Phenyl Benzoate Derivative Patents (Class 252/299.67)
  • Patent number: 7122227
    Abstract: The invention relates to chiral photoisomerizable compounds of formula (I) wherein X1, X2, X3, X4, X5 and X6 have the meanings given in claim 1, to liquid crystalline mixtures and polymers containing them, and to the use of chiral photoisomerizable compounds, liquid crystalline mixtures and polymers containing them in optical and electrooptical devices like liquid crystal displays or projection systems, in optical elements like polarizers, retardation films, compensators, color filters or holographic elements, in liquid crystal pigments and colored films or coatings for decorative or security applications, cosmetic and pharmaceutical compositions, in nonlinear optics and optical information storage.
    Type: Grant
    Filed: September 21, 2001
    Date of Patent: October 17, 2006
    Assignee: Merck Patent Gesellschaft
    Inventors: Julian Vaughn-Spickers, Simon Greenfield, Ian Victor Edward Hassall, Christopher Dunn, Richard Harding, Tony Jenkins, Alison May
  • Patent number: 7115307
    Abstract: Nematic liquid crystal mixtures with weak zenithal anchoring energy for bistable display devices, comprising at least 40% by weight of compounds with strong molecular polarisability and strong dipole moment.
    Type: Grant
    Filed: February 25, 2004
    Date of Patent: October 3, 2006
    Assignee: Nemoptic
    Inventors: Jean Claude Dubois, Didier Gallaire, Stéphane Joly, Ivan N Dozov, Philippe Martinot-Lagarde, Daniel N Stoenescu
  • Patent number: 7108801
    Abstract: A method for producing a blend comprising randomly substituted mesogens comprising: providing one or more platform molecules have the following general structure: wherein at least one member selected from the group consisting of X and Y comprises one or more spacer groups; R2 is a bulky organic group whereby, when both X and Y are reacted with polymerizable groups to produce polymerizable mesogens, R2 provides sufficient steric hindrance to achieve a nematic state at room temperature while suppressing crystallinity of the polymerizable mesogens at room temperature; and, R1 and R3 are selected from groups less bulky than R2; and independently substituting at least one member selected from the group consisting of X and Y with a polymerizable group, thereby producing a blend of randomly substituted mesogens.
    Type: Grant
    Filed: January 23, 2002
    Date of Patent: September 19, 2006
    Assignee: Southwest Reasearch Institute
    Inventors: Stephen T. Wellinghoff, Douglas P. Hanson
  • Patent number: 7105106
    Abstract: Thermotropic liquid crystalline polymers are produced by the reaction of a polyester made from an aromatic dicarboxylic acid and a diol, one or more hydroxycarboxylic acids, a stoichiometric excess of an aromatic diol, and a carboxylic acid anhydride. Also disclosed are novel liquid crystalline polymers that may be produced by this process. These liquid crystalline polymers are useful as molding resins and shaped articles thereof are produced. In particular, the articles include films, sheets, containers and portions thereof comprising these LCPs.
    Type: Grant
    Filed: July 11, 2003
    Date of Patent: September 12, 2006
    Assignee: E. I. du Pont de Nemour and Company
    Inventors: Michael Robert Samuels, Marion Glen Waggoner, Julius Uradnisheck
  • Patent number: 7105210
    Abstract: A liquid-crystalline medium based on a mixture of polar compounds of positive dielectric anisotropy, which contains one or more compounds of the formula I and one or more compounds of the formula IA in which R1, R2, ring A, L1-8, Z1, X1 and X2 are as defined in claim 1.
    Type: Grant
    Filed: March 5, 2004
    Date of Patent: September 12, 2006
    Assignee: Merck Patent GmbH
    Inventors: Michael Heckmeier, Brigitte Schuler, Izumi Saito, Sabine Schoen, Peer Kirsch
  • Patent number: 7101595
    Abstract: The present invention provides a compound represented by formula (1) defined in the specification. The invention further provides a liquid crystal composition comprising at least two compounds, which at least one compound out of them is the above compound. The invention still further provides a polymer obtained by polymerizing the above composition, and uses of the polymer such as a molded article having an optical anisotropy, an optical compensation element, a wavelength functional plate, an optical element, and a liquid crystal display element comprising the polymer.
    Type: Grant
    Filed: July 29, 2004
    Date of Patent: September 5, 2006
    Assignees: Chisso Corporation, Chisso Petrochemical Corporation
    Inventors: Ryushi Shundo, Hiromichi Inoue, Tomohiro Etou
  • Patent number: 7098359
    Abstract: New, efficient methods for making novel platform molecules and polymerizable mesogens are provided, as well as the novel mesogens and methods of using same.
