and then allowed to separate into a sludge and a supernate. The supernate is skimmed or filtered from the sludge and blended with the dilute waste stream to form a second dilute waste stream. The sludge remaining is mixed with cementitious material, rinsed to dissolve soluble components, then pressed to remove excess water and dissolved solids before being allowed to cure. The dilute waste stream is also chemically treated to decompose carbonate complexes and metal ions and then mixed with cationic polymer to cause the precipitated solids to flocculate. Filtration of the flocculant removes sufficient solids to allow the waste water to be discharged to the surface of a stream.
    Type: Grant
    Filed: February 21, 1992
    Date of Patent: December 28, 1993
    Inventors: John B. Pickett, Hollis L. Martin, Christine A. Langton, Willie W. Harley
  • Patent number: 5271848
    Abstract: Bauxite mineral is used directly, to remove phosphates from water, in a high efficiency, highly economical system. The process of the invention involves the step of contacting the waste water stream with Bauxite for a time sufficient to lower the phosphate concentration to a predetermined lower level. The predetermined lower level is typically less than about 2 mg/l of water, and can be to a concentration of less than 1 mg/l. The Bauxite has an average particle size of greater than about 50 mesh. Advantageously, the particle size is at least about one quarter of an inch.The Bauxite which is used can be washed and graded to produce Bauxite having a particle size on the order of about one quarter of an inch. The Bauxite can be ground to an average particle size of at least about 50 mesh to produce a material having a higher reaction rate.
    Type: Grant
    Filed: March 10, 1992
    Date of Patent: December 21, 1993
    Inventors: Rodney W. Smith, William M. Markham, Walter W. Robinson
  • Patent number: 5266200
    Abstract: A complete mix activated sludge basin is operated as a Sequence Continuous Reactor by cyclically aerating the mixed liquor to form an aerobic cycle at selected high dissolved oxygen levels, during which nitrification takes place, and cyclically mixing the liquor without aerating to form anoxic cycles at selected low dissolved oxygen levels, during which denitrification takes place. Field adjustments can be made by the operator in the dissolved oxygen levels and in the duration of the aerobic and anoxic cycles, whereby ammonia removal, nitrification, and denitrification can continue to be done efficiently during both summer and winter temperature conditions, during conditions varying from warm to cold inlet wastewater temperatures, during extreme variations in food supply, and during pronounced variations in biomass concentration and activity.
    Type: Grant
    Filed: April 17, 1991
    Date of Patent: November 30, 1993
    Inventor: John H. Reid
  • Patent number: 5262064
    Abstract: A method of dewatering mineral-containing phosphatic clay sludge comprising adding to the sludge (a) an aqueous solution or emulsion of acrylamide polymer flocculating agent and (b) a microfiber additive. By using this method, such mineral-containing sludges can be quickly dewatered into a cake comprising 25-35% solids which can then be further processed to a 60% solids-containing material. The method is particularly suitable for use in methods for treating, recovering, rehabilitating and recycling residue of mining operations. With modification, the method is also suitable for dewatering organic sludges.
    Type: Grant
    Filed: September 26, 1991
    Date of Patent: November 16, 1993
    Assignee: Florida Institute of Phosphate Research
    Inventor: Hassan E. El-Shall
  • Patent number: 5256309
    Abstract: The present invention relates to a method and an apparatus, in which the quality of a large amount of water and/or the quantity of dissolved oxygen in said water is improved and which are characterized in that water, in which slaked lime is dissolved in advance, and/or water of high oxygen content, which is generated in advance, is supplied into water pumped by an intermittent pneumatic water pumping unit so that the water having the slaked lime dissolved therein and/or the water of high oxygen content is diffused in the large amount of water.
