Injection Molding Of Polyolefin-type Foam Patents (Class 264/DIG83)
  • Patent number: 4201742
    Abstract: This invention substantially improves the surface finish on resin filled foamed molded plastic products manufactured by injection molding by pre-heating the skin surface of that part of the mold in contact with the part prior to the injection cycle of the machine and then subsequently chilling the mold via internal tube connections to shorten the time needed in the manufacturing cycle for solidifying the part sufficiently for release from the mold.
    Type: Grant
    Filed: February 13, 1978
    Date of Patent: May 6, 1980
    Assignee: Ex-Cell-O Corporation
    Inventor: James W. Hendry
  • Patent number: 4191523
    Abstract: An apparatus for molding shaped bodies from foamable plastics such as foamable polyurethane resin material comprises a two-piece mold 20, 21 fastened to two clamping plates 17, 18 of a mold holder 11, all of which can revolve around parallel axes 34, 35, 36. The upper plate 18 can move toward the fixed lower plate 17 and back again. The plates are locked and urged together during the molding process by pairs of hydraulic cylinders 28, 29 and 30, 31 mounted on opposite sides of the mold halves 20, 21.
    Type: Grant
    Filed: June 16, 1978
    Date of Patent: March 4, 1980
    Assignee: Herbert Kannegiesser Kommanditgesellschaft
    Inventors: Jean-Pierre Niederst, Karl Holzinger
  • Patent number: 4188356
    Abstract: The instant invention relates to a method and an apparatus for the production of a foam-forming reaction mixture or homogeneous material-forming reaction mixture from at least two liquid reactants and for the subsequent introduction thereof into a cavity, and in particular into the cavity of a mold. The reactants are introduced into a mixing zone where they are mixed together. The mixture is subsequently fed through an outlet of controlled cross-section and charged into a cavity. In order to carry out the method, an apparatus is provided which comprises a mixing chamber arranged in a housing and having inlet openings for the reactants and an outlet opening for the reaction mixture, wherein an adjustable baffle plate is arranged opposite the outlet opening axially of the outlet opening.
    Type: Grant
    Filed: August 9, 1978
    Date of Patent: February 12, 1980
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gerd Weber, Dieter Skoupi, Hermann Schafer
  • Patent number: 4188457
    Abstract: A bung for closing a wine bottle in the manner of a cork is formed in a conventional injection-moulding machine from ethylene-vinyl acetate copolymer (EVA) with the addition of sodium metabisulphite and sodium bicarbonate. The sodium metabisulphite, which is in stoichiometric excess in relation to the sodium bicarbonate, decomposes to liberate sulphur dioxide. The sodium bicarbonate decomposes to liberate water and carbon dioxide. The bung as moulded accordingly has a foamed core with a liquid-impervious skin. It contains sulphur dioxide, and water enabling the sulphur dioxide to act as an oxygen scavenger when the bung is in use in a wine bottle. The bung therefore provides the bottle with a long shelf life, with no noticeable tainting of the wine.
    Type: Grant
    Filed: April 14, 1977
    Date of Patent: February 12, 1980
    Assignee: Metal Box Limited
    Inventor: Arnold M. Throp
  • Patent number: 4187352
    Abstract: A process for working up thermoplastic synthetic resin material, in particular unsorted thermoplastic synthetic resin waste material into an article having the working and processing properties of wood, and in which the material is subjected to a mixing operation in a housing including a screw member, and is fluidized, moulded, cooled in the mould, and removed from the mould. According to the invention, the synthetic resin material is supplied to an extruder without a screen member and without an extrusion nozzle, and kept therein until there is obtained a material that is fluid owing to temperature increase, and which material contains a gas when it leaves the extruder. The material is then passed into a mould having open ends, one of which is connected to the outlet of the extruder.
    Type: Grant
    Filed: March 7, 1978
    Date of Patent: February 5, 1980
    Assignee: Lankhorst Touwfabrieken B.V.
    Inventor: Eduard J. G. Klobbie
  • Patent number: 4185060
    Abstract: Thermoplastic granules mixed with a blowing agent are processed in a barrel unit which encloses a rotating screw which mixes, works and plasticizes the mixture so that at the leading end of the barrel it is in a molten condition suitable for extrusion or injection molding. The screw has two compression stages with an intermediate decompression stage therebetween. At a location corresponding to the decompression stage of the screw the barrel has a vent therein which permits the escape of moisture vapors and other unwanted volatiles in the mixture. At the vent zone the forward faces of the screw flights are undercut to minimize the discharge of mixture through the vent.
