Fluorocarbon Resin Patents (Class 264/127)
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Patent number: 11439958Abstract: A porous polytetrafluoroethylene (PTFE) membrane of the present disclosure has a water vapor permeability, as measured according to Japanese Industrial Standard (JIS) L 1099 (method B-1), of 150000 g/(m2·day) or more in a thickness direction of the membrane. The porous PTFE membrane of the present disclosure, when attached as a waterproof air-permeable membrane to a housing of an electrical component or electrical device, allows water vapor residing inside the housing to be quickly discharged out of the housing.Type: GrantFiled: December 18, 2017Date of Patent: September 13, 2022Assignee: NITTO DENKO CORPORATIONInventors: Teppei Tezuka, Youzou Yano, Kazuhiro Omura, Tomoyuki Kasagi
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Patent number: 11260637Abstract: A sheet containing a carbon fiber and a fluororesin layer disposed around a carbon monofilament constituting the carbon fiber. A fluororesin constituting the fluororesin layer is polyvinylidene fluoride. Further, the sheet has a tensile strength of 400 MPa or higher. Also disclosed is a laminate including a first layer and a second layer that is disposed on the first layer and that includes the sheet; a pipe including the laminate; a riser tube including the pipe and a flowline including the pipe.Type: GrantFiled: March 7, 2018Date of Patent: March 1, 2022Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Yuuki Kuwajima, Hayato Tsuda
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Patent number: 11242630Abstract: A wettable, dispersion spun fluoropolymer fiber prepared from non-melt-processible fluoropolymer particles.Type: GrantFiled: March 23, 2016Date of Patent: February 8, 2022Assignee: Toray Fluorofibers (America), Inc.Inventors: Arthur Nelson, Taigi Yokota, Dung Trieu, Trevor Guldstrand, Matthew Hutto
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Patent number: 11155935Abstract: A method for forming porous fibers is provided. The fibers are formed from a thermoplastic composition containing a continuous phase, which includes a matrix polymer, and a nanoinclusion additive that is at least partially incompatible with the matrix polymer so that it becomes dispersed within the continuous phase as discrete nano-scale phase domains. The method generally includes traversing a bundle of the fibers over one or more draw bars that are in contact with a fluidic medium (e.g., water). In certain embodiments, for example, the draw bar(s) are submerged in the fluidic medium. The fluidic medium is lower than the melting temperature of the matrix polymer.Type: GrantFiled: December 9, 2016Date of Patent: October 26, 2021Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Neil T. Scholl, Vasily A. Topolkaraev, Antonio J. Carrillo Ojeda, Ryan J. McEneany, Theodore T. Tower
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Patent number: 10799617Abstract: Fibrous materials and methods of manufacturing fibrous materials are disclosed. In particular, this application discloses methods of making and processing serially deposited fibrous structures, such as serially deposited fibrous mats. Serially deposited fibrous mats may be used in implantable medical devices with various characteristics and features. Serially deposited fibrous mats of various mat thickness, fiber size, porosity, pore size, and fiber density are disclosed. Additionally, serially deposited fibrous mats having various amounts of fiber structures (such as intersections, branches, and bundles) per unit area are also disclosed.Type: GrantFiled: March 12, 2014Date of Patent: October 13, 2020Assignee: Merit Medical Systems, Inc.Inventors: Wayne L. Mower, John William Hall, Rachel L. Simmons, Bart Dolmatch, F. Mark Ferguson
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Patent number: 10759887Abstract: An electric wire and coil covered with a cured product of a heat- or photo-curable fluorinated polymer and having high insulating properties and high productivity. An electric wire having a conductor wire and a covering layer covering the outer periphery of the conductor wire. The covering layer is made of a cured product of a curable composition which has a fluorinated polymer containing at least three functional groups represented by the following formula (F): —Rf1COZ1 (F). In formula (F), Rf1 is a single bond, a fluoroalkylene group, or a fluoroalkylene group with at least two carbon atoms having an etheric oxygen atom between carbon-carbon atoms, Z1 is NR1NR2H, NR3OR4 or OR5, and R1, R2, R3, R4 and R5 are each independently a hydrogen atom or an alkyl group.Type: GrantFiled: June 26, 2019Date of Patent: September 1, 2020Assignee: AGC Inc.Inventors: Masahiro Ohkura, Norihide Sugiyama
