Ion Collectors Patents (Class 250/489)
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Patent number: 11774413Abstract: A preparative liquid chromatograph includes a liquid chromatograph section, a trap section, an eluent supply section, a collector, and a flow path switching section. The flow path switching section is configured to be selectively switched to a component trap mode that connects the liquid chromatograph section and the trap section in such a way that a sample component separated in a separation column is trapped by a trap column of the trap section; and a collection mode that connects the eluent supply section and the trap section and connects the trap section and the collector in such a way that the components trapped in the trap column are eluted by an eluent from the eluent supply section and are guided to the collector.Type: GrantFiled: July 2, 2021Date of Patent: October 3, 2023Assignee: Shimadzu CorporationInventor: Tomoyuki Yamazaki
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Patent number: 11600482Abstract: An ion trap apparatus is provided. The ion trap apparatus comprises two or more radio frequency (RF) rails formed with substantially parallel longitudinal axes and with substantially coplanar upper surfaces; and two or more sequences of trapping and/or transport (TT) electrodes with each sequence formed to extend substantially parallel to the substantially parallel longitudinal axes of the RF rails. The two or more RF rails and the two or more sequences of TT electrodes define an ion trap. The two or more sequences of TT electrodes are arranged into a number of zones. Each zone comprises wide matched groups of TT electrodes and at least one narrow matched group of TT electrodes. A wide TT electrode is longer and/or wider in a direction substantially parallel to the substantially parallel longitudinal axes of the RF rails than a narrow TT electrode.Type: GrantFiled: May 5, 2021Date of Patent: March 7, 2023Assignee: Quantinuum LLCInventors: Philip Makotyn, David Hayes, Russell Stutz, Patricia Lee, John Gaebler, Christopher Langer
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Patent number: 11037776Abstract: An ion trap apparatus is provided. The ion trap apparatus comprises two or more radio frequency (RF) rails formed with substantially parallel longitudinal axes and with substantially coplanar upper surfaces; and two or more sequences of trapping and/or transport (TT) electrodes with each sequence formed to extend substantially parallel to the substantially parallel longitudinal axes of the RF rails. The two or more RF rails and the two or more sequences of TT electrodes define an ion trap. The two or more sequences of TT electrodes are arranged into a number of zones. Each zone comprises wide matched groups of TT electrodes and at least one narrow matched group of TT electrodes. A wide TT electrode is longer and/or wider in a direction substantially parallel to the substantially parallel longitudinal axes of the RF rails than a narrow TT electrode.Type: GrantFiled: December 17, 2019Date of Patent: June 15, 2021Assignee: Honeywell International Inc.Inventors: Philip Makotyn, David Hayes, Russell Stutz, Patricia Lee, John Gaebler, Christopher Langer
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Patent number: 10950408Abstract: Apparatuses, systems, and methods for ion traps are described herein. One apparatus includes a number of microwave (MW) rails and a number of radio frequency (RF) rails formed with substantially parallel longitudinal axes and with substantially coplanar upper surfaces. The apparatus includes two sequences of direct current (DC) electrodes with each sequence formed to extend substantially parallel to the substantially parallel longitudinal axes of the MW rails and the RF rails. The apparatus further includes a number of through-silicon vias (TSVs) formed through a substrate of the ion trap and a trench capacitor formed in the substrate around at least one TSV.Type: GrantFiled: January 28, 2020Date of Patent: March 16, 2021Assignee: Honeywell International Inc.Inventor: Daniel Youngner
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Patent number: 10304650Abstract: Apparatuses, systems, and methods for ion traps are described herein. One apparatus includes a number of microwave (MW) rails and a number of radio frequency (RF) rails formed with substantially parallel longitudinal axes and with substantially coplanar upper surfaces. The apparatus includes two sequences of direct current (DC) electrodes with each sequence formed to extend substantially parallel to the substantially parallel longitudinal axes of the MW rails and the RF rails. The apparatus further includes a number of through-silicon vias (TSVs) formed through a substrate of the ion trap and a trench capacitor formed in the substrate around at least one TSV.Type: GrantFiled: March 13, 2018Date of Patent: May 28, 2019Assignee: Honeywell International Inc.Inventor: Daniel Youngner
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Patent number: 9916957Abstract: Apparatuses, systems, and methods for ion traps are described herein. One apparatus includes a number of microwave (MW) rails and a number of radio frequency (RF) rails formed with substantially parallel longitudinal axes and with substantially coplanar upper surfaces. The apparatus includes two sequences of direct current (DC) electrodes with each sequence formed to extend substantially parallel to the substantially parallel longitudinal axes of the MW rails and the RF rails. The apparatus further includes a number of through-silicon vias (TSVs) formed through a substrate of the ion trap and a trench capacitor formed in the substrate around at least one TSV.Type: GrantFiled: October 25, 2016Date of Patent: March 13, 2018Assignee: Honeywell International Inc.Inventor: Daniel Youngner