    Type: Grant
    Filed: November 25, 1991
    Date of Patent: October 26, 1993
    Assignee: Kaiyo Kogyo Kabushiki Kaisha
    Inventor: Masahiko Makino
  • Patent number: 5252214
    Abstract: A modified activated sludge system is provided wherein wastewater is treated to reduce BOD, nitrogen, and/or phosphorus. The disclosed system features a zone sequence nitrification/denitrification, with nitrification induced by recycling mixed liquor that contains a significant concentration of oxygen and nitrifying bacteria. With a further modification, the main treatment zones of the treatment system are split into two or more parallel treatment trains that are either high-loaded with BOD or low-loaded with BOD. The high-loaded sections facilitate the sludge generation and BOD removal, while the low-loaded sections are operated for nitrification and to enhance the growth of nitrifying bacteria. The parallel treatment zones combine and pass into a final denitrification zone. Phosphorus removal is achieved with phosphate release in a reverse flow regime to the main treatment, and phosphate retention primarily in aerated treatment zones in the main stream of the process.
    Type: Grant
    Filed: January 31, 1992
    Date of Patent: October 12, 1993
    Inventors: Gunter Lorenz, Jurgen Lorenz
  • Patent number: 5248422
    Abstract: A BOD-containing wastewater also containing unacceptable levels of phosphorous, nitrogen or mixtures thereof is introduced into and mixed with recycled activated sludge in a first aeration zone including at least one partially submerged rotatable biological contactor under conditions whereby the overall dissolved oxygen content of the mixed liquor in the first aeration zone is about 0.7 to about 1.5 mg/l so as to cause microorganisms capable of storing phosphates under oxidizing conditions to release soluble phosphates into the mixed liquor, the mixed liquor from the first aeration zone is transferred to a subsequent aeration zone and aerated under conditions whereby the overall dissolved oxygen content of the mixed liquor is greater than about 1.
    Type: Grant
    Filed: May 28, 1992
    Date of Patent: September 28, 1993
    Inventor: Kenneth E. Neu
  • Patent number: 5242592
    Abstract: Activated sludge process for biological waste water treatment comprises controlling the supply of oxygen to a single tank reactor in response to the phosphate concentration in the anaerobic phase independent of turbidity. The oxic phase is initiated if the maximum turbidity set point is exceeded in the usual manner. However, if the phosphate concentration exceeds its maximum set point before the turbidity reaches a maximum, then the oxic phase is initiated to end phosphate release. Acetic acid can be added to increase phosphate elimination at the end of the anaerobic phase, prior to switching on the supply of oxygen.
    Type: Grant
    Filed: October 13, 1992
    Date of Patent: September 7, 1993
    Assignee: Schreiber Corporation, Inc.
    Inventor: Wilhelm Ballnus
  • Patent number: 5238579
    Abstract: A method is proposed for performing precipitation reactions which yields precipitate particles in the form of flakes. The precipitate particles are coarse, having cross-measurements in the order of 10 to 400 microns. According to this method, a suitable precipitant is one which will react with the ionic species to be precipitated and which is sparingly soluble, such as lime, and therefore capable of forming a slurry as opposed to a solution. Prior to adding the precipitant to the solution containing ions to be precipitated, the precipitant is slurried, normally in aqueous medium, and flocculated such that discrete floccules having diameters in the order of 1 to 6 mm are formed. Upon addition of the flocculated precipitant to the solution containing ions to be precipitated, a layer of precipitate forms on the surface of the precipitant floccules, encapsulating or partially encapsulating the floccule.
    Type: Grant
    Filed: November 30, 1992
    Date of Patent: August 24, 1993
    Assignees: Falconbridge Limited, Paul Shibley and Associates, Ltd.
    Inventor: Paul W. M. Shibley
  • Patent number: 5227056
    Abstract: The present invention relates to a method and apparatus, in which the quality of a large amount of water and/or the quantity of dissolved oxygen in the water is improved. Water in which slaked lime is dissolved in advance and/or water of a high oxygen content which is generated in advance is supplied into water pumped by an intermittent pneumatic water pumping unit so that the water having the slaked lime dissolved therein and/or the water of high oxygen content is diffused in the large amount of water. The present invention also relates to a method and apparatus, in which the quality of a large amount of water and/or the quantity of dissolved oxygen in the large amount of water is improved by water with slaked lime dissolved therein and/or water of high oxygen content being conducted to the bottom of a lake or the like. An intermittent pneumatic water pumping unit is operated in the lake or the like so that the large amount of water is caused to flow up and down and be agitated.
