Zinc Or Aluminium Containing Patents (Class 252/400.52)
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Patent number: 9005355Abstract: Anticorrosive coating compositions as disclosed comprise a binding polymer and an aluminum phosphate corrosion inhibiting pigment dispersed therein. The coating composition comprises up to 25 percent by weight aluminum phosphate. The binding polymer can include solvent-borne polymers, water-borne polymers, solventless polymers, and combinations thereof. The aluminum phosphate is made by sol gel process of combining an aluminum salt with phosphoric acid and a base material. Aluminum phosphate colloidal particles are nanometer sized, and aggregate to form substantially spherical particles. The coating composition provides a controlled delivery of phosphate anions of 100 to 1,500 ppm, depending on post-formation treatment of the aluminum phosphate, and has a total solubles content of less than 1500 ppm, The amorphous aluminum phosphate is free of alkali metals and alkaline earth metals, and has a water adsorption potential of up to about 25 percent by weight water when present in a cured film.Type: GrantFiled: October 15, 2010Date of Patent: April 14, 2015Assignee: Bunge Amorphic Solutions LLCInventor: Raymond E. Foscante
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Publication number: 20150038626Abstract: The present invention relates to a composition comprising a metal complex of a 1,3-diketone and an optionally substituted full ester of a monool or a diol and a monocarboxylic acid; wherein a mixture consisting of (a) and (b) has a viscosity of less or equal than 40 mPa·s when measured at 80° C.Type: ApplicationFiled: January 23, 2012Publication date: February 5, 2015Applicant: AMRIL AGInventors: Peter Daute, Jurgen Waldmann
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Publication number: 20140027339Abstract: The invention relates to compounds of the structure of formula I and II: where X is selected from the group consisting of O, S and NH; Y, A and B are independently selected from the group consisting of N and CH; D, E and F are independently selected from the group consisting of CH, N, O and S; the symbol — represents a single or a double bond; and R1, R2 and R3 are independently selected from the group consisting of H, electron withdrawing groups and electron releasing groups. In other embodiments, the compounds are used as oxygen scavengers and in barrier compositions and articles.Type: ApplicationFiled: March 25, 2013Publication date: January 30, 2014Inventor: Constar International, Inc.
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Patent number: 8603392Abstract: Corrosion-inhibited hypochlorite compositions and methods of use are disclosed. Corrosion inhibitors including sugar acids and calcium compounds, polyacrylate and calcium compounds, and/or zinc and calcium compounds are used with hypochlorite sources to enhance the longevity and performance of electrochemical cells as well as reducing corrosion of metal in contact with the generated hypochlorite sources. The methods for generation employ a variety of electrochemical cells, beneficially including use of portable electrochemical cell system for production of corrosion-inhibited hypochlorite cleaning solutions.Type: GrantFiled: June 25, 2012Date of Patent: December 10, 2013Assignee: Ecolab USA Inc.Inventors: Jenna Johnson, Kim R. Smith, Erik C. Olson, Steven E. Lentsch
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Patent number: 8506854Abstract: The present invention relates to a stabilizer system for halogenated polymers comprising, as component (A), calcium monocarbonatohydroxodialuminate of the formula (A) CamAl2(OH)6+2(m-1)CO3*nH2O??(A), where m=from 3.8 to 4.2, and n=from 0 to 3, and, as component (B), a catena-2,2?,2?-nitrilotrisethanolperchloratolithium or -sodium coordination polymer (B1) with a monomer unit of the formula where Mt=Li or Na, An=OClO3 and q=1, and/or a quaternary or ternary ammonium or phosphonium perchlorate (B2). The present invention further relates to compositions and articles comprising these stabilizer systems, and to the use of the systems and compositions.Type: GrantFiled: August 4, 2008Date of Patent: August 13, 2013Assignee: Nabaltec AGInventors: Trupti Dave, Wolfgang Wehner
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Patent number: 8496853Abstract: Corrosion inhibitor compositions and methods of use are disclosed. Zinc and calcium corrosion inhibitors combined with hypochlorite sources provide use solutions for effective corrosion inhibition for metal surfaces.Type: GrantFiled: June 12, 2012Date of Patent: July 30, 2013Assignee: Ecolab USA Inc.Inventors: Erik C. Olson, Kim R. Smith, Steven E. Lentsch
