Disparate Treatment Of Article Subsequent To Working, Molding, Or Shaping Patents (Class 264/232)
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Publication number: 20030046896Abstract: The present invention relates to a method of manufacturing an ocherous panel for use as an interior building material that has excellent insulating properties and that is superior to conventional building materials such as cement, concrete, rock wool and soundproofing boards in strength, fire resistance and soundproofing, and interior aesthetic appeal. The method according to the present invention is characterized in that it uses about 45 wt % of ocher, about 45 wt % of sawdust and about 10 wt % of sodium silicate liquid instead of the composition that was used in the prior art which caused contamination of the air and decomposition of the panel due to absorption of moisture in the air.Type: ApplicationFiled: August 27, 2002Publication date: March 13, 2003Inventors: Jae Seon Chang, Myung Ja Chun
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Patent number: 6517752Abstract: A surface reforming method for a plastic molded product of this invention is characterized by comprising a step (a) for immersing a plastic molded product into supercritical carbon dioxide or subcritical carbon dioxide under a temperature lower than the glass transition temperature of said plastic, and a step (b) for vaporizing carbon dioxide adhered to the surface of the plastic molded product under a temperature lower than the glass transition temperature of said plastic. A plastic molded product may be composed of a polymer having a polar group.Type: GrantFiled: September 19, 2000Date of Patent: February 11, 2003Assignee: Daicel Chemical Industries, Ltd.Inventors: Masanori Hiraishi, Hiroshi Takahashi
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Publication number: 20030020198Abstract: A new shaped activated carbon and the method of its manufacture are disclosed. The invention resides in the crosslinking of a polymeric cellulose, such as sodium carboxymethylcellulose (CMC), within the carbon bodies after they are shaped, employing the CMC as a binder for the activated carbon. The approach to attain product mechanical strength and water stability by crosslinking rather than high temperature heat treatment is not obvious from the prior art teaching. The crosslinking reaction occurs at temperatures below 270° C. In addition, this new binder technology produces shaped carbon bodies having key properties beyond the best level that has been accomplished with other binders.Type: ApplicationFiled: April 11, 2001Publication date: January 30, 2003Applicant: Westvaco CorporationInventors: Peter D.A. McCrae, Tiejun Zhang, David R.B. Walker
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Publication number: 20020190421Abstract: A method of manufacturing thermoplastic flexible transparent PVC film (sheet) without flow marks and air pit is capably provided with high efficient production to upgrade the quality of plastic film (sheet), which is included the following steps: calendering melted plastic material by calenders into melting plastic film (sheet) with predetermined thickness, quickly chilling and setting the melting plastic film (sheet) with chilling water, removing water from the cooled plastic film, heating the plastic film to dry out any residual water and controlling the plastic film again to a temperature from 30° C. to 85° C., and applying a pressure ranging from 1 kg/cm2 to 8 kg/cm2 on the plastic film (sheet) while winding it into a roll. Plastic film (sheet) produced with this method has good transparency and smooth surface without flow mark and air pit.Type: ApplicationFiled: May 14, 2001Publication date: December 19, 2002Inventor: Tai-Hsiung Lin
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Publication number: 20020171176Abstract: A detoxification process for rendering three-dimensional objects formed by solid freeform fabrication techniques biocompatible for use in long-term dermal contact applications. The process nullifies cytotoxins normally present in objects formed by solid freeform fabrication techniques rendering such techniques as viable for the production of biocompatible devices such as stents, artery valve components, bone implant supports, pacemaker shells, surgical tools, and the like. In one embodiment, a custom hearing aid shell is produced by stereolithography from an acrylate photopolymer resin that was detoxified for long-term dermal contact application. The detoxification process makes three-dimensional objects created by solid freeform fabrication techniques available for products requiring biocompatibility.Type: ApplicationFiled: March 30, 2001Publication date: November 21, 2002Inventor: Stephen D. Hanna
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Patent number: 6475417Abstract: The present invention is directed to a golf ball comprising a solid core component that includes a relatively hard central portion and a relatively soft skin portion surrounding the central portion. Various preferred embodiment golf balls are disclosed utilizing this core configuration. A golf ball comprising the noted core component having a wound layer disposed about the core skin portion is described. Another preferred embodiment relates to the use of the noted core component having a multi-layer cover assembly surrounding the core. Various methods for producing such golf ball core components are disclosed.Type: GrantFiled: December 22, 2000Date of Patent: November 5, 2002Assignee: Spalding Sports Worldwide, Inc.Inventors: R. Dennis Nesbitt, Michael J. Sullivan, Terence Melvin
