With Free Metal Patents (Class 252/503)
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Publication number: 20120301782Abstract: Powder milling techniques, tin-based alloys formed thereby, and the use of such alloys as electrode compositions for lithium ion batteries are provided. The alloys include tin and at least one transition metal but contain no silicon. The powder milling is done using low energy roller milling (pebble milling).Type: ApplicationFiled: July 27, 2012Publication date: November 29, 2012Inventors: Jeffrey R. Dahn, Pierre P. Ferguson, Mark N. Obrovac, Dinh B. Le, James R. Landucci
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Patent number: 8318049Abstract: An electron emission source includes nano-sized acicular materials and a cracked portion formed in at least one portion of the electron emission source. The acicular materials are exposed between inner walls of the cracked portion. A method for preparing the electron emission source, a field emission device including the electron emission source, and a composition for forming the electron emission source are also provided in the present invention.Type: GrantFiled: June 30, 2009Date of Patent: November 27, 2012Assignee: Samsung Electronics Co., Ltd.Inventors: Yong-chul Kim, In-taek Han, Ho-suk Kang
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Patent number: 8308990Abstract: The invention relates to a carbon nanofiber containing at least iron (Fe) and vanadium (V), wherein the iron (Fe) is present in an amount of 6 mass % or less and the vanadium (V) is present in an amount of 3 mass % or less as a metal element other than carbon, wherein a graphite plane is inclined to the fiber axis.Type: GrantFiled: December 20, 2010Date of Patent: November 13, 2012Assignee: Showa Denko K.K.Inventors: Gaku Oriji, Eiji Kambara
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Patent number: 8303692Abstract: A polymer membrane, based on a facilitated transport mechanism, for separating olefins from paraffins, and a method for fabricating is provided. In the polymer membrane for facilitated transport, silver nanoparticles are partially cationized and play a role as a carrier for transporting olefins across the membrane, with p-benzoquinone serving as an electron acceptor.Type: GrantFiled: December 13, 2006Date of Patent: November 6, 2012Assignee: Industry-University Cooperation Foundation Hanyang UniversityInventors: Yong-Soo Kang, Kook-Heon Char, Sang-Wook Kang
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Publication number: 20120276451Abstract: A method for preparing an electrode composition, including a step of forming a suspension, in an unbuffered aqueous acid medium having a pH of 1 or in a buffered acid medium having a pH less than or equal to 4, containing an electrode active material in the form of particles of an element M selected from Si, Sn, and Ge, a polymer binder having reactive groups capable of reacting with hydroxyl groups in an acid medium, and an agent generating electronic conductivity. The invention also relates to the electrode obtained according to the method, as well as to a battery including such an electrode.Type: ApplicationFiled: January 28, 2010Publication date: November 1, 2012Inventors: Bernard Lestriez, Dominique Guyomard, Driss Mazouzi, Lionel Roue
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Publication number: 20120270108Abstract: In one aspect, an anode active material is provided. The anode active material may include a crystalline carbon-based material that includes a core having a lattice spacing d002 of about 0.35 nm or more, and titanium-based oxide particles.Type: ApplicationFiled: March 8, 2012Publication date: October 25, 2012Applicant: Samsung SDI Co., Ltd.Inventors: Chang-Su Shin, Jae-Myung Kim, So-Ra Lee, Ui-Song Do, Beom-Kwon Kim
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Publication number: 20120256138Abstract: Disclosed is an electrochemical device, using, as an electrode material, a poly(ionic liquid)-modified graphene manufactured by binding an ionic liquid polymer to the surface of graphene.Type: ApplicationFiled: December 22, 2010Publication date: October 11, 2012Inventors: Kwang Suck Suh, Jong Eun Kim, Tae Young Kim
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Patent number: 8278658Abstract: An device according to the present invention comprises: graphene; and a metal electrode, the metal electrode and the graphene being electrically connected, the following relationship of Eq. (1) being satisfied: coth ? ( r GP r C ? S ) < 1.3 , Eq . ? ( 1 ) where rGP (in units of ?/?m2) denotes the electrical resistance of a graphene layer per unit area, rC (in units of ??m2) denotes the contact resistance per unit area between the graphene layer and a metal electrode, and S denotes the contact area (in units of ?m2) between the graphene layer and the metal electrode.Type: GrantFiled: April 26, 2010Date of Patent: October 2, 2012Assignee: Hitachi, Ltd.Inventors: Makoto Okai, Motoyuki Hirooka