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Patent number: 8303851Abstract: Mixtures of additives in granular form comprising: one or more stabilizers for organic polymers; one or more organic or inorganic pigments; and/or one or more dyes; obtained by extrusion at a temperature capable of enabling the partial or total melting of the lowest-melting component. The above mixtures can be used in the stabilization and dyeing of organic polymers.Type: GrantFiled: January 18, 2008Date of Patent: November 6, 2012Assignee: Great Lakes Chemical (Europe) GmbHInventors: Carlo Neri, Corrado Callierotti
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Publication number: 20120208941Abstract: The invention relates to a stabilizer system comprising a thermal stabilizer and a supported, at least partly calcined dolomite of the formula Mt1X1*CaX2 where Mt1=Mg or Zn; X1=O or (OH)2; X2=O; (OH)2 or CO3, wherein the calcined dolomite has been supported with a metal perchlorate of the formula Mt2(ClO4)m*nH2O where Mt2=Li, Na, K, Mg, Ca, Ba, Zn, Al, La, Ce; m=1, 2 or 3, m being selected so as to compensate for the charge of the metal ion Mt2; n=0 to 3 and wherein the stabilizer system does not comprise any of the compounds selected from the group consisting of (B) and (C) when Mt1 is Mg, and wherein (B) at least one nitrogen-containing organic compound is selected from the group consisting of (B1) and (B2), (B1) being a tert-alkanolamine and (B2) being an enaminone or a urea, and (C) an alkaline earth metal aluminohydroxocarbonate of the formula (C) (M1?xZnx)yAl2(OH)4+2y CO3* zH2O (C) where M=magnesium or/and calcium; x=0 to 0.5; y=2 to 8 and z=0 to 12.Type: ApplicationFiled: September 24, 2010Publication date: August 16, 2012Inventor: Walter Reith
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Patent number: 8128841Abstract: A method and composition are provided for the operation of an evaporative cooling tower with minimal, or no, blowdown. In some embodiments, the method involves using sodium cation-exchanged softened water as makeup water for the cooling tower, providing a bypass filter for suspended solids removal from the cooling water, treating the cooling water with a composition for control of corrosion and deposition, and using an effective biocide for control of biological growth within the cooling tower system. In some embodiments, a composition is provided that comprises AMPS acrylic terpolymer, sodium silicate, phosphate ions, and polyphosphate ions. When dosed at the recommended levels, the composition controls corrosion of cooling system materials to generally acceptable levels in spite of the extremely corrosive environment resulting from the cycling of sodium cation-exchanged softened water in the cooling tower.Type: GrantFiled: September 11, 2009Date of Patent: March 6, 2012Assignee: Prochemtech International, Inc.Inventor: Timothy E. Keister
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Publication number: 20110306501Abstract: The present invention relates to microcapsules with a core/shell structure which comprise at least one low molecular weight, anionic surfactant and have a metal oxide-containing shell, to a process for producing such microcapsules with a core/shell structure, to the use of the microcapsules with the core/shell structure and to preparations comprising the microcapsules with the core/shell structure.Type: ApplicationFiled: June 8, 2011Publication date: December 15, 2011Applicant: BASF SEInventors: Jing Dreher, Matthias Laubender, Michael Kutschera
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Patent number: 8012373Abstract: An anti-corrosion compound including a hydrocarbon grease and an aluminum/indium/zinc powder blended into the hydrocarbon grease.Type: GrantFiled: May 12, 2009Date of Patent: September 6, 2011Assignee: Raytheon CompanyInventor: Robert E. Walsh
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Publication number: 20110130273Abstract: Process for the preparation of modified ZnO particles in which a zinc salt and a base are mixed in a polar solvent and, if appropriate after the precipitation of a precipitation product, the polar solvent is removed and a residue is obtained, where the residue is taken up in a nonpolar solvent, surface-active substances are added, optionally further effect substances are added and then the modified ZnO particles are separated off from further by-products. Materials such as plastics, coatings or paints comprising modified ZnO particles. Methods for the incorporation of modified ZnO particles into materials, where the modified ZnO particles are incorporated into the materials in the form of dispersions or suspensions. Use of modified ZnO particles for protecting material against the effect of light, heat, oxygen or free radicals, as catalysts, for semiconductive films or cosmetic applications.Type: ApplicationFiled: July 14, 2009Publication date: June 2, 2011Applicant: BASF SEInventors: Andrey Karpov, Hartmut Hibst, Simon Schambony, Richard Riggs, Sylke Haremza