    Type: Grant
    Filed: October 24, 1991
    Date of Patent: July 13, 1993
    Assignee: Kaiyo Kogyo Kabushiki Kaisha
    Inventor: Masahiko Makino
  • Patent number: 5223130
    Abstract: The device comprises a back module 2, consisting of a housing 4 provided with an opening 10 and with a window 11, and of a front element 3, consisting of a container 20 having a tub shape and turned upside-down, designed to be partially inserted into the window 11 of the housing 4, with the lower edge of the latter below the water level of a water basin and with the opening 10 totally sunk.A blowing unit 12 feeds air into a diffusing element 33, inside the housing 4, so that the air released in water, when going up again to the surface, is collected into said container together with the resulting froth which bears, in suspension, the products of oxidizing reactions of phosphorus compounds contained in water. The froth is then collected by collecting means 35.
    Type: Grant
    Filed: December 11, 1991
    Date of Patent: June 29, 1993
    Assignee: Farm Fish, S.r.l.
    Inventor: Angiolin Valfrido
  • Patent number: 5213681
    Abstract: The present invention relates to a system and method for biologically removing nitrogen from wastewater. Both the system and method entails forming a mixed liquor and transferring the mixed liquor to a series of nitrogen removal stages. Each nitrogen removal stage includes both anoxic and aerobic treatment zones. Mixed liquor is recycled back and forth between the anoxic and aerobic treatment zone of each stage. Because of this basic flow scheme, the process gives rise to a high reactor rate and highly efficient nitrogen removal process.
    Type: Grant
    Filed: September 9, 1991
    Date of Patent: May 25, 1993
    Assignee: T. Kruger, Inc.
    Inventor: Peter Kos
  • Patent number: 5182021
    Abstract: A method is disclosed for attaining concurrent biological nitrification and dentrification in an aerobic zone of an activated sludge treatment plant. The method comprises aerating a mixed liquor in an aerobic stage of a secondary treatment zone to attain nitrification of ammonia values to NO.sub.x, transferring the mixed liquor to a settling zone where activated sludge is allowed to settle from the mixed liquor, transferring at least a portion of the sludge to an anaerobic sludge holding zone where it is held for a prolonged period, and returning the aged sludge from the sludge holding zone to the secondary treatment zone for mixing with influent wastewater. By holding the sludge in the sludge holding zone for a prolonged period, a culture of organisms is developed which exhibits an oxygen respiration block in the presence of NO.sub.x. When returned to the aerobic zone where nitrification is achieved, these organisms utilize the NO.sub.
    Type: Grant
    Filed: December 16, 1991
    Date of Patent: January 26, 1993
    Assignee: Lehigh University
    Inventor: Marshall L. Spector
  • Patent number: 5176834
    Abstract: A method for reducing the concentration of target co-ions in a liquid feed mixture comprising target co-ions and counter-ions by adding a colloid such as a polyelectrolyte or surfactant comprising a colloidal ion and colloidal counter-ions to the feed mixture wherein the colloidal ion has the same type of charge as the target co-ion. The feed mixture containing the colloid is filtered through an ultrafiltration membrane having pores small enough to block the passage of the colloidal ion.
    Type: Grant
    Filed: May 20, 1991
    Date of Patent: January 5, 1993
    Assignee: Board of Regents of the University of Oklahoma
    Inventors: Sherril D. Christian, Edwin E. Tucker, John F. Scamehorn
  • Patent number: 5173187
    Abstract: The present invention provides a process for the control of a biological rification stage of the aerobic activated sludge type, wherein at least one of the micro-organisms most frequently present in the activated sludge is continuously monitored with regard to the amount thereof in that, in a representative sample from the activated sludge and/or from the inlet of the activated sludge tank, this micro-organism is bound to fluorescence-labelled antibodies directed against the chosen micro-organism or this micro-organism is allowed to react with a fluorogenic substrate by means of a special metabolic ability, the amount of the thus fluorescence-labelled micro-organism is determined by flow cytometry and, at the same time, the total amount of the micro-organism present is determined by scattered light measurement and/or coloration of the DNA and, depending upon the measurement values thus obtained, the amount of at least one particular micro-organism and/or the growth conditions for this micro-organism is regula
    Type: Grant
    Filed: March 23, 1989
    Date of Patent: December 22, 1992
    Assignee: Orpegen Medizinisch-Molekularbiologische Forschungsgesellschaft m.b.H.
