Having Utility As A Reactive Material In An Electrochemical Cell; E.g., Battery, Etc. Patents (Class 252/182.1)
  • Patent number: 12191489
    Abstract: A negative active material for a rechargeable lithium battery includes a secondary particle in which a plurality of natural graphite primary particles are agglomerated, the plurality of primary particles including natural graphite, and the secondary particle including pores, and an amorphous carbon positioned in the pores, wherein an area of the amorphous carbon is about 10% to about 30% based on a total area of 100% of the negative active material, in a cross-section of the negative active material.
    Type: Grant
    Filed: March 3, 2021
    Date of Patent: January 7, 2025
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Sunil Park, Narae Kim, Jaehou Nah, Joongho Moon, Hyun Soh, Eunjoo Lee
  • Patent number: 12187614
    Abstract: The present application discloses a composite graphite material and a method for preparing the same, a secondary battery, and an apparatus. The composite graphite material includes a core material and a coating layer that coats at least a portion of the surface of the core material, the core material including graphite, and the coating layer including a coating material containing a cyclic structure moiety, wherein the composite graphite material has a weight-loss rate of from 0.1% to 0.55% when the composite graphite material is heated in an atmosphere of an inert non-oxidative gas at a temperature rising from 40° C. to 800° C. The composite graphite material can enhance the gram capability and reduce the expansion rate of an electrode plate, and more preferably, can improve the cycle performance and kinetic performance of a battery as well.
    Type: Grant
    Filed: September 15, 2021
    Date of Patent: January 7, 2025
    Assignee: CONTEMPORARY AMPEREX TECHNOLOGY (HONG KONG) LIMITED
    Inventors: Chengdu Liang, Yuzhen Zhao, Yan Wen, Qisen Huang
  • Patent number: 12191486
    Abstract: A method for preparing a positive electrode active material for a lithium battery consisting of a lithiated oxide comprising titanium and optionally one or more other metal elements comprising the following successive steps: a) a step of forming a precipitate comprising titanium and the optional other metal element(s) by contacting a titanium coordination complex and, if necessary, at least one salt of the other metal element(s) with an aqueous medium; b) a step of recovering the precipitate thus formed; c) a step of calcining the precipitate in the presence of a lithium source.
    Type: Grant
    Filed: September 29, 2021
    Date of Patent: January 7, 2025
    Assignees: COMMISSARIAT À L'ÉNERGIE ATOMIQUE ET AUX ÉNERGIES ALTERNATIVES, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
    Inventors: David Peralta, Carole Bourbon, Jean-François Colin, Nathalie Herlin-Boime, Jérémie Fondard
  • Patent number: 12172891
    Abstract: The present invention relates to the field of lithium battery material preparation technologies, particularly to a method for preparing lithium iron phosphate using the by-product ferrous sulfate from titanium dioxide. The method comprises the following steps: dissolving by-product ferrous sulfate from titanium dioxide in acidic aqueous solution, stirring with iron powder for reaction; adding iron phosphate or lithium iron phosphate waste powder to the solution, heating and stirring the mixture, allowing the mixture to settle and cool, and filtering the cooled mixture to obtain a purified ferrous sulfate solution; and adding phosphoric acid and a lithium hydroxide solution in an autoclave, and finally adding the purified ferrous sulfate solution, heating the mixture under stirring, then filtering, washing, and drying the mixture to obtain lithium iron phosphate powder; Using it as an iron source to prepare positive electrode materials for lithium-ion batteries has excellent electrochemical performance.
    Type: Grant
    Filed: March 29, 2024
    Date of Patent: December 24, 2024
    Assignee: SHENZHEN WARRANT NEW ENERGY CO., LTD.
    Inventor: Yihong Tian
  • Patent number: 12176527
    Abstract: A positive electrode active material, including: a secondary particle formed from a primary particle. The secondary particle includes an inner part and an outer part that wraps the inner part. A ratio of an average particle size of primary particles in the outer part to an average particle size of primary particles in the inner part is G, and 1.1?G?10. The outer part is a region from an interface of the secondary particle to a surface of the secondary particle, and the inner part is a region from the interface of the secondary particle to a center of the secondary particle. The positive electrode active material in this disclosure improves cycle performance while ensuring good rate performance.
    Type: Grant
    Filed: March 15, 2021
    Date of Patent: December 24, 2024
    Assignee: Ningde Amperex Technology Limited
    Inventor: Ye Lang
  • Patent number: 12154719
    Abstract: A electrochemical device negative electrode includes: a negative electrode core material; and a negative electrode material layer supported on the negative electrode core material. The negative electrode material layer contains a carbon material. And a surface layer portion of the negative electrode material layer has a lithium carbonate-containing region.
