Having Utility As A Reactive Material In An Electrochemical Cell; E.g., Battery, Etc. Patents (Class 252/182.1)
  • Publication number: 20150010823
    Abstract: In an aspect, a positive active material for a rechargeable lithium battery including overlithiated layered oxide (OLO), a method of preparing the same, and a positive electrode for a rechargeable lithium battery and a rechargeable lithium battery including the same is disclosed.
    Type: Application
    Filed: June 10, 2014
    Publication date: January 8, 2015
    Inventors: Byong-Yong Yu, Jay-Hyok Song, Jun-Seok Park, Andrei Kapylou, Chang-Wook Kim, Yong-Chan You, Sun-Ho Kang
  • Patent number: 8926860
    Abstract: The present invention relates to a cathode active material with whole particle concentration gradient for a lithium secondary battery, a method for preparing same, and a lithium secondary battery having same, and more specifically, to a composite cathode active material, a method for manufacturing same, and a lithium secondary battery having same, the composite cathode active material having excellent lifetime characteristics and charge/discharge characteristics through the stabilization of crystal structure as the concentration of a metal comprising the cathode active material shows concentration gradient in the whole particle, and having thermostability even in high temperatures.
    Type: Grant
    Filed: December 27, 2011
    Date of Patent: January 6, 2015
    Assignee: Industry-University Cooperation Foundation Hanyang University
    Inventors: Yang-Kook Sun, Hyung Joo Noh
  • Patent number: 8927152
    Abstract: Provided is a binder for an electrode of a lithium rechargeable battery including a copolymer of Chemical Formula 1, which increases adhesion between the electrode and an active material by employing a copolymer based on polyacrylamide, while having excellent heat resistance and mechanical strength, an electrode for a rechargeable battery including the same, and a rechargeable battery including the electrode. The binder and electrode can improve charge and discharge cycle life characteristics of the rechargeable battery.
    Type: Grant
    Filed: March 13, 2013
    Date of Patent: January 6, 2015
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Byungjoo Chung, Namseon Kim, Yangsoo Kim, Kwangshik Choi
  • Publication number: 20150001442
    Abstract: Provided is a method for synthesizing air electrode powder, which uses instead of an organic solvent lanthanum-nitrate, strontium-nitrate, cobalt-nitrate, and iron-nitrate, which are affordable and can undergo water-based synthesis, by controlling additional mol ratio and a synthesis temperature of a chelate agent and an esterification reaction accelerating agent instead of complex process controlling conditions, such as a hydrolysis condition and pH in order to control particle shape.
    Type: Application
    Filed: October 9, 2012
    Publication date: January 1, 2015
    Applicant: Korea Institute of Industrial Technology
    Inventors: Ho Sung Kim, Ju Hee Kang, Hyo Sin Kim, Jin Hun Jo, Yeong Mok Kim, Sang Hun Heo, Ik Hyun Oh
  • Publication number: 20150004486
    Abstract: It is possible to form a secondary cell having excellent charge-discharge cycle properties and to improve dispersibility of the active substance and the auxiliary conductor and pliability and close adhesion of the electrodes by using a composition for forming a secondary cell electrode that comprises at least one of an electrode active substance (A) and a carbon material (B) that serves as an auxiliary conductor, a water-soluble additive (C) that is a water-soluble additive formed from carbon atoms, oxygen atoms, and hydrogen atoms and that has 2 to 20 oxygen atoms per 1 molecule, and water (D).
    Type: Application
    Filed: February 1, 2013
    Publication date: January 1, 2015
    Inventors: Yasuyuki Moroishi, Issey Haruta, Akihiko Hatemata
  • Publication number: 20150004489
    Abstract: A method of preparing a positive active material for a lithium secondary battery represented by the following Chemical Formula 1 (LiwNixCoyMn1-x-y-zMzO2) includes: (a) preparing a metal salt aqueous solution including a lithium raw material, a manganese raw material, a nickel raw material, and a cobalt raw material; (b) wet-pulverizing the metal salt aqueous solution using beads having a particle diameter of 0.05 to 0.30 mm at 2000 to 6000 rpm for 2 to 12 hours to prepare a slurry; (c) adding a carbon source to the slurry; (d) spray-drying the slurry of the step (c) to prepare a mixed powder; and (e) heat-treating the mixed powder.
    Type: Application
    Filed: September 21, 2012
    Publication date: January 1, 2015
    Applicant: KOREA ELECTRONICS TECHNOLOGY INSTITUTE
    Inventors: Jun Ho Song, Young Jun Kim, Jae-Hun Kim, Kyoung Joon Lee, Min-Woo Lee
  • Publication number: 20150004491
    Abstract: The present invention provides a positive-electrode active material for non-aqueous secondary battery comprising a sodium transition metal composite oxide represented by Formula: NaxFe1-yMyO2, wherein 0.4?x?0.7, 0.25?y<1.0, and M is at least one element selected from the group consisting of manganese, cobalt and nickel, the sodium transition metal composite oxide having a crystal structure substantially composed of P63/mmc alone.