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Patent number: 10537836Abstract: A filter medium for an air filter includes a pre-collection member, a first porous film, and a second porous film arranged in order from the side that is upstream of the air current. Each of the first porous film and the second porous film has a pressure loss of 30 Pa or more and 90 Pa or less when air is passed through each porous film at a flow rate of 5.3 cm/s, and has a collection efficiency of 95% or more and 99.9% or less for NaCl particles having a particle diameter of 0.3 ?m when air containing the NaCl particles is passed through each of the porous films at a flow rate of 5.3 cm/s. The pre-collection member has a pressure loss of 5 Pa or more and less than 55 Pa when air is passed through the pre-collection member at a flow rate of 5.3 cm/s, has a collection efficiency of 15% or more and less than 85% for NaCl particles having a particle diameter of 0.3 ?m when air containing the NaCl particles is passed through the pre-collection member at a flow rate of 5.3 cm/s, and has a thickness of more than 0.Type: GrantFiled: March 8, 2017Date of Patent: January 21, 2020Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Tatsumi Sakano, Kunihiko Inui, Yoshiyuki Shibuya, Hideyuki Kiyotani
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Patent number: 10377866Abstract: Fluoropolymer articles having a high surface roughness and high coarseness are provided. In one embodiment, a fiber is provided that has a surface roughness expressed as a peak-to-valley distance (Rt) greater than 10 micrometers and an average surface roughness (Ra) greater than 1.5 micrometers. In another embodiment, a membrane having a coarseness index ?/EBP of at least 0.3 g/cm3/psi and an air permeability of 15 ft3/ft2/min or higher is provided. The fluoropolymer articles are produced by a process that includes forming a paste-formed fluoropolymer product at a temperature lower than 50° C., densifying the paste-formed product, and then stretching the dens Pied paste-formed fluoropolymer product in at least one direction. In exemplary embodiments, the fluoropolymer may be polytetrafluoroethylene (PTFE), a modified PTFE, a TFE copolymer, a fluorothermoplastic, a fluoroelastomer, or combinations thereof.Type: GrantFiled: October 11, 2013Date of Patent: August 13, 2019Assignees: W. L. Gore & Associates, Inc., W. L. Gore & Associates GmbHInventors: Michael Wendlandt, Wolfgang Bürger, John William Dolan
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Patent number: 10376331Abstract: Sheaths for medical instruments cover wrist mechanisms to provide a barrier to infiltration of biological material into the instrument, electrical isolation of energized portions of the instrument, seal the instrument to help maintain cavity pressure within a patient, or reduce the chance that two jointed instruments will tangle during a medical procedure.Type: GrantFiled: July 8, 2010Date of Patent: August 13, 2019Assignee: Intuitive Surgical Operations, Inc.Inventors: Thomas G. Cooper, S. Christopher Anderson, Matthew R. Williams
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Patent number: 10138161Abstract: The present invention pertains to a process for manufacturing a fluoropolymer composite, said process comprising the following sequential steps: (i) providing an aqueous latex comprising from 10% to 40% by weight, preferably from 15% to 35% by weight of at least one fluoropolymer comprising recurring units derived from vinylidene fluoride (VDF) [polymer (VDF)]; (ii) up-concentrating the aqueous latex provided in step (i) thereby providing an up-concentrated aqueous latex comprising from 45% to 60% by weight, preferably from 45% to 55% by weight of at least one polymer (VDF); (iii) contacting one continuous fiber or a bunch of continuous fibers with the up-concentrated aqueous latex provided in step (ii); (iv) squeezing the impregnated fibrous material provided in step (iii); (v) drying the squeezed fibrous material provided in step (iv), typically at a temperature comprised between 100° C. and 120° C.; (vi) baking the dried fibrous material provided in step (v) at a temperature comprised between 190° C.Type: GrantFiled: May 29, 2014Date of Patent: November 27, 2018Assignee: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.Inventors: Eliana Ieva, Rui Liu, Elisabetta Sartirana
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Patent number: 10030157Abstract: In one aspect, microporous membranes are described herein demonstrating composite architectures and properties suitable for electronic and/or optical applications. In some embodiments, a composite membrane described herein includes a microporous polymeric matrix or substrate having an interconnected pore structure and an index of refraction and an electrically conductive coating deposited over one or more surfaces of the microporous polymeric matrix. In other embodiments, the pores are filled and the membranes are substantially transparent.Type: GrantFiled: April 15, 2015Date of Patent: July 24, 2018Assignee: Celgard, LLCInventors: Karl F. Humiston, Kristoffer K. Stokes
