Iron, Cobalt, Or Nickel Compound Patents (Class 252/521.2)
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Patent number: 12074330Abstract: A conductive array, a composite membrane including the conductive array, a lithium battery, and a method of manufacturing the conductive array. The conductive array includes a plurality of ion conductive inorganic particles spaced apart from each other, wherein the circumferences (x) and the width (y) of a top surface of an ion conductive inorganic particle of the plurality of ion conductive inorganic particles in plan view satisfy Inequality (1), x?3.2y, and??Inequality (1) a distance between a first ion conductive inorganic particle of the plurality of ion conductive inorganic particles and an adjacent second ion conductive inorganic particle in a plan view is 0% to about 20% of the width of the surface of the ion conductive inorganic particle.Type: GrantFiled: December 30, 2019Date of Patent: August 27, 2024Assignee: SAMSUNG ELECTRONICS CO., LTD.Inventors: Wonsung Choi, Kyounghwan Choi, Youngeal Kim, Hyunjin Kim, Huisu Jeong
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Patent number: 12030787Abstract: The present invention generally relates to a process for synthesizing rare earth-doped cobalt-chromite (CoCr2-xRxO4) pigments for capacitive and resistive humidity sensor applications, the process includes of crushing individually metal nitrates and rare earth material (R) using a hydraulic press to form a powder of metal nitrates and rare earth nitrates; dissolving the powder of metal nitrates and rare earth material (R) with fuels in 30 milliliters of distilled water with constant stirring using a magnetic stirrer to form a green color solution; heating the green color solution at 425 degrees Celsius for half an hour to obtain a green powder; extracting and grinding the green powder in an agate mortar for 1 hour to form a fine green pigment; and annealing the fine green pigment in a muffle furnace for two hours at a temperature of 500-600 degrees to remove organic residue and obtain rare earth-doped cobalt-chromite (CoCr2-xRxO4) pigments.Type: GrantFiled: April 28, 2023Date of Patent: July 9, 2024Assignees: Princess Nourah bint Abdurahman UniversityInventors: Mohd. Shkir, Thamraa Alshahrani, Anuj Kumar, S. AlFaify, Mohd Ubaidullah, N. Senthilkumar, Jagadeesha Angadi. V
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Patent number: 11973221Abstract: It is related to a positive active material for lithium secondary battery, a manufacturing method thereof, and a lithium secondary battery containing the same, provides that a positive active material for lithium secondary battery, wherein, it is a layered lithium metal compound comprises nickel, cobalt, and manganese, and aluminum, zirconium, and boron are doped.Type: GrantFiled: December 12, 2018Date of Patent: April 30, 2024Assignees: POSCO HOLDINGS INC., RESEARCH INSTITUTE OF INDUSTRIAL SCIENCE & TECHNOLOGY, POSCO FUTURE M CO., LTD.Inventors: Sang Cheol Nam, Sang Hyuk Lee, Junghoon Kim
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Patent number: 11309543Abstract: The present invention provides an electrode active composition represented by formula (I). Li1+xMnaNibO2+x.LiyCoyO2y.D*C (I), wherein x>0, 0<y<0.1, a+b=1, 1.2?a/b?3.0; and D and C are optional dopants and coating agents that contain no cobalt element. The active compositions of Formula (I) exhibit electrochemical properties comparable to those with a higher cobalt amount, such as NCM523 electrode material (LiNi0.5Co0.2Mn0.3O2).Type: GrantFiled: July 18, 2019Date of Patent: April 19, 2022Assignees: Guangxi Nowphene Energy Storage Technologies Co., Ltd, Boston Global Technologies, LLCInventors: Guiqing Huang, Boshan Mo, Youde Mo
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Patent number: 11024847Abstract: A positive electrode active material for a lithium secondary battery, including secondary particles formed by aggregation of primary particles capable of being doped and undoped with lithium ions, said positive electrode active material having: an ?-NaFeO2 type crystal structure represented by formula: Li[Lix(NiaCobMncMd)1-x]O2 (I), wherein 0?x?0.1, 0.7<a<1, 0<b<0.2, 0?c<0.2, 0<d<0.1, a+b+c+d=1, and M is at least one metal element selected from the group consisting of Fe, Cr, Ti, Mg, Al, Zr, Ca, Sc, V, Cr, Cu, Zn, Ga, Ge, Sr, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, In and Sn; and a crystallite size ?/crystallite size ? ratio (?/?) of 1.60 to 2.40, wherein the crystallite size ? is within a peak region of 2?=18.7±1° and the crystallite size ? is within a peak region of 2?=44.4±1°, each determined by a powder X-ray diffraction measurement using Cu-K? radiation.Type: GrantFiled: December 22, 2015Date of Patent: June 1, 2021Assignees: SUMITOMO CHEMICAL COMPANY, LIMITED, TANAKA CHEMICAL CORPORATIONInventors: Jun-ichi Kageura, Hiroyuki Kurita, Yuichiro Imanari
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Patent number: 10847787Abstract: A positive active material, a positive electrode and a lithium battery including the same, and a method of preparing the positive active material, the positive active material including a core, the core including a compound capable of reversibly intercalating and deintercalating lithium; and a lithium ion conductive ceramic compound on a surface of the core, the ceramic compound being doped with fluorine (F), sulfur (S), or a combination thereof.Type: GrantFiled: June 1, 2016Date of Patent: November 24, 2020Assignee: SAMSUNG SDI CO., LTD.Inventors: Jungmin Han, Jaehong Lim, Yongchan You
