Containing Nickel, Chromium, And Iron Patents (Class 219/146.23)
  • Patent number: 11634804
    Abstract: Provided is an austenitic stainless steel weld joint that is excellent in polythionic acid SCC resistance and naphthenic acid corrosion resistance, and is also excellent in creep ductility. An austenitic stainless steel weld joint includes a base material and a weld metal. The weld metal has a chemical composition at its width-center position and at its thickness-center position consisting of, in mass %, C: 0.050% or less, Si: 0.01 to 1.00%, Mn: 0.01 to 3.00%, P: 0.030% or less, S: 0.015% or less, Cr: 15.0 to 25.0%, Ni: 20.0 to 70.0%, Mo: 1.30 to 10.00%, Nb: 0.05 to 3.00%, N: 0.150% or less, and B: 0.0050% or less, with the balance: Fe and impurities.
    Type: Grant
    Filed: February 28, 2019
    Date of Patent: April 25, 2023
    Assignee: NIPPON STEEL CORPORATION
    Inventors: Kana Jotoku, Kenta Yamada, Hirokazu Okada, Takahiro Osuki
  • Patent number: 10821559
    Abstract: An electrode in which the metallurgical structure of the active surface includes incoherent chromium precipitates, more than 90% of which have a surface of projection of less than 1 ?m2, the incoherent chromium precipitates having a size at least between 10 and 50 nm. The electrode further has a fibrous structure that is visible in a cross-section of the active surface of the electrode following surfacing and chemical etching. The fibrous structure includes a plurality of radial fibers having a thickness of less than 1 mm and of a substantially central fiberless region that has a diameter of less than 3 mm. The electrical conductivity of the electrode is greater than 85% IUPAC. The method for obtaining the electrode in a continuous casting process as well as to a use of the electrode in a resistive spot welding process.
    Type: Grant
    Filed: February 10, 2016
    Date of Patent: November 3, 2020
    Assignee: LEBRONZE ALLOYS
    Inventors: Nicolas Francois, Thierry Soreau, Francois Primaux
  • Patent number: 9821401
    Abstract: Weld metals and methods for welding ferritic steels are provided. The weld metals have high strength and high ductile tearing resistance and are suitable for use in strain based pipelines. The weld metal contains retained austenite and has a cellular microstructure with cell walls containing lath martensite and cell interiors containing degenerate upper bainite. The weld metals are comprised of between 0.02 and 0.12 wt % carbon, between 7.50 and 14.50 wt % nickel, not greater than about 1.00 wt % manganese, not greater than about 0.30 wt % silicon, not greater than about 150 ppm oxygen, not greater than about 100 ppm sulfur, not greater than about 75 ppm phosphorus, and the balance essentially iron. Other elements may be added to enhance the properties of the weld metal. The weld metals are applied using a power source with current waveform control which produces a smooth, controlled welding arc and weld pool in the absence of CO2 or oxygen in the shielding gas.
    Type: Grant
    Filed: December 12, 2011
    Date of Patent: November 21, 2017
    Assignee: ExxonMobil Upstream Research Company
    Inventors: Douglas P. Fairchild, Mario L. Macia, Steven J. Ford, Nathan E. Nissley, Raghavan Ayer, Hyun-Woo Jin, Adnan Ozekcin
  • Patent number: 9707643
    Abstract: The invention relates generally to welding and, more specifically, to welding wires for arc welding, such as Gas Metal Arc Welding (GMAW) or Flux Core Arc Welding (FCAW). In one embodiment, a tubular welding wire includes a sheath and a core. Further, the core includes a carbon source and an agglomerate having a Group I or Group II compound, silicon dioxide, and titanium dioxide. Additionally, the carbon source and the agglomerate together comprise less than 10% of the core by weight.
    Type: Grant
    Filed: April 4, 2013
    Date of Patent: July 18, 2017
    Assignee: HOBART BROTHERS COMPANY
    Inventors: Steven Edward Barhorst, Mario Anthony Amata
  • Patent number: 8992698
    Abstract: Provided is a welding metal in which the chemical component composition thereof is appropriately controlled; an A value that is specified by a predetermined relational expression satisfies the requirement of being 3.8% to 9.0%; an X value that is specified by a predetermined relational expression satisfies the requirement of being 0.5% or greater; the area percentage of carbide particles having a circle-equivalent diameter of 0.20 ?m or greater in the welding metal is 4.0% or less; and the number of carbide particles having a circle-equivalent diameter of 1.0 ?m or greater is 1000 particles/mm2 or less. This welding metal, which can exhibit not only high strength but also good low-temperature toughness and good drop-weight characteristics, is useful as a material for a pressure vessel in a nuclear power plant.
    Type: Grant
    Filed: April 8, 2011
    Date of Patent: March 31, 2015
    Assignee: Kobe Steel. Ltd.
    Inventors: Hidenori Nako, Yoshitomi Okazaki, Ken Yamashita, Minoru Otsu, Hideaki Takauchi
  • Patent number: 8973806
    Abstract: A class of nickel based alloys having a fine grain structure resistant to stress corrosion cracking, and methods of alloy design to produce further alloys within the class are presented. The alloys act as suitable welding materials in similar applications to that of Alloy 622. The fine-grained structure of these novel alloys may also be advantageous for other reasons as well such as wear, impact, abrasion, corrosion, etc. These alloys have similar phases to Alloy 622 in that they are composed primarily of austenitic nickel, however the phase morphology is a much finer grained structure opposed to the long dendritic grains common to Alloy 622 when it is subject to cooling rates from a liquid state inherent to the welding process.
