Abstract: Wax based invisible inks have been discovered that emit light at various wavelengths in the visible region when they are excited by UV light. This allows lower layer clear text information to be written on an object with a regular, visible ink and an upper layer bar code to be written over the lower layer text information with an ink that is invisible to the naked eye. This allows the lower layer text information and upper layer bar code to contain more information than conventional bar codes. These inks allow printing and decoding invisible bar codes over printed information with visible inks. The detection by fluorescence of these invisible inks provides a high signal to noise ratio and no interference with the visible printed information.

Abstract: An object of the present invention is to provide an ink, and ink jet recording method and apparatus using the ink which has excellent dispersion stability, discharge stability and recovery properties, and which can be kept in the weak alkali region even if it contains carbon black with low pH, which is generally considered to be difficult to handle and which can obtain a high-density image. The ink contains acid carbon black having a volatile content within the range 3.5 to 8% by weight, and a water-soluble resin having a weight average molecular weight within the range of 3,000 to 30,000, both of which are dissolved in an aqueous liquid medium, and a compound represented by the following formula (I), wherein the ratio by weight between the acid carbon black and the water-soluble resin is within the range of 3:1 to 10:1.R.sub.1 R.sub.2 NCONHCH.sub.2 CH.sub.2 OH (I)wherein R.sub.1 and R.sub.2 each is hydrogen or C.sub.n H.sub.2n OH, n is 2 or 3, with the proviso that R.sub.1 and R.sub.

Abstract: Permanent aqueous marker inks are provided which include surfactant, a pigment, a film-forming polymer, and water. The surfactant may be a combination of a hydrocarbon, preferably an alkylphenol ethyoxylate and a fluorocarbon, or it may be a silicone.

Abstract: A process for the preparation of inks comprised ofi) flushing pigment into a sulfonated polyester resin, and which resin possesses a degree of sulfonation of from between about 2.5 and about 20 mol percent;ii) dispersing the pigmented polyester resin in water at a temperature of from about 40.degree. C. about 95.degree. C. by a polytron shearing device operating at speeds of from about 100 to about 5,000 revolutions to yield stable pigmented submicron sized particles of from about 5 to about 150 nanometers; and thereafter separating said submicron particles and mixing said submicron particles with water.

Abstract: An invisible ink has been discovered that utilizes a substituted phthalocyanine dye in combination with selected waxes and resins. The resulting ink is one that has use in thermal printing and is transparent or almost transparent in white light, but is responsive to infra-red light in the range of 720 to 1000 nm. The preferred waxes are polyethylene wax, natural paraffin wax and carnauba wax, and the preferred resin is ethyl vinyl acetate polymer.

Abstract: A water base erasable ink composition which comprises:(a) water as a solvent in amounts of 50-90% by weight;(b) a coloring agent dispersed or dissolved in water in amounts of 1-30% by weight;(c) an aqueous emulsion of at least one nonvolatile or only slightly volatile compound which is liquid at room temperatures and is selected from the group consisting of aliphatic carboxylic acid esters, higher hydrocarbons and higher alcohols in dry amounts of 1-20% by weight; and(d) a water soluble resin or a water-solubilized resin which is film forming at room temperatures in amounts of 0.1-15% by weight. The water soluble resin or water-solubilized resin may be displaced by an aqueous emulsion or a hydrosol of water insoluble resins.

Abstract: An ink jet ink especially for printing on to plain paper comprises a suspension in (a) non aqueous solvent of (b) a disperse phase comprising: (i)) a water-insoluble dyestuff which is insoluble in said solvent at the ink jet operating temperature and below; (ii) a water insoluble resinous dispersant for the dyestuff which in the amount used is capable of forming a solution in the said solvent at the ink jet operating temperature, (iii) a polymer binder to hold the dyestuff on the surface of the paper.

Abstract: An erasable ink composition contains an aqueous dispersion of water-insoluble polymer-encapsulated colorant obtained from the emulsion polymerization of at least one hydrophobic emulsion-polymerizable monomer with at least a portion of the monomer containing colorant dissolved therein. The ink is intended for use in any of a variety of marking instruments, in particular, a ball-point pen.