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Publication number: 20020150723Abstract: A process for producing self-cleaning surfaces, in which an at least partially hydrophobic, surface structure is formed by securing particles on a polymer surface, which comprises applying, to the polymer surface, at least one solvent which comprises the particles and which solvates the polymer surface, and securing at least part of the particles to the polymer surface by removing the solvent; self-cleaning surfaces obtained by the process; and objects containing self-cleaning surfaces obtained by the process.Type: ApplicationFiled: April 9, 2002Publication date: October 17, 2002Applicant: CREAVIS GESELLSCHAFT F. TECHN. U. INNOVATION MBHInventors: Markus Oles, Edwin Nun
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Publication number: 20020150724Abstract: A self-cleaning surface which has an artificial, at least partially hydrophobic, surface structure of elevations and depressions, where the elevations and depressions are formed by particles secured by a carrier on the surface, wherein the particles have a fissured structure with elevations and/or depressions in the nanometer range; and a process for making such a surface.Type: ApplicationFiled: April 9, 2002Publication date: October 17, 2002Applicant: CREAVIS GESELLSCHAFT F. TECHN. U. INNOVATION MBHInventors: Edwin Nun, Markus Oles, Bernhard Schleich
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Patent number: 6458307Abstract: A method of manufacturing a golf ball is disclosed. A cover is molded through use of either a thermoplastic resin having a group capable of reacting with an isocyanate group or a thermoplastic resin containing a compound having two or more groups capable of reacting with an isocyanate group. Subsequently, a polyisocyanate compound is caused to permeate into the surface layer of the cover to thereby cause the reaction between the polyisocyanate compound and the group(s) capable of reacting with the isocyanate group. As a result, a modified layer having excellent properties is formed at the surface of the cover formed from thermoplastic resin. In this case, a non-yellowing polyurethane resin is preferably used as the thermoplastic resin having a group capable of reacting with an isocyanate group, and 4,4-diphenylmethane diisocyanate (MDI) is preferably used as the polyisocyanate compound.Type: GrantFiled: January 22, 1999Date of Patent: October 1, 2002Assignee: Bridgestone Sports Co., Ltd.Inventors: Michio Inoue, Keisuke Ihara, Hirotaka Shimosaka, Yutaka Masutani, Atsuki Kasashima
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Patent number: 6451205Abstract: A method of manufacturing a filter comprises the steps of assembling multiple layers of filtration material on top of one another to form an assembly; holding the assembly between an ultrasonic weld horn and a weld nest so that the assembly has a marginal area outside of an edge formed on either the nest or the weld horn; and operating the weld horn so as to cause the marginal area to be cut off from the assembly at the edge and to simultaneously seal together the layers of filtration material of the remaining assembly at the edge. A filter made by the process and an apparatus used to practice the process are also disclosed.Type: GrantFiled: April 5, 2000Date of Patent: September 17, 2002Assignee: Filtertek Inc.Inventor: Steven B. McGaw, Jr.
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Publication number: 20020119577Abstract: A membrane having a refined surface as well as to a process and an apparatus for producing such a membrane, and which is useful, in particular, for rapid diagnostic tests for identifying specific analytes in liquid media.Type: ApplicationFiled: January 22, 2002Publication date: August 29, 2002Inventors: Hans Beer, Klaus Froese, Lothar Knoechelmann, Duane B. Piechocki
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Publication number: 20020110584Abstract: A moisturizing and therapeutic glove is disclosed which includes a thin layer of Aloe Vera coated evenly and uniformly on an inside surface of the glove. Aloe Vera is attached to the surface through a dehydration process achieved with a controlled drying method. Aloe Vera soothes the hand during the wearing of the glove.Type: ApplicationFiled: April 2, 2002Publication date: August 15, 2002Inventor: Belle L. Chou
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Publication number: 20020089081Abstract: An improved layer normalizing device for use in dimensionally normalizing layers of a three-dimensional model produced by a selective deposition modeling technique. The layer normalizing device employs a wicking member having a body and a normalizing surface for dimensionally normalizing the object while the object is being built layer by layer. The body includes a plurality of interstices, and when the wicking member is sufficiently heated to cause the build material to become flowable, excess material is drawn by capillary action from the layer of the object being normalized and into the wicking member. A refreshing means is provided to remove the excess build material from the interstices of the wicking member and allow the wicking member to draw additional build material by capillary action.Type: ApplicationFiled: January 5, 2001Publication date: July 11, 2002Inventor: Jon Jody Fong
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Publication number: 20020066975Abstract: The allergens and extractable protein content of a latex device can be reduced by subjecting the un-cured latex device to a pre-cure leaching treatment with a solution containing a protease, followed by curing and a post-cure leaching treatment.Type: ApplicationFiled: September 17, 2001Publication date: June 6, 2002Applicant: Novozymes A/SInventor: Niels Elvig
