Abstract: An ammonia synthesis apparatus has a piston arranged to reciprocate within a cylinder, a piston rod arranged to drive the piston in a reciprocal motion within the cylinder, an inlet valve linking a supply of nitrogen and hydrogen to the interior of the cylinder; an outlet valve allowing exhaust of ammonia from the cylinder, and a drive mechanism providing drive to the piston rod.

Abstract: A synthesis plant (309A) includes a compression device (360A) that increases a pressure differential between the bottom product pressure of a cryogenic separator (340A) and the delivery pressure of the bottom product to a downstream plant component. Such increased pressure differential is employed to increase cooling in the separator (340A) to thereby significantly reduce the volume of excess air. In most preferred aspects, at least part of the energy required for the compression device is provided by expansion (320A) of the separator feed.

Abstract: Method for purification of ammonia or mixtures of nitrogen and hydrogen, or nitrogen, hydrogen and ammonia, where ammonia or a mixture of gases under pressure of from 0.1 to 25 MPa is passed through a column packed with aluminium oxide with a large specific surface area, the ammonia or mixture of gases is then passed through a column packed with CaO, NaOH, KOH or an NaOH/KOH melt, separately or in a mixture, at 20 to 70° C. and under pressure of from 0.1 to 25 MPa, and the ammonia or mixture of gases is passed through a column packed with activated carbon having a specific area of 100-3000 m2/g with sodium, potassium, caesium, magnesium, calcium, strontium, barium or cerium nitrates(V) or nitrates(III) deposited on its surface, separately or in a mixture.

Abstract: The goal of the invention consists in making available a method for supplying fuel to a pressurized gasification system, which ensures, in economically efficient manner, that the emission of pollutants from the coal transfer and the transport is minimized or completely avoided. This is achieved in that a gas that contains at least 10 ppm vol. CO is used for transfer and/or conveying, whereby a gas that contains oxygen is mixed into this gas, and that this gas mixture is heated to a temperature that oxidizes at least 10% of the pollutants contained in the gas.

Abstract: A system (10) for delivery of dilute fluid, utilizing an active fluid source (12), a diluent fluid source (14), a fluid flow metering device (24) for dispensing of one of the active and diluent fluids, a mixer (28) arranged to mix the active and diluent fluids to form a diluted active fluid mixture, and a monitor (42) arranged to sense concentration of active fluid and/or diluent fluid in the diluted active fluid mixture, and responsively adjust the fluid flow metering device (24) to achieve a predetermined concentration of active fluid in the diluted active fluid mixture. A pressure controller (38) is arranged to control flow of the other of the active and diluent fluids so as to maintain a predetermined pressure of the diluted active fluid mixture dispensed from the system. The fluid dispensed from the system then can be adjustably controlled by a flow rate controller, e.g., a mass flow controller, to provide a desired flow to a fluid-utilizing unit, such as a semiconductor process tool.

Abstract: A process for producing ammonia synthesis gas from a hydrocarbon-containing feedstock, with steps of primary reforming, secondary reforming with an oxidant stream, and further treatment of the synthesis gas including shift, removal of carbon dioxide and methanation, wherein the synthesis gas delivered by secondary reforming is subject to a medium-temperature shift (MTS) at a temperature between 200 and 350° C., and primary reforming is operated with a steam-to-carbon ratio lower than 2. A corresponding method for revamping an ammonia plant is disclosed, where an existing HTS reactor is modified to operate at medium temperature, or replaced with a new MTS reactor, and the steam-to-carbon ratio in the primary reformer is lowered to a value in the range 1-5-2, thus reducing inert steam in the flow rate trough the equipments of the front-end.

Abstract: A process and related equipment for producing ammonia synthesis gas are disclosed, wherein a raw syngas (13) is purified in a cryogenic section (CS) and a nitrogen-rich liquid stream (30) is separated from the raw syngas flow during purification and HN ratio adjustment, and wherein the pressure of said liquid stream (30) is reduced in a turbine (80) to enhance net refrigerative effect for the cryogenic section. Embodiments wherein chilling is also provided by a low-pressure or high-pressure syngas expander are also disclosed.