    Type: Grant
    Filed: November 27, 2019
    Date of Patent: November 26, 2024
    Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
    Inventors: Yusuke Nakamura, Hideo Sakata, Toshiaki Shimizu
  • Patent number: 12151949
    Abstract: Various lithium cobalt oxides materials having a chemical formula of Lix Coy Oz, and method and apparatus of producing the various lithium cobalt oxides materials are provided. The method includes adjusting a molar ratio MLiSalt:MCoSalt of a lithium-containing salt, and a cobalt-containing salt within a liquid mixture to be equivalent to a ratio of x:y, drying a mist of the liquid mixture in the presence of a gas to form a gas-solid mixture, separating the gas-solid mixture into one or more solid particles of an oxide material, and annealing the solid particles of the oxide material in the presence of another gas flow to obtain crystalized particles of the lithium cobalt oxide material. The process system has a mist generator, a drying chamber, one or more gas-solid separator, and one or more reactors.
    Type: Grant
    Filed: September 17, 2021
    Date of Patent: November 26, 2024
    Inventors: Haixia Deng, Shengfeng Liu, Min-Duan Liu, Mengchen Liu, Liang-Yuh Chen
  • Patent number: 12145859
    Abstract: A cathode material, a preparation method thereof, a lithium ion battery and a vehicle are provided. The cathode material comprises cathode material particles comprising a central area, and a surface layer area, wherein the central area comprises lithium oxide, and the surface layer area comprises lithium oxide and elemental sulfur, in which the lithium oxide comprises ?LiNimConX(1-m-n)O2·(1??)Li2MO3, where 0???1, X comprises at least one selected from Mn, Al, Nb, and Fe, M comprises at least one selected from Mn, Al, Nb, Fe, Co, and Ni, 0?m<1, and 0?n<1.
    Type: Grant
    Filed: July 10, 2019
    Date of Patent: November 19, 2024
    Assignee: BYD COMPANY LIMITED
    Inventors: Dongjie Hu, Hao Wei
  • Patent number: 12148928
    Abstract: In one or more embodiment described herein, a precursor of an active material of an electrode of a lead-acid battery may be made by a process that includes forming an active material paste and curing the active material paste to form the precursor of the active material of the electrode of the lead-acid battery. The active material paste may be made by combining at least water, an acid, a glass composition having at least 25 wt. % of a single metal oxide, and lead oxide. The metal oxide may be selected from barium oxide, lead oxide, zinc oxide, or antimony oxide.
    Type: Grant
    Filed: August 26, 2021
    Date of Patent: November 19, 2024
    Assignee: Hammond Group, Inc.
    Inventors: Marvin C. Ho, Thomas David Wojcinski
  • Patent number: 12148920
    Abstract: A cathode material, a preparation method thereof, and a lithium ion battery are provided. The cathode material comprises cathode material particles comprising a central area, an intermediate layer, and a surface layer, wherein the intermediate layer is located between the central area and the surface layer; and the central area comprises a lithium oxide, the intermediate layer comprises elemental sulfur, and the surface layer comprises elemental sulfur and elemental carbon, in which the lithium oxide comprises ?LiNimConX(1-m-n)O2·(1??)Li2MO3, where 0???1, X includes at least one selected from Mn, Al, Nb, and Fe, M includes at least one selected from Mn, Al, Nb, Fe, Co, and Ni, 0?m<1, and 0?n<1.
    Type: Grant
    Filed: July 10, 2019
    Date of Patent: November 19, 2024
    Assignee: BYD COMPANY LIMITED
    Inventors: Dongjie Hu, Hao Wei
  • Patent number: 12142755
    Abstract: A manufacturing method of a carbon-coated lithium iron phosphate material including steps of: (a) providing a first slurry, a lithium source, and a first carbon source having a first weight, wherein the first slurry is formed from an iron source and a phosphorus source, and the first weight is equal to an input value; (b) mixing and grinding the first carbon source, the lithium source and the first slurry to form a second slurry; (c) performing a carbon content analysis on the second slurry to obtain a loss value, wherein the loss value is smaller than the input value and greater than zero; (d) adding a second carbon source having a second weight into the second slurry to form a third slurry, wherein the second weight is equal to the loss value; (e) drying and sintering the third slurry to form the carbon-coated lithium iron phosphate material.
    Type: Grant
    Filed: July 29, 2023
    Date of Patent: November 12, 2024
    Assignee: Advanced Lithium Electrochemistry Co., Ltd.
    Inventors: Ya-Hui Wang, Feng-Yen Tsai
  • Patent number: 12132194
    Abstract: A negative active material for a rechargeable lithium battery and a rechargeable lithium battery including the same are disclosed, and the negative active material includes a primary particle of a crystalline carbon-based material and secondary particle that is an assembly of the primary particles, wherein a ratio of an average particle diameter (D50) of the secondary particle relative to an average particle diameter (D50) of the primary particle (average particle diameter (D50) of the secondary particle/average particle diameter (D50) of the primary particle) ranges from about 1.5 to about 5 and an aspect ratio of the primary particle ranges from about 1 to about 7.