    Type: Grant
    Filed: July 5, 2002
    Date of Patent: August 29, 2006
    Assignee: Southwest Research Institute
    Inventors: Stephen T. Wellinghoff, Douglas P. Hanson
  • Patent number: 7094358
    Abstract: Resin blends comprising liquid crystal monomers and secondary monomers useful to blend with liquid crystal monomers to maintain a nematic state under processing conditions while maintaining low cute shrinkage, particularly suitable for use in dental resin composites.
    Type: Grant
    Filed: March 7, 2002
    Date of Patent: August 22, 2006
    Assignee: The University of Texas System
    Inventors: Barry K. Norling, Neera Satsangi
  • Patent number: 7094359
    Abstract: An object of the present invention is to provide a micro powder capable of producing a thin film with precision thickness. This object is achieved by a micro powder having an average particle size of from 0.5 to 50 ?m, obtained by grinding a liquid crystalline polyester having a flow beginning temperature of from 200° C. to 270° C.
    Type: Grant
    Filed: March 13, 2003
    Date of Patent: August 22, 2006
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Satoshi Okamoto, Manabu Hirakawa
  • Patent number: 7087273
    Abstract: A novel liquid crystalline compound has the formula: Z1-(CH2)n-L1-P1-L2-P2-L3-P3-L4-(CH2)m-Z2 ??(1) wherein Z1 and Z2 are each independently a group represented by any one of formulas (2), (3) and (4) below, L1, L2, L3, and L4 each independently indicate direct bond or are a group represented by any of —O—, —O—CO—, or —CO—O—, P1 and P2 are each independently a group represented by formula (5) below, and P3 indicates direct bond or is a group represented by formula (5) below, n and m are each independently an integer of 0 to 8; wherein X is selected from the group consisting of hydrogen, methyl, or halogen and provides an optical film with an excellent capability of retaining the aligned liquid crystal orientation which has been fixed and in mechanical strength.
    Type: Grant
    Filed: March 16, 2004
    Date of Patent: August 8, 2006
    Assignee: Nippon Oil Corporation
    Inventors: Takuya Matsumoto, Hitoshi Mazaki
  • Patent number: 7081280
    Abstract: A liquid-crystalline medium containing a mixture of polar compounds of positive dielectric anisotropy. The mixture contains one or more compounds of formula I in which: R is H, an alkyl or alkenyl radical having 1 to 15 carbon atoms which is unsubstituted, monosubstituted by CN or CF3 or at least monosubstituted by halogen, where one or more CH2 groups in these radicals are optionally, in each case independently of one another, replaced by —O—, —S—, —CO—, —CO—O—, —O—CO— or —O—CO—O in such a way that O atoms are not linked directly to one another; is a trans-1,4-cyclohexylene ring, in which one or two CH2 groups are optionally replaced by —O— and/or —S—, or a cyclohexenylene ring; Y is halogenated alkyl, halogenated alkenyl, halogenated alkoxy or halogenated alkenyloxy having 1 to 6 carbon atoms; Z is —OCH2—, —CH2CH2—, —CH?CH—, —CF2O—, —OCF2—, —C2F4— or a single bond; and n is 1 or 2.
    Type: Grant
    Filed: July 2, 2004
    Date of Patent: July 25, 2006
    Assignee: Merck Patent GmbH
    Inventors: Michael Heckmeier, Brigitte Schuler, Kazuaki Tarumi, Peer Kirsch, Volker Reiffenrath
  • Patent number: 7081281
    Abstract: The present invention provides a polymerizable liquid crystal compound having an excellent durability against blue laser light and having a small refractive index and small light absorption, a liquid crystal composition containing the compound, and an optical anisotropic material using the liquid crystal composition. The polymerizable liquid crystal compound represented by the following formula (1), provided that R1 is a hydrogen atom or a methyl group, Cy is a trans-1,4-cyclohexylene group, X1 is a 1,4-phenylene group or a trans-1,4-cyclohexlyene group, and R2 is a C1-8 alkyl group. The above 1,4-phenylene group and the trans-1,4-cyclohexylene group may be such that a hydrogen atom bonded to a carbon atom in each group may be substituted by a fluorine atom, a chlorine atom or a methyl group.
    Type: Grant
    Filed: February 10, 2006
    Date of Patent: July 25, 2006
    Assignee: Asahi Glass Company, Limited
    Inventors: Hiroshi Kumai, Hiromichi Nagayama
  • Patent number: 7078079
    Abstract: The invention relates to a liquid-crystalline medium based on a mixture of polar compounds of positive dielectric anisotropy, characterised in that it comprises one or more compounds of the general formula I in which R1, L1, L2, L3, L4, L5, L6, Z1, Z2, X, v and u are as defined in claim 1.
