Absorptive, Or Bindive, And Chemically Yieldive (e.g., Ion Exchanger) Patents (Class 252/184)
  • Patent number: 11994499
    Abstract: The present disclosure relates to the determination of analytes in a sample using chromatography. The present disclosure provides methods of separating an analyte from a sample. The method includes introducing a sample comprising the analytes into a chromatographic system. The chromatographic system has a flow path disposed in an interior of the chromatographic system, at least a portion of the flow path having an active coating, and a chromatographic column having a stationary phase material in an interior of the chromatographic column that facilitates separation of the analytes in the sample through interaction with at least one analyte in the sample. The active coating is selected to interact with at least one analyte in the sample through (1) a repulsive force, (2) a secondary interaction, or (3) a retention mechanism distinct from the interaction with the stationary phase material.
    Type: Grant
    Filed: February 25, 2020
    Date of Patent: May 28, 2024
    Inventors: Matthew A. Lauber, Martin Gilar, Mathew H. DeLano, Michael Donegan
  • Patent number: 11850570
    Abstract: Supported amine polymer adsorbents based on polymers containing only or primarily primary amines sites are to be used as regenerable adsorbents for CO.sub.2 capture from ultra-dilute gas streams, such as ambient air, or from mixtures of gases containing preferably at least 10% oxygen. and can also be useful for use at the moderate gas pressures found in typical post-combustion capture processes, such as flue gas from large point sources such as coal-fired power plants. Preferred supported solid amine adsorbents of this invention are based on poly(allylamine) (“PAA”) and poly(vinyl amine) (“PVAm”), both of which are linear polymers, and their derivatives, containing substantially all primary amine groups, supported on substrates. Preferred such substrates include silica mesocellular foam (MCF) and mesoporous-.gamma.-alumina, as well on mesoporous-.gamma.-alumina coated throughout the pores of MCF, most preferably of monolithic structure.
    Type: Grant
    Filed: July 12, 2021
    Date of Patent: December 26, 2023
    Assignee: Georgia Tech Research Corporation
    Inventors: Ratayakorn Khunsupat, Christopher W. Jones, Sumit Bali
  • Patent number: 11707708
    Abstract: A method for capturing carbon dioxide includes contacting a carbon dioxide lean gas mixture with water. One or more acid gas impurities may pass from the carbon dioxide lean gas mixture to the water to form a gas mixture and an aqueous effluent. The gas mixture is passed to a pressure swing adsorption system or a temperature swing adsorption system to increase a concentration of carbon dioxide in the gas mixture to form a carbon dioxide enriched gas mixture. The carbon dioxide enriched gas mixture is contacted with the aqueous effluent in a carbon dioxide scrubber. Carbon dioxide passes from the carbon dioxide enriched gas mixture to the aqueous effluent to form a stripped gas and acid gas enriched water. The acid gas enriched water is passed to a reactive rock formation. The one or more acid gas impurities and carbon dioxide are mineralized and permanently sequestered.
    Type: Grant
    Filed: October 15, 2021
    Date of Patent: July 25, 2023
    Assignee: Saudi Arabian Oil Company
    Inventors: Zeyad Tareq Ahmed, Serguey Viktorov Arkadakskiy, Noushad Kunnummal
  • Patent number: 11680081
    Abstract: Methods that include providing and reacting a solid support and an alkali-stable ligand derived from an immunoglobulin-binding bacterial protein to form a separation matrix having covalently coupled alkali-stable ligands; and washing with a wash solution comprising at least 10 mM of an alkali metal hydroxide.
    Type: Grant
    Filed: December 13, 2018
    Date of Patent: June 20, 2023
    Inventors: Gustav Rodrigo, Mats Ander, Ronnie Palmgren, Tomas Bjorkman
  • Patent number: 11565240
    Abstract: A mixed mode affinity chromatography carrier includes a substrate, a hydrophilic polymer, an antibody-binding cyclic peptide, and a cation exchange group.
    Type: Grant
    Filed: May 3, 2019
    Date of Patent: January 31, 2023
    Assignee: FUJIFILM Corporation
    Inventor: Shiori Kihara
  • Patent number: 11554358
    Abstract: The present invention relates to the field of solid materials for the adsorption of lithium. In particular, the present invention relates to a novel process for preparing a solid crystalline material formed preferably in extrudate form, of formula (LiCl)x.2Al(OH)3,nH2O with n being between 0.01 and 10, x being between 0.4 and 1, comprising a step a) to precipitate boehmite under specific conditions of temperature and pH, a step to place the precipitate obtained in contact with a specific quantity of LiCl, at least one forming step preferably via extrusion, said process also comprising a final hydrothermal treatment step, all allowing an increase in lithium adsorption capacity and in the adsorption kinetics of the materials obtained compared to prior art materials, when used in a process to extract lithium from saline solutions.