    Type: Grant
    Filed: May 31, 2023
    Date of Patent: October 29, 2024
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Ji Woo Ahn, Dongwoo Kim, Jaehou Nah, Bumjin Chang, Yurim Cha, Yeonjoo Choi, Ilyoung Choi
  • Patent number: 12119494
    Abstract: The purpose of the present invention is to provide positive electrode active substance particles for a lithium ion secondary battery, such particles being capable of producing a lithium ion secondary battery having excellent high-speed discharge properties. The present invention is a granulated body of a positive electrode active substance for a lithium ion secondary battery, wherein the primary particle average diameter is 10 to 80 nm and the number of primary particles having a diameter of 100 nm or greater is no more than 5.0%.
    Type: Grant
    Filed: December 23, 2020
    Date of Patent: October 15, 2024
    Assignee: TORAY INDUSTRIES, INC.
    Inventors: Hiroaki Kawamura, Tomoya Onozuka
  • Patent number: 12110442
    Abstract: Provided is a novel technique related to electrochemical devices that can cause an electrochemical device to display excellent rate characteristics and high-temperature storage characteristics. The electrochemical device is produced using a dispersant composition for an electrochemical device that contains a polymer A. This polymer A includes a nitrile group-containing monomer unit and has an intrinsic viscosity of not less than 0.15 dL/g and less than 1.20 dL/g when dissolved in N-methyl-2-pyrrolidone and measured at a temperature of 25° C.
    Type: Grant
    Filed: August 16, 2021
    Date of Patent: October 8, 2024
    Assignee: ZEON CORPORATION
    Inventor: Kazuki Asai
  • Patent number: 12100836
    Abstract: A method of producing a positive electrode active material for a nonaqueous electrolyte secondary battery, the method includes preparing nickel-containing composite oxide particles having a ratio 1D90/1D10 of a 90% particle size 1D90 to a 10% particle size 1D10 in volume-based cumulative particle size distribution is 3 or less; mixing the composite oxide particles and a lithium compound to obtain a first mixture; subjecting the first mixture to a first heat treatment at a first temperature and a second heat treatment at a second temperature higher than the first temperature to obtain a first heat-treated product; and subjecting the first heat-treated material to a dispersion treatment.
    Type: Grant
    Filed: June 27, 2023
    Date of Patent: September 24, 2024
    Assignee: NICHIA CORPORATION
    Inventors: Kenichi Kobayashi, Yukiko Sano
  • Patent number: 12100858
    Abstract: A method for producing a solid electrolyte membrane (3) or an anode unit for a solid-state battery, in which method a powder mixture consisting of a solid electrolyte material and polytetrafluoroethylene is produced for the solid electrolyte membrane (3) and a powder mixture consisting of an electrode material, a solid electrolyte material, an electrically conductive conduction additive and polytetrafluoroethylene is produced for the anode unit, at least partially fibrillated polytetrafluoroethylene is formed by applying shear forces to the powder mixture, and the powder mixture is shaped into a flexible composite layer. The powder mixture has at most 1 wt. % polytetrafluoroethylene.
    Type: Grant
    Filed: December 17, 2019
    Date of Patent: September 24, 2024
    Assignees: FRAUNHOFER-GESELLSCHAFT ZUR FOERDERUNG DER ANGEWANDTEN FORSCHUNG B.V., TECHNISCHE UNIVERSITÄT DRESDEN
    Inventors: Felix Hippauf, Benjamin Schumm, Sebastian Tschoecke, Holger Althues, Stefan Kaskel, Susanne Doerfler
  • Patent number: 12095083
    Abstract: A cathode active material includes a composition expressed as: Li1+?(NixMnyCoz)M1?(Nix?Mny?Coz?)M21-?O2; or Na1+?(NixMnyCoz)M1?(Nix?Mny?Coz?)M21-?O2; where: M1 represents a core composition comprising of Ni, Mn, and/or Co or a combination of at two of thereof; M2 represents a surface composition having at least 50% Co, and, optionally Ni and/or Mn; the structure of M2 may be a composite structure and includes a rock-salt or disordered rock-salt phase; 0.5??<1, 0?x?1, 0?y?0.5, 0?z?1, 0?x??0.5, 0?y??0.5, 0.5?z??1, and ?0.1???0.1; the sum of x, y and z is 0.9-1.1, and the sum of x?, y? and z? is 0.9-1.1.
    Type: Grant
    Filed: March 4, 2020
    Date of Patent: September 17, 2024
    Assignee: UCHICAGO ARGONNE, LLC
    Inventors: Tongchao Liu, Khalil Amine
  • Patent number: 12095118
    Abstract: A secondary battery includes a wound electrode body. The wound electrode body includes a positive electrode, a negative electrode, and a separator. The positive electrode and the negative electrode are stacked on each other with the separator interposed therebetween and are wound about a winding axis. The wound electrode body has a section perpendicular to the winding axis. The section has an elongated shape that includes a flat part and a pair of curved parts. The curved parts oppose each other with the flat part interposed therebetween. The negative electrode includes a negative electrode current collector and a negative electrode active material layer provided on the negative electrode current collector. A width of the wound electrode body, a wound-layer number of the wound electrode body, and a ratio of a second distance to a first distance satisfy at least one of Condition A and Condition B.
