High Polymeric (resinous) Antistatic Agents Patents (Class 260/DIG17)
Digests
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Patent number: 5609969Abstract: The invention comprises a self supporting electronic packaging article comprising an insulative polymer overcoated with an antistatic/protective coating system comprising from about 8 mg/m.sup.2 to about 70 mg/m.sup.2 vanadium pentoxide, from about 36 mg/m.sup.2 to about 270 mg/m.sup.2 of a polymer latex having a hydrophilic functionality, and from about 210 mg/m.sup.2 to about 842 mg/m.sup.2 of a nonsulfonated protective topical binder, all of which may be contained in a single coating, or which may be contained in a two-layer coating system.Type: GrantFiled: June 30, 1995Date of Patent: March 11, 1997Assignee: Minnesota Mining and Manufacturing CompanyInventors: William J. Clatanoff, Eric D. Morrison, Nanayakkara L. D. Somasiri
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Patent number: 5082730Abstract: Disclosed herein are a stretched antistatic laminate film comprising at least one coating layer containing a polymer having pyrrolidium rings in the main molecular chain, and a polyester film layer, a magnetic recording medium using the same, and a recording material for heat sensitive transfer printing using the same.Type: GrantFiled: December 2, 1988Date of Patent: January 21, 1992Assignee: Diafoil Company, LimitedInventors: Naohiro Takeda, Yuzo Otani, Nariaki Okajima, Masahiro Kita
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Patent number: 4719263Abstract: Thermoplastic and thermoset materials containing an effective amount of an antistatic agent for improving antistatic properties thereof, the antistatic agent is selected from homopolymers and copolymers of an epihalohydrin.Type: GrantFiled: May 10, 1985Date of Patent: January 12, 1988Assignee: The B. F. Goodrich CompanyInventors: James P. Barnhouse, Simon H. Yu
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Patent number: 4604425Abstract: The surface of a polymer material is modified by adding to the material a block copolymer. The block copolymer has a hydrophilic polymer portion and a polymer portion which is compatible with the polymer material to be modified. The block copolymer can be easily syntheized in the presence of a polymeric peroxide and can easily and permanently modify the surface of the polymer material.Type: GrantFiled: April 18, 1984Date of Patent: August 5, 1986Assignee: Nippon Oil and Fats Co.Inventors: Hiroshi Ohmura, Yoshihiro Oshibe, Masaharu Nakayama, Takashi Yamamoto
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Patent number: 4579902Abstract: The present invention provides a permanently antistatic, injection moldable thermoplastic composition comprising a polybutylene terephthalate resin having an intrinsic viscosity in the range of about 0.7 to about 1.4 deciliters per gram measured in ortho-chlorophenol at 25.degree. C., an antistatic dopant comprising an electron acceptor compound, an electron donor compound, and polytetrafluoroethlene, and less than about 10 percent by weight based on the total weight of the molding composition of carbon fibers having lengths between about 0.1 and about 1.0 inch. Such a molding composition exhibits a volume resistivity of less than 1.times.10.sup.8 ohm-cm, exceptional low wear performance, excellent mechanical properties, and ease of manufacture.Type: GrantFiled: December 5, 1984Date of Patent: April 1, 1986Assignee: Celanese CorporationInventor: David P. O'Brien
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Patent number: 4416668Abstract: This invention relates to imides of .alpha.-olefin-maleic copolymers and to blends of imides of .alpha.-olefin-maleic copolymer and .alpha.-olefin-sulfur dioxide copolymers; and to systems, such as hydrocarbon fuels, containing such compositions as antistatic agents.Type: GrantFiled: June 4, 1982Date of Patent: November 22, 1983Assignee: Petrolite CorporationInventor: Neil E. S. Thompson
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Patent number: 4391741Abstract: A polyoxymethylene composition comprising (a) 100 parts by weight of polyoxymethylene, (b) 2 to 15 parts by weight of electrically conductive carbon black, and (c) 2 to 20 parts by weight of low-density polyethylene has excellent antistatic properties. Shaped articles produced by the polyoxymethylene composition show excellent effects on preventing noise due to static electricity and adhesion of dust.Type: GrantFiled: June 25, 1979Date of Patent: July 5, 1983Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Junzo Masamoto, Minoru Hamada, Isamu Suzuki, Takeo Yoshida
