Luminescent Patents (Class 252/646)
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Patent number: 11312876Abstract: An ink composition is provided. The composition includes a binder material and at least one narrow band emission phosphor being uniformly dispersed throughout the composition, wherein the narrow band emission phosphor has a D50 particle size from about 0.1 ?m to about 15 ?m and is selected from the group consisting of a green-emitting U6+-containing phosphor, a green-emitting Mn2+-containing phosphor, a red-emitting phosphor based on complex fluoride materials activated by Mn4+, and a mixture thereof. A device is also provided.Type: GrantFiled: January 19, 2021Date of Patent: April 26, 2022Assignee: GENERAL ELECTRIC COMPANYInventors: Mark D. Doherty, Yangang Liang, Jie Jerry Liu, Samuel Joseph Camardello, James Edward Murphy
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Patent number: 9011735Abstract: Compositions comprising nanosized objects (i.e., nanoparticles) in which at least one observable marker, such as a radioisotope or fluorophore, is incorporated within the nanosized object. The nanosized objects include, for example, metal or semi-metal oxide (e.g., silica), quantum dot, noble metal, magnetic metal oxide, organic polymer, metal salt, and core-shell nanoparticles, wherein the label is incorporated within the nanoparticle or selectively in a metal oxide shell of a core-shell nanoparticle. Methods of preparing the volume-labeled nanoparticles are also described.Type: GrantFiled: December 30, 2010Date of Patent: April 21, 2015Assignee: UT-Battelle, LLCInventors: Wei Wang, Baohua Gu, Scott T. Retterer, Mitchel J. Doktycz
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Patent number: 8697982Abstract: A radiation-emitting polymer composition includes a polysiloxane polymer including tritium and a wavelength-shifter chemically bonded as a side chain to the polysiloxane polymer or chemically bonded as a side chain to a siloxane carrier dispersed within the polysiloxane polymer. The wavelength-shifter includes a plurality of cyclic chemical moieties and emits electromagnetic radiation in response to radiation emitted by the tritium.Type: GrantFiled: October 28, 2013Date of Patent: April 15, 2014Assignee: LEP America, IncorporatedInventors: James W. Smith, Bruce McKague
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Patent number: 8663820Abstract: The invention relates to a printed document of value having at least one authenticity feature in the form of a luminescent substance based on doped host lattices. The host lattice has a strong crystal field and is doped with at least one chromophore with the electron configuration (3d)2.Type: GrantFiled: March 5, 2002Date of Patent: March 4, 2014Assignee: Giesecke & Devrient GmbHInventors: Thomas Giering, Rainer Hoppe, Fritz Stahr
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Patent number: 8569610Abstract: A light-emitting polymer composition includes a polysiloxane polymer having tritium that emits radiation and a wavelength-shifter chemically bonded to the polysiloxane polymer or a siloxane carrier dispersed within the polysiloxane polymer. The wavelength-shifter emits light in response to the radiation.Type: GrantFiled: August 23, 2010Date of Patent: October 29, 2013Assignee: Power and Light Sources, IncorporatedInventors: James W. Smith, Bruce McKague
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Patent number: 8475681Abstract: Neutron scintillating materials are provided, including boron substitution scintillation materials, boron and Li substitution scintillation materials, and Gd-based substitution scintillation materials.Type: GrantFiled: July 11, 2011Date of Patent: July 2, 2013Assignee: University of South CarolinaInventor: Thomas Vogt
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Publication number: 20120168671Abstract: Compositions comprising nanosized objects (i.e., nanoparticles) in which at least one observable marker, such as a radioisotope or fluorophore, is incorporated within the nanosized object. The nanosized objects include, for example, metal or semi-metal oxide (e.g., silica), quantum dot, noble metal, magnetic metal oxide, organic polymer, metal salt, and core-shell nanoparticles, wherein the label is incorporated within the nanoparticle or selectively in a metal oxide shell of a core-shell nanoparticle. Methods of preparing the volume-labeled nanoparticles are also described.Type: ApplicationFiled: December 30, 2010Publication date: July 5, 2012Applicant: UT-BATTELLE, LLCInventors: Wei Wang, Baohua Gu, Scott T. Retterer, Mitchel J. Doktycz