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Patent number: 9818577Abstract: A method for evaluating a specimen, the method can include positioning an energy dispersive X-ray (EDX) detector at a first position; scanning a flat surface of the specimen by a charged particle beam that exits from a charged particle beam optics tip and propagates through an aperture of an EDX detector tip; detecting, by the EDX detector, x-ray photons emitted from the flat surface as a result of the scanning of the flat surface with the charged particle beam; after a completion of the scanning of the flat surface, positioning the EDX detector at a second position in which a distance between the EDX detector tip and a plane of the flat surface exceeds a distance between the plane of the flat surface and the charged particle beam optics tip; and wherein a projection of the EDX detector on the plane of the flat surface virtually falls on the flat surface when the EDX detector is positioned at the first position and when the EDX detector is positioned at the second position.Type: GrantFiled: January 25, 2016Date of Patent: November 14, 2017Assignee: APPLIED MATERIALS ISRAEL LTD.Inventors: Alon Litman, Efim Vinnitsky
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Patent number: 9341585Abstract: An X-ray detector includes a housing and an X-ray sensing device provided within the housing along the axis of the housing, wherein the housing is structured to be coupled to the electron column or sample chamber of a charged particle beam device. The X-ray detector also includes an electron detector structured to detect a plurality of electrons ejected from a sample in response to an electron beam impinging on the sample, the electron detector being coupled to the housing on or near the axis such that a first line of sight to the electron detector from a point at which the electron beam impinges on the sample is similar to a second line of sight to the X-ray sensing device from the point at which the electron beam impinges on the sample such that X-ray and Backscattered electron images will show similar parallax and shadowing effects.Type: GrantFiled: October 15, 2013Date of Patent: May 17, 2016Assignee: PulseTor, LLCInventors: Nicholas C. Barbi, Richard B. Mott
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Patent number: 9040907Abstract: An apparatus includes an electrostatic ion trap and electronics configured to measure parameters of the ion trap and configured to adjust ion trap settings based on the measured parameters. A method of tuning the electrostatic ion trap includes, under automatic electronic control, measuring parameters of the ion trap and adjusting ion trap settings based on the measured parameters.Type: GrantFiled: October 30, 2012Date of Patent: May 26, 2015Assignee: MKS Instruments, Inc.Inventors: Gerardo A. Brucker, G. Jeffery Rathbone, Brian J. Horvath, Timothy C. Swinney, Stephen C. Blouch, Jeffrey G. McCarthy, Timothy R. Piwonka-Corle
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Publication number: 20150109660Abstract: Disclosed is a method for fabricating a wavelength conversion device that is capable of suppressing unintended and random polarization reversal due to heating thereby achieving higher wavelength conversion efficiency. The method includes: forming an insulating layer on one place of a crystal substrate naturally and uniformly polarized in a thickness direction; forming an insulating layer pattern with line-and-space by photolithography; then supplying conductive fluid to both planes of the crystal substrate to apply voltage to the crystal substrate, thereby a wavelength conversion device that is periodically polarization-reversed is fabricated. When temperature of the crystal substrate decreases after heating, an ionizer supplies ions to a surface of the crystal substrate, negative ions collect on +z plane, and positive ion collect on ?z plane, thereby unintended and random polarization reversal is suppressed.Type: ApplicationFiled: October 13, 2014Publication date: April 23, 2015Applicant: USHIO DENKI KABUSHIKI KAISHAInventor: Keisuke OTA
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Publication number: 20150076366Abstract: The invention relates to devices and methods for the storage of ions in mass spectrometers. The invention proposes the generation and superposition of two multipole fields of different order, independent of each other, in an RF multipole rod system. In an embodiment with eight pole rods, for example, it is thus possible to jointly store low-energy electrons in a central RF quadrupole field, which effectively acts only on electrons and holds them together radially, on the one hand, and multiply charged heavy positive ions in an RF octopole field, which effectively acts only on the ions, on the other hand, in order to fragment the positive ions by electron capture dissociation (ECD).Type: ApplicationFiled: November 21, 2014Publication date: March 19, 2015Inventor: Carsten Stoermer
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Publication number: 20150048246Abstract: An annular ion guide is disclosed comprising inner and outer electrodes. Ions are confined within an annular ion guiding region by RF or pseudo-potential barriers in both an outward and inward radial direction.Type: ApplicationFiled: October 1, 2012Publication date: February 19, 2015Inventors: Martin Raymond Green, David J. Landridge