    Type: Grant
    Filed: December 20, 2013
    Date of Patent: March 10, 2015
    Assignee: Scoperta, Inc.
    Inventor: Justin Lee Cheney
  • Patent number: 8975559
    Abstract: Methods for forming an aluminum weld on an aluminum work surface are disclosed. The methods include providing an aluminum metal-core wire having a sheath with an outer surface and a core composition within the sheath, applying a voltage to the aluminum metal-core wire in the vicinity of the aluminum work surface to generate an arc, and melting the wire and the work surface to form the weld. The sheath is formed with an inorganic lubricant on its outer surface and the core composition includes metal powders, metal alloy powders, or combinations thereof and less than about 5% of non-metallic components or non-metallic agents based on the weight of the wire.
    Type: Grant
    Filed: September 13, 2004
    Date of Patent: March 10, 2015
    Assignee: Hobart Brothers Company
    Inventors: James M. Keegan, Sundaram Nagarajan, Sushil R. Jana
  • Publication number: 20150060413
    Abstract: A method of depositing a corrosion resistant material via a plasma transferred wire arc (PTWA) thermal spray method on the cylinder surface of heavy duty diesel internal combustion engines. The PTWA process uses a stainless steel hollow core wire that is filled with a metal oxide or carbide powder. The powder can be 100% chromium carbide.
    Type: Application
    Filed: September 4, 2014
    Publication date: March 5, 2015
    Applicant: MAHLE INDUSTRIES, INC.
    Inventor: Thomas SMITH
  • Patent number: 8932415
    Abstract: Provided is a welding metal in which a predetermined chemical component composition is satisfied, the A value as specified by formula (1) is 3.8% to 9.0%, and the surface area percentage of carbide having a circle-equivalent diameter of 0.20 ?m or greater in the welding metal is 4.0% or less. A value=0.8×[C]?0.05×[Si]+0.5×[Mn]+0.5×[Cu]+[Ni]?0.5×[Mo]+0.2×[Cr]??(1) (Provided that [C], [Si], [Mn], [Cu], [Ni], [Mo] and [Cr] are the C, Si, Mn, Cu, Ni, Mo and Cr content (by mass percent), respectively) The welding metal is useful as a material for a pressure vessel of a nuclear power plant as the welding metal is high in strength and has good low-temperature toughness and drop-weight characteristics.
    Type: Grant
    Filed: January 24, 2011
    Date of Patent: January 13, 2015
    Assignee: Kobe Steel, Ltd.
    Inventors: Hidenori Nako, Yoshitomi Okazaki, Ken Yamashita, Minoru Otsu, Hideaki Takauchi
  • Publication number: 20140349136
    Abstract: The present disclosure relates generally to welding alloys and, more specifically, to welding consumables (e.g., welding wires and rods) for arc welding operations. In an embodiment, a welding consumable includes less than approximately 1 wt % manganese as well as one or more strengthening agents selected from the group: nickel, cobalt, copper, carbon, molybdenum, chromium, vanadium, silicon, and boron. The welding consumable also includes one or more grain control agents selected from the group: niobium, tantalum, titanium, zirconium, and boron, wherein the welding consumable includes less than approximately 0.6 wt % grain control agents. Additionally, the welding consumable has a carbon equivalence (CE) value that is less than approximately 0.23. The welding consumable is designed to provide a manganese fume generation rate that is less than approximately 0.01 grams per minute during a welding operation.
    Type: Application
    Filed: August 12, 2014
    Publication date: November 27, 2014
    Inventors: Steven Edward Barhorst, Kevin M. Krieger, Joseph C. Bundy, Mario Anthony Amata, Daryl L. Duncan, Susan Renata Fiore
  • Publication number: 20140332517
    Abstract: The present disclosure relates generally to welding alloys and, more specifically, to welding consumables (e.g., welding wires and rods) for welding, such as Gas Metal Arc Welding (GMAW), Gas Tungsten Arc Welding (GTAW), Shielded Metal Arc Welding (SMAW), and Flux Core Arc Welding (FCAW). In an embodiment, a welding alloy includes less than approximately 1 wt % manganese as well as one or more strengthening agents selected from the group: nickel, cobalt, copper, carbon, molybdenum, chromium, vanadium, silicon, and boron. Additionally, the welding alloy has a carbon equivalence (CE) value that is less than approximately 0.23, according to the Ito and Bessyo carbon equivalence equation. The welding alloy also includes one or more grain control agents selected from the group: niobium, tantalum, titanium, zirconium, and boron, wherein the welding alloy includes less than approximately 0.6 wt % grain control agents.
    Type: Application
    Filed: April 30, 2014
    Publication date: November 13, 2014
    Applicant: HOBART BROTHERS COMPANY
    Inventors: Steven Edward Barhorst, Kevin M. Krieger, Joseph C. Bundy, Mario Anthony Amata, Daryl L. Duncan, Susan Renata Fiore
  • Patent number: 8878099
    Abstract: The present invention provides flux cored wire for welding duplex stainless steel which refines the solidified crystal grains for obtaining weld metal superior in toughness and ductility, characterized by containing, as the chemical ingredients included in the steel sheath and flux, by mass % with respect to the mass of the wire as a whole, C: 0.001 to 0.1%, Si: 0.01 to 1.0%, Mn: 2.0 to 6.0%, Cr: 17.0 to 27.0%, Ni: 1.0 to 10.0%, Mo: 0.1 to 3.0%, Al: 0.002 to 0.05%, Mg: 0.0005 to 0.01%, Ti: 0.001 to 0.5%, and N: 0.10 to 0.30%, further limiting P to 0.03% or less and S to 0.01% or less, satisfying 0.73×Cr equivalents?Ni equivalents?4.0 and Ti (mass %)×N (mass %)?0.0004, and having a balance of iron and unavoidable impurities.