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Patent number: 4382881Abstract: A method of preparing an antistatic coating exhibiting a desired value of surface resistivity which is substantially stable with respect to time takes as its starting point a commercial antistatic product having a synthetic resin base and substantially free from metallic particles but of which the surface resistivity, measured after mixing with its hardener and drying, is very much below the desired value. A compatible insulating resin is added to this product so as to raise the surface resistivity, still measured after mixing with the hardener and drying, to a value much higher than the desired value. The resulting product is then subjected to an accelerated ageing treatment causing a reduction in surface resistivity with terminal asymptotic development to the level of the desired value. Such a coating may be applied to radomes and other aircraft surface elements, and has the advantage that its conductivity does not increase appreciably with age.Type: GrantFiled: August 14, 1980Date of Patent: May 10, 1983Assignee: Avions Marcel Dassault-Breguet AviationInventor: Fernand J. Levy
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Patent number: 4337188Abstract: A composition capable of being used for the manufacture of polyolefin film having so-called "cling" properties is disclosed. The composition consists essentially of(a) an intimate mixture of 75-98 weight percent of a first component and 2-25 weight percent of a second component, and(b) at least 200 ppm, based on the weight of (a), of an agent selected from the class consisting of(i) an organic compound having at least one polar group and at least one group selected from the class consisting of alkylene and alkylene interrupted by oxygen, said alkylene having at least eight carbon atoms and said compound being a liquid or a waxy solid;(ii) mineral oil;(iii) a liquid polyolefin; and(iv) an organic phosphate ester that is a liquid or waxy solid; and mixtures of such agents.A preferred agent is N,N-bis(2-hydroxyethyl) alkylamine where the alkyl group is C.sub.12 -C.sub.18 alkyl group. The first component is a blend of 10-100 percent of at least one homopolymer of ethylene having a density of 0.915-0.930 g/cm.sup.Type: GrantFiled: October 24, 1980Date of Patent: June 29, 1982Assignee: Du Pont Canada Inc.Inventors: David C. Climenhage, Walter R. Eadie
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Patent number: 4314040Abstract: A concentrated antistatic composition adapted for incorporation into various polymers such as olefins is prepared by admixing a liquid ethoxylated amine antistatic agent, such as an N,N-bis-(2-hydroxyethyl)alkenyl or mixed alkenyl and alkyl (C.sub.6 -C.sub.18) amine, with various polymers such as, for example, polypropylene, heating to form a homogeneous liquid and rapidly cooling the mixture to form a solid antistatic agent. A normally liquid antistatic agent can thus be simply and readily blended into a polymer such as polyethylene as a dry, solid product to impart antistatic properties to the blended resin.Type: GrantFiled: February 11, 1980Date of Patent: February 2, 1982Assignee: Akzona IncorporatedInventors: Anthony J. Castro, James W. Stoll
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Patent number: 4312966Abstract: A flame-retardant, antistatic synthetic polymeric fiber which is the product of the process of dispersing in said fiber about 1 percent to about 12 percent by weight of a polymer composition which is the reaction product of a polyester of a polyoxyalkylene compound having as a nucleus a nitrogen-containing reactive hydrogen containing compound with a reactant selected from the group consisting of at least one of an aliphatic or aromatic diacid, anhydride or acid halide thereof and a diol wherein at least one of said reactant is halogenated.Type: GrantFiled: June 20, 1980Date of Patent: January 26, 1982Assignee: BASF Wyandotte CorporationInventors: David D. Newkirk, Robert B. Login, Basil Thir