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Publication number: 20150041640Abstract: An ion trap includes a containment region for containing ions, and a plurality of electrodes positioned on a regular polyhedral structure encompassing the containment region. An electrode is positioned on each vertex of the encompassing structure and at least one of the polygonal surfaces includes additional electrodes configured to form a plurality of quadrupoles on the surface. Alternating RF voltage is applied to the plurality of electrodes, so that directly neighboring electrodes are of equal amplitude and opposite polarity at any point in time. This configuration on the polyhedral structure forms a potential barrier for repelling the ions from each of the regular polygonal surfaces and containing them in the trap. Mass selective filters can be formed from the quadrupoles for parallel mass analysis in different m/z windows. Application of a small DC potential to a plate electrode outside the quadrupoles preferentially depletes single charged ions for enhanced signal-to-noise analysis.Type: ApplicationFiled: September 23, 2014Publication date: February 12, 2015Inventors: Andrew N. Krutchinsky, Vadim Sherman, Herbert Cohen, Brian T. Chait
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Publication number: 20140299761Abstract: A mass or mass to charge ratio selective ion trap is disclosed having an increased charge storage capacity. A RF voltage acts to confine ions in a first (y) direction within the ion trap. A DC voltage and/or an RF voltage acts to confine ions in a second (x) direction within the ion trap. A quadratic DC potential well acts to confine ions in a third (z) direction within the ion trap. Ions are excited in the third (z) direction and are caused to be mass or mass to charge ratio selectively ejected in the third (z) direction.Type: ApplicationFiled: August 22, 2012Publication date: October 9, 2014Applicant: MICROMASS UK LIMITEDInventors: Kevin Giles, Martin Raymond Green, Daniel James Kenny, David J. Langridge, Jason Lee Wildgoose
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Publication number: 20140291501Abstract: A method of mass spectrometry is disclosed comprising directing first photons from a laser onto ions located within a 2D or linear ion guide or ion trap. The frequency of the first photons is scanned and first photons and/or second photons emitted by the ions are detected. The ions are then mass analysed using a Time of Flight mass analyser.Type: ApplicationFiled: July 6, 2012Publication date: October 2, 2014Applicant: MICROMASS UK LIMITEDInventors: Jeffery Mark Brown, Kevin Giles, Daniel James Kenny, Paul Murray, Keith Richardson
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Publication number: 20140284469Abstract: A RF only quadrupole rod set mass filter or mass analyser and a linear quadrupole ion trap with axial ejection are disclosed comprising a first pair of rod electrodes, a second pair of rod electrodes and an energy filter. The first pair of rod electrodes is longer than the second pair of rod electrodes. Ions having desired mass to charge ratios experience fringing fields at an exit region which results in the ions possessing sufficient axial kinetic energy to be transmitted by the energy filter. Other ions possess insufficient axial kinetic energy to be transmitted by the energy filter and are attenuated.Type: ApplicationFiled: September 17, 2012Publication date: September 25, 2014Inventors: David J. Langridge, Daniel James Kenny
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Publication number: 20140264001Abstract: A miniature electrode apparatus is disclosed for trapping charged particles, the apparatus including, along a longitudinal direction: a first end cap electrode; a central electrode having an aperture; and a second end cap electrode. The aperture is elongated in the lateral plane and extends through the central electrode along the longitudinal direction and the central electrode surrounds the aperture in a lateral plane perpendicular to the longitudinal direction to define a transverse cavity for trapping charged particles.Type: ApplicationFiled: March 15, 2013Publication date: September 18, 2014Applicant: THE UNIVERSITY OF NORTH CAROLINA OF CHAPEL HILLInventor: THE UNIVERSITY OF NORTH CAROLINA OF CHAPEL HILL
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Publication number: 20140264006Abstract: Apparatuses and methods for performing mass analysis are disclosed. One such apparatus may include an ion trap device. The ion trap device may comprise a first end cap having a first aperture and a second end cap having a second aperture, wherein the first aperture and the second aperture may define an ejection axis. The ion trap device may also comprise a ring electrode substantially coaxially aligned between the first and second end caps. The ring electrode may include an opening extending along a radial direction of the ring electrode, wherein the radial direction is substantially perpendicular to the ejection axis. One such method may include ionizing a sample in an ion trap through an opening separating at least part of first and second ring sections of the ion trap and detecting ions ejected though an aperture on an end cap of the ion trap.Type: ApplicationFiled: March 14, 2014Publication date: September 18, 2014Applicant: 1st Detect CorporationInventors: David RAFFERTY, Michael SPENCER
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Publication number: 20140264068Abstract: An apparatus includes an electrostatic ion trap and electronics configured to measure parameters of the ion trap and configured to adjust ion trap settings based on the measured parameters. A method of tuning the electrostatic ion trap includes, under automatic electronic control, measuring parameters of the ion trap and adjusting ion trap settings based on the measured parameters.Type: ApplicationFiled: October 30, 2012Publication date: September 18, 2014Inventors: Gerardo A. Brucker, G. Jefferey Rathbone, Brian J. Horvath, Timothy C. Swinney, Stephen C. Blouch, Jeffrey G. McCarthy, Timothy R. Piwonka-Corle