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Publication number: 20020055784Abstract: A composite bearing insert for a total knee joint or a unicondylar knee joint which minimizes or eliminates the production of wear debris resulting from relative motion at the interface between the endoskeleton and a tibial tray of a knee joint prosthesis. The composite bearing insert includes an endoskeleton and a polymer portion which is preferably molded into and locked within the endoskeleton. The endoskeleton is configured to be locked to a tibial component, such as a tibial tray or keel. The modularity of the assembly facilitates the interchangeability of various composite bearing inserts with various tibial components.Type: ApplicationFiled: October 7, 1999Publication date: May 9, 2002Inventors: Albert Burstein, Raymond Cloutier
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Publication number: 20020036364Abstract: A method for molding an agglomeration of fused microspheres to create a fragrance delivery system by use of room temperature setting binders. The molded pre-glass agglomeration has an extended fragrance release time exceeding a year and a half, and uses microcapillary action to quickly uptake oils and alcohols. The molded pre-glass agglomeration provides a slow release of fragrance without the escape of any residual liquid. The molded pre-glass agglomeration may be replenished, an unlimited number of times, with fragrance containing oils and alcohols after the odor fades. The molded pre-glass agglomerations may also be colored or dyed.Type: ApplicationFiled: February 23, 2001Publication date: March 28, 2002Inventor: James Mosbaugh
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Patent number: 6337041Abstract: A method is used to make a vulcanized elastomer capable of combining with Polyurethane to form a product without the use of an adhesive. The method includes the formation of the mixture of an vulcanizable elastomer. The mixture is stabilized in a nitrogen-containing chamber before the mixture is vulcanized. The vulcanized elastomer is formed in a molding tool and is subsequently degreased with a liquid containing a non-ionic interfacial agent. The degreased elastomer is dried by baking before being coated with the acetoacetate solution containing chloro cyanuric acid. The coated elastomer is dried again by baking before being stabilized in a dustproof environment for 48 hours. Upon completion of the dustproof stabilization, the elastomer is ready for combining with Polyurethane without the help of an adhesive.Type: GrantFiled: October 20, 1999Date of Patent: January 8, 2002Inventor: Chih-Hsiung Kuo
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Publication number: 20010050447Abstract: A method of manufacturing a golf ball is disclosed. A cover is molded through use of either a thermoplastic resin having a group capable of reacting with an isocyanate group or a thermoplastic resin containing a compound having two or more groups capable of reacting with an isocyanate group. Subsequently, a polyisocyanate compound is caused to permeate into the surface layer of the cover to thereby cause the reaction between the polyisocyanate compound and the group(s) capable of reacting with the isocyanate group. As a result, a modified layer having excellent properties is formed at the surface of the cover formed from thermoplastic resin. In this case, a non-yellowing polyurethane resin is preferably used as the thermoplastic resin having a group capable of reacting with an isocyanate group, and 4,4-diphenylmethane diisocyanate (MDI) is preferably used as the polyisocyanate compound.Type: ApplicationFiled: January 22, 1999Publication date: December 13, 2001Inventors: MICHIO INOUE, KEISUKE IHARA, HIROTAKA SHIMOSAKA, YUTAKA MASUTANI, ATSUKI KASASHIMA
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Patent number: 6316512Abstract: New cross-linked polymeric foam compositions, and methods for making the same, are provided. The new compositions utilize novel cross-linked polyolefin copolymers and show improvements in strength, toughness, flexibility, heat resistance and heat-sealing temperature ranges as compared to conventional low density polyethylene compositions. The new compositions also show processing improvements over linear low density polyethylene. The novel polyolefins, which are essentially linear, comprise ethylene polymerized with at least one alpha-unsaturated C3 to C20 olefinic comonomer, and optionally at least one C3 to C20 polyene, and exhibit, in an uncross-linked sense, a resin density in the range of about 0.86 g/cm3 to about 0.96 g/cm3, a melt index in the range of about 0.5 dg/min to about 100 dg/min, a molecular weight distribution in the range of from about 1.5 to about 3.5, and a composition distribution breadth index greater than about 45 percent.Type: GrantFiled: April 24, 2000Date of Patent: November 13, 2001Assignee: Sentinel Products Corp.Inventors: John D. Bambara, Matthew L. Kozma, Robert F. Hurley
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Patent number: 6306238Abstract: Methods of thermal annealing of plastic pieces immediately after hot melt forming are disclosed to accelerate the time required to achieve dimensional stability. The present methods include the essential steps of: (A) forming molten plastic into molded plastic pieces and rapidly cooling to below the melting point of the plastic in a mold to form shaped cooled plastic pieces; (B) immediately thereafter, heating the plastic pieces to a temperature of about 150° to 170° F. (65.5° to 80° C.) to form heated plastic pieces; and, thereafter, (C) cooling the heated plastic pieces to room temperature to form thermally annealed plastic pieces. Tn its product aspect, the present invention resides in physically aged thermoplastic pieces having reduced rates of age shrinkage.Type: GrantFiled: June 10, 1999Date of Patent: October 23, 2001Assignee: General Mills, Inc.Inventors: Paul M. Torniainen, William E. Archibald, John Daugherty