    Type: Application
    Filed: June 27, 2014
    Publication date: January 1, 2015
    Inventors: Hideaki YOSHIWARA, Tsutomu YAMADA, Masahiro MURAYAMA
  • Patent number: 8920683
    Abstract: A sputtering target which is composed of a sintered body of an oxide which contains at least indium, tin, and zinc and includes a spinel structure compound of Zn2SnO4 and a bixbyite structure compound of In2O3. A sputtering target includes indium, tin, zinc, and oxygen with only a peak ascribed to a bixbyite structure compound being substantially observed by X-ray diffraction (XRD).
    Type: Grant
    Filed: December 13, 2012
    Date of Patent: December 30, 2014
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Koki Yano, Kazuyoshi Inoue, Nobuo Tanaka, Akira Kaijo, Satoshi Umeno
  • Patent number: 8920765
    Abstract: A graphite material suitable as an electrode material for non-aqueous electrolytic secondary batteries; a method for producing the same and a carbon material for battery electrodes; and a secondary battery. The graphite material includes crystallite graphite particles wherein an oxygen amount (a) (mass %) in a region from a particle surface of the graphite material to a depth of 40 nm is within a range of 0.010?(a)?0.04 as determined by a peak intensity of O1s obtained by HAX-PES measurement using a hard X-ray of 7,940 eV.
    Type: Grant
    Filed: October 5, 2012
    Date of Patent: December 30, 2014
    Assignee: Showa Denko K.K.
    Inventors: Akinori Sudoh, Yuuichi Kamijou, Masako Tanaka, Tomohiro Abe
  • Patent number: 8920976
    Abstract: A nonaqueous electrolyte secondary battery disclosed in the present application includes: a positive electrode capable of absorbing and releasing lithium, containing a positive electrode active material composed of a lithium-containing transition metal oxide having a layered crystalline structure; and a negative electrode capable of absorbing and releasing lithium, containing a negative electrode active material composed of a lithium-containing transition metal oxide obtained by substituting some of Ti element of a lithium-containing titanium oxide having a spinel crystalline structure with one or more element different from Ti, wherein a retention of the negative electrode is set to be greater than a retention of the positive electrode, and an irreversible capacity rate of the negative electrode is set to be greater than an irreversible capacity rate of the positive electrode, whereby a discharge ends by negative electrode limitation.
    Type: Grant
    Filed: April 18, 2012
    Date of Patent: December 30, 2014
    Assignee: Panasonic Corporation
    Inventors: Natsumi Goto, Takashi Takeuchi, Masaki Hasegawa
  • Patent number: 8920687
    Abstract: Provided is a cathode active material for nonaqueous electrolyte rechargeable batteries which allows production of batteries having improved load characteristics with stable quality, and also allows production of batteries having high capacity. Also provided are a cathode for nonaqueous electrolyte rechargeable batteries and a nonaqueous electrolyte rechargeable battery. The cathode active material includes secondary particles each composed of a plurality of primary particles, and/or single crystal grains, and has a specific surface area of not smaller than 20 m2/g and smaller than 0.50 m2/g, wherein average number A represented by formula (1) is not less than 1 and not more than 10: A=(m+p)/(m+s) (m: the number of single crystal grains; p: the number of primary particles composing the secondary particles; s: the number of secondary particles).
    Type: Grant
    Filed: December 26, 2007
    Date of Patent: December 30, 2014
    Assignee: Santoku Corporation
    Inventors: Tetsu Fujiwara, Masayuki Moritaka, Akihito Kaneko
  • Patent number: 8920672
    Abstract: The present invention relates to negative active materials for rechargeable lithium batteries, manufacturing methods thereof, and rechargeable lithium batteries including the negative active materials. A negative active material for a rechargeable lithium battery includes a core including a material capable of carrying out reversible oxidation and reduction reactions and a coating layer formed on the core. The coating layer has a reticular structure.
    Type: Grant
    Filed: January 10, 2012
    Date of Patent: December 30, 2014
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Nam-Soon Choi, Sung-Soo Kim, Yong-Mook Kang, Kyoung-Han Yew
  • Publication number: 20140377655
    Abstract: A composite cathode active material, a method of preparing the composite cathode active material, a cathode including the composite cathode active material, and a lithium battery including the cathode. The composite cathode active material includes a lithium intercalatable material; and a garnet oxide, wherein an amount of the garnet oxide is about 1.9 wt % or less, based on a total weight of the composite cathode active material.
    Type: Application
    Filed: April 25, 2014
    Publication date: December 25, 2014
    Applicant: Samsung Electronics Co., Ltd.
    Inventors: Jun-young MUN, Jae-myung LEE, Gue-sung KIM, Yoon-sok KANG, Myung-hoon KIM, Jun-ho PARK, Jin-hwan PARK, Jae-gu YOON, Byung-jin CHOI
  • Publication number: 20140374652
    Abstract: A hydrogen storage alloy material includes a primary phase having an ABx type structure and a secondary phase having a B2 structure that enhances the electrochemical properties of the alloy. The A component of the primary phase includes La and Ce, and the B component of the primary phase includes Ni, Co, Al, and Mn. The secondary phase may include Al, Mn, and Ni. Also disclosed are battery systems including the alloy material.