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Publication number: 20110129628Abstract: The present invention relates to a stabilizer system for halogenated polymers comprising, as component (A), calcium monocarbonatohydroxodialuminate of the formula (A) CamAl2(OH)6+2(m?1)CO3*nH2O??(A), where m=from 3.8 to 4.2, and n=from 0 to 3, and, as component (B), a catena-2,2?,2?-nitrilotrisethanolperchloratolithium or -sodium coordination polymer (B1) with a monomer unit of the formula where Mt=Li or Na, An=OClO3 and q=1, and/or a quaternary or ternary ammonium or phosphonium perchlorate (B2). The present invention further relates to compositions and articles comprising these stabilizer systems, and to the use of the systems and compositions.Type: ApplicationFiled: August 4, 2008Publication date: June 2, 2011Inventors: Trupti Dave, Wolfgang Wehner
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Patent number: 7671118Abstract: A stabilizer system for stabilizing halogen-containing polymers comprising a perchlorate salt and at least one indole compound, a composition comprising such a stabilizer system, process for stabilizing a chlorine-containing polymer using such a stabilizer system, and an article manufacture comprising PVC stabilized by such a stabilizer system.Type: GrantFiled: March 28, 2006Date of Patent: March 2, 2010Assignee: Chemtura Vinyl Additives, GmbHInventors: Wolfgang Wehner, Hans-Helmut Friedrich
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Patent number: 7659397Abstract: Zinc pyrithione and copper pyrithione are highly evaluated in the market as an antidandruff agent for shampoo, or an antifouling agent for ship bottom paint and fish-farming net, or an antibacterial/antifungal agent or preservative/mildewcide for industrial products and household articles. For enhancing the market value thereof, there has been a demand for a product that not only attains an increase in conventional antibacterial/antifungal effects but also exhibits novel bioactive effects and that achieves improvement with respect to problems and drawbacks relating to properties, such as solubility in seawater, and stability, such as thermal stability and weather resistance, of polymer materials. There is provided a novel pyrithione complex compound obtained by converting the conventional pyrithione metal salt to a complex compound with an oxide or hydroxide of metal such as zinc, copper or aluminum.Type: GrantFiled: October 22, 2004Date of Patent: February 9, 2010Assignee: YHS Ltd.Inventor: Yasuhiro Hidaka
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Publication number: 20090312465Abstract: Systems and compositions have a three component antioxidant blend for extending color and clarity of a thermoplastic polymer. The antioxidant blend includes a zinc dithiocarbamate, a phenolic and a thioether with a weight ratio range of about 1-2:1-2:1-2. A loading level of the antioxidant blend is from about 0.01 wt. % to about 1 wt. % of the systems and compositions.Type: ApplicationFiled: January 16, 2009Publication date: December 17, 2009Applicant: R.T. VANDERBILT COMPANY, INC.Inventor: JOHN M. DeMASSA
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Patent number: 7497901Abstract: Complexes of copper and/or zinc with molybdate and/or tungstate were solubilized in ammonia or ammoniacal solution providing preservative solutions that fully penetrate wood. With loss of the ammonia from the wood, the complexes were stably retained in the wood providing a long lasting preservative.Type: GrantFiled: December 21, 2006Date of Patent: March 3, 2009Assignee: E. I. dupont de Nemours and CompanyInventors: Albert Gordon Anderson, John Feaster, Damini Patel, Mark Scialdone
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Patent number: 7488433Abstract: Synergistic stabilizer compositions are employed to stabilize halogen-containing vinyl polymers from, for example, degradation and discoloration. The stabilizer compositions comprise a zinc compound, a dihydropyridine or polydihydropyridine, a beta-diketone and a latent mercaptan.Type: GrantFiled: June 29, 2005Date of Patent: February 10, 2009Assignee: Rohm and Haas CompanyInventor: Lionel R. Price