    Type: Grant
    Filed: February 9, 2021
    Date of Patent: September 17, 2024
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Takaaki Matsui, Kazuki Honda, Rikako Imoto, Hideki Nakai, Takashi Sato
  • Patent number: 12095087
    Abstract: A lithium transition metal phosphate material comprising lithium iron phosphate doped with very precise amounts of aluminium dopant, the material having formula LiyFe1-xAlxPO4, in which 0.8?y?1.2 and 0.0120?x?0.0180. When x is within this range, the capacity of the material can be improved, and good or excellent distribution of aluminium in the lithium metal phosphate is observed.
    Type: Grant
    Filed: September 13, 2019
    Date of Patent: September 17, 2024
    Assignee: Johnson Matthey PLC
    Inventors: Ludovic Briquet, Maria Rivas-Velazco, Noelia Cabello-Moreno, Mahrez Amri
  • Patent number: 12087945
    Abstract: A cathode active material for a lithium secondary battery including a lithium-transition metal composite oxide particle is provided. A crystal grain size of the lithium-transition metal composite oxide particle measured by an XRD analysis is 250 nm or more, and an XRD peak intensity ratio of the lithium-transition metal composite oxide particle is 9.8% or less. A lithium secondary battery including the lithium-transition metal composite oxide particle and having improved life-span and rate capability is provided.
    Type: Grant
    Filed: June 3, 2021
    Date of Patent: September 10, 2024
    Assignee: SK INNOVATION CO., LTD.
    Inventors: Sang Han Lee, Min Gu Kang, Jeong Bae Yoon, Yong Hyun Cho
  • Patent number: 12080878
    Abstract: An anode layer for all-solid secondary batteries, an all-solid secondary battery, and a method of manufacturing an all-solid secondary battery, the anode layer including an anode current collector; and a first anode active material layer on the anode current collector, wherein the first anode active material layer includes a metal-carbon composite including a metal, carbon, and a polyol.
    Type: Grant
    Filed: October 13, 2021
    Date of Patent: September 3, 2024
    Assignee: SAMSUNG SDI CO., LTD.
    Inventors: Jinkyu Kim, Jinhoon Yang, Yunchae Jung, Byeonggyu Cho, Sangil Han
  • Patent number: 12074311
    Abstract: Resin-adhered graphite particles are obtained by causing a modified novolac-type phenolic resin to adhere to graphite particles. At least part of surfaces of the graphite particles is coated with a carbonaceous coating by heating the resin-adhered graphite particles in a non-oxidizing atmosphere at 900 to 1,500° C. to carbonize the modified novolac-type phenolic resin. Arylene groups having hydroxy groups account for 5 to 95 mol % of arylene groups constituting the modified novolac-type phenolic resin. The obtained carbonaceous substance-coated graphite particles exhibit excellent battery properties when used as a negative electrode material for a lithium ion secondary battery.
    Type: Grant
    Filed: September 8, 2021
    Date of Patent: August 27, 2024
    Assignee: JFE Steel Corporation
    Inventors: Ryuta Haga, Motoharu Obika, Kunihiko Eguchi, Yoshikazu Kobayashi, Masakatsu Asami
  • Patent number: 12074324
    Abstract: According to an exemplary embodiment of the present disclosure, a negative electrode active material includes metal-silicon-carbon based particles including a MaSibC matrix, wherein M in the MaSibC matrix is one or more selected from the group consisting of Li, Mg, Na, Ca, and Al, 0.35?a?1, and 1?b?2. Since at the time of charging and discharging a battery, formation of an irreversible phase may be minimized by the MaSibC matrix, initial efficiency of the battery may be improved, and electrical conductivity, physical strength, and chemical stability may be improved, such that capacity and lifecycle characteristics of the battery may be improved.
    Type: Grant
    Filed: October 18, 2019
    Date of Patent: August 27, 2024
    Assignee: LG ENERGY SOLUTION, LTD.
    Inventors: Il Geun Oh, Yong Ju Lee, Su Min Lee
  • Patent number: 12068481
    Abstract: Provided is a Ni-based positive electrode active material for a sodium ion secondary battery having an excellent discharge capacity. A positive electrode active material for a sodium ion secondary battery, the positive electrode active material being composed of crystals represented by a general formula Nax (Ni1-aMa)yP2Oz (where M represents at least one transition metal element selected from the group consisting of Fe, Cr, Mn, and Co and the following are satisfied: 0.6?x?4, 0.3?y?2.7, 0?a?0.9, and 6?z<7.5).