Abstract: An apparatus and a method for inhibiting metal dusting corrosion of a tubesheet inside a shell-and-tube heat exchanger having at least one exit nozzle for transmitting at least one process fluid from the shell-and-tube heat exchanger include and use: an isolation baffle disposed inside the shell-and-tube heat exchanger at a location between a first exit nozzle and the tubesheet, whereby an isolated space exists between the tubesheet and the isolation baffle; and a means for purging the isolated space with a purging fluid.

Abstract: A system for producing ammonia by integrating blast furnace ironmaking with ammonia production wherein cryogenic rectification links the two systems enabling the production of ammonia synthesis gas from blast furnace gas for use in the ammonia production.

Abstract: The present invention provides a process for the production of a synthesis gas mixture containing carbon oxides and hydrogen from a hydrocarbon feedstock material comprising: providing a reforming zone having a plurality of chambers charged with a catalyst effective for catalysis of at least one reforming reaction; supplying to the chambers of the reforming zone a vaporous mixture of the hydrocarbon feedstock and a reforming reagent; maintaining the reforming zone under suitable reforming conditions for reforming of the hydrocarbon feedstock and reforming reagent to form the synthesis gas mixture by supplying to the reforming zone a fuel for heating the chambers by combustion and by supplying to the steam reforming zone a vaporous steam comprising combustion oxygen in which the fuel may be combusted; humidifying the vaporous steam comprising combustion oxygen; exchanging heat between the humidified vaporous steam comprising combustion oxygen entering the reforming zone and the synthesis gas mixture exiting th

Abstract: The invention generally relates to gelled oil compositions which employ aluminum complex soaps as gelling agents. The gelled oils comprise an oil component, a bleed inhibitor of polybutene, and optional amounts of antioxidant and pour point depressant. The gelled oils are particularly suited for use as buffer tube gels and as filling compounds for waveguides.

Abstract: This invention relates to lubricants for two-cycle engines comprising a major amount of at least one oil of lubricating viscosity and a minor amount of at least one compound of the general formulaA.sup.y- M.sup.y+ (I)wherein M represents one or more metal ions, y is the total valence of all M and A represents one or more anion containing groups having a total of about y individual anionic moieties and each anion containing group is a group of the formula ##STR1## wherein T is selected from the group consisting of ##STR2## Additive concentrates and lubricant-fuel mixtures for two cycle engines are also disclosed as well as methods for operating two-cycle engines.

Abstract: A process for the preparation of ammonia synthesis gas by steam reforming and/or partial oxidation of a hydrocarbon feedstock comprises the further steps of catalytically converting a part of the synthesis gas to methanol, liquifying and separating the prepared methanol from remaining nitrogen rich gas, then reconverting the nitrogen depleted methanol to hydrogen and carbon oxides gas and recombining the gas with the reminder of the nitrogen containing synthesis gas to obtain stoichiometric ammonia synthesis gas.

Abstract: The present invention provides a composition for use in compression refrigeration and air-conditioning comprising: (a) 1,1-dichloro-2,2,2-trifluoroethane; and (b) a sufficient amount to provide lubrication of a lubricant therefor wherein said lubricant is an aliphatic non-hydrogen containing compound, an aliphatic compound having greater than about 80 percent non-hydrogen containing atoms, or an aliphatic hydrogen-containing compound having greater than about 80 percent exterior primary hydrogens, has a viscosity of about 5 to about 150 centistokes at 37.degree. C., and is miscible in combination with said 1,1-dichloro-2,2,2-trifluoroethane in the range of about 0.degree. C. to at least +20.degree. C. The compositions may further comprise an effective amount of stabilizer.The present composition is useful in compression refrigeration and air-conditioning equipment.