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Patent number: 7462227Abstract: Complexes of ibuprofen and copper and/or zinc were solubilized in ammoniacal solution providing preservative solutions that fully penetrate wood. With loss of the ammonia from the wood, the complexes were stably retained in the wood providing a long lasting preservative.Type: GrantFiled: December 21, 2006Date of Patent: December 9, 2008Assignee: E.I. du Pont de Nemours and CompanyInventors: Albert Gordon Anderson, John Feaster, Damini Patel, Mark Scialdone
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Patent number: 7112622Abstract: The present invention encompasses a novel organic based composition which includes at least one organic based heat stabilizer component, and at least one stabilizer modifying component selected from the group of liquid calcium soap and 1,3,5-tris (2-hydroxyethyl) cyanuric acid. The invention also encompasses heat stabilized polymer compositions made with the novel organic based composition disclosed herein.Type: GrantFiled: March 3, 2003Date of Patent: September 26, 2006Assignee: Rohm and Haas CompanyInventors: Paul Brian Adams, Tod Charles Duvall, Gene Kelly Norris
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Patent number: 7078459Abstract: Liquid overbased calcium/barium/zinc ternary systems are provided for stabilizing halogen-containing polymers. These overbased ternary stabilizer systems are shelf stable liquids and provide polyvinyl chloride compositions with improvements in thermal stability, early color, clarity and plate-out resistance.Type: GrantFiled: May 20, 2004Date of Patent: July 18, 2006Assignee: Hammond Group, Inc.Inventors: James E. Reddy, Jeremy A. Hackett
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Patent number: 7077981Abstract: The invention relates to stabilizer systems, containing at least: a) a perchlorate salt; b) at least one or more compounds from the group consisting of carbamides, indole derivatives and enamines of formula (I), wherein n=1 or 2 and X=O or NR1; n=3–6 and X=O; R1=H, C1–C4-alkyl, C2–C6-alkenyl, C6–C10-aryl, C7–C18-alkaryl or C7–C18-aralkyl; R2 (if n=1)=C1–C22-alkyl, C2–C22-alkenyl or aryl, preferably phenyl, optionally substituted with up to 3 hydroxy, C1–C4-alkoxy or C1–C9-alkyl; or R2 (if n=2–6)=linear or branched C1-22-alkylene, optionally interrupted by one or more O or S atoms, wherein R2 (if n=3) can also be a C2–C3-alkyl trisubstituted isocyanurate; if X=NH R2 can also be H. Said stabilizer systems are suitable for stabilizing halogen-containing polymers, more particularly PVC.Type: GrantFiled: December 12, 2001Date of Patent: July 18, 2006Assignee: Crompton Vinyl Additives GmbHInventors: Wolfgang Wehner, Hans-Helmut Friedrich
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Patent number: 7041236Abstract: An aerosol archival product that includes an aerosol archival composition and may be disposed in a pressurized container. The aerosol archival composition includes one or more chlorinated fluorinated hydrocarbons, an amino-containing compound and a basic metal compound. The aerosol archival composition may also contain an adhesion promoter.Type: GrantFiled: February 28, 2005Date of Patent: May 9, 2006Assignee: The Sherwin-Williams CompanyInventors: Barbara J. Farkas, James J. Johnson
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Patent number: 6984416Abstract: A method of preserving cellulosic material that includes the application of an archival composition on the substrate. The aerosol archival product includes an aerosol archival composition and may be disposed in a pressurized container. The aerosol archival composition includes one or more chlorinated fluorinated hydrocarbons, an amino-containing compound and a basic metal compound. The aerosol archival composition may also contain an adhesion promoter.Type: GrantFiled: February 28, 2005Date of Patent: January 10, 2006Assignee: The Sherwin-Williams CompanyInventors: Barbara J. Farkas, James J. Johnson
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Patent number: 6974632Abstract: A substrate that is treated with an archival composition. An aerosol archival product includes the aerosol archival composition and may be disposed in a pressurized container. The aerosol archival composition includes one or more chlorinated fluorinated hydrocarbons, an amino-containing compound and a basic metal compound. The aerosol archival composition may also contain an adhesion promoter.Type: GrantFiled: February 28, 2005Date of Patent: December 13, 2005Assignee: The Sherwin-Williams CompanyInventors: Barbara J. Farkas, James J. Johnson