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Patent number: 8835884Abstract: A charged particle beam apparatus including a charged particle emission gun with which cleaning of a tip is possible without stopping the operation of the charged particle emission gun for a long time and without heating the tip. The charged particle emission gun includes a cleaning photo-irradiation apparatus that generates ultraviolet light or infrared light to irradiate a tip, and an optical fiber for guiding the ultraviolet light or the infrared light toward the tip. The cleaning photo-irradiation apparatus generates ultraviolet light or an infrared light with a predetermined wavelength and intensity to desorb a molecule adsorbed on the tip through photon stimulated desorption, or to desorb a molecule adsorbed on the tip through photon stimulated desorption and ionize the desorbed molecule.Type: GrantFiled: December 8, 2011Date of Patent: September 16, 2014Assignee: Hitachi High-Technologies CorporationInventor: Noriaki Arai
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Publication number: 20140252224Abstract: An ion trap for a mass spectrometer is disclosed. The ion trap includes a ring electrode and first and second electrodes which are arranged on opposite sides of the ring electrode. The ring electrode and the first and second electrodes are configured to generate an electric field based on the received RF signal. The first electrode defines a first aperture and the second electrode defines a second aperture, the first aperture and the second aperture being asymmetric relative to each other and configured to generate a hexapole field.Type: ApplicationFiled: November 18, 2013Publication date: September 11, 2014Applicant: 1st DETECT CORPORATIONInventors: David Rafferty, Michael Spencer
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Publication number: 20140246582Abstract: An ion trap includes a containment region for containing ions, and a plurality of electrodes positioned on a regular polyhedral structure encompassing the containment region. An electrode is positioned on each vertex of the encompassing structure and at least one of the polygonal surfaces includes additional electrodes configured to form a plurality of quadrupoles on the surface. Alternating RF voltage is applied to the plurality of electrodes, so that directly neighboring electrodes are of equal amplitude and opposite polarity at any point in time. This configuration on the polyhedral structure forms a potential barrier for repelling the ions from each of the regular polygonal surfaces and containing them in the trap. Mass selective filters can be formed from the quadrupoles for parallel mass analysis in different m/z windows. Application of a small DC potential to a plate electrode outside the quadrupoles preferentially depletes single charged ions for enhanced signal-to-noise analysis.Type: ApplicationFiled: December 20, 2013Publication date: September 4, 2014Applicant: The Rockefeller UniversityInventors: Andrew N. Krutchinsky, Vadim Sherman, Herbert Cohen, Brian T. Chait
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Publication number: 20140246599Abstract: An apparatus for illuminating individual particles comprising a device for moving and directing air containing particles into a system, the system comprising an electrodynamic linear quadrupole section, an ultra-violet electromagnetic radiation source located along the electrodynamic linear quadrupole section, and a collection device for collecting the particles. A method of illuminating individual particles comprising moving and directing air containing particles into a system, controlling the air flow by using an air pump that continuously pulls or pushes air through the system, directing the particles into an electrodynamic linear quadrupole section, confining the particles to the central axis of the electrodynamic linear quadrupole section, illuminating the particles with ultra-violet electromagnetic radiation, interrogating the particles, and collecting the particles.Type: ApplicationFiled: November 18, 2013Publication date: September 4, 2014Applicant: The Government of the United States of America, as represented by the Secretary of the NavyInventors: Matthew B Hart, Patrick M Nolan, Jay D Eversole
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Publication number: 20140239197Abstract: An electrostatic trap such as an orbitrap is disclosed, with an electrode structure. An electrostatic trapping field of the form U?(r, ?, z) is generated to trap ions within the trap so that they undergo isochronous oscillations. The trapping field U?(r, ?, z) is the result of a perturbation W to an ideal field U(r, ?, z) which, for example, is hyperlogarithmic in the case of an orbitrap. The perturbation W may be introduced in various ways, such as by distorting the geometry of the trap so that it no longer follows an equipotential of the ideal field U(r, ?, z), or by adding a distortion field (either electric or magnetic). The magnitude of the perturbation is such that at least some of the trapped ions have an absolute phase spread of more than zero but less than 2? radians over an ion detection period Tm.Type: ApplicationFiled: May 5, 2014Publication date: August 28, 2014Applicant: Thermo Fisher Scientific (Bremen) GmbHInventors: Alexander A. MAKAROV, Eduard V. DENISOV, Gerhard JUNG, Wilko BALSCHUN, Stevan R. HORNING