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Publication number: 20120237831Abstract: A method of preparing tin (Sn) nanoparticles based on a bottom-up approach is provided. The method includes combining a first solution comprising Sn ions with a second solution comprising a reducing agent. After the combination, the Sn ions and the reducing agent undergo a reaction in which at least some of the Sn ions are reduced to Sn nanoparticles. The first solution comprises a tin salt dissolved in a solvent; the second solution comprises an alkali metal and naphthalene dissolved in a solvent; and the combined solution further comprises a capping agent that moderates a growth of aggregates of the Sn nanoparticles.Type: ApplicationFiled: May 8, 2012Publication date: September 20, 2012Applicant: LOCKHEED MARTIN CORPORATIONInventors: Justin S. GOLIGHTLY, Alfred A. Zinn
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Publication number: 20120228555Abstract: Particular embodiments of the current method disclose a method for making graphene, comprising providing a starting material and heating the starting material for a time and to a temperature effective to produce graphene. Certain embodiments utilize starting materials comprising carbonaceous materials used in conjunction with, or comprising, sulfur, and essentially free of a transition metal. The graphene produced by the current method can be used to coat graphene-coatable materials.Type: ApplicationFiled: February 3, 2012Publication date: September 13, 2012Inventors: I. Francis Cheng, David N. McIlroy, Jeremy Foutch, Peter R. Griffiths
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Publication number: 20120228157Abstract: Nanostructures comprising carbon and metal catalyst that are formed on a substrate, such as a silicon substrate, are contacted with a composition that, among other useful modifications, protects the nano structures and renders them stable in the presence of oxidizing agents in an aqueous environment. The protected nano structures are rendered stable over an extended period of time and thereby remain useful during such period as components of an electrode, for example, for detecting electrochemical species such as free chlorine, total chlorine, or both in water.Type: ApplicationFiled: November 11, 2010Publication date: September 13, 2012Applicant: NanoSelect, Inc.Inventors: Chunhong Li, Piu Francis Man, David J. Ruggieri
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Patent number: 8263843Abstract: A metal matrix composite is disclosed that includes graphene nanoplatelets dispersed in a metal matrix. The composite provides for improved thermal conductivity. The composite may be formed into heat spreaders or other thermal management devices to provide improved cooling to electronic and electrical equipment and semiconductor devices.Type: GrantFiled: November 6, 2009Date of Patent: September 11, 2012Assignee: The Boeing CompanyInventors: Namsoo Paul Kim, James Ping Huang
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Publication number: 20120212249Abstract: The present invention relates to a hard and wear-resisting probe and manufacturing method thereof, and particularly relates to a hard and wear-resisting probe comprising tungsten steel (WC) and manufacturing method thereof. This hard and wear-resisting probe is substantially made of a tungsten steel with high hardness and wear resistance so that the probe is difficult to be worn and the lifetime of the probe is longer. Furthermore, the frequencies for changing the probe and the cost of testing are reduced, and the testing efficiency can be improved.Type: ApplicationFiled: August 10, 2011Publication date: August 23, 2012Applicant: KING YUAN ELECTRONICS CO., LTDInventors: FONG JAY CHEN, CHIU-FANG CHANG
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Patent number: 8246860Abstract: A carbon nanotube composite includes a free-standing carbon nanotube structure and an amount of reinforcements. The free-standing carbon nanotube structure includes an amount of carbon nanotubes. The reinforcements are located on the carbon nanotubes and combining the carbon nanotubes together.Type: GrantFiled: June 24, 2010Date of Patent: August 21, 2012Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.Inventors: Kai Liu, Rui-Feng Zhou, Ying-Hui Sun, Kai-Li Jiang, Shou-Shan Fan
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Patent number: 8247760Abstract: Ultra-cold (nano-Kelvin) neutral atoms can be trapped, manipulated, and measured, using integrated current carrying micro-structures on a nearby surface (Atom Chips). This can be utilized for the realization of ultra-sensitive sensors and quantum computation devices based on the quantum mechanical properties of the trapped atoms. However, harmful processes arise from the interactions between the atoms and the nearby surface. According to the present invention these harmful processes can be highly suppressed by using electrically anisotropic materials. It is shown that time-independent trapping potential corrugation leading to fragmentation of the trapped atom cloud can be suppressed, and that time dependent noise processes arising from the coupling of atoms to the nearby surface, and leading to loss of atoms from the trap, heating and loss of coherence can be significantly reduced.Type: GrantFiled: August 11, 2008Date of Patent: August 21, 2012Assignee: Ben-Gurion University of the NegevInventors: Tal David, Yonathan Japha, Valery Dikovsky, Ron Folman