    Type: Grant
    Filed: March 17, 1978
    Date of Patent: January 22, 1980
    Inventor: Michael Ladney, Jr.
  • Patent number: 4164523
    Abstract: Shaped synthetic-resin bodies are made in a separable mold by injecting a flowable mass of a synthetic-resin material into the mold cavity. To precool the mass and cause an initial setting at least of the surface thereof, a liquefied gas, i.e. a low-boiling liquid which is in a gaseous state at room temperature and atmospheric pressure, is introduced between the mass and the walls of the cavity. The coolant is discharged from the cavity through at least one controllable cross-section outlet to regulate the contact time between the coolant and the mass. The initially set precooled body is ejected from the mold and is subjected to final cooling and temperature homogenization (tempering), e.g. in a liquid bath.
    Type: Grant
    Filed: April 5, 1978
    Date of Patent: August 14, 1979
    Inventor: Robert Hanning
  • Patent number: 4159368
    Abstract: Polystyrene (copolymer) foam is produced by forming a polystyrene (copolymer) solution in an hermetically sealed container using a solvent having a high vapor pressure and a low boiling point, and progressively releasing the thus formed solution under temperature and pressure conditions allowing rapid evaporation of the solvent.
    Type: Grant
    Filed: September 27, 1976
    Date of Patent: June 26, 1979
    Assignee: Etablissements Francois Salomon et Fils
    Inventor: Georges P. J. Salomon
  • Patent number: 4155969
    Abstract: A method for the manufacture by foam molding of plastic products by first injecting into a mold non-cellular plastic resin and then injecting a foamed plastic resin of the same basic composition as the non-cellular plastic resin. The process and apparatus consisting of a single extruder and single injection chamber wherein the non-cellular and foamed plastic resin are extruded from the same extruder and stored in an accumulator until shot into the mold by a hydraulic cylinder. Controls are provided for the correct amount of each type of resin to be extruded and stored and the process can be adapted so that the sprue portion of the final product will be solid resin. By a simple addition, coloring of the resin may be accomplished so that the basic resin, method or apparatus will not require changes.
    Type: Grant
    Filed: October 25, 1977
    Date of Patent: May 22, 1979
    Assignee: Ex-Cell-O Corporation
    Inventor: James W. Hendry
  • Patent number: 4154784
    Abstract: Unitary molded plastic hinged article and method of making in which a fluid molten mixture of heat softenable resin and a blowing agent in substantially unfoamed condition is introduced into an expandable mold cavity to fill the cavity and the mold is expanded to allow foaming of the resin to form at least one foam cored article section while the resin adjacent the mold surface is still fluid and in which the hinge structure is formed by a member adapted to form a thin, flex portion and portions transitional from the thickness of the flex portion to the thickness of a cored article section, the shaping member being slidably disposed in an aperture in the mold with portions of the walls of the aperture exposed within the mold cavity at the time the molten mixture is introduced and the exposed portions of the walls being wiped by the shaping member when the mold is expanded.
    Type: Grant
    Filed: April 20, 1978
    Date of Patent: May 15, 1979
    Assignee: USM Corporation
    Inventor: Edward A. Ruhl
  • Patent number: 4153657
    Abstract: Polyurethane foam is used in a three-piece vehicle wheel as a load bearing and load transmitting structural element. The rim of the wheel, an inner wheel disc, and an outer decorative wheel disc are bonded together by the polyurethane foam. The rim includes an interlock lip to interlock the rim with the inner disc and an interlock lip that interlocks the rim with the outer decorative disc. The wheel can be manufactured by placing the rim, inner disc, and outer disc in a die and injecting the polyurethane foam composition into the interconnected volume enclosed and defined by those wheel components. The foam curing process then occurs in situ. Alternatively, the rim, inner disc, and outer disc can be adhesively bonded to a preformed polyurethane foam member. The resultant vehicle wheel, manufactured by either process, is characterized by high strength, light weight, and a decorative appearance.