Abstract: This invention relates to improved water-soluble acrylic latex compositions. In particular, this invention relates to acrylic latex compositions produced by reacting monomers with water-soluble support resins derived from reacting a modified rosin with an alkanolamine containing at least one secondary amine and at least one hydroxyl group. These acrylic latex compositions can be utilized to produce water-based flexographic and gravure ink formulations.

Abstract: High-temperature-resistant, flexible screen printing inks containing as binder a thermoplastic aromatic polycarbonate with a molecular weight M.sub.w (weight average) of at least 10,000 which contains bifunctional carbonate structural units corresponding to formula (I): ##STR1## in which R.sup.1 and R.sup.2 independently of one another represent hydrogen, halogen, C.sub.1-8 alkyl, C.sub.5-6 cycloalkyl, C.sub.6-10 aralkyl,m is an integer of 4 to 7R.sup.3 and R.sup.4 may be individually selected for each X and, independently of one another, represent hydrogen or C.sub.1-6 alkyl andX represents carbonwith the proviso that, at least one atom X, R.sup.3 and R.sup.4 are both alkyl, and halogen-free solvents or solvent mixtures.

Abstract: A method is disclosed for dispersing a pigment to obtain a pigment dispersion. The method involves dispersing 100 parts by weight of a pigment, 0.1 to 30 parts by weight of a specific pigment dispersing agent and 5 to 300 parts by weight of a water-based resin in 100 to 2,000 parts by weight of an aqueous medium having a water-soluble organic solvent concentration of 4 to 15% by weight. Pigments are obtained which are suitable for the production of water-based coating compositions or water-based inks excellent in fluidity, storage stability, gloss of a coating, sharpness and tinting strength.

Abstract: The water-based recording ink according to the present invention comprises water, a pigment, a water-soluble homopolymer and a copolymer having both a hydrophobic portion and a hydrophilic portion.The ink according to the present invention can provide a print having excellent density, light fastness and water resistance. Furthermore, the water-based recording ink has such various properties necessary for use as an ink jet recording ink that it does not clog a fine ejection nozzle, has excellent rubbing resistance and setting to dry in the print, is free from aggregation or settlement of solid matter, such as a pigment particle, and exhibits no change in the properties of the ink even when stored at a high temperature or a low temperature for a long period of time and can be redispersed by stirring or further addition of a solvent even when the pigment once aggregated.

Abstract: A radiation-curable ink composition contains a vehicle mixture comprising: (A) at least one linear polyester oligomer and/or polymer substantially free of an acid group and free of a polymerizable double bond in a molecule, wherein 1 to 10 double bonds are pendent from the linear polyester chain, and/or mixture thereof, (B) at least one single double bond-containing carboxylic acid wherein the acid has at least one acid group, and/or carboxylic ester of the said acid, and/or carboxylic amide of the said acid, and/or mixture thereof, (C) a double bond-containing polycarboxylic ester, wherein 2 to 10 acid groups are present and at least 2 double bonds are pendent from the ester having 2 to 10 acid groups, (D) at least one double bond-containing fluorinated carboxylic ester, and/or block copolymer comprising a fluorinated alkyl group-containing polymer segment and a (meth)acrylic polymer segment, and/or block copolymer comprising a siloxane group-containing polymer segment and a (meth)acrylic polymer segment, an

Abstract: A water base erasable ink composition which comprises:(a) water as a solvent in amounts of 50-90% by weight;(b) a coloring agent dispersed or dissolved in water in amounts of 1-30% by weight;(c) an aqueous emulsion of at least one nonvolatile or only slightly volatile compound which is liquid at room temperatures and is selected from the group consisting of aliphatic carboxylic acid esters, higher hydrocarbons and higher alcohols in dry amounts of 1-20% by weight; and(d) a water soluble resin or a water-solubilized resin which is film forming at room temperatures in amounts of 0.1-15% by weight.The water soluble resin or water-solubilized resin may be displaced by an aqueous emulsion or a hydrosol of water insoluble resins.