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Patent number: 10004832Abstract: A method to make a PTFE skived film capable of exhibiting, with a single layer, sliding properties, barrier properties with regard to a liquid contact surface, and excellent tear resistance during injection molding. This skived film is obtained by cutting a polytetrafluoroethylene block or a modified polytetrafluoroethylene block subjected to a thermal fusion treatment under reduced pressure or subjected to a pressurized thermal fusion treatment after being subjected to fusion under reduced pressure.Type: GrantFiled: January 5, 2016Date of Patent: June 26, 2018Assignee: COKI ENGINEERING INC.Inventor: Akira Yotsutsuji
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Patent number: 9988758Abstract: Woven and knit fabrics containing expanded polytetrafluoroethylene (ePTFE) fibers and at least one other fiber are provided. The ePTFE fiber may be woven or knit as a single, non-twisted fiber, as part of a multifilament fiber, or may be twisted or braided with another fiber. The ePTFE fiber, whether alone or in combination with a weave fiber(s), may be utilized in either the warp and/or the weft direction. The woven and knit fabrics are concurrently breathable, lightweight, durable, drapable, and fast drying. The ePTFE fibers have a substantially rectangular configuration. In some embodiments, the woven or knit fabric is flame resistant. In addition, the woven and knit fabrics are quiet, soft, and drapable. Treatments may be provided to the surface of the ePTFE fiber and/or the fabrics to impart one or more desired functionality, such as, for example, oleophobicity, anti-microbial, contamination resistance, or UV stability.Type: GrantFiled: December 14, 2015Date of Patent: June 5, 2018Assignee: W. L. Gore & Associates, Inc.Inventors: David J. Minor, Mustafa Arifoglu, Raymond B. Minor
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Patent number: 9963564Abstract: A modified fluorine-containing copolymer obtained by irradiating a copolymer with radiation at a temperature of not higher than the melting point of the copolymer. The copolymer includes at least one copolymer selected from a copolymer including a tetrafluoroethylene unit and a perfluoro(alkyl vinyl ether) unit and a copolymer including a tetrafluoroethylene unit and a hexafluoropropylene unit, and has 10 to 10000 functional groups in total per 106 carbon atoms.Type: GrantFiled: December 19, 2014Date of Patent: May 8, 2018Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Hitoshi Imamura, Takahisa Aoyama, Hideki Kono, Tatsuya Funaoka, Hirokazu Itou
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Patent number: 9909637Abstract: A damper device includes a stator, a rotor, and a viscous fluid imparting a resistance to a rotation or a relative rotation of the rotor, and forms a braking force by the resistance. In the rotor, an annular seal portion made of soft synthetic resin is provided by integral molding. The stator includes an annular space in which the viscous fluid is filled, and a main member portion of the rotor is housed in the annular space. The annular seal portion comprises an outside annular portion provided in an outer circumferential portion of the rotor; an inside annular portion provided in an inner circumferential portion of the rotor; and a connection portion therebetween.Type: GrantFiled: January 28, 2015Date of Patent: March 6, 2018Assignee: NIFCO INC.Inventor: Makoto Muranaka
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Patent number: 9819040Abstract: A printed fuel cell having integrated gas channels, and having an anode layer, where a first gas diffusion electrode layer is periodically fixed to the anode layer, wherein the periodically fixed first gas diffusion electrode layer defines hydrogen flow field channels. A first catalyst material is coated or infused to the first gas diffusion electrode layer. An electrolyte membrane covers portions of the anode layer and first gas diffusion electrode layer with the first catalyst material. A second catalyst material is coated or infused to the electrolyte membrane. A second gas diffusion electrode layer is in operative association with the electrolyte membrane and second catalyst material, on a surface of the electrolyte membrane different from a surface of the electrolyte membrane which is in contact with the first gas diffusion electrode layer, and a perforated cathode is in contact with the second gas diffusion electrode layer.Type: GrantFiled: January 22, 2013Date of Patent: November 14, 2017Assignee: PALO ALTO RESEARCH CENTER INCORPORATEDInventor: Karl A. Littau
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Patent number: 9728299Abstract: The present invention provides a material based on high density polytetrafluoroethylene (PTFE) and its applications, such as in the production of electric cable. The PTFE material of the invention includes PTFE, a metal oxide, a lubricant and a wetting agent.Type: GrantFiled: June 30, 2011Date of Patent: August 8, 2017Assignee: PRODUITS PLASTIQUES PERFORMANTS HOLDING—3P HOLDINGInventors: David Cade, Emmanuel Garraud