Abstract: Aqueous compositions of emulsified oxyaluminum acylate solutions comprising solutions of oxyaluminum acylate in a largely water insoluble solvent, an alcohol or an organic acid, an emulsifier or mixture of emulsifiers, and water are provided. Articles comprising substrates rendered water-repellent with such emulsions are provided as well. A process for the preparation of such articles is also provided.

Abstract: Overbased magnesium sulphonates having increased resistance to interactions are prepared from sulphonic acids prepared from alkylates with long and medium chain alkyl groups. Compositions comprising such overbased magnesium sulphonate are particularly suitable for use in combination with high molecular weight dispersants and/or friction modifiers. Stable sediment-free lubricating oil compositions (including lubricants and concentrates therefor) can be prepared which can meet SG quality and the Tier II fuel economy requirements.

Abstract: Improved automatic transmission fluids (ATF's) and gear lubricant compositions comprising a low concentration of an oil-soluble transistion metal compound are provided. The transition metal compound ameliorates low temperature thickening in ATF's and high temperature thickening in gear lubricants.

Abstract: A process for the simultaneous production of methanol synthesis gas and ammonia synthesis gas proceeds from the crude gas of a coal gasification, which initially is subjected to a H.sub.2 S-washing at low temperatures. Then follows a splitting of the desulfurized gas into two partial streams, of which one partial stream is led directly into the CO.sub.2 -washing which serves for production of the methanol-synthesis gas. Another partial stream is in contrast initially subjected to a conversion. From the converted gas then a partial stream is branched off which is provided for the production of ammonia-synthesis gas, whereas the remainder of the converted gas is led into the CO.sub.2 -washing serving for the production of the methanol-synthesis gas. The partial straem serving for the production of the ammonia-synthesis gas is treated to a separate CO.sub.2 -washing, in which simultaneously the so-called purge gas from the ammonia-synthesis is led in. The H.sub.2 S-washing and the CO.sub.

Abstract: Fouling of metallic surfaces contacted with hydrocarbon oils at elevated temperatures is reduced by combining the oils with foulant-inhibiting amounts of thiadiazole compounds or triazole compounds, or aluminum compounds in combinations containing thiadiazole, triazole and acid compounds.

Abstract: A method for making an oil additive comprising adding 2 gallons of 3% sodium hypochlorite to 45 gallons of diesel oil fuel, or similar proportions, to form a sulphur free fuel, removing all water and foreign matter formed by the sodium hypochlorite, blending 30 gallons of 24% lead naphthanate with 15 gallons of said sulphur free fuel, 15 gallons of light-weight mineral oil and about 1/2 gallon of 0.75% nitro benzene, or similar proportions to form a blended mixture, and heating the blended mixture slowly and uniformly to 152.degree. F.

Abstract: A raw ammonia synthesis gas, preferably containing an excess of nitrogen, is converted to synthesis ready ammonia synthesis gas by two pressure swing adsorption (PSA) stages operated in succession. If the raw gas contains carbon monoxide this is chemically removed, e.g. by methanation, between the PSA stages. In the first PSA stage, CO.sub.2 is removed and waste gas from the second PSA stage is preferably fed back to the first PSA stage for sweeping, purging or repressurizing. In a preferred system the first PSA cycle includes a sweep with CO.sub.2 -rich gas prior to depressurization and purge with second PSA waste gas. In the second PSA stage inert medium boiling gases, and any unwanted nitrogen are removed as the waste gas.

Abstract: Production of ammonia synthesis gas by partial oxidation of a hydrocarbon feedstock, using air, oxygen enriched air, or oxygen depleted air, in admixture with steam, followed by shift and the removal of the excess of nitrogen, and also impurities such as carbon oxides and methane, by pressure swing adsorption (PSA). The PSA waste gas is combusted and used to heat the air and/or steam prior to the use thereof in the partial oxidation.