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Patent number: 8246861Abstract: A method for making a carbon nanotube composite includes providing a free-standing carbon nanotube structure and a reacting liquid with a metal compound dissolved therein, treating the carbon nanotube structure by applying the reacting liquid on the carbon nanotube structure, and heating the treated carbon nanotube structure in an oxide-free environment to decompose the metal compound.Type: GrantFiled: June 30, 2010Date of Patent: August 21, 2012Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.Inventors: Rui-Feng Zhou, Chui-Zhou Meng, Kai Liu, Kai-Li Jiang, Chang-Hong Liu, Shou-Shan Fan
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Patent number: 8226856Abstract: Embodiments of the invention relate to a silicon semiconductor device, and a conductive silver paste for use in the front side of a solar cell device.Type: GrantFiled: October 20, 2008Date of Patent: July 24, 2012Assignee: E I Du Pont de Nemours and CompanyInventors: Alan Frederick Carroll, Kenneth Warren Hang
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Patent number: 8227685Abstract: A graphene sheet including an intercalation compound and 2 to about 300 unit graphene layers, wherein each of the unit graphene layers includes a polycyclic aromatic molecule in which a plurality of carbon atoms in the polycyclic aromatic molecule are covalently bonded to each other; and wherein the intercalation compound is interposed between the unit graphene layers.Type: GrantFiled: February 17, 2010Date of Patent: July 24, 2012Assignee: Samsung Electronics Co., Ltd.Inventor: Jae-young Choi
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Publication number: 20120181486Abstract: A single step process for degrading plastic waste by converting the plastic waste into carbonaceous products via thermal decomposition of the plastic waste by placing the plastic waste into a reactor, heating the plastic waste under an inert or air atmosphere until the temperature of about 700° C. is achieved, allowing the reactor to cool down, and recovering the resulting decomposition products therefrom. The decomposition products that this process yields are carbonaceous materials, and more specifically carbon nanotubes having a partially filled core (encapsulated) adjacent to one end of the nanotube. Additionally, in the presence of a transition metal compound, this thermal decomposition process produces multi-walled carbon nanotubes.Type: ApplicationFiled: March 16, 2012Publication date: July 19, 2012Applicant: UCHICAGO ARGONNE, LLCInventors: Vilas G. Pol, Pappannan Thiyagarajan
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Publication number: 20120177930Abstract: The present invention relates to adhesives that are suitable for use as electrically conductive materials in the fabrication of electronic devices, integrated circuits, semiconductor devices, solar cells and/or solar modules. The adhesives comprise at least one resin component, at least one nitrogen-containing curative, at least one low melting point metal filler, and optionally at least one electrically conductive filler, which is different from the metal filler.Type: ApplicationFiled: January 6, 2012Publication date: July 12, 2012Inventor: Anja Henckens
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Publication number: 20120164777Abstract: The invention relates to a composition for printing conductor tracks onto a substrate, especially for solar cells, using a laser printing process, which composition comprises 30 to 90% by weight of electrically conductive particles, 0 to 7% by weight of glass frit, 0 to 8% by weight of at least one matrix material, 0 to 8% by weight of at least one organometallic compound, 0 to 5% by weight of at least one additive and 3 to 69% by weight of solvent. The composition further comprises 0.5 to 15% by weight of nanoparticles as absorbents for laser radiation, which nanoparticles are particles of silver, gold, platinum, palladium, tungsten, nickel, tin, iron, indium tin oxide, titanium carbide or titanium nitride. The composition comprises not more than 1% by weight of elemental carbon.Type: ApplicationFiled: August 25, 2010Publication date: June 28, 2012Applicant: BASF SEInventors: Frank Kleine Jaeger, Stephan Hermes