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Patent number: 10782638Abstract: A heater of an embodiment includes a substrate, a resistance heating element, and a thermistor. The substrate includes a first surface and a second surface located on the side opposite to the first surface. The resistance heating element is disposed on the first surface. The thermistor is disposed on the second surface and does not contain lead.Type: GrantFiled: August 19, 2019Date of Patent: September 22, 2020Assignee: Toshiba Lighting & Technology CorporationInventors: Satoko Kato, Kentaro Kimura
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Patent number: 10490807Abstract: A lithium metal oxide powder for use as a cathode material in a rechargeable battery, consisting of Li metal oxide core particles having a general formula Li1+d(NixMnyCozZrkM?m)i?dO2±eAr; wherein Al2O3 is attached to the surface of the core particles; wherein 0?d?0.08, 0.2?x?0.9, 0<y?0.7, 0<z?0.4, 0?m?0.02, 0<k?0.05, e<0.02, 0?f?0.02 and x+y+z+k+m=1; M? consisting of either one or more elements from the group Al, Mg, Ti, Cr, V, Fe and Ga; A consisting of either one or more elements from the group F, P, C, CI, S, Si, Ba, Y, Ca, B, Sn, Sb, Na and Zn; and wherein the Al2O3 content in the powder is between 0.05 and 1 wt %.Type: GrantFiled: March 3, 2015Date of Patent: November 26, 2019Assignees: Umicore, Umicore Korea Ltd.Inventors: Liang Zhu, Jens Paulsen, Hyo Sun Ahn, HeonPyo Hong
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Patent number: 10446355Abstract: A hybrid device, comprising: a first electrode, disposed on a first side of the hybrid device, a second electrode, disposed on a second side of the hybrid device, opposite the first side. The hybrid device may further include at least one layer, disposed between the first electrode and the second electrode, the at least one layer comprising a negative temperature coefficient material and a plurality of conductive particles, wherein the hybrid device exhibits a positive temperature coefficient characteristic and a negative temperature coefficient characteristic.Type: GrantFiled: April 27, 2017Date of Patent: October 15, 2019Assignee: LITTELFUSE, INC.Inventors: Chun-Kwan Tsang, Jianhua Chen
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Patent number: 10424792Abstract: A lithium ion battery includes an anode and a cathode. The cathode includes a lithium, manganese, nickel, and oxygen containing compound. An electrolyte is disposed between the anode and the cathode. A protective layer is deposited between the cathode and the electrolyte. The protective layer includes pure lithium phosphorus oxynitride and variations that include metal dopants such as Fe, Ti, Ni, V, Cr, Cu, and Co. A method for making a cathode and a method for operating a battery are also disclosed.Type: GrantFiled: January 26, 2017Date of Patent: September 24, 2019Assignee: UT-Battelle LLCInventors: Nancy J. Dudney, Chengdu Liang, Jagjit Nanda, Gabriel M. Veith, Yoongu Kim, Surendra Kumar Martha
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Patent number: 10256467Abstract: An object is to provide an electrode material with high electrical conductivity and a power storage device using the electrode material. An object is to provide an electrode material with high capacity and a power storage device using the electrode material. Provided is a particulate electrode material including a core containing a compound represented by a general formula Li2MSiO4 (in the formula, M represents at least one kind of an element selected from Fe, Co, Mn, and Ni) as a main component, and a covering layer containing a compound represented by a general formula LiMPO4 as a main component and covering the core. Further, a solid solution material is provided between the core and the covering layer. With such a structure, an electrode material with high electrical conductivity can be obtained. Further, with such an electrode material, a power storage device with high discharge capacity can be obtained.Type: GrantFiled: August 10, 2016Date of Patent: April 9, 2019Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventor: Masaki Yamakaji
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Patent number: 10109851Abstract: A composite cathode active material includes a material capable of intercalating or deintercalating lithium; and a solid ion conductor. A cathode and a lithium battery each include the composite cathode active material. A method of preparing a composite cathode active material includes: mixing a core including a cathode active material and a solid ion conductor; and forming a coating layer including the solid ion conductor on the core utilizing a dry method.Type: GrantFiled: December 11, 2014Date of Patent: October 23, 2018Assignee: Samsung SDI Co., Ltd.Inventors: Yu-Mi Song, Ming-Zi Hong, Do-Hyung Park, Seon-Young Kwon, Joong-Ho Moon, Ju-Hyeong Han, Han-Eol Park, Min-Han Kim, Kyoung-Hyun Kim, Ki-Hyun Kim, Sang-Hoon Kim
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Patent number: 10003072Abstract: A secondary battery having an improved life characteristics is provided by the use of a positive electrode active material for a secondary battery, comprising (a) a surface layer comprising a lithium metal composite oxide having a spinel crystal structure represented by space group Fd-3m, and (b) an internal portion comprising a lithium metal composite oxide having a spinel crystal structure represented by space group P4332.Type: GrantFiled: November 5, 2014Date of Patent: June 19, 2018Assignee: NEC CorporationInventors: Takehiro Noguchi, Makiko Takahashi, Shin Serizawa