    Type: Grant
    Filed: October 31, 1977
    Date of Patent: May 8, 1979
    Inventor: Raymond J. Wilcox
  • Patent number: 4152798
    Abstract: A process for producing cork lines which comprises holding a leader or lers with a pair of metal molds having at the junctional surfaces thereof one or more cavities for forming a float or floats and one or more furrows formed so as to pass through said cavity or cavities for holding said leader or leaders, injecting a molten synthetic resin mixed witha foaming agent into said cavity or cavities to effect molding and foaming of said resin, cooling said metal molds and taking out a flat or floats integrally fixed to said leader or leaders from said metal molds.
    Type: Grant
    Filed: April 27, 1977
    Date of Patent: May 8, 1979
    Assignee: (Ashimoro Industry, Co., Ltd.) Ashimori Kogyo Kabushiki Kaisha
    Inventors: Seshiro Akaura, Yasushi Nagamune, Takeshi Nakamura
  • Patent number: 4152495
    Abstract: Certain polymeric modifiers are surprisingly effective for injection molding and extruding thermoplastic structural foam of lower density, improved appearance, more uniform cell structure, and for lowering injection molding cycle time.
    Type: Grant
    Filed: April 6, 1976
    Date of Patent: May 1, 1979
    Assignee: Rohm and Haas Company
    Inventor: Russell A. Labar
  • Patent number: 4150074
    Abstract: Multi-station reaction injection molding apparatus, and method, are disclosed for in-place foaming of polymerizable resins in articles advanced along a production line, as for example in the manufacture of insulated appliance housings such as refrigerator cabinets. The articles are selectively diverted from a feed conveyor, one to each of a plurality of pour stations adjacent the feed conveyor. At the stations, injection of foamable resin mix is accomplished by reaction injection type molding heads which combine at least two liquid resin components. These components are suitably catalyzed to react and form a cellular or foamed polymerized resin. The liquid components are separately but continuously supplied to respective supply manifolds to which all of the heads are connected in parallel by shunting ducts. Excess unmixed liquid components are returned separately from each of the heads through recycle shunting ducts to respective recycle manifolds.
    Type: Grant
    Filed: December 28, 1976
    Date of Patent: April 17, 1979
    Assignee: The Upjohn Company
    Inventor: Peter J. Tilgner
  • Patent number: 4144297
    Abstract: A method of forming a ball core is disclosed. A flowable homogeneous mass of a thermoplastic resin and a blowing agent is injected into the spherical cavity of a mold under temperature and pressure conditions sufficient to activate the blowing agent. The mold is cooled to 32.degree. to 65.degree. F. so as to form a skin on the surface of the mass. The mass is held within the mold cavity for a sufficient time so that the skin has adequate strength to prevent its rupture by blowing agent contained within the mass, upon removal of the mass from the mold cavity. The mass is cooled at an exterior temperature of 32.degree. to 65.degree. F. A ball core for baseballs and softballs is also disclosed.
    Type: Grant
    Filed: December 7, 1977
    Date of Patent: March 13, 1979
    Assignee: Home of Champions, S. A.
    Inventor: Julius Tomar
  • Patent number: 4141944
    Abstract: A process is provided for producing an imitation wood workpiece by forming a synthetic resin workpiece having a cellular plastic core and a densified covering layer after extruding and solidifying synthetic resin and thereafter imparting an appearance of wood grain to the synthetic resin workpiece by heating the densified covering layer of the workpiece and by relief embossing texture furrows in portions of the densified covering layer.
    Type: Grant
    Filed: March 25, 1977
    Date of Patent: February 27, 1979
    Assignee: Gebruder Kommerling Kunststoffwerke G.m.b.H.
    Inventors: Gerd L. Anstadt, Helmut Kesseler
  • Patent number: 4140672
    Abstract: A process for producing moldings comprises the steps of injecting a plastified synthetic resin into a mold cavity, thereafter or simultaneously injecting heated fluid having a viscosity of 0.01 - 100 poise into the same mold cavity to fill it with said fluid in such a manner that said heated fluid is surrounded by said synthetic resin within said mold cavity and releasing said fluid from said mold cavity after at least a portion of said synthetic resin has set. If the injected synthetic resin contains any foaming agent, a foamed article having its outer smooth skin can be obtained according to the present invention. If the injected synthetic resin contains no foaming agent, a hollow, smooth-surfaced article can be obtained.
