Use Of One Or More Blowing Agents Together Patents (Class 264/DIG5)
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Patent number: 3962154Abstract: A method for producing an improved molded thermoplastic polymeric resinous article comprising: introducing a heat plastified thermoplastic polymeric resinous material into a mold in the presence of a finely divided inorganic material; cooling said heat plastified thermoplastic polymeric resinous material; removing from said mold said cooled mold shaped thermoplastic polymeric resinous material having finely divided inorganic material incorporated therein.Type: GrantFiled: May 31, 1974Date of Patent: June 8, 1976Assignee: Standard Oil CompanyInventor: Ernst A. Egli
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Patent number: 3962387Abstract: Plastic molding machine, primarily adapted for generating and molding a closed-cell foam thermoplastic material. The foam is generated by introducing a gas inert to the thermoplastic material into a granular mixture of same so that the gas is thoroughly intermixed among the granular particles. The gas is then held under pressure while the granular particles are reduced to a flowable material, said pressure being sufficient to assure that the gas will not be expelled therefrom during such process. In one preferred embodiment, gas is mixed into the granular thermoplastic in a hopper and held therein under pressure as said granular material is fed into a screw and plasticated thereby.The plastic material is then conducted at a relatively low pressure, such as that generated by the extrusion machine used for plasticating the material, through a branched system past a check valve in each branch of said system, to an injection assembly.Type: GrantFiled: July 24, 1973Date of Patent: June 8, 1976Assignee: Ex-Cell-O CorporationInventor: James W. Hendry
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Patent number: 3959545Abstract: An expanded rubber, e.g., a foam or sponge-type material is obtained by admixing with a high green strength rubber an expanding or blowing agent, causing the agent to function and then quenching the expanding product to cool and set the same for example with cold water. Various applications of the process include cushioning material, rug underlay, shoe insole, slipper-type footwearing apparel, etc.Type: GrantFiled: February 6, 1974Date of Patent: May 25, 1976Assignee: Phillips Petroleum CompanyInventor: Roy W. Siedenstrang
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Patent number: 3959049Abstract: A process for the production of artificial leathers having excellent air permeability and resembling a natural leather is provided, which comprises incorporating a catalyst, a foam stabilizer and, optionally, a pigment and other additive into an isocyanate-terminated polyurethane prepolymer formed by compounding a polyester diol derived from an aliphatic dicarboxylic acid with an organic polyisocyanate so that the [NCO]/[OH] ratio is within a range of from 2.0 to 4.0, to thereby form a substantially solvent-free paint having a viscosity adjusted to 70 to 1000 poises, coating the paint on a release paper in an amount of 50 to 400 g/m.sup.2, applying the release paper to a substrate, allowing foaming and polymerization reactions to proceed in an atmosphere of a dry-bulb temperature of 40.degree. to 95.degree.C.Type: GrantFiled: June 26, 1974Date of Patent: May 25, 1976Assignee: Nippon Cloth Industry Co., Ltd.Inventors: Yoshinobu Tanaka, Hidehiko Maki, Tamio Ishiai, Tasaku Nishii, Singi Oota
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Patent number: 3957936Abstract: Filaments having a substantially increased inner surface, in particular porous filaments of filaments having a cracked, notched or nicked surface of thermoplsatic material are produced by subjecting filaments of thermoplastic material, preferably containing a pore-forming agent, to a heating medium at a temperature at least 100.degree., preferably 150.degree.C.Type: GrantFiled: July 22, 1971Date of Patent: May 18, 1976Assignee: Raduner & Co., AGInventor: Alfred E. Lauchenauer
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Patent number: 3956451Abstract: Apparatus for molding a composite styled wheel for use on automotive passenger vehicles and the like, a method of constructing such a wheel employing the molding apparatus and a method of constructing such molding apparatus, wherein a portion of the mold comprises a conventional metal vehicle wheel having a drop center rim secured to a central disc or body having the usual bolt circle holes and a central aperture so that the disc can be mounted on an axle, drum or disc brake assembly. The metal wheel is employed in conjunction with an upper back-up clamp and lower mold part to define therewith a sealed cavity for molding and attaching a three-dimensional contoured plastic overlay, the overlay thus being molded in situ and permanently attached to the outboard side of the wheel in the mold apparatus.Type: GrantFiled: June 29, 1973Date of Patent: May 11, 1976Assignee: Motor Wheel CorporationInventor: Leslie R. Adams