    Type: Grant
    Filed: September 20, 2001
    Date of Patent: July 18, 2006
    Assignee: Merck Patent GmbH
    Inventors: Michael Heckmeier, Brigitte Schuler, Achim Goetz, Peer Kirsch, Detlef Pauluth, Matthias Bremer, Sabine Schoen, Georg Lüssem, Christian Hock
  • Patent number: 7074464
    Abstract: A compound represented by the formula (1). wherein Ra is alkyl having 1 to 10 carbon(s) and, in that alkyl, any of —CH2— may be replaced with —O—, —S—, —CO—, —CH?CH— or —C?C— or any of hydrogens may be replaced with halogen or —CN; A1, A2 and A3 are independently 1,4-cycolohexylene, 1,4-cyclohexenylene, 1,4-phenylene, naphthalene-2,6-diyl, 1,2,3,4-tetrahydronaphthalene-2,6-diyl, decahydronaphthalene-2,6-diyl or 1,4-bicyclo[2.2.2]octylene and, in such a ring, any —CH2— may be replaced with —O—, any —CH? may be replaced with —N? and any hydrogen may be replaced with halogen; Z1, Z2 and Z3 are independently a single bond, —(CH2)2—, —(CF2)2—, —COO—, —OCO—, —CH2O—, —OCH2—, —CF2O—, —OCF2—, —CH?CH—, —CF?CF—, —C?C—, —(CH2)4—, —(CH2)3O— or —O(CH2)3—; p and q are independently 0 or 1. Also provided is a liquid crystal composition containing the same and a liquid crystal display element containing the composition.
    Type: Grant
    Filed: May 13, 2004
    Date of Patent: July 11, 2006
    Assignees: Chisso Petrochemical Corporation, Chisso Corporation
    Inventor: Takashi Kato
  • Patent number: 7070711
    Abstract: Liquid crystalline compositions contain no functional group the synthesis of which is difficult, such as (meth)acrylate and epoxy group and comprise (A) an oxetane compound having an optically active portion, (B) a side chain liquid crystalline polymeric substance having an oxetanyl group, and (C) a photo cation generator and/or a thermal cation generator. The use of the composition can provide a cholesteric-aligned liquid crystal film with excellent alignment retention properties after being fixed in the liquid crystal state and mechanical strength, without employing any complicated step such as photo irradiation under an inert gas atmosphere.
    Type: Grant
    Filed: October 14, 2004
    Date of Patent: July 4, 2006
    Assignee: Nippon Oil Corporation
    Inventors: Takashi Seki, Takuya Matsumoto, Toru Nakamura, Hitoshi Mazaki
  • Patent number: 7070712
    Abstract: There is disclosed a liquid crystalline polyacetylene having a repeat structure of the formula where spa is a spacer group and mes is a mesogenic substituent.
    Type: Grant
    Filed: April 12, 2005
    Date of Patent: July 4, 2006
    Assignee: The Hong Kong University of Science & Technology
    Inventors: Ben Zhong Tang, Wing Yip Lam, Xiangxing Kong, Hoi Sing Kwok
  • Patent number: 7070838
    Abstract: The present invention provides a compound represented by formula (1) defined in the specification and a liquid crystal composition comprising the compound. The invention further provides a polymer obtained by polymerization of compound or composition above, and further the present invention provides a film, an optical anisotropic material, A ¼ or ½ wavelength functional plate, an optical compensation element, an optical element and a liquid crystal display element employing the polymer.
    Type: Grant
    Filed: June 23, 2004
    Date of Patent: July 4, 2006
    Assignees: Chisso Petrochemical Corporation, Chisso Corporation
    Inventors: Yasuyuki Sasada, Motoki Yanai
  • Patent number: 7063805
    Abstract: A nematic liquid crystal composition includes a compound of formula (1) and a host mixture: wherein ‘R’ is chosen from CnH2n+1O, CnH2n+1, CnH2n+1S or CnH2n?1; ‘n’ is an integer of 1 to 15; ‘A’ is ‘a’ is 0 or 1; ‘B’ is —CH2CH2—, —C?C—, —C?C— or ‘b’ is 0 or 1; ‘D’ is —CH2CH2—, —C?C— or —C?C—; ‘d’ is 0 or 1; ‘X’ is H, F, Cl, Br, NCS or CN; and ‘Y’ is from NCS, SCN or F. A liquid crystal display apparatus employing the nematic liquid crystal composition has a high response speed and a high phase transition temperature. In addition, the nematic liquid crystal composition has an augmented birefringence and a dielectric anisotropy. The liquid crystal display apparatus using the nematic liquid crystal composition may have an enhanced brightness.