    Type: Application
    Filed: June 25, 2013
    Publication date: December 25, 2014
    Applicant: Ovonic Battery Company, Inc.
    Inventors: Kwo-hsiung Young, Benjamin Chao
  • Publication number: 20140377653
    Abstract: The present invention relates to a method of preparing a porous silicon-based negative electrode active material comprising: mixing a porous silica (SiO2) and an aluminum powder; oxidizing all or part of the aluminum powder as an aluminum oxide while at the same time reducing all or part of the porous silica as a porous silicon (Si) by heat-treating a mixture of the porous silica with the aluminum powder, a negative electrode active material, and a rechargeable lithium battery including the same.
    Type: Application
    Filed: June 20, 2014
    Publication date: December 25, 2014
    Inventors: Soojin PARK, Sin Ho CHOI, Ji Hyun YOON, Byoung Man BANG
  • Publication number: 20140377660
    Abstract: Provided is a lithium composite oxide having a uniform and suitable particle size and high specific surface area due to a hollow structure that can be produced on an industrial scale. A nickel composite hydroxide as a raw material thereof is obtained controlling the particle size distribution of the nickel composite hydroxide, the nickel composite hydroxide having a structure comprising a center section that comprises minute primary particles, and an outer-shell section that exists on the outside of the center section and comprises plate shaped primary particles that are larger than the primary particles of the center section, by a nucleation process and a particle growth process that are separated by controlling the pH during crystallization, and by controlling the reaction atmosphere in each process and the manganese content in a metal compound that is supplied in each process.
    Type: Application
    Filed: December 20, 2012
    Publication date: December 25, 2014
    Inventors: Atsushi Fukui, Hiroyuki Toya
  • Publication number: 20140374651
    Abstract: A structurally and compositionally disordered electrochemically active alloy material is provided with excellent capacity and cycle life, as well as superior high-rate dischargeability. The alloy employs a disordered A2B4+x(AB5) structure, wherein x is a number between 1 and 4. This crystal structure combined with a tailored amount of electrochemically active AB5 secondary phase material produces superior electrochemical properties.
    Type: Application
    Filed: June 25, 2013
    Publication date: December 25, 2014
    Applicant: Ovonic Battery Company, Inc.
    Inventors: Kwo-hsiung Young, Taihei Ouchi
  • Publication number: 20140377662
    Abstract: Disclosed are compositions containing a formula of LixTiyV1Bz wherein x, y, and z are real numbers greater than zero. In certain embodiments, x is not greater than 7, and y is not greater than 6, or a combination thereof. The composition may be a microporous aerogel, a mesoporous aerogel, a crystalline structure, or a combination thereof. In certain embodiments, the composition may be an aerogel, and a surface of the aerogel comprises microcrystals, nanocrystals or a combination thereof. The compositions have very low densities. Also disclosed are methods to produce the composition and use of the composition in energy storage devices.
    Type: Application
    Filed: June 19, 2014
    Publication date: December 25, 2014
    Inventor: Nilanjan DEB
  • Publication number: 20140377664
    Abstract: An all-solid-state lithium battery, thermo-electromechanical activation of Li2S in sulfide based solid state electrolyte with transition metal sulfides, and electromechanical evolution of a bulk-type all-solid-state iron sulfur cathode, are disclosed. An example all-solid-state lithium battery includes a cathode having a transition metal sulfide mixed with elemental sulfur to increase electrical conductivity. In one example method of in-situ electomechanical synthesis of Pyrite (FeS2) from Sulfide (FeS) and elemental sulfur (S) precursors for operation of a solid-state lithium battery, FeS+S composite electrodes are cycled at moderately elevated temperatures.
    Type: Application
    Filed: January 9, 2013
    Publication date: December 25, 2014
    Inventors: Thomas A. Yersak, Se-Hee Lee, Conrad Stoldt
  • Patent number: 8916062
    Abstract: A composition for forming an electrode. The composition includes a metal fluoride, such as copper fluoride, and a matrix material. The matrix material adds capacity to the electrode. The copper fluoride compound is characterized by a first voltage range in which the copper fluoride compound is electrochemically active and the matrix material characterized by a second voltage range in which the matrix material is electrochemically active and substantially stable. A method for forming the composition is included.
    Type: Grant
    Filed: March 19, 2014
    Date of Patent: December 23, 2014
    Assignee: Wildcat Discovery Technologies, Inc.