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Publication number: 20120153243Abstract: Neutron scintillating materials are provided, including boron substitution scintillation materials, boron and Li substitution scintillation materials, and Gd-based substitution scintillation materials.Type: ApplicationFiled: July 11, 2011Publication date: June 21, 2012Applicant: UNIVERSITY OF SOUTH CAROLINAInventor: Thomas Vogt
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Publication number: 20120145217Abstract: A light-emitting polymer composition includes a polysiloxane polymer having tritium that emits radiation and a wavelength-shifter chemically bonded to the polysiloxane polymer or a siloxane carrier dispersed within the polysiloxane polymer. The wavelength-shifter emits light in response to the radiation.Type: ApplicationFiled: August 23, 2010Publication date: June 14, 2012Inventors: James W. Smith, Bruce McKague
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Patent number: 8177998Abstract: The invention is directed to a liquid scintillating composition containing (i) one or more non-polar organic solvents; (ii) (lithium-6)-containing nanoparticles having a size of up to 10 nm and surface-capped by hydrophobic molecules; and (iii) one or more fluorophores. The invention is also directed to a liquid scintillator containing the above composition.Type: GrantFiled: October 26, 2009Date of Patent: May 15, 2012Assignee: UT-Battelle, LLCInventors: Sheng Dai, Banu Kesanli, John S. Neal
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Publication number: 20110147574Abstract: Systems and methods for calibrating a nuclear medicine (NM) imaging system are provided that include an NM calibration source. The NM calibration source includes an isotope source having an energy spectrum with at least one energy peak and a fluorescence layer adjacent the isotope source creating at least one additional energy peak in the energy spectrum.Type: ApplicationFiled: December 23, 2009Publication date: June 23, 2011Inventors: Ira Blevis, Yaron Hefetz
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Patent number: 7622532Abstract: The present invention relates generally to synthesis of radioactive material, such as a tritiated polymer, and an apparatus for generating electrical current from the nuclear decay process of a radioactive material. In one embodiment, the invention relates to an energy cell (e.g., a battery) for generating electrical current derived from particle emissions occurring within a radioactive material such as a tritiated polymer) on pore walls of a porous semiconductor. The radioactive material may be introduced into the energy cell by a wetting process.Type: GrantFiled: February 16, 2007Date of Patent: November 24, 2009Assignees: William Marsh Rice University, BetaBatt, Inc.Inventors: Larry L. Gadeken, Paul S. Engel, Kenneth S. Laverdure
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Patent number: 7572392Abstract: Solid-state scintillating compositions for detecting neutrons comprise a Li4Zn(PO4)2 host lattice. Methods of making scintillating compositions comprise: dissolving a lithium-6 precursor and a zinc precursor in a solvent to form a solution; combining phosphoric acid with the solution; combining a base with the solution to form a precipitate; and heating the precipitate to form a Li4Zn(PO4)2 host lattice.Type: GrantFiled: January 10, 2007Date of Patent: August 11, 2009Assignee: General Electric CompanyInventors: Brent Allen Clothier, Sergio Paulo Martins Loureiro, Venkat Subramaniam Venkataramani, Alok Mani Srivastava
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Patent number: 7501077Abstract: Composite scintillator material consisting of a binderless sintered mixture of a Lithium (Li) compound containing 6Li as the neutron converter and Y2SiO5:Ce as the scintillation phosphor, and the use of this material as a method for neutron detection. Other embodiments of the invention include various other Li compounds.Type: GrantFiled: August 28, 2006Date of Patent: March 10, 2009Assignee: UT-Battelle, LLCInventors: Jason P. Hodges, M. Lowell Crow, Jr., Ronald G. Cooper
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Patent number: 6890457Abstract: An adhesive containing a far infrared radiation ceramic powder emitting far infrared rays and a radiation source ceramic powder emitting radiations and anions. The radiation source ceramic powder includes silicon dioxide, aluminum oxide, iron oxide, titanium oxide, calcium oxide, magnesium oxide, potassium oxide, sodium oxide and zirconium and/or radium. The adhesive according to the present invention relaxes human beings, helps spontaneous recovery from diseases and improves health by the synergistic effects of far infrared rays, anions and radiations.Type: GrantFiled: January 14, 2003Date of Patent: May 10, 2005Inventors: Katsuhiko Umehara, Toshiyuki Waragai