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Patent number: 4259087Abstract: This invention relates to compositions comprising (1) .alpha.-olefin-acrylonitrile copolymers and (2) polymeric polyamines; and to such compositions in combination with organic liquids such as hydrocarbon fluids in which such compositions are effective as antistatic agents.Type: GrantFiled: December 15, 1978Date of Patent: March 31, 1981Assignee: Petrolite CorporationInventors: Michael I. Naiman, J. Irvine Knepper, Neil E. S. Thompson
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Patent number: 4259474Abstract: The sulfur-containing polyoxyalkylenes having the formula: ##STR1## wherein E is --SW or a halogen atom; W is hydrogen, phenyl, alkyl of 1 to 4 carbon atoms, an alkali metal or ammonium ion, or a heterocyclic radical containing from 2 to 4 hetero atoms in a 5-or 6-membered ring which may be monocyclic or may be fused to an aromatic ring; A, C and D represent lower alkylene of 2 to 4 carbon atoms; B is alkylene of 2 to 8 carbon atoms; y and z are each integers having a value of 0 to 50; x is an integer having a value of from 2 to 50; and n is an integer having a value of from 1 to 30; and intermixtures of said polyoxyalkylenes.The above compounds display a wide variety of uses; however, all are active metal working lubricants.Type: GrantFiled: September 25, 1979Date of Patent: March 31, 1981Assignee: GAF CorporationInventors: Paritosh M. Chakrabarti, Lindley S. Wood, David J. Tracy
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Patent number: 4248934Abstract: The invention relates to fibre or filament mixtures consisting of high shrinkage side-by-side bifilar (mod)acrylic fibres or filaments separately containing TiO.sub.2 and carbon black and of normal fibres or filaments of polyamide, polyester, polyalkylene, poly(mod)acrylic, wool or cotton.Type: GrantFiled: July 5, 1978Date of Patent: February 3, 1981Assignee: Bayer AktiengesellschaftInventors: Martin Wandel, Helmut Engelhard, Ernst Gutschik, Manfred Reichardt, Geert Christoph
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Patent number: 4226750Abstract: Two plastics which were heretofore impossible to combine, can be combined with each other if the one to be added is converted to a porodin gel by heating the same at a temperature of at least 180.degree. C. with a substance that does not dissolve the polymer, and then cooling to below 120.degree.. The porodin gel can then be easily admixed with the other plastic material in an amount of 1 to 50% by weight, preferably 5 to 20% by weight based on the weight of the modified plastic material. Examples are the incorporation of polyethylene or polypropylene or polymethyl methacrylate in polyvinyl chloride, or the incorporation of polystyrene in polypropylene, or the incorporation of polymethyl methacrylate in polyethylene.Type: GrantFiled: June 13, 1978Date of Patent: October 7, 1980Assignee: Muanyagipari Kutato IntezetInventors: Miklos Dimitrov, Franciska K. Keleman nee Gulyas, Richard Marko, Tamas Pazonyi, Bela Pukanszky, Andras Riczko
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Patent number: 4210556Abstract: A concentrated antistatic composition adapted for incorporation into various polymers such as olefins is prepared by admixing a liquid ethoxylated amine antistatic agent, such as an N,N-bis-(2-hydroxyethyl) alkenyl or mixed alkenyl and alkyl (C.sub.6 -C.sub.18)amine, with various polymers such as, for example, polypropylene, heating to form a homogeneous liquid and rapidly cooling the mixture to form a solid antistatic agent. A normally liquid antistatic agent can thus be simply and readily blended into a polymer such as polyethylene as a dry, solid product to impart antistatic properties to the blended resin.Type: GrantFiled: October 27, 1978Date of Patent: July 1, 1980Assignee: Akzona IncorporatedInventors: Anthony J. Castro, James W. Stoll
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Patent number: 4201824Abstract: Novel linear hydrophilic polyurethane polymers are presented. The polymers provide outstanding soil-release, anti-soil redeposition and anti-static properties when applied to natural and synthetic textile substrates, especially textile substrates containing polyester fibers. These polyurethanes are particularly useful in detergent compositions.Type: GrantFiled: June 7, 1977Date of Patent: May 6, 1980Assignee: Rhone-Poulenc IndustriesInventors: Robert Violland, Alain Lagasse