    Type: Grant
    Filed: May 23, 2017
    Date of Patent: January 17, 2023
    Inventors: Malika Boualleg, Fabien Burdet, Yohan Florent Oudart
  • Patent number: 11529610
    Abstract: Functionalized particulate support material and chromatographic media prepared therefrom are disclosed. The functionalized particulate support material is a plurality of particles, each particle having a particle surface. Chemically bonded to and extending from the surface of the particles is a combination of hydrophobic and hydrophilic functional groups. The hydrophobic functional groups enable polymerization of one or more monomers onto the particle surface while the hydrophilic functional groups provide increased wettability of the particle surface compared to an unmodified particle surface. The functionalized particulate support material may be further processed so as to form polymer chains extending from the hydrophobic functional groups. In one embodiment, the resulting polymer functionalized material is useful as a chromatographic media in chromatography columns or cartridges, such as in a liquid chromatography (HPLC) column.
    Type: Grant
    Filed: September 16, 2013
    Date of Patent: December 20, 2022
    Assignee: W.R. GRACE & CO.-CONN.
    Inventor: Feng Gu
  • Patent number: 11512368
    Abstract: Embodiments of the invention relate to a process for removing fluoride from a solution or suspension containing zinc, in particular a solution of zinc sulfate, a defluoridated solution of zinc sulfate obtainable by such a process, its use as well as processes for producing zinc and hydrogen fluoride or hydrofluoric acid. The process for removing fluoride comprises (i) providing a solution or suspension A containing zinc, wherein the solution or suspension A containing zinc further contains fluoride ions; (ii) adding a solution B containing a dissolved salt of a rare earth element to the solution or suspension A containing zinc, wherein a solid comprising a rare earth element fluoride and a solution C containing zinc are formed; and (iii) separating the solid from the solution C containing zinc, wherein the solution C containing zinc has a lower concentration of fluoride ions than the solution or suspension A containing zinc.
    Type: Grant
    Filed: April 6, 2017
    Date of Patent: November 29, 2022
    Inventors: Fritz Ludewig, Stefan Steinlechner, Jürgen Antrekowitsch
  • Patent number: 11229896
    Abstract: Chromatography media and devices containing chromatography media are disclosed. Methods of making chromatography devices and methods of using chromatography devices containing the chromatography media are also disclosed.
    Type: Grant
    Filed: January 15, 2015
    Date of Patent: January 25, 2022
    Assignees: W.R. Grace & Co.—CONN., Repligen Corporation
    Inventors: Feng Gu, Surya Kiran Chodavarapu, James Bogdanor, Dennis McCreary, James Neil Pryor, James Rusche, James Peyser, Thomas Pauly
  • Patent number: 11186893
    Abstract: A method for extracting a rare earth element from a rare earth-containing substance, the method comprising mixing the rare earth-containing substance with a protic ionic liquid, such as: wherein R1 is selected from hydrogen atom and hydrocarbon groups containing 1 to 6 carbon atoms; R2 and R3 are independently selected from hydrocarbon groups containing 1 to 12 carbon atoms; and X? is an anionic species; to produce a composition of the formula (RE)(amide)yXz at least partially dissolved in the protic ionic liquid, wherein RE is at least one rare earth element having an atomic number selected from 39, 57-71, and 90-103; y is 2-6; z is a number that charge balances the total positive charge of RE; and the amide is the conjugate base of the cationic portion of the protic ionic liquid of Formula (1) and has the following formula:
    Type: Grant
    Filed: May 22, 2020
    Date of Patent: November 30, 2021
    Assignee: UT-Battelle, LLC
    Inventors: John William Freiderich, Huimin Luo, Bruce A. Moyer, Sheng Dai
  • Patent number: 11097971
    Abstract: A composition for solid pellets and a process for removing water from particulate material slurries produced by horizontal drilling, vertical drilling and dredging of bodies of water are disclosed. The composition comprises a precipitating agent, a purification agent and, optionally, a binding agent. The process comprises the steps of 1) water removal accomplished by diffusing a chemical reagent into the particulate material source stream that results in separating out a clean water fraction and 2) reacting the sludge with a demulsifier and a superabsorbent polymer that locks onto the water in the remaining slurry thus turning the slurry into a solid crust. The crust is ground into a particulate form and disposed in a landfill. The combined effect of the treatments is the thickening of the particulate material slurry from about 10% solids to about 25% solids. The removed water may be used for further drilling and drinking.
    Type: Grant
    Filed: January 3, 2020
    Date of Patent: August 24, 2021
    Inventors: Aicardo Roa-Espinosa, Michelle H Pham
  • Patent number: 11040307
    Abstract: A method for removing at least one contaminant from a fluid stream by filtering the fluid stream with a filtration medium. The filtration medium includes an impregnate. The impregnate includes a surfactant such as sulfamic acid. The medium has from about 0.1 to about 25% by weight of impregnate. The method is useful for removing one or more volatile organic compounds, particularly formaldehyde, from the fluid stream. In some embodiments, the method includes removing at least two volatile organic compound contaminants from the fluid stream.