    Type: Grant
    Filed: January 4, 1978
    Date of Patent: February 20, 1979
    Assignee: Asahi-Dow Limited
    Inventor: Hiroshi Kataoka
  • Patent number: 4133858
    Abstract: This invention relates to an improved injection foam molding method in which a foamable mixture of molten synthetic polymer resin and a chemical blowing agent in unfoamed condition is injected into a gas-pressurized expandable mold having a mold section movable for expanding the mold cavity to a position in which the surface of that section is in registry to the surface of another mold section, in which process the mold is filled under conditions resisting foaming of the material prior to filling of the mold and a novel controlled time sequence effective to form a fine mold crease line is employed in releasing the gas pressure and expanding the mold to allow foaming of the mixture into conformity with the mold surface.
    Type: Grant
    Filed: December 14, 1977
    Date of Patent: January 9, 1979
    Assignee: USM Corporation
    Inventors: Akifumi Hayakawa, Akira Aiba, Eiki Orihara, Kiyoshi Fukushima
  • Patent number: 4129636
    Abstract: A process is provided for introducing mixed foamable reactants to a mold. The process involves introducing the reactants into a mixing chamber through injection apertures in its side wall portion. The mixing chamber has an outlet aperture communicating with the cavity of the mold. Prior to introducing the reactants into the mixing chamber, a displacement piston having a smaller cross-section than the mixing chamber is inserted into the outlet aperture of the mixing chamber so that the injection apertures communicate with the mold cavity by means of a generally annular passage.
    Type: Grant
    Filed: November 18, 1976
    Date of Patent: December 12, 1978
    Assignee: Bayer Aktiengesellschaft
    Inventors: Heinrich Boden, Ulrich Knipp
  • Patent number: 4129635
    Abstract: Foamable synthetic resin materials are plastified and injected into a mold cavity in an amount less than the volume of mold cavity and a body of gas under pressure is charged in the mold cavity in such manner that it is enclosed by said resin materials. When the injected resin materials sets at least at its outer surface layer, the gas is discharged out of the mold cavity so that the foamable resin materials can be expanded in the hollow portion formed by the pressure of the charged gas. Said foamable resin materials may be surrounded by unfoamable resin materials in the mold cavity.
    Type: Grant
    Filed: July 8, 1977
    Date of Patent: December 12, 1978
    Assignee: Asahi-Dow Limited
    Inventors: Akio Yasuike, Hiroshi Kataoka, Kaoru Toyouchi
  • Patent number: 4126662
    Abstract: An injection molded polymer having limited surface gloss is provided by preparing an admixture of an injection moldable polymer substrate and an additive chosen from among the group consisting of finely divided textile fibers, finely divided hydrocarbon polymers, and blowing agents and injection molding an article from the admixture. In the embodiment of the invention employing blowing agents the admixing is carried out at a temperature below that at which the blowing agent is activated and the injection molding is carried out at a temperature sufficient to activate the decomposition of the blowing agent.
    Type: Grant
    Filed: October 9, 1975
    Date of Patent: November 21, 1978
    Assignee: Phillips Petroleum Co., Inc.
    Inventor: Terence C. Middlebrook
  • Patent number: 4125490
    Abstract: A rigid, dimentionally stable, distortion-free article of foamed polyvinyl aromatic resin, having a solid outer skin, is formed by incorporating in a foamable polyvinyl aromatic resin a finely, divided inert solid that has been surface treated to render the solid hydrophobic and then molding the foamable composition under foaming conditions. Foamed polyvinyl aromatic resin articles molded in accordance with the present invention have physical dimensions capable of meeting tolerances in the order of .+-. 0.002 inches and are suitable for use in the manufacture of precision measuring devices and, particularly, frames for level instruments.
    Type: Grant
    Filed: April 6, 1976
    Date of Patent: November 14, 1978
    Inventor: Siebolt Hettinga
  • Patent number: 4115491
    Abstract: Thermoplastic articles with highly porous cores and less porous or nonporous skins are injection-molded with the aid of a nozzle having a flow divider disposed upstream of its aprue for splitting the oncoming plastic mass into a homogeneous outer stream and an inner stream admixed with a foaming agent, the two streams merging inside the gate of a mold cavity. The foaming agent enters through a central channel which may be provided with one or more ducts alternately usable to introduce pressure fluid and coolant into the cavity lined with coalescing layers of nonfoamed and foamed plastic. The flow divider may be axially movable within the nozzle to serve as a control valve and flow regulator.