    Inventors: Wei Tong, Steven Kaye, David Keogh, Cory O'Neill
  • Publication number: 20140370390
    Abstract: Disclosed are a method for preparing a positive electrode active material for a lithium secondary battery and a positive electrode active material for a lithium secondary battery, the method including: preparing a mixture of a precursor represented by Chemical Formula 1 below, a lithium composite oxide represented by Chemical Formula 2 below and capable of intercalating/deintercalating lithium ions, and a lithium feed material; and firing the prepared mixture: A(OH)2-a??[Chemical Formula 1] Li[LizA(1-z-a)Da]EbO2-b??[Chemical Formula 2]
    Type: Application
    Filed: August 29, 2014
    Publication date: December 18, 2014
    Inventors: Su An Choi, Seung Won Lee, Sang-Hoon Jeon
  • Publication number: 20140370383
    Abstract: Disclosed is a composition comprising an ethylene copolymer and a halogenated polymer, wherein the ethylene copolymer comprises or is produced from repeat units derived from ethylene and a comonomer selected from the group consisting of an ?,?-unsaturated monocarboxylic acid or its derivative, an ?,?-unsaturated dicarboxylic acid or its derivative, an epoxide-containing monomer, a vinyl ester, or combinations of two or more thereof; and the composition can further comprise a curing agent to crosslink the ethylene copolymer. The composition is useful as a binder for a lithium ion battery.
    Type: Application
    Filed: June 11, 2014
    Publication date: December 18, 2014
    Inventors: CHONGSOO LIM, Daniel P. Fore
  • Publication number: 20140367609
    Abstract: An active material for a lithium secondary battery, a method of manufacturing the same, an electrode including the active material, and a lithium secondary battery including the electrode, the active material including a lithium composite oxide represented by the following Formula 1: Li[LixNiaCobMnc]O2-yFy.
    Type: Application
    Filed: September 26, 2013
    Publication date: December 18, 2014
    Applicant: SAMSUNG SDI CO., LTD.
    Inventors: Andrei KAPYLOU, Jay-Hyok SONG, Evgeniya MATULEVICH, Chang-Wook KIM, Yong-Chan YOU, Sun-Ho KANG
  • Publication number: 20140370187
    Abstract: A method is provided for synthesizing iron hexacyanoferrate (FeHCF). The method forms a first solution of a ferrocyanide source [A4Fe(CN)6.PH2O] material dissolved in a first solvent, where “A” is an alkali metal ion. A second solution is formed of a Fe(II) source dissolved in a second solvent. A reducing agent is added and, optionally, an alkali metal salt. The first and second solutions may be purged with an inert gas. The second solution is combined with the first solution to form a third solution in a low oxygen environment. The third solution is agitated in a low oxygen environment, and AX+1Fe2(CN)6.ZH2O is formed, where X is in the range of 0 to 1. The method isolates the AX+1Fe2(CN)6.ZH2O from the third solution, and dries the AX+1Fe2(CN)6.ZH2O under vacuum at a temperature greater than 60 degrees C.
    Type: Application
    Filed: August 28, 2014
    Publication date: December 18, 2014
    Inventors: Sean Vail, Yuhao Lu, Jong-Jan Lee
  • Publication number: 20140367610
    Abstract: An active material for a secondary battery with improved life characteristics is provided. An active material for a secondary battery according to this exemplary embodiment is an active material for a secondary battery represented by Lia1(Nix1Mn2-x1-y1-x1M1y1 M2z1)O4 wherein 0<x1, 0<y1, 0<z1, x1+y1+z1<2, and 0?a1?2; M1 is at least one selected from Si and Ti; and M2 is at least one selected from Li, B, Mg, Na, K, and Ca. In addition, an active material for a secondary battery according to this exemplary embodiment is an active material for a secondary battery represented by Lia2(Nix2Mn2-x2-y2-z2M3y2M4z2)O4 wherein 0<x2, 0<y2, 0<z2<0.03, x2+y2+z2<2, and 0?a2?2; M3 is at least one selected from Si and Ti; and M4 is at least one selected from Li, B, Mg, Al, Na, K, and Ca, and includes at least Al.
    Type: Application
    Filed: March 29, 2012
    Publication date: December 18, 2014
    Inventors: Takehiro Noguchi, Hideaki Sasaki, Makiko Uehara
  • Publication number: 20140361216
    Abstract: Disclosed is a cathode active material for a lithium ion secondary battery which includes a lithium manganese borate compound and a manganese oxide. The lithium manganese borate compound contains a larger amount of lithium than conventional lithium manganese borate compounds. Therefore, a larger amount of lithium is deintercalated in a battery including the cathode active material, and as a result, the specific capacity of the battery reaches 100-160 mAh/g, which is much higher than that of conventional lithium ion secondary batteries (<80 mAh/g). Also disclosed is a method for producing the cathode active material.
    Type: Application
    Filed: September 26, 2013
    Publication date: December 11, 2014
    Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY
    Inventors: Kyung Yoon CHUNG, Ji Ung KIM, Ji-Young KIM, Byung Won CHO, Won Young CHANG
  • Publication number: 20140363739
    Abstract: There is provided a preparation method of a sodium vanadium oxide-based (Na1+xV1-xO2) anode material for a sodium ion secondary battery synthesized by mixing particles of precursors such as sodium carbonate (Na2CO3) and vanadium oxide (V2O3) and pyrolyzing a mixture in a mixed gas atmosphere composed of 90 mol % of nitrogen gas and 10 mol % of hydrogen gas through a solid-state reaction. The sodium vanadium oxide-based anode material prepared according to the present invention shows a small change in volume caused by an initial irreversible capacity and continuous charge/discharge reactions, and thus it is useful for providing a next-generation sodium ion secondary battery having stable charge/discharge characteristics and cycle performance.