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Patent number: 6274078Abstract: A method of removing a core from a CMC component in which the core was used to form an internal cavity. According to one embodiment of the invention, the core is removed from a fully densified CMC component by heating the component and core to a temperature at which the core deteriorates but below a temperature at which the component would melt or otherwise be damaged. According to a second embodiment of this invention, the component is only partially densified, and then impregnated with a coating material that is resistant to a leaching compound capable of removing the core. The core can then be removed using the leaching compound without damage to the internal surfaces of the component defined by the core when the component was fabricated.Type: GrantFiled: January 27, 1999Date of Patent: August 14, 2001Assignee: General Electric CompanyInventors: Thomas J. Dunyak, James D. Steibel, David R. Chang, Peggy E. Jones
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Patent number: 6261491Abstract: A system for producing blocks of open-cell, flexible polyurethane foam material and for conditioning each freshly-manufactured block to impart thereto optimal flexible foam properties. The system includes means to pour the flowable constituent of the foam material to be manufactured into a production station at the inlet of a conveyor, the constituents interacting to create on the conveyor a block of open-cell flexible foam material which is then wrapped in a plastic film casing that exposes the leading and trailing end of the block so that the encased block is open ended. The conveyor transports the wrapped block toward the rear end of a gate in a conditioning station having a port therein whose front end is coupled by an air duct to a suction fan.Type: GrantFiled: December 28, 1999Date of Patent: July 17, 2001Assignee: TAS Enterprises, L.L.C.Inventor: Delane Marlowe
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Patent number: 6258305Abstract: A method of net-shaping using aerogel materials is provided by first forming a sol, aging the sol to form a gel, with the gel having a fluid component and having been formed into a medium selected from the group consisting of a powder, bulk material, or granular aerobeads, derivatizing the surface of the gel to render the surface unreactive toward further condensation, removing a portion of the fluid component of the final shaped gel to form a partially dried medium, placing the medium into a cavity, wherein the volume of said medium is less that the volume of the cavity, and removing a portion of the fluid component of the medium. The removal, such as by heating at a temperature of approximately less than 50° C., applying a vacuum, or both, causes the volume of the medium to increase and to form a solid aerogel. The material can be easily removed by exposing the material to a solvent, thereby reducing the volume of the material.Type: GrantFiled: March 29, 2000Date of Patent: July 10, 2001Assignee: Sandia CorporationInventors: C. Jeffrey Brinker, Carol S. Ashey, Scott T. Reed, Chunangad S. Sriram, Thomas M. Harris
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Patent number: 6217822Abstract: A method and an apparatus for making straight fuel cell tubes are disclosed. Extruded tubes comprising powders of fuel cell material and a solvent are dried by rotating the extruded tubes. The rotation process provides uniform circumferential drying which results in uniform linear shrinkage of the tubes. The resultant dried tubes are very straight, thereby eliminating subsequent straightening steps required with conventional processes. The method is particularly useful for forming inner air electrode tubes of solid oxide fuel cells.Type: GrantFiled: February 9, 1998Date of Patent: April 17, 2001Assignee: Siemens Westinghouse Power CorporationInventor: Brian P. Borglum
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Patent number: 6210625Abstract: The invention is a method of making a novel spherical form of granulated products that can be effectively used in various product forms in drug, fertilizer, foodstuff, feed, agricultural chemical, catalyst, ceramics, powder metallurgy, detergent, plastic, and bio-material fields, for instance, as catalysts, lightweight materials, sound-insulating materials, microcapsules, and lightweight aggregates. To obtain a granulated product which is a spherical solid shell having a spherical space therein, a polymer having high water absorption properties is swollen by the absorption of water therein, and then brought in contact with a powder to form a powder layer all over the surface of the swollen polymer particle. This spherical particle is then dried and fired if necessary.Type: GrantFiled: March 29, 1999Date of Patent: April 3, 2001Assignee: Mikuni CorporationInventors: Mitsuhiro Matsushita, Shinpei Inamura
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Patent number: 6200510Abstract: A method of applying an indicia to the surface of a cellulose casing by non contact printing wherein the indicium is applied in-line with the casing manufacture at a location between the wet end and the dry end of the casing manufacturing process wherein the indicia comprises an ink that is cured and cross linked with the cellulose prior to the casing reaching the dry end of the process. The indicia preferably is in the form of a dot matrix pattern that is visible yet presents no barrier to the passage of smoke.Type: GrantFiled: October 13, 1998Date of Patent: March 13, 2001Assignee: Viskase CorporationInventors: Paul Edmund DuCharme, Jr., Rama Ramagopal