    Type: Grant
    Filed: May 17, 1976
    Date of Patent: September 19, 1978
    Inventor: Robert Hanning
  • Patent number: 4111861
    Abstract: This invention relates to compositions and methods for forming polyether polyurethanes utilizing internal release additives for the purpose of facilitating mold release in the production of molded objects. The invention discloses four classes of internal release additives: (1) mixtures of aliphatic or aryl carboxylic acid and a polar metal compound; (2) carboxyalkylsiloxanes; (3) aliphatic glyoximes; and (4) aralkyl quaternary ammonium salts.
    Type: Grant
    Filed: September 24, 1976
    Date of Patent: September 5, 1978
    Assignee: Union Carbide Corporation
    Inventor: Robert Everett Godlewski
  • Patent number: 4096218
    Abstract: A method of producing foamed thermoplastic resin articles having smooth and glossy surfaces free from swirl marks and hair cracks, which comprises melting a thermoplastic resin containing a condensable blowing agent and an organic chemical blowing agent, injecting, in full shot, the molten resin into a mold cavity to which a pressurized gas is being applied during said injection, terminating the application of the pressurized gas to the mold cavity, enlarging the volume in said molded cavity by movement of a mold wall, and thereafter cooling and solidifying the resin to form the foamed articles.
    Type: Grant
    Filed: July 27, 1976
    Date of Patent: June 20, 1978
    Assignee: Asahi-Dow Limited
    Inventors: Akio Yasuike, Tsutomu Odagiri, Toshiba Machine Co. Limited
  • Patent number: 4092385
    Abstract: A method of injection molding foamed articles wherein, after the mold is closed and while the mold is held closed, a gas counterpressure is generated within the mold cavity against which a portion of the foamable resin is injected under a pressure which prevents foaming. Thereafter, a shape-forming element adapted to be retracted to be flush with a wall of the mold cavity in the final phase thereof, is advanced to force the nonfoamed material, still against the gas counterpressure, into the remainder of the cavity. After a skin has formed, on the mass within the mold cavity the latter element is retracted to permit foaming, preferably after foaming has been initiated by allowing a portion of the foamable mass to recede into the injection cylinder during the inception of the foaming process.
    Type: Grant
    Filed: November 24, 1975
    Date of Patent: May 30, 1978
    Assignee: Institute Po Metaloznanie I Technologia Na Metalite
    Inventors: Angel Tonchev Balevski, Ivan Dimov Nikolov, Evgeni Hristov Mateev, Todor Kostadinov Trifonov, Vassil Vladimirov Kojuharov
  • Patent number: 4078875
    Abstract: Process and apparatus for injection molding plastic to provide a foamed core with an unfoamed outer skin.
    Type: Grant
    Filed: February 2, 1977
    Date of Patent: March 14, 1978
    Assignee: Schloemann-Siemag Akt.
    Inventor: Helmut Eckardt
  • Patent number: 4073844
    Abstract: In a method for the preparation of crosslinked polyolefin foams by charging a polyolefin or its blend with other thermoplastic resins containing a crosslinking agent, foaming agent and if necessary a filler into the heated mold having a changeable cavity and, after decomposition of the crosslinking and foaming agents, retracting the moving-plate of the mold by a definite distance to increase the cavity and at the same time cooling the mold, an improvement for the preparation of the crosslinked polyolefin foams having excellent appearance and dimensional stability, comprising using a mold of which the moving-plate is constructed with a body and a sliding-piece, the body holding the piece slidably whereby the sliding-piece is left behind owing to sliding between the two even on rapid retraction of the body and then retracts at the rate corresponding to the foaming pressure of the resin, in other words, at a self-controllable rate and the mold for the preparation thereof.
    Type: Grant
    Filed: March 15, 1976
    Date of Patent: February 14, 1978
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Motomu Wada, Masakazu Inoue, Kazunori Furukawa, Shigeyoshi Matsubara
  • Patent number: 4070426
    Abstract: A method of making nylon (polycarbonamide) foam involving the use of a multi-phase carboxylic acid-containing polymer which reacts with the amine groups of the nylon to produce water which blows the foam during the process.
    Type: Grant
    Filed: March 22, 1977
    Date of Patent: January 24, 1978
    Assignee: Rohm and Haas Company
    Inventor: Marshall T. Purvis
  • Patent number: 4067673
    Abstract: An apparatus for the manufacture by foam molding of plastic products by first injecting into a mold solid plastic resin and then injecting a foamed plastic resin of the same basic composition as the solid plastic resin. The process and apparatus consisting of a single extruder and single injection chamber wherein the solid and foamed plastic resin are extruded and stored until shot into the mold by hydraulic pressure. Controls are provided for the correct amount of each type of resin to be extruded and stored and the process can be adapted so that the sprue portion of the product will be solid resin and by a simple addition, coloring may be added so that the basic resin, method or apparatus will not require changes.