    Type: Grant
    Filed: January 24, 2017
    Date of Patent: June 22, 2021
    Assignee: PURAFIL, INC.
    Inventor: William G. England
  • Patent number: 10987652
    Abstract: A gel particle film of amino group-having polymer compound particles has a large acid gas absorption amount and desorption amount per unit volume, and has a high acid gas absorption rate and desorption rate per unit mass, and further has high stability. A gas absorber having the gel particle film supported on a carrier is useful as an acid gas separation material having good energy efficiency.
    Type: Grant
    Filed: August 14, 2015
    Date of Patent: April 27, 2021
    Inventors: Yu Hoshino, Yoshiko Miura, Yukinori Ohshiro
  • Patent number: 10850254
    Abstract: The present invention relates to the field of solid materials for the adsorption of lithium. In particular, the present invention relates to a new method for the preparation of a crystallized and shaped solid material, preferably in extruded form, of formula LiXx.2Al(OH)3,nH2O, wherein n is between 0.01 and 10, x is 1 when X is an anion selected from among chloride, hydroxide and nitrate anions, and x is 0.5 when X is an anion selected from among sulfate and carbonate anions, comprising a boehmite precipitation step a) under specific temperature and pH conditions, at least one basic mixing shaping step, wherein the method also comprises a final hydrothermal treatment step, all to increase the lithium adsorption capacity and the kinetics of adsorption of the materials obtained, compared with the materials of the prior art when it is used in a method for lithium extraction from saline solutions.
    Type: Grant
    Filed: November 24, 2016
    Date of Patent: December 1, 2020
    Inventors: Malika Boualleg, Fabien André Pierre Burdet, Morgan Julien Florian Gohin
  • Patent number: 10854890
    Abstract: The present invention relates to a cross-linked porous membrane from hydrolysis of ester-containing side chain and a preparation method thereof. Firstly, membrane material is obtained through copolymerization of four monomers including butyl methacrylate, styrene, sodium sulfonated styrene and vinylbenzyl chloride. In membrane formation, a small amount of lithium chloride micromolecule porogen is added and cross-linked by using tetramethyl hexamethylene diamine to prepare a nanoscale dense membrane through hydrolysis under the alkaline condition. Through the characteristic of hydrolysis of a butyl ester side chain in the polymer under the alkaline condition, the space originally occupied by the butyl ester in the hydrolyzed membrane is vacated; and after hydrolysis, with the appearance of carboxylic acid ionic conduction groups, a large quantity of ester bonds is hydrolyzed, so that the patency of ion transfer channels in the membrane is enhanced. Thus, ionic conductivity of the membrane is greatly enhanced.
    Type: Grant
    Filed: May 21, 2018
    Date of Patent: December 1, 2020
    Inventors: Fengxiang Zhang, Yanjiao Ma, Shupeng Zhao, Ruijun Gan
  • Patent number: 10829699
    Abstract: Certain functionalized aldehydes scavengers may be used to at least partially scavenge sulfur-containing contaminants from fluid systems containing hydrocarbons and/or water. The contaminants scavenged or otherwise removed include, but are not necessarily limited to, H2S, mercaptans, and/or sulfides. Suitable scavengers include, but are not necessarily limited to, reaction products of glycolaldehyde with aldehydes; reaction products of glycolaldehyde with a nitrogen-containing reactant (e.g. an amine, a triazine, an imine, an aminal, and/or polyamines); non-nitrogen-containing reaction products of a hydrated aldehyde with certain second aldehydes; reaction products of 1,3,5-trioxane with hydroxyl-rich compounds (e.g. glyoxal, polyethylene glycol, polypropylene glycol, pentaerythritol, and/or sugars); and reaction products of certain aldehydes with certain phenols; and combinations of these reaction products.
    Type: Grant
    Filed: September 27, 2019
    Date of Patent: November 10, 2020
    Assignee: Baker Hughes Holdings LLC
    Inventors: Jerry J. Weers, Soma Chakraborty, Vaithilingam Panchalingam
  • Patent number: 10800732
    Abstract: Disclosed are a series of malonamide derivatives having a chemical structure(I), their synthesis, and evaluation of their bioactivities against bacterial cell, bacterial-infected C. elegans and mice.
    Type: Grant
    Filed: August 12, 2016
    Date of Patent: October 13, 2020
    Inventors: Chung-Wai Shiau, Hao-Chieh Chiu
  • Patent number: 10745606
    Abstract: The present application discloses drilling fluid compositions, methods for making drilling fluids, and methods for drilling subterranean wells utilizing the drilling fluids. According to one embodiment, a drilling fluid composition may include an oil phase, an aqueous phase, and a rheology modifier. The rheology modifier may include a layered double hydroxide, such as Mg/Al-Myristate layered double hydroxide.