    Type: Grant
    Filed: June 8, 2022
    Date of Patent: August 20, 2024
    Assignee: NIPPON ELECTRIC GLASS CO., LTD.
    Inventor: Hideo Yamauchi
  • Patent number: 12062792
    Abstract: A negative electrode material for a lithium-ion secondary cell, comprising carbon particles having an oxygen content of 0.15% by mass or less.
    Type: Grant
    Filed: November 22, 2018
    Date of Patent: August 13, 2024
    Assignee: RESONAC CORPORATION
    Inventors: Hideyuki Tsuchiya, Tsutomu Satoh
  • Patent number: 12062781
    Abstract: A cathode material includes a lithium composite oxide matrix including lithium (Li) and at least one selected from the group consisting of cobalt (Co), nickel (Ni), manganese (Mn), and aluminium (Al), and has a surface layer which is a rocksalt structure and includes tungsten (W); and a material layer formed on the surface layer of the lithium composite oxide matrix and including tungsten (W) and lithium (Li). The cathode material of the present application provides excellent high-temperature cycle and high-temperature storage performance, and the capability of discharge at a high rate, and improves the safety performance of the electrochemical device.
    Type: Grant
    Filed: February 21, 2020
    Date of Patent: August 13, 2024
    Assignees: NINGDE AMPEREX TECHNOLOGY LIMITED, DONGGUAN AMPEREX TECHNOLOGY LIMITED
    Inventors: Yangyang Zhang, Gang Peng, Ye Lang, Wenyuan Liu
  • Patent number: 12057573
    Abstract: The invention relates to composite materials comprising lithiated or partially-lithiated graphite or graphene, and silicon having particles sizes from about 1 ?m to about 100 ?m, and that have an electrochemical rest potential less than about 2 V measured against Li/Li+, wherein graphitic material is mixed with silicon powder in a molar ratio of 9:1 to 1:9 and with lithium powder to an amount of the lithium in the composite material in the range of about 10 molar % to 100 molar % of the stochiometrically maximally possible lithium absorption, and to methods for production thereof.
    Type: Grant
    Filed: January 6, 2023
    Date of Patent: August 6, 2024
    Assignee: ALBEMARLE GERMANY GmbH
    Inventors: Ulrich Wietelmann, Ute Emmel, Christopher Kurth, Stefan Scherer, Thorsten Buhrmester, Gerd Krämer
  • Patent number: 12057585
    Abstract: A conductive composition for a secondary battery, a slurry comprising the same, an electrode comprising the same and a method of preparing the conductive composition are provided. The conductive composition comprises a polymeric material, a carbon nanomaterial and an anionic stabilizing agent. The polymeric material comprises a copolymer comprising a structural unit derived from an acid group-containing monomer and a structural unit derived from a polar group-containing monomer. The conductive composition exhibits an improved stability and dispersibility in water. In addition, battery cells comprising a cathode prepared using the conductive composition disclosed herein exhibit impressive electrochemical performances.
    Type: Grant
    Filed: June 2, 2021
    Date of Patent: August 6, 2024
    Assignee: GRST International Limited
    Inventors: Kam Piu Ho, Yingkai Jiang, Xinying Sun
  • Patent number: 12040475
    Abstract: According to one embodiment, an electrode material is provided. The electrode material includes active material particle containing: a niobium-titanium composite oxide having an average composition in which a molar ratio of niobium to titanium (MNb/MTi) is greater than 2; and at least one element A selected from the group consisting of potassium, iron and phosphorus. The active material particle contain the element A at a concentration in the range of 100 ppm to 2000 ppm.
    Type: Grant
    Filed: January 22, 2021
    Date of Patent: July 16, 2024
    Assignee: KABUSHIKI KAISHA TOSHIBA
    Inventors: Yasuhiro Harada, Kazuomi Yoshima, Norio Takami
  • Patent number: 12040474
    Abstract: A free-standing electrode film may comprise an electrode active material and a composite binder comprising polytetrafluoroethylene (PTFE) and polyvinylpyrrolidone (PVP). An electrode for an energy storage device may comprise a current collector and a film on the current collector, the film including an electrode active material and a composite binder comprising PTFE and PVP. A method of manufacturing a free-standing electrode film may comprise preparing a mixture including an electrode active material and a composite binder, the composite binder comprising PTFE and one or more additional binders selected from the group consisting of PVP, polyvinylidene fluoride (PVDF), polyethylene oxide (PEO), and carboxymethylcellulose (CMC). The method may further comprise adding a solvent to the mixture, subjecting the mixture to a shear force, and, after the solvent has been added and the mixture has been subjected to the shear force, pressing the mixture into a free-standing film.
    Type: Grant
    Filed: November 13, 2020
    Date of Patent: July 16, 2024
    Assignee: LICAP TECHNOLOGIES, INC.