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Patent number: 6855270Abstract: The present invention relates to the use of nanoscintillation systems, or nanoparticles containing fluor molecules, that can be used to detect an electron-emitting or alpha-particle-emitting radioisotope in the absence of organic-solvents commonly used in organic-based liquid scintillation cocktails. The invention also relates to compositions and use of three oil-in-water microemulsion precursors that can be engineered rapidly, reproducibly, and cost-effectively to produce useful nanoparticles less than 100 nanometers.Type: GrantFiled: June 6, 2002Date of Patent: February 15, 2005Assignee: The University of Kentucky Research FoundationInventors: Russell J. Mumper, Michael Jay
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Publication number: 20040178388Abstract: The present invention relates to the use of nanoscintillation systems, or nanoparticles containing fluor molecules, that can be used to detect an electron-emitting or alpha-particle-emitting radioisotope in the absence of organic-solvents commonly used in organic-based liquid scintillation cocktails. The invention also relates to compositions and use of three oil-in-water microemulsion precursors that can be engineered rapidly, reproducibly, and cost-effectively to produce useful nanoparticles less than 100 nanometers.Type: ApplicationFiled: June 6, 2002Publication date: September 16, 2004Applicant: The University of Kentucky Research FoundationInventors: Russell J. Mumper, Michael Jay
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Patent number: 6544442Abstract: Disclosed is a composition of matter comprising a tributyl phosphate complex of a group 3, lanthanide, actinide, or group 13 salt in an organic carrier and a method of making the complex. These materials are suitable for use in solid or liquid organic scintillators, as in x-ray absorption standards, x-ray fluorescence standards, and neutron detector calibration standards.Type: GrantFiled: September 22, 1999Date of Patent: April 8, 2003Assignee: UT-Battelle, LLCInventors: Zane W. Bell, Chuen Huei-Ho, Gilbert M. Brown, Charles Hurlbut
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Publication number: 20010002246Abstract: The present invention relates to a compound based on an alkaline-earth metal, on sulphur and on aluminium, on gallium or indium, to its process of preparation and to its use as luminophore. The compound of the invention corresponds to the formula AB2S4, in which A represents an alkaline-earth metal and B aluminum, gallium, or indium and it is characterized in that it is provided in the form of a powder with a residual oxygen content of not more that 1.5% and composed of particles with a mean size of not more than 10 &mgr;m. This compound is obtained by a process which contains the following stages: a solution or a suspension comprising salts of the elements A and B is formed, the solution or the suspension is dried by atomization and the product obtained in the preceding stages is reacted with carbon disulphide or with a mixture of hydrogen sulphide and or carbon disulphide. The compound of the invention can be used as a luminophore, in particular in cathodoluminescence.Type: ApplicationFiled: December 15, 2000Publication date: May 31, 2001Inventors: Denis Huguenin, Pierre MacAudiere
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Patent number: 5744320Abstract: The present invention relates to single and dual-reporter luminescence assays utilizing general and specific reagents to quench enzyme-mediated reactions. In one embodiment of the invention, a reagent is added to the assay which non-specifically quenches enzyme-mediated luminescent reactions. In another embodiment of the invention, a reagent is added to the assay which simultaneously quenches one enzyme-mediated luminescent reaction while activating another distinct enzyme-mediated luminescent reaction. An assay kit containing specific quench reagents, and the reagents themselves are also disclosed.Type: GrantFiled: June 7, 1995Date of Patent: April 28, 1998Assignee: Promega CorporationInventors: Bruce A. Sherf, Keith V. Wood, Elaine T. Schenborn