    Type: Application
    Filed: August 14, 2013
    Publication date: December 11, 2014
    Applicant: Korea Institute Of Science And Technology
    Inventors: Hyung Sun KIM, Byung Won CHO, Si Hyoung OH, Ju Hyeon AHN, Yong Ho LEE, Won Chang CHOI
  • Publication number: 20140363737
    Abstract: A lithium ion secondary battery in which a high capacity, as well as a high level of safety, is achieved, by using an oxide material containing Li and Fe for a negative electrode active material. In the lithium ion secondary battery, the negative electrode active material is a mixed phase of LiFeO2 and LiFe5O8 and a material in which the value calculated as the ratio of the height of a diffraction peak belonging to LiFeO2 (200) plane and the height of a diffraction peak belonging to LiFe5O8 (311) plane, which are obtained by X-ray diffraction method, is 0.18 to 20.4.
    Type: Application
    Filed: December 5, 2012
    Publication date: December 11, 2014
    Applicant: Hitachi, Ltd.
    Inventor: Kazushige Kohno
  • Publication number: 20140361226
    Abstract: This invention relates to an anode active material comprising at least one iron oxide selected from the group consisting of amorphous iron oxides, ferrihydrite, and lepidocrocite. The invention also relates to a lithium ion secondary battery anode material comprising the anode active material as a constituent component, a lithium ion secondary battery anode comprising the lithium ion secondary battery anode material, and a lithium ion secondary battery comprising the lithium ion secondary battery anode.
    Type: Application
    Filed: December 27, 2012
    Publication date: December 11, 2014
    Applicants: National University Corporation Okayama University, Kyoto University, Tokyo Institute of Technology
    Inventors: Jun Takada, Hideki Hashimoto, Tatsuo Fujii, Makoto Nakanishi, Ryoji Kanno, Genki Kobayashi, Mikio Takano
  • Publication number: 20140363715
    Abstract: To provide a binder for a storage battery device, whereby good adhesion in an electrode and flexibility are obtainable, and it is possible to realize good charge and discharge characteristics when used for a secondary battery. A binder for a storage battery device, which is made of a fluorinated copolymer comprising structural units (a) derived from tetrafluoroethylene and structural units (b) derived from propylene, wherein the molar ratio (a)/(b) is from 40/60 to 50/50, and the total of the structural units (a) and (b) is at least 90 mol % in all structural units.
    Type: Application
    Filed: August 26, 2014
    Publication date: December 11, 2014
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Mizuna TOYODA, Takehiro KOSE, Hiroki NAGAI
  • Patent number: 8906551
    Abstract: The present disclosure is directed at an electrode for a battery wherein the electrode comprises clathrate alloys of silicon, germanium or tin. In method form, the present disclosure is directed at methods of forming clathrate alloys of silicon, germanium or tin which methods lead to the formation of empty cage structures suitable for use as electrodes in rechargeable type batteries.
    Type: Grant
    Filed: April 20, 2012
    Date of Patent: December 9, 2014
    Assignee: Southwest Research Institute
    Inventors: Candace K. Chan, Michael A. Miller, Kwai S. Chan
  • Patent number: 8906557
    Abstract: Anode active materials and methods of preparing the same are provided. One anode active material includes a carbonaceous material capable of improving battery cycle characteristics. The carbonaceous material bonds to and coats metal active material particles and fibrous metallic particles to suppress volumetric changes.
    Type: Grant
    Filed: March 22, 2007
    Date of Patent: December 9, 2014
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Gue-sung Kim, Yong-nam Ham, Han-su Kim, Dong-min Im
  • Patent number: 8906254
    Abstract: Disclosed are a cathode material for a secondary battery, and a manufacturing method of the same. The cathode material includes a lithium manganese phosphate LiMnPO4/sodium manganese fluorophosphate Na2MnPO4F composite, in which the LiMnPO4 and Na2MnPO4F have different crystal structures. Additionally, the method of manufacturing the cathode material may be done in a single step through a hydrothermal synthesis, which greatly reduces the time and cost of production. Additionally, the disclosure provides that the electric conductivity of the cathode material may be improved through carbon coating, thereby providing a cathode material with excellent electrochemical activity.
    Type: Grant
    Filed: May 31, 2012
    Date of Patent: December 9, 2014
    Assignees: Hyundai Motor Company, Korea Electronics Technology Institute
    Inventors: Sa Heum Kim, Dong Gun Kim, Young Jun Kim, Jun Ho Song, Woo Suk Cho, Jeom Soo Kim, Dong Jin Kim
  • Patent number: 8906255
    Abstract: The lithium-ion secondary battery in which a positive electrode contains Lia(M)b(PO4)cFd (M=VO or V, 0.9?a?3.3, 0.9?b?2.2, 0.9?c?3.3, 0?d?2.0) as an active material and 1 to 300 ppm of sulfur is used.