    Inventors: Bibek Tiwari, Linda Zhong, Bae Hyun Kim, Hyeunhwan An
  • Patent number: 12034108
    Abstract: A secondary battery includes a wound electrode body having a positive electrode, a negative electrode, and a separator. The positive electrode and the negative electrode are stacked on each other with the separator interposed therebetween and are wound about a winding axis. The wound electrode body has a section perpendicular to the winding axis. The section has an elongated shape that includes a flat part and a pair of curved parts. The curved parts oppose each other with the flat part interposed therebetween. The negative electrode includes a negative electrode current collector and a negative electrode active material layer provided on the negative electrode current collector. A ratio of a second distance to a first distance is less than 1.
    Type: Grant
    Filed: February 9, 2021
    Date of Patent: July 9, 2024
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Rikako Imoto, Takaaki Matsui, Hideki Nakai
  • Patent number: 12034179
    Abstract: The present disclosure provides a separator for a zinc secondary battery that can inhibit short circuiting in a zinc secondary battery. The separator for a zinc secondary battery of the disclosure has a porous substrate layer and a titanium oxide-containing porous layer laminated onto the porous substrate layer, wherein the titanium oxide-containing porous layer comprises a titanium oxide represented by TixOy, where 0<x, 0<y, and y<2x. The titanium oxide may be TiO, Ti2O, Ti2O3, Ti3O, Ti3O5, Ti4O5, Ti4O7, Ti5O9, Ti6O, Ti6O11, T17O13, T18O15 or T19O17.
    Type: Grant
    Filed: December 17, 2021
    Date of Patent: July 9, 2024
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventor: Hiroshi Suyama
  • Patent number: 12034149
    Abstract: A positive active material for a rechargeable lithium battery includes a lithium nickel-based composite oxide and a lithium manganese composite oxide, wherein the positive active material includes a surface-modifying layer including lithium fluoride on the surface of at least one of the lithium nickel-based composite oxide and the lithium manganese composite oxide. The lithium nickel-based composite oxide includes a secondary particle in which a plurality of plate-shaped primary particles are agglomerated, and the secondary particle has a regular array structure in which (003) planes of the plurality of primary particles are aligned or oriented normal to the surface of the secondary particle. The lithium manganese composite oxide is present in two or more types of crystal lattice structures.
    Type: Grant
    Filed: January 30, 2020
    Date of Patent: July 9, 2024
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Sungsoo Kim, Donghyun Kil
  • Patent number: 12025580
    Abstract: An ion detection sensor fabrication method includes: preparing an ion-sensitive film preparation solution; preparing an ion-sensitive mixed layer preparation solution by mixing the ion-sensitive film preparation solution with graphene powder; and forming an ion-sensitive mixed layer sensitive to a target ion by applying the ion-sensitive mixed layer preparation solution to fill a gap between a source and a drain spaced apart from each other and to cover at least a portion of an upper surface of each of the source and the drain.
    Type: Grant
    Filed: October 18, 2021
    Date of Patent: July 2, 2024
    Assignee: MCK TECH CO., LTD.
    Inventors: Seung Min Cho, Min Gu Cho, Ki Soo Kim, Hong Gi Oh
  • Patent number: 12021228
    Abstract: A method of producing a positive electrode material for a secondary battery includes preparing a lithium composite transition metal oxide containing nickel, cobalt, and manganese, forming a coating layer on a surface of the lithium composite transition metal oxide, and post-treating the lithium composite transition metal oxide having the coating layer formed thereon, wherein the post-treating is performed by exposing the lithium composite transition metal oxide having the coating layer formed thereon to moisture at a relative humidity of 10% to 50% at 25° C., and then heat treating the lithium composite transition metal oxide to remove residual moisture.
    Type: Grant
    Filed: December 4, 2020
    Date of Patent: June 25, 2024
    Assignee: LG Energy Solution, Ltd.
    Inventors: Gi Beom Han, Wang Mo Jung, Sang Wook Lee, Hak Yoon Kim, So Ra Baek, Jung Min Han
  • Patent number: 12021220
    Abstract: A cathode material comprising: a cathode active material of formula LiNixMnyCozO2 or NaNixMnyCozO2 and having a partial or whole particle concentration gradient, wherein at least two or three elements concentration gradually change in the part or whole particle from the center part to the surface part of the particle (i.e. along a vector radius); 0.5<x?1, 0?y?0.33, 0?z?0.33.
    Type: Grant
    Filed: April 12, 2023
    Date of Patent: June 25, 2024
    Assignee: UCHICAGO ARGONNE, LLC
    Inventors: Khalil Amine, Tongchao Liu, Jun Lu
  • Patent number: 12009501
    Abstract: A method of making an electrode by providing a mixture of first particles of silver or silver oxide and second particles of an inorganic porogen, molding the mixture, cohering the mixture to form a green body, demolding the green body, heating the green body to form a monolith, to convert any silver oxide to silver, and to fuse the first particles together, and submerging the monolith in a liquid that removes the second particles.