    Type: Grant
    Filed: June 30, 2004
    Date of Patent: June 20, 2006
    Assignee: Samsung Electronics Co., Ltd.
    Inventor: Byeong-Seob Ban
  • Patent number: 7060200
    Abstract: The invention relates to multireactive polymerizable mesogenic compounds of formula I R1—MG—R2I wherein R1, R2 and MG have the meaning given in claim 1, to a polymerizable mesogenic composition comprising at least two components, at least one which is a compound of formula I, to a linear or crosslinked polymer obtainable by polymerization of one or more compounds of formula I or of a polymerizable composition comprising one or more compounds of formula I and to the use of a compound of formula I, or a polymerizable composition or polymer obtainable thereof, in optical elements such as polarizers, optical retardation or compensation films, alignment layers, colour filters or holographic elements, in liquid crystal displays such as PDLC, polymer gel or polymer stabilized cholesteric texture (PSCT) displays, in adhesives, synthetic resins with anisotropic mechanical properties, cosmetics, diagnostics or liquid crystal pigments, for decorative and security applications, and for nonlinear optics or optical infor
    Type: Grant
    Filed: September 1, 2000
    Date of Patent: June 13, 2006
    Assignee: Merck Patent GmbH
    Inventors: Louise Farrand, David Coates
  • Patent number: 7056561
    Abstract: The invention relates to a liquid-crystalline medium based on a mixture of polar compounds of positive dielectric anisotropy, characterised in that it comprises one or more ester compounds of the formula I and one or more compounds of the formula IA in which R1, R2, ring A, ring B, L1-6, Z1, Z2, X1 and X2 are as defined in claim 1.
    Type: Grant
    Filed: September 9, 2004
    Date of Patent: June 6, 2006
    Assignee: Merck Patent GmbH
    Inventors: Michael Heckmeier, Sabine Schoen, Peer Kirsch, Brigitte Schuler, Izumi Saito
  • Patent number: 7052744
    Abstract: Nematic liquid-crystal mixtures comprising one or more compounds of the formula I in which R1 and R2 are as defined herein, are suitable for use in TN and STN liquid-crystal displays.
    Type: Grant
    Filed: April 7, 2004
    Date of Patent: May 30, 2006
    Assignee: Merck Patent GmbH
    Inventors: Harald Hirschmann, Sven Schuepfer, Renate Graulich, Martina Weidner, Kevin Adlem, Mark John Goulding, Patricia Saxton
  • Patent number: 7052742
    Abstract: Fluorinated five-membered ring compounds of the formula (I) R1—X—(A1—M1)a—(A2—M2)b—A3—Y—E ??(I) where E is a radical T—Z—R2 containing a five-membered ring and, for example, T is undirected and is 4-fluorothiophene-2,5-diyl, 3-fluorothiophene-2,5-diyl, 3-fluorothiophene-2,4-diyl, 5-fluorothiophene-2,4-diyl, furan-2,5-diyl, furan-2,4-diyl, isoxazole-3,5-diyl, thiazole-2,5-diyl, thiazole-2,4-diyl, cyclopentane-1,3-diyl or cyclopentene-1,3-diyl, R1 and R2 are hydrogen, X is a single bond, —O—, OC(?O)—, —C(?O)O— or —OC(?O)O—, Y is —OC(?O)—, —OCH2—, —CH2CH2—, Z is a single bond or —O—, A1, A2, A3 are each, independently of one another, phenylene-1,4-diyl, M1, M2 are undirected and are each, independently of one another, —OC(?O)—, —OCH2—, —CH2CH2—, —OC(?O)CH2CH2—, —OCH2CH2CH2—, —C?C—, —CH2CH2CH2CH2— or a single bond, a, b are each, independently of one another, 0 or 1, are used in FLC mixtures.
    Type: Grant
    Filed: August 31, 2000
    Date of Patent: May 30, 2006
    Assignee: Clariant International Ltd.
    Inventors: Barbara Hornung, Toshiaki Nonaka, Ayako Ogawa, Wolfgang Schmidt, Rainer Wingen
  • Patent number: 7048974
    Abstract: The invention relates to TN and STN liquid-crystal displays and to the nematic liquid-crystal mixtures used therein, characterised in that they comprise one or more compounds of the formula I and one or more compounds of the formula II in which ring A, R1, R2 and Y are as defined in Claim 1.