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Patent number: 9867889Abstract: Methods are provided for the generation of nanostructures suitable for use in magnetic resonance imaging where the nanostructures have at least one dimension of about 2 nm or less. In particular, the methods comprise the selective use of incubation temperatures that result in the controlled removal of ligands from metallic cores to which they are attached, allowing the metallic cores or the precursor moieties to unite to form nanostructures of defined and predictable shapes, but having at least one dimension significantly less that at least one other dimension. Accordingly, the nanostructures of the disclosure may be ultrathin sheets, rods, whiskers and the like, or even structures that are thin and porous resembling rice grains. The temperatures useful in the methods of the disclosure are less than 300° C. and allow for progressive elevation of the incubation temperature.Type: GrantFiled: September 26, 2011Date of Patent: January 16, 2018Assignee: The Board of Trustees of the University of AlabamaInventor: Yuping Y. Bao
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Patent number: 9786911Abstract: Disclosed is a cathode active material for secondary batteries comprising at least one compound selected from the following formula 1: (1?s?t)[Li(LiaMn(1?a?x?y)NixCoy)O2]*s[Li2CO3]*t[LiOH]??(1) wherein 0<a<0.2, 0<x<0.9, 0<y<0.5, a+x+y<1, 0<s<0.03, and 0<t<0.03; and a, x and y represent a molar ratio, and a and t represent a weight ratio. The cathode active material has long lifespan at room temperature and high temperatures and provides superior stability, although charge and discharge are repeated at a high current.Type: GrantFiled: June 21, 2012Date of Patent: October 10, 2017Assignee: LG Chem, Ltd.Inventors: Sung-Kyun Chang, Hong Kyu Park, Sin Young Park, Jin-hyung Lim, DongHun Lee
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Patent number: 9716268Abstract: A positive electrode including a positive electrode mixture layer containing a positive electrode active material represented by Li1.08Ni0.43Co0.26Mn0.24O2 having a layered structure, a negative electrode containing a negative electrode active material, a separator provided between the positive electrode and the negative electrode, and a nonaqueous electrolyte are included, in which a film composed of carbon black permeable to lithium ions is formed on a surface of the positive electrode active material, and the film contains lithium fluoride particles serving as metal halide particles.Type: GrantFiled: February 28, 2013Date of Patent: July 25, 2017Assignee: SANYO Electric Co., Ltd.Inventors: Kazunari Okita, Tadayoshi Tanaka, Takatoshi Higuchi, Hiroyuki Fujimoto, Yoshinori Kida
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Patent number: 9543582Abstract: The present invention relates to a method for preparing a lithium iron phosphate nanopowder, including the steps of (a) preparing a mixture solution by adding a lithium precursor, an iron precursor and a phosphorus precursor in a triethanolamine solvent, and (b) putting the mixture solution into a reactor and heating to prepare the lithium iron phosphate nanopowder under pressure conditions of 1 bar to 10 bar, and a lithium iron phosphate nanopowder prepared by the method. When compared to a common hydrothermal synthesis method, a supercritical hydrothermal synthesis method and a glycothermal synthesis method, a reaction may be performed under a relatively lower pressure. Thus, a high temperature/high pressure reactor is not necessary and process safety and economic feasibility may be secured. In addition, a lithium iron phosphate nanopowder having uniform particle size and effectively controlled particle size distribution may be easily prepared.Type: GrantFiled: October 9, 2014Date of Patent: January 10, 2017Assignee: LG Chem, Ltd.Inventors: In Kook Jun, Seung Beom Cho, Myoung Hwan Oh
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Patent number: 9484717Abstract: The disclosure pertains to ignition systems and more particularly to spark igniters for burners and burner pilots. The spark igniter provided, is configured such that an electric field concentration between two electrodes increases while keeping output voltage unchanged.Type: GrantFiled: December 10, 2014Date of Patent: November 1, 2016Assignee: Chentronics, LLCInventors: Andrew H. Strong, Ewen M. Kelly
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Patent number: 9058913Abstract: The invention relates to a cobalt-free NTC ceramic having the composition Nia?Cub?Coc?MndO4 where 0.09<a?<0.6, 0.02<b?<0.65, 0.12<c?<0.58 and 1.6<d?<2.1. The invention further relates to a method for producing a cobalt-free NTC ceramic, the composition of which is derived from a cobalt-containing NTC ceramic of general formula NiaCubCocMndO4 where 0.09<a<0.6, 0.02<b<0.65, 0.12<c<0.58 and 1.6<d<2.1, wherein Co is replaced by Zn.Type: GrantFiled: May 19, 2011Date of Patent: June 16, 2015Assignee: EPCOS AGInventor: Adalbert Feltz
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Patent number: 9029018Abstract: A method for making a lithium battery cathode material is disclosed. A mixed solution including a solvent, an iron salt material, a vanadium source material and a phosphate material is provided. An alkaline solution is added in the mixed solution to make the mixed solution have a pH value ranging from about 1.5 to 5. The iron salt, the vanadium source material and the phosphate material react with each other to form a plurality particles of iron phosphate precursor doped with vanadium which are added in a mixture of a lithium source solution and a reducing agent to form a slurry of lithium iron phosphate precursor doped with vanadium. The slurry of lithium iron phosphate precursor doped with vanadium is heat-treated.Type: GrantFiled: December 27, 2010Date of Patent: May 12, 2015Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.Inventors: Gai Yang, Chang-Yin Jiang, Jian Gao, Jie-Rong Ying, Jian-Jun Li, Xiang-Ming He