Abstract: A carbonaceous feedstock, e.g. coal or heavy oil, having a low hydrogen to carbon atomic ratio is partially oxidized using air, or oxygen enriched or depleted air, to form a crude gas which is subjected to catalytic shift and excess steam removal. Carbon dioxide and nitrogen are then removed from the resultant raw gas, which has a hydrogen to nitrogen, plus carbon monoxide, volume ratio in the range 0.5 to 1.5 and a nitrogen content at least 10 times the carbon monoxide content, in a pressure swing adsorption process thereby producing a product gas stream containing at least 50% hydrogen and 0.5 to 40% nitrogen, by volume. The waste gas from the pressure swing adsorption may be catalytically combusted to power a turbine driving the compressor for the air or the crude gas.

Abstract: Solutions of complexed mixed soaps of vanadium and at least one other metal in organic solvents are produced by the reaction of an inorganic vanadium compound, an oxidizable metal, and an organic monocarboxylic acid, in the presence of oxygen, water, and an inert, water-immiscible organic solvent.

Abstract: A process for removal of excess nitrogen and carbon oxides from a raw synthesis gas used to make ammonia. The raw synthesis gas is divided into two portions. The first portion is methanated to remove carbon oxides and then cooled to condense part of its nitrogen content. The condensed nitrogen is fed to the top of a nitrogen wash column. The second portion of the raw synthesis gas is passed over an absorbent which removes carbon dioxide and water vapor. It is then cooled to condense excess nitrogen. The remaining gas is fed to the bottom of a nitrogen wash column where it is washed free of carbon monoxide by the nitrogen condensed from the methanated gas stream.

Abstract: The synthesis gas for an ammonia synthesis process is refined by treating same in an adsorption-desorption unit to remove nitrogen either during the carbon oxide removal step or in the ammonia synthesis loop.

Abstract: An improved process for making synthetic ammonia wherein a make-up synthesis gas is added to recycled unreacted gas from a catalytic conversion loop including the steps of introducing a volatile anti-icing compound into the hot make-up gas to vaporize the compound, cooling the gas and vaporized anti-icing compound to condense part of the anti-icing compound, separating the condensed anti-icing compound and dissolved impurities from the make-up gas, further cooling the make-up gas to a temperature at which the remaining anti-icing compound condenses essentially completely, separating the condensed remaining anti-icing compound from the make-up gas, mixing the resulting make-up gas at the low temperature with liquid ammonia to saturate the make-up gas with ammonia, separating unvaporized liquid ammonia from the saturated make-up gas, mixing the saturated make-up gas with recycle and passing the mixed gases directly to the catalytic ammonia synthesis converter.

Abstract: A process for producing ammonia synthesis gas in which a pressure swing adsorption unit is utilized to replace former CO.sub.2 removal, methanation, drying and purification steps. To increase the efficiency of the process, a hydrogen fuel cell is utilized to generate electricity and a high purity nitrogen purge stream for a pressure swing absorption unit. Accordingly, after reforming and high temperature catalytic shift conversion, the feed stream is divided into a first stream to feed the fuel cell and a second stream which is directly introduced to the pressure swing adsorption unit. After the first stream is reacted in the fuel cell, a nitrogen rich stream is passed to a de-oxygenation unit and then utilized as the pressure swing adsorption purge stream.

Abstract: The reformed gas mixture to be employed for ammonia synthesis is purified, following shift conversion, by the selective catalytic oxidation of residual carbon monoxide and the selective adsorption of carbon dioxide and water so as to render unnecessary the methanation of carbon oxides.

Abstract: What are disclosed are lubricating greases containing aluminum complex soaps prepared from aluminum isopropoxides modified for stability and improved flash point.