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Patent number: 6897254Abstract: Halogen-containing polymer compositions containing a heat stabilizer comprising a latent mercaptan, a zinc salt, and a free mercaptan as a separate entity are protected during processing by the degradation products of the latent (i.e., blocked) mercaptan. A free mercaptan is among those products. The separate free mercaptan (i.e., an alien free mercaptan) enhances the activity of the latent mercaptan in a synergistic manner.Type: GrantFiled: December 2, 2002Date of Patent: May 24, 2005Assignee: Rohm and Haas CompanyInventors: Paul Brian Adams, Gene Kelly Norris
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Patent number: 6890455Abstract: An aerosol archival product that includes an aerosol archival composition disposed in a pressurized container. The aerosol archival composition includes one or more chlorinated fluorinated hydrocarbons, an amino-containing compound and a basic metal compound. The aerosol archival composition may also contain an adhesion promoter.Type: GrantFiled: January 23, 2004Date of Patent: May 10, 2005Assignee: The Sherwin-Williams CompanyInventors: Barbara J. Farkas, James J. Johnson
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Overbased metal carbonate/carboxylate microemulsions and halogen-containing polymers containing same
Patent number: 6835328Abstract: A metal carbonate/carboxylate microemulsion imparting static and dynamic thermal stability to a halogen-containing polymer is provided which comprises (a) a metal carbonate/carboxylate obtained from the reaction of an oxide and/or hydroxide of a metal selected from the group consisting of sodium, potassium, calcium, magnesium, zinc and mixtures thereof and an aliphatic acid in which the aliphatic moiety contains up to about 30 carbon atoms and carbon dioxide in an oil; b) one or more non-phenolic compounds having about two or about three hydroxyl groups; and, c) one or more polyols, alcohol ethoxylates and/or alcohol propoxylates having from about 6 to about 24 carbon atoms in the alcohol and/or 0 to 3 ethylene oxide units and/or 0 to 3 propylene oxide units.Type: GrantFiled: September 24, 2003Date of Patent: December 28, 2004Assignee: Crompton CorporationInventors: Julius Fakinlede, Michael H. Fisch, Ulrich Stewen, Radu Bacaloglu, Shah Mukund, Ilze Bacaloglu, Wahib I. Farahat -
Publication number: 20040204522Abstract: Synergistic stabilizer compositions are employed to stabilize halogen-containing vinyl polymers from, for example, degradation and discoloration.Type: ApplicationFiled: March 15, 2004Publication date: October 14, 2004Inventors: Steven Christopher Austen, Paul Brian Adams, Gary Martin Conroy, Gene Kelly Norris
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Patent number: 6773631Abstract: Liquid overbased calcium/barium/zinc ternary systems are provided for stabilizing halogen-containing polymers. These overbased ternary stabilizer systems are shelf stable liquids and provide polyvinyl chloride compositions with improvements in thermal stability, early color, clarity and plate-out resistance.Type: GrantFiled: March 15, 2002Date of Patent: August 10, 2004Assignee: Hammond Group, Inc.Inventors: James E. Reddy, Jeremy A. Hackett
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Patent number: 6746625Abstract: The present invention relates to a new class of blowing inhibitors and a method for discovering such inhibitors with determinable inhibition activities. The new class of blowing inhibitors are organo-silanes that may be directly adsorbed onto active catalytic sites of blowing catalysts and that can inhibit the thermo-catalytic efficiency of such catalysts.Type: GrantFiled: May 20, 2002Date of Patent: June 8, 2004Assignee: Congoleum CorporationInventors: Anthony A. Parker, Thomas E. Janini, Peter Rohrbacher
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Publication number: 20040079925Abstract: A fuel additive is directed to preventing slagging, a phenomenon caused by the ash in a fuel particularly during the combustion of a fuel having such a large ash content as is typically found in coal or oil coke, for example. It is formed of a composition having one or more compounds selected from among aluminum compounds, silica compounds, titanium compounds and zirconium compounds invariably of the form of ultrafine particles having a particle diameter in the range of 3 to 200 nm and no less than 2 wt. % of an alkali metal (R═Na or K) compound as reduced to the R2O concentration dispersed in a stable state in water and/or oil. When a liquid fuel oil and/or a solid fuel is made to incorporate the fuel additive therein and then subjected to combustion, the deposited ash can be easily peeled and shed from the surface of the furnace wall or the water pipes.Type: ApplicationFiled: September 23, 2003Publication date: April 29, 2004Inventors: Masaki Shouji, Teruo Onozawa, Shigeru Nakai