    Type: Grant
    Filed: June 2, 2023
    Date of Patent: June 11, 2024
    Assignee: The Government of the United States of America, as represented by the Secretary of the Navy
    Inventors: Ryan H. DeBlock, Debra R. Rolison, Jeffrey W. Long, Zachary G. Neale
  • Patent number: 12002964
    Abstract: An electrochemical device includes a first electrode plate. The first electrode plate includes a current collector and an active material layer. The current collector includes a first substrate and a second substrate that are stacked together. The second substrate is disposed between the first substrate and the active material layer. And 100 MPa?Rm1?Rm2?400 MPa, Rm1 is a tensile strength of the first substrate and Rm2 is a tensile strength of the second substrate. The current collector that includes the first substrate and the second substrate is adopted, thereby suppressing both the elongation deformation of the electrode plate and the detachment of the active material layer.
    Type: Grant
    Filed: March 18, 2022
    Date of Patent: June 4, 2024
    Assignee: NINGDE AMPEREX TECHNOLOGY LIMITED
    Inventor: Qiangqiang Tang
  • Patent number: 12002958
    Abstract: The present invention relates to composite particles containing silicon and carbon, wherein a domain size region of vacancies of 2 nm or less is 44% by volume or more and 70% by volume or less when volume distribution information of domain sizes obtained by fitting a small-angle X-ray scattering spectrum of the composite particles with a spherical model in a carbon-vacancy binary system is accumulated in ascending order, and a true density calculated by dry density measurement by a constant volume expansion method using helium gas is 1.80 g/cm3 or more and 2.20 g/cm3 or less.
    Type: Grant
    Filed: May 28, 2021
    Date of Patent: June 4, 2024
    Assignee: Resonac Corporation
    Inventors: Naoto Kawaguchi, Yuji Ito, Masato Fujita, Hirofumi Inoue
  • Patent number: 11990614
    Abstract: According to one embodiment, provided is an active material including a composite oxide having a tetragonal crystal structure. The composite oxide is represented by general formula LiaTibNb2?2dMc+2dO2b+5+3c. Here, M is one selected from the group consisting of W and Mo, 0?a?b+4+3c, 0<b<2?2d, and 0<c<2?4d.
    Type: Grant
    Filed: August 31, 2021
    Date of Patent: May 21, 2024
    Assignee: KABUSHIKI KAISHA TOSHIBA
    Inventors: Kazuki Ise, Hirofumi Yasumiishi, Keigo Hoshina, Yasuhiro Harada, Norio Takami
  • Patent number: 11990606
    Abstract: A negative electrode active material for non-aqueous electrolyte secondary batteries, including: lithium silicate composite particles including a lithium silicate phase and silicon particles dispersed in the lithium silicate phase, the lithium silicate phase being an oxide phase including Li, Si, O, and M, where M is an element other than the following elements: Group 1 elements of alkali metals, Group 16 elements of oxygen group, Group 18 elements of rare gas, and Si. An amount of each element relative to a total amount of Li, Si and M in the lithium silicate phase is 3 to 55 mol % for Li, 25 mol % or more for Si, and 3 to 50 mol % for M. A carbon material is present inside the lithium silicate composite particles; and an area ratio of the carbon material occupying a cross section of the composite particles is 0.008 to 6%.
    Type: Grant
    Filed: October 29, 2018
    Date of Patent: May 21, 2024
    Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
    Inventors: Yohei Uchiyama, Norihisa Yamamoto, Tatsuya Akira
  • Patent number: 11984577
    Abstract: A method of making an electrode includes the step of mixing active material particles, radiation curable resin precursors, and electrically conductive particles to create an electrode precursor mixture. The electrode precursor mixture is electrostatically sprayed onto a current collector to provide an electrode preform. The electrode preform is heated and calendered to melt the resin precursor such that the resin precursor surrounds the active particles and electrically conductive particles. Radiation is applied to the electrode preform sufficient to cure the radiation curable resin precursors into resin.
    Type: Grant
    Filed: March 29, 2022
    Date of Patent: May 14, 2024
    Assignee: UT-BATTELLE, LLC
    Inventors: Zhijia Du, Christopher James Janke, Jianlin Li, David L. Wood, III, Claus Daniel
  • Patent number: 11978891
    Abstract: The present invention relates to a positive electrode active material, in which primary particles included in a secondary particle exhibit an aspect ratio gradient which gradually increases from the center of the secondary particle to the surface thereof, and a lithium secondary battery which uses a positive electrode containing the positive electrode active material.
    Type: Grant
    Filed: June 18, 2020
    Date of Patent: May 7, 2024
    Assignee: ECOPRO BM CO., LTD.