    Type: Grant
    Filed: August 9, 2018
    Date of Patent: August 18, 2020
    Assignees: Saudi Arabian Oil Company, Durham University, M-I Drilling Fluids UK Ltd
    Inventors: Musarrat Halima Mohammed, Andrew Whiting, Manohara Gudiyor Veerabhadrappa, Hugh Christopher Greenwell, John Adrian Hall, Gasan Selman Alabedi, Michael Hayward Hodder
  • Patent number: 10647903
    Abstract: The present application discloses drilling fluid compositions, methods for making drilling fluids, and methods for drilling subterranean wells utilizing the drilling fluids. According to one embodiment, a drilling fluid composition may include an oil phase, an aqueous phase, an emulsifier, and a rheology modifier. The emulsifier may include an amino amide, and the rheology modifier may include a layered double hydroxide, such as Mg/Al-Myristate layered double hydroxide.
    Type: Grant
    Filed: August 9, 2018
    Date of Patent: May 12, 2020
    Assignees: Saudi Arabian Oil Company, Durham University, M-I Drilling Fluids UK Ltd
    Inventors: Musarrat Halima Mohammed, Andrew Whiting, Mona Al Batal, Manohara Gudiyor Veerabhadrappa, Hugh Christopher Greenwell, John Adrian Hall, Gasan Selman Alabedi, Michael Hayward Hodder
  • Patent number: 10363544
    Abstract: It is an object to provide a particulate water-absorbing agent having a high fluid retention capacity under pressure and reduced moisture absorption blocking properties, and a method for producing the same. A particulate water-absorbing agent including a water-insoluble metal phosphate including an anion of a phosphoric acid compound and a divalent or trivalent metal cation, the water-insoluble metal phosphate having a crystallite size of less than 0.15 ?m, wherein the particulate water-absorbing agent has a fluid retention capacity under pressure of 2.06 kpa of 20 g/g or more.
    Type: Grant
    Filed: March 31, 2015
    Date of Patent: July 30, 2019
    Inventors: Taishi Kobayashi, Mariko Tamaki, Hiroyuki Ikeuchi
  • Patent number: 10279307
    Abstract: In one aspect, the invention provides a method for the capture of at least one acid gas in a composition, the release of said gas from said composition, and the subsequent regeneration of said composition for re-use, said method comprising performing, in order, the steps of: (a) capturing the at least one acid gas by contacting said at least one gas with a capture composition comprising at least one salt of a carboxylic acid and at least one water-miscible non-aqueous solvent; (b) releasing said at least one acid gas by adding at least one protic solvent or agent to said composition; and (c) regenerating the capture composition by partial or complete removal of said added protic solvent or agent from said composition. Optionally, said capture composition comprising at least one salt of a carboxylic acid and at least one water-miscible non-aqueous solvent additionally comprises water or another protic solvent.
    Type: Grant
    Filed: December 19, 2014
    Date of Patent: May 7, 2019
    Assignee: C-Capture Ltd.
    Inventors: Christopher Mark Rayner, Douglas Cahalane Barnes, Gergely Jakab, Caspar Schoolderman
  • Patent number: 10266915
    Abstract: A solid particulate composition useful in extracting a lithium salt from aqueous solutions, the composition comprising lithium, metal atoms, oxygen atoms, and at least one anionic species (X) selected from halide, nitrate, sulfate, carbonate and bicarbonate, all in a framework structure, wherein said metal atoms are selected from at least one of oxophilic main group metal and oxophilic transition metal atoms, provided that, if the metal atoms comprise aluminum atoms, then at least 10 mol % of said aluminum atoms are substituted with at least one metal atom selected from said at least one oxophilic main group and oxophilic transition metal atoms, other than aluminum, and wherein said lithium is present in said composition in an amount less than a saturated amount in order to permit extraction of lithium salt. Methods for extracting and recovering a lithium salt from an aqueous solution by use of the above-described composition are also described.
    Type: Grant
    Filed: April 14, 2016
    Date of Patent: April 23, 2019
    Assignees: UT-Battelle, LLC, Alger Alternative Energy, LLC
    Inventors: Mariappan Parans Paranthaman, Ramesh R. Bhave, Bruce A. Moyer, Stephen Harrison
  • Patent number: 10170251
    Abstract: A combined hydrothermal and activation process that uses hemp bast fiber as the precursor to achieve graphene-like carbon nanosheets, a carbon nanosheet including carbonized crystalline cellulose, a carbon nanosheet formed by carbonizing crystalline cellulose, a capacitative structure includes interconnected carbon nanosheets of carbonized crystalline cellulose, a method of forming a nanosheet including carbonizing crystalline cellulose to create carbonized crystalline cellulose. The interconnected two-dimensional carbon nanosheets also contain very high levels of mesoporosity.