    Inventors: Werner Nader, Carl T. Nebe, Gerhard Nebe, Christian Birr
  • Patent number: 5171452
    Abstract: Phosphoric acid wastewater treatment to substantially eliminate discharge of contaminants to the environment. Acid pond water from conventional wet-phosphoric acid manufacturing is replaced by gypsum pond water having a pH closely matching that of the surroundings. Essentially all fluorides are insolubilized and substantially all phosphoric acid is recovered, minimizing loss to the environment.
    Type: Grant
    Filed: March 14, 1991
    Date of Patent: December 15, 1992
    Inventors: Gordon F. Palm, R. George Hartig
  • Patent number: 5154830
    Abstract: Phosphates which are dissolved or contained in suspension are substantially completely removed from a low-solids waste water which has been clarified. Precipitating and flocculating agents for transforming the dissolved phosphated to an undissolved form are added to the low-solids wate water and precipitation products and suspended matter are removed by microsieving through mesh openings in the range of about 10 to 150 .mu.m. Microsieving is preferably effected in two stages including a preliminary sieving through mesh openings from 60 to 150 .mu.m and a fine sieving through mesh openings from 10 to 80 .mu.m.
    Type: Grant
    Filed: April 25, 1991
    Date of Patent: October 13, 1992
    Assignee: Passavant-Werke AG
    Inventors: Ulrich Paul, Willi Schaper, Carl-Adolf Eschenbach, Karl Seel, Hubert Coenen
  • Patent number: 5141646
    Abstract: A process for the treatment of organic waste is described which comprises the steps of:a) feeding input waste in an input line to an ATAD reactor where the waste is subjected to biological digestion;b) settling out a portion of a biomass formed in the digestion unit;c) hydrolyzing the separated portion in a hydrolysis vessel;d) returning hydrolyzed effluent to the input line upstream of the ATAD reactor; ande) periodically removing clear decant from the reactor. Variations of this process include removal of nutrients from the clear decant; feeding solid organic waste by a grinder upstream of the mixer; feeding the mixed material initially to an AAD vessel from which methane gas is removed, and then to the ATAD reactor, with or without nutrient removal.
    Type: Grant
    Filed: March 12, 1991
    Date of Patent: August 25, 1992
    Assignee: Environmental Resources Management, Inc.
    Inventor: Alan F. Rozich
  • Patent number: 5112499
    Abstract: A two-stage process for treating acidic gypsum pond water for reuse or for discharge is disclosed. The first stage blends raw acidic pond water with recycled lime-treated slurry from the second stage of the process. The resulting elevation in pH causes CaF.sub.2 and SiO.sub.2 to precipitate and the precipitated material is discarded onto the gypsum storage area. The supernatant water can be used in the wet grinding mill and/or further treated in a second stage with lime to produce treated water which meets government environment standards for discharge. The slurry of calcium phosphate formed in the second (liming) stage is recycled to the first stage.
    Type: Grant
    Filed: May 22, 1991
    Date of Patent: May 12, 1992
    Assignee: Freeport-McMoran Resource Partners, Limited Partnership
    Inventors: Michael A. Murray, Charles W. Weston
  • Patent number: 5102554
    Abstract: In a method of recovering phosphor for picture tubes from phosphor sludge, the phosphor sludge is first subjected to a steam treatment, thereby causing substances adhering to the surface of the phosphor particles to pass into solution. The phosphor is then washed several times. Following wet screening, one then obtains a phosphor suspension that can be further processed just like virgin phosphor. The said method does not comprise any drying or calcining processes. The steam treatment causes the phosphor particles in the phosphor sludge to lose their tendency to cluster and form lumps, so that one obtains a high-yield suspension of very fine phosphor particles that can be further processed without any additional grinding or homogenization steps.