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Patent number: 4165303Abstract: Polyamides and polyesters having greatly improved resistance to static electricity buildup are obtained by the incorporation of about 0.1 to 20 weight percent poly(alkylene ether) esters of polybasic acid. The antistatic properties of these polymers is significantly improved when poly(ethylene oxide) esters of dimer and trimer acids are employed.Type: GrantFiled: August 26, 1977Date of Patent: August 21, 1979Assignee: Emery Industries, Inc.Inventors: Irwin S. Schlossman, Robert E. Wiman
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Patent number: 4151139Abstract: The invention provides novel polyaddition products of polyglycol diepoxides and polyamine derivatives, which products are useful as antistatic agents.Type: GrantFiled: February 27, 1978Date of Patent: April 24, 1979Assignee: Sandoz Ltd.Inventor: Richard Hochreuter
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Patent number: 4147742Abstract: A concentrated antistatic composition adapted for incorporation into various polymers such as olefins is prepared by admixing a liquid ethoxylated amine antistatic agent, such as an N,N-bis-(2-hydroxyethyl) alkenyl or mixed alkenyl and alkyl (C.sub.6 -C.sub.18) amine, with various polymers such as, for example, polypropylene, heating to form a homogeneous liquid and rapidly cooling the mixture to form a solid antistatic agent. A normally liquid antistatic agent can thus be simply and readily blended into a polymer such as polyethylene as a dry, solid product to impart antistatic properties to the blended resin.Type: GrantFiled: October 15, 1975Date of Patent: April 3, 1979Assignee: Akzona IncorporatedInventors: Anthony J. Castro, James W. Stoll
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Patent number: 4144206Abstract: A static dissipating heat curable silicone rubber composition comprising a diorganopolysiloxane polymer, a filler and a peroxide curing catalyst and as the static discharging agent a polyether-polysiloxane copolymer.Type: GrantFiled: January 13, 1978Date of Patent: March 13, 1979Assignee: General Electric CompanyInventor: Gerald E. Symeon
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Patent number: 4091049Abstract: Powder coating compositions are disclosed which, exclusive of pigments and other nonreactive components, comprise a coreactive mixture of: (A) a copolymer of between about 8 and about 30 weight percent of a glycidyl ester of a monoethylenically unsaturated acid and between about 92 and about 70 weight percent of other monoethylenically unsaturated monomers, said copolymer having a glass transition temperature in the range of 40.degree. C to 90.degree. C and a number average molecular weight (M.sub.n) in the range of about 2500 to about 8500; and (B) a carboxyl terminated crosslinking agent in the amount of 0.8 to 1.2 carboxyl groups for each epoxy group in the copolymer.Type: GrantFiled: December 18, 1973Date of Patent: May 23, 1978Assignee: Ford Motor CompanyInventors: Santokh S. Labana, Yun-Feng Chang
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Patent number: 4091048Abstract: Powder coating compositions are disclosed which, exclusive of pigments and other nonreactive components, comprise a coreactive mixture of: (A) a copolymer of between about 5 and about 20 weight percent of a glycidyl ester of a monoethylenically unsaturated acid and between about 95 to about 80 weight percent of other monoethylenically unsaturated monomers, said copolymer having a glass transition temperature in the range of 40.degree. C to 90.degree. C and a number average molecular weight (M.sub.n) of between about 2500 and about 8500; and (B) an organic carboxylic acid anhydride crosslinking agent, said anhydride being present in the amount of from about 0.4 to about 1.0 anhydride groups for each epoxy group in the copolymer.Type: GrantFiled: December 18, 1973Date of Patent: May 23, 1978Assignee: Ford Motor CompanyInventors: Santokh S. Labana, Ares N. Theodore
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Patent number: 4084048Abstract: Polyfunctional polymers of which the side branches contain dioxathiazole-2-oxide groups are described. They possess the reactivity of dioxathiazole-2-oxide and can in addition contain other reactive groups. They can be used for the manufacture of moldings, coatings or adhesives.Type: GrantFiled: September 22, 1975Date of Patent: April 11, 1978Assignee: BASF AktiengesellschaftInventors: Herbert Naarmann, Heinz Pohlemann
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Patent number: 4044070Abstract: Powder coating compositions are disclosed which comprise a blend of coreactable, thermosettable copolymers one of which has at least two different functional groups while the other is qualitatively monofunctional and quantitatively polyfunctional. Ordinarily, the polymer having at least two different functional groups, will be quantitatively polyfunctional and qualitatively difunctional although it may contain more than two different functional groups. In the preferred embodiments, the first or difunctional copolymer of the blend has either (1) epoxy functionality and amide functionality, (2) epoxy functionality and hydroxy functionality, (3) carboxy functionality and amide functionality, or (4) carboxy functionality and hydroxy functionality and is crosslinkable with the second copolymer through at least two different types of functional groups on the first copolymer.Type: GrantFiled: February 18, 1976Date of Patent: August 23, 1977Assignee: Ford Motor CompanyInventors: Santokh S. Labana, Ares N. Theodore
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Patent number: 4041001Abstract: A method for preparing wash-resistant antistatic synthetic fibrous substrates and compositions utilized therefor are disclosed. The method comprises applying a novel antistatic composition comprising a sulfonated polymer and a polyhydroxy organic compound to a synthetic fibrous substrate, curing the antistatic composition and thereby forming a wash-resistant antistatic coating for the substrate.Type: GrantFiled: November 25, 1974Date of Patent: August 9, 1977Assignee: National Starch and Chemical CorporationInventors: Chester D. Szymanski, Ronald DeMartino
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Patent number: 4035441Abstract: A polyester filament in which a polyether-polyester block copolymer is dispersed as fine striae along the filament axis, at least one of which is substantially endless. Process for preparing the same includes a melt spinning apparatus with static mixing elements interposed between separate molten polymer feed passageways and spinneret holes.Type: GrantFiled: June 24, 1974Date of Patent: July 12, 1977Assignee: Toray Industries, Inc.Inventors: Tadakazu Endo, Masanori Takeuchi, Tuneo Hanada, Kiyoshi Nakagawa, Hideo Komatsu, Itaru Nakamura
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Patent number: 4032595Abstract: The reaction product of a polyalkoxylated triglyceride with an ester of oxalic or malonic acid in the ratio of at least 2 molecules of the latter to 1 molecule of the former, also synthetic polymers containing a minor proportion of the reaction product.Type: GrantFiled: August 5, 1975Date of Patent: June 28, 1977Assignee: Imperial Chemical Industries LimitedInventors: Ian Stuart Fisher, James Eric McIntyre
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Patent number: 4014955Abstract: The cross-linked macromolecular polyethers containing ionic bonds are obtained by reacting polyhydric phenols which contain amino groups (Mannich bases) on the one hand with compounds which contain on average more than one epoxide group per molecule, and on the other hand with organic compounds which contain at least 2 halogen atoms. The reaction is on the one hand a polyaddition, and on the other a polyquaternization. The adducts manufactured in this way have a reduced tendency to take on a static charge and can be used with advantage in the textile and paper sectors.Type: GrantFiled: February 7, 1974Date of Patent: March 29, 1977Assignee: Ciba-Geigy AGInventor: Alfred Renner
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Patent number: 4012366Abstract: Polymers which contain hydroxamic acid-O-sulfonyl groups in the side chains and which accordingly can undergo important substitution reactions. The polymers may also contain other reactive groups and may be used for the manufacture of moldings, coatings or adhesives.Type: GrantFiled: November 17, 1975Date of Patent: March 15, 1977Assignee: BASF AktiengesellschaftInventors: Herbert Naarmann, Heinz Pohlemann
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Patent number: 3998905Abstract: Powder coating compositions are disclosed which comprise a blend of coreactable, thermosettable copolymers one of which has at least two different functional groups while the other is qualitatively monofunctional and quantitatively polyfunctional. Ordinarily, the polymer having at least two different functional groups, will be quantitatively polyfunctional and qualitatively difunctional although it may contain more than two different functional groups. In the preferred embodiments, the first or difunctional copolymer of the blend has either (1) epoxy functionality and amide functionality, (2) epoxy functionality and hydroxy functionality, (3) carboxy functionality and amide functionality, or (4) carboxy functionality and hydroxy functionality and is crosslinkable with the second copolymer through at least two different types of functional groups on the first copolymer.Type: GrantFiled: February 18, 1976Date of Patent: December 21, 1976Assignee: Ford Motor CompanyInventors: Santokh S. Labana, Ares N. Theodore
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Patent number: 3989866Abstract: Disclosed herein are novel synthetic polyamide fibers of generally triangular cross-sectional area having fibrils of polystyrene dispersed throughout as a discontinuous phase. The polyamide fibers are especially useful because of their enhanced antisoiling properties and can be advantageously employed in carpets, upholstery coverings, etc., where soiling is a problem.Type: GrantFiled: June 6, 1975Date of Patent: November 2, 1976Assignee: Akzona IncorporatedInventors: Brewster B. Eskridge, Boyce M. Lyon
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Patent number: 3988158Abstract: Antistatic and antifoaming agents for use with light sensitive silver halide photographic materials comprised of polymerized pyridyl-type compounds are disclosed.Type: GrantFiled: October 6, 1975Date of Patent: October 26, 1976Assignee: Konishiroku Photo Industry Co., Inc.Inventors: Toshio Muramatsu, Koichi Nagayasu, Masayuki Kimura, Sadatugu Terada, Masayoshi Mayama
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Patent number: 3976719Abstract: Powder coating compositions are disclosed which comprise a blend of coreactable, thermosettable copolymers each of which have at least two different functional groups. Ordinarily, these polymers will be qualitatively difunctional, although they may contain more than two different functional groups, and quantitatively polyfunctional. At least one of the copolymers has epoxy functionality as one of its two or more different functionalities. Thus, in the preferred embodiments, the first copolymer of the blend has epoxy functionality and a second functionality selected from amide functionality, anhydride functionality and hydroxy functionality and is crosslinkable with the second copolymer through at least two different types of functional groups on the first copolymer.Type: GrantFiled: August 21, 1975Date of Patent: August 24, 1976Assignee: Ford Motor CompanyInventors: Santokh S. Labana, Ares N. Theodore
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Patent number: 3976715Abstract: Powder coating compositions are disclosed which comprise a blend of coreactable, thermosettable copolymers each of which have at least two different functional groups. Ordinarily, these polymers will be qualitatively difunctional, although they may contain more than two different functional groups, and quantitatively polyfunctional. At least one of the copolymers has epoxy functionality as one of its two or more different functionalities. Thus, in the preferred embodiments, the first copolymer of the blend has epoxy functionality and a second functionality selected from amide functionality, anhydride functionality and hydroxy functionality and is crosslinkable with the second copolymer through at least two different types of functional groups on the first copolymer.Type: GrantFiled: August 21, 1975Date of Patent: August 24, 1976Assignee: Ford Motor CompanyInventors: Santokh S. Labana, Ares N. Theodore