    Type: Grant
    Filed: September 21, 2016
    Date of Patent: January 1, 2019
    Assignee: The Governors of the University of Alberta
    Inventors: David Mitlin, Huanlei Wang, Zhanwei Xu, Zhi Li, Chris Holt
  • Patent number: 10066030
    Abstract: The invention relates to a process for the polymerization of olefins comprising the comprising the steps of a. Polymerizing olefins in a reaction mixture comprising monomers, diluent, processing aids to prepare a product stream comprising polyolefins, monomers and diluent; b. Removing the polyolefins from the product stream to obtain a purge stream; c. Removing gaseous components from the purge stream to obtain a liquid fraction; d. Treating the liquid fraction with at least one ionic liquid to obtain a fraction containing unsaturated hydrocarbons; e. Recycling the fraction containing unsaturated hydrocarbons to the reaction mixture, optionally after purification of said fraction containing unsaturated hydrocarbons.
    Type: Grant
    Filed: December 22, 2015
    Date of Patent: September 4, 2018
    Inventor: Mpho Prudence Setlhaku
  • Patent number: 9938303
    Abstract: Disclosed are Si-containing thin film forming precursors, methods of synthesizing the same, and methods of using the same to deposit silicon-containing films using vapor deposition processes for manufacturing semiconductors, photovoltaics, LCD-TFT, flat panel-type devices, refractory materials, or aeronautics.
    Type: Grant
    Filed: July 19, 2013
    Date of Patent: April 10, 2018
    Assignee: American Air Liquide, Inc.
    Inventors: Christian Dussarrat, Glenn Kuchenbeiser, Venkateswara R. Pallem
  • Patent number: 9937366
    Abstract: A compact ignition system for chemical oxygen generators for possible use in an aircraft. The chemical oxygen generator is configured such that a majority of the ignition system can be accommodated within an interior of the generator body. In some embodiments, the ignition system is positioned within a recess of an upper surface of the core of the generator. Housing a majority of the ignition system within the generator allows the overall oxygen-generating capacity of the generator to be increased without requiring a corresponding increase in the overall length of the generator.
    Type: Grant
    Filed: October 10, 2014
    Date of Patent: April 10, 2018
    Assignee: AVOX Systems Inc.
    Inventors: William A. Mack, Jr., William A. Donofrio, Dean A. Kubik, Yelena Aleshina
  • Patent number: 9889430
    Abstract: The process provided herein is concerned with disposal of oxidized sulfur compounds formed by oxidative desulfurization. The process uses solid base catalyst in the presence of a caustic solution or solid base catalyst pretreated with a base and eliminates the need to separate the sulfones from the hydrocarbon streams and recover the hydrocarbons.
    Type: Grant
    Filed: December 30, 2015
    Date of Patent: February 13, 2018
    Assignee: Saudi Arabian Oil Company
    Inventors: Omer Refa Koseoglu, Abdennour Bourane
  • Patent number: 9879857
    Abstract: The combustion and flue gas treatment system includes a furnace for combusting a fuel with an oxidizer generating a flue gas, ducting for the flue gas connected to a NOx removal unit and a SOx removal unit, and a recirculation line for recirculating a part of the flue gas back to the furnace. The SOx removal unit is located upstream of the NOx removal unit with reference to the flue gas flow. The recirculation line is connected to the ducting downstream the SOx removal unit.
    Type: Grant
    Filed: July 31, 2015
    Date of Patent: January 30, 2018
    Assignee: General Electric Technology GmbH
    Inventors: Olaf Stallmann, Wuyin Wang, Erik W. Böös
  • Patent number: 9868107
    Abstract: Provided are materials and processes for removing nitrogen dioxide gas from a sample by contacting the sample with a filtration media that includes a MOF, optionally an amine containing MOF. The resulting filtration media has the ability to sequester nitrogen dioxide with little conversion to nitric oxide, is stable, and highly functional so as to be useful in protective equipment or other filtration systems.
    Type: Grant
    Filed: February 13, 2017
    Date of Patent: January 16, 2018
    Assignee: The United States of America as Represented by the Secretary of the Army
    Inventor: Gregory W Peterson
  • Patent number: 9826777
    Abstract: The filter using technology for reducing the smell of tobacco smoke on hands, according to one embodiment of the present invention, comprises: a filter unit for filtering tobacco smoke, the filter unit being coupled to a tobacco shred; and filter-wrapping paper for wrapping the filter unit. The filter unit or the filter-wrapping paper may contain a material for reducing the smell of tobacco smoke. According to the embodiment of the present invention, green tea extracts containing catechin or other materials for reducing the smell of tobacco smoke, e.g. citric acids, glycerols, tannic acids and the like can be added to a tobacco filter to remove the smell from tobacco smoke generated during smoking, thus significantly lowering the strength of the smell of tobacco smoke on the hands of a smoker as compared to conventional tobacco filters.