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Patent number: 9028726Abstract: The present invention provides a sputtering target suitable for producing an amorphous transparent conductive film which can be formed without heating a substrate and without feeding water during the sputtering; which is easily crystallized by low-temperature annealing; and which has low resistivity after the crystallization. An oxide sintered compact containing an indium oxide as a main component, while containing tin as a first additive element, and one or more elements selected from germanium, nickel, manganese, and aluminum as a second additive element, with the content of tin which is the first additive element being 2-15 atom % relative to the total content of indium and tin, and the total content of the second additive element being 0.1-2 atom % relative to the total content of indium, tin and the second additive element.Type: GrantFiled: September 18, 2009Date of Patent: May 12, 2015Assignee: JX Nippon Mining & Metals CorporationInventors: Masakatsu Ikisawa, Masataka Yahagi
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Publication number: 20150123050Abstract: A positive-electrode active material with improved electrical conductivity, and a power storage device using the material are provided. A positive-electrode active material with large capacity, and a power storage device using the material are provided. A core including lithium metal oxide is used as a core of a main material of the positive-electrode active material, and one to ten pieces of graphene is used as a covering layer for the core. A hole is provided for graphene, whereby transmission of a lithium ion is facilitated, resulting in improvement of use efficiency of current.Type: ApplicationFiled: January 5, 2015Publication date: May 7, 2015Inventors: Shunpei Yamazaki, Tamae Moriwaka, Takuya Hirohashi, Kuniharu Nomoto, Takuya Miwa
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Publication number: 20150118563Abstract: The present invention discloses a lithium-rich positive electrode material, a lithium battery positive electrode, and a lithium battery. The lithium-rich positive electrode material has a coating structure, where a general structural formula of a core of the coating structure is as follows: z[xLi2MO3·(1?x)LiMeO2]·(1?z)Li1+dMy2?dO, where in the formula, 0<x<1, 0<z<1, and 0<d<?; M is at least one of Mn, Ti, Zr, and Cr, Me is at least one of Mn, Co, Ni, Ti, Cr, V, Fe, Al, Mg, and Zr, and My is at least one of Mn, Ni, and Co; and a coating layer of the coating structure is a compound whose general formula is MmMz, where in the formula, Mm is at least one of Zn, Ti, Zr, and Al, and Mz is O or F. The lithium battery positive electrode and the lithium battery both include the lithium-rich positive electrode material.Type: ApplicationFiled: December 31, 2014Publication date: April 30, 2015Inventor: Chaohui Chen
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Patent number: 9005481Abstract: The invention relates to a method for manufacturing a composite positive electrode active material being a composite of a positive electrode active material and carbon nanotubes. The manufacturing method includes preparing an aqueous solution of a starting material of a positive electrode active material containing a starting material of the positive electrode active material, and an aqueous solution of solubilized carbon nanotubes containing the carbon nanotubes and a solubilizing material that is composed of a water-soluble polymer whose solubilization retention rate of carbon nanotubes does not decrease with rising temperature; and synthesizing a positive electrode active material-carbon nanotube composite by mixing the aqueous solution of a starting material of a positive electrode active material and the aqueous solution of solubilized carbon nanotubes, and performing hydrothermal synthesis.Type: GrantFiled: January 14, 2011Date of Patent: April 14, 2015Assignee: Toyota Jidosha Kabushiki KaishaInventors: Satoshi Yoshida, Hiroki Kubo, Masahiro Iwasaki
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Patent number: 9005490Abstract: A solid state sintered material is described that includes a mixed oxide of lanthanum, strontium, cobalt, iron and oxygen, and CaCO3 inclusions. The solid state sintered material can also include calcium oxide, which can form from thermal composition of calcium carbonate. The solid state sintered material can also include a pore-forming particulate material such as carbon black and/or a doped ceramic metal oxide ionic conductor such as Sm-doped ceria uniformly dispersed in the solid state sintered material. The solid state sintered material can be formed from a two-step process in which a portion of the CaCO3 is mixed with the mixed oxide materials and heated to form porous agglomerates, and the remaining CaCO3 is added during the formation of a sintering paste. The solid state sintered material described herein can be used as a cathode material for solid oxide fuel cell.Type: GrantFiled: December 14, 2012Date of Patent: April 14, 2015Assignee: Delphi Technologies, Inc.Inventors: Kailash C. Jain, Rick D. Kerr, Joseph M Keller, Joseph V. Bonadies