    Type: Grant
    Filed: May 27, 2009
    Date of Patent: November 4, 2014
    Assignee: Nippon Steel & Sumikin Stainless Steel Corporation
    Inventors: Hiroshige Inoue, Manabu Mizumoto, Takashi Namekata, Yusuke Oikawa
  • Publication number: 20140286698
    Abstract: There is provided a welding material used for welding of SUS310 stainless steel base metal that contains at least one of Nb and V and is excellent in intergranular corrosion resistance, the chemical composition of the welding material consisting, by mass percent, of C: 0.02% or less, Si: 2% or less, Mn: 2% or less, Cr: 26 to 50%, N: 0.15% or less, P: 0.02% or less, S: 0.002% or less, and Ni: a content percentage satisfying [5?Ni?Cr?14], and the balance of Fe and impurities. Also, there is provided a welding joint of an austenitic stainless steel, which consists of the base metal and a weld metal formed by using the welding material.
    Type: Application
    Filed: May 11, 2012
    Publication date: September 25, 2014
    Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Takahiro Osuki, Kiyoko Takeda, Tetsuo Yokoyama, Hiroyuki Anada, Masatoshi Toyoda
  • Publication number: 20140263248
    Abstract: Various embodiments of a metal cored wires and methods are disclosed. In one embodiment of the present invention, a metal cored wire comprises a metal sheath and a metal-powder core material comprising manganese particles. The manganese particles are coated with a coating material to reduce the manganese fumes and exposure during welding.
    Type: Application
    Filed: March 14, 2014
    Publication date: September 18, 2014
    Applicant: Postle Industries, Inc.
    Inventor: Christopher J. Postle
  • Patent number: 8765052
    Abstract: Weld deposit compositions with improved abrasion and corrosion resistance are provided by balancing percent weights of Chromium (Cr), Titanium (Ti), Niobium (Nb), and Boron (B) to allow the Chromium content of the weld matrix to be minimally reduced during carbide formation. The result is an enriched Chromium matrix that has excellent corrosion resistance in combination with highly abrasion resistant dispersed carbides.
    Type: Grant
    Filed: March 27, 2012
    Date of Patent: July 1, 2014
    Assignee: Stoody Company
    Inventors: Jack Wallin, Ravi Menon, Tim Barnhart
  • Patent number: 8729418
    Abstract: A method produces a welded connection between first and second components each having inner and outer sides interconnected by an end face. The first component has a ferritic basic body carrying a plating at the inside and having an end face with a buffer layer of Ni-based alloy. The second component is of austenitic material. The end faces of the components enclose a weld groove. An austenitic root, connecting the plating to the end face of the second component, is welded in the weld groove. An intermediate layer of a nickel alloy having at least 90% nickel is welded onto the root. The intermediate layer is connected to the end faces of the plating and the second component. A weld seam is then produced in the remaining weld groove using a nickel-based welding additive. A method for repairing a welded connection between first and second components is also provided.
    Type: Grant
    Filed: June 4, 2012
    Date of Patent: May 20, 2014
    Assignee: Areva GmbH
    Inventors: Erhard Brueckner, Gerhard Engelhard, Siegried Guegel
  • Publication number: 20140131338
    Abstract: Various embodiments of a metal cored wires, hardband alloys, and methods are disclosed. In one embodiment of the present invention, a hardbanding wire comprises from about from about 16% to about 30% by weight chromium; from about 4% to about 10% by weight nickel; from about 0.05% to about 0.8% by weight nitrogen; from about 1% to about 4% by weight manganese; from about 1% to about 4% by weight carbon from about 0.5% to about 5% by weight molybdenum; from about 0.25% to about 2% by weight silicon; and the remainder is iron including trace elements. The hardband alloy produced by the metal cored wire meets API magnetic permeability specifications and has improved metal to metal, adhesive wear resistance compared to conventional hardband alloys.
    Type: Application
    Filed: November 12, 2013
    Publication date: May 15, 2014
    Applicant: Postle Industries, Inc.
    Inventor: Christopher J. Postle
  • Patent number: 8704135
    Abstract: A welding system is disclosed for performing a short arc welding process between an advancing wire electrode and a workpiece. The system comprises a power source with a controller for creating a current pulse introducing energy into the electrode to melt the end of the electrode and a low current quiescent metal transfer section following the end of the melting pulse during which the melted electrode short circuits against the workpiece; a timer to measure the actual time between the end of the pulse and the short circuit; a device for setting a desired time from the pulse to the short circuit; a circuit to create a corrective signal based upon the difference between the actual time and the desired time; and, a circuit responsive to the corrective signal to control a given parameter of the current pulse. Also disclosed is a strategy for arc welding utilizing a cored electrode that produces welds with low levels of contaminants and which are strong, tough, and durable.
    Type: Grant
    Filed: January 20, 2006
    Date of Patent: April 22, 2014
    Assignee: Lincoln Global, Inc.