    Type: Grant
    Filed: August 29, 2012
    Date of Patent: November 28, 2017
    Assignee: KT&G Corporation
    Inventors: Man Seok Seo, Hyun Suk Cho, In Hyeog Oh, Burm Ho Yang, Han Jae Shin, Mi Jang, Jong Yeol Kim
  • Patent number: 9821270
    Abstract: The invention relates to a method of selectively removing hydrogen sulfide H2S from a gaseous effluent comprising at least H2S and CO2, wherein a stage of selective absorption of hydrogen sulfide over CO2 is carried out by contacting said effluent with a solution comprising (a) water and (b) at least the following diamine: 1,2-bis(2-dimethylaminoethoxy)ethane and wherein the absorption selectivity is controlled by adding (c) a viscosifying compound to the absorbent solution.
    Type: Grant
    Filed: December 5, 2013
    Date of Patent: November 21, 2017
    Inventors: Julien Grandjean, Dominique Le Pennec, Bruno Delfort
  • Patent number: 9732016
    Abstract: Disclosed are systems and methods which provide a process stream comprising a gaseous component, capture the gaseous component from the process stream by an ionic liquid solvent of a separator, and recover a captured gaseous component from the ionic liquid solvent in a regenerator. A second gaseous component from the process stream may be captured by the ionic liquid solvent of the separator, and the second gaseous component may be recovered from the ionic liquid solvent in the regenerator. Alternatively, the second gaseous component from the process stream may be uncaptured by the ionic liquid solvent, and the uncaptured second gaseous component may be recovered from a membrane unit.
    Type: Grant
    Filed: December 11, 2015
    Date of Patent: August 15, 2017
    Assignees: Chevron Phillips Chemical Company LP, Chevron U.S.A. Inc.
    Inventors: Lei Ji, Ai-Fu Chang, Michael S. Driver, Hye Kyung Timken
  • Patent number: 9561466
    Abstract: The invention is a process for absorbing sulfur dioxide from a gaseous stream with the aid of an ionic liquid, followed by the release of sulfur dioxide from the ionic liquid on addition of a polar solvent and the regeneration of the ionic liquid.
    Type: Grant
    Filed: July 13, 2015
    Date of Patent: February 7, 2017
    Inventors: Yoel Sasson, Tatyana Sachs, Effi Dvash, Zach Barnea
  • Patent number: 9533253
    Abstract: A process of mixing methyldiethanolamine to water to produce a first mixture. 2-amino-2-methyl-1-propanol is added to the first mixture to form a second mixture. The second mixture is then heated while mixing to form a third mixture. Piperazine is then added to the third mixture to form a solvent.
    Type: Grant
    Filed: June 4, 2015
    Date of Patent: January 3, 2017
    Assignee: Phillips 66 Company
    Inventors: Frederick Bynum Closmann, David Hamilton Van Wagener, Clint Aichele
  • Patent number: 9452426
    Abstract: Problem To provide a method for easily producing an adsorbing material used for the removal and recovery of metals and ions in a solution, which is highly durable and has various adsorptive functional groups and forms applicable for various purposes.
    Type: Grant
    Filed: January 26, 2013
    Date of Patent: September 27, 2016
    Inventors: Yoshinori Inoue, Takehiro Kajiwara, Mitsuru Saito
  • Patent number: 9441157
    Abstract: This disclosure refers to the fabrication of an active oxygen-absorbing compound composed of a sodium erythorbate and a non-organic salt of a transition metal encapsulated through the sol-gel method in a silica matrix. This compound can be part of the package's structure for oxidation-sensitive products or contained in the surrounding atmosphere to decrease the oxygen concentration. This application describes the method for the fabrication of the oxygen-absorber, as well as its encapsulation and incorporation in polymeric matrixes.
    Type: Grant
    Filed: March 18, 2011
    Date of Patent: September 13, 2016
    Inventors: Jorge Alberto Medina Perilla, Angela Maria Garcia Mora, Andrea Marcela Arias Herrera, Ronald Vicente Joven Pineda
  • Patent number: 9365783
    Abstract: The invention relates to a process and an apparatus for producing synthesis gas (5) by steam reforming, in which nitrogen is separated off from a starting material (1) containing hydrocarbons and nitrogen in order to produce a low-nitrogen feed (4) for a burner-fired steam reformer (D), with formation of a hydrocarbon-containing residual gas (2) which subsequently serves as fuel (6). Nitrogen is separated off adsorptively (N) from the starting material and the hydrocarbon-containing residual gas (2) is used for firing the steam reformer (D).
    Type: Grant
    Filed: December 3, 2014
    Date of Patent: June 14, 2016
    Inventor: Martin Lang
  • Patent number: 9326501
    Abstract: The preservation or extension of the life of oxygen perishable products such as fresh or cooked meats; fresh vegetables and fruits; dried vegetables, fruits and meats; packaged pharmaceuticals or biologicals; open and enclosed marketing display cases of meats, fruits and vegetables; and packaging, warehousing and transportation of meats, fruits, and vegetables is obtained by subjecting such products to an atmosphere obtained from gas permeable packets of an oxygen scavenging composition comprising a sodium carbonate mineral and one or more carboxylic acids. When the environment surrounding the oxygen perishable product is subjected to the packets of gaseous permeable oxygen scavenging compositions, oxygen is taken in by the scavenging composition and also the presence of carbon dioxide in the surrounding environment is enhanced thereby minimizing or eliminating the effect the oxygen on the oxygen perishable products.
    Type: Grant
    Filed: August 29, 2014
    Date of Patent: May 3, 2016
    Assignee: JP Patents L.L.C.
    Inventor: Peter E. Fuller
  • Patent number: 9260596
    Abstract: Provided is a resin composition which is excellent in an oxygen-absorbing performance, a resin strength and a resin processability. The oxygen-absorbing resin composition is characterized by containing a polyolefin resin, a transition metal catalyst and a polyamide resin obtained by polycondensation of aromatic diamine and dicarboxylic acid, wherein an end amino group concentration of the above polyamide resin is 30 ?eq/g or less, and a total content of the transition metal catalyst and the polyamide resin is 15 to 60% by weight based on a whole amount of the oxygen-absorbing resin composition.
    Type: Grant
    Filed: June 15, 2010
    Date of Patent: February 16, 2016
    Inventors: Takashi Kashiba, Satoshi Okada, Shinpei Iwamoto, Akihiro Masuda, Kiyonori Michiba
  • Patent number: 9227187
    Abstract: The invention relates to a method for functionalization of inorganic particles by polymers comprising at least one recurrent unit bearing at least one proton exchange group comprising the following steps: a) a step for functionalization of inorganic particles by an anionic polymerization termination agent comprising at least one group capable of being bound to the surface of said particles; b) a step for anionic polymerization of at least one monomer bearing at least one precursor group of a proton exchange group; c) a step for putting the particles obtained in step a) in contact with the polymers obtained in step b), in return for which the obtained particles are particles functionalized by said polymers by reaction between a reactive end of said polymeric polymers and at least one group of the aforementioned termination agent; and d) a step for transformation of the precursor group(s) of said proton exchange group(s).
    Type: Grant
    Filed: November 28, 2011
    Date of Patent: January 5, 2016
    Inventors: Jannick Bigarre, Renaud Perrin, Pierrick Buvat, Herve Galiano
  • Patent number: 9044739
    Abstract: Foam-based adsorbents and a related method of manufacture are provided. The foam-based adsorbents include polymer foam with grafted side chains and an increased surface area per unit weight to increase the adsorption of dissolved metals, for example uranium, from aqueous solutions. A method for forming the foam-based adsorbents includes irradiating polymer foam, grafting with polymerizable reactive monomers, reacting with hydroxylamine, and conditioning with an alkaline solution. Foam-based adsorbents formed according to the present method demonstrated a significantly improved uranium adsorption capacity per unit weight over existing adsorbents.
    Type: Grant
    Filed: March 27, 2014
    Date of Patent: June 2, 2015
    Assignee: UT-Battelle, LLC
    Inventors: Christopher J. Janke, Sheng Dai, Yatsandra Oyola
  • Publication number: 20150147243
    Abstract: Compositions for reducing the aggregate content of a protein preparation include a first substrate having a first surface-bound ligand possessing a metal affinity functionality and a second surface-bound ligand optionally provided on a second substrate and having an aggregate charge opposite to that of the metal affinity functionality of the first substrate, wherein the first surface-bound ligand and the second surface-bound ligand are positioned such that the protein preparation may contact both the first surface-bound ligand and the second surface-bound ligand simultaneously.
    Type: Application
    Filed: November 26, 2014
    Publication date: May 28, 2015
    Inventor: Peter Gagnon
  • Patent number: 9034100
    Abstract: The invention relates to CO2 capturing binder with an amortized environmental cost, the method of manufacture thereof by means of selecting, purifying and optimizing the carbide lime paste for use as a cementing material, and aggregates for the manufacture of lime paints and slurries, stuccos, mortars and concretes having multiple applications in the construction industry, in architectural restoration, in public works and land conditioning, object of the present invention. It is basically characterized in that the raw material is the residue in the form of sludge generated in the industrial manufacture of acetylene (C2H2) from calcium carbide (CaC2) the fundamental component of which is calcium hydroxide (Ca(OH)2) in highly reactive nanometric formations treated in a specific manner according to the invention.
