Nonbiodegradable Surfacant Patents (Class 210/910)
  • Patent number: 8709263
    Abstract: A method of removing contaminants from slurry samples is set forth. The method includes the utilization of repeated pressurizing and depressurizing steps to disrupt solidified particles in solid-containing slurries thereby increasing decontamination efficiency. An expansion fluid is injected into the slurry sample sufficient to create microbubbles when the slurry sample is depressurized. The micro bubbles mechanically disrupt the solidified particles increasing contaminant exposure. The microbubbles also provide for increased interfacial regions where contaminants can accumulate at gas-liquid thin films that are in close proximity to and can be effectively removed using a suitable expansion fluid and optional decontamination agents.
    Type: Grant
    Filed: April 11, 2007
    Date of Patent: April 29, 2014
    Assignee: University of Utah Research Foundation
    Inventor: P. K. Andy Hong
  • Patent number: 8425784
    Abstract: A method for increasing ozone concentration in a liquid can include: providing a gas having ozone; introducing the ozone-containing gas into a liquid, wherein the liquid and ozone combination has a temperature between about 0.8 and about 1.5 times the critical temperature of ozone; and increasing isothermally, the pressure of the ozone-containing gas above the liquid to about 0.3 to about 5 times the critical pressure of ozone so as to increase the ozone concentration in the liquid. The temperature is expressed in absolute units (Kelvin or Rankin). The method can be used for removing ozone from a gas or for purifying ozone. The liquid having a high ozone concentration can be used for ozonolysis of a substrate.
    Type: Grant
    Filed: November 4, 2008
    Date of Patent: April 23, 2013
    Assignees: University of Kansas, Archer Daniels Midland Company
    Inventors: Bala Subramaniam, Daryle Busch, Andrew M. Danby, Thomas P. Binder
  • Patent number: 8419948
    Abstract: A method for treating wastewater treats wastewater. In an embodiment, the method for treating wastewater includes treating wastewater comprising a chemical oxygen demand. The method includes dissolving an iron compound in the wastewater. The method also includes adjusting the pH of the wastewater to reduce the chemical oxygen demand of the wastewater.
    Type: Grant
    Filed: November 22, 2009
    Date of Patent: April 16, 2013
    Assignee: United Laboratories International, LLC
    Inventor: Jack G. Frost
  • Patent number: 7204929
    Abstract: Method of treating an aqueous effluent containing organic matters in solution, comprising the following successive steps: the effluent is rendered basic; the effluent rendered basic is mineralized by being brought into contact with a gaseous oxidizing agent; the mineralized basic effluent is rendered acidic; and the effluent rendered acidic is again mineralized by being brought into contact with the gaseous oxidizing agent.
    Type: Grant
    Filed: June 20, 2002
    Date of Patent: April 17, 2007
    Assignee: Commissariat a l'Energie Atomique
    Inventors: Jean-Michel Fulconis, Jacques Delagrange, Jean Sarrazin
  • Patent number: 7018541
    Abstract: The present invention provides a method of removing a fluorinated surfactant from waste water comprising fluoropolymer particles. The method comprises (i) adding a non-fluorinated surfactant to the waste water (ii) contacting the thus obtained waste water with adsorbent particles to adsorb at least a portion of the fluorinated surfactant to the adsorbent particles and (iii) separating the waste water and the adsorbent particles.
    Type: Grant
    Filed: January 12, 2005
    Date of Patent: March 28, 2006
    Assignee: 3M Innovative Properties Company
    Inventors: Klaus Hintzer, Egon Obermaier, Werner Schwertfeger
  • Patent number: 5965024
    Abstract: The microbiological degradation of alkylene amine acetates under alkaline conditions using microorganisms present in activated sludge is achieved by contacting the alkylene amine acetate-containing waste, at a pH of about 9 or less, with activated sludge containing a wide range of microorganisms, in the absence of carrier materials.
    Type: Grant
    Filed: December 22, 1997
    Date of Patent: October 12, 1999
    Assignee: Akzo Nobel N.V.