    Inventors: Badri K. Narayanan, Russell K. Myers, Patrick T. Soltis
  • Patent number: 8629374
    Abstract: A cored electrode having reduced moisture pick-up properties and which forms a weld bead with low diffusible hydrogen in a gas shielded electric arc welding process. The cored electrode includes a metal sheath and a fill composition. The fill composition includes titanium dioxide, slag forming agent and a sodium-silica-titanate compound.
    Type: Grant
    Filed: April 5, 2005
    Date of Patent: January 14, 2014
    Assignee: Lincoln Global, Inc.
    Inventor: Rajeev Katiyar
  • Patent number: 8623154
    Abstract: An electron-beam welded joint including, by mass %, C: 0.02% to 0.1%, Si: 0.03% to 0.30%, Mn: 1.5% to 2.5%, Ti: 0.005 to 0.015%, N: 0.0020 to 0.0060%, O: 0.0010% to 0.0035%, Nb: 0% to 0.020%, V: 0% to 0.030%, Cr: 0% to 0.50%, Mo: 0% to 0.50%, Cu: 0% to 0.25%, Ni: 0% to 0.50%, B: 0% to 0.0030%, S: limited to 0.010% or less, P: limited to 0.015% or less, Al: limited to 0.004% or less, and a balance consisting of iron and unavoidable impurities, wherein an index value CeEB is 0.49% to 0.60%, a number of oxides having an equivalent circle diameter of 1.0 ?m or more is 20 pieces/mm2 or less, and a number of oxides having an equivalent circle diameter of 0.05 ?m or more and less than 0.5 ?m is 1×103 pieces/mm2 to 1×105 pieces/mm2 at a thickness center portion.
    Type: Grant
    Filed: October 27, 2011
    Date of Patent: January 7, 2014
    Assignee: Nippon Steel & Sumitomo Metal Corporation
    Inventors: Ryuichi Honma, Ryuji Uemori, Tadashi Ishikawa, Akihiko Kojima, Manabu Hoshino
  • Publication number: 20130306602
    Abstract: A weld metal contains Cr: 28.0% to 31.5% by mass, Fe: 7.0% to 11.0% by mass, Nb and Ta: 1.5% to 2.5% by mass in total, C: 0.015% to 0.040% by mass, Mn: 0.5% to 4.0% by mass, N: 0.005% to 0.080% by mass, Si: 0.70% by mass or less (and more than 0%), Al: 0.50% by mass or less, Ti: 0.50% by mass or less, Mo: 0.50% by mass or less, Cu: 0.50% by mass or less, B: 0.0010% by mass or less, Zr: 0.0010% by mass or less, Co: 0.10% by mass or less, P: 0.015% by mass or less, and S: 0.015% by mass or less, the remainder being Ni and incidental impurities.
    Type: Application
    Filed: March 15, 2013
    Publication date: November 21, 2013
    Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)
    Inventor: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)
  • Publication number: 20130292362
    Abstract: Weld metals and methods for welding ferritic steels are provided. The weld metals have high strength and high ductile tearing resistance and are suitable for use in strain based pipelines. The weld metal contains retained austenite and has a cellular microstructure with cell walls containing lath martensite and cell interiors containing degenerate upper bainite. The weld metals are comprised of between 0.02 and 0.12 wt % carbon, between 7.50 and 14.50 wt % nickel, not greater than about 1.00 wt % manganese, not greater than about 0.30 wt % silicon, not greater than about 150 ppm oxygen, not greater than about 100 ppm sulfur, not greater than about 75 ppm phosphorus, and the balance essentially iron. Other elements may be added to enhance the properties of the weld metal. The weld metals are applied using a power source with current waveform control which produces a smooth, controlled welding arc and weld pool in the absence of CO2 or oxygen in the shielding gas.
    Type: Application
    Filed: December 12, 2011
    Publication date: November 7, 2013
    Inventors: Douglas P. Fairchild, Mario L. Macia, Steven J. Ford, Nathan E. Nissley, Raghavan Ayer, Hyun-Woo Jin, Adnan Ozekcin
  • Publication number: 20130294819
    Abstract: Weld deposit compositions with improved crack resistance, improved wear resistance, and improved hardness are provided by controlling matrix grain size and balancing Titanium and/or Niobium with Carbon and/or Boron content. Additionally, the presence of coarse chromium carbides is drastically decreased to reduce the amount of check-cracking. Preferably, the weld deposit is produced from a flux-cored or metal-cored wire. The weld deposit characteristics include a matrix having a fine grain size, small evenly dispersed carbides within the matrix, and a small amount of Carbon in the matrix.
    Type: Application
    Filed: July 1, 2013
    Publication date: November 7, 2013
    Inventors: Ravi Menon, Jack Garry Wallin, Francis Lewis LeClaire
  • Patent number: 8574381
    Abstract: To provide weld metal that has a high strength and toughness in the as-welded condition or in the annealed condition. The weld metal of the present invention contains by weight %, C: 0.04-0.15%, Si: 0.50% or less, Mn: 1.0-1.9%, Ni: 1.0-4.0%, Cr: 0.10-1.0%, Mo: 0.20 to 1.2%, Ti: 0.010-0.060%, Al: 0.030% or less, O: 0.15-0.060%, N: 0.010% or less, Fe and inevitable impurities as the remaining contents. The weld metal is further characterized by the fact that the ratio of Ti content (%) to Si content (%) i.e., [compound type Ti]/[compound type Si] is more than 1.5, and the number A defined by the following formula is 0.50 or more, wherein A=[Ti]/([O]?1.1×[Al]+0.05×[Si]).