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Patent number: 9631589Abstract: It has been discovered that the function of a fuel filter monitor can be accomplished without the use of SAP. The present invention provides a fuel filter monitor comprising an ePTFE membrane, a support structure adjacent to said ePTFE membrane wherein the membrane is disposed upstream of the support and said monitor prevents penetration of water to the downstream of said fuel wet monitor, where the water can be in the form of discrete water drops in the fuel, or a bulk water stream which displaces the upstream fuel.Type: GrantFiled: October 9, 2013Date of Patent: April 25, 2017Assignee: W. L. Gore & Associates, Inc.Inventor: Gary P. Harp
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Patent number: 9630806Abstract: A method for constructing an interface between a sheave and a coated belt or rope of an elevator system, includes determining the surface energy of a surface of a coated belt or rope; and selecting a sheave such that the sheave has a work of adhesion between the coated belt or rope and the sheave, the work of adhesion meeting a defined relationship with a work of adhesion threshold.Type: GrantFiled: May 16, 2012Date of Patent: April 25, 2017Assignee: OTIS ELEVATOR COMPANYInventors: John P. Wesson, Xiaomei Yu, David R. Polak
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Patent number: 9601820Abstract: A dielectric waveguide interconnect system has a dielectric waveguide (DWG) a core surrounded by a cladding along the length of the DWG. One or more periodic structures are embedded along the length of the DWG such that the core of the DWG is integral to each of the one or more periodic structures.Type: GrantFiled: December 22, 2014Date of Patent: March 21, 2017Assignee: TEXAS INSTRUMENTS INCORPORATEDInventors: Juan Alejandro Herbsommer, Benjamin S. Cook
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Patent number: 9480953Abstract: The present invention provides a composite filter media for use in a fuel stream wherein the composite media provides significantly improved resistance to water penetration as indicated by the FWWPP normalized for fuel IFT and a reduced resistance to flow of the fuel stream as indicated by the Ratio of Resistances.Type: GrantFiled: October 9, 2013Date of Patent: November 1, 2016Assignee: W. L. Gore & Associates, Inc.Inventor: Gary P. Harp
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Patent number: 9462681Abstract: A conductive film includes a base film, a primer layer formed on the base film, the primer layer having voids, and a conductive layer formed on the primer layer. The conductive layer includes a conductor that contains a nano-material forming a network structure.Type: GrantFiled: March 4, 2014Date of Patent: October 4, 2016Assignee: LG Electronics Inc.Inventors: Yangwook Hur, Jeyong Moon
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Patent number: 9446344Abstract: The invention describes a method for enriching at least one component from a gaseous mixture of substances, comprising the steps of (i) contacting a flow of a first gaseous mixture of substances which contains at least one component to be enriched, with a composite material at a first pressure p1 such that the at least one component to be enriched is adsorbed to the composite material and a charged composite material is obtained, said composite material comprising (a) a porous matrix of a fluorine-containing polymer having a percentage of tetrafluoroethylene monomer units of at least 95 mol % based on the total number of monomer units and (b) zeolite particles which are embedded in the matrix and around which matrix filaments extend; (ii) disrupting the flow of the gaseous mixture of substances and (iii) desorbing the at least one component to be enriched from the charged composite material by reducing the pressure to a pressure p2, with p1?p2?200 mbar, such that a second gaseous mixture of substances is prodType: GrantFiled: June 1, 2012Date of Patent: September 20, 2016Assignee: CLARIANT PRODUKTE (DEUTSCHLAND) GMBHInventors: Achim Koch, Michael Zavrel, Christoph Kröhnke, Ulrich Kettling
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Patent number: 9421499Abstract: The invention offers a microporous modified-polytetrafluoroethylene membrane that is a microporous membrane having a significantly small pore diameter and narrow pore-diameter distribution and that can remove microscopic foreign particles at high efficiency when used as a filtration membrane.Type: GrantFiled: January 21, 2013Date of Patent: August 23, 2016Assignee: SUMITOMO ELECTRIC FINE POLYMER, INC.Inventors: Fumihiro Hayashi, Aya Oya, Atsushi Uno
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Patent number: 9175777Abstract: A flow controller is provided. The controller includes a shell body, a first supporting member, a driving shaft and an elliptical valve. The shell body has a passage passed therethrough. The first supporting member is assembled to the shell body. The driving shaft is assembled to the first supporting member. The elliptical valve is pivotally assembled in the passage and is connected with the driving shaft. The elliptical valve is rotated by the driving shaft for opening or closing the passage. When the passage is closed by the elliptical valve, the elliptical valve tightly abuts against an inner circular wall of the shell body for completely closing the passage, so that the controller is suitable in a high temperature and high pressure environment.Type: GrantFiled: December 18, 2014Date of Patent: November 3, 2015Inventors: Jun-Chien Chen, Chien-Yu Liu