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Publication number: 20120164531Abstract: An energy storage composite particle is provided, which includes a carbon film, a conductive carbon component, an energy storage grain, and a conductive carbon fiber. The carbon film surrounds a space. The conductive carbon component and the energy storage grain are disposed in the space. The conductive carbon fiber is electrically connected to the conductive carbon component, the energy storage grain, and the carbon film, and the conductive carbon fiber extends from the inside of the space to the outside of the space. The energy storage composite particle has a high gravimetric capacity, a high coulomb efficiency, and a long cycle life. Furthermore, a battery negative electrode material and a battery using the energy storage composite particle are also provided.Type: ApplicationFiled: September 9, 2011Publication date: June 28, 2012Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventors: Jin-Ming Chen, Yen-Po Chang, Shih-Chieh Liao, Chi-Ju Cheng
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Publication number: 20120138347Abstract: Printable compositions comprising: (a) 5 to 40 parts by weight of silver nanoparticles having a maximum effective diameter of 150 nm, as determined by laser correlation spectroscopy; (b) 50 to 99.5 parts by weight of water; (c) 0.01 to 15 parts by weight of a dispersing agent; (d) 0.5 to 5 parts by weight of a film former; and (g) 30 to 70 parts by weight of metal particles having a maximum effective diameter of 10 ?m, as determined by laser correlation spectroscopy; wherein the printable composition has a viscosity of at least 1 Pa·s; processes for producing electrically conductive coatings using such compositions and electrically conductive coatings prepared thereby.Type: ApplicationFiled: January 13, 2012Publication date: June 7, 2012Applicant: Bayer MaterialScience AGInventors: Stefan BAHNMÜLLER, Stefanie EIDEN, Stephan Michael MEIER, Dirk STORCH, Bernard DUNKEL
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Publication number: 20120132859Abstract: “A composite electrode includes a mixture of active matter (AM) particles and EC material particles generating an electronic conductivity, the mixture being supported by an electrical lead forming a DC current collector. The electrode can be manufactured by a method which consists of modifying the AM particles and the EC particles so as to react with each other and with the material of the collector in order to form covalent and electrostatic bonds between said particles, as well as between the particles and the current collector, and then placing the different constituents in contact.Type: ApplicationFiled: April 6, 2010Publication date: May 31, 2012Inventors: Bernard Lestriez, Dominique Guyomard, Joël Gaubicher
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Publication number: 20120132358Abstract: A method for removing a carbonization catalyst from a graphene sheet, the method includes contacting the carbonization catalyst with a salt solution, which is capable of oxidizing the carbonization catalyst.Type: ApplicationFiled: February 2, 2012Publication date: May 31, 2012Applicant: SAMSUNG ELECTRONICS CO., LTD.Inventors: Jaeyoung CHOI, Keun Soo KIM, Byung Hee HONG
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Publication number: 20120126181Abstract: Preparation methods, compositions, and articles useful for electronic and optical applications. Methods for reducing metal ions to metals in the presence of IUPAC Group 14 elements in their +2 oxidation state, the metal products, and articles comprising the metal products. Compositions comprising metal nanowires and ions of IUPAC Group 14 elements, the metal nanowires, and articles comprising the metal nanowires.Type: ApplicationFiled: May 19, 2011Publication date: May 24, 2012Inventors: David R. Whitcomb, William D. Ramsden, Doreen C. Lynch
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Publication number: 20120128996Abstract: The present invention relates to a metal nanobelt and a method of manufacturing the same, and a conductive ink composition and a conductive film including the same. The metal nanobelt can be easily manufactured at a normal temperature and pressure without requiring the application of high temperature and pressure, and also can be used to form a conductive film or conductive pattern that exhibits excellent conductivity if the conductive ink composition including the same is printed onto a substrate before a heat treatment or a drying process is carried out at low temperature. Therefore, the metal nanobelt and the conductive ink composition may be applied very appropriately for the formation of conductive patterns or conductive films for semiconductor devices, displays, solar cells in environments requiring low temperature heating. The metal nanobelt has a length of 500 nm or more, a length/width ratio of 10 or more, and a width/thickness ratio of 3 or more.Type: ApplicationFiled: September 10, 2009Publication date: May 24, 2012Applicant: LG Chem LtdInventors: Won-Jong Kwon, Jae-Hong Kim, Sun-Mi Jin, Sang-Uck Lee, Young-Soo Lim