    Type: Grant
    Filed: January 11, 1991
    Date of Patent: April 7, 1992
    Assignee: Nokia Unterhaltungselektronik
    Inventor: Peter Groner
  • Patent number: 5098567
    Abstract: A waste water treatment process wherein an iron contactor or iron contact are immersed in a treatment tank, into which waste water flows. In the treatment tank sulfate reducing bacteria are made to coexist with activated sludge or biofilters, wherein a velocity of flow of agitating stream on the outer surfaces of said iron contactor or contactors is set at 10 to 20 cm/sec, under an aerobic treatment. Iron ions are made to elute from said iron contactor or contactors by utilizing electrochemical iron corrosion through the agency of oxygen concentration cells on the outer surfaces of said iron contactor or contactors on conditions that dissolved oxygen concentration in the treatment tank is 1 to 3.2 mg/l and the oxidation-reduction potential is -200 to -400 millivolts (mV). Under an anaerobic treatment, iron ions are made to elute by utilziing microorganism-corrosion on the outer surfaces of said iron contactor or contactors on condition that dissolved oxygen concentration in the treatment tank is 0 mg/l.
    Type: Grant
    Filed: December 12, 1990
    Date of Patent: March 24, 1992
    Assignee: Nishihara Environmental Sanitation Research Corporation Limited
    Inventor: Takeshi Nishiguchi
  • Patent number: 5098572
    Abstract: A method of treating water with activated sludge, comprising a process for depolluting said water including a stage in which carbon pollution is oxidized, a nitrification stage which may optionally be associated with a denitrification state and/or a dephosphating stage, and a sludge ageing process. The method further includes a sludge concentration stage, said stage being performed upstream from the sludge ageing stage, said concentration being performed by phase separation using compressed air, e.g. in a flotation tank (3), and the concentrated sludge being recycled via the sludge ageing stage.
    Type: Grant
    Filed: September 21, 1990
    Date of Patent: March 24, 1992
    Assignee: Lyonnaise des Eaux
    Inventors: Gerard Faup, Jean-Marc Audic
  • Patent number: 5098579
    Abstract: Disclosed is a method for treating in a continuous manner an aqueous solution containing ions of a given type in order to remove these ions from the solution. According to this method, the aqueous solution containing the ions to be removed is first neutralized if it is acidic. Then, it is contacted with a metal salt which is sparingly soluble in water and has a very strong affinity to react with the ions to be removed to form therewith another salt which is insoluble in water, for a period of time sufficient to allow this other salt to be formed and precipitate. This method is very efficient and can be used, by way of example, for removing chromium ions from an industrial waste water, using barium carbonate as sparingly soluble salt.
    Type: Grant
    Filed: April 23, 1990
    Date of Patent: March 24, 1992
    Assignee: Hydro Quebec
    Inventors: Charles H. Leigh, Michel Laurin
  • Patent number: 5076928
    Abstract: A method for biologically removing approximately seventy-five percent of the phosphate contaminants from wastewater comprises controlling the aerator to a single activated sludge tank according to the turbidity of the water and the effluent requirements. Oxic, anoxic, and anaerobic reactions occur sequentially over the entire volume of the single reactor. Greater phosphate removal requires a simultaneous chemical precipitation.
    Type: Grant
    Filed: March 14, 1990
    Date of Patent: December 31, 1991
    Assignee: Schreiber Corporation, Inc.
    Inventor: Wilhelm Ballnus
  • Patent number: 5075007
    Abstract: Wastewater containing impurities refractory to secondary treatment is first introducted into an aerobic biological treatment stage operating with an oxygen-enriched stream and subsequently into a precipitation stage where the biologically treated wastewater is combined with Ca(OH).sub.2 to precipitate Ca(OH).sub.2 CaCO.sub.3 sludge which adsorbs or occludes impurities. The clear liquid, separated from the resultant sludge, is passed to a second precipitation stage where it reacts with a CO.sub.2 and oxygen-containing waste gas at least in part from the aerobic biological treatment stage, thereby forming additional CaCO.sub.3. Waste gas withdrawn from the second precipitation stage, being enriched in oxygen is recycled to the aerobic biological treatment stage.