    Type: Grant
    Filed: March 18, 2013
    Date of Patent: December 9, 2014
    Assignee: TDK Corporation
    Inventors: Atsushi Sano, Keitaro Otsuki
  • Publication number: 20140356702
    Abstract: Provided is a positive electrode for an alkaline storage battery, capable of achieving a high charge efficiency over a wide range of temperature including high temperatures. The positive electrode includes a positive electrode material mixture including: a nickel oxide as a positive electrode active material; a first additive; and a second additive differing from the first additive. An amount of sulfate ions SO42? remaining in the nickel oxide is 0.45 mass % or less. The first additive is a compound including at least one selected from the group consisting of ytterbium, indium, calcium, barium, beryllium, antimony, erbium, thulium, and lutetium. The second additive is a compound including at least one selected from the group consisting of titanium, vanadium, scandium, niobium, zirconium, and zinc.
    Type: Application
    Filed: March 4, 2013
    Publication date: December 4, 2014
    Inventor: Kiyoshi Hayashi
  • Publication number: 20140353555
    Abstract: A method of manufacturing a multicomponent lithium phosphate compound particle with an olivine structure of formula LiyM11-ZM2ZPO4, M1 is Fe, Mn or Co; Y satisfies 0.9?Y?1.2; M2 is Mn, Co, Mg, Ti or Al; and Z satisfies 0<Z?0.1, in which the M2 concentration is continuously lowered from a surface of the particle to a core portion of the particle. The method includes mixing a lithium M1 phosphate compound with an olivine structure of formula LiXM1PO4, M1 is Fe, Mn or Co, and X satisfies 0.9?X?1.2, and a precursor of a lithium M2 phosphate compound with an olivine structure of formula LiXM2PO4, M2 is Mn, Co, Mg, Ti or Al, and X satisfies 0.9?X?1.2, to form a mixture; and subjecting the mixture to heating in an inert atmosphere or a vacuum.
    Type: Application
    Filed: August 14, 2014
    Publication date: December 4, 2014
    Applicants: THE FURUKAWA BATTERY CO., LTD., SUMITOMO OSAKA CEMENT CO., LTD., TOKYO METROPOLITAN UNIVERSITY
    Inventors: Hidetoshi ABE, Tomonori SUZUKI, Takashi EGURO, Kiyoshi KANAMURA, Mitsumasa SAITO
  • Publication number: 20140353547
    Abstract: Provided is a new spinel type lithium manganese transition metal oxide for use in lithium batteries, which can increase the capacity retention ratio during cycling, and can increase the power output retention ratio during cycling. Disclosed is a spinel type lithium manganese transition metal oxide having an angle of repose of 50° to 75°, and having an amount of moisture (25° C. to 300° C.) measured by the Karl Fischer method of more than 0 ppm and less than 400 ppm.
    Type: Application
    Filed: December 27, 2012
    Publication date: December 4, 2014
    Inventors: Tetsuya Mitsumoto, Hitohiko Ide, Shinya Kagei, Yoshimi Hata, Natsumi Shibamura
  • Publication number: 20140353548
    Abstract: The present invention provides a LiCoO2-containing powder comprising LiCoO2 having a stoichiometric composition via heat treatment of a lithium cobalt oxide and a lithium buffer material to make equilibrium of a lithium chemical potential therebetween; a lithium buffer material which acts as a Li acceptor or a Li donor to remove or supplement Li-excess or Li-deficiency, coexisting with a stoichiometric lithium metal oxide; and a method for preparing a LiCoO2-containing powder. Further, provided is an electrode comprising the above-mentioned LiCoO2-containing powder as an active material, and a rechargeable battery comprising the same electrode. The present invention enables production of a LiCoO2 electrode active material which has improved high-temperature storage properties and high-voltage cycling properties, and is robust in composition fluctuation in the production process.
    Type: Application
    Filed: August 20, 2014
    Publication date: December 4, 2014
    Inventors: Jens M. Paulsen, Sun Sik Shin, Hong-Kyu Park
  • Publication number: 20140356720
    Abstract: A substituted lithium-manganese metal phosphate of formula LiFexMn1-x-yMyPO4 in which M is a bivalent metal from the group Sn, Pb, Zn, Ca, Sr, Ba, Co, Ti and Cd and wherein: x<1, y<0.3 and x+y<1, a process for producing it as well as its use as cathode material in a secondary lithium-ion battery.