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Publication number: 20120118480Abstract: The present invention is to provide an anisotropic conductive adhesive (ACA) for ultrasonic wave adhesion, which electrically connects a first electrode, which is an electrode of a connection portion of a first electronic component, with a second electrode, which is an electrode of a connection portion of a second electronic component. The anisotropic conductive adhesive includes an insulating polymer resin, conductive adhesive particles which are melted by heat generated from the ultrasonic waves applied to the anisotropic conductive adhesive, and spacer particles, which have a melting point higher than that of the adhesive particles, and wherein the adhesive particles are melted and made to come in surface contact with at least one electrode selected from the first electrode and the second electrode, and the first electrode and the second electrode are electrically connected with a constant gap maintained between the first electrode and the second electrode by the spacer particles.Type: ApplicationFiled: January 13, 2012Publication date: May 17, 2012Inventors: Kyung-Wook PAIK, Kiwon Lee, Seung Ho Kim
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Publication number: 20120119159Abstract: A bondable conductive ink comprising carbon nanotubes, larger diameter conductive particles having at least one dimension of at least 100 nanometers which are not carbon nanotubes, a polymer, and a solvent, and a method of producing this bondable conductive ink. The ink is highly suitable for producing circuit assemblies having non-conductive substrates upon which printed conductors, formed from the bondable conductive ink, may be easily and selectively interconnected to another circuit assembly device, and/or apparatus.Type: ApplicationFiled: January 24, 2012Publication date: May 17, 2012Inventor: Joel S. Douglas
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Publication number: 20120111599Abstract: Systems and methods for forming conductive materials. The conductive materials can be applied using a printer in single or multiple passes onto a substrate. The conductive materials are composed of electrical conductors such as carbon nanotubes (including functionalized carbon nanotubes and metal-coated carbon nanotubes), grapheme, a polycyclic aromatic hydrocarbon (e.g. pentacene and bisperipentacene), metal nanoparticles, an inherently conductive polymer (ICP), and combinations thereof. Once the conductive materials are applied, the materials are dried and sintered to form adherent conductive materials on the substrate. The adherent conductive materials can be used in applications such as damage detection, particle removal, and smart coating systems.Type: ApplicationFiled: October 21, 2011Publication date: May 10, 2012Applicant: United States Of America as Represented by the Administrator of the National Aeronautics and SpacInventors: Luke B. Roberson, Martha K. Williams, Tracy L. Gibson, LaNetra C. Tate, Sarah J. Snyder, Craig R. Fortier
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Publication number: 20120115033Abstract: A negative active material for a rechargeable lithium battery includes a core including crystalline carbon, a metal nano particle and a MOx nano particle (where x is from 0.5 to 1.5, and M is Si, Sn, In, Al, or a combination thereof) disposed on the core surface, and a coating layer including an amorphous carbon surrounding the core surface, the metal nano particle and the MOx nano particle.Type: ApplicationFiled: March 21, 2011Publication date: May 10, 2012Inventors: Bong-Chull Kim, Cheol-Hee Hwang, Dong-Yung Kim, Se-Ho Park, Hyun-Jun Choi, In-Ho Jung, Su-Ho Song
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Publication number: 20120107538Abstract: A conductive thermoset material is provided that provides shielding against electromagnetic radiation. The conductive thermoset material includes an intermixed conductive material dispersed essentially throughout. An antisettling additive is present in the conductive thermoset material to support dispersion, optionally, homogenous dispersion of the conductive material in the resin. The conductive thermoset material is formable into one or more articles. The articles may be transportable and resistant to significant conductivity changes by contact with other surfaces.Type: ApplicationFiled: October 31, 2011Publication date: May 3, 2012Inventors: Brian A. Beach, Thomas Atkins