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Publication number: 20140166895Abstract: An ion guide is disclosed comprising a plurality of axial groupings of electrodes, wherein each axial grouping of electrodes comprises a ring or annular electrode which has been radially segmented into a plurality of electrode segments.Type: ApplicationFiled: February 24, 2014Publication date: June 19, 2014Applicant: Micromass UK LimitedInventor: Daniel James Kenny
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Publication number: 20140145095Abstract: A method of operating a quadrupole mass spectrometer is described where one of the stages thereof has a pairs of opposing rods and one of the pair of rods is operated with a zero voltage potential difference therebetween and the other of the pair of opposing rods is operated with a voltage potential difference therebetween. The potential field unbalance causes the analyte ions to deviate from the axial centerline of the stage so as to undergo additional RF heating. The stage is operated in a transmission mode and the resultant reaction products may be further processed in subsequent stages or output to a mass spectrometer.Type: ApplicationFiled: June 14, 2012Publication date: May 29, 2014Inventors: Scott A. McLuckey, Ian K. Webb
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Publication number: 20140131568Abstract: A mass spectrometer is disclosed comprising a quadrupole rod set ion trap wherein a potential field is created at the exit of the ion trap which decreases with increasing radius in one radial direction. Ions within the on trap are mass selectively excited in a radial direction. Ions which have been excited in the radial direction experience a potential field which no longer confines the ions axially within the ion trap but which instead acts to extract the ions and hence causes the ions to be ejected axially from the ion trap.Type: ApplicationFiled: January 17, 2014Publication date: May 15, 2014Applicant: Micromass UK LimitedInventors: Martin Raymond Green, Daniel James Kenny, David J. Langridge, Jason Lee Wildgoose
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Patent number: 8698108Abstract: A system of measuring ion beam current in a process chamber using conductive liners is disclosed. A conductive liner is used to shield the walls of the process chamber. An ion measuring device, such as an ammeter, is used to measure the current created by the ions that impact the conductive liner. In some embodiments, a mechanism to contain secondary electrons generated in the process chamber is employed. Additionally, the ions that impact the scan system or workpiece may also be measured, thereby allowing the current of the entire ion beam to be measured.Type: GrantFiled: March 8, 2013Date of Patent: April 15, 2014Assignee: Varian Semiconductor Equipment Associates, Inc.Inventors: Joseph P. Dzengeleski, Eric Hermanson, Robert J. Mitchell, Tyler Rockwell, James W. Wilkinson, James Paul Buonodono, Frank Sinclair
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Patent number: 8698073Abstract: The present invention provides an ion collection device for an ion mobility spectrometer and an ion mobility spectrometer. The ion collection device comprises: an aperture grid for restraining influence of ion drift movement in a drift region on ion collection; and a first electrode disposed at a downstream side of the aperture grid in an ion drift direction, the first electrode is mechanically and electrically coupled with the aperture grid. With the above configuration, the aperture grid and the first electrode are at the same electric potential, and form a focusing electrical field with an ion collection part. Therefore, ions entering the collection region will not scatter into a shield cover.Type: GrantFiled: June 28, 2010Date of Patent: April 15, 2014Assignee: Nuctech Company LimitedInventors: Yuanjing Li, Zhiqiang Chen, Qingjun Zhang
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Publication number: 20140077075Abstract: This invention relates generally to multi-reflection electrostatic systems, and more particularly to improvements in and relating to the Orbitrap electrostatic ion trap. A method of operating an electrostatic ion trapping device having an array of electrodes operable to mimic a single electrode is proposed, the method comprising determining three or more different voltages that, when applied to respective electrodes of the plurality of electrodes, generate an electrostatic trapping field that approximates the field that would be generated by applying a voltage to the single electrode, and applying the three or more so determined voltages to the respective electrodes. Further improvements lie in measuring a plurality of features from peaks with different intensities from one or more collected mass spectra to derive characteristics, and using the measured characteristics to improve the voltages to be applied to the plurality of electrodes.Type: ApplicationFiled: November 19, 2013Publication date: March 20, 2014Applicant: Thermo Finnigan LLCInventor: Alexander Alekseevich MAKAROV