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Patent number: 9005488Abstract: The invention aims at an aqueous ink for high-temperature electrochemical cell electrodes and/or electrolyte containing particles of at least one mineral filler, at least one binder, and at least one dispersant. It also concerns the electrode and the electrolyte using such an ink.Type: GrantFiled: March 8, 2013Date of Patent: April 14, 2015Assignee: Commissariat a l'Energie Atomique et aux Energies AlternativesInventor: Richard Laucournet
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Patent number: 8968594Abstract: A method is employed for producing a positive electrode active material for a lithium secondary battery that comprises mixing lithium phosphate having a particle diameter D90 of 100 ?m or less, an M element-containing compound having a particle diameter D90 of 100 ?m or less (where, M is one type or two or more types of elements selected from the group consisting of Mg, Ca, Fe, Mn, Ni, Co, Zn, Ge, Cu, Cr, Ti, Sr, Ba, Sc, Y, Al, Ga, In, Si, B and rare earth elements) and water, adjusting the concentration of the M element with respect to water to 4 moles/L or more to obtain a raw material, and producing olivine-type LiMPO4 by carrying out hydrothermal synthesis using the raw material.Type: GrantFiled: March 24, 2014Date of Patent: March 3, 2015Assignee: Showa Denko K.K.Inventors: Akihisa Tonegawa, Akihiko Shirakawa, Isao Kabe, Gaku Oriji
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Patent number: 8945498Abstract: To simply manufacture a lithium-containing oxide at lower manufacturing cost. A method for manufacturing a lithium-containing composite oxide expressed by a general formula LiMPO4 (M is one or more of Fe (II), Mn (II), Co (II), and Ni (II)). A solution containing Li and P is formed and then is dripped in a solution containing M (M is one or more of Fe (II), Mn (II), Co (II), and Ni (II)) to form a mixed solution. By a hydrothermal method using the mixed solution, a single crystal particle of a lithium-containing composite oxide expressed by the general formula LiMPO4 (M is one or more of Fe (II), Mn (II), Co (II), and Ni (II)) is manufactured.Type: GrantFiled: March 14, 2012Date of Patent: February 3, 2015Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventor: Tomoya Futamura
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Patent number: 8940656Abstract: Disclosed are a photocatalyst of CoP2 loaded red phosphorus, a preparation method thereof, and a method for photocatalytic hydrogen production from water under visible light irradiation over the photocatalyst of CoP2 loaded red phosphorus.Type: GrantFiled: September 11, 2013Date of Patent: January 27, 2015Assignee: The Chinese University of Hong KongInventors: Chai Mei Jimmy Yu, Feng Wang
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Patent number: 8936707Abstract: A sputtering target of nonmagnetic-particle-dispersed ferromagnetic material is provided having a phase (A) such that nonmagnetic particles are dispersed in a ferromagnetic material formed from a Co—Cr alloy containing 5 at % or more and 20 at % or less of Cr and Co as the remainder thereof, and schistose textures (B) with a short side of 30 to 100 ?m and a long side of 50 to 300 ?m formed from a Co—Cr alloy phase in the phase (A); wherein each of the foregoing nonmagnetic particles has such a shape and size that the particle is smaller than all hypothetical circles with a radius of 1 ?m around an arbitrary point within the nonmagnetic particle, or a shape and size with at least two contact points or intersection points between the respective hypothetical circles and the interface of the ferromagnetic material and the nonmagnetic material.Type: GrantFiled: September 13, 2012Date of Patent: January 20, 2015Assignee: JX Nippon Mining & Metals CorporationInventor: Atsushi Sato
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Publication number: 20150017544Abstract: This invention discloses an electrochemical device having a multilayer structure and methods for making such a device. Specifically, this invention discloses a multilayer electrochemical device having nano-sized cobalt oxyhydroxide conductive agents and/or active materials within the polymer layers.Type: ApplicationFiled: June 18, 2014Publication date: January 15, 2015Inventors: Binay Prasad, Levi T. Thompson, Paul G. Rasmussen
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Patent number: 8932444Abstract: A sputtering target of nonmagnetic-particle-dispersed ferromagnetic material is provided having a phase (A) such that nonmagnetic particles are dispersed in a ferromagnetic material formed from a Co—Cr alloy containing 5 at % or more and 20 at % or less of Cr and Co as the remainder thereof, and schistose textures (B) with a short side of 30 to 100 ?m and a long side of 50 to 300 ?m formed from a Co—Cr alloy phase in the phase (A); wherein each of the foregoing nonmagnetic particles has such a shape and size that the particle is smaller than all hypothetical circles with a radius of 1 ?m around an arbitrary point within the nonmagnetic particle, or a shape and size with at least two contact points or intersection points between the respective hypothetical circles and the interface of the ferromagnetic material and the nonmagnetic material.Type: GrantFiled: September 13, 2012Date of Patent: January 13, 2015Assignee: JX Nippon Mining & Metals CorporationInventor: Atsushi Sato