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Patent number: 3956438Abstract: Process for producing a partially foamed thermoplastic polymer product in a single screw extruder by dividing an initial melt stream of the polymer into separate partial melt streams conveyed individually by the extruder to a shaping or forming die, uniformly mixing a foaming agent with at least one but not all of the separate and individually conveyed partial melt streams, and then rejoining all of said melt streams in the die in abutting core and shell layers with foaming of at least one but not all of said layers.Type: GrantFiled: October 9, 1973Date of Patent: May 11, 1976Assignee: Barmag Barmer Maschinenfabrik AktiengesellschaftInventor: Heinz Schippers
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Patent number: 3953558Abstract: A method of moulding foamed synthetic resin pellets of polyolefine in a mould, wherein the synthetic resin pellets are prepared with volumne of closed cells being more than 65 % of the total volume of the total cells and having an inorganic gas in the cells at a pressure higher than 1.18 atmospheres, then filled in a mould which is not completely gas tight, and then heated to expand and tightly adhere to each other. The pressure in the mould can be lower than ordinary pressure or at a vacuum and the pressure of the resin can be at a pressure higher than ordinary pressure. The moulded product may be removed from the mould after cooling or during cooling when the inner temperature of the product is between its melting point and a temperature 50.degree.C below the melting point. The obtained product may be stored at a temperature of 30.degree. to 70.degree.C below the melting point.Type: GrantFiled: December 18, 1973Date of Patent: April 27, 1976Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Itaru Hatano, Minoru Hara, Tsuneo Kitamura, Akira Ando, Yasuyuki Suganuma
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Patent number: 3950484Abstract: A method for producing an improved molded thermoplastic polymeric resinous article comprising: introducing a heat plastified thermoplastic polymeric resinous material into a mold in the presence of a finely divided inorganic material; cooling the heat plastified thermoplastic polymeric resinous material; removing from the mold the cooled mold-shaped thermoplastic polymeric resinous article having finely divided inorganic material incorporated therein.Type: GrantFiled: August 30, 1974Date of Patent: April 13, 1976Assignee: Standard Oil CompanyInventor: Ernst A. Egli
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Patent number: 3949029Abstract: In the production of a porous shaped inorganic structure wherein an inorganic solids-containing suspension is mixed with a gas-generating compound and the suspension is poured into a mold, the improvement which comprises employing as said gas-generating compound a molecular sieve zeolite laden with a gas.Type: GrantFiled: June 24, 1974Date of Patent: April 6, 1976Assignee: Bayer AktiengesellschaftInventor: Gunter Ulisch
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Patent number: 3946096Abstract: An extrudate element is inserted into a base material so that a portion of the extrudate enters into or traverses the base material. The inserted extrudate element, the constituent of the base material, or both are composed of an expandable extrudate containing an expansion agent. The expansion agent is activated during or after insertion of the extrudate element to cause enlargement of the expandable extrudate and/or the substrate or base. This enlargement fixes the extrudate element into the base material by tightening the inserted element against the base material to wedge it in place, as by causing portions of the inserted element to enter interstices of the base material, or by causing the inserted element to expand on both sides of the insertion opening to a diameter greater than that of the insertion opening. The insertion and subsequent fixing into a base material of a plurality of elements produces a pile surfaced article.Type: GrantFiled: August 28, 1973Date of Patent: March 23, 1976Assignee: Phillips Petroleum CompanyInventor: Paul L. Gomory
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Patent number: 3940467Abstract: A process for producing a swirl-free, indent-free foamed thermoplastic structural article in which water is utilized as a foaming agent. Water and a melted thermoplastic resin are mixed together in an extruder to form a pressurized foamable mixture. The foamable mixture from the extruder is collected in an accumulator and from there is delivered to a cavity in a mold in a suitable clamping device. The pressure in the cavity is lower than the pressure of the foamable mixture in the accumulator or extruder therefore when the foamable mixture enters the cavity the foaming agent is released and the thermoplastic resin is frothed and expands to completely fill the cavity. The melted foamed thermoplastic resin cools in the mold and solidifies to form a foamed thermoplastic structural article. The quantity of water introduced into the extruder is between about 0.1 weight percent to about 0.5 weight percent of the thermoplastic resin charge in the extruder.Type: GrantFiled: December 18, 1974Date of Patent: February 24, 1976Assignee: Bethlehem Steel CorporationInventor: Armand E. Brachman
