Nonbiodegradable Surfacant Patents (Class 210/910)
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Patent number: 8709263Abstract: A method of removing contaminants from slurry samples is set forth. The method includes the utilization of repeated pressurizing and depressurizing steps to disrupt solidified particles in solid-containing slurries thereby increasing decontamination efficiency. An expansion fluid is injected into the slurry sample sufficient to create microbubbles when the slurry sample is depressurized. The micro bubbles mechanically disrupt the solidified particles increasing contaminant exposure. The microbubbles also provide for increased interfacial regions where contaminants can accumulate at gas-liquid thin films that are in close proximity to and can be effectively removed using a suitable expansion fluid and optional decontamination agents.Type: GrantFiled: April 11, 2007Date of Patent: April 29, 2014Assignee: University of Utah Research FoundationInventor: P. K. Andy Hong
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Patent number: 8425784Abstract: A method for increasing ozone concentration in a liquid can include: providing a gas having ozone; introducing the ozone-containing gas into a liquid, wherein the liquid and ozone combination has a temperature between about 0.8 and about 1.5 times the critical temperature of ozone; and increasing isothermally, the pressure of the ozone-containing gas above the liquid to about 0.3 to about 5 times the critical pressure of ozone so as to increase the ozone concentration in the liquid. The temperature is expressed in absolute units (Kelvin or Rankin). The method can be used for removing ozone from a gas or for purifying ozone. The liquid having a high ozone concentration can be used for ozonolysis of a substrate.Type: GrantFiled: November 4, 2008Date of Patent: April 23, 2013Assignees: University of Kansas, Archer Daniels Midland CompanyInventors: Bala Subramaniam, Daryle Busch, Andrew M. Danby, Thomas P. Binder
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Patent number: 8419948Abstract: A method for treating wastewater treats wastewater. In an embodiment, the method for treating wastewater includes treating wastewater comprising a chemical oxygen demand. The method includes dissolving an iron compound in the wastewater. The method also includes adjusting the pH of the wastewater to reduce the chemical oxygen demand of the wastewater.Type: GrantFiled: November 22, 2009Date of Patent: April 16, 2013Assignee: United Laboratories International, LLCInventor: Jack G. Frost
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Patent number: 7204929Abstract: Method of treating an aqueous effluent containing organic matters in solution, comprising the following successive steps: the effluent is rendered basic; the effluent rendered basic is mineralized by being brought into contact with a gaseous oxidizing agent; the mineralized basic effluent is rendered acidic; and the effluent rendered acidic is again mineralized by being brought into contact with the gaseous oxidizing agent.Type: GrantFiled: June 20, 2002Date of Patent: April 17, 2007Assignee: Commissariat a l'Energie AtomiqueInventors: Jean-Michel Fulconis, Jacques Delagrange, Jean Sarrazin
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Patent number: 7018541Abstract: The present invention provides a method of removing a fluorinated surfactant from waste water comprising fluoropolymer particles. The method comprises (i) adding a non-fluorinated surfactant to the waste water (ii) contacting the thus obtained waste water with adsorbent particles to adsorb at least a portion of the fluorinated surfactant to the adsorbent particles and (iii) separating the waste water and the adsorbent particles.Type: GrantFiled: January 12, 2005Date of Patent: March 28, 2006Assignee: 3M Innovative Properties CompanyInventors: Klaus Hintzer, Egon Obermaier, Werner Schwertfeger
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Patent number: 5965024Abstract: The microbiological degradation of alkylene amine acetates under alkaline conditions using microorganisms present in activated sludge is achieved by contacting the alkylene amine acetate-containing waste, at a pH of about 9 or less, with activated sludge containing a wide range of microorganisms, in the absence of carrier materials.Type: GrantFiled: December 22, 1997Date of Patent: October 12, 1999Assignee: Akzo Nobel N.V.Inventors: Cornelis Gijsbertus Van Ginkel, Eltjo Boelema
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Patent number: 5885459Abstract: Waste water from a laundry (1) is collected in a storage container (3), fluffs and textile sheddings are separated through filtering sieves (2). The volume of the container is set so that it may store the amount of waste water produced for example during two days. The waste water is supplied with a bio-reactor (4) that works in aerobic conditions. Air is lead into the bio-reactor (4) at its lower end (5), establishing aerobic conditions therein. The biologically considered water leaves the bio-reactor (4) at the top end (6) of the column-shaped bio-reactor (4) and is supplied to an active coal column that acts as an adsorber (7). The adsorptively purified water leaves the adsorber (7) packed with active coal through the duct (8), is collected in a storage container (9) and if required is returned through duct (10) to the laundry, if required after 5 to 20% fresh water are added.Type: GrantFiled: November 25, 1996Date of Patent: March 23, 1999Assignee: Buck Werke GmbH & Co.Inventors: Elke Lerche, Karin Kneist, Hartmut Rohbeck, Doris Hillemann, Ralf Schwarz