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Patent number: 8932480Abstract: The present invention provides a LiCoO2-containing powder comprising LiCoO2 having a stoichiometric composition via heat treatment of a lithium cobalt oxide and a lithium buffer material to make equilibrium of a lithium chemical potential there between; a lithium buffer material which acts as a Li acceptor or a Li donor to remove or supplement Li-excess or Li-deficiency, coexisting with a stoichiometric lithium metal oxide; and a method for preparing a LiCoO2-containing powder. Further, provided is an electrode comprising the above-mentioned LiCoO2-containing powder as an active material, and a rechargeable battery comprising the same electrode.Type: GrantFiled: December 15, 2010Date of Patent: January 13, 2015Assignee: LG Chem, Ltd.Inventors: Jens M. Paulsen, Sun Sik Shin, Hong-Kyu Park
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Patent number: 8920687Abstract: Provided is a cathode active material for nonaqueous electrolyte rechargeable batteries which allows production of batteries having improved load characteristics with stable quality, and also allows production of batteries having high capacity. Also provided are a cathode for nonaqueous electrolyte rechargeable batteries and a nonaqueous electrolyte rechargeable battery. The cathode active material includes secondary particles each composed of a plurality of primary particles, and/or single crystal grains, and has a specific surface area of not smaller than 20 m2/g and smaller than 0.50 m2/g, wherein average number A represented by formula (1) is not less than 1 and not more than 10: A=(m+p)/(m+s) (m: the number of single crystal grains; p: the number of primary particles composing the secondary particles; s: the number of secondary particles).Type: GrantFiled: December 26, 2007Date of Patent: December 30, 2014Assignee: Santoku CorporationInventors: Tetsu Fujiwara, Masayuki Moritaka, Akihito Kaneko
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Patent number: 8906553Abstract: A cathode electrode material for use in rechargeable Li-ion batteries, based on the integration of two Li-based materials of NASICON- and Spinel-type structures, is described in the present invention. The structure and composition of the cathode can be described by a core material and a surface coating surrounding the core material, wherein the core of the cathode particle is of the formula LiMn2-xNixO4?? (0.5?x?0 & 0???1) and having a spinel crystal structure, the surface coating is of the formula Li1+xMxTi2-x(PO4)3 (M: is a trivalent cation, 0.5?x?0) having a NASICON-type crystal structure.Type: GrantFiled: February 28, 2011Date of Patent: December 9, 2014Assignee: NEI CorporationInventors: Nader Marandian Hagh, Farid Badway, Ganesh Skandan
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Publication number: 20140346410Abstract: An anode composite material for lithium ion battery and a preparation method thereof. The composite material is a composite material formed by compounding at least one of SiCO, SiCNO, SiCN and SiBCN with LiaMbPO4, wherein 0.95?a?1.1, 0.95?b?1.1, and M is at least one of Fe, Co, Ni and Mn. The content of at least one of SiCO, SiCNO, SiCN and SiBCN in the anode composite material is in a range of 1-20 wt % of the total weight of the composite material. The composite material formed by compounding at least one of SiCO, SiCNO, SiCN and SiBCN with LiaMbPO4 is obtained by adding LiaMbPO4 into at least one organosilicon polymer of polysiloxane, polysilazane, and polyborosilazane, and then curing, crosslinking, and pyrolysing. Compared with LiaMbPO4, the composite material has a notable improvement in electrochemistry performance and tap density.Type: ApplicationFiled: December 20, 2011Publication date: November 27, 2014Applicant: GENERAL RESEARCH INSTITUTE FOR NONFERROUS METALSInventors: Shigang Lu, Surong Kan, Xiangjun Zhang, Weihua Jin
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Patent number: 8883047Abstract: Compositions related to skutterudite-based thermoelectric materials are disclosed. Such compositions can result in materials that have enhanced ZT values relative to one or more bulk materials from which the compositions are derived. Thermoelectric materials such as n-type and p-type skutterudites with high thermoelectric figures-of-merit can include materials with filler atoms and/or materials formed by compacting particles (e.g., nanoparticles) into a material with a plurality of grains each having a portion having a skutterudite-based structure. Methods of forming thermoelectric skutterudites, which can include the use of hot press processes to consolidate particles, are also disclosed. The particles to be consolidated can be derived from (e.g., grinded from), skutterudite-based bulk materials, elemental materials, other non-Skutterudite-based materials, or combinations of such materials.Type: GrantFiled: April 30, 2009Date of Patent: November 11, 2014Assignees: Massachusetts Institute of Technology, Trustees of Boston CollegeInventors: Zhifeng Ren, Jian Yang, Xiao Yan, Qinyu He, Gang Chen, Qing Hao
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Publication number: 20140284526Abstract: The present invention is directed to processing techniques and systems of metal fluoride based material, including but not limited to nickel difluoride, copper difluoride, manganese fluoride, chromium fluoride, bismuth fluoride, iron trifluoride, iron difluoride, iron oxyfluoride, metal doped iron fluorides, e.g., FexM1-xFy (M=metals, which can be Co, Ni, Cu, Cr, Mn, Bi and Ti) materials. An exemplary implementation involves mixing a first compound comprising a metal material, nitrogen, and oxygen to a second compound comprising hydrogen fluoride. The mixed compound is milled to form metal fluoride precursor and a certain byproduct. The byproduct is removed, and the metal fluoride precursor is treated to form iron trifluoride product. There are other embodiments as well.Type: ApplicationFiled: March 21, 2014Publication date: September 25, 2014Applicant: QuantumScape CorporationInventor: Jon Shan