    Type: Application
    Filed: January 28, 2011
    Publication date: December 4, 2014
    Applicant: SUED-CHEMIE IP GMBH & CO. KG
    Inventors: Gerhard Nuspl, Nicholas Tran, Jasmin Dollinger, Christian Vogler
  • Publication number: 20140353545
    Abstract: Provided is a method for preparing a lithium mixed transition metal oxide, comprising subjecting Li2CO3 and a mixed transition metal precursor to a solid-state reaction under an oxygen-deficient atmosphere with an oxygen concentration of 10 to 50% to thereby prepare a powdered lithium mixed transition metal oxide having a composition represented by Formula I of LixMyO2 wherein M, x and y are as defined in the specification. Therefore, since the high-Ni lithium mixed transition metal oxide having a given composition can be prepared by a simple solid-state reaction in air, using a raw material that is cheap and easy to handle, the present invention enables industrial-scale production of the lithium mixed transition metal oxide with significantly decreased production costs and high production efficiency.
    Type: Application
    Filed: July 17, 2014
    Publication date: December 4, 2014
    Applicant: LG Chem, Ltd.
    Inventors: Hong-Kyu Park, Sun sik Shin, Sin young Park, Ho suk Shin, Jens M. Paulsen
  • Publication number: 20140356712
    Abstract: Disclosed are a precursor for a rechargeable lithium battery, a positive active material including the same, a preparation method thereof, and a rechargeable lithium battery including the positive active material. More particularly, the present invention relates to a precursor including a sheet-shaped plate having a thickness of about 1 nm to about 30 nm and that is represented by the following Chemical Formula 1. NixCOyMn1-x-y-zMz(OH)2??[Chemical Formula 1] In the above Chemical Formula 1, 0<x<1, 0?y<1, 0.5?1?x?y?z, and 0?z<1, and M is at least one kind of metal selected from the group consisting of Al, Mg, Fe, Cu, Zn, Cr, Ag, Ca, Na, K, In, Ga, Ge, V, Mo, Nb, Si, Ti, and Zr.
    Type: Application
    Filed: September 18, 2012
    Publication date: December 4, 2014
    Inventors: Jun Ho Song, Young Jun Kim, Jeom-Soo Kim, Woo Suk Cho, Jae-Hun Kim, Jun Sung Lee, Jin Hwa Kim, Kyoung Joon Lee
  • Publication number: 20140356708
    Abstract: The present invention is to provide a negative electrode active material for nonaqueous secondary batteries, which prevents increase in negative electrode resistance and improves initial charge/discharge efficiency and the effect of preventing gas generation and which is excellent in cycle characteristics. The present invention relates to a negative electrode active material for nonaqueous secondary batteries, which comprises an active material (A) capable of occluding and releasing lithium ions and an organic compound (B), wherein the organic compound (B) has a basic group and a lithium ion-coordinating group, and has a specific structure (S).
    Type: Application
    Filed: August 14, 2014
    Publication date: December 4, 2014
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Yuuya ARIKAWA, Teruyuki Okayasu, Rie Fujita, Aoi Sakai, Naomi Fujimori, Nobuhiko Ueno, Naoto Maru
  • Publication number: 20140356719
    Abstract: Provided is an electrode active material comprising a nickel-based lithium transition metal oxide (LiMO2) wherein the nickel-based lithium transition metal oxide contains nickel (Ni) and at least one transition metal selected from the group consisting of manganese (Mn) and cobalt (Co), wherein the content of nickel is 50% or higher, based on the total weight of transition metals, and has a layered crystal structure and an average primary diameter of 3 ?m or higher, wherein the amount of Ni2+ taking the lithium site in the layered crystal structure is 5.0 atom % or less.
    Type: Application
    Filed: August 15, 2014
    Publication date: December 4, 2014
    Inventors: Sinyoung PARK, Sung kyun CHANG, Hong-Kyu PARK, Seung Tae HONG, Youngsun CHOI
  • Publication number: 20140353546
    Abstract: A negative electrode active material for an electric device includes an alloy containing, in terms of mass ratio, 35%?Si?78%, 7%?Sn?30%, 0%<Ti?37% and/or 35%?Si?52%, 30%?Sn?51%, 0%<Ti?35%, and inevitable impurities as a residue. The negative electrode active material can be obtained with a multi DC magnetron sputtering apparatus by use of, for example, silicon, tin and titanium as targets. An electric device employing the negative electrode active material can keep a high discharge capacity and ensure a high cycle property.
    Type: Application
    Filed: November 5, 2012
    Publication date: December 4, 2014
    Inventors: Manabu Watanabe, Osamu Tanaka, Masao Yoshida
  • Patent number: 8900490
    Abstract: This invention provides a titanic acid compound-type electrode active material having a high battery capacity and, at the same time, having excellent cycle characteristics. The titanic acid compound exhibits an X-ray diffraction pattern corresponding to a bronze-type titanium dioxide except for a peak for a (003) face and a (?601) face and having a lattice spacing difference between the (003) face and the (?601) face, i.e., d(003)?d(?601), of not more than 0.0040 nm. The titanic acid compound may be produced by reacting a layered alkali metal titanate, represented by a compositional formula MxM?x/3Ti2?x/3O4 wherein M and M?, which may be the same or different, represent an alkali metal; and x is in the range of 0.50 to 1.0, with an acidic compound and then heating the reaction product at a temperature in the range of 250 to 450° C.