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Patent number: 6191252Abstract: This invention is an improvement in standard polymerizations procedures, i.e., addition-type and step-growth type polymerizations, wherein momomers are reacted to form a growing polymer chain. The improvement includes employing an effective amount of a trifunctional monomer (such as a trifunctional amine, anhydride, or phenol) in the polymerization procedure to form a mixture of polymeric materials consisting of branced polymers, star-shaped polymers, and linear polymers. This mixture of polymeric materials has a lower melt temperature and a lower melt viscosity than corresponding linear polymeric materials of equivalent molecular weight.Type: GrantFiled: June 18, 1996Date of Patent: February 20, 2001Inventor: Brian J. Jensen
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Patent number: 6143219Abstract: The present invention discloses a generic method for producing void and gas occlusion free materials, as well as apparatuses for batch and continuous production of same. This generic method can be utilized in the production of a wide variety of polymeric compounds and composites and specifically encompasses the two ends of the polymeric composite spectrum, that is, polymer concretes on the one hand, and fiber-reinforced polymer composites on the other. The composite materials of the present invention are characterized by visual count as being void and gas occlusion free to the level of 1 micron at 1250.times. magnification. Concomitantly, the invention produces useful polymer concrete materials which exhibit substantially improved integrity for easy machining at high speeds, and high dielectric and mechanical strength, as compared with composite materials produced by conventional methods.Type: GrantFiled: November 20, 1998Date of Patent: November 7, 2000Assignee: Mardela International Inc. S.A.Inventors: Victor H. Vidaurre, Wilfredo G. Bendek, Jorge L. Dufeu
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Patent number: 6136237Abstract: A method for fabricating a fiber-reinforced ceramic matrix composite (FRCMC) part includes the steps of forming a blank from FRCMC material such that the blank has a dimension approximating a desired finished dimension for the part measuring the dimension of the blank in an unloaded condition, applying a load to the blank and then removing the load so as to cause permanent strain of the blank, measuring the dimension of the blank after the load has been applied and then removed, and comparing the measured dimension after loading to the previously measured dimension. In a preferred embodiment of the invention, if the dimension after loading differs from the dimension previously measured, the loading and measuring steps are repeated. After each loading cycle, the blank is measured and the measured dimension is compared to that previously measured after the prior loading cycle.Type: GrantFiled: April 13, 1999Date of Patent: October 24, 2000Assignee: The Boeing CompanyInventors: Andreas Straub, Jerry Brockmeyer, Eric Krieg
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Patent number: 6103775Abstract: New cross-linked polymeric foam compositions, and methods for making the same, are provided. The new compositions utilize novel cross-linked polyolefin copolymers and show improvements in strength, toughness, flexibility, heat resistance and heat-sealing temperature ranges as compared to conventional low density polyethylene compositions. The new compositions also show processing improvements over linear low density polyethylene. The novel polyolefins, which are essentially linear, comprise ethylene polymerized with at least one alpha-unsaturated C3 to C20 olefinic comonomer, and optionally at least one C3 to C20 polyene, and exhibit, in an uncross-linked sense, a resin density in the range of about 0.86 g/cm.sup.3 to about 0.96 g/cm.sup.3, a melt index in the range of about 0.5 dg/min to about 100 dg/min, a molecular weight distribution in the range of from about 1.5 to about 3.5, and a composition distribution breadth index greater than about 45 percent.Type: GrantFiled: March 16, 1999Date of Patent: August 15, 2000Assignee: Sentinel Products Corp.Inventors: John D. Bambara, Matthew L. Kozma, Robert F. Hurley
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Patent number: 6077907Abstract: Molded polyolefin articles of improved dimensional stability at elevated temperatures and improved stiffness and consist of mixtures of modified propylene polymers, which are synthesized by free radical coupling reactions or polymer-like reactions of functionalized polypropenes, and of unmodified propylene polymers, crystalline copolymers of propylene and .alpha.-olefins, elastic copolymers of ethylene and .alpha.-olefins, largely amorphous polypropylenes, non-isotactic propylene homopolymers, and auxiliary materials.The molded polyolefin articles, produced by blow molding or injection molding are suitable for use in the packaging industry, for use in the domestic appliances industry, to meet the requirements of laboratories and hospitals, for gardening and agricultural implements, for transporting containers for components in the automobile industry, and for components of machines and of electric and electronic equipment.Type: GrantFiled: June 18, 1998Date of Patent: June 20, 2000Assignee: Borealis AGInventors: Manfred Raetzsch, Achim Hesse, Norbert Reichelt, Ulf Panzer, Markus Gahleitner, Max Wachholder, Karl Kloimstein