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Publication number: 20140272579Abstract: A compound MjXp which is particularly suitable for use in a battery prepared by the complexometric precursor formulation methodology wherein: Mj is at least one positive ion selected from the group consisting of alkali metals, alkaline earth metals and transition metals and j is an integer representing the moles of said positive ion per moles of said MjXp; and Xp, a negative anion or polyanion from Groups IIIA, IV A, VA, VIA and VIIA and may be one or more anion or polyanion and p is an integer representing the moles of said negative ion per moles of said MjXp.Type: ApplicationFiled: March 15, 2013Publication date: September 18, 2014Applicant: PERFECT LITHIUM CORP.Inventor: Teresita Frianeza-Kullberg
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Publication number: 20140264190Abstract: A composition for forming an electrode. The composition includes a metal fluoride compound doped with a dopant. The addition of the dopant: (i) improves the bulk conductivity of the composition as compared to the undoped metal fluoride compound; (ii) changes the bandgap of the composition as compared to the undoped metal fluoride compound; or (iii) induces the formation of a conductive metallic network. A method of making the composition is included.Type: ApplicationFiled: March 19, 2014Publication date: September 18, 2014Applicant: Wildcat Discovery Technologies, Inc.Inventors: Wei Tong, Steven Kaye, David Keogh, Cory O'Neill
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Publication number: 20140264198Abstract: A composition for forming an electrode. The composition includes a metal fluoride, such as copper fluoride, and a matrix material. The matrix material adds capacity to the electrode. The copper fluoride compound is characterized by a first voltage range in which the copper fluoride compound is electrochemically active and the matrix material characterized by a second voltage range in which the matrix material is electrochemically active and substantially stable. A method for forming the composition is included.Type: ApplicationFiled: March 19, 2014Publication date: September 18, 2014Applicant: Wildcat Discovery Technologies, Inc.Inventors: Wei Tong, Steven Kaye, David Keogh, Cory O'Neill
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Publication number: 20140272581Abstract: A method of forming an electrode active material by reacting a metal fluoride and a reactant. The reactant can be a metal oxide, metal phosphate, metal fluoride, or a precursors expected to decompose to oxides. The method includes a milling step and an annealing step. The method can alternately include a solution coating step. Also included is the composition formed following the method.Type: ApplicationFiled: March 19, 2014Publication date: September 18, 2014Applicant: Wildcat Discovery Technologies, Inc.Inventors: Steven Kaye, David Keogh, Cory O'Neill
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Patent number: 8828605Abstract: In one embodiment, an active cathode material comprises a mixture that includes: at least one of a lithium cobaltate and a lithium nickelate; and at least one of a manganate spinel represented by an empirical formula of Li(1+x1)(Mn1?y1A?y1)2?x1Oz1 and an olivine compound represented by an empirical formula of Li(1?x2)A?x2MPO4. In another embodiment, an active cathode material comprises a mixture that includes: a lithium nickelate selected from the group consisting of LiCoO2-coated LiNi0.8Co0.15Al0.05O2, and Li(Ni1/3Co1/3Mn1/3)O2; and a manganate spinel represented by an empirical formula of Li(1+x7)Mn2?y7Oz7. A lithium-ion battery and a battery pack each independently employ a cathode that includes an active cathode material as described above.Type: GrantFiled: November 9, 2010Date of Patent: September 9, 2014Assignee: Boston-Power, Inc.Inventor: Christina M. Lampe-Onnerud
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Patent number: 8828277Abstract: A method of producing a nanocomposite thermoelectric conversion material includes preparing a solution that contains salts of a plurality of first elements constituting a thermoelectric conversion material, and a salt of a second element that has a redox potential lower than redox potentials of the first elements; precipitating the first elements, thereby producing a matrix-precursor that is a precursor of a matrix made of the thermoelectric conversion material, by adding a reducing agent to the solution; precipitating the second element in the matrix-precursor, thereby producing slurry containing the first elements and the second element, by further adding the reducing agent to the solution; and alloying the plurality of the first elements, thereby producing the matrix (70) made of the thermoelectric conversion material, and producing nano-sized phonon-scattering particles (80) including the second element, which are dispersed in the matrix (70), by filtering and washing the slurry, and then, heat-treating tType: GrantFiled: June 18, 2010Date of Patent: September 9, 2014Assignee: Toyota Jidosha Kabushiki KaishaInventors: Junya Murai, Takuji Kita