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Publication number: 20140061458Abstract: In an ion cyclotron resonance cell, which is enclosed at its ends by electrode structure elements with DC voltages of alternating polarity, longitudinal electrodes are divided so that the ICR measurement cell between the electrode structure elements consists of at least three sections. An excitation of ion cyclotron motions can be performed by applying additional trapping voltages to longitudinal electrodes located closest to the electrode structure elements and introducing ions into the center set of longitudinal electrodes. The ions are then excited into cyclotron orbits by applying radiofrequency excitation pulses to at least two rows of longitudinal electrodes to produce orbiting ion clouds. Subsequently, the additional trapping voltages are removed and an ion-attracting DC voltage is superimposed on the DC voltages. Ions excited to circular orbits can be detected using detection electrodes in the outer ICR cell sections.Type: ApplicationFiled: January 7, 2008Publication date: March 6, 2014Applicant: Bruker Daltonik GmbHInventor: Gokhan Baykut
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Methods and systems for detecting terahertz radiation by radiation enhanced emission of fluorescence
Patent number: 8653462Abstract: Methods and systems for detecting radiation, particularly, terahertz (THz) radiation, are disclosed. The methods and systems disclosed include directing an optical beam in a volume of gas; ionizing at least a portion of the volume of gas with the optical beam to produce a plasma; and detecting a fluorescence produced from an interaction of a radiation wave with the plasma. The information contained in the characteristics of the detected fluorescence, for example, the amplitude and/or phase are used to characterize the radiation wave. Aspects of the invention may be used for homeland security, medicine, and astronomy, among other fields.Type: GrantFiled: April 27, 2011Date of Patent: February 18, 2014Assignee: Rensselaer Polytechnic InstituteInventors: Xi-Cheng Zhang, Jingle Liu -
Publication number: 20140034825Abstract: An ion trap includes a trap exit at which an ion energy adjusting device is located. The adjusting device may be configured for focusing a beam of ions ejected from the trap, reducing the energy distribution of the ions, and/or reducing the average kinetic energy of the ions. The adjusting device may include lenses to which RF and/or DC voltages are applied.Type: ApplicationFiled: March 15, 2013Publication date: February 6, 2014Applicant: Agilent Technologies, Inc.Inventor: Agilent Technologies, Inc.
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Publication number: 20140027628Abstract: An ion trap comprises a ring electrode and opposite first and second endcap electrodes situated at opposite ends of the ring electrode. A waveform generator is configured to vary both frequency and amplitude of an AC waveform applied across the first and second endcap electrodes as a function of time, thereby exciting ions with a band of resonant secular frequencies substantially without exciting ions with adjacent secular frequencies.Type: ApplicationFiled: July 26, 2012Publication date: January 30, 2014Applicant: HAMILTON SUNDSTRAND CORPORATIONInventor: Brian M. Sutin
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Patent number: 8637813Abstract: A system and method for laser desorption of an analyte from a specimen and capturing of the analyte in a suspended solvent to form a testing solution are described. The method can include providing a specimen supported by a desorption region of a specimen stage and desorbing an analyte from a target site of the specimen with a laser beam centered at a radiation wavelength (?). The desorption region is transparent to the radiation wavelength (?) and the sampling probe and a laser source emitting the laser beam are on opposite sides of a primary surface of the specimen stage. The system can also be arranged where the laser source and the sampling probe are on the same side of a primary surface of the specimen stage. The testing solution can then be analyzed using an analytical instrument or undergo further processing.Type: GrantFiled: October 1, 2010Date of Patent: January 28, 2014Assignee: UT-Battelle, LLCInventors: Gary J. Van Berkel, Vilmos Kertesz
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Publication number: 20140008533Abstract: The invention proposes a method for the collective ejection of ions from a 3D RF ion trap with a ring electrode and two end cap electrodes, which comprises the following steps: (a) the RF voltage of a high-quality resonant circuit applied to the ring electrode is replaced with a second RF voltage at the two end cap electrodes which can be changed or switched faster than the high voltage at the ring electrode, keeping the ions stored, (b) the second RF voltage at the end cap electrodes is then switched down or off abruptly, releasing the ions, and (c) the released ions are ejected through an opening in one of the end cap electrodes by switching on a DC voltage on at least one of the end cap electrodes.Type: ApplicationFiled: June 26, 2013Publication date: January 9, 2014Inventors: Andreas Brekenfeld, Christoph Gebhardt, Ralf Hartmer
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Patent number: 8569723Abstract: An extreme ultraviolet light source apparatus has a magnetic field generator which generates a magnetic field region around a direction of the magnetic field passing through a plasma region in which a plasma is to be generated and converges charged particles including ion emitted from the plasma region toward the direction of the magnetic field, a first charged particle collector (receiver) mounted at both sides of an axis of the magnetic field in the magnetic field region in order to collect (receive) the charged particles converged by the magnetic field, a target supply unit supplying a target from a nozzle located outside a converging region in which the charged particles are to be converged inside the magnetic field region in an extreme ultraviolet light generating chamber, and a target collector located at a position opposite to the nozzle, the target retrieval portion retrieving a residual target which does not contribute to generation of the plasma.Type: GrantFiled: July 14, 2011Date of Patent: October 29, 2013Assignee: Gigaphoton Inc.Inventors: Shinji Nagai, Takanobu Ishihara, Kouji Kakizaki, Tamotsu Abe