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Patent number: 9174174Abstract: A separation membrane including a separation-functional layer is provided, wherein the separation-functional layer contains a polyvinylidene fluoride-type resin having a melt viscosity of 3,300 Pa·s or more, and also the separation-functional layer has a three-dimensional network structure. A separation membrane is provided having high virus removal performance, high pure water permeability, and high physical durability and high chemical strength, which can also be used in the field of water treatment.Type: GrantFiled: September 18, 2009Date of Patent: November 3, 2015Assignee: Toray Industries, Inc.Inventors: Kenji Komori, Toshiyuki Ishizaki, Kenta Iwai, Xunyao Fu, Shinichi Minegishi, Nao Minaki
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Patent number: 9074084Abstract: Blended fluoropolymer compositions are provided, in which a liquid dispersion of a first fluoropolymer is blended with a liquid dispersion of a second fluoropolymer. The first fluoropolymer may be polytetrafluoroethylene (PTFE), such as a low molecular weight PTFE (LPTFE) in the form of an aqueous dispersion having a mean particle size of less than 1.0 microns (?m) and a first melt temperature (Tm) of 332° C. or less. The second fluoropolymer may be a melt processable fluoropolymer (MPF), such as methylfluoroalkoxy (MFA), fluorinated ethylene propylene (FEP), or perfluoroalkoxy (PFA), for example, in the form of an aqueous dispersion having a mean particle size of less than 1.0 microns (?m). When the blended fluoropolymer composition is dried, a crystal structure representing a true alloy of the fluoropolymers is formed, having melt characteristics that differ from those of the individual fluoropolymers.Type: GrantFiled: November 15, 2011Date of Patent: July 7, 2015Assignee: Whitford CorporationInventors: Leonard W. Harvey, Michael Coates, Julie K. Wright
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Patent number: 8840824Abstract: Single, continuous PTFE layers having lateral zones of varied characteristics are described. Some of the lateral zone embodiments may include PTFE material having little or no nodal and fibril microstructure. Methods of manufacturing PTFE layers allow for controllable permeability and porosity of the layers, in addition to other characteristics. The characteristics may vary from one lateral zone of a PTFE layer to a second lateral zone of a PTFE layer. In some embodiments, the PTFE layers may act as a barrier layer in an endovascular graft or other medical device.Type: GrantFiled: October 22, 2010Date of Patent: September 23, 2014Assignee: Trivascular, Inc.Inventors: Joseph W. Humphrey, Jeffry B. Skiba
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Patent number: 8784710Abstract: A method of making an expanded polytetrafluoroethylene (ePTFE) membrane including the steps of: providing an unsintered or partially sintered ePTFE membrane; matting the unsintered or partially sintered ePTFE membrane; and immediately thereafter, sintering the matted ePTFE membrane. A method for making ePTFE tubes includes the steps of: providing an unsintered or partially sintered ePTFE membrane; wrapping the ePTFE membrane around a mandrel or form tool to form an ePTFE tube; matting the ePTFE tube; immediately thereafter, sintering the matted ePTFE tube; and removing the sintered ePTFE tube from the mandrel or form tool.Type: GrantFiled: March 18, 2010Date of Patent: July 22, 2014Assignee: Phillips Scientific Inc.Inventors: Douglas R. Hansen, James V. Phillips
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Patent number: 8728372Abstract: Thin PTFE layers are described having little or no node and fibril microstructure and methods of manufacturing PTFE layers are disclosed that allow for controllable permeability and porosity of the layers. In some embodiments, the PTFE layers may act as a barrier layer in an endovascular graft or other medical device.Type: GrantFiled: October 29, 2010Date of Patent: May 20, 2014Assignee: TriVascular, Inc.Inventors: Joseph W. Humphrey, Jeffrey B. Skiba
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Patent number: 8728993Abstract: A PTFE-based composite material includes a PTFE major phase filled with a metal oxide minor phase. The major phase is intermixed with the metal oxide minor phase, wherein the minor phase includes a plurality of irregularly shaped metal oxide nanoparticles. The irregularly shaped nanoparticles provide substantial reductions in steady state wear rate over otherwise similar nanocomposites. The metal oxide can comprise aluminum oxide.Type: GrantFiled: January 11, 2013Date of Patent: May 20, 2014Assignee: University of Florida Research Foundation, Inc.Inventors: W. Gregory Sawyer, David L. Burris