    Type: Grant
    Filed: May 4, 2010
    Date of Patent: May 19, 2015
    Inventors: Miguel Angel Bermejo Sotillo, Carlos Rodriguez Navarro, Encarnación Ruiz Agudo, Kerstin Elert
  • Publication number: 20150133712
    Abstract: Described herein is a material for reversibly binding to a carotenoid comprising a support coupled to silver ions in an amount to enable reversible binding with carotenoids, and wherein with the exception of silver ions, is substantially free of transition metals. Also described herein is a process for reversibly binding a carotenoid, the process comprising the steps of: providing a support coupled to silver ions in an amount to enable reversible binding with the carotenoid, wherein with the exception of silver, the support is substantially free of transition metals, contacting the support with the carotenoid under binding conditions to bind it thereto and dissociating the carotenoidod from the support under dissociating conditions to release the carotenoid.
    Type: Application
    Filed: February 20, 2014
    Publication date: May 14, 2015
    Inventors: Pratap Kumar Deheri, Srinivasan Varadalambedu Nithianandam, Mahesh Dahyabhai Patel
  • Publication number: 20150132202
    Abstract: This invention relates to a method for preparing a lithium activated alumina intercalate solid by contacting a three-dimensional activated alumina with a lithium salt under conditions sufficient to infuse lithium salts into activated alumina for the selective extraction and recovery of lithium from lithium containing solutions, including brines.
    Type: Application
    Filed: October 31, 2014
    Publication date: May 14, 2015
    Inventors: Stephen Harrison, C. V. Krishnamohan Sharma, M. Scott Conley
  • Patent number: 9017455
    Abstract: This invention relates to sulfur based compounds useful in methods of carbon dioxide or sulfur dioxide removal.
    Type: Grant
    Filed: March 11, 2011
    Date of Patent: April 28, 2015
    Assignee: E I du Pont de Nemours and Company
    Inventor: Mark A. Scialdone
  • Publication number: 20150105240
    Abstract: The present disclosure is directed to a desulphurisation agent for removing sulphurous species from a diluent or process stream, and a use of such agent. In some examples, the agent may include a compound of manganese, pore forming particles and a compound of copper. The agent may be introduced into or mixed with the diluent or process stream to effectuate removal of sulphorous species from the diluent or process stream.
    Type: Application
    Filed: September 23, 2014
    Publication date: April 16, 2015
    Inventor: Rodney Martin Sambrook
  • Patent number: 8992868
    Abstract: Dry processes, apparatus, compositions and systems are provided for reducing emissions of mercury and optionally sulfur oxides and/or HCl. In an embodiment the copper-based mercury remediation composition comprises a copper ammonium complex having an empirical formula of C2H7CuNO2 or any of the other materials described, which include compositions defined by the formula Cu(NH3)x(lower carboxylate)y, wherein the lower carboxylate is selected from the group consisting of formate, acetate and propionate, x is an integer from 0 to 4, y is an integer from 0 to 2, and x+y is equal to or greater than 1. Sulfur oxides and/or HCl can be additionally reduced by introduction of dolomite hydrate sorbent, and additional mercury remediation chemicals as manganese oxides can be employed. The treated gas stream is treated with a particulate removal device.
    Type: Grant
    Filed: April 30, 2013
    Date of Patent: March 31, 2015
    Assignee: Fuel Tech, Inc.
    Inventors: Christopher R. Smyrniotis, Kent W. Schulz, Emelito P. Rivera, Mingming Fang, Ian Saratovsky
  • Publication number: 20150086801
    Abstract: A method for manufacturing a complex for carbon dioxide separation, the complex for carbon dioxide separation including a support and a carbon dioxide separation layer on the support, and the method including: applying, on the support, a coating liquid for forming the carbon dioxide separation layer including: a water-absorbing polymer, an alkali metal salt, and a filler having a density lower than a density of the alkali metal salt, a new Mohs hardness of 2 or greater, and a volume average particle diameter that is 30% or less of a thickness of the carbon dioxide separation layer; and drying the coating liquid applied for forming the carbon dioxide separation layer to obtain the carbon dioxide separation layer.
    Type: Application
    Filed: December 3, 2014
    Publication date: March 26, 2015
    Inventors: Daisuke HIRAKI, Kenichi ISHIZUKA
  • Publication number: 20150075740
    Abstract: The present invention provides methods for producing exfoliated clay platelets from a swellable clay material. In embodiments, the method for producing exfoliated clay platelets includes providing an exfoliating agent comprising an anionic extractant, and exposing the swellable clay material to the exfoliating agent, wherein the exfoliating agent produces exfoliated clay platelets from the swellable clay material. Methods for treating paper precursors and paper sheets are also disclosed, as are paper products formed from such paper precursors or paper sheets.
    Type: Application
    Filed: August 12, 2014
    Publication date: March 19, 2015
    Inventors: Gangadhar Jogikalmath, Andrea Schneider, David S. Soane