    Inventors: Cornelis Gijsbertus Van Ginkel, Eltjo Boelema
  • Patent number: 5885459
    Abstract: Waste water from a laundry (1) is collected in a storage container (3), fluffs and textile sheddings are separated through filtering sieves (2). The volume of the container is set so that it may store the amount of waste water produced for example during two days. The waste water is supplied with a bio-reactor (4) that works in aerobic conditions. Air is lead into the bio-reactor (4) at its lower end (5), establishing aerobic conditions therein. The biologically considered water leaves the bio-reactor (4) at the top end (6) of the column-shaped bio-reactor (4) and is supplied to an active coal column that acts as an adsorber (7). The adsorptively purified water leaves the adsorber (7) packed with active coal through the duct (8), is collected in a storage container (9) and if required is returned through duct (10) to the laundry, if required after 5 to 20% fresh water are added.
    Type: Grant
    Filed: November 25, 1996
    Date of Patent: March 23, 1999
    Assignee: Buck Werke GmbH & Co.
    Inventors: Elke Lerche, Karin Kneist, Hartmut Rohbeck, Doris Hillemann, Ralf Schwarz
  • Patent number: 5868924
    Abstract: A water purifier which produces ultrapure water from a variety of feed sources. The feed source water may be potable tap, distilled, deionized, or water treated by reverse osmosis. The water is passed through a first purification media (30) and then through a chamber (34) where it is exposed to ultraviolet light in the presence of titanium dioxide. The water is then passed through a second purification media (38) to a dispensing valve (40). Operating the dispensing valve (40) provides ultrapure water from the purifier having a specific resistance of at least 18.0 megohm-cm and a TOC count of less than one ppb.
    Type: Grant
    Filed: February 14, 1997
    Date of Patent: February 9, 1999
    Assignee: Barnstead/Thermolyne Corporation
    Inventors: Charles T. Nachtman, Chester E. Chomka, James R. Edwards
  • Patent number: 5853596
    Abstract: A method for reducing the COD of water containing an emulsion of organic material in water. The emulsion contains insoluble organic material and a surfactant. The COD is reduced by mixing a cationic polymer flocculent with the water and maintaining the temperature at from 37.degree. C. to 95.degree. C. for a sufficient length of time for an organic phase and water with reduced COD to form.
    Type: Grant
    Filed: December 9, 1996
    Date of Patent: December 29, 1998
    Assignee: Henkel Corporation
    Inventor: Michael W. Gibson
  • Patent number: 5755973
    Abstract: A portable wastewater treatment system for recycling an aqueous surfactant solution utilized in a parts washer assembly for cleaning parts. The system including a contaminated solution storage tank, a treated solution storage tank, and a portable wastewater treatment apparatus wherein contaminated aqueous surfactant solution is collected in the contaminated solution storage tank, withdrawn from the contaminated solution storage tank, injected with air and passed into a mixing zone where the mixture is sprayed with water. The treated solution in the mixing zone is passed into a quiescent zone where light sludge is passed to the top of the quiescent zone and heavy sludge is passed to the bottom of the quiescent zone, the treated wastewater being disposed between the light sludge and the heavy sludge and the treated wastewater being passed from the quiescent zone into a discharge zone where the treated wastewater is discharged therefrom. The heavy sludge is selectively discharged from the quiescent zone.
    Type: Grant
    Filed: March 20, 1996
    Date of Patent: May 26, 1998
    Assignee: JTJ Systems, Inc.
    Inventor: Joseph P. Krieger
  • Patent number: 5632899
    Abstract: The present invention is directed to methods of detoxifying water containing alkylthioalkylamine compounds. The methods comprise adding to an aqueous system containing alkylthioalkylamines, a sufficient quantity of a swelling type natural or synthetic clay to neutralize the toxicity associated with alkylthioalkylamines to aquatic organisms.