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Patent number: 5714342Abstract: The present invention provides for novel reagents whose fluorescence increases in the presence of particular proteases. The reagents comprise a characteristically folded peptide backbone each end of which is conjugated to a fluorophore. When the folded peptide is cleaved, as by digestion with a protease, the fluorophores provide a high intensity fluorescent signal at a visible wavelength. Because of their high fluorescence signal in the visible wavelengths, these protease indicators are particularly well suited for detection of protease activity in biological samples, in particular in frozen tissue sections. Thus this invention also provides for methods of detecting protease activity in situ in frozen sections.Type: GrantFiled: October 27, 1995Date of Patent: February 3, 1998Assignee: OncoImmunin, Inc.Inventors: Akira Komoriya, Beverly S. Packard
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Patent number: 5658494Abstract: Novel compounds obtainable by reacting together an imido-reagent such as diphenylphosphonimido-triphenylphosphorane), or a phosphine oxide such as p-tolyldiphenylphosphine oxide, with a chelate of a transition or lanthanide or actinide metal, such as tris(dibenzoylmethide)europium III, have the property of fluorescing in UV radiation. The invention includes solid polymer bodies containing such compounds, or chelates of transition or lanthanide or actinide metals generally, the bodies having the property of emitting light or infra-red radiation when subjected to a flux of ultra-violet or ionising radiation by virtue of internally generated, e.g. by tritium ionising radiation. The body is preferably of polystyrene formed by polymerising the monomer in the presence of the compound or metal chelate.Type: GrantFiled: May 22, 1995Date of Patent: August 19, 1997Assignee: Amersham International plcInventors: Colin David Bell, John Hewer Coles Howse, Nigel Bosworth, David Martin James
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Patent number: 5494654Abstract: Additives are proposed for compositions comprising radiolabelled organic compounds e.g. 32P-labelled nucleotides. Stabilisers are selected from tryptophan, para-aminobenzoate, indoleacetate and the azole group. Dyes are selected from Sulphorhodamine B, Xylene Cyanol, Azocarmine B and New Coccine. Preferred compositions contain both stabiliser and dye.Type: GrantFiled: August 23, 1993Date of Patent: February 27, 1996Assignee: Amersham International plcInventors: Roger M. Price, Christopher C. May, Elizabeth M. Buckley, Timothy Stone
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Patent number: 5435937Abstract: Novel compounds obtainable by reacting together an imido-reagent such as diphenylphosphonimidotriphenylphosphorane) with a chelate of a transition or lanthanide or actinide metal, such as tris(dibenzoylmethide) europium III, has the property of fluorescing in UV radiation. The invention includes solid polymer bodies containing such compounds, or chelates of transition or lanthanide or actinide metals generally, the bodies having the property of emitting light by virtue of internally generated, e.g. by tritium ionising radiation. The body is preferably of polystyrene formed by polymerising the monomer in the presence of the compound or metal chelate.Type: GrantFiled: February 12, 1993Date of Patent: July 25, 1995Assignee: Amersham International plcInventors: Colin D. Bell, John H. C. Howse
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Patent number: 5306445Abstract: The invention relates to a composition for the volumetric generation of radiation. The composition comprises a porous substrate loaded with a component capable of emitting radiation upon interaction with an exciting radiation. Preferably, the composition is an aerogel substrate loaded with a component, e.g., a phosphor, capable of interacting with exciting radiation of a first energy, e.g., ultraviolet light, to produce radiation of a second energy, e.g., visible light.Type: GrantFiled: May 18, 1992Date of Patent: April 26, 1994Assignee: The United States of America as represented by the United States Department of EnergyInventors: Scott Reed, Robert J. Walko, Carol S. Ashley, C. Jeffrey Brinker
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Patent number: 5240647Abstract: The invention provides a process for loading an aerogel substrate with tritium and the resultant compositions. According to the process, an aerogel substrate is hydrolyzed so that surface OH groups are formed. The hydrolyzed aerogel is then subjected to tritium exchange employing, for example, a tritium-containing gas, whereby tritium atoms replace H atoms of surface OH groups. OH and/or CH groups of residual alcohol present in the aerogel may also undergo tritium exchange.Type: GrantFiled: September 3, 1991Date of Patent: August 31, 1993Inventors: Carol S. Ashley, C. Jeffrey Brinker, Scott Reed, Robert J. Walko