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Patent number: 6019922Abstract: A powder free medical glove having an outer side a silicon treated surface and the inside of cross linked coagulated glove bonded with a layer formed of an anti-blocking composition. The anti-blocking composition includes of a polymer or copolymer mixed together with a micronised high density polyethylene material and wax in suitable blends that result in the composition having anti-blocking and improved lubricity properties. The medical glove with the skin contacting anti-blocking coating enables donning of the glove to be effected without the aid of donning powder such as starch powder. When the finished glove is washed and rinsed with water to remove the coagulant powder, and the said glove treated with a silicon solution, a glove substantially free of loose powder glove is produced and has good lubricity for donning.Type: GrantFiled: September 30, 1998Date of Patent: February 1, 2000Assignee: Johnson & Johnson Mfg Sn BhdInventors: Noorman Abu Hassan, Chak Choy Yuen
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Patent number: 5953884Abstract: An apparatus and method are provided for manufacturing articles, such as syringe barrels, substantially free from contaminants. The apparatus is an enclosure defining at least a class 100 and MCB-3 environment, and includes a molding isolation module and a packaging isolation module. Any contaminants that may exist within the enclosure are removed by the use of horizontal and vertical laminar airflows directed into air filter units. Further, the molding temperature may be selected such that it renders the fabricated articles substantially free from contaminants. The molding isolation module and packaging isolation module keep the fabricated articles substantially free from contaminants from the time the articles are molded to the time the articles are placed in sealed containers for shipment.Type: GrantFiled: July 17, 1997Date of Patent: September 21, 1999Assignee: Medrad, Inc.Inventors: Mark Lawecki, Eugene A. Gelblum, Michelle Robinson, Ralph E. Wolstenholme, Eugene B. Wolstenholme
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Patent number: 5912315Abstract: The present invention relates to the polymer composite possesses excellent mechanical properties such as restorable ability or shock resistance, coating property, and adhesiveness. It is preferred that the disperse phase is distributed homogeneously.The polymer composite of the present invention is obtained by polymerizing a vinyl monomer selected from the group consisting of a styrenic monomer, acrylonitrile, methacrylonitrile, an ethylenically unsaturated carboxylic acid, anhydride of said carboxylic acid, and ester of said carboxylic acid in the presence of a rubber-like copolymer and a thermoplastic resin selected from the group consisting of a polyolefin, a polyamide, a polyimide, a polyarylene ether, a polyacetal and a polyester without a substantial amount of a solvent. The polymer composite is preferable that a part of vinyl monomer is grafted to the rubber-like copolymer and the polyolefin, and the thermoplastic resin forms a matrix phase.Type: GrantFiled: January 24, 1996Date of Patent: June 15, 1999Assignee: Sanyo Chemical Industries, Ltd.Inventor: Takafumi Horiie
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Patent number: 5910277Abstract: A fine powder of polytetrafluoroethylene is mixed with a liquid lubricant, and the mixture is molded into an unsintered sheet by at least one of an extrusion method and a rolling method. The liquid lubricant is removed from the sheet by at least one of a heating method and an extrusion method. This sheet-form molding is stretched in the machine direction to produce a sheet-form polytetrafluoroethylene molding which, upon analysis with a differential scanning calorimeter, gives a crystal fusion curve having an endothermic peak in the temperature range of 345.+-.5 .degree. C. and which has a degree of crystallization of from 0.1 to 0.85 and a specific gravity of 1.4 or lower. The molding is then stretched in the transverse direction to produce a porous polytetrafluoroethylene (PTFE) membrane. The process is effective in producing, with good reproducibility, a useful porous PTFE membrane which has a high collection efficiency and a low pressure loss and is reduced in the leakage of coarse particles.Type: GrantFiled: May 16, 1997Date of Patent: June 8, 1999Assignee: Nitto Denko CorporationInventors: Toshiaki Ishino, Norikane Nabata, Takuya Maeoka
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Patent number: 5897817Abstract: Methods are disclosed for making semipermeable membranes from cellulose acetate and for making medical devices therefrom. In the process, a molten liquid comprising cellulose acetate (CA) is extruded to produce a membrane. The solvent and non-solvent are removed from the membrane to produce a semipermeable membrane having a water permeability. The semipermeable membrane is impregnated with a liquid consisting essentially of water to render the semipermeable membrane capable of being stored until time of use without undergoing a substantial loss in water permeability. The semipermeable membrane can be incorporated in a casing in order to produce a medical product, wherein the membrane is impregnated in the product.Type: GrantFiled: July 8, 1997Date of Patent: April 27, 1999Assignee: Althin Medical, Inc.Inventors: John M. Radovich, Melvin Rothberg, George Washington
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Patent number: 5885493Abstract: A method of drying a green particulate article includes the steps of:a. Providing a green article which includes a particulate material and a pore phase material, the pore phase material including a solvent; andb. contacting the green article with a liquid desiccant for a period of time sufficient to remove at least a portion of the solvent from the green article, the pore phase material acting as a semipermeable barrier to allow the solvent to be sorbed into the liquid desiccant, the pore phase material substantially preventing the liquid desiccant from entering the pores.Type: GrantFiled: November 4, 1997Date of Patent: March 23, 1999Assignee: Lockheed Martin Energy Research CorporationInventors: Mark A. Janney, James O. Kiggans, Jr.