    Type: Grant
    Filed: September 2, 1975
    Date of Patent: January 10, 1978
    Assignee: Ex-Cell-O Corporation
    Inventor: James W. Hendry
  • Patent number: 4053545
    Abstract: Novel dense foam articles having a solid plastic sheet coating on at least a portion of the surface are prepared by injection molding plastic foam into a mold containing a thermoformed solid plastic sheet having the configuration of at least a part of the mold and fitted to a matching mold surface.
    Type: Grant
    Filed: July 29, 1975
    Date of Patent: October 11, 1977
    Assignee: Standard Oil Company (Indiana)
    Inventor: Clifford Charles Fay
  • Patent number: 4048275
    Abstract: An injection molding process for forming cross-linked, foamed moldings of an ethylenic polymer by passing a molding composition comprising an ethylenic polymer/cross-linking agent/foaming agent blend through the cylinder of an injection molding machine without substantially decomposing the cross-linking agent and the foaming agent, introducing the molding composition into a molding composition holding chamber provided at the exit end of the cylinder of the injection molding machine to decompose the cross-linking agent and the foaming agent therein, and injecting the molding composition into a mold.The invention also provides apparatus for carrying out the process comprising an injection molding cylinder for conveying and plasticizing the molding composition and a molding composition holding chamber provided at the exit end of the cylinder.
    Type: Grant
    Filed: October 30, 1975
    Date of Patent: September 13, 1977
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Teruyoshi Usamoto, Kenji Miyawaki, Toshiaki Shiota, Hideki Takeuchi, Yoshio Tadokoro
  • Patent number: 4043715
    Abstract: Apparatus for making a foamed plastics product. A foamed plastics product is formed by introducing into an at least substantially fully plasticated material a series of discontinuous gaseous bubbles while said plasticating material is under a substantial and often variable pressure, accumulating said material and intermixed bubbles in an injection zone while maintaining said pressure thereon and thereafter injecting said material into a mold whereupon said pressure is sufficiently released to permit expansion of said gas bubbles and the formation of a foam thereby. Said gas is introduced, as aforesaid, by a series of separate injections wherein the pressure on the gas being injected rises from substantially zero to a level potentially in excess of the highest pressure expected to be developed within the plasticating means.
    Type: Grant
    Filed: June 2, 1975
    Date of Patent: August 23, 1977
    Assignee: Ex-Cell-O Corporation
    Inventor: James W. Hendry
  • Patent number: 4033710
    Abstract: Thermoplastic articles with highly porous cores and less porous or nonporous skins are injection-molded with the aid of a nozzle having a flow divider disposed upstream of its sprue for splitting the oncoming plastic mass into a homogeneous outer stream and an inner stream admixed with a foaming agent, the two streams merging inside the gate of a mold cavity. The foaming agent enters through a central channel which may be provided with one or more ducts alternately usable to introduce pressure fluid and coolant into the cavity lined with coalescing layers of nonfoamed and foamed plastic. The flow divider may be axially movable within the nozzle to serve as a control valve and flow regulator.
    Type: Grant
    Filed: July 25, 1975
    Date of Patent: July 5, 1977
    Inventor: Robert Hanning
  • Patent number: 4017225
    Abstract: An apparatus for the production of injection-molded synthetic-resin bodies having core portions and skin portions of different densities wherein a blowing agent is introduced into the core material to form macroscopic bubbles or cavities therein within the mold and under the molding conditions so that the expanding body of core material presses the skin material against the walls of the mold. The core material is injected coaxially with the skin material but under conditions such that expansion under the effect of the macropore-producing blowing agent does not occur to any significant extent until the core material is within the mold. This is a division of application Ser. No. 507,465, filed Sept. 19, 1974.
    Type: Grant
    Filed: April 29, 1975
    Date of Patent: April 12, 1977
    Assignee: Societa Internazionale per lo Sfruttamento di Brevetti S.A.