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Publication number: 20120107597Abstract: According to some embodiments, the present invention provides a system and method for supporting a carbon nanotube array that involve an entangled carbon nanotube mat integral with the array, where the mat is embedded in an embedding material. The embedding material may be depositable on a carbon nanotube. A depositable material may be metallic or nonmetallic. The embedding material may be an adhesive material. The adhesive material may optionally be mixed with a metal powder. The embedding material may be supported by a substrate or self-supportive. The embedding material may be conductive or nonconductive. The system and method provide superior mechanical and, when applicable, electrical, contact between the carbon nanotubes in the array and the embedding material. The optional use of a conductive material for the embedding material provides a mechanism useful for integration of carbon nanotube arrays into electronic devices.Type: ApplicationFiled: April 23, 2007Publication date: May 3, 2012Applicant: WILLIAM MARSH RICE UNIVERSITYInventors: Myung Jong Kim, Nolan Walker Nicholas, W. Carter Kittrell, Howard K. Schmidt
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Publication number: 20120103670Abstract: Articles comprising a composition comprising a polymeric binder and at least one carbonaceous filler, wherein the article has a compositional gradient such that the concentration of the filler is increased or decreased in at least one direction in the article. Methods for their preparation and structures comprising the articles are also described.Type: ApplicationFiled: June 30, 2009Publication date: May 3, 2012Applicant: VORBECK MATERIALS CORP.Inventor: John S. Lettow
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Publication number: 20120107683Abstract: A composite of electrode active material including aggregates formed by self-assembly of electrode active material nanoparticles and carbon nanotubes, and a fabrication method thereof are disclosed. This composite is in the form of a network in which at least some of the carbon nanotubes connect two or more aggregates that are not directly contacting each other, creating an entangled structure in which a plurality of aggregates and a plurality of carbon nanotube strands are intertwined. Due to the highly conductive properties of the carbon nanotubes in this composite, charge carriers can be rapidly transferred between the self-assembled aggregates. This composite may be prepared by preparing a dispersion in which the nanoparticles and/or carbon nanotubes are dispersed without any organic binders, simultaneously spraying the nanoparticles and the carbon nanotubes on a current collector through electrospray, and then subjecting the composite material formed on the current collector to a heat treatment.Type: ApplicationFiled: October 20, 2011Publication date: May 3, 2012Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGYInventors: Il Doo KIM, Jin Hoon CHOI
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Publication number: 20120099231Abstract: A discharge gap filling composition which includes metal powders (A) and a binder component (B), wherein surfaces of primary particles of the metal powders (A) are coated with a film composed of a metal oxide, and the primary particles of the metal powders (A) have a flake form. An electrostatic discharge protector is obtained using the composition.Type: ApplicationFiled: June 15, 2010Publication date: April 26, 2012Applicant: SHOWA DENKO K.K.Inventors: Yoshimitsu Ishihara, Mina Onishi, Yukihiko Azuma, Fumiaki Naka
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Publication number: 20120100303Abstract: Disclosed are amorphous carbon nanofibers including copper nanoparticles or copper alloy nanoparticles, copper composite nanoparticles prepared by grinding the amorphous carbon nanofibers and implemented as surfaces of Cu-included particles are partially or wholly coated with amorphous carbons, a dispersed solution including the copper composite nanoparticles, and preparation methods thereof and the amorphous carbon nanofibers include nanoparticles including copper, copper nanoparticles or copper alloy nanoparticles, and, the copper composite nanoparticles are implemented as surfaces of Cu-included particles are partially or wholly coated with amorphous carbons.Type: ApplicationFiled: October 24, 2011Publication date: April 26, 2012Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGYInventors: Il Doo KIM, Yong-Won SONG, Jae-Min HONG
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Publication number: 20120097237Abstract: The present invention relates to a paste and a solar cell using the paste. The paste according to an embodiment of the present invention comprises three and more than aluminum powders having different shape, size, and type, a glass frit, and an organic vehicle, wherein the aluminum powers includes a first powder of 40 to 50 wt %, a second powder of 20 to 30 wt %, and a third powder of 0.1 to 2 wt %, and the first to third powders have one or more than different shapes of a globular shape, a flat shape, a nano shape, and combinations thereof.Type: ApplicationFiled: April 7, 2010Publication date: April 26, 2012Applicant: LG Innotek Co., Ltd.Inventors: In Jae Lee, Jin Gyeong Park, Jun Phil Eom, Soon Gil Kim