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Publication number: 20130264496Abstract: Provided is a charged particle emission gun with which cleaning of a tip is possible without stopping the operation of the charged particle emission gun for a long time and without heating the tip. The charged particle emission gun includes a cleaning photo-irradiation apparatus that generates ultraviolet light or infrared light to irradiate a tip, and an optical fiber for guiding the ultraviolet light or the infrared light toward the tip. The cleaning photo-irradiation apparatus generates ultraviolet light or an infrared light with a predetermined wavelength and intensity to desorb a molecule adsorbed on the tip through photon stimulated desorption, or to desorb a molecule adsorbed on the tip through photon stimulated desorption and ionize the desorbed molecule.Type: ApplicationFiled: December 8, 2011Publication date: October 10, 2013Applicant: HITACHI HIGH-TECHNOLOGIES CORPORATIONInventor: Noriaki Arai
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Publication number: 20130221242Abstract: A mass spectrometer is disclosed comprising a quadrupole rod set ion trap wherein a potential field is created at the exit of the ion trap which decreases with increasing radius in one radial direction. Ions within the ion trap are mass selectively excited in a radial direction. Ions which have been excited in the radial direction experience a potential field which no longer confines the ions axially within the ion trap but which instead acts to extract the ions and hence causes the ions to be ejected axially from the ion trap.Type: ApplicationFiled: March 21, 2013Publication date: August 29, 2013Applicant: MICROMASS UK LIMITEDInventor: MICROMASS UK LIMITED
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Publication number: 20130214152Abstract: A combination of electrodes that are cylindrical and an asymmetric arrangement of cylindrical and planar electrodes are used to create electric fields that compensate for toroidal curvature in a toroidal ion trap, the design lending itself to high precision manufacturing and miniaturization, converging ion paths that enhance detection, higher pressure operation, and optimization of the shape of the electric fields by careful arrangement of the electrodes.Type: ApplicationFiled: August 20, 2012Publication date: August 22, 2013Inventors: Daniel E. Austin, Nicholas R. Taylor
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Publication number: 20130153763Abstract: The invention provides an element (12), comprising: a nanoporous insulating film (20) (such as a thin nanoporous diamond film) and first and second conducting layers (18a, 18b) on first and second opposed sides respectively of the film (20). Also provided are a vacuum pump (10), an ion source (80) and an ion trap (98), each comprising such an element (12).Type: ApplicationFiled: June 17, 2011Publication date: June 20, 2013Applicant: GBC SCIENTIFIC EQUIPMENT PTY. LTD.Inventor: Andrew Saint
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Publication number: 20130146761Abstract: The geometry of a Kingdon ion trap, in which harmonic ion oscillation in a potential well in a longitudinal direction is completely decoupled from ion oscillation in a direction transverse to the longitudinal direction, is arranged so that the oscillating ions introduced through the entrance tube cannot return to the entrance tube until they have performed several longitudinal oscillations during which time heavier ions can be introduced into the trap. In one embodiment, ions enter the trap via an entrance tube extending through, but electrically insulated from, one of the Kingdon trap housing electrodes and located outside the minimum of the potential well in the longitudinal direction.Type: ApplicationFiled: December 6, 2012Publication date: June 13, 2013Applicant: BRUKER DALTONIK GMBHInventor: Bruker Daltonik GmbH
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Patent number: 8455847Abstract: In an ion implanter, an ion current measurement device is disposed behind a mask co-planarly with respect to a surface of a target substrate as if said target substrate was positioned on a platen. The ion current measurement device is translated across the ion beam. The current of the ion beam directed through a plurality of apertures of the mask is measured using the ion current measurement device. In this manner, the position of the mask with respect to the ion beam as well as the condition of the mask may be determined based on the ion current profile measured by the ion current measurement device.Type: GrantFiled: March 23, 2012Date of Patent: June 4, 2013Assignee: Varian Semiconductor Equipment Associates, Inc.Inventors: Benjamin B. Riordon, Nicholas P. T. Bateman, William T. Weaver, Russell J. Low
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Publication number: 20130099137Abstract: An ion trap for a mass spectrometer has a conductive central electrode with an aperture extending from a first open end to a second open end. A conductive first electrode end cap is disposed proximate to the first open end thereby forming a first intrinsic capacitance between the first end cap and the central electrode. A conductive second electrode end cap is disposed proximate to the second open end thereby forming a second intrinsic capacitance between the second end cap and the central electrode. A first circuit couples the second end cap to a reference potential. A signal source generating an AC trap signal is coupled to the central electrode. An excitation signal is impressed on the second end cap in response to a voltage division of the trap signal by the first intrinsic capacitance and the first circuit.Type: ApplicationFiled: December 17, 2012Publication date: April 25, 2013Applicant: 1st Detect CorporationInventor: David Rafferty