    Type: Grant
    Filed: April 25, 2002
    Date of Patent: May 23, 2006
    Assignee: Merck Patentgesellschaft Mit Beschrankter Haftung
    Inventors: Antje Mühlfeld, Michael Junge, Harald Hirschmann, Sabine Schoen, Juliane Suermann, Ursula Patwal, Dagmar Zimmermann
  • Patent number: 7045176
    Abstract: The present invention relates to a liquid crystal composition having a high-speed response property and a liquid crystal display using the same, more particularly to a liquid crystal composition, wherein the liquid crystal has a high phase transition temperature, large birefringence index and modulus of elasticity, and a wide operable nematic temperature range, so that a high-speed response can be obtained to be useful for many liquid crystal devices including LCDs, and a liquid crystal display using the same.
    Type: Grant
    Filed: November 26, 2003
    Date of Patent: May 16, 2006
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Yong-Kuk Yun, Bong-Hee Kim, Bong-Sung Seo, Byeong-Seob Ban
  • Patent number: 7041347
    Abstract: Liquid-crystalline media comprising one or more compounds of the formula I in which Ra, Rb, L and r are as defined herein, are suitable for use in, for example, TN and STN liquid crystal displays
    Type: Grant
    Filed: February 13, 2004
    Date of Patent: May 9, 2006
    Assignee: Merck Patent GmbH
    Inventors: Harald Hirschmann, Martina Weidner, Sven Schüpfer, Renate Graulich, Mark John Goulding, Martin Heeney, Warren Duffy
  • Patent number: 7041234
    Abstract: A method for producing platform molecules comprising: forming a mixture comprising first and second phenylene rings comprising halogenated carboxylic groups, and a third phenylene ring comprising a desired substituent and a first functionality at a para-position to a second funcitonality; and exposing the mixture to conditions effective to react the first halogenated carboxylic group with the first functionality to produce a first ester bond, and the second halogenated carboxylic group with the second functionality to produce a second ester bond; producing platform molecules comprising terminal groups comprising the first functional group at a position para to first ester bond and the second functional group at a position para to the second ester bond.
    Type: Grant
    Filed: January 23, 2002
    Date of Patent: May 9, 2006
    Assignee: Southwest Research Institute
    Inventors: Stephen T. Wellinghoff, Douglas P. Hanson
  • Patent number: 7033654
    Abstract: A liquid-crystalline medium based on a mixture of polar compounds of positive dielectric anisotropy, which medium exhibits a birefringence value of ?0.065 and includes one or more compounds of formula Ia and at least one compound of the formula Xc or Xd: in which R, alkyl, alkenyl and alkenyl* are as defined in claim 1.
    Type: Grant
    Filed: July 2, 2004
    Date of Patent: April 25, 2006
    Assignee: Merck Patent GmbH
    Inventors: Michael Heckmeier, Brigitte Schuler, Kazuaki Tarumi, Peer Kirsch, Volker Reiffenrath
  • Patent number: 7033651
    Abstract: The invention relates to a liquid-crystalline medium comprising a mixture of at least two compounds of the general formula (I) R1-Am-Bn-Z1-C-Z2-D-R2??(I) in which R1 is H, an alkyl or alkenyl radical having 1 to 15 carbon atoms and 2 to 15 carbon atoms, respectively, which is unsubstituted, monosubstituted by CN or CF3 or at least monosubstituted by halogen, where one or more CH2 groups in these radicals may also, in each case independently of one another, be replaced by —O—, —S—, ?—CO—, —CO—O—, —O—CO— or —O—CO—O— in such a way that O atoms are not linked directly to one another; A, B, C and D are each, independently of one another, in which Y, Y1, Y2, Y3, Y4, Y5 and Y6 are each, independently of one another, H or F; C is, in addition to the abovementioned meanings, Z1 and Z2 are each, independently of one another, a single bond, —CH2O—, —OCH2—, —CH2—CH2—, —CH?CH—, —C?C—, —CF2—CF2—, 13 CF2O—, —OCF2— or —CO—O—; R2 is, in addition to the abovementioned meanings of R1, F, CF3, OCF3, OCHF2, OCH2CF
    Type: Grant
    Filed: April 17, 2001
    Date of Patent: April 25, 2006
    Assignee: Merck Patent GmbH
    Inventors: Michael Heckmeier, Detlef Pauluth
  • Patent number: 7029729
    Abstract: The invention provides a cholesteric liquid crystal composition that includes at least one cholesteric liquid crystal precursor, and at least one non-liquid crystalline additive that is a non-liquid crystalline compound of formula I The invention also provides cholesteric liquid crystal films and optical bodies formed from cholesteric liquid crystal compositions of the invention. The invention further provides an optical display that includes a display medium, and a reflective polarizer including a cholesteric liquid crystal composition in accordance with the invention.