    Type: Grant
    Filed: March 25, 2010
    Date of Patent: November 5, 2013
    Assignee: Kobe Steel, Ltd.
    Inventors: Hidenori Nako, Yoshitomi Okazaki, Ken Yamashita, Hideaki Takauchi, Minoru Otsu
  • Patent number: 8568901
    Abstract: An alloy for use as a welding overlay for boiler tubes in a low NOx coal-fired boiler comprising in % by weight: 36 to 43% Cr, 0.2 to 5.0% Fe, 0-2.0% Nb, 0-1% Mo, 0.3 to 1% Ti, 0.5 to 2% Al, 0.005 to 0.05% C, 0.005 to 0.020% (Mg+Ca), 0-1% Mn, 0-0.5% Si, less than 0.01% S, balance substantially Ni and trace additions and impurities. The alloy provides exceptional coal ash corrosion resistance in low partial pressures of oxygen. The alloy also increases in hardness and in thermal conductivity at service temperature over time. The increased hardness improves erosion resistance of the tubes while the increased thermal conductivity improves the thermal efficiency of the boiler and its power generation capabilities.
    Type: Grant
    Filed: November 19, 2007
    Date of Patent: October 29, 2013
    Assignee: Huntington Alloys Corporation
    Inventors: Samuel D. Kiser, Brian A. Baker
  • Patent number: 8562759
    Abstract: Disclosed herein are iron-based alloys having a structure comprising fine-grained ferritic matrix and having a 60+ Rockwell C surface, wherein the ferritic matrix comprises <10 ?m Nb and W carbide precipitates. Also disclosed are methods of welding comprising forming a crack free hardbanding weld overlay coating with such an iron-based alloy. Also disclosed are methods of designing an alloy capable of forming a crack free hardbanding weld overlay, the methods comprising the step determining an amorphous forming epicenter composition, determining a variant composition having a predetermined change in constituent elements from the amorphous forming epicenter composition, and forming and analyzing an alloy having the variant composition.
    Type: Grant
    Filed: September 17, 2010
    Date of Patent: October 22, 2013
    Assignee: Scoperta, Inc.
    Inventors: Justin Lee Cheney, John Hamilton Madok
  • Patent number: 8563897
    Abstract: Provided is a welding wire and method for manufacturing a welding wire providing for quality welds on 300 series stainless steel and similar materials. A metal powder core is encapsulated in a metal sheath. The metal sheath composition comprising up to about 6% nickel, by weight, and may correspond to a series 400 stainless steel. A combination of the metal sheath and the metal powder core provides an overall alloy content of a series 300 stainless steel.
    Type: Grant
    Filed: April 30, 2007
    Date of Patent: October 22, 2013
    Assignee: Illinois Tool Works Inc.
    Inventors: Daryl L. Duncan, Robert Rutherford
  • Patent number: 8562760
    Abstract: Disclosed herein are iron-based alloys having a microstructure comprising a fine-grained ferritic matrix and having a 60+ Rockwell C surface, wherein the ferritic matrix comprises <10 ?m Nb and W carbide precipitates. Also disclosed are methods of welding comprising forming a crack free hardbanding weld overlay coating with such an iron-based alloy. Also disclosed are methods of designing an alloy capable of forming a crack free hardbanding weld overlay, the methods comprising the steps of determining an amorphous forming epicenter composition, determining a variant composition having a predetermined change in constituent elements from the amorphous forming epicenter composition, and forming and analyzing an alloy having the variant composition.
    Type: Grant
    Filed: November 3, 2010
    Date of Patent: October 22, 2013
    Assignee: Scoperta, Inc.
    Inventors: Justin Lee Cheney, John Hamilton Madok
  • Patent number: 8530791
    Abstract: This disclosure provides a joining area and method between copper and stainless steel or titanium, as well as the permanent cathode obtained, where said joining area is made of a first zone of a copper-nickel (Cu—Ni) alloy, an intermediate zone with a mostly nickel alloy or pure nickel and a second zone made of a stainless steel-nickel alloy, which is the result of the participating materials being cast in an arc welding process, for example TIG, MIG or manual arc using electrodes of nickel as welding contributor between said materials and their space arrangement, that is to say, leaving a separation between the materials when performing the welding process, thus ensuring as follows: a) greater tensile strength, b) a substantial improvement of corrosion resistance of the joint welding, and c) improvement of conductibility, which can be improved still further by modifying the straight design of the conducting bar by providing it with the “horn”-type shape.
    Type: Grant
    Filed: September 11, 2009
    Date of Patent: September 10, 2013
    Assignee: Industria Proveedora de Partes Metalurgicas Limitada
    Inventors: Antonio Carracedo Rosende, Horacio Rafart Mouthon
  • Patent number: 8466389
    Abstract: A method for producing superalloy weld wire and weld wire having fewer inclusions, and specifically fewer hafnia inclusions, and superalloy weld wire, particularly hafnium-containing superalloy weld wire, produced by this method. The method includes producing directionally solidified cast rod in a diameter of less than about ½ inch. The rod preferably is produced by investment casting or by continuous casting. The directional solidification process results in rod having inclusions such as oxides and dirt segregated into portions of the casting where they are easily removed. The cast rod can then be formed into semi-finished weld wire using a single extrusion step, followed by grinding to the final required diameter.
    Type: Grant
    Filed: February 20, 2003
    Date of Patent: June 18, 2013
    Assignee: General Electric Company
    Inventor: Russell Wayne Smashey
  • Patent number: 8343419
    Abstract: An object of the present invention is to provide a Ni base alloy solid wire for welding, which has excellent cracking resistance to ductility dip cracking in weld metal, can increase the tensile strength of the weld metal to not less than the tensile strength of the base material, and has excellent weldability. The present invention provides a solid wire which has a composition containing Cr: 27.0 to 31.5 mass %, Ti: 0.50 to 0.90 mass %, Nb: 0.40 to 0.70 mass %, Ta: 0.10 to 0.30 mass %, C: 0.010 to 0.030 mass %, and Fe: 5.0 to 11.0 mass %, and is regulated to Al: 0.10 mass % or less, N: 0.020 mass % or less, Zr 0.005 mass % or less, P:0.010 mass % or less, S: 0.0050 mass % or less, Si: 0.50 mass % or less, and Mn: 1.00 mass % or less, with the balance including Ni and inevitable impurities.
    Type: Grant
    Filed: February 8, 2011
    Date of Patent: January 1, 2013
    Assignee: Kobe Steel, Ltd.
    Inventors: Tetsunao Ikeda, Masaki Shimamoto, Shun Izutani, Hiroaki Kawamoto, Yushi Sawada, Hirohisa Watanabe
  • Patent number: 8294065
    Abstract: A stainless steel wire having a flux core for welding zinc-based alloy coated steel sheet having an outer metal sheath coating a core of flux wherein in total having in mass (%) as percentage to the total mass of the wire: C: 0.01-0.05%, Si: 0.1-1.5%, Mn: 0.5-3.0%, Ni: 7.0-10.0%, Cr: 26.0-30.0%, wherein an F value defined as a function of the above components ranges from 30 to 50, the flux further having a slag formation agent in mass (%) as percentage to the total mass of the wire: TiO2: 0.6-2.6%, SiO2: 1.8-3.8%, ZrO2: 1.0-3.5%, and optionally Al2O3: 0.1-1.0%, wherein the slag formation agent in total is less than 10%, and the wire further containing Fe and residual impurities.
    Type: Grant
    Filed: July 4, 2007
    Date of Patent: October 23, 2012
    Assignee: Nippon Steel Corporation
    Inventors: Manabu Mizumoto, Shinji Kodama, Kenichi Asai
  • Patent number: 8287805
    Abstract: The present invention relates an iron based brazing material comprising an alloy consisting essentially of: 15 to 30 wt % chromium (Cr); 0 to 5.0 wt % manganese (Mn); 15 to 30 wt % nickel (Ni); 1.0 to 12 wt % molybdenum (Mo); 0 to 4.0 wt % copper (Cu); 0 to 1.0 wt % nitrogen (N); 0 to 20 wt % silicone (Si); 0 to 2.0 wt % boron (B); 0 to 16 wt % phosphorus (P); optionally 0.0 to 2.5 wt % of each of one or more of elements selected from the group consisting of carbon (C), vanadium (V), titanium (Ti), tungsten (W), aluminum (Al), niobium (Nb), hafnium (Hf), and tantalum (Ta); the alloy being balanced with Fe, and small inevitable amounts of contaminating elements; and wherein Si, B and P are in amounts effective to lower melting temperature, and Si, B, and P are contained in amounts according to the following formula: Index=wt % P+1.1×wt % Si+3×wt % B, and the value of the Index is within the range of from about 5 wt % to about 20.
    Type: Grant
    Filed: November 14, 2007
    Date of Patent: October 16, 2012
    Assignee: Alfa Laval Corporate AB
    Inventor: Per Sjödin
  • Patent number: 8258432
    Abstract: Welds made in TRIP steel workpieces by non-autogenous welding techniques can be made to approximate both the composition and microstructure of the TRIP steel being welded by formulating the weld to have controlled amounts of ? phase (austenite) stabilizers and cementite suppressors.
    Type: Grant
    Filed: March 4, 2009
    Date of Patent: September 4, 2012
    Assignee: Lincoln Global, Inc.
    Inventor: Badri K. Narayanan
  • Patent number: 8217295
    Abstract: A method produces a welded connection between first and second components each having inner and outer sides interconnected by an end face. The first component has a ferritic basic body carrying a plating at the inside and having an end face with a buffer layer of Ni-based alloy. The second component is of austenitic material. The end faces of the components enclose a weld groove. An austenitic root, connecting the plating to the end face of the second component, is welded in the weld groove. An intermediate layer of a nickel alloy having at least 90% nickel is welded onto the root. The intermediate layer is connected to the end faces of the plating and the second component. A weld seam is then produced in the remaining weld groove using a nickel-based welding additive. A method for repairing a welded connection between first and second components is also provided.
    Type: Grant
    Filed: October 31, 2007
    Date of Patent: July 10, 2012
    Assignee: Areva NP GmbH
    Inventors: Erhard Brückner, Gerhard Engelhard, Siegfried Gügel
  • Publication number: 20120152928
    Abstract: The invention relates to an auxiliary material for soldering steel sheets, wherein the auxiliary material comprises weight percentages of 15 to 40% Zn, 5 to 30% Mn, 0.01 to 10% Ni, and typical impurities no greater than 1%, and the remainder Cu.