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Publication number: 20130075602Abstract: The invention relates to devices and methods for the storage of ions in mass spectrometers. The invention proposes the generation and superposition of two multipole fields of different order, independent of each other, in an RF multipole rod system. In an embodiment with eight pole rods, for example, it is thus possible to jointly store low-energy electrons in a central RF quadrupole field, which effectively acts only on electrons and holds them together radially, on the one hand, and multiply charged heavy positive ions in an RF octopole field, which effectively acts only on the ions, on the other hand, in order to fragment the positive ions by electron capture dissociation (ECD).Type: ApplicationFiled: September 27, 2012Publication date: March 28, 2013Applicant: Bruker Daltonik GmbHInventor: Carsten Stoermer
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Publication number: 20130037711Abstract: Ions are introduced into a Kingdon ion trap in which the ions can oscillate harmonically in a potential well in the longitudinal direction, essentially decoupled from their transverse motion by a Kingdon ion guide, which can consist of a drill-hole through the wall of the ion trap housing electrodes and a central wire. An injection potential is first applied to the wire, but once the heaviest ions of interest have been injected into the trap, the potential of the wire is switched to the potential of the housing electrodes, to trap the ions in the trap. The ions introduced into the Kingdon ion trap may come from a small ion cloud, located in a Paul trap.Type: ApplicationFiled: July 26, 2012Publication date: February 14, 2013Applicant: BRUKER DALTONIK GMBHInventor: Claus KÖSTER
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Publication number: 20120286172Abstract: The subject matter described herein relates to a method for collection of atmospheric ions subject to an electron avalanche associated with a gas multiplication effect between parallel plate collectors. A voltage source can be provided. The voltage source can provide a voltage that can cause a high electric field between two consecutive plates of the plurality of parallel plates. The high electric field can cause an electron avalanche that can cause electron multiplication. Energy associated with these multiplied electrons can be extracted, and studied to give insight into where the most abundant source of atmospheric charge is located. Related apparatus, systems, techniques and articles are also described.Type: ApplicationFiled: May 12, 2011Publication date: November 15, 2012Applicant: Sefe, Inc.Inventors: Ryan Coulson, Bryce Jones, Michael Hurowitz
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Publication number: 20120267526Abstract: An ion trap mass analyser is disclosed comprising a segmented rod set. Ions are trapped radially within the mass analyser by a radial pseudo-potential well. The ions are also confined axially within a quadratic axial potential well. An AC voltage or potential is applied to the electrodes comprising the ion trap mass analyser in order to excite parametrically ions within the ion trap.Type: ApplicationFiled: June 29, 2012Publication date: October 25, 2012Applicant: MICROMASS UK LIMITEDInventor: Martin Green
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Patent number: 8164068Abstract: In an ion implanter, an ion current measurement device is disposed behind a mask co-planarly with respect to a surface of a target substrate as if said target substrate was positioned on a platen. The ion current measurement device is translated across the ion beam. The current of the ion beam directed through a plurality of apertures of the mask is measured using the ion current measurement device. In this manner, the position of the mask with respect to the ion beam as well as the condition of the mask may be determined based on the ion current profile measured by the ion current measurement device.Type: GrantFiled: July 28, 2010Date of Patent: April 24, 2012Assignee: Varian Semiconductor Equipment Associates, Inc.Inventors: Benjamin B. Riordon, Nicholas P. T. Bateman, William T. Weaver, Russell J. Low
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Patent number: 8063390Abstract: An electron cooling system and method for increasing the phase space intensity and overall intensity of ion beams in multiple overlap regions, including a vacuum chamber to allow a single electron beam to be merged and separated with multiple ion beams, an electron supply device including a cathode to generate the electron beam, an electron collector device including a collection plate to collect the electron beam, multiple magnetic field generation devices to guide the electrons on their desired trajectories, and multiple electrodes to set the velocity of the electron beam independently in each overlap region. By overlapping the electron and ion beams, thermal energy is transferred from the ion beams to the electron beam, which allows an increase in the phase space density and overall density of the ion beams.Type: GrantFiled: March 3, 2010Date of Patent: November 22, 2011Inventor: Delbert J. Larson