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Patent number: 5883144Abstract: New cross-linked polymeric foam compositions, and methods for making the same, are provided. The new compositions utilize novel cross-linked polyolefin copolymers and show improvements in strength, toughness, flexibility, heat resistance and heat-sealing temperature ranges as compared to conventional low density polyethylene compositions. The new compositions also show processing improvements over linear low density polyethylene. The novel polyolefins, which are essentially linear, comprise ethylene polymerized with at least one alpha-unsaturated C3 to C20 olefinic comonomer, and optionally at least one C3 to C20 polyene, and exhibit, in an uncross-linked sense, a resin density in the range of about 0.86 g/cm.sup.3 to about 0.96 g/cm.sup.3, a melt index in the range of about 0.5 dg/min to about 100 dg/min, a molecular weight distribution in the range of from about 1.5 to about 3.5, and a composition distribution breadth index greater than about 45 percent.Type: GrantFiled: November 15, 1996Date of Patent: March 16, 1999Assignee: Sentinel Products Corp.Inventors: John D. Bambara, Matthew L. Kozma, Robert F. Hurley
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Patent number: 5883145Abstract: New cross-linked polymeric foam compositions, and methods for making the same, are provided. The new compositions utilize novel cross-linked polyolefin copolymers and show improvements in strength, toughness, flexibility, heat resistance and heat-sealing temperature ranges as compared to conventional low density polyethylene compositions. The new compositions also show processing improvements over linear low density polyethylene. The novel polyolefins, which are essentially linear, comprise ethylene polymerized with at least one alpha-unsaturated C3 to C20 olefinic comonomer, and optionally at least one C3 to C20 polyene, and exhibit, in an uncross-linked sense, a resin density in the range of about 0.86 g/cm3 to about 0.96 g/cm3, a melt index in the range of about 0.5 dg/min to about 100 dg/min, a molecular weight distribution in the range of from about 1.5 to about 3.5, and a composition distribution breadth index greater than about 45 percent.Type: GrantFiled: February 25, 1997Date of Patent: March 16, 1999Assignee: Sentinel Products Corp.Inventors: Robert F. Hurley, Matthew L. Kozma, Kurt A. Feichtinger
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Patent number: 5879603Abstract: A mold for producing a masonry unit with a roughened texture side surface having a plurality of side walls defining a mold cavity open at its top and bottom, adapted to receive masonry fill material by way of its open top, and to discharge molded fill material in the form of a block of predetermined height by way of its open bottom; and opposed, inwardly extending generally parallel upper and lower lips along at least one of said side walls, the upper lip being located at a predetermined height above the lower lip and the lower lip being located at the bottom of the mold cavity.Type: GrantFiled: November 8, 1996Date of Patent: March 9, 1999Assignee: Anchor Wall Systems, Inc.Inventor: Dick J. Sievert
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Patent number: 5863297Abstract: This invention provides molded, biodegradable porous polymeric implant materials having a pore size distribution throughout the material which is substantially uniform. These materials can be molded into implants of any desired size and shape without loss of uniformity of pore size distribution. The implants are useful as biodegradable scaffolds for cell growth in healing of tissue defects. When manufactured to have an aspect ratio greater than about 3, the implants can be further hand-shaped to fit the defect into which they are placed and the desired shape for the regrown tissue.Type: GrantFiled: October 8, 1996Date of Patent: January 26, 1999Assignee: OsteoBiologics, Inc.Inventors: Mary Ann Walter, Neil C. Leatherbury, Mark Q. Niederauer
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Patent number: 5851459Abstract: A method is illustrated for manufacturing bicycle cranks in which a layer of foamable material is applied on an outer surface of a metallic member which has two holes respectively defined in two ends thereof. A layer of composite preimpregnated material is then applied on the layer of foamable material. Thereafter, the metallic member is mounted in a mold and then heated to make the foamable material foam, thereby achieving formation of a semi-product crank by means of formation of the foamable material, the composite preimpregnated material, and the metallic member. After removal from the mold, the holes of the semi-product crank is tapped, and the semi-product crank is then trimmed and ground. Patching is applied to make an outer surface of the crank smooth.Type: GrantFiled: December 12, 1997Date of Patent: December 22, 1998Inventor: Jason Chen
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Patent number: 5840782Abstract: Reaction system for preparing microcellular elastomers comprising an isocyanate-terminated prepolymer, a polyol and water.Type: GrantFiled: September 8, 1995Date of Patent: November 24, 1998Assignee: Imperial Chemical Industries PLCInventors: Dominicus Limerkens, Christopher Phanopoulos, Johan Mietje Jozef Indesteege