Abstract: Difficulties associated with the operational stability of a conventional cryogenic plant for manufacturing ammonia synthesis gas from a stream rich in hydrogen and a stream of nitrogen are reduced by using three heat exchangers in place of the conventional single heat exchanger. In use, the first heat exchanger, which is preferably arranged with its cold end uppermost, is used to cool the stream of nitrogen to a temperature which:(a) if the nitrogen is above its critical pressure is between 8.degree. and 28.degree. C. above its critical temperature; or(b) if the nitrogen is below its critical pressure is between 3.degree. and 9.degree. C. above its dew point.Part of the nitrogen leaving the first heat exchanger is passed downwardly through a third heat exchanger where it is further cooled before being introduced into a nitrogen wash column where it acts as reflux. The third heat exchanger is cooled by vapor leaving the top of the nitrogen wash column.

Abstract: An improved process for making a mixed oxyaluminum acylate composition wherein the mole ratio of aromatic to aliphatic radicals ranges from about to 2:3 to 19:1 and improved aluminum complex greases made using a mixed oxyaluminum acylate wherein the mole ratio of aromatic to aliphatic radicals is from about 2:3 to 3:1.

Abstract: A continuous process for making aluminum complex greases involving the step of passing a mixed dispersion of oxyaluminum acylate and carboxylic acid material in a grease making oil through a reaction zone.

Abstract: Mixed aromatic/aliphatic oxyaluminum acylates wherein the ratio of the number of aromatic radicals to the number of aliphatic radicals ranges from 3:1 to 19:1 and a process for making such compounds. Also premix compositions useful in grease manufacture are provided along with methods for preparing new greases therefrom.

Abstract: Mixed aromatic/aliphatic oxyaluminum acylates are provided which have utility for the manufacture of greases without generating by-product alcohol and without requiring the use of water.

Abstract: Difficulties associated with the operational stability of a conventional cryogenic plant for manufacturing ammonia synthesis gas from a stream rich in hydrogen and a stream of nitrogen are reduced by using three heat exchangers in place of the conventional single heat exchanger. In use, the first heat exchanger, which is preferably arranged with its cold end uppermost, is used to cool the stream of nitrogen to a temperature which:(a) if the nitrogen is above its critical pressure is between 8.degree. and 28.degree. C. above its critical temperature; or(b) if the nitrogen is below its critical pressure is between 3.degree. and 9.degree. C. above its dew point.Part of the nitrogen leaving the first heat exchanger is passed downwardly through a third heat exchanger where it is further cooled before being introduced into a nitrogen wash column where it acts as reflux. The third heat exchanger is cooled by vapor leaving the top of the nitrogen wash column.

Abstract: This invention deals with new lubricant compositions comprising a liquid lubricant thickened with a zirconium polymer containing a bridged zirconium atom where the bridged groups are the anions of phosphinic acids of structure RR'P(X)XH or of carboxylic acids of structure RCOOH where R and R' are selected from hydrogen, alkyl, aryl, fluorinated and perfluorinated alkyl and aryl groups and X is oxygen or sulfur.

Abstract: Metallo-organic compositions soluble in oils and hydrocarbon solvents, of a high transitional metal content and highly overbased character, are prepared from sources of transitional metals (or of transitional in conjunction with nontransitional metals) reacted with mixed organic acids comprising at least one monocarboxylic acid and a second acid, either a sulfonic acid or a different molecular weight monocarboxylic acid. Formation of the complexes requires the use of excesses of metal over acids, and the use of an oxygen-supplying material such as air, regardless of whether the metal source be a free metal, an oxide or a hydroxide. Alkoxyalkanols or glycols may be used in addition to the required acids.

Abstract: A process for manufacturing high dropping point aluminum complex soap thickened greases having selected consistency, water resistance, rheopectic properties, and antiwear properties.

Abstract: The Polymer of 1,2,4-thiadiazole of the structure ##STR1## AND LUBRICANTS CONTAINING SAID POLYMER ARE PROVIDED.

Abstract: Novel 4-(3,5-dialkyl-4-hydroxyphenyl)-1,2-dithiole-3-thiones are used as additives for organic materials. They are prepared by reacting a corresponding alkylated phenol with sulfur and if necessary reacting the resulting compound with sodium disulphide and then with a corresponding halide.