    Type: Grant
    Filed: February 24, 2003
    Date of Patent: April 18, 2006
    Assignee: 3M Innovative Properties Company
    Inventors: Terence D. Spawn, Marc D. Radcliffe, Richard J. Pokorny
  • Patent number: 7029731
    Abstract: The invention relates to a liquid-crystalline medium based on a mixture of polar compounds having positive dielectric anisotropy, characterized in that it comprises one or more compounds of the general formula I in which R, A1, Z1, Y and L are as defined in claim 1.
    Type: Grant
    Filed: August 6, 2003
    Date of Patent: April 18, 2006
    Assignee: Merck Patent GmbH
    Inventors: Kazuaki Tarumi, Brigitte Schuler, Eike Poetsch, Volker Reiffenrath, Yukiomi Tanaka
  • Patent number: 7026022
    Abstract: The invention relates to a liquid crystalline medium characterized by containing one or more compounds of general formula (I) and one or more compounds of formula (II), wherein R1, R2, R3, R4 and c have the meanings as cited in Claim No. 1.
    Type: Grant
    Filed: January 14, 2005
    Date of Patent: April 11, 2006
    Assignee: Merck Patent GmbH
    Inventors: Melanie Klasen-Memmer, Dagmar Klement, Matthias Bremer
  • Patent number: 7026020
    Abstract: The invention relates to a liquid-crystalline medium based on a mixture of polar compounds of positive dielectric anisotropy, which medium comprises one or more compounds the general formula Ia and one or more compounds selected from the group consisting of compounds of the formula III and V to VIII: The notations r, R, R0, X0, Z0 and Y1-4 are defined herein.
    Type: Grant
    Filed: July 2, 2004
    Date of Patent: April 11, 2006
    Assignee: Merck Patent GmbH
    Inventors: Michael Heckmeier, Brigitte Schuler, Kazuaki Tarumi, Peer Kirsch, Volker Reiffenrath
  • Patent number: 7022259
    Abstract: A liquid crystal compound with high helical twisting power, a method for preparing the same, and a liquid crystal composition containing the same. The liquid crystal compounds include cyclic group chain structures similar to the liquid crystal to serve as the core structure, and multi-ring structures of natural alcohol with optical activity, such as alcoholates of terpenol, borneol, cinchonidine, quinine, or derivatives thereof. As a result, the liquid crystal composition containing the liquid crystal compounds can filter out light of specific wavelengths from incident light due to optical activity and high helical twisting power thereof.
    Type: Grant
    Filed: September 30, 2003
    Date of Patent: April 4, 2006
    Assignee: Industrial Technology Research Institute
    Inventors: Dao-Hung Lee, Ding-Jen Chen, Kung-Lung Cheng
  • Patent number: 7014791
    Abstract: Liquid crystalline polymer having repeat units derived from 4,4?-biphenol, terephthalic acid, 2,6-naphthalenedicarboxylic acid, and 4-hydroxybenzoic acid in a limited compositional range have melting points of 400° C. or more, and are useful for molded articles and for films, particularly for uses where good high temperature resistance is needed.
    Type: Grant
    Filed: December 2, 2003
    Date of Patent: March 21, 2006
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Marion G. Waggoner, Michael Robert Samuels
  • Patent number: 7001648
    Abstract: A glassy chiral-nematic liquid crystal composition includes a compound having the structural formula wherein each N represents a nematic group connected to the 1, 3, 5-benzenetricarbonyl central moiety by a carboxylic ester linkage and Ch represents a chiral group connected to the central moiety by a carboxylic ester linkage. An optical device is formed from at least one of the glassy chiral-nematic liquid crystal compositions.
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: February 21, 2006
    Assignee: University of Rochester
    Inventors: Shaw H. Chen, Huang-Ming Philip Chen
  • Patent number: 7001646
    Abstract: The invention relates to a liquid crystalline medium based on a mixture of polar compounds with positive dielectric anisotropy, characterized in that said medium contains one or more alkenyl compounds of the formula (I) and one or more compounds of the formula (IA) wherein R, R1, R2, ring A and ring B, L1, L2; L3; L4; X, Z1, Z2, y and z have the meanings cited in Claim 1.