    Inventor: Robert Hanning
  • Patent number: 4014966
    Abstract: A method of injection molding a body of synthetic resin with a smooth surface and a porous core, which comprises the steps of injecting into a mold first outer synthetic resin forming a smooth surface of the body and thereafter synthetic-resin core material containing an expanding or foaming agent. Only part of the outer material is first injected, the remainder being injected simultaneously with the synthetic-resin core material.
    Type: Grant
    Filed: November 5, 1974
    Date of Patent: March 29, 1977
    Inventor: Robert Hanning
  • Patent number: 4013391
    Abstract: An apparatus for mixing and molding a chemically foamable reaction mixture is comprised of a mold with a mixing chamber which has its outlet aperture in a wall of the mold and a displacement piston mounted in the opposite wall. An ejector piston is displaceable within the mix chamber and may be so channelled as to serve as a control piston. This ejector piston is displaceable from a position wherein the injection apertures lie between it and the mold cavity to a position wherein its end surface is flush with the mold wall. The displacement piston is so mounted that it may extend across the mold cavity and intrude into the outlet aperture of the mixing chamber. This displacement piston has a diameter smaller than the diameter of those portions of the mixing chamber into which it protrudes so that when this piston is within the mixing chamber an annular cavity is formed between it and the side walls of the mixing chamber. It is withdrawable to a position flush with the mold wall it protrudes through.
    Type: Grant
    Filed: March 14, 1975
    Date of Patent: March 22, 1977
    Assignee: Bayer Aktiengesellschaft
    Inventors: Heinrich Boden, Ulrich Knipp
  • Patent number: 3991146
    Abstract: Encapsulating an insert in plastics by injection moulding with one face of the insert bearing against the mould thus supporting the insert against movement during injection with subsequent relative movement between insert and the supporting mould face to allow the injected material to flow round that face of the insert.
    Type: Grant
    Filed: March 27, 1975
    Date of Patent: November 9, 1976
    Assignee: Imperial Chemical Industries Limited
    Inventor: Ian Torrance Barrie
  • Patent number: 3991147
    Abstract: A process for molding foam products substantially free from flaws caused by air bubbles in the foamable reaction mixture wherein a foamable reaction mixture having a viscosity .eta. in cP between 100 cP and 2500 cP is introduced into a mold cavity through an opening in the mold wall and against the wall of the cavity opposite the opening of a mold in which the thickness of the cavity and the thickness s of the resulting molded product adjacent to the opening at the time the mixture is introduced into the cavity is maintained at 0.5 mm to 15 mm under conditions whereby the radial distribution rate w.sub.radial in m/sec., .eta.
    Type: Grant
    Filed: September 16, 1974
    Date of Patent: November 9, 1976
    Assignee: Bayer Aktiengesellschaft
    Inventors: Ulrich Knipp, Heinrich Boden
  • Patent number: 3988403
    Abstract: A process is disclosed for producing a structural foam article having a surface that reproducibly and faithfully replicates the surface of the mold within which the article was made. The process is an improvement in the "low pressure" process for producing structural foam, wherein the improvement resides in introducing the molten mixture of foamable thermoplastic material and blowing agent into the mold under such conditions that a no-slip boundary condition is maintained at an interface between the flowing thermoplastic and a predetermined portion of the interior surface of the mold, and by maintaining the temperature at said interface at or above a certain temperature (termed "replication temperature"), while the thermoplastic is flowing in the mold.
    Type: Grant
    Filed: May 22, 1975
    Date of Patent: October 26, 1976
    Assignee: Union Carbide Corporation
    Inventors: Richard G. Angell, Jr., Robert J. Anderson, Kenneth E. Hobbs, David E. James, B. Duane Marsh
  • Patent number: 3983196
    Abstract: A settable foam plastic product being formed in a mold cavity is compressed, after a film has formed on the surface of the product, but before final setting of the product. This compression step, which is carried out by reducing the volume of the mold cavity, has the advantage of increasing the accuracy of reproduction of fine surface detail. The compression step also permits stops to be readily removed to enable subsequent full opening of the mold cavity. This use of movable stops in turn facilitates absorption of the forces encountered during the injection step with less massive machine structure than heretofore, resulting in the possibility of economical manufacture of larger products. The machine also includes an improved mold cavity construction in which the parting planes are perpendicular to the main plane of the product, and incorporating laterally movable end and side mold members to facilitate removal of the product and the formation of surface detail on edge surfaces of the product.