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Patent number: 5834584Abstract: An electrically conductive rubber roller for electrophotography which does not exhibit touch memory or bleed out of remnant siloxanes, even after 18 days of storage without use, and, in a preferred form, exhibits little change in electric resistance with changes in environment. This roller is made by making a rubber molding material composition containing a raw polysiloxane rubber which does not contain more than 5,000 ppm of low molecular weight polysiloxanes, cyclic siloxanes and non-functional silicone oils (remnant siloxanes); molding this composition into a roller; at least primarily crosslinking the rubber in the roller; and then subjecting the crosslinked rubber roller to heating under a vacuum.Type: GrantFiled: April 25, 1995Date of Patent: November 10, 1998Assignee: Sumitomo Rubber Industries Ltd.Inventors: Hitoshi Itani, Yuji Yamasaki, Hirotoshi Murakami
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Patent number: 5820800Abstract: The invention relates to a method for manufacturing vacuum suction pads, in which, in addition to reductions of contaminant components, the material of vacuum suction pads is subjected to an improved surface treatment which prevents deposition of pad marks on work surfaces and reduces frictional resistance of suction pads on work surfaces to lessen their fatigue. Suction pads of synthetic rubber, to be connected to a vacuum source, are each formed with a thin halogenation-hardened layer at least on a sucking surfaces to be held in contact with a work surface.Type: GrantFiled: September 13, 1996Date of Patent: October 13, 1998Assignee: SMC CorporationInventors: Shigekazu Nagai, Shuuzou Sakurai, Tadasu Kawamoto
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Patent number: 5817259Abstract: A method and apparatus is provided for controlling the reconfiguration of a moulded boat hull structure as it is cooled from its moulding temperature to ambient temperature. A dynamic cooling fixture is utilized having movable panels that support substantially the entire inner and outer hull surfaces during the entire cooling process. This results in the cooling of the hull in a manner which will be devoid of wrinkles, depressions, or other disadvantageous discontinuities.Type: GrantFiled: October 4, 1996Date of Patent: October 6, 1998Assignee: Allied Logic CorporationInventors: Rich Pignata, Mark White
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Patent number: 5811050Abstract: An EMI shield for personal computers, cellular telephones, and other electronic devices is constructed from thermoformable polymeric material which is then metallized on all surfaces by vacuum metallization techniques to provide an inexpensive, lightweight, yet effective EMI shield.Type: GrantFiled: June 5, 1995Date of Patent: September 22, 1998Inventor: John F. Gabower
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Patent number: 5800647Abstract: Compositions, methods, and apparatus for manufacturing sheets having a highly inorganically filled matrix. Suitable inorganically filled mixtures are prepared by mixing together an organic polymer binder, water, one or more aggregate materials, fibers, and optional admixtures in the correct proportions in order to form a sheet which has the desired performance criteria. The inorganically filled mixtures are formed into sheets by first extruding the mixtures and the passing the extruded materials between a set of rollers. The rolled sheets are dried in an accelerated manner to form a substantially hardened sheet, such as by heated rollers and/or a drying chamber. The inorganically filled sheets may have properties substantially similar to sheets presently made from traditional materials like paper, paperboard, polystyrene, plastic, or metal. Such sheets can be rolled, pressed, scored, perforated, folded, and glued.Type: GrantFiled: November 24, 1993Date of Patent: September 1, 1998Assignee: E. Khashoggi Industries, LLCInventors: Per Just Andersen, Simon K. Hodson
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Patent number: 5798437Abstract: An amphiphilic block copolymer including a hydrophilic internal segment and polymeric articles made therefrom.Type: GrantFiled: July 29, 1996Date of Patent: August 25, 1998Assignee: Circe Biomedical, Inc.Inventors: Lawrence Francis Hancock, Alan Jay Kishbaugh, Marc Ellous Parham
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Patent number: 5783136Abstract: A method of preparing a stereolithographically produced prototype for experimental stress analysis. The method includes creating a 3-D solid model prototype through a stereolithographic process. The prototype is cleaned in an alcohol bath and cured by exposing the prototype to a bath of ultraviolet light. Further, curing of the prototype is accomplished by placing the prototype in a thermal oven at an elevated temperature for a period of time. Upon removal and after cooling of the prototype, the prototype can be tested using several different experimental stress analysis procedures.Type: GrantFiled: September 9, 1996Date of Patent: July 21, 1998Assignee: Ford Global Technologies, Inc.Inventor: Neal Floyd Enke