    Type: Grant
    Filed: July 20, 1995
    Date of Patent: May 27, 1997
    Assignee: BetzDearborn Inc.
    Inventors: Joseph C. Petrille, III, Michael W. Werner, Wilson K. Whitekettle
  • Patent number: 5534159
    Abstract: A portable wastewater treatment system for recycling an aqueous surfactant solution utilized in a parts washer assembly for cleaning parts. The system including a contaminated solution storage tank, a treated solution storage tank, and a portable wastewater treatment apparatus wherein contaminated aqueous surfactant solution is collected in the contaminated solution storage tank, withdrawn from the contaminated solution storage tank, injected with air and passed into a mixing zone where the mixture is sprayed with water. The treated solution in the mixing zone is passed into a quiescent zone where light sludge is passed to the top of the quiescent zone and heavy sludge is passed to the bottom of the quiescent zone, the treated wastewater being disposed between the light sludge and the heavy sludge and the treated wastewater being passed from the quiescent zone into a discharge zone where the treated wastewater is discharged therefrom. The heavy sludge is selectively discharged from the quiescent zone.
    Type: Grant
    Filed: September 2, 1994
    Date of Patent: July 9, 1996
    Assignee: JTJ Systems, Inc.
    Inventor: Joseph P. Krieger
  • Patent number: 5487834
    Abstract: Novel methods for purifying contaminated subsurface groundwater are disclosed. The method is involves contacting the contaminated subsurface groundwater with methanotrophic or heterotrophic microorganisms which produce contaminant-degrading enzymes. The microorganisms are derived from surface cultures and are injected into the ground so as to act as a biofilter. The contaminants which may be treated include organic or metallic materials and radionuclides.
    Type: Grant
    Filed: February 9, 1993
    Date of Patent: January 30, 1996
    Assignee: The Regents of the University of California
    Inventors: Margaret L. Carman, Kenneth J. Jackson, Richard B. Knapp, John P. Knezovich, Nilesh N. Shah, Robert T. Taylor
  • Patent number: 5449467
    Abstract: The present invention aims at providing an economical process for purifying water which can produce clean water by treating polluted water, which contains agricultural chemicals, organic solvents (particularly, halocarbon) and surface active agents (particularly, those with side chains) which are hard to treat according to a conventional activated sludge process, under moderate conditions readily and promptly, and also, which process is characterized by adding titanium oxide and iron salt into water to be treated, and irradiating light thereupon.
    Type: Grant
    Filed: November 3, 1993
    Date of Patent: September 12, 1995
    Assignees: Director General of Agency of Industrial Science and Technology, Kato Manufacturing Corporation Limited, Aiwa Corporation Limited
    Inventors: Hiroshi Taoda, Eiji Watanabe, Tatsuro Horiuchi, Shigekazu Kato, Seiichiro Omori, Hiroaki Yokoi
  • Patent number: 5419840
    Abstract: A method of treating chemical liquid effluent to render it more environmentally acceptable, comprising the addition of hydrogen peroxide, or a compound capable of liberating hydrogen peroxide, to the effluent to react with and break down a sequestering agent. The reaction rate may be enhanced by the addition of a small amount of a compound including a transition metal ion, especially the nitrate or sulphate of iron or manganese.
    Type: Grant
    Filed: June 17, 1993
    Date of Patent: May 30, 1995
    Assignee: Eastman Kodak Company
    Inventor: John R. Fyson
  • Patent number: 5169536
    Abstract: The present invention is directed to a method of detoxifying water containing a cationic surfactant based biocide. The method comprises adding to an aqueous stream including a biocide containing cationic surfactants a sufficient quantity of a combination including clay and a non surface active sulfonate such as a polymerized alkyl naphthalene sulfonate. The combination allows for a high solids detoxification treatment.
    Type: Grant
    Filed: April 28, 1992
    Date of Patent: December 8, 1992
    Assignee: Betz Laboratories, Inc.