    Type: Grant
    Filed: July 18, 1974
    Date of Patent: September 28, 1976
    Assignee: The Dow Chemical Company
    Inventor: Charles H. Gray
  • Patent number: 3982870
    Abstract: Apparatus to practice the method of forming foam molded articles without the defects caused by incompletely mixed reactants in the mold cavity is provided. A mixing chamber bounded by a sidewall portion having injection apertures, an outlet aperture which communicates with the mold cavity and a first ejector piston displaceable within the bore of the mixing chamber is provided. Opposite said outlet aperture is a second ejector piston which is retracted at the start of the mold filling operation to provide a receiving chamber in the mold wall. As the mold filling proceeds, this piston is displaced towards the mold cavity until its end surface forms a planar surface with the mold wall. Optionally, this piston may be displaced into the mold cavity to eject the molded article.
    Type: Grant
    Filed: March 14, 1975
    Date of Patent: September 28, 1976
    Assignee: Bayer Aktiengesellschaft
    Inventors: Heinrich Boden, Ulrich Knipp
  • Patent number: 3962387
    Abstract: Plastic molding machine, primarily adapted for generating and molding a closed-cell foam thermoplastic material. The foam is generated by introducing a gas inert to the thermoplastic material into a granular mixture of same so that the gas is thoroughly intermixed among the granular particles. The gas is then held under pressure while the granular particles are reduced to a flowable material, said pressure being sufficient to assure that the gas will not be expelled therefrom during such process. In one preferred embodiment, gas is mixed into the granular thermoplastic in a hopper and held therein under pressure as said granular material is fed into a screw and plasticated thereby.The plastic material is then conducted at a relatively low pressure, such as that generated by the extrusion machine used for plasticating the material, through a branched system past a check valve in each branch of said system, to an injection assembly.
    Type: Grant
    Filed: July 24, 1973
    Date of Patent: June 8, 1976
    Assignee: Ex-Cell-O Corporation
    Inventor: James W. Hendry
  • Patent number: 3962154
    Abstract: A method for producing an improved molded thermoplastic polymeric resinous article comprising: introducing a heat plastified thermoplastic polymeric resinous material into a mold in the presence of a finely divided inorganic material; cooling said heat plastified thermoplastic polymeric resinous material; removing from said mold said cooled mold shaped thermoplastic polymeric resinous material having finely divided inorganic material incorporated therein.
    Type: Grant
    Filed: May 31, 1974
    Date of Patent: June 8, 1976
    Assignee: Standard Oil Company
    Inventor: Ernst A. Egli
  • Patent number: 3960996
    Abstract: A method of and apparatus for the molding of foamed thermoplastic bodies with integral skins wherein, for each mold operation after the first, a portion of previously foamed material produced by expansion in the mold cavity, is temporarily accumulated behind a body of unfoamed thermoplastic and the foamed and unfoamed material are then forced into the mold cavity and permitted to expand therein.
    Type: Grant
    Filed: September 21, 1973
    Date of Patent: June 1, 1976
    Assignee: Institut po Metaloznanie i Technologia na Metalite
    Inventors: Anguel Tonchev Balevski, Ivan Dimov Nikolov, Asparuh Mihailov Antonov, Stefan Georgiev Semerdjiev
  • Patent number: 3954926
    Abstract: Synthetic-resin bodies, preferably composed of hardenable synthetic resins and especially thermosetting resins are formed by introducing a foamable resin into a mold cavity, setting the foamable resin upon permitting the same to expand to fill the mold cavity, and thereafter introducing into the mold cavity, without changing the volume thereof, at least one additional synthetic resin while the foamed body is plastically deformable but possesses sufficient rupture strength to prevent penetration. The resulting body thus has a surface layer of the second material which displaces the foamed first material.
    Type: Grant
    Filed: June 5, 1972
    Date of Patent: May 4, 1976
    Inventors: Fritz Wilhelm Pahl, Jobst Harreis
  • Patent number: 3953560
    Abstract: The invention relates to structures such as folding (tambour) doors comprising longitudinal juxtaposed slats and comprises a method of making such structures by introducing a molten synthetic resinous mass containing a foaming agent into a mould, permitting foaming of the mass and compressing the mass with a ribbed mould plunger to a predetermined distance above the floor of the mould to constitute the hinges.
    Type: Grant
    Filed: August 28, 1974
    Date of Patent: April 27, 1976
    Assignee: Polycrate (Proprietary) Limited
    Inventor: