Fiber Patents (Class 260/DIG23)
  • Patent number: 5688596
    Abstract: An aromatic polyamide filament includes extremely fine inorganic material having a high refractive index of 2.0 or more and an extremely fine average particle size of 0.3 .mu.m or less and dispersed, in an amount of 0.1 to 5% based on the total weight of the filament, in at least a surface portion of an aromatic polyamide filament matrix; has an individual filament thickness of 0.5 to 50 deniers, a tensile strength of 18 g/d or more, an ultimate elongation of 3.5% or more and an initial modulus of 450 g/d; and exhibits an enhanced weathering resistance derived from the high ultraviolet ray-reflecting, shielding and absorbing properties of the extremely fine inorganic particles dispersed in the filament matrix.
    Type: Grant
    Filed: March 20, 1995
    Date of Patent: November 18, 1997
    Assignee: Teijin Limited
    Inventors: Osamu Makino, Toshitsugu Matsuki, Toshihiro Santa
  • Patent number: 4504545
    Abstract: A polyamide fiber excellent in strength, which is characterized by being made of a polyamide having a relative viscosity of not less than 3.5 (measured on a 96% by weight sulfuric acid solution having a polyamide concentration of 10 mg/ml at 20.degree. C.), showing an index of birefringence (.DELTA.n) of not less than 50.times.10.sup.-3 and having the following relationship between the break strength and the break elongation:Break strength (g/d).times.(Break elongation (%)).sup.1/2 .gtoreq.46.0, the index of birefringence in the section of fiber satisfying the following relationship:.DELTA.n.sub.A -.DELTA.n.sub.B .gtoreq.0.5.times.10.sup.-3(wherein .DELTA.n.sub.A is the index of birefringence of fiber at the position of r/R=0.9, .DELTA.n.sub.B is the index of birefringence of fiber at the position of r/R=0.0, R is the radius of the section of fiber and r is the distance from the central axis of the section of fiber).
    Type: Grant
    Filed: September 8, 1982
    Date of Patent: March 12, 1985
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Kazuo Kurita, Hideaki Ishihara
  • Patent number: 4346146
    Abstract: Porous flame retarded acrylic synthetic fibers consisting of cellulose acetate and a modacrylic copolymer containing vinyl chloride and/or vinylidene chloride are produced by spinning an organic solvent solution of a polymer consisting of cellulose acetate and the above described modacrylic copolymer into a coagulation bath, primarily drawing the spun fibers at a draw ratio of 2.5.about.8.0, drying the water swelled fibers at 100.degree..about.180.degree. C. to a water content of no greater than 1.0% by weight and secondarily drawing the dried fibers under wet heat at a draw ratio of no greater than 3 times.
    Type: Grant
    Filed: June 6, 1980
    Date of Patent: August 24, 1982
    Assignees: Kanebo, Ltd., Kanebo Synthetic Fibers, Ltd.
    Inventors: Yoshikazu Kondo, Toshihiro Yamamoto, Takaji Yamamoto
  • Patent number: 4343859
    Abstract: The present invention relates to an improved process for forming elastomeric fibers for elastic yarn from neutralized sulfonated elastomeric polymers, and novel elastomeric fiber compositions derived therefrom, wherein the neutralized sulfonated elastomeric polymer is dissolved in a mixed solvent consisting of a backbone solvent and a polar cosolvent and spun into fibers. The neutralized sulfonated elastomeric polymer has about 10 to about 50 meq. sulfonate groups per 100 grams of sulfonated elastomeric polymer, of which at least 95% are neutralized with a cation being selected from the group consisting of antimony, iron, lead, aluminum, and Groups I-A, II-A, IB and II-B of the Periodic Table of Elements and mixtures thereof. The solution of the neutralized sulfonated elastomeric polymer having a Brookfield viscosity at room temperature at about 6 rpm of about 1,000 to about 200,000 cps is fabricated into fibers by wet or dry spinning through a spinner having a plurality of orifices therein.
    Type: Grant
    Filed: August 21, 1980
    Date of Patent: August 10, 1982
    Assignee: Exxon Research & Engineering Co.
    Inventors: Robert D. Lundberg, Henry S. Makowski
  • Patent number: 4294884
    Abstract: An acrylic fiber having improved basic dyeability and the method for making the same wherein an acrylic polymer containing a sulfonated vinyl monomer as a part thereof is dissolved in a suitable solvent to form a spinning dope and a solution of a second or additive polymer dissolved in the same solvent is added to the dope which is then spun to form fibers. The second polymer is selected from the group consisting of cellulose triacetate, polymethyl methacrylate, polyvinyl chloride, a polyamide of hexamethylenediamine with 1,1,3-trimethyl-5-carboxy-3-(p-carboxyphenyl) indane and a polyamide of hexamethylene diamine with isophthalic acid. The spin dope will contain 10 to 35 weight percent of polymer solids, with the amount of the second or additive polymer being 0.5 to 25 weight percent of the total polymer solids. Fibers spun from the dope have enhanced basic dyeability. The method is effective only when the acrylic polymer contains a sulfonated vinyl monomer as part of the acrylic polymer backbone.
    Type: Grant
    Filed: June 6, 1980
    Date of Patent: October 13, 1981
    Assignee: Monsanto Company
    Inventors: Hartwig C. Bach, Helmuth E. Hinderer
  • Patent number: 4293613
    Abstract: Disclosed is an acrylic fiber having improved basic dyeability. The fiber is made by a process wherein a copolymer of an acrylic monomer and a sulfonated vinyl monomer is dissolved in a solvent to form a spinning dope and a solution of polystyrene in the same solvent is added to the dope prior to spinning the dope to form fibers. The polystyrene will be in the form of a separate phase dispersed throughout the spinning dope and the fibers formed from the dope. Fibers formed from this polystyrene-containing dope have improved basic dyeability.
    Type: Grant
    Filed: June 6, 1980
    Date of Patent: October 6, 1981
    Assignee: Monsanto Company
    Inventors: Hartwig C. Bach, Helmuth E. Hinderer
  • Patent number: 4160760
    Abstract: A method for interacting Prussian blue with polyacrylonitrile in the presence of dimethylformamide to produce a polymer solid exhibiting a high degree of color fastness, levelness, and stability and having enhanced and highly useful electrical properties.
    Type: Grant
    Filed: August 22, 1977
    Date of Patent: July 10, 1979
    Assignee: Northwestern University
    Inventors: Stephen H. Carr, Samuel I. Stupp
  • Patent number: 4082658
    Abstract: Hollow fiber membranes of copolymers of ethylene with 5 to 20 weight percent of copolymerizable vinyl monomers display much superior permeabilities to organic compounds than do polyethylene hollow fibers, less loss of permeability upon storage or use and good strength. Use of such new hollow fiber membranes affords an improved process for the separation of phenols from aqueous solutions thereof through permeation.
    Type: Grant
    Filed: February 9, 1977
    Date of Patent: April 4, 1978
    Assignee: Monsanto Company
    Inventors: Alfred Keith Fritzsche, Richard L. Leonard
  • Patent number: 4049613
    Abstract: Carbon fiber-polyetherimide matrix composites are provided, based on the use of polyetherimide having terminal nitro groups. The carbon fiber-polyetherimide composites have high strength, high modulus and superior solvent resistance.
    Type: Grant
    Filed: September 7, 1976
    Date of Patent: September 20, 1977
    Assignee: General Electric Company
    Inventor: Dwain M. White
  • Patent number: 4024119
    Abstract: Sulfone polymers are disclosed containing bibenzyl sulfone repeating units having the formula ##STR1## These polymers exhibit good mechanical properties, toughness, flexiblity, thermal and chemical stability and can be heat processed, extruded, drawn or otherwise formed into shaped articles having a high degree of strength and good dielectric properties.
    Type: Grant
    Filed: January 12, 1976
    Date of Patent: May 17, 1977
    Assignee: Foster Grant Co., Inc.
    Inventor: Fred Max Sonnenberg
  • Patent number: 4007248
    Abstract: A method for obtaining delustered polyacrylonitrile fibers, wherein fibers are formed from a spinning solution, that is, being a mixture of two copolymer solutions, one of them being polyacrylonitrile and the other a ter grafted copolymer of acrylonitrile and styrene on rubber such as butadiene or butadiene-styrene rubber-ABS-copolymer.
    Type: Grant
    Filed: December 23, 1974
    Date of Patent: February 8, 1977
    Assignee: DSO "Neftochim"
    Inventors: Spas Kostadinov Kostadinov, Iveta Markova Benrey, Vassil Angelov Shopov, Marika Yokimova Kostadinova, Maria Staneva Dimitrova