    Inventors: Stephen R. Vasconcellos, Larry A. Lyons, Michael F. Mohn
  • Patent number: 5076937
    Abstract: Method and apparatus for removing impurities from a laundry wash effluent including the steps and means therefor of acidifying the solution, infusing a gas into the solution and coalescing the released contaminant droplets by means of baffle plates into droplets sufficient to achieve buoyany with respect to the solution. The resulting top layer of buoyant droplets is skimmed from the solution and the remaining solution is adjusted to a neutral pH for discharge.
    Type: Grant
    Filed: July 26, 1990
    Date of Patent: December 31, 1991
    Assignee: Unitog Rental Services, Inc.
    Inventor: Stephen M. Montgomery
  • Patent number: 4781860
    Abstract: An improved method of disposing of radioactive or hazardous liquid aqueous waste compositions having a substantial amount of dissolved solids comprises mixing the liquid under a high mechanical shear with a clay selected from the group consisting of attapulgite, sepiolite, and mixtures thereof. Water soluble or miscible organic liquids as well as liquid hydrocarbon mixtures thereof may also be solidified by utilizing the aforesaid clays together with an organic ammonium montmorillonite having at least 10 carbon atoms, the amount of montmorillonite used being proportional to the amount of liquid hydrocarbon present.
    Type: Grant
    Filed: May 11, 1987
    Date of Patent: November 1, 1988
    Assignees: James W. Ayres, Farrell D. Rowsell
    Inventor: Darryl J. Doan
  • Patent number: 4773939
    Abstract: The process of regenerating a soil-laden detergent solution comprising contacting said solution with a soil collector comprising a polyfunctional quaternary ammonium compound which is at least substantially insoluble in the solution and/or immobilized on a solid correspondingly insoluble in the solution.
    Type: Grant
    Filed: February 20, 1987
    Date of Patent: September 27, 1988
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Alfred Meffert, Andreas Syldatk, Brigitte Giesen, Ingo Wegener
  • Patent number: 4676315
    Abstract: A method is disclosed for concentrating surfactant in an aqueous solution. The method comprises adding to the solution a component incompatible with the surfactant, such as a water-soluble polymer, thereby displacing the surfactant from the aqueous phase of the solution. The component remains in the aqueous phase and the surfactant goes into a surfactant-rich phase. The surfactant-rich phase can then be separated from the aqueous phase by conventional separation devices or techniques. This method is particularly applicable to concentrating surfactant recovered from a reservoir following an enhanced oil recovery process employing surfactant. The method may be practiced in the field or off-site.
    Type: Grant
    Filed: February 5, 1986
    Date of Patent: June 30, 1987
    Assignee: Exxon Production Research Company
    Inventor: James R. Bragg
  • Patent number: 4401574
    Abstract: Paint waste water containing dispersed paint solids is clarified by flocculating the solids with a basic poly aluminum chloride having the following structural formula:Al.sub.n (OH).sub.m Cl.sub.3n-mwherein n and m are integers and 3n is larger than m, and the basicity is from 30% to 83%.
    Type: Grant
    Filed: July 21, 1981
    Date of Patent: August 30, 1983
    Assignee: Drew Chemical Corporation
    Inventors: Thomas A. Farrington, Tamara Nowakowski
  • Patent number: RE34041
    Abstract: An improved method of disposing of radioactive or hazardous liquid aqueous waste compositions having a substantial amount of dissolved solids comprises mixing the liquid under a high mechanical shear with a clay selected from the group consisting of attapulgite, sepiolite, and mixtures thereof. Water soluble or miscible organic liquids as well as liquid hydrocarbon mixtures thereof may also be solidified by utilizing the aforesaid clays together with an organic ammonium montmorillonite having at least 10 carbon atoms, the amount of montmorillonite used being proportional to the amount of liquid hydrocarbon present.
    Type: Grant
    Filed: October 16, 1990
    Date of Patent: August 25, 1992
    Assignees: James William Ayres, Farrell D. Rowsell
    Inventor: Darryl J. Doan