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Patent number: 8715559Abstract: A tetrafluoroethylene resin molded article obtained by fusing PTFE by heating a tetrafluoroethylene resin by heating, and then executing a gradual cooling or a cooling including a holding at a temperature equal to or higher than 313° C. and lower than 321° C. for 10 minutes or longer, and having, when heated to 365° C., then cooled to 245° C. with a rate of ?1° C./min, and then heated to 365° C. with a rate of 10° C./min, a heat of fusion which, within a range from 296 to 343° C., is equal to or larger than 32 J/g and less than 47.8 J/g, a porous article obtained by expanding the molded article, and a composite article, a filter, an impact deformation absorber and a sealing material utilizing the molded article or the porous article.Type: GrantFiled: September 8, 2006Date of Patent: May 6, 2014Assignee: Sumitomo Electric Fine Polymer, Inc.Inventors: Fumihiro Hayashi, Shinichi Kanazawa, Atsushi Uno, Akira Udagawa, Shigetoshi Ikeda, Toshiaki Yagi
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Patent number: 8685424Abstract: A method of preparing antimicrobial-containing polymeric products is provided, the method involving electrospinning a dispersion comprising a dispersible polymer, a fiberizing polymer, and one or more antimicrobial agents. The electrospun material is heated to remove solvent and the fiberizing polymer, giving a nonwoven polymeric material having antimicrobial agent incorporated therein. The material can be in the form of, for example, a non-woven sheet, tube, or covering.Type: GrantFiled: October 13, 2011Date of Patent: April 1, 2014Assignee: Zeus Industrial Products, Inc.Inventors: Robert L. Ballard, Bruce L. Anneaux, Joshua L. Manasco
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Patent number: 8628843Abstract: The present invention provides sintered composite polymeric materials and methods of making and using the same. The sintered composite polymeric materials are made by sintering composite particles comprising a polytetrafluoroethylene component and a carbonaceous component, wherein the carbonaceous component is dispersed throughout the polytetrafluoroethylene component.Type: GrantFiled: October 23, 2009Date of Patent: January 14, 2014Assignee: Porex CorporationInventor: Andrew James MacLennan
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Patent number: 8609249Abstract: A method for making a thin walled ePTFE tube having improved axial and radial strength includes the steps of: providing an unsintered or partially sintered ePTFE membrane; wrapping the ePTFE membrane around a mandrel or form tool to form an ePTFE tube; matting the ePTFE tube; immediately thereafter, sintering the matted ePTFE tube; removing the sintered ePTFE tube from the mandrel or form tool; stretching the sintered ePTFE tube in the axial direction; stretching the ePTFE tube in the radial direction over a second mandrel that is greater in diameter than the reduced axially stretched diameter, but less than the first mandrel diameter; overwrapping the second mandrel with a second ePTFE membrane; matting the ePTFE tube; immediately thereafter, sintering the matted ePTFE tube; and removing the sintered ePTFE tube from the second mandrel or form tool.Type: GrantFiled: July 20, 2011Date of Patent: December 17, 2013Assignee: Phillips Scientific Inc.Inventors: Douglas R. Hansen, James V. Phillips
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Patent number: 8383561Abstract: A PTFE-based composite material includes a PTFE major phase filled with a metal oxide minor phase. The major phase is intermixed with the metal oxide minor phase, wherein the minor phase includes a plurality of irregularly shaped metal oxide nanoparticles. The irregularly shaped nanoparticles provide substantial reductions in steady state wear rate over otherwise similar nanocomposites. The metal oxide can comprise aluminum oxide.Type: GrantFiled: August 24, 2010Date of Patent: February 26, 2013Assignee: University of Florida Research Foundation, inc.Inventors: W. Gregory Sawyer, David L. Burris
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Patent number: 8377352Abstract: A medical catheter tube containing a tetrafluoroethylene polymer, which has a wall thickness of 0.1 mm or below and exhibits a tensile strength (S1) at 1.0 mm displacement of 5.0 N/mm or above; and a process for the production of medical catheter tubes, characterized by molding a composition both a tetrafluoroethylene polymer and a lubricant having high affinity for the polymer by paste extrusion. The invention provides thin-wall medical catheter tubes excellent in elongation resistance, kink resistance and internal cavity lubricity.Type: GrantFiled: March 29, 2011Date of Patent: February 19, 2013Assignee: Kaneka CorporationInventors: Satoshi Inamoto, Fumihiko Nakao, Mitsuharu Korogi, Tsuyoshi Mihayashi
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Patent number: 8354619Abstract: An electric wire comprises a non-oxidized conductor of copper alloy having no outer coating and in direct contact with a PTFE-based sheath. It is fabricated as follows: providing a copper alloy conductor without an outer coating; forming a sheath of a PTFE-based material around the conductor; and heating the wire in order to evaporate the lubricant and sinter the sheath. In order to avoid oxidizing the copper during the heating step, the wire is heated mainly in an atmosphere having a low oxygen content. The lubricant evaporation and/or sintering line for stabilizing the sheath of the electric wire comprises one or more ovens, each having an enclosure in which an atmosphere having a low oxygen content is maintained.Type: GrantFiled: July 12, 2010Date of Patent: January 15, 2013Assignee: Axon'CableInventor: Sophie Perez
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Patent number: 8298462Abstract: This invention relates to a method of uniaxially expanding a fluoropolymer product including the steps of expanding a green fluoropolymer product in a first direction to create a first-expanded fluoropolymer product, and expanding the first-expanded fluoropolymer product in the same first direction. As a result with the subject invention, it has been found that ultra-high expansion and a variety of different porous/fibril structures can be achieved by using subsequent expansion steps in the same direction. Various considerations exist with such methodology, including the selection of rates of expansion of both steps, the amount of expansion of both steps, pre-heating and cutting the product between expansion steps. Although the present invention can be used with various fluoropolymer products, it is particularly well-suited for use with PTFE.Type: GrantFiled: December 30, 2004Date of Patent: October 30, 2012Assignee: Boston Scientific Scimed, Inc.Inventors: Michael Luk, Jeff Sewell, Jason Hill
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Patent number: 8231974Abstract: A fluoropolymer molding method and the resulting molded article are disclosed where the fluoropolymer is composed of fluoropolymer particles each having a multi-layer structure that consists of at least two types of fluoropolymers having different melting points, with at least one inner layer made of a fluoropolymer with a melting point higher than that of the outermost fluoropolymer. The fluoropolymer of the at least one inner layer is molded at a temperature higher than the melting point of the lowest melting point of the fluoropolymers that form the outermost layers of the multi-layer-structure fluoropolymer particles, and lower than the melting point of the fluoropolymer having the highest melting point. The resulting articles have excellent chemical liquid resistance and gas impermeability and low linear expansion coefficient.Type: GrantFiled: March 15, 2012Date of Patent: July 31, 2012Assignee: Dupont Mitsui Fluorochemicals Co LtdInventor: Takao Nishio
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Patent number: 8187534Abstract: The present invention provides porous barrier compositions comprising color change indicators and methods of making and using the same.Type: GrantFiled: February 12, 2008Date of Patent: May 29, 2012Assignee: Porex CorporationInventor: Guoqiang Mao
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Patent number: 8178030Abstract: An improved process for forming a PTFE mat is described. The process includes providing a dispersion with PTFE, a fiberizing polymer and a solvent wherein said dispersion has a viscosity of at least 50,000 cP. An apparatus is provided which comprises a charge source and a target a distance from the charge source. A voltage source is provided which creates a first charge at the charge source and an opposing charge at the target. The dispersion is electrostatically charged by contact with the charge source. The electrostatically charged dispersion is collected on the target to form a mat precursor which is heated to remove the solvent and the fiberizing polymer thereby forming the PTFE mat.Type: GrantFiled: January 19, 2010Date of Patent: May 15, 2012Assignee: Zeus Industrial Products, Inc.Inventors: Bruce L. Anneaux, Robert Ballard, David P. Garner
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Patent number: 8158041Abstract: Extruded, stretched, sintered tubular PTFE materials are produced which are suited for use in the medical field as liners and covers for expandable stents. The PTFE materials have an unusually low REC (Radial Expansion Coefficient) and RER (Radial Expansion Ratio).Type: GrantFiled: December 28, 2007Date of Patent: April 17, 2012Assignee: Bard Peripheral Vascular, Inc.Inventor: William M. Colone
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Patent number: 8158260Abstract: A fluoropolymer molding method and the resulting molded article are disclosed where the fluoropolymer is composed of fluoropolymer particles each having a multi-layer structure that consists of at least two types of fluoropolymers having different melting points, with at least one inner layer made of a fluoropolymer with a melting point higher than that of the outermost fluoropolymer. The fluoropolymer of the at least one inner layer is molded at a temperature higher than the melting point of the lowest melting point of the fluoropolymers that form the outermost layers of the multi-layer-structure fluoropolymer particles, and lower than the melting point of the fluoropolymer having the highest melting point. The resulting articles have excellent chemical liquid resistance and gas impermeability and low linear expansion coefficient.Type: GrantFiled: May 29, 2007Date of Patent: April 17, 2012Assignee: Dupont Mitsui Fluorochemicals Co LtdInventor: Takao Nishio
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Patent number: 8153041Abstract: To provide a membrane capable of efficiently collecting fine particles for a long period of time, disclosed is a polytetrafluoroethylene microporous membrane wherein the mean pore size in the surface of the membrane is larger than the mean pore size in the back thereof and the mean pore size continuously changes from the surface toward the back.Type: GrantFiled: November 11, 2010Date of Patent: April 10, 2012Assignee: FUJIFILM CorporationInventors: Hidetaka Okada, Kouhei Kawahara, Toshiki Taguchi
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Patent number: 8141717Abstract: The present invention provides sintered polymeric materials and methods of making the same which are useful in a variety of applications. In one embodiment, the present invention provides a sintered polymeric material comprising at least one plastic and at least one elastomer.Type: GrantFiled: August 20, 2007Date of Patent: March 27, 2012Assignee: Porex CorporationInventors: James P. Wingo, Michael E. Witover, Guoqiang Mao, Andre Maertens, Gerald Kunth, Daniel George Fullerton, Ike Iaokim Haldopoulos, Take Huat Tan, Deborah B. Reed
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Patent number: 8007700Abstract: An electric cable for conveying signals, the cable having a diameter of less than 2 mm and comprising at least one conductor in an insulating sheath, the sheath having a dielectric constant ? of less than 1.7. To achieve this, the sheath is made of PTFE and it includes at least one continuous cell.Type: GrantFiled: August 1, 2008Date of Patent: August 30, 2011Assignee: Axon'CableInventor: Sophie Perez
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Patent number: 7985361Abstract: A process for dispersion spinning non-melt-processible fluoropolymer fiber in which a mixture of an aqueous dispersion of non-melt-processible polytetrafluoroethylene or modified polytetrafluoroethylene fluoropolymer particles and an aqueous solution of matrix polymer is formed. The non melt-processible particles have an SSG of less than about 2.40. The aqueous dispersion contains an aliphatic alcohol ethoxylate nonionic surfactant having a 20% residuals temperature determined by thermogravimetric analysis (TGA) of less than about 290° C. and is essentially free of surfactants containing aromatic groups. The dispersion has a fluorinated surfactant content of less than about 300 ppm. The mixture is extruded into a coagulation bath containing a concentration of ions which coagulate the matrix polymer to form an intermediate fiber structure. The intermediate fiber structure is sintered to decompose the matrix polymer and coalesce.Type: GrantFiled: May 21, 2008Date of Patent: July 26, 2011Assignee: E. I. du Pont de Nemours and CompanyInventors: Devin Flowers, Clay Woodward Jones, Robert John Cavanaugh
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Patent number: 7976751Abstract: An expanded porous polytetrafluoroethylene film having residual strain of at most 11.0% as measured after a load required to indent a rod, which is in a columnar form that its outer diameter is at least 2 mm and at least 1.9 times as much as the thickness of the film, and has a smooth plane perpendicular to its axis at a free end surface thereof and a modulus of longitudinal elasticity of at least 1.0×104 kgf/mm2, up to 20% of the film thickness at a strain rate of 100%/min from the free end surface is applied repeatedly 20 times, and a production process of the porous film, in which a step of compressing an expanded porous polytetrafluoroethylene film having a high draw ratio is provided.Type: GrantFiled: February 19, 2009Date of Patent: July 12, 2011Assignee: Sumitomo Electric Industries, Ltd.Inventors: Fumihiro Hayashi, Yasuhiro Okuda
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Patent number: 7942275Abstract: A method of making a porous membrane includes, in an exemplary embodiment, mixing together a first fine powder PTFE resin and a second fine powder PTFE resin to form a PTFE resin mixture. The first PTFE resin having a characteristic of forming more and longer fibrils than fibrils formed from the second PTFE resin. The second PTFE resin having a characteristic of forming thicker nodes than nodes formed from the first PTFE resin. The method also includes forming a preform from the PTFE resin mixture, extruding the preform into a tape, passing the tape through a plurality of opposing calender rolls to form a calendered tape having a thickness of about 380 ?m to about 1200 ?m, and stretching the calendered tape in the transverse direction to form a porous membrane having a plurality of nodes and fibrils and having a thickness of at least about 100 ?m.Type: GrantFiled: July 8, 2008Date of Patent: May 17, 2011Assignee: BHA Group, Inc.Inventor: Gopakumar Thottupurathu