    Inventors: Moon Ho Choi, Gyeong Jae Heo, Hyun Jong Yu, Seung Hyun Choi, Yu Gyeong Chun
  • Patent number: 11978907
    Abstract: Disclosed are a positive electrode for a lithium secondary battery, a winding element for a lithium secondary battery, and a lithium secondary battery, wherein the positive electrode includes a positive active material and a mixing binder including a first binder, a second binder, and a third binder, the first binder includes at least one selected from copolymers including polyvinylidene fluoride, acid-modified polyvinylidene fluoride, and acid-modified polyvinylidene fluoride, and the mixing binder includes the first binder at a proportion of 30 wt % to 60 wt % relative to the total weight of the mixing binder, and has a tensile modulus of 200 MPa to 600 MPa.
    Type: Grant
    Filed: February 16, 2017
    Date of Patent: May 7, 2024
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Keisuke Nomura, Hironobu Fukahori
  • Patent number: 11970401
    Abstract: The formation of amorphous silicon for use in, for example, lithium-ion batteries is disclosed. The process can include milling a plurality of silicon nanocrystals having an average particle diameter and a percent crystallinity greater than about 60%, in a unit designed to reduce the average particle diameter to the same or a larger size, thereby forming a plurality of amorphous silicon nanoparticles having about the same average particle diameter as the silicon nanocrystals and a percent crystallinity of less than about 50%.
    Type: Grant
    Filed: July 30, 2020
    Date of Patent: April 30, 2024
    Assignee: Advano, Inc.
    Inventors: Gregory Alan Marus, Jonathan Goodman, Meysam Shahami
  • Patent number: 11973224
    Abstract: A battery comprising an acidified metal oxide (“AMO”) material, preferably in monodisperse nanoparticulate form 20 nm or less in size, having a pH<7 when suspended in a 5 wt % aqueous solution and a Hammett function H0>?12, at least on its surface.
    Type: Grant
    Filed: February 13, 2023
    Date of Patent: April 30, 2024
    Assignee: HHeLi, LLC
    Inventor: Paige L. Johnson
  • Patent number: 11967711
    Abstract: A compound of the general formula: wherein x is equal to or greater than 0.175 and equal to or less than 0.325 and y is equal to or greater than 0.05 and equal to or less than 0.35. In another embodiment, x is equal to zero and y is greater than 0.12 and equal to or less than 0.4. The compound is also formulated into a positive electrode for use in an electrochemical cell.
    Type: Grant
    Filed: December 18, 2018
    Date of Patent: April 23, 2024
    Assignee: Dyson Technology Limited
    Inventors: Matthew Robert Roberts, Peter George Bruce, Niccolo Guerrini, Rong Hao, Francis Gachau Kinyanjui
  • Patent number: 11958939
    Abstract: A polyimide precursor solution contains: an aqueous solvent containing water; particles; and a polyimide precursor, wherein the polyimide precursor has a high molecular weight region A containing a high molecular weight side maximum value and a low molecular weight region B containing a low molecular weight side maximum value in an elution curve obtained by gel permeation chromatography, a weight average molecular weight in the high molecular weight region A is 50,000 or more, a weight average molecular weight in the low molecular weight region B is 10,000 or more and 30,000 or less, and a value of a/(a+b) is 0.60 or more and 0.98 or less in which a represents an area of the high molecular weight region A and b represents an area of the low molecular weight region B.
    Type: Grant
    Filed: August 16, 2021
    Date of Patent: April 16, 2024
    Assignee: FUJIFILM Business Innovation Corp.
    Inventors: Kosuke Nakada, Shigeru Seitoku, Takeshi Iwanaga, Tomoyo Okubo, Hajime Sugahara, Hidekazu Hirose
  • Patent number: 11962008
    Abstract: A lead-based alloy containing alloying additions of bismuth, antimony, arsenic, and tin is used for the production of doped leady oxides, lead-acid battery active materials, lead-acid battery electrodes, and lead-acid batteries.
    Type: Grant
    Filed: December 5, 2022
    Date of Patent: April 16, 2024
    Assignee: RSR TECHNOLOGIES, INC.
    Inventors: R. David Prengaman, Timothy W. Ellis, Matthew T. Raiford
  • Patent number: 11955631
    Abstract: A composite cathode active material, a cathode and a lithium battery each including the composite cathode active material, and a method of manufacturing the composite cathode active material. The composite cathode active material includes a core including a plurality of primary particles, and a shell disposed on the core, wherein a primary particle of the plurality of primary particles includes a lithium nickel transition metal oxide, the shell includes a first composition and a second composition, wherein the first composition contains a first metal and the second composition contains a second metal, wherein the first metal includes a metal of Groups 2, 4, 5, and 7 to 15, the second metal includes a metal of Group 3, and the first composition includes a first phase and the second composition includes a second phase that is distinguishable from the first phase.
    Type: Grant
    Filed: March 20, 2019
    Date of Patent: April 9, 2024
    Assignees: SAMSUNG ELECTRONICS CO., LTD., SAMSUNG SDI.CO., LTD.
    Inventors: Dongwook Shin, Sukgi Hong, Jinhwan Park, Byungjin Choi