    Type: Grant
    Filed: December 18, 2000
    Date of Patent: February 21, 2006
    Assignee: Merck Patent GmbH
    Inventors: Michael Heckmeier, Brigitte Schuler, Achim Goetz, Peer Kirsch, Eike Poetsch, Detlef Pauluth
  • Patent number: 7001647
    Abstract: A novel perfluoroallyloxy compound represented by general formula (I) and a liquid crystal composition containing the compound are disclosed.
    Type: Grant
    Filed: December 4, 2003
    Date of Patent: February 21, 2006
    Assignee: Asahi Denka Co., Ltd.
    Inventors: Hirokatsu Shinano, Takahiro Otsuka, Masatomi Irisawa
  • Patent number: 6974607
    Abstract: Tetrahydropyran derivatives having at least one ester group (—CO—O—) and at least one group —CN, —NCS, —F, —Cl, —OCHF2, —OCF3, —CF3, —OCHFCF3, —OCF2CHFCF3, SF5, or —OCF2CF3; a process for preparing said tetrahydropyran derivatives, and the use of said tetrahydropyran derivatives as a component in a liquid crystal composition.
    Type: Grant
    Filed: May 27, 2004
    Date of Patent: December 13, 2005
    Assignee: Merck Patent GmbH
    Inventors: Mark John Goulding, Warren Duffy, Kevin Adlem, Peer Kirsch, Alexander Hahn, Eike Poetsch, Werner Binder, Volker Meyer, Melanie Klasen-Memmer, Michael Heckmeier, Georg Lüssem
  • Patent number: 6964794
    Abstract: The invention relates to a liquid-crystalline medium based on a mixture of polar compounds of positive dielectric anisotropy, characterized in that it comprises one or more compounds of the formula I in which R1, L1 and L2 are as defined in claim 1.
    Type: Grant
    Filed: July 8, 2004
    Date of Patent: November 15, 2005
    Assignee: Merck Patent GmbH
    Inventors: Michael Heckmeier, Brigitte Schuler, Izumi Saito, Volker Reiffenrath, Georg Luessem, Christian Hock
  • Patent number: 6962733
    Abstract: The invention relates to a liquid-crystalline medium based on a mixture of polar compounds of positive dielectric anisotropy, characterized in that it comprises one or more compounds of the formula I in which R1, L1 and L2 are as defined in claim 1.
    Type: Grant
    Filed: July 8, 2004
    Date of Patent: November 8, 2005
    Assignee: Merck Patent GmbH
    Inventors: Michael Heckmeier, Brigitte Schuler, Izumi Saito, Volker Reiffenrath, Georg Luessem, Christian Hock
  • Patent number: 6953610
    Abstract: A liquid-crystalline medium based on a mixture of polar compounds of positive dielectric anisotropy, which contains: one or more compounds of the general formula I ?in which R, ?Y, Z and n are as defined in claim 1, one or more compounds of the following formulae IIa, IIb, IIc and IId and one or more compounds of the formula in which Ro, Xo, Y2 and r are as defined in claim 1.
    Type: Grant
    Filed: July 2, 2004
    Date of Patent: October 11, 2005
    Assignee: Merck Patent GmbH
    Inventors: Michael Heckmeier, Brigitte Schuler, Kazuaki Tarumi, Peer Kirsch, Volker Reiffenrath
  • Patent number: 6951669
    Abstract: A liquid-crystalline medium having a mixture of polar compounds of positive dielectric anisotropy is described.
    Type: Grant
    Filed: July 2, 2004
    Date of Patent: October 4, 2005
    Assignee: Merck Patent GmbH
    Inventors: Michael Heckmeier, Brigitte Schuler, Kazuaki Tarumi, Peer Kirsch, Volker Reiffenrath
  • Patent number: 6939940
    Abstract: Main chain thermotropic liquid crystal esters, ester-imides, and ester-amides were prepared from AA, BB, and AB type monomeric materials and were end-capped with phenylacetylene, phenylmaleimide, or nadimide reactive end-groups. The resulting reactive end-capped liquid crystal oligomers exhibit a variety of improved and preferred physical properties. The end-capped liquid crystal oligomers are thermotropic and have, preferably, molecular weights in the range of approximately 1000-15,000 grams per mole. The end-capped liquid crystal oligomers have broad liquid crystalline melting ranges and exhibit high melt stability and very low melt viscosities at accessible temperatures. The end-capped liquid crystal oligomers are stable for up to an hour in the melt phase.