    Type: Application
    Filed: July 5, 2010
    Publication date: June 21, 2012
    Inventor: Eberhard Schmid
  • Patent number: 8187725
    Abstract: A nickel, chromium, iron alloy and method for use in producing weld deposits and weldments formed therefrom. The alloy comprises, in weight percent, about 28.5 to 31.0% chromium; about 0 to 16% iron; less than about 1.0% manganese; about 2.1 to 4.0% niobium plus tantalum; 1.0 to 6.5% molybdenum; less than 0.50% silicon; 0.01 to 0.35% titanium; 0 to 0.25% aluminum; less than 1.0% copper; less than 1.0% tungsten; less than 0.5% cobalt; less than about 0.10% zirconium; less than about 0.01% sulfur; less than 0.01% boron; less than 0.03% carbon; less than about 0.02% phosphorous; 0.002 to 0.015% magnesium plus calcium; and balance nickel and incidental impurities. The method includes the steps of forming a welding electrode from the above alloy composition and melting the electrode to form a weld deposit. A preferred weldment may be in the form of a tubesheet of a nuclear reactor.
    Type: Grant
    Filed: July 19, 2007
    Date of Patent: May 29, 2012
    Assignees: Huntington Alloys Corporation, Areva NP Inc.
    Inventors: Samuel D. Kiser, Brian A. Baker, David E. Waskey
  • Patent number: 8168922
    Abstract: A cored electrode to form a high manganese metal deposition that includes at least about 4 weight percent manganese and at least about 10 weight percent chromium which is useful in joining dissimilar metals and/or for depositing buffer layers on carbon steel and/or low alloy steels.
    Type: Grant
    Filed: October 18, 2004
    Date of Patent: May 1, 2012
    Assignee: Lincoln Global, Inc.
    Inventor: Damian J. Kotecki
  • Patent number: 8158907
    Abstract: A low alloy or mild steel weld containing a slag-modifying additive selected from the group consisting of antimony, bismuth, germanium and compounds thereof; A weld wire for forming a low alloy or mild steel weld containing a slag-modifying additive selected from the group consisting of antimony, bismuth, germanium and compounds thereof.
    Type: Grant
    Filed: February 27, 2003
    Date of Patent: April 17, 2012
    Assignee: Hobart Brothers Company
    Inventor: Anthony Franklin Nikodym
  • Patent number: 8153935
    Abstract: A flux cored wire for duplex stainless steel and a manufacturing method thereof are provided. The flux cored wire can include a sheath and a flux filled into the sheath. The flux cored wire comprises about 24.0-30.0 wt % Cr, about 7.0-10.5 wt % Ni, about 2.0-4.0 wt % Mo, about 0.10-2.50 wt % Cu, about 0.40-1.00 wt % Si, about 1.5-3.0 wt % Mn, about 0.10-0.30 wt % N compound (converted value of N), and the remainder including Fe and inevitable impurities on the basis of the total weight of the wire. The flux comprises about 6.50-12.00 wt % of TiO2+SiO2+ZrO2+Al2O3, about 0.10-0.50 wt % of Li2O+K2O+Na2O, about 0.10-2.00 wt % of the other oxides, and about 0.10-0.50 wt % of metal fluoride (converted value of F) on the basis of the total weight of the wire. The flux can be filled into the sheath at a ratio of about 26-35%.
    Type: Grant
    Filed: October 19, 2007
    Date of Patent: April 10, 2012
    Assignee: Kiswel Ltd.
    Inventors: Jong Hun Jang, Sang Jun Hur
  • Patent number: 8137613
    Abstract: An austenitic stainless steel welded joint, whose base metal and weld metal each comprises, by mass percent, C: not more than 0.3%, Si: not more than 2%, Mn: 0.01 to 3.0%, P: more than 0.04% to not more than 0.3%, S: not more than 0.03%, Cr: 12 to 30%, Ni: 6 to 55%, rare earth metal(s): more than 0.2% to not more than 0.6%, sol. Al: 0.001 to 3% and N: not more than 0.3%, with the balance being Fe and impurities, and satisfies the formula of (Cr+1.5×Si+2×P)/(Ni+0.31×Mn+22×C+14.2×N+5×P)<1.388, in spite of having a high P content and showing the fully austenitic solidification, has excellent resistance to the weld solidification cracking. Therefore, the said austenitic stainless steel welded joint can be widely used in such fields where a welding fabrication is required. Each element symbol in the above formula represents the content by mass percent of the element concerned.
    Type: Grant
    Filed: July 14, 2009
    Date of Patent: March 20, 2012
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventors: Takahiro Osuki, Kazuhiro Ogawa, Hirokazu Okada, Masaaki Igarashi
  • Patent number: 8119951
    Abstract: A low alloy or mild steel weld containing a slag-modifying additive selected from the group consisting of antimony, bismuth, germanium and compounds thereof; A weld wire for forming a low alloy or mild steel weld containing a slag-modifying additive selected from the group consisting of antimony, bismuth, germanium and compounds thereof.
    Type: Grant
    Filed: February 26, 2003
    Date of Patent: February 21, 2012
    Assignee: Hobart Brothers Company
    Inventor: Anthony Franklin Nikodym
  • Publication number: 20110315668
    Abstract: A hard composite composition comprises a binder; and a polymodal blend of matrix powder. In an embodiment, the polymodal blend of matrix powder has at least one local maxima at a particle size of 30 ?m or less, at least one local maxima at a particle size of 200 ?m or more, and at least one local minima between a particle size of about 30 ?m to about 200 ?m that has a value that is less than the local maxima at a particle size of 30 ?m or less.
    Type: Application
    Filed: October 12, 2010
    Publication date: December 29, 2011
    Inventor: Garrett T. Olsen
  • Patent number: 8044324
    Abstract: A solid wire contains C of 0.020 to 0.100 mass percent, Si of 0.25 to 1.10 mass percent, Mn of 1.20 to 1.65 mass percent, P of 0.008 to 0.017 mass percent, S of 0.045 to 0.150 mass percent, O of 0.0050 mass percent or less, N of 0.0050 mass percent or less, wherein P*(O+N)*105?15 is satisfied, and the remainder including Fe and impurities, wherein the relevant impurities contain Ti of 0.15 mass percent or less, B of 0.0050 mass percent or less, and Cr, Ni, Al, Nb, V, Zr, La and Ce of 0.20 mass percent or less respectively. According to such a configuration, a solid wire is provided, in which while increase in welding cost is controlled to the minimum, stability of wire feed, burn-through resistance, undercut resistance, and crack resistance are excellent, slag and spatter are hardly produced, hardness of weld metal is equal to or higher than that of base metal, and brittle fracture hardly occurs.
    Type: Grant
    Filed: November 15, 2007
    Date of Patent: October 25, 2011
    Assignee: Kobe Steel, Ltd.
    Inventors: Reiichi Suzuki, Yu Umehara
  • Patent number: 7989732
    Abstract: A method of AC welding that includes the step of supplying AC current with a given waveform from a power source to an advancing electrode and workpiece. The AC current is used to melt the electrode and to thereby deposit metal from the electrode onto the workpiece. The electrode includes a particulate arc stabilizing compound. The particulate arc stabilizing compound includes sodium and titanium dioxide. The particulate arc stabilizing compound constitutes over 20% by weight of the core of the electrode.
    Type: Grant
    Filed: June 15, 2005
    Date of Patent: August 2, 2011
    Assignee: Lincoln Global, Inc.
    Inventors: Nikhil Karogal, Rajeev Katiyar
  • Patent number: 7879460
    Abstract: Disclosed is a welding wire for joining cast iron and stainless steel, having a composition of 0.03 wt % or less of C, 2.0˜3.0 wt % of Si, 12.0˜14.0 wt % of Mn, 7.0˜9.0 wt % of Cr, 45.0˜47.0 wt % of Ni, 0.5˜0.8 wt % of Nb, and 2.0˜3.0 wt % of Mo, with a balance of Fe. Using the welding wire, a weld zone which has no hot cracks and is sound and good can be obtained.
    Type: Grant
    Filed: November 25, 2008
    Date of Patent: February 1, 2011
    Assignee: Hyundai Motor Company
    Inventor: Jae Gyu Jung
  • Patent number: 7812284
    Abstract: Various slag systems exhibiting improved flow characteristics and weld puddle properties are provided. Also provided are flux cored electrodes for producing the noted slag systems and related methods of arc welding.
    Type: Grant
    Filed: July 12, 2005
    Date of Patent: October 12, 2010
    Assignee: Lincoln Global, Inc.
    Inventors: Badri K. Narayanan, Patrick T. Soltis
  • Patent number: 7803465
    Abstract: A cored reactive metal wire is formed by gathering at least three strands of continuously fed elongated reactive metal wires into a bundle and aligning the bundle of wires with a continuously fed sheet of metal sheath. The bundle of wires is then compacted into a generally cylindrical shape and clad with the sheet of metal sheath whereby the compacted bundle of reactive metal wires form a core of the cored wire in which the core has a substantially larger diameter than each of the strands of continuously fed elongated reactive metal wires.
    Type: Grant
    Filed: June 17, 2008
    Date of Patent: September 28, 2010
    Assignee: Specialty Minerals (Michigan) Inc.
    Inventor: Dominick M. Colavito
  • Patent number: 7786407
    Abstract: Patent of Invention for PROCESS CAPILLARY ELECTRIC WELDING OF LOW AND HIGH ALLOY STEELS, HARDENED OR NOT, AND BI-METALS, FOR THE OBTAINMENT OF A DETERMINED TEXTURE, WITHOUT THERMAL TREATMENT, in which the first layer (1) is used to line the bevel and its root with electrodes of crystallization of the deposited welding material, said weld being adequate for the obtainment of the austenitic plus ferretic texture. With the second layer (2), proceed with the filling of the bevel with the crystallization of the deposited weld, obtaining a perlitic or pearlitic plus troostitic texture, while in the third and fifth layers (3, 5), the electrode for the obtainment of an austenitic plus ferritic texture. In the fourth layer (4), the electrode of deposited weld crystallization for the obtainment of a sorbitic plus bainitic texture is used, and in the sixth layer (6), an electrode for deposited weld crystallization for the obtainment of a bainitic texture is used.
    Type: Grant
    Filed: June 2, 2005
    Date of Patent: August 31, 2010
    Inventor: Bela Guth
  • Patent number: 7743967
    Abstract: A chromium-free welding consumable and a method of welding stainless steel to reduce the presence of chromium emissions. The consumable is made from an alloy that reduces the emission of chromium during a welding process, and include predominantly nickel, with between approximately five and twenty five percent by weight copper, up to approximately five percent by weight of palladium, up to approximately ten percent by weight of molybdenum and up to five percent non-copper alloying ingredients. Welding consumables made from the alloy are particularly well-suited for welding austenitic stainless steels, such as type 304 stainless steel. The method involves using chromium-free weld filler material with a stainless steel base material.
    Type: Grant
    Filed: February 11, 2008
    Date of Patent: June 29, 2010
    Assignee: The Ohio State University
    Inventors: Gerald S. Frankel, John C. Lippold