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Patent number: 3976718Abstract: Powder coating compositions are disclosed which comprise a blend of coreactable, thermosettable copolymers each of which have at least two different functional groups. Ordinarily, these polymers will be qualitatively difunctional, although they may contain more than two different functional groups, and quantitatively polyfunctional. At least one of the copolymers has epoxy functionality as one of its two or more different functionalities. Thus, in the preferred embodiments, the first copolymer of the blend has epoxy functionality and a second functionality selected from amide functionality, anhydride functionality and hydroxy functionality and is crosslinkable with the second copolymer through at least two different types of functional groups on the first copolymer.Type: GrantFiled: August 21, 1975Date of Patent: August 24, 1976Assignee: Ford Motor CompanyInventors: Santokh S. Labana, Ares N. Theodore
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Patent number: 3976717Abstract: Powder coating compositions are disclosed which comprise a blend of coreactable, thermosettable copolymers each of which have at least two different functional groups. Ordinarily, these polymers will be qualitatively difunctional, although they may contain more than two different functional groups, and quantitatively polyfunctional. At least one of the copolymers has epoxy functionality as one of its two or more different functionalities. Thus, in the preferred embodiments, the first copolymer of the blend has epoxy functionality and a second functionality selected from amide functionality, anhydride functionality and hydroxy functionality and is crosslinkable with the second copolymer through at least two different types of functional groups on the first copolymer.Type: GrantFiled: August 21, 1975Date of Patent: August 24, 1976Assignee: Ford Motor CompanyInventors: Santokh S. Labana, Ares N. Theodore
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Patent number: 3976716Abstract: Powder coating compositions are disclosed which comprise a blend of coreactable, thermosettable copolymers each of which have at least two different functional groups. Ordinarily, these polymers will be qualitatively difunctional, although they may contain more than two different functional groups, and quantitatively polyfunctional. At least one of the copolymers has epoxy functionality as one of its two or more different functionalities. Thus, in the preferred embodiments, the first copolymer of the blend has epoxy functionality and a second functionality selected from amide functionality, anhydride functionality and hydroxy functionality and is crosslinkable with the second copolymer through at least two different types of functional groups on the first copolymer.Type: GrantFiled: August 21, 1975Date of Patent: August 24, 1976Assignee: Ford Motor CompanyInventors: Santokh S. Labana, Ares N. Theodore
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Patent number: 3963803Abstract: An acrylic fiber having excellent antistatic properties is obtained by mixing a polymer (A) consisting mainly of acrylonitrile with a copolymer (B) consisting mainly of a polyetherpolyester block copolymer consisting of a polyester and compound represented by the general formula (1): ##EQU1## (wherein each of m and n is O or a positive integer, wherein 25 .ltoreq. m + n .ltoreq. 1000, and m .gtoreq. 10).Type: GrantFiled: September 24, 1973Date of Patent: June 15, 1976Assignee: Toray Industries, Inc.Inventors: Hiroyoshi Tanaka, Haruo Obara, Teruo Koseki, Hajime Machida, Michihiko Tanaka, Shigeru Fujii
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Patent number: 3959404Abstract: Powder coating compositions are disclosed which, exclusive of pigments and non-reactive components, comprise a coreactive mixture of: (A) a copolymer of between about 8 and about 30 weight percent of a glycidyl ester of a monoethylenically unsaturated acid and between about 92 and about 70 weight percent of other monoethylenically unsaturated monomers, said copolymer having a glass transition temperature in the range of 40.degree. to 90.degree.C and a number average molecular weight (M.sub.n) of between about 2500 and about 8500; and (B) a phenolic hydroxy terminated compound in the amount of between about 0.8 and 1.2 phenolic hydroxy groups for each epoxy group in the copolymer.Type: GrantFiled: December 18, 1973Date of Patent: May 25, 1976Assignee: Ford Motor CompanyInventors: Santokh S. Labana, Ares N. Theodore