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Publication number: 20120094178Abstract: Composite electrode material for a rechargeable battery cell includes an electroactive material; and a polymeric binder including pendant carboxyl groups, characterised in that (i) the electroactive material includes one or more components selected from the group including an electroactive metal, an electroactive semi-metal, an electroactive ceramic material, an electroactive metalloid, an electroactive semi-conductor, an electroactive alloy of a metal, an electroactive alloy of a semi metal and an electroactive compound of a metal or a semi-metal, (ii) the polymeric binder has a molecular weight in the range 300,000 to 3,000,000 and (iii) 50 to 90% of the carboxyl groups of the polymeric binder are in the form of a metal ion carboxylate salt. A method of making a composite electrode material, an electrode, cells including electrodes and devices using such cells are also disclosed.Type: ApplicationFiled: November 1, 2011Publication date: April 19, 2012Inventors: Melanie J. Loveridge, Michael Jonathan Lain, Fazlil Coowar, Mamdouh Elsayed Abdelsalam
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Publication number: 20120080648Abstract: A composite material has general Formula (1-x)J-(x)Q wherein: J is a metal carbon alloy of formula SnzSiz?MetwMet?w?Ct; Q is a metal oxide of formula A?M?M???O?; A is Li, Na, or K; M, M?, Met, and Met? are individually Ge, Mo, Al, Ga, As, Sb, Te, Ti, Ta, Zr, Ca, Mg, Sr, Ba, Li, Na, K, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Nb, Rt, Ru or Cd; 0<x<1; ? is 0, 1, or 2; 0<??1; 0????1; ? is 0.5, 1, 2, or 3; 0<t?5; and the sum of z, z?, w, and w? is greater than 0.Type: ApplicationFiled: September 16, 2011Publication date: April 5, 2012Inventors: Ali Abouimrane, Khalil Amine
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Publication number: 20120077017Abstract: The invention proposes a process for producing a metal matrix composite material composed of a metal matrix having at least one metal component and at least one reinforcing component arranged in the metal matrix, in which at least one of the components is sprayed onto a substrate by means of a thermal spraying process, use being made of at least one reinforcing component comprising carbon in the form of nano tubes, nano fibers, graphenes, fullerenes, flakes or diamond. Also proposed is a corresponding material, in particular in the form of a coating, and the use of such a material.Type: ApplicationFiled: May 27, 2010Publication date: March 29, 2012Inventors: Isabell Buresch, Werner Kroemmer
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Publication number: 20120068122Abstract: In one embodiment, a method for producing a graphene-containing composition is provided, the method comprising: (i) mixing a graphene oxide with a medium to form a mixture; and (ii) heating the mixture to a temperature above about 40° C., whereby a graphene-containing composition is formed from the mixture. Composites of polymers with disperse functionalized graphene sheets and the applications thereof are also described.Type: ApplicationFiled: May 28, 2010Publication date: March 22, 2012Inventors: David Kranbuehl, Sarah Cotts, Hannes C. Schniepp, Minzhin Cai, Arthur Jaeton Glover
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Patent number: 8137516Abstract: The hydrogen-oxygen generating electrode plate using a carbon nano tube includes a carbon nano tube (CNT); a carbon (C); NiO; NaTaO3; and a catalyst. The method for manufacturing a hydrogen and oxygen generating electrode plate using a carbon nano tube, includes a step S1 for grinding into high-density powders; a step S2 for uniformly mixing carbon nano tube powder, carbon powder, NiO powder, NaTaO3 powder and catalyst and forming a mixture having a high distribution degree; a step S3 for inputting the mixture into a mold and pressing the same and forming a pressing forming object; and a step S4 for plasticity-forming the pressing forming object in a vacuum plasticity furnace.Type: GrantFiled: August 4, 2009Date of Patent: March 20, 2012Inventor: Boo-Sung Hwang
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Publication number: 20120064409Abstract: A nano graphene-enhanced particulate for use as a lithium-ion battery anode active material, wherein the particulate is formed of a single sheet of graphene or a plurality of graphene sheets and a plurality of fine anode active material particles with a size smaller than 10 ?m. The graphene sheets and the particles are mutually bonded or agglomerated into the particulate with at least a graphene sheet embracing the anode active material particles. The amount of graphene is at least 0.01% by weight and the amount of the anode active material is at least 0.1% by weight, all based on the total weight of the particulate. A lithium-ion battery having an anode containing these graphene-enhanced particulates exhibits a stable charge and discharge cycling response, a high specific capacity per unit mass, a high first-cycle efficiency, a high capacity per electrode volume, and a long cycle life.Type: ApplicationFiled: September 10, 2010Publication date: March 15, 2012Inventors: Aruna Zhamu, Jinjun Shi, Guorong Chen, Qing Fang, Bor Z. Jang