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Publication number: 20030227006Abstract: The present invention encompasses a novel organic based composition which includes at least one organic based heat stabilizer component, and at least one stabilizer modifying component selected from the group of liquid calcium soap and 1,3,5-tris (2-hydroxyethyl) cyanuric acid. The invention also encompasses heat stabilized polymer compositions made with the novel organic based composition disclosed herein.Type: ApplicationFiled: March 3, 2003Publication date: December 11, 2003Inventors: Paul Brian Adams, Tod Charles Duvall, Gene Kelly Norris
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Patent number: 6620340Abstract: The invention is directed to a method for providing a corrosion inhibiting aqueous solution which includes zinc orthophosphate where the zinc orthophosphate is solubilized. The invention is directed to a method of making a substantially contaminant-free, concentrated aqueous solution of zinc orthophosphate from zinc metal or zinc oxide and aqueous phosphoric acid.Type: GrantFiled: April 18, 2002Date of Patent: September 16, 2003Assignee: Carus CorporationInventors: Richard E. Deblois, Kenneth S. Pisarczyk
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Patent number: 6420461Abstract: The present invention relates to novel compounds of the formula (III) in which the substituents are as defined in the description, to a process for their preparation and to mixtures with other compounds. The compounds of the formula (III) are suitable for stabilizing organic material against the effect of light and heat.Type: GrantFiled: November 12, 1999Date of Patent: July 16, 2002Assignee: Clariant GmbHInventors: Thomas Stährfeldt, Mathias Mehrer, Matthias Zäh, Gerhard Pfahler
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Patent number: 6391384Abstract: The invention is directed to a method for providing a corrosion inhibiting aqueous solution which includes zinc orthophosphate where the zinc orthophosphate is solubilized. The invention is directed to a method of making a substantially contaminant-free, concentrated aqueous solution of zinc orthophosphate from zinc metal or zinc oxide and aqueous phosphoric acid.Type: GrantFiled: July 10, 2000Date of Patent: May 21, 2002Assignee: Carus CorporationInventors: Richard E. Deblois, Kenneth S. Pisarczyk
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Patent number: 6361833Abstract: A composition and process for treating metal surfaces that contain at a weight ratio from 1:5,000 to 5,000:1 of at least one metal acetylacetonate selected from the group consisting of Al(C5H7O2)3, V(C5H7O2)3, VO(C5H7O2)2, Zn(C5H7O2)2, and Zr(C5H7O2)4, and at least one compound selected from water-soluble inorganic titanium compounds and water-soluble inorganic zirconium compounds, provides a non-chromate-type composition for imparting an excellent corrosion resistance and paint adherence to the surface of metals, particularly aluminum and its alloys, magnesium and its alloys and zinc and its alloys.Type: GrantFiled: April 30, 2001Date of Patent: March 26, 2002Assignee: Henkel CorporationInventors: Kazuya Nakada, Motoki Kawaguchi
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Patent number: 6348164Abstract: Shelf stable liquid overbased calcium carboxylates are prepared by reacting a calcium base with a monocarboxylic acid, and carbonating in the presence of a promoter mixture with a phenol and an alcohol under controlled temperature conditions, to produce shelf stable liquids. Mixed metal stabilizer compositions are prepared by blending the stable liquid calcium carboxylate with a metal carboxylate of zinc, cadmium or tin. The mixed metal carboxylates are also shelf stable and are used for stabilizing halogen-containing polymers to provide heat stability, clarity and improved plate out properties.Type: GrantFiled: May 11, 1999Date of Patent: February 19, 2002Assignee: OMG Americas, Inc.Inventors: Rajesh Khattar, Benjamin Paul Labovitz, Paulette Baker
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Patent number: 6248258Abstract: An oxygen absorbent comprising an aliphatic hydrocarbon(s) with an unsaturated group(s) and/or an unsaturated fatty acid compound(s) and a catalyst containing both a transition metal salt(s) and a non-transition metal salt(s) is provided, whereby an oxygen absorbing velocity is remarkedly promoted.Type: GrantFiled: June 14, 1999Date of Patent: June 19, 2001Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Kazuyuki Tomita, Tatsuo Iwai, Tomoharu Himeshima, Takayuki Watanabe, Junko Baba