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Patent number: 8821765Abstract: The present invention provides a cathode active material for a lithium secondary battery containing therein an open pore having a protrusion which is formed so as to extend from the inner surface of the open pore toward the center of the open pore. Specifically, the protrusion is formed so as to extend toward the center of a virtual circle formed by approximating the shape of a cross section of the open pore to a circular shape. The protrusion is formed of the same material as the remaining portion of the cathode active material.Type: GrantFiled: August 4, 2011Date of Patent: September 2, 2014Assignee: NGK Insulators, Ltd.Inventors: Ryuta Sugiura, Akira Urakawa, Nobuyuki Kobayashi, Tsutomu Nanataki
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Patent number: 8821766Abstract: The present invention aims at providing lithium manganate having a high output and an excellent high-temperature stability. The above aim can be achieved by lithium manganate particles having a primary particle diameter of not less than 1 ?m and an average particle diameter (D50) of kinetic particles of not less than 1 ?m and not more than 10 ?m, which are substantially in the form of single crystal particles and have a composition represented by the following chemical formula: Li1+xMn2-x-yYyO4 in which Y is at least one element selected from the group consisting of Al, Mg and Co; x and y satisfy 0.03?x?0.15 and 0.05?y?0.20, respectively, wherein the Y element is uniformly dispersed within the respective particles, and an intensity ratio of I(400)/I(111) thereof is not less than 33% and an intensity ratio of I(440)/I(111) thereof is not less than 16%.Type: GrantFiled: March 7, 2013Date of Patent: September 2, 2014Assignee: Toda Kogyo CorporationInventors: Masayuki Uegami, Akihisa Kajiyama, Kazutoshi Ishizaki, Hideaki Sadamura
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Patent number: 8808584Abstract: It is an object of the present invention to provide an active material for a lithium secondary battery having high discharge capacity and excellent in high rate discharge characteristics and a lithium secondary battery using the same. The active material for a lithium secondary battery containing a solid solution of a lithium-transition metal composite oxide having an ?-NaFeO2 type crystal structure and the lithium secondary battery using the same have features that the composition ratios of the metal elements contained in the solid solution satisfy Li1+(x/3)Co1?x?y?zNiy/2Mgz/2Mn(2x/3)+(y/2)+(z/2) (x>0; y>0; z>0; x+y+z<1); the active material has an X-ray diffraction pattern capable of belonging to space group P3112; and the active material has discharge capacity exceeding 200 mAh/g.Type: GrantFiled: August 20, 2010Date of Patent: August 19, 2014Assignee: GS Yuasa International Ltd.Inventors: Daisuke Endo, Yoshihiro Katayama, Toshiyuki Nukuda
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Patent number: 8801974Abstract: A method for making a composite of cobalt oxide is disclosed. An aluminum nitrate solution is provided. Lithium cobalt oxide particles are introduced into the aluminum nitrate solution. The lithium cobalt oxide particles are mixed with the aluminum nitrate solution to form a mixture. A phosphate solution is added into the mixture to react with the aluminum nitrate solution and form an aluminum phosphate layer on surfaces of the lithium cobalt oxide particles. The lithium cobalt oxide particles with the aluminum phosphate layer formed on the surfaces thereof are heat treated to form a lithium cobalt oxide composite. The lithium cobalt oxide composite is electrochemical lithium-deintercalated at a voltage of Vx, wherein 4.5V<Vx?5V to form a cobalt oxide. The present disclosure also relates to a cobalt oxide and a composite of cobalt oxide.Type: GrantFiled: October 26, 2011Date of Patent: August 12, 2014Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.Inventors: Jian-Jun Li, Xiang-Ming He, Li Wang, Dan Wang, Xian-Kun Huang, Chang-Yin Jiang
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Patent number: 8801960Abstract: Because of the composition represented by General Formula: Li1+x+?Ni(1?x?y+?)/2Mn(1?x?y??)/2MyO2 (where 0?x?0.05, ?0.05?x+??0.05, 0?y?0.4; ?0.1???0.1 (when 0?y?0.2) or ?0.24???0.24 (when 0.2<y?0.4); and M is at least one element selected from the group consisting of Ti, Cr, Fe, Co, Cu, Zn, Al, Ge and Sn), a high-density lithium-containing complex oxide with high stability of a layered crystal structure and excellent reversibility of charging/discharging can be provided, and a high-capacity non-aqueous secondary battery excellent in durability is realized by using such an oxide for a positive electrode.Type: GrantFiled: January 31, 2008Date of Patent: August 12, 2014Assignee: Hitachi Maxell, Ltd.Inventors: Atsushi Ueda, Kazutaka Uchitomi, Shigeo Aoyama
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Publication number: 20140220362Abstract: The present invention provides an electrochromic nanocomposite film. In an exemplary embodiment, the electrochromic nanocomposite film, includes (1) a solid matrix of oxide based material and (2) transparent conducting oxide (TCO) nanostructures embedded in the matrix. In a further embodiment, the electrochromic nanocomposite film farther includes a substrate upon which the matrix is deposited. The present invention also provides a method of preparing an electrochromic nanocomposite film.Type: ApplicationFiled: July 24, 2012Publication date: August 7, 2014Applicant: THE REGENTS OF THE UNIVERSITY OF CALIFORNIAInventors: Delia Milliron, Anna Llordes, Raffaella Buonsanti, Guillermo Garcia