    Type: Grant
    Filed: August 27, 2008
    Date of Patent: December 2, 2014
    Assignee: Ishihara Sangyo Kaisha, Ltd.
    Inventors: Hirofumi Taniguchi, Masatoshi Honma
  • Publication number: 20140346394
    Abstract: Provided is an electrode active material comprising a nickel-based lithium transition metal oxide (LiMO2) wherein the nickel-based lithium transition metal oxide contains nickel (Ni) and at least one transition metal selected from the group consisting of manganese (Mn) and cobalt (Co), wherein the content of nickel is 50% or higher, based on the total weight of transition metals, and has a layered crystal structure and an average primary diameter of 3 ?m or higher, wherein the amount of Ni2+ taking the lithium site in the layered crystal structure is 5.0 atom % or less.
    Type: Application
    Filed: August 15, 2014
    Publication date: November 27, 2014
    Inventors: Sinyoung PARK, Sung kyun CHANG, Hong-Kyu PARK, Seung Tae HONG, Youngsun CHOI
  • Publication number: 20140346393
    Abstract: Disclosed is a transition metal precursor used for preparation of lithium composite transition metal oxide, the transition metal precursor comprising a composite transition metal compound represented by the following Formula 1: M(OH1?x)2?yAy/n??(1) wherein M comprises two or more selected from the group consisting of Ni, Co, Mn, Al, Cu, Fe, Mg, B, Cr and second period transition metals; A comprises one or more anions except OH1?x; 0?x?0.5; 0.01?y?0.5; and n is an oxidation number of A. The transition metal precursor according to the present invention contains a specific anion. A lithium composite transition metal oxide prepared using the transition metal precursor comprises the anion homogeneously present on the surface and inside thereof, and a secondary battery based on the lithium composite transition metal oxide thus exerts superior power and lifespan characteristics, and high charge and discharge efficiency.
    Type: Application
    Filed: August 6, 2014
    Publication date: November 27, 2014
    Inventors: Byung Chun Park, Ho Suk Shin, Sung-Kyun Chang, Seong Hoon Kang, Dong Hun Lee, Sang Min Park
  • Publication number: 20140349184
    Abstract: The presently disclosed and/or claimed inventive process(es), procedure(s), method(s), product(s), result(s), and/or concept(s) (collectively hereinafter referred to as the “presently disclosed and/or claimed inventive concept(s)”) relates generally to the composition of a binder for use in battery electrodes and methods of preparing such. More particularly, but not by way of limitation, the presently disclosed and/or claimed inventive concept(s) relates to a binder composition containing an ionizable water soluble polymer and a redispersible powder containing a latex, a protective colloid, and an anticaking agent for use in the production and manufacture of electrodes of a lithium ion battery. Additionally, the presently disclosed and/or claimed inventive concept(s) relates generally to the compositions and methods of making electrodes, both anodes and cathodes, with a binder composition containing an ionizable water soluble polymer and a redispersible powder.
    Type: Application
    Filed: May 21, 2014
    Publication date: November 27, 2014
    Applicant: HERCULES CORPORATED
    Inventors: Sung Gun Chu, Alan E Goliaszewski
  • Publication number: 20140346392
    Abstract: Provided is a method for manufacturing a cathode active material for a lithium secondary battery, the method including heat-treating a precursor aqueous solution containing a lithium precursor, a transition metal precursor, and an organic acid containing a carboxyl group, and having a chelation index (C.I) value less than 1 and 0.5 or more, wherein the chelation index value is defined by transmittance of a peak located in a wavenumber from 1,700 to 1,710 cm?1 and transmittance of a peak located in a wavenumber from 1,550 to 1,610 cm?1 in Fourier transform infrared (FTIR) spectroscopy spectrum.
    Type: Application
    Filed: December 6, 2012
    Publication date: November 27, 2014
    Inventors: Jung In Yeon, Kook Hyun Han, Min Gu Kang, Seong Ho Lee
  • Publication number: 20140349185
    Abstract: A binder resin composition for secondary battery electrodes is described as containing a polymer (A) that has a structural unit represented by general formula (1) and a water-insoluble particulate polymer (B-1) and/or a water-soluble polymer (B-2) where (A), (B-1) and (B-2) are defined as described. A slurry for secondary battery electrodes contains the binder resin composition, an active material and a solvent. An electrode for secondary batteries is provided with a collector and an electrode layer that is arranged on the collector, where the electrode layer contains an active material and the binder resin composition. Alternatively, the electrode layer is obtained by applying the slurry for secondary battery electrodes to the collector, and drying the slurry thereon.
    Type: Application
    Filed: January 11, 2013
    Publication date: November 27, 2014
    Applicant: MITSUBISHI RAYON CO., LTD.
    Inventors: Fumino Momose, Haruki Okada, Ayako Shimonaka, Mitsufumi Nodono, Daisuke Fujikawa, Hikaru Momose, Akihiro Ishii