Odor (including Control Or Abatement) Patents (Class 210/916)
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Patent number: 11548785Abstract: The invention is directed to a control method for a process to convert bisulphide to elemental sulphur in an aqueous solution comprising sulphide-oxidising bacteria wherein the process is controlled by applying a potential between the anode electrode and the cathode electrode or between the anode electrode and the reference electrode of an electrochemical cell resulting in a current between the cathode electrode and the anode electrode, measuring a current as measured by an electrochemical cell and adapting the process in response to the measured current. The process to convert bisulphide may comprise the following steps: (a) contacting bisulphide with oxidised sulphide-oxidising bacteria in the aqueous solution and elemental sulphur, (b) oxidizing the reduced sulphide-oxidising bacteria, (c) using the oxidised sulphide-oxidising bacteria obtained in step (b) in step (a) and (d) isolating elemental sulphur from the aqueous solution obtained in step (a) and/or step (b).Type: GrantFiled: May 30, 2018Date of Patent: January 10, 2023Assignee: PAQELL B.V.Inventors: Johannes Bernardus Maria Klok, Annemiek Ter Heijne, Frederikus De Rink, Cees Jan Nico Buisman
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Patent number: 10035128Abstract: Compositions that can be used to adsorb low concentration, of unwanted or target substances from a dynamic fluid stream or from an enclosed static vapor phase. Such adsorbency can be obtained with thermoplastic materials used in the form of bulk polymer or a film, fiber, web, woven fabric, non-woven fabric, sheet, packaging and other such structures including or surrounding the enclosed volume. The concentration should be reduced to non-offensive sensed limits or a limit that does not produce a biological response.Type: GrantFiled: October 17, 2017Date of Patent: July 31, 2018Assignee: Cellresin Technologies, LLCInventor: Willard E. Wood
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Patent number: 8992780Abstract: The invention provides methods and compositions for reducing the malodorous sulfide gas released by a wastewater treatment system. The method preserves the vitality of waste consuming organisms within the system. The method comprises the steps of: determining the SRP PAA demand of the system, determining the aerobic PAA demand of the system, and adding a composition in an amount such that it is in excess of the SRP PAA demand but is below the aerobic PAA demand. Even though the composition increases the amount of sulfates within the wastewater it reduces the amount of SRP which prevents the malodorous sulfite gas release. The composition comprises at least one percarboxyacid.Type: GrantFiled: May 10, 2013Date of Patent: March 31, 2015Assignee: Ecolab USA IncInventors: Gary L. Champion, Victor Keasler, Robert J Ryther
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Patent number: 8795518Abstract: A method and system for waste water treatment and disposal includes the use of a sealed chamber having a plurality of sealed light transmitting windows and a relatively large basin connected to the chamber by a large multi-channel conduit. A large fan exhausts gases, humidity and odor from the chamber into a lower portion of the basin. An upper portion of the basin includes a multi-layer grid including layers of hydro stones and/or artificial hydro stones, sand, fertilizer and earth together with a plurality of shallow rooted trees. Any carbon dioxide produced by the waste water is ultimately converted to oxygen.Type: GrantFiled: May 26, 2011Date of Patent: August 5, 2014Inventor: Abdulreidha Alsaffar
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Patent number: 8721887Abstract: Methods and systems for utilizing biological wastewater treatment processes to remove nutrients from wastewater containing reduced sulfide compounds may include treating the wastewater in an anaerobic zone, an anoxic zone, and an aerobic zone. The wastewater is first treated in the anaerobic zone to uptake residual biodegradable organic material using specialized bacteria known as phosphorus accumulating organisms (“PAOs”) and glycogen accumulating organisms (“GAOs”). After treatment in the anaerobic zone, the wastewater is treated in an anoxic zone to convert nitrates to nitrogen gas and sulfur to sulfates. Following treatment in the anoxic zone, the wastewater is treated in the aerobic zone to oxidize ammonia to nitrate and to complete removal of phosphorus. After treatment in the aerobic zone, the wastewater may be treated in other zones, or may be delivered to a liquid-solids treatment stage.Type: GrantFiled: December 7, 2010Date of Patent: May 13, 2014Assignee: CH2M Hill, Inc.Inventors: Glen T. Daigger, Julian Sandino, Steven J. Goodwin
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Patent number: 8298416Abstract: The present invention relates to a deodorizing apparatus using native microorganisms. Specifically, the present invention relates to a deodorizing apparatus using native microorganisms for removal of malodors of sewage treatment plant sludge, comprising a native microorganism activating tank, where a colony of the native microorganisms in a spore state is germinated and activated through a proliferation process under conditions where oxygen and organic materials are supplied, and the native microorganisms returned from a second deodorizing tank is further activated; and a first and a second deodorizing tanks which remove malodorants from untreated matter under conditions where oxygen and the activated native microorganisms are continuously supplied.Type: GrantFiled: February 24, 2010Date of Patent: October 30, 2012Assignee: Korea Institute of Science and TechnologyInventors: Wan Cheol Park, Tae Hyung Kim, Mi Ae Lee, Kyung Lyong Choi
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Patent number: 8119003Abstract: A method for reducing the odors of an anaerobically digested dewatered biosolids or other biosolids or sludge may include separating first anaerobically digested dewatered biosolids into first and second portions, storing second anaerobically digested dewatered biosolids, removing a portion of the second biosolids, and mixing the removed second biosolids portion with the first portion of the first biosolids. The method may be implemented in a system including a separation device, first, second and third transporters, a storage area, and a mixer. The separation device may separate the first biosolids into first and second portions. The first transporter may transport the first portion to the mixer. The second transporter may transport the second portion to the storage area. The second portion may be stored in the storage area for a select time period. The third transporter may transport a portion of the stored first biosolids to the mixer for blending.Type: GrantFiled: December 3, 2008Date of Patent: February 21, 2012Assignee: CH2M Hill, Inc.Inventor: Todd Owen Williams
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Patent number: 8097165Abstract: Modified and insoluble starches are utilized for eliminating natural organic substances/contaminants from liquids and in particular from liquids used for food applications, such as drinking water, beverages, fruit juices or syrups, as well as natural water, industrial process water, or wastewater.Type: GrantFiled: June 28, 2005Date of Patent: January 17, 2012Assignee: Rhodia OperationsInventors: Caroline Mabille, Jean-Francois Sassi, Vincent Monin, Yves Mottot
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Patent number: 7972532Abstract: A synergistic composition is provided for controlling odor from waste products. The composition comprises a combination of nitrate salt, sulfide-consuming compound, pH-elevating compound, sulfide-oxidizing, nitrate-reducing bacteria, and sulfide-oxidizing enzyme. The method includes adding a sufficient amount of the composition to a waste stream to provide sufficient sulfide-consuming compound to effect immediate removal of sulfide. The composition incorporates a pH elevating compound, which both decreases the amount of gaseous H2S and puts the aqueous phase into a pH range where naturally occurring bacteria can more easily metabolize the sulfide. The composition also includes one or more nitrate salts which will accomplish longer term prevention of odors. Specific bacteria are incorporated into the formulation to insure that the nitrate has the right type and amount of bacteria present to prevent formation of and/or consume sulfide.Type: GrantFiled: May 15, 2009Date of Patent: July 5, 2011Assignee: Siemens Industry, Inc.Inventors: Gregory D. Simpson, Glenn W. Holden
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Patent number: 7967989Abstract: A sulfurous acid treated wastewater disposal method employing soil aquifer treatment (SAT) for artificial recharge of groundwater through infiltration basins allowing fully or partially-treated sewage effluent to infiltrate into the soil and move down to the groundwater through a “vadose” zone, which acts as a natural filter to remove essentially all suspended solids, biodegradable materials, bacteria, viruses, and other microorganisms.Type: GrantFiled: March 10, 2009Date of Patent: June 28, 2011Assignee: Earth Renaissance Technologies, LLCInventors: Terry Gong, John Harmon, Marcus G. Theodore
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Patent number: 7824557Abstract: A process has been found which increases the efficiency and effectiveness of introducing antimicrobial compounds into complex biofilm matrices through the use of liposome carriers, thereby removing the biofouling in industrial water bearing systems, including piping, heat exchanges, condensers, filtration systems and fluid storage tanks. According to one embodiment of the invention, antimicrobial compound containing liposomes are added to water systems prone to biofouling and biofilm formation. The liposomes, being similar in composition to microbial membranes or cells, are readily incorporated into the existing biofilm. Once the antimicrobial compound containing liposomes become entrained with the biofilm matrix, the decomposition or programmed disintegration of the liposome proceeds. Thereafter the biocidal aqueous core is released to react directly with the biofilm encased microorganisms.Type: GrantFiled: August 8, 2007Date of Patent: November 2, 2010Assignee: General Electric CompanyInventors: Wilson Kurt Whitekettle, Gloria Jean Tafel, Qing Zhao
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Patent number: 7731856Abstract: A method of treating waste matter from animals, the method comprising: a) collecting waste matter from the animals; b) inhibiting urease activity in said collected waste matter; and c) separating said urease-activity inhibited waste matter into a urea-rich fraction and a urea-lean fraction; a system for treating waste matter from animals; a urea-lean biogas fuel product; a urea-rich animal waste-matter product; a method of controlling the content of nitrogen in manure from animals; a method of reducing gaseous ammonia in stables for animals; a stable for animals; a biogas reactor system for producing biogas from waste matter from animals; a method of producing urea from waste matter of animals; a method of producing urea formaldehyde; and a method of producing biogas fuel from waste matter of animals.Type: GrantFiled: July 26, 2004Date of Patent: June 8, 2010Assignee: Waste 2 Green, LLCInventor: Dennis Wowern Nielsen
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Patent number: 7713410Abstract: In a waste water treatment apparatus and/or method, waste water containing aminoethanol and dimethyl sulfoxide is introduced into a first denitrification tank within a first waste water treatment apparatus. Malodorous gas generated in the first waste water treatment apparatus is decomposed and treated in a second waste water treatment apparatus where another waste water is treated as another system. The second waste water treatment apparatus has a second nitrification tank including a semi-anaerobic section. The malodorous gas is introduced from the first waste water treatment apparatus into a scrubber. The malodorous gas is treated by sludge which is circulated between the second nitrification tank and the scrubber.Type: GrantFiled: September 12, 2006Date of Patent: May 11, 2010Assignee: Sharp Kabuhsiki KaishaInventors: Kazuyuki Yamasaki, Kazuyuki Sakata
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Patent number: 7713416Abstract: A process for transforming sludge into NPK type granulated fertilizer in which the energy consume is reduced a 90% thanks to the addition of a special filtration step in which the water content is reduced a 50% and the remaining water is evaporated by the exothermic reaction occurring in the process. Additionally, the process of the present invention includes mechanisms that allow some of the by products generated by some of the reactions, to adsorb crystallization water and reduce the humidity of the mass without using external energy.Type: GrantFiled: August 25, 2006Date of Patent: May 11, 2010Assignee: Chemical Biosolids Inc.Inventor: José Cabello-Fuentes
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Patent number: 7604741Abstract: An apparatus and method produces nitrate ions on-site from water, natural gas and air extracted in proximity to the apparatus. The apparatus generates nitrate ions and brings the nitrate ions into contact with an aqueous system. Hydrogen sulfide present in the aqueous system is removed and the production of hydrogen sulfide by sulfate-reducing bacteria (SRB) is eliminated by introducing into the system nitrate ions, whereby denitrifying microorganisms, using nitrate, outcompete the sulfate-reducing bacteria for the available carbon nutrients, thus preventing the SRB from producing hydrogen sulfide. Nitrate ions generated by the apparatus and added to the aqueous system which contains the denitrifying microorganisms can enhance oil recovery by means of microbial enhanced oil recovery mechanisms.Type: GrantFiled: February 27, 2009Date of Patent: October 20, 2009Assignee: The Lata Group Inc.Inventors: Donald O. Hitzman, D. Michael Dennis, Bruce Alan Iiams
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Patent number: 7585413Abstract: Novel methods and apparatuses are disclosed for the treatment of wastewater to reduce, often associated, offensive odors. Irrigation of oxygenated liquid on top of a permeable cover effectively creates an aerobic treatment zone at the top of the lagoon whereby odorous gases being produced anaerobically below the cover are metabolized within this zone before being released to the atmosphere. This same system also serves to increase evaporation from the overall waste handling system therefore substantially reducing or eliminating the need for land application of treated wastewater.Type: GrantFiled: August 1, 2005Date of Patent: September 8, 2009Inventor: Robert O. Hoffland
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Patent number: 7569199Abstract: High surface area iron oxides that can be ferroxane-derived iron oxides are described, as well as methods of using the same to remove at least a portion of one or more sulfur-containing species from a gas stream or liquid stream.Type: GrantFiled: May 9, 2007Date of Patent: August 4, 2009Assignee: Oxane Materials, Inc.Inventors: Andrew R. Barron, Christopher E. Coker, John R. Loscutova
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Patent number: 7553420Abstract: A synergistic composition is provided for controlling odor from waste products. The composition comprises a combination of nitrate salt, sulfide-consuming compound, pH-elevating compound, sulfide-oxidizing, nitrate-reducing bacteria, and sulfide-oxidizing enzyme. The method includes adding a sufficient amount of the composition to a waste stream to provide sufficient sulfide-consuming compound to effect immediate removal of sulfide. The composition incorporates a pH elevating compound, which both decreases the amount of gaseous H2S and puts the aqueous phase into a pH range where naturally occurring bacteria can more easily metabolize the sulfide. The composition also includes one or more nitrate salts which will accomplish longer term prevention of odors. Specific bacteria are incorporated into the formulation to insure that the nitrate has the right type and amount of bacteria present to prevent formation of and/or consume sulfide.Type: GrantFiled: September 21, 2007Date of Patent: June 30, 2009Assignee: Siemens Water Technologies Corp.Inventors: Gregory D. Simpson, Glenn W. Holden
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Patent number: 7537699Abstract: A method for reducing the odors of an anaerobically digested dewatered biosolids or other biosolids or sludge may include separating first anaerobically digested dewatered biosolids into first and second portions, storing second anaerobically digested dewatered biosolids, removing a portion of the second biosolids, and mixing the removed second biosolids portion with the first portion of the first biosolids. The method may be implemented in a system including a separation device, first, second and third transporters, a storage area, and a mixer. The separation device may separate the first biosolids into first and second portions. The first transporter may transport the first portion to the mixer. The second transporter may transport the second portion to the storage area. The storage area may store the second portion for a select time period. The third transporter may transport a portion of the stored first biosolids to the mixer for blending.Type: GrantFiled: October 15, 2007Date of Patent: May 26, 2009Assignee: CH2M Hill, Inc.Inventor: Todd Owen Williams
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Patent number: 7510652Abstract: A fuel filter for removing fuel impurities, particularly thiophenes, includes a hollow housing having a filter element therein. The filter element includes a substrate, which may include a nonwoven fiber web, a plurality of particles, or both of these. Where particles are used, the substrate may be homogeneous or may be a mixture of different particles. The substrate may include a sorbent selected from the group consisting of metals, metal oxides, metallic salts, organometallic compounds, catalysts, and oxidizing agents. Optionally, a sulfur-treating reactant may be operatively associated with the substrate to reduce the concentration of thiophenes in fuel passing through the filter.Type: GrantFiled: December 10, 2007Date of Patent: March 31, 2009Assignee: Honeywell International Inc.Inventors: Ronald Paul Rohrbach, Russell Johnson, Peter D. Unger, Gordon William Jones, Daniel E. Bause, Gary B. Zulauf
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Patent number: 7507391Abstract: Sulphur oxides are generated from a liquid stream of hydrogen sulphide by feeding the liquid stream to a vacuum stripper where the stream is contacted with a stripping gas including steam under reduce pressure. Hydrogen sulphide is transferred to the stripping gas, whereby a loaded stripping gas is obtained. Water in the loaded stripping gas is condensed producing a H2S rich stream. The H2S is then burned in the stream to produce a stream rich in oxides of sulphur.Type: GrantFiled: August 10, 2007Date of Patent: March 24, 2009Assignee: Nederlandse Organisatie voor Toegepast-Natuurwetenschappelijk Onderzoek TNOInventors: Jacob Hendrik Obbo Hazewinkel, Johannes Wouterus Van Groenestijn, Koen Peter Henri Meesters
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Patent number: 7504035Abstract: A method of treating putrescible cakes to reduce the E. Coli and odor present in the cake and prevent further odor generation comprising the step of maintaining the cake under substantially anoxic condition in the presence of ammonium and/or nitrate moieties at pH 7.5 to pH 10.5 for a period of more than 1 day, the cake having a solids content of between 20% to 75% by weight.Type: GrantFiled: September 28, 2006Date of Patent: March 17, 2009Assignee: United Utilities PLCInventors: Son Le, Duc Do
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Patent number: 7485230Abstract: A system and method integrating treatment of waste, polar Fats/Oils/Greases (FOG) with conventional anaerobic wastewater treatment facilities for biologically fueling digestion of solids in, and steady state production of methane from treated wastewater streams that includes a slipstream loop circulating warmed, actively digesting sludge from the base to the head of the anaerobic wastewater treatment facility, a conditioning tank with input screened by a rock trap, actively digesting sludge pumped from the slipstream loop into the tank via the rock trap, before and after FOG wastes are pumped from a hauler tank via a hose connecting to the rock trap into the conditioning tank and mixed with actively digesting sludge in the tank to produce a feedstock slurry rich in volatile fatty acids for injection at a metered rate back into the actively digesting sludge slipstream loop for introduction at the head of the anaerobic wastewater treatment facility.Type: GrantFiled: March 8, 2007Date of Patent: February 3, 2009Inventors: Joseph A. Magner, Richard V. York
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Patent number: 7479224Abstract: A method of biologically purifying waste water, said method including the following steps in the following sequence a) an aeration step for stripping off H2S and other gases and for removing bactericides from the water, b) a step of decomposing organic matter, c) a sludge precipitation step, d) a clarification step and e) a nitrification step followed by a completing secondary settling step. This method is carried out in a plant, preferably a mini purification plant of the type “immersed aerated bio filter plant” for purifying waste water from households without connection to a sewage system. The plant includes an aerated settling tank (1), a unit for decomposing organic matter (2), a first sludge precipitation unit (5), a nitrification unit (8) and a completing sludge settling unit (5?). The primary settling unit includes means for providing aeration.Type: GrantFiled: September 3, 2002Date of Patent: January 20, 2009Assignee: KWH Pipe (Danmark) ASInventor: Henrik Ulf Hedegaard
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Publication number: 20080290024Abstract: A method for reducing the odors of an anaerobically digested dewatered biosolids or other biosolids or sludge may include separating first anaerobically digested dewatered biosolids into first and second portions, storing second anaerobically digested dewatered biosolids, removing a portion of the second biosolids, and mixing the removed second biosolids portion with the first portion of the first biosolids. The method may be implemented in a system including a separation device, first, second and third transporters, a storage area, and a mixer. The separation device may separate the first biosolids into first and second portions. The first transporter may transport the first portion to the mixer. The second transporter may transport the second portion to the storage area. The storage area may store the second portion for a select time period. The third transporter may transport a portion of the stored first biosolids to the mixer for blending.Type: ApplicationFiled: October 15, 2007Publication date: November 27, 2008Inventor: Todd Owen Williams
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Patent number: 7442353Abstract: A process by which heat is removed from a reactant fluid to reach the operating temperature of a known pollutant removal method and said heat is recirculated to raise the temperature of the product fluid. The process can be utilized whenever an intermediate step reaction requires a lower reaction temperature than the prior and next steps. The benefits of a heat-recirculating cooler include the ability to use known pollutant removal methods and increased thermal efficiency of the system.Type: GrantFiled: October 21, 2004Date of Patent: October 28, 2008Assignee: The United States of America as represented by the United States Department of EnergyInventors: George A. Richards, David A. Berry
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Patent number: 7438877Abstract: Selective, irreversible removal of hydrogen sulfide (H2S) and other sulfhydryl compounds from a gas stream, such as sour natural gas and sour hydrocarbon liquids is achieved with a scavenging agent having hydroxyalkyl functionality and alkylamine functionality. This scavenger possesses a higher capacity for H2S removal compared with a scavenger having only hydroxyalkyl functionality. The scavenging agent is made by reacting at least one alkanolamine and at least one alkyl amine with an aldehyde, such as formaldehyde.Type: GrantFiled: September 1, 2006Date of Patent: October 21, 2008Assignee: Baker Hughes IncorporatedInventors: Tauseef Salma, Alexander A. Lambert, III, Gordon T. Rivers
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Patent number: 7438815Abstract: Lipids, such as plant oils and animal fats, are effective for treatment of animal wastes to inhibit both the emission of ammonia and other odors, and the discharge of particulate matter, microorganisms, and endotoxins, therefrom. Inhibition of ammonia volatilization and particulate or microbial discharge is effected by application of an effective amount of a lipid containing composition onto the animal wastes. Moreover, when used in combination with solutions of salts of acidic proton donors such as aluminum chloride, aluminum nitrate, and alum, these lipids significantly improve the effectiveness of the proton donors to inhibit the release of ammonia and reduce phosphorous solubility.Type: GrantFiled: December 15, 2006Date of Patent: October 21, 2008Assignee: The United States of America as represented by the Secretary of AgricultureInventor: Philip A. Moore, Jr.
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Patent number: 7429329Abstract: A hybrid chemical/mechanical dewatering sewage treatment plant and method employing rapid sludge chemical dewatering technology in conjunction with slower conventional mechanical dewatering solids agglomeration and disposal methods to meet operating constraints and environmental permitting restrictions and siting limitations for disposal of sewage and wastewater.Type: GrantFiled: August 12, 2005Date of Patent: September 30, 2008Assignee: Earth Renaissance Technologies, LLCInventor: Marcus G. Theodore
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Patent number: 7427357Abstract: An object of the present invention is to provide a process for a high-performance upflow anaerobic sludge treatment (methane fermentation treatment) targeting an organic wastewater containing an inorganic sulfur compound and an apparatus therefor. The invention relates to a process for methane fermentation treatment of an organic wastewater containing a sulfur compound, which includes: detecting a concentration of hydrogen sulfide in a biogas generated from a step of methane fermentation treatment; and, conducting a control of subjecting the organic wastewater to a desulfurization treatment operation in the case that the concentration of hydrogen sulfide in the biogas exceeds a predetermined value, and to an apparatus therefor.Type: GrantFiled: July 15, 2004Date of Patent: September 23, 2008Assignee: Ebara CorporationInventors: Kazumasa Kamachi, Yasuhiro Honma, Toshihiro Tanaka, Yuji Tsukamoto
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Patent number: 7419607Abstract: A biofilm resistant fluid handling system is provided having at least one structural component adapted to retain or deliver fluid. The at least one structural component is formed from a biofilm resistant material comprising polymeric resin and an inorganic carrier conjugated with a biocidal metal ion. When a surface of the at least one structural component is exposed to a continuous or intermittent aqueous solution environment the formation of active biofilm on the surface is prevented and planktonic bacteria in proximity of said surface is killed. Additionally, methods for extending the biocidal properties of a biofilm resistant fluid handling system are provided.Type: GrantFiled: April 6, 2004Date of Patent: September 2, 2008Inventor: Bradley Downs
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Patent number: 7416668Abstract: A chemical/biological wastewater treatment plant method and apparatus employing rapid sludge chemical dewatering technology in conjunction with an environmental biological system for treating the separated treated wastewater by land applying it for plant consumption, and/or passing it through aqueous plant or microbial reduction of the dissolved solids and ammonia for BOD compliance to produce water of sufficient quality to meet open stream and ocean effluent discharge requirements; and disposing of the high BTU low moisture solids.Type: GrantFiled: March 27, 2007Date of Patent: August 26, 2008Assignee: Earth Renaissance Technologies, LLCInventor: Marcus G. Theodore
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Patent number: 7410589Abstract: The invention relates to a method of treating manure such that odor from the manure is significantly reduced or eliminated and producing therefrom recyclable water, value-added biosolids and ammonia. Specifically, the manure is combined with lime at high pH. The material is mixed under negative pressure and the basic conditions cause ammonia to be evolved from the manure which is then drawn off and recovered. A coagulating agent is then added which further promotes floc formation within the manure. Following further mixing, flocs are separated from the liquid portion. A struvite-promoting chemical and a coagulant are then added to the liquid portion which causes further floc formation, and the flocs are again separated from the substantially clear liquid. It is of note that as a result of this process, the solids are highly hydrophobic and dry very quickly. It is of further note that solids isolated from either step can be combined and sold, for example, as fertilizer, as discussed below.Type: GrantFiled: July 26, 2002Date of Patent: August 12, 2008Inventor: Gurunathan Lakshman
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Method and apparatus for the methane fermentation treatment of wastewater containing sulfur compound
Patent number: 7374682Abstract: A method and apparatus for the anaerobic methane fermentation treatment of a wastewater containing a sulfur compound. An oxidizing agent is added to an organic wastewater to oxidize the sulfur compound contained therein to molecular sulfur before the anaerobic treatment step. The wastewater is then introduced into the anaerobic treatment step for the methane fermentation treatment thereof. The amount of the oxidizing agent to be added to the wastewater is controlled using as an indicator the concentration of the residual oxidizing agent in the water flowing into the anaerobic treatment step and/or the concentration of hydrogen sulfide in a biogas generated. The oxidizing agent may be ozone, hydrogen peroxide, sodium hypochlorite or a bromine based oxidizing agent. When the concentration of hydrogen sulfide in a biogas generated in the anaerobic treatment step is used as said indicator, the oxidizing agent may be suitably added such that the concentration of hydrogen sulfide is 3% or less.Type: GrantFiled: March 29, 2004Date of Patent: May 20, 2008Assignee: Ebara CorporationInventors: Kazumasa Kamachi, Yasuhiro Honma, Toshihiro Tanaka, Toshio Tsukamoto -
Patent number: 7361283Abstract: Contaminated waste streams or soil or sludge is subjected to a first treatment stage with an acid liquor at a pH below 2 and at a solids content from 5 to 30%; then the liquid and solid phases from the first treatment stage are separated; the solids from the first treatment stage are mixed with a fresh acid liquor at a pH below 2 and a solids content from 5 to 30%; the liquid and solid phases from the second treatment stage are separated; the liquor separated from the first treatment stage is reacted with a base to precipitate the metals; the precipitated metals are separated and the liquor is recycled for reuse in the process; the solids separated from the second treatment stage are neutralized to adjust the pH to a level acceptable for a soil conditioner or fertilizer or other customized products; and the liquor from the second stage is used as the acidic liquor in the first treatment stage.Type: GrantFiled: January 19, 2004Date of Patent: April 22, 2008Assignee: Australian Organic Resources Pty. Ltd.Inventors: Bodo Heller, Christopher Michael Starks
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Patent number: 7320753Abstract: An ambient anaerobic digester system for anaerobic digestion of animal waste with biogas production and recovery is provided. The anaerobic digester system includes a substantially flexible bladder for anaerobically digesting the animal waste with biogas production and transmitting the biogas to at least one biogas storage container, biogas use device or a combination thereof. In a preferred form, the substantially flexible bladder has a waste inlet, a digester effluent outlet, one or more sludge access ports and a biogas outlet in a top surface thereof. The anaerobic digester system may inexpensively, simply, reliably, and effectively be used to treat animal waste without energy expenditure and little capital expense, thus minimizing pollution typically caused by animal waste.Type: GrantFiled: March 5, 2007Date of Patent: January 22, 2008Assignee: The United States of America as represented by the United States Environmental Protection AgencyInventor: Kurt Frederich Roos
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Patent number: 7316782Abstract: A fuel filter for removing fuel impurities, particularly thiophenes, includes a hollow housing having a filter element therein. The filter element includes a substrate, which may include a nonwoven fiber web, a plurality of particles, or both of these. Where particles are used, the substrate may be homogeneous or may be a mixture of different particles. The substrate may include a sorbent selected from the group consisting of metals, metal oxides, metallic salts, organometallic compounds, catalysts, and oxidizing agents. Optionally, a sulfur-treating reactant may be operatively associated with the substrate to reduce the concentration of thiophenes in fuel passing through the filter.Type: GrantFiled: August 13, 2004Date of Patent: January 8, 2008Assignee: Honeywell International, Inc.Inventors: Ronald Paul Rohrbach, Russell Johnson, Peter D. Unger, Gordon William Jones, Damiel E. Bause, Gary B. Zulauf
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Patent number: 7300593Abstract: A process for purifying dry cleaning solvents from a mixture containing used dry cleaning solvents and contaminants, such as laundry soils, fabric treating agents.Type: GrantFiled: June 24, 2004Date of Patent: November 27, 2007Assignee: The Procter & Gamble CompanyInventors: Victor Manuel Arredondo, Mark Robert Sivik, Robb Richard Gardner, Jeffrey Scott Dupont, John Christian Haught, Arseni Valerevich Radomyselski, Jeffrey John Hopkins, William Michael Scheper, Hiroshi Oh
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Patent number: 7300594Abstract: A process for purifying a lipophilic fluid employing a functionalized fabric treating agent. The functionalized fabric treating agent is capable of delivering fabric treating benefits in a non-aqueous fabric article treatment process and is designed for easy removal from the non-aqueous solvent after the fabric article treatment process. Laundry soils can also be removed by this process. The present invention also relates to a fabric treatment composition containing the functionalized fabric treating agent.Type: GrantFiled: June 24, 2004Date of Patent: November 27, 2007Assignee: The Procter & Gamble CompanyInventors: Victor Manuel Arredondo, Mark Robert Sivik, Robb Richard Gardner, Jeffrey Scott Dupont, John Christian Haught, Arseni Valerevich Radomyselski, Jeffrey Jon Hopkins, William Michael Scheper, Hiroshi Oh
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Patent number: 7285217Abstract: A synergistic composition is provided for controlling odor from waste products. The composition comprises a combination of nitrate salt, sulfide-consuming compound, pH-elevating compound, sulfide-oxidizing, nitrate-reducing bacteria, and sulfide-oxidizing enzyme. The method includes adding a sufficient amount of the composition to a waste stream to provide sufficient sulfide-consuming compound to effect immediate removal of sulfide. The composition incorporates a pH elevating compound, which both decreases the amount of gaseous H2S and puts the aqueous phase into a pH range where naturally occurring bacteria can more easily metabolize the sulfide. The composition also includes one or more nitrate salts which will accomplish longer term prevention of odors. Specific bacteria are incorporated into the formulation to insure that the nitrate has the right type and amount of bacteria present to prevent formation of and/or consume sulfide.Type: GrantFiled: November 17, 2004Date of Patent: October 23, 2007Assignee: Siemens Water Technologies Corp.Inventors: Gregory D. Simpson, Glenn W. Holden
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Patent number: 7273561Abstract: An apparatus and method of determining chemical dosage required to reduce sulfides in wastewater includes providing a headspace apart from the wastewater. The temperature of the wastewater and the concentration of sulfide gas in the headspace are measured. Dissolved hydrogen sulfide gas concentrations in the wastewater are calculated from the temperature of the wastewater and the concentration of sulfide gas in said headspace. When pH is monitored, dissolved sulfide concentrations can be calculated.Type: GrantFiled: October 19, 2004Date of Patent: September 25, 2007Assignee: Waitaki Research CorporationInventor: David G Palmer
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Patent number: 7255796Abstract: The present invention relates to a fast acting chemical treatment for preventing the generation of hydrogen sulfide odor by the microbial metabolic activities of sulfate reducing bacteria. Specifically, the invention relates to a method for preventing hydrogen sulfide odor generation in a sulfur species-containing aqueous medium, which includes adding to the aqueous medium an effective amount for the purpose of a sulfide scavenger treatment selected from the group consisting of glyoxal, triazine, n-chlorosuccinimide, and mixtures thereof.Type: GrantFiled: July 8, 2004Date of Patent: August 14, 2007Assignee: General Electric CompanyInventors: Zhuo Chen, Wendy Segal, David B. Ritz, Wilson K. Whitekettle
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Patent number: 7201847Abstract: A method of treating wastewater sources such as sewer systems or those from pulp and paper mills which contain biomass waste involves adding white rot fungi in the presence of glucose. While glucose may be directly added to the wastewater source, it has been found to be more economical to reduce or substantially remove color from the wastewater by additionally adding brown rot fungi in the presence of cellulose and hemi-cellulose. The addition of bacteria has also been found helpful to improve the reduction in color, biological oxygen demand, as well as chemical oxygen demand in wastewater sludge reduction.Type: GrantFiled: January 5, 2005Date of Patent: April 10, 2007Inventors: Michael Bowling, Phil Adams
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Patent number: 7186341Abstract: A method and apparatus for treating wastewater streams by adding, either separately or as a mixture, a nitrate containing compound and an alkaline material in an amount sufficient to achieve a lower concentration of atmospheric hydrogen sulfide and dissolved sulfides downstream of the addition as compared to the atmospheric hydrogen sulfide and dissolved sulfides present in the wastewater stream prior to the addition. By adding alkaline material in addition to a nitrate containing compounds, the amount of nitrate containing compound added can be reduced by at least 10% as compared to the amount of nitrate that would theoretically need to be added in the absence of alkaline material to achieve a comparable lower concentration of atmospheric hydrogen sulfide and dissolved sulfides in the wastewater stream.Type: GrantFiled: April 24, 2006Date of Patent: March 6, 2007Assignee: Siemens Water Technologies Holding Corp.Inventors: David J. Hunniford, David L. Morano, James Paul Harshman
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Patent number: 7179389Abstract: The use of a composition effective in treatments for a waste treatment or sewage system is provided. The process of preparing such composition includes contacting hydrogen peroxide, glycolic acid, and water. The process can additionally include contacting with one or more additional components such as isopropyl alcohol.Type: GrantFiled: February 11, 2005Date of Patent: February 20, 2007Inventor: James E. McClung
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Patent number: 7166227Abstract: A method of treating, in wastewater purification, sludge containing organic matter, divalent iron and phosphorus, in which the sludge that is treated is made to contain dissolved iron and phosphorus at a molar ratio Fe:P of above 1:1, the sludge is treated at 0–100° C. with an acid at a pH of 1–5 for dissolution of divalent iron and phosphorus from the sludge, the sludge is supplied with an oxidizer selected from hydrogen peroxide and percompounds, wherein divalent iron is oxidized by Fenton's reaction to trivalent iron, and (i) trivalent iron is precipitated as trivalent iron phosphate (ii) free radicals with a deodorization and sanitation effect are formed by Fenton's reaction, the sludge is then dewatered at a pH of at most 7, and the aqueous solution obtained in dewatering is recirculated to the wastewater purification.Type: GrantFiled: April 22, 2004Date of Patent: January 23, 2007Assignee: Kemira Kemi ABInventors: Göran Karlsson, Ingemar Karsson, Lennart Pettersson, Michael Recktenwald
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Patent number: 7163629Abstract: Enhanced wastewater treatment utilizing directed energy to promote degradation of sludge is disclosed. The directed energy is delivered in a stream circulating to and from an anaerobic digester. The directed energy incorporates mechanical shear energy, ultrasonic energy, and/or hydraulic shear energy. Characterization of odor potential is further disclosed involving the analyzing volatilized sulfur-containing species from dewatered sludge. The odor potential can be used to control operation of the wastewater treatment by controlling the directed energy and/or polymer dose.Type: GrantFiled: July 28, 2004Date of Patent: January 16, 2007Assignee: Virginia Tech Intellectual Properties, Inc.Inventors: Mohammad Abu-Orf, Charles D. Blumenschein, John T. Novak, Christopher D. Muller, Mark Laquidara
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Patent number: 7160712Abstract: Disclosed herein is a method for treating odors in wastewater treatment bodies. The pH of the body is preferably established above about 6 and most preferably above about 7, usually by adding a base to the body. The oxidation reduction potential of the body is established at about ?300 mV or higher and more preferably about ?200 mV or higher, usually by adding an oxidizing agent such as oxygen or nitrates. After these conditions are established, sulfur oxidizing bacteria are added to the body. These preferably include Paracoccus denitrificans (formerly called Thiosphaera pantotropha) ATTC number 35,512. The sulfur oxidizing bacterial population should be established at levels of at least about 1×104 cfu/mL and more preferably at levels of 1×105 to 1×106 cfu/mL or higher. The increased ORP and pH levels make sulfate reduction thermodynamically unfavorable. Additionally, the presence of an alternative electron acceptor such as oxygen or nitrate allows the sulfur oxidizing bacteria to oxidize organic acids.Type: GrantFiled: August 29, 2002Date of Patent: January 9, 2007Assignee: Novozymes A/SInventor: John A. Christiansen
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Patent number: 7140433Abstract: A new class of sulfur scavenging or converting compositions is disclosed comprising diamine terminated, amine-aldehyde adducts, where the adducts are substantially bimolecular amine-aldehyde adducts and the composition is substantially free of trimer and/or triazines. Methods for making and using the new class of sulfur scavenging or converting composition are also disclosed.Type: GrantFiled: December 12, 2003Date of Patent: November 28, 2006Assignee: Clearwater International, LLCInventors: Larry W. Gatlin, Daniel R. Dostie, Timothy Eric Gatlin
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Patent number: 7138049Abstract: A method and apparatus for treating wastewater streams by adding, either separately or as a mixture, a nitrate containing compound and an alkaline material in an amount sufficient to achieve a lower concentration of atmospheric hydrogen sulfide and dissolved sulfides downstream of the addition as compared to the atmospheric hydrogen sulfide and dissolved sulfides present in the wastewater stream prior to the addition. By adding alkaline material in addition to a nitrate containing compounds, the amount of nitrate containing compound added can be reduced by at least 10% as compared to the amount of nitrate that would theoretically need to be added in the absence of alkaline material to achieve a comparable lower concentration of atmospheric hydrogen sulfide and dissolved sulfides in the wastewater stream.Type: GrantFiled: July 7, 2005Date of Patent: November 21, 2006Assignee: USFilter CorporationInventors: David J. Hunniford, David L. Morano, James Paul Harshman