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Patent number: 5868924Abstract: A water purifier which produces ultrapure water from a variety of feed sources. The feed source water may be potable tap, distilled, deionized, or water treated by reverse osmosis. The water is passed through a first purification media (30) and then through a chamber (34) where it is exposed to ultraviolet light in the presence of titanium dioxide. The water is then passed through a second purification media (38) to a dispensing valve (40). Operating the dispensing valve (40) provides ultrapure water from the purifier having a specific resistance of at least 18.0 megohm-cm and a TOC count of less than one ppb.Type: GrantFiled: February 14, 1997Date of Patent: February 9, 1999Assignee: Barnstead/Thermolyne CorporationInventors: Charles T. Nachtman, Chester E. Chomka, James R. Edwards
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Patent number: 5853596Abstract: A method for reducing the COD of water containing an emulsion of organic material in water. The emulsion contains insoluble organic material and a surfactant. The COD is reduced by mixing a cationic polymer flocculent with the water and maintaining the temperature at from 37.degree. C. to 95.degree. C. for a sufficient length of time for an organic phase and water with reduced COD to form.Type: GrantFiled: December 9, 1996Date of Patent: December 29, 1998Assignee: Henkel CorporationInventor: Michael W. Gibson
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Patent number: 5755973Abstract: A portable wastewater treatment system for recycling an aqueous surfactant solution utilized in a parts washer assembly for cleaning parts. The system including a contaminated solution storage tank, a treated solution storage tank, and a portable wastewater treatment apparatus wherein contaminated aqueous surfactant solution is collected in the contaminated solution storage tank, withdrawn from the contaminated solution storage tank, injected with air and passed into a mixing zone where the mixture is sprayed with water. The treated solution in the mixing zone is passed into a quiescent zone where light sludge is passed to the top of the quiescent zone and heavy sludge is passed to the bottom of the quiescent zone, the treated wastewater being disposed between the light sludge and the heavy sludge and the treated wastewater being passed from the quiescent zone into a discharge zone where the treated wastewater is discharged therefrom. The heavy sludge is selectively discharged from the quiescent zone.Type: GrantFiled: March 20, 1996Date of Patent: May 26, 1998Assignee: JTJ Systems, Inc.Inventor: Joseph P. Krieger
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Patent number: 5632899Abstract: The present invention is directed to methods of detoxifying water containing alkylthioalkylamine compounds. The methods comprise adding to an aqueous system containing alkylthioalkylamines, a sufficient quantity of a swelling type natural or synthetic clay to neutralize the toxicity associated with alkylthioalkylamines to aquatic organisms.Type: GrantFiled: July 20, 1995Date of Patent: May 27, 1997Assignee: BetzDearborn Inc.Inventors: Joseph C. Petrille, III, Michael W. Werner, Wilson K. Whitekettle
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Patent number: 5534159Abstract: A portable wastewater treatment system for recycling an aqueous surfactant solution utilized in a parts washer assembly for cleaning parts. The system including a contaminated solution storage tank, a treated solution storage tank, and a portable wastewater treatment apparatus wherein contaminated aqueous surfactant solution is collected in the contaminated solution storage tank, withdrawn from the contaminated solution storage tank, injected with air and passed into a mixing zone where the mixture is sprayed with water. The treated solution in the mixing zone is passed into a quiescent zone where light sludge is passed to the top of the quiescent zone and heavy sludge is passed to the bottom of the quiescent zone, the treated wastewater being disposed between the light sludge and the heavy sludge and the treated wastewater being passed from the quiescent zone into a discharge zone where the treated wastewater is discharged therefrom. The heavy sludge is selectively discharged from the quiescent zone.Type: GrantFiled: September 2, 1994Date of Patent: July 9, 1996Assignee: JTJ Systems, Inc.Inventor: Joseph P. Krieger
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Patent number: 5487834Abstract: Novel methods for purifying contaminated subsurface groundwater are disclosed. The method is involves contacting the contaminated subsurface groundwater with methanotrophic or heterotrophic microorganisms which produce contaminant-degrading enzymes. The microorganisms are derived from surface cultures and are injected into the ground so as to act as a biofilter. The contaminants which may be treated include organic or metallic materials and radionuclides.Type: GrantFiled: February 9, 1993Date of Patent: January 30, 1996Assignee: The Regents of the University of CaliforniaInventors: Margaret L. Carman, Kenneth J. Jackson, Richard B. Knapp, John P. Knezovich, Nilesh N. Shah, Robert T. Taylor
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Patent number: 5449467Abstract: The present invention aims at providing an economical process for purifying water which can produce clean water by treating polluted water, which contains agricultural chemicals, organic solvents (particularly, halocarbon) and surface active agents (particularly, those with side chains) which are hard to treat according to a conventional activated sludge process, under moderate conditions readily and promptly, and also, which process is characterized by adding titanium oxide and iron salt into water to be treated, and irradiating light thereupon.Type: GrantFiled: November 3, 1993Date of Patent: September 12, 1995Assignees: Director General of Agency of Industrial Science and Technology, Kato Manufacturing Corporation Limited, Aiwa Corporation LimitedInventors: Hiroshi Taoda, Eiji Watanabe, Tatsuro Horiuchi, Shigekazu Kato, Seiichiro Omori, Hiroaki Yokoi
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Patent number: 5419840Abstract: A method of treating chemical liquid effluent to render it more environmentally acceptable, comprising the addition of hydrogen peroxide, or a compound capable of liberating hydrogen peroxide, to the effluent to react with and break down a sequestering agent. The reaction rate may be enhanced by the addition of a small amount of a compound including a transition metal ion, especially the nitrate or sulphate of iron or manganese.Type: GrantFiled: June 17, 1993Date of Patent: May 30, 1995Assignee: Eastman Kodak CompanyInventor: John R. Fyson
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Patent number: 5169536Abstract: The present invention is directed to a method of detoxifying water containing a cationic surfactant based biocide. The method comprises adding to an aqueous stream including a biocide containing cationic surfactants a sufficient quantity of a combination including clay and a non surface active sulfonate such as a polymerized alkyl naphthalene sulfonate. The combination allows for a high solids detoxification treatment.Type: GrantFiled: April 28, 1992Date of Patent: December 8, 1992Assignee: Betz Laboratories, Inc.Inventors: Stephen R. Vasconcellos, Larry A. Lyons, Michael F. Mohn
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Patent number: 5076937Abstract: Method and apparatus for removing impurities from a laundry wash effluent including the steps and means therefor of acidifying the solution, infusing a gas into the solution and coalescing the released contaminant droplets by means of baffle plates into droplets sufficient to achieve buoyany with respect to the solution. The resulting top layer of buoyant droplets is skimmed from the solution and the remaining solution is adjusted to a neutral pH for discharge.Type: GrantFiled: July 26, 1990Date of Patent: December 31, 1991Assignee: Unitog Rental Services, Inc.Inventor: Stephen M. Montgomery
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Patent number: 4781860Abstract: An improved method of disposing of radioactive or hazardous liquid aqueous waste compositions having a substantial amount of dissolved solids comprises mixing the liquid under a high mechanical shear with a clay selected from the group consisting of attapulgite, sepiolite, and mixtures thereof. Water soluble or miscible organic liquids as well as liquid hydrocarbon mixtures thereof may also be solidified by utilizing the aforesaid clays together with an organic ammonium montmorillonite having at least 10 carbon atoms, the amount of montmorillonite used being proportional to the amount of liquid hydrocarbon present.Type: GrantFiled: May 11, 1987Date of Patent: November 1, 1988Assignees: James W. Ayres, Farrell D. RowsellInventor: Darryl J. Doan
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Patent number: 4773939Abstract: The process of regenerating a soil-laden detergent solution comprising contacting said solution with a soil collector comprising a polyfunctional quaternary ammonium compound which is at least substantially insoluble in the solution and/or immobilized on a solid correspondingly insoluble in the solution.Type: GrantFiled: February 20, 1987Date of Patent: September 27, 1988Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Alfred Meffert, Andreas Syldatk, Brigitte Giesen, Ingo Wegener
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Patent number: 4676315Abstract: A method is disclosed for concentrating surfactant in an aqueous solution. The method comprises adding to the solution a component incompatible with the surfactant, such as a water-soluble polymer, thereby displacing the surfactant from the aqueous phase of the solution. The component remains in the aqueous phase and the surfactant goes into a surfactant-rich phase. The surfactant-rich phase can then be separated from the aqueous phase by conventional separation devices or techniques. This method is particularly applicable to concentrating surfactant recovered from a reservoir following an enhanced oil recovery process employing surfactant. The method may be practiced in the field or off-site.Type: GrantFiled: February 5, 1986Date of Patent: June 30, 1987Assignee: Exxon Production Research CompanyInventor: James R. Bragg
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Patent number: 4401574Abstract: Paint waste water containing dispersed paint solids is clarified by flocculating the solids with a basic poly aluminum chloride having the following structural formula:Al.sub.n (OH).sub.m Cl.sub.3n-mwherein n and m are integers and 3n is larger than m, and the basicity is from 30% to 83%.Type: GrantFiled: July 21, 1981Date of Patent: August 30, 1983Assignee: Drew Chemical CorporationInventors: Thomas A. Farrington, Tamara Nowakowski
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Patent number: RE34041Abstract: An improved method of disposing of radioactive or hazardous liquid aqueous waste compositions having a substantial amount of dissolved solids comprises mixing the liquid under a high mechanical shear with a clay selected from the group consisting of attapulgite, sepiolite, and mixtures thereof. Water soluble or miscible organic liquids as well as liquid hydrocarbon mixtures thereof may also be solidified by utilizing the aforesaid clays together with an organic ammonium montmorillonite having at least 10 carbon atoms, the amount of montmorillonite used being proportional to the amount of liquid hydrocarbon present.Type: GrantFiled: October 16, 1990Date of Patent: August 25, 1992Assignees: James William Ayres, Farrell D. RowsellInventor: Darryl J. Doan