Abstract: A water base dye ink composition which comprises:(i) water as a solvent;(ii) a carboxyl group containing styrenic resin having an average weight of 1500-30000 and an acid value of 150-300, in an amount of 2-20% by weight;(iii) at least one anionic dye selected from the group consisting of:(a) a metal complex azo acid dye;(b) C.I. direct black; and(c) C.I. acid yellow 110, C.I. acid yellow 127, C.I. direct yellow 100, C.I. 20215, C.I. 20216, C.I. 20230, C.I. 23266, C.I. 23635, C.I. 40002, C.I. 40215, C.I. 42655 and C.I. 42660, in an amount of 0.01-10% by weight; and(iv) an alkali which is volatile at normal temperatures in such an amount as put the ink composition at a pH in the range of 6 to 9.5.

Abstract: An aqueous pigment ink composition for writing utensils is provided, which is capable of providing handwritings with good opacifying properties and exhibits little difference in whiteness between handwritings obtained immediately after writing and after drying. When the composition is applied to the inner stick type of writing utensils, an ink having good opacifying properties is passed out. The ink composition comprises, at least, an emulsion of styrene resin-based doughnut-shaped flat particles as a white opacifying agent.

Abstract: A flushing vehicle for lithographic inks is the reaction product of a tall oil rosin-modified maleic ester resin with an acid number of less than about 30, and about 2-16 wt. %, based on the weight of the ester, of a polyamide resin with an amine number less than about 110. The flushing vehicle is prepared by heating a reaction mixture containing the rosin-modified ester and the polyamide resin to a temperature of about 190.degree.-280.degree. C.; and holding at a temperature of 190.degree.-280.degree. C. until the viscosity of the reaction mixture becomes constant.

Abstract: An ink is described, comprising an amine having a boiling point of between about 120.degree. C. and about 200.degree. C., an acrylic binder selected to render the ink filterable, a direct dye or acid dye substituted with at least 3 amino groups, and water.

Abstract: A marking device for marking numbers on tickets of games of chance, such as "throw-away" bingo tickets, includes a container having a mouth and a porous applicator body mounted into the mouth. An aqueous, translucent, vibrant colored, substantially freely flowing liquid ink composition is contained in the container, and is applied to the game-of-chance tickets through the porous applicator body. The ink contains, in the aqueous medium, a dyed melamine copolymer resin which is known and available in the trade under the DAYGLO mark. The dyed melamine copolymer pigment provides the unusually bright color to the ink composition of the invention.

Abstract: The invention relates to polyamide resins and to their use as vehicles in the manufacture of printing inks. These poly-amide resins can be obtained by condensation of dimeric fatty acids, monomeric fatty acids, ethylenediamine, and adducts containing amino groups and prepared from aromatic or cycloaliphatic glycidyl ethers and amines containing primary amino groups.

Abstract: A water-soluble dye, free from cellulose reactive groups, of the formula: ##STR1## wherein R.sup.1 is --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H,R.sup.2 is H or --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H, orR.sup.1 and R.sup.2 together with the nitrogen atom form a morpholine ringa and b are different and from 1 to 8m is from 1 to 10;n is from 0 to 9;M is H, ammonium, or a monovalent metal;X (i) NR.sup.1 R.sup.2, (ii) NR.sup.3 R.sup.4, in which R.sup.3 and R.sup.

Abstract: A water-based ink composition for a ball-point pen comprises: a colorant selected from dyes or pigments; a water-soluble organic solvent; water; and a metal salt and/or an amine salt of N-acyl sarcosine. This ink can effectively prevent the wear of a ball seat of the pen caused by the rotation of a ball of the same to make it possible to keep good ink-discharging properties of the pen, whereby a smooth writing of the pen can be performed.

Abstract: Disclosed is an ink jet ink composition comprising a liquid vehicle such as water or ethanol, a dye, and a linear N-hydroxyl substituted polyethyleneimine polymer. In a preferred embodiment, the linear N-hydroxyl substituted polyethyleneimine polymer is selected from the group consisting of linear poly(N-hydroxyethylethyleneimine), linear poly(N-hydroxypropylethyleneimine), and linear poly(N-hydroxymethylethyleneimine). Also disclosed is a process for generating images with the disclosed inks in ink jet printing processes, including continuous stream ink jet printing processes. Further, a process for preparing the linear N-hydroxyl substituted polyethyleneimine polymers included in the inks of the present invention is also disclosed.

Abstract: An ink jet ink composition useful for printing on plain paper at room temperature comprises a colloidal suspension of a nonaqueous solvent (e.g. selected glycol ethers) and dispersed particles comprising a natural resin or synthetic polymer which is insoluble in water but soluble in the solvent at room temperature, and a dyestuff which is soluble in or bindable to the resin or polymer at room temperature but substantially insoluble in the solvent at room temperature. The ink composition is fluid and has a low viscosity at room temperature.

Abstract: An erasable system including a marking element providing a substantially non-porous marking surface and an erasable marking composition for applying markings to the marking surface. The erasable marking composition comprises a dispersion of a particulate film-forming polymeric material and a colorant and preferably also include a water soluble polymer.

Abstract: A process for printing an image on the surface of an article. The process provides a thixotropic thermal curable ink in a recess of a printing plate which is a facsimile of the image to be printed on the article. The ink is adapted to adhere to the printing plate upon contact therewith. The ink is adapted to conform to the facsimile of the image formed in the recess of said printing plate upon application stress to the ink.

Abstract: An ink composition for use in ink jet printing to print images on a vinyl substrate which contains vinyl polymers and plasticizers, the composition being formulated to include a resin component having a pendant amino group, a dye, and a carrier. The composition can be applied to vinyl substrates without fading with time, due to degradation of the printed images by plasticizers present in the vinyl substrate.

Abstract: A phase change ink carrier composition is combined with a compatible colorant to form a phase change ink composition of this invention. A thin film of substantially uniform thickness of that phase change ink carrier composition, and the ink produced therefrom, has a high degree of lightness and chroma. The thin films of a substantially uniform thickness of the ink composition are also rectilinearly light transmissive. The carrier composition is preferably a fatty amide-containing compound.

Abstract: The present invention relates to a typewriter ribbon made up of a flexible thin support and a transferable mass placed on the flexible thin support. The transferable mass comprises a surface-active dispersing agent and a surface-active resin dissolved in a medium-boiling solvent.This ribbon is useful for correctable typing on delicate or treated paper, e.g., photocopied paper.

Abstract: An ink for ink-jet recording is provided which comprises a liquid composition essentially comprised of a coloring matter, a volatile solvent having a vapor pressure of 1 mmHg or more at 25.degree. C., and a material being solid at room temperature and having a molecular weight of 300 or more; and prepared so as to satisfy formula B.sub.1 /A.sub.1 .gtoreq.3, assuming viscosity as A.sub.1 cP at 25.degree. C. measured when the content of the solid material in said composition is 10% by weight, and assuming viscosity as B.sub.1 cP at 25.degree. C. measured when the content of the solid material in said composition is 30% by weight. An ink-jet recording process employing the above mentioned ink is also provided.

Abstract: An ink composition for use in ink jet printing to print images on a vinyl substrate which contains vinyl polymers and plasticizers, the composition being formulated to include a resin component having a pendant amino group, a dye, and a carrier. The composition can be applied to vinyl substrates without fading with time, due to degradation of the printed images by plasticizers present in the vinyl substrate.

Abstract: This invention relates to an erasable ballpoint pen ink before being cured, especially one which can be easily erased by using an eraser directly after it is written on paper, but which, after a longer period of time, becomes cured. The erasable ballpoint pen ink comprises an alcohol soluble pigment, a carrier, solvent and glycerol in such a way that the above mentioned components are in the weight-percentage ratio as follows, when the total weight of the ink is 100%: alcohol soluble pigment 10-20%, carrier 40-70%, solvent 15-35%, and glycerol 3-15%.

Abstract: A wet laid watermark of uncoated paper is simulated by the use of a resin or resin-plasticizer mixture dissolved in a slow evaporating, high boiling solvent. A sufficient quantity of the low viscosity solution is printed onto an uncoated paper sheet of stationary grade by a standard flexographic press to penetrate the paper fiber and deposit a non-tacky solid having a refractive index which closely approximates that of cellulose. The resulting image of the print is visible to both faces of the paper sheet.

Abstract: A marking ink composition comprising a colorant, an organic solvent, a resin soluble in said organic solvent and a decaglycerol fatty acid ester represented by the general formula (1): ##STR1## wherein R is an acyl group or a hydrogen atom. The marking ink composition of the present invention exhibits an excellent resistance to drying of a nib of a pen so that the nib undergoes no significant drying even when the pen is left to stand with its cap removed.

Abstract: A pressurized roller pen includes a thixotropic viscoelastic ink that is a gel at rest, but becomes a thin liquid under the shearing action of the pen's revolving ball-point. This ink includes a polyacrylic resin polymer, at least one highly polar solvent, at least one solvent of low or medium polarity, and colloidal silica, together with pigments, dyes, surfactants and/or pH modifiers.

Abstract: Disclosed is a coloring material including a rubber having a sulfonic acid group or a salt thereof, which is dyed with a basic dye. The coloring material is prepared by adding a solution of an alkali in an alcohol to a solution of a chlorosulfonated polyolefin in an organic solvent and then adding a basic dye to the obtained reaction liquid, or adding a basic dye to a solution of a sulfonated product of a rubber in an organic solvent, and optionally removing the solvent from the obtained solution.

Abstract: Disclosed is a wipe-erasable ink composition for a writing board, which has good erasability and long-period stability. This ink composition comprises a colored polymer formed by dyeing an organic solvent-soluble resin having a sulfonic acid group or a salt thereof with a basic dye, a volatile organic solvent and, as additives, (A) a nonionic surface active agent having an HLB value of 8 to 14 and/or a cationic organic compound, and (B) a slightly volatile or nonvolatile organic compound.

Abstract: A method of printing an electrically conductive thick film ink onto a polymeric substrate. The ink comprises a polymeric binder, which is preferably a fluoropolymer, a solvent for the binder, and an electrically conductive filler. At the printing temperature the solvent is a latent solvent for the binder. After printing the temperature is raised, so that first the binder dissolves in the solvent, and then the solvent vaporizes and the binder cures. The ink may be applied to a conductive polymer, preferably fluoropolymer, substrate and used as a heater.

Abstract: A coloring material comprising a solution of an alcohol-soluble resin having a sulfonic acid group or a salt thereof, which is dyed with a basic dye, in a solvent comprising an alcohol as a main component. The coloring material is prepared either by (a) polymerizing an ethylenically unsaturated sulfonic acid or a salt thereof in water and adding a basic dye to the obtained aqueous liquid of the formed polymer or (b) carrying out said polymerization in the presence of a basic dye, and dissolving (i) the obtained aqueous liquid of the formed colored polymer of (ii) a colored polymer obtained by removing water from the obtained aqueous liquid of the formed colored polymer in a solvent comprising an alcohol as a main component; or, (a') carrying out said polymerization in a solvent comprising an alcohol as a main component and then adding a basic dye to the obtained polymer solution, or (b') carrying out said polymerization in the presence of a basic dye.

Abstract: A water-soluble dye, free from cellulose reactive groups, of the formula: ##STR1## wherein R.sup.1 is --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H,R.sup.2 is H or --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H, orR.sup.1 & R.sup.2 together with the nitrogen atom form a morpholine ringa & b are different and from 1 to 8m is from 1 to 10;n is from 0 to 9;M is H, ammonium, or a monovalent metal;X (i) NR.sup.1 R.sup.2, (ii) NR.sup.3 R.sup.4, in which R.sup.3 and R.sup.

Abstract: Disclosed is a process for the preparation of ink compositions useful for jet printing processes which comprises (1) dissolving in water immiscible organic solvent a polymer composition and an organic oil soluble dye; (2) adding an aqueous phase water surfactant mixture thereto; (3) affecting emulsification thereof; and (4) subsequently evaporating from the aforementioned mixture the solvent thereby resulting in an ink with the dye trapped in the polymer particles suspended in the aqueous phase.

Abstract: Disclosed is a heterophase ink composition comprised of a water insoluble polymer dispersed in a liquid medium, the polymer containing therein an oil soluble dye, and a nonionic stabilizer permanently attached thereto.

Abstract: Disclosed in an ink jet composition comprised of a major amount of water, a hydroxyethylated polyethylenimine polymer, and a dye component wherein the polymer has incorporated therein from about 65 percent by weight to about 80 percent by weight of hydroxyethyl groups.

Abstract: Polyamide condensation products, adaptable to use as antislip agents, formed between 1.5 to 2 equivalent parts of a polymerized fatty acid and 1 equivalent part of an amine component comprising a diprimary ether diamine, optionally together with a co-diamine, and nonslip coating compositions comprising such an antislip agent and a printing ink binder optionally together with solvents, dyes, pigments, antioxidants and the like.

Abstract: There is provided hereby a coloring composition having an excellent water resistance and solution stability, which comprises a reaction mixture of(a) a vinyl compound soluble in water or in a water soluble organic solvent, with(b) a compound which contains more than two groups having a active hydrogen, at least one group of which is an amino group or imino group,in the presence of a water soluble dye and optionally a solvent.

Abstract: An aqueous colored polymer is provided, which comprises (a) a homopolymer of an ethylenically unsaturated sulfonic acid or its salt or (b) a copolymer of an ethylenically unsaturated sulfonic acid or its salt with other ethylenically unsaturated monomer, said homopolymer or copolymer being dyed with a basic dye and having a lowest film-forming temperature of not higher than 35.degree. C. The aqueous colored polymer is prepared by polymerizing an ethylenically unsaturated sulfonic acid or its salt, or its mixture with other ethylenically unsaturated monomer by an aqueous solution or emulsion polymerization procedure at a temperature of not higher than 100.degree. C. in a specified amount of water and then adding a basic dye to the resulting polymer solution or emulsion, or carrying out this solution or emulsion polymerization in the presence of a basic dye. The aqueous polymer is useful as an aqueous ink such as an ink for the ink jet recording.

Abstract: An ink composition for writing or marking on an absorbent or pervious writing surface to provide a writing or marking composed of an inner portion of a first color with outer contour portions therearound of a second color, which composition comprises:a first colorant,a second colorant anda vehicle,said first colorant being dispersed in said vehicle and having a particle size sufficiently large so as to substantially not permeate or be absorbed into said writing surface andsaid second colorant being dispersed or dissolved in said vehicle, being capable of substantially permeating or being absorbed into said writing surface and diffusing into the area on said surface proximate to said writing,whereby said second colorant forms said outer contour portions around said inner portion of said first colorant.

Abstract: In an ink-jet recording process which comprises forming droplets of an ink and recording on an image receiving material by using the droplets, said ink is prepared by dispersing fine particles of pigment into aqueous dispersion medium containing polymer having both a hydrophilic and a hydrophobic construction portion. An average particle size (D micron) of the pigment and an average molecular weight of the polymer satisfy the relationship represented by the following equation.D.times.5.times.10.sup.2 .ltoreq.WAnd the ratio of molecular weight of the pigment to average molecular weight of the polymer is a value in the range from 1:2 to 1:150.

Abstract: Synthetic resins suitable for use in printing ink compositions are described comprising (a) a predominant amount of dicyclopentadiene and lesser amounts of (b) at least one member selected from the group consisting of dimerized aliphatic, cyclic, and non-cyclic dienes of five carbon atoms; debutanized aromatic concentrates; C-5 olefins; acyclic conjugated C-5 dienes; mono-olefins, diolefins and polyenes each having more than five carbon atoms and having no aromatic rings, (c) at least one member selected from the group consisting of tall oil; fatty acid-containing materials and rosin acid-containing materials, (d) at least one ethylenically unsaturated lower aliphatic dicarboxylic acid or anhydride, and (e) at least one member selected from the group consisting of materials containing two or more reactive groups, at least one of which must be a hydroxyl group.

Abstract: Polyamides which are alcohol-soluble at room temperature, are useful in formulating printing inks, and which comprise dimerized fatty acids, at least one aliphatic unbranched monocarboxylic acid and at least one aliphatic branched monocarboxylic acid as the acid component, and ethylenediamine and hexamethylenediamine as the amine component, and printing inks formulated therefrom.