    Type: Grant
    Filed: May 25, 1990
    Date of Patent: December 24, 1991
    Assignee: Linde Aktiengesellschaft
    Inventors: Manfred Morper, Wolfgang Reiser
  • Patent number: 5071559
    Abstract: The invention relates to a method for processing manure, comprising the steps of:i) adding an organic carrier liquid to the manure;ii) concentrating the mixture of manure and carrier liquid;iii) condensing the formed vapor;vi) anaerobic treating of the condensate; andv) aerobic treating of the effluent from the anaerobic treatment.Preferably the effluent deriving from the anaerobic treatment is denitrified in a denitrification unit and nitrified in a nitrification unit, and wherein a portion of the sludge-influent mixture from the nitrification unit is recirculated to the denitrification unit.The treating yield is greater than 90%, preferably greater than 95%, such as 97-99% BOD.
    Type: Grant
    Filed: April 20, 1990
    Date of Patent: December 10, 1991
    Assignee: MeMon B.V.
    Inventor: Erik D. J. Bleeker
  • Patent number: 5039427
    Abstract: A method of treating lake water to remove suspended solids and to precipitate and inactivate phosphorus comprises adding aluminum hydroxide sulfate to the water in a concentration such that the pH of the water is maintained at a level of greater than 6.0 and precipitation of suspended solids and precipitation and inactivation of phosphorus occurs. This invention is advantageous in that it provides a method of removing suspended solids as well as precipitating and inactivating phosphorus in water while simultaneously preventing the solublizing of toxic amounts of aluminum into the water with subsequent detrimental effects to aquatic life.
    Type: Grant
    Filed: June 19, 1990
    Date of Patent: August 13, 1991
    Assignee: General Chemical Corporation
    Inventor: Brett R. Conover
  • Patent number: 5022993
    Abstract: The present invention entails a process for treating wastewater utilizing a return activated sludge process. Primary sludge is separated from the wastewater stream and conveyed into a fermentation tank and held a sufficient time to permit hydrolysis of suspended solids so as to produce soluble substrates. Part of the soluble substrates are mixed with nutrified return activated sludge and held for a selected time period to form conditioned return activated sludge. Thereafter, the conditioned return activated sludge is mixed in an initial aerobic treatment zone with pretreated wastewater. Thereafter, the mixed conditioned return activated sludge and pretreatd wastewater is conveyed through a series of treatment zones, which includes at least one anoxic treatment zone, to which part of the soluble substrates are added, where nitrogen and other pollutants are removed from the wastewater.
    Type: Grant
    Filed: August 4, 1989
    Date of Patent: June 11, 1991
    Assignee: Orange Water and Sewer Authority
    Inventor: Ronald E. Williamson
  • Patent number: 5008224
    Abstract: An amorphous substance obtained by mixing volcanic ash with or without added clay and water and, if necessary, a surfactant, kneading the mixture, and shaping and firing. Additives such as camphor or naphthalene may be included prior to firing for plasticity and to form pores. The resultant mixture possesses an ability to adsorb phosphorus selectively. When this substance is placed in contact with a phosphorus-containing liquid, it removes phosphorus from the liquid.
    Type: Grant
    Filed: June 30, 1989
    Date of Patent: April 16, 1991
    Assignees: Agency of Industrial Science and Technology, Ministry of International Trade and Industry
    Inventors: Eiji Watanabe, Nasakazu Horio, Kenzi Suzuki
  • Patent number: 4999111
    Abstract: The present invention entails a process for treating wastewater utilizing a return activated sludge process. Primary sludge is separated from the wastewater stream and conveyed into a fermentation tank and held a sufficient time to permit hydrolysis of suspended solids so as to produce soluble substrates. The soluble substrates are mixed with the return activated sludge and held for a selected time period in an anoxic zone, to form conditioned, denitrified return activated sludge, followed by anaerobic treatment, to produce microorganisms that are capable of biologically removing phosphorus. Thereafter, the conditioned return activated sludge is mixed in an initial aerobic treatment zone with pretreated wastewater. Thereafter, the mixed conditioned return activated sludge and pretreated wastewater may be conveyed through a series of treatment zones, which may include at least one anoxic treatment zone.
    Type: Grant
    Filed: November 28, 1989
    Date of Patent: March 12, 1991
    Assignee: Orange Water and Sewer Authority
    Inventor: Ronald E. Williamson