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Patent number: 3939237Abstract: A novel tube or sheet-shaped fluid transmitting porous material containing as a substrate, a polyolefin. Such porous material can be readily produced by subjecting a mixture of a polyolefin, a specific secondary polymer and a decomposition type blowing agent to extrusion moulding. The present porous material has certain unique features in its structure characterized in that there are recurring communications between cell wall openings forming a passage through which a fluid can pass. This porous material has excellent gas and liquid transmitting properties as well as an excellent filtering property and, in addition, is superior in resistance to chemicals and also has mechanical strength. Therefore, the porous material according to this invention is widely applicable in agriculture and industry as well as in the fields of synthetic leather etc.Type: GrantFiled: April 22, 1974Date of Patent: February 17, 1976Assignee: Asahi Dow, Ltd.Inventors: Hirokuni Naito, Isao Yoshimura, Hisao Tashiro
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Patent number: 3937777Abstract: A process and apparatus for continuous production of molded sheets of a foamed thermoplastic synthetic resin, wherein a synthetic resin is fed into a screw extruder and a low boiling point liquid expanding agent is introduced under high pressure into the extruder and admixed with the resin in the extruder and thereafter the resulting admixture is extruded in the form of a plurality of foam filaments to insure proper distribution of the admixture to the nozzles of the extruder. A gear pump is provided for each nozzle. Also, to avoid collapsing of the foam means are provided for tempering the foam filaments by the application of heat.Type: GrantFiled: November 27, 1972Date of Patent: February 10, 1976Assignee: Dynamit Nobel AGInventors: Michael Wienand, Jurgen Hasberg, Franz-Werner Alfter
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Patent number: 3933548Abstract: Thin flexible urethane foam film layers are produced by spreading a layer of polyurethane reactants over a carrier sheet at a uniform layer thickness. The polyurethane reactants consist essentially of an isocyanate and a hydroxyl terminated polyol having an inorganic carbon dioxide producing blowing agent incorporated therein and being free of water. The unconfined film layer is then heated to a temperature in the range of from 260.degree.F to 390.degree.F to cause gellation and release of the carbon dioxide in the mixture with final formation of a uniform thickness flexible polyurethane foam product.Type: GrantFiled: August 19, 1974Date of Patent: January 20, 1976Assignee: Beatrice Foods Co.Inventors: Harry M. Anderson, Jr., Charles K. Knisely
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Patent number: 3932569Abstract: An improved method for the manufacture of free-flow packing material particularly characterized by its ability to isolate packed items and to absorb the energy of potentially destructive shocks and impacts. The method produces individual units of the packing material which are structurally in the form of elongate flat "bows," wherein two self-adhered layers of foamed expanded plastic material form a central portion of the "bow" and curved outward extensions of these layers form two oppositely extending flat loops. The flat bow-shaped units are individually of a size and shape to provide a desired free-flowing characteristic, and are formed of a foamed expanded crushable plastic material which inherently possesses a shock absorbing characteristic.Type: GrantFiled: July 12, 1974Date of Patent: January 13, 1976Assignee: Free-Flow Packaging CorporationInventor: Gunter G. Fuss
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Patent number: 3931379Abstract: A process for the manufacture of profiled products by extruding in a substantially non-expanded state an expandable styrene polymer composition through a die orifice having the desired profile and subsequently passing the extruded material through a sizing member wherein it expands to the desired profile and cross-section to produce an article having a porous inner cross-section and a solid, non-foamed outer layer and wherein the styrene polymer composition employed is one containing from about 0.2 to 1.0 parts by weight of an alkaline earth metal carbonate blowing agent and from about 0.2 to 1.0 parts by weight of an organic acid per 100 parts by weight of styrene polymer.Type: GrantFiled: July 17, 1973Date of Patent: January 6, 1976Assignee: Cosden Oil & Chemical CompanyInventors: Bob Joe Cruson, Ronald D. Medley