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Patent number: 5137659Abstract: The invention relates to a composition for the volumetric generation of radiation, wherein a first substance functions as a source of exciting radiation, and a second substance interacts with the exciting radiation to provide a second radiation. The compositions comprise a porous substrate which is loaded with: a source of exciting radiation, a component capable of emitting radiation upon interaction with the exciting radiation, or both. Preferably, the composition is an aerogel substrate loaded with both a source of exciting radiation, such as tritium, and a component capable of interacting with the exciting radiation, e.g., a phosphor, to produce radiation of a second energy.Type: GrantFiled: March 20, 1990Date of Patent: August 11, 1992Assignee: The United States of America as represented by the United States Department of EnergyInventors: Carol S. Ashley, C. Jeffrey Brinker, Scott Reed, Robert J. Walko
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Patent number: 5126442Abstract: New and useful chromophores have been isolated from the reaction mixture of proteins exposed to reducing sugars in the presence of sulfite over time. The chromophores are believed to be intermediates in nonenzymatic polypeptide glycosylation. The measurement of this chromophore makes possible both qualitative and quantitative assessment of the presence of nonenzymatic browning. Diagnostic and test kits are also disclosed.Type: GrantFiled: January 8, 1991Date of Patent: June 30, 1992Assignee: The Rockefeller UniversityInventors: James G. Farmar, Peter Ulrich, Anthony Cerami
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Patent number: 5122305Abstract: The invention relates to a composition for the volumetric generation of radiation, wherein a first substance functions as a source of exciting radiation, and a second substance interacts with the exciting radiation to provide a second radiation. The compositions comprise a porous substrate which is loaded with: a source of exciting radiation, a component capable of emitting radiation upon interaction with the exciting radiation, or both. In the composition, a composite is formed from a carrier material and at least one of the source of the exciting radiation or the component which is capable of interacting with the exciting radiation. The composite is then employed for loading a porous substrate, preferably an aerogel substrate.Type: GrantFiled: March 20, 1990Date of Patent: June 16, 1992Inventors: Carol S. Ashley, C. Jeffrey Brinker, Scott Reed, Timothy J. Shepodd, Leroy E. Leonard, Robert E. Ellefson, John T. Gill, Robert J. Walko, Clifford L. Renschler
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Patent number: 5100587Abstract: A new type of RL light source consisting of a zeolite crystalline material, the intralattice spaces of which a tritiated compound and a luminophore are sorbed, and which material is optionally further dispersed in a refractive index-matched polymer matrix.Type: GrantFiled: December 27, 1990Date of Patent: March 31, 1992Assignee: The United States of America as represented by the Department of EnergyInventors: Roger L. Clough, John T. Gill, Daniel B. Hawkins, Clifford L. Renschler, Timothy J. Shepodd, Henry M. Smith
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Patent number: 5078919Abstract: The invention provides a process for loading an aerogel substrate with tritium and the resultant compositions. According to the process, an aerogel substrate is hydrolyzed so that surface OH groups are formed. The hydrolyzed aerogel is then subjected to tritium exchange employing, for example, a tritium-containing gas, whereby tritium atoms replace H atoms of surface OH groups. OH and/or CH groups of residual alcohol present in the aerogel may also undergo tritium exchange.Type: GrantFiled: March 20, 1990Date of Patent: January 7, 1992Assignee: The United States of America as represented by the United States Department of EnergyInventors: Carol S. Ashley, C. Jeffrey Brinker, Robert E. Ellefson, John T. Gill, Scott Reed, Robert J. Walko
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Patent number: 5011781Abstract: Disclosed is an improved autoradiography enhancer composition and method of use. The enhancer composition uses an acid anhydride as a dehydration agent.Type: GrantFiled: July 31, 1989Date of Patent: April 30, 1991Assignee: Electron Microscope Supplies CorporationInventor: Coleman Bess
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Patent number: 4997597Abstract: A solid state radioluminescent composition for light source comprises an optically clear polymer organic matrix containing tritiated organic materials and dyes capable of "red" shifting primary scintillation emissions from the polymer matrix. The tritiated organic materials are made by reducing, with tritium, an unsaturated organic compound that prior to reduction contains olefinic or alkynylic bonds.Type: GrantFiled: November 13, 1989Date of Patent: March 5, 1991Assignee: The United States of America as represented by the United States Department of EnergyInventors: Roger L. Clough, John T. Gill, Daniel B. Hawkins, Clifford L. Renschler, Timothy J. Shepodd, Henry M. Smith
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Patent number: 4889660Abstract: A radioluminescent light source comprises a solid mixture of a phosphorescent substance and a tritiated polymer. The solid mixture forms a solid mass having length, width, and thickness dimensions, and is capable of self-support. In one aspect of the invention, the phosphorescent substance comprises solid phosphor particles supported or surrounded within a solid matix by a tritium containing polymer. The tritium containing polymer comprises a polymer backbone which is essentially void of tritium.Type: GrantFiled: December 24, 1987Date of Patent: December 26, 1989Assignee: Battelle Memorial InstituteInventors: George A. Jensen, David A. Nelson, Peter M. Molton
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Patent number: 4871480Abstract: Disclosed is an improved autoradiography enhancer composition and method of use. The enhancer composition uses an acid anhydride as a dehydration agent.Type: GrantFiled: November 24, 1987Date of Patent: October 3, 1989Assignee: Electron Microscope Supplies CorporationInventor: Coleman Bess
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Patent number: 4710319Abstract: The subject invention provides an autofluorography kit composition comprising (i) a first aqueous solution of a water soluble fluor having a formula selected from R--CO.sub.2 --X; R--SO.sub.3 --X; and R--NH.sub.3 --Y; where X and Y are any counterion capable of imparting water solubility, and R is a fluor molecule; and (ii) a second aqueous solution of a precipitator capable of precipitating the water soluble fluor in an electrophoresis gel matrix.Type: GrantFiled: November 8, 1985Date of Patent: December 1, 1987Assignee: E. I. Du Pont de Nemours and CompanyInventors: Duk-Hi Lee, Susan E. Feierberg, Patricia Mayer
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Patent number: 4624799Abstract: A liquid, homogeneous mixture for use in the LSC (Liquid Scintillation Counting) analysis technique, comprising a scintillation liquid, a scintillator and a surfactant, wherein the surfactant includes one or more phosphoric acid esters having formula 1 and/or formula 2 of the sheet of formulae, in which R', R" and R'" represent an organic group, which phosphor acid esters are neutralized to a pH, at which the neutralization product comprises a mono- and/or diphosphate with an alkaline material having a pK.sub.a of at least 5, and in which of the organic phosphoric acid esters having formula 1, R" and R'" may be the same or different.Type: GrantFiled: September 14, 1984Date of Patent: November 25, 1986Assignee: Packard Instrument B.V.Inventors: Theodorus C. J. M. Hegge, Jan ter Wiel
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Patent number: 4595599Abstract: A luminescent compound, comprising a phosphor group or groups and an alkylalkoxysilane, and a luminescent composition comprising such luminescent compound and a radioactive substance to provide a source of exciting radiation for the luminescent compound in the composition. The present invention further comprises a method for rendering siliceous surfaces luminescent comprising applying the compound or composition to the surface and reacting the compound or composition with water after the compound or composition has migrated into the surface to hydrolyze the compound or composition. The present invention further comprises a luminescent structure having a siliceous surface incorporating the products of the reaction between the surface, water and the compound or composition of the present invention.Type: GrantFiled: June 21, 1985Date of Patent: June 17, 1986Assignee: Advanced Chemical Technologies CompanyInventors: Roy N. Brown, Mike F. Stout, Arnulf P. Hagen, Leo Garwin
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Patent number: RE45930Abstract: The present invention provides for a composition comprising an inorganic scintillator comprising a lanthanide-doped strontium barium mixed halide useful for detecting nuclear material.Type: GrantFiled: December 12, 2014Date of Patent: March 15, 2016Assignee: The Regents of The University of CaliforniaInventors: Gautam Gundiah, Gregory A. Bizarri, Stephen M. Hanrahan, Edith D. Bourret-Courchesne, Stephen E. Derenzo