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Publication number: 20120045687Abstract: Methods of preparing negative active materials and negative active materials are provided herein. The preparation methods include: A) mixing a carbon material, an organic polymer, a Sn-containing compound—optionally with water—to obtain a mixed solution system; B) adding a complexing agent into the mixed solution system obtained in step A optionally while stirring to form an intermediate solution; C) adding a reducing agent into the intermediate solution obtained in step B to a reaction product; D) optionally filtering, washing and then drying the reaction product to obtain the negative active material.Type: ApplicationFiled: August 18, 2011Publication date: February 23, 2012Inventors: Qiang Wang, Lu Zhang, Li Ma, Yan Zhu, Zhenyue Wu
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Publication number: 20120040249Abstract: A negative active material for a rechargeable lithium battery, a method of preparing the same, and a rechargeable lithium battery including the same, the negative active material including carbon core particles; a metallic material on the carbon core particles; and a carbon thin film covering the carbon core particles and the metallic material, wherein the carbon core particles have an interplanar spacing (d002) of about 0.34 nm to about 0.40 nm at a (002) plane measured by X-ray diffraction (XRD) using a CuK? ray, and the carbon thin film has a thickness of about 1 nm to about 500 nm.Type: ApplicationFiled: February 1, 2011Publication date: February 16, 2012Inventors: Kyeu-Yoon Sheem, Bok-Hyun Ka, Eui-Hwan Song
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Publication number: 20120040245Abstract: Provided is an electrode composition comprising an active material that includes cobalt, tin, and carbon along with methods of making and using the same. Also provided are electrodes that include the provided electrode compositions, electrochemical cells that include the provided electrodes, and battery packs that include at least one of the provided electrochemical cells. In some embodiments, the composition also includes iron.Type: ApplicationFiled: October 27, 2011Publication date: February 16, 2012Inventors: Jeffrey R. DAHN, Dinh Ba Le, Pierre P. Ferguson, Mark N. Obrovac
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Publication number: 20120032118Abstract: A cathode material for fluoride-based conversion electrodes includes a matrix of graphite nanocarbon containing a dispersion of alkali metal ions, fluoride ions and metal nanoparticles with maximum particle sizes of 20 nm. Further there is provides a method for such cathode material that includes heating a metal and an organic compound during a single thermal treatment step until the organic compound is decomposed; and adding an alkali metal fluoride either before or after the thermal treatment step to the organic compound. Finally, there is provided a method of making an alkali metal ion battery, that includes utilizing the aforesaid cathode material for a fluoride-based conversion electrode in the battery.Type: ApplicationFiled: April 3, 2010Publication date: February 9, 2012Inventors: Maximilian Fichtner, Horst Hahn, Raju Prakash
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Publication number: 20120025147Abstract: A novel method for preparing unique composition high-performance anode materials with high energy density, high power density, high stability, and excellent cyclability for electrochemical energy storage devices, in particular for lithium ion batteries, wherein this method and material circumvent and surpass the limitations of those methods and materials currently available.Type: ApplicationFiled: March 2, 2010Publication date: February 2, 2012Applicant: THE REGENTS OF THE UNIVERSITY OF CALIFORNIAInventors: Hong-Li Zhang, Daniel E. Morse
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Publication number: 20120007028Abstract: The present invention relates to polymer-silicon composite particles using silicon having high energy density, a method of making the same, an anode and a lithium secondary battery including the same. The silicon having high energy density is used as an anode active material to provide a lithium secondary battery having large capacity. Silicon-polymer composite particles having a metal plated on the surface thereof are provided to solve the problem that silicon has low electrical conductivity and a method of preparing the same is provided to produce an electrode having improved electrical conductivity. Furthermore, silicon-polymer composite particles having a metal coated on the surface thereof through electroless plating are prepared and an electrode is formed using the silicon-polymer composite particles.Type: ApplicationFiled: July 11, 2011Publication date: January 12, 2012Applicant: LG CHEM, LTD.Inventors: Sun Jung Hwang, Dong Seok Shin, Yoon Kyung Kwon, Geun Chang Chung, Jung Seok Choi