    Type: Grant
    Filed: January 5, 2001
    Date of Patent: September 6, 2005
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Theodorous J. Dingemans, Erik S. Weiser, Terry L. St. Clair
  • Patent number: 6936312
    Abstract: A liquid crystal composition comprising a first component consisting of at least one compound selected from a group of compounds represented by Formula (I) and a second component consisting of at least one compound selected from a group of compounds represented by Formulas (II-1) to (II-8): in which each symbols of Formula (I) are defined in the specification and Formulas (II-1) to (II-8) and their symbols are also defined in the specification.
    Type: Grant
    Filed: April 9, 2003
    Date of Patent: August 30, 2005
    Assignees: Chisso Corporation, Chisso Petrochemical Corporation
    Inventors: Yuzuru Torii, Hitoshi Yamamoto
  • Patent number: 6936186
    Abstract: A mesomorphic compound having an ionic conductivity is used as an electrolyte for a secondary battery, etc. The mesomorphic compound has a partial structure which includes (a) a mesomorphic mesogen group and (b) two divalent groups. Each of the two divalent groups is directly connected to the mesogen group, and each of the two divalent groups is represented by the following formula: (OCH2CH2)x or (OCH2CH(CH3))y in which x and y are respectively an integer of 3 to 25. The mesomorphic compound may be a polymeric mesomorphic compound.
    Type: Grant
    Filed: July 20, 2001
    Date of Patent: August 30, 2005
    Assignee: Canon Kabushiki Kaisha
    Inventors: Satoshi Igawa, Shinichi Nakamura
  • Patent number: 6933022
    Abstract: The invention relates to a liquid crystalline medium characterized by containing one or more compounds of general formula (I) and one or more compounds of formula (II), wherein R1, R2, R3, R4 and c have the meanings as cited in Claim No. 1.
    Type: Grant
    Filed: April 29, 2002
    Date of Patent: August 23, 2005
    Assignee: Merck Patent GmbH
    Inventors: Melanie Klasen-Memmer, Dagmar Klement, Matthias Bremer
  • Patent number: 6929833
    Abstract: Liquid-crystalline mediums based on a mixture of polar compounds having positive dielectric aniostropy, characterized in that they comprise one or more compounds of the general formula I in which R, A1, Z1, Y and L are as defined herein, are suitable for use in MLC, TN and STN dispalys.
    Type: Grant
    Filed: April 4, 2003
    Date of Patent: August 16, 2005
    Assignee: Merck Patent GmbH
    Inventors: Kazuaki Tarumi, Brigitte Schuler, Eike Poetsch, Volker Reiffenrath, Yukiomi Tanaka
  • Patent number: 6921560
    Abstract: A liquid crystal composition having a negative dielectric anisotropy, containing at least one compound selected from the group of compounds represented by Formulas (1-1), (1-2), (1-3) and (1-4) as a first component: wherein R5 is alkyl or alkenyl; R2 is alkyl or alkoxy; A5 is 1,4-phenylene or 2-fluoro-1,4-phenylene; and A6 is 1,4-phenylene, 2-fluoro-1,4-phenylene or 2,3-difluoro-1,4-phenylene.
    Type: Grant
    Filed: February 3, 2004
    Date of Patent: July 26, 2005
    Assignees: Chisso Petrochemical Corporation, Chisso Corporation
    Inventors: Eiji Okabe, Yoshitaka Tomi, Masayuki Saito, Hitoshi Yamamoto
  • Patent number: 6919108
    Abstract: A liquid crystal composition containing at least one compound selected from compounds of formula (1) and formula (2) as a first component, at least one compound selected from compounds of formula (3) as a second component, and at least one compound selected from compounds of formula (4) as a third component: wherein R1 is alkyl; R2 is alkyl or alkenyl; Z1 and Z2 are independently a single bond or —(CH2)2—; X1 is hydrogen or fluorine; and Y1 is fluorine or —OCF3. Also provided is a liquid crystal display element containing the composition.
    Type: Grant
    Filed: December 3, 2003
    Date of Patent: July 19, 2005
    Assignees: Chisso Petrochemical Corporation, Chisso Corporation
    Inventors: Yoshitaka Tomi, Eiji Okabe
  • Patent number: 6908645
    Abstract: The invention relates to liquid-crystalline compounds of the formula I and to a liquid-crystalline medium based on a mixture of polar compounds, characterized in that it comprises one or more compounds of the general formula I in which R1, L1, L2, L3, L4, L5, L6, Z1, Z2, X, v and u are as defined in claim 1.
    Type: Grant
    Filed: September 30, 2003
    Date of Patent: June 21, 2005
    Assignee: Merck Patent GmbH
    Inventors: Peer Kirsch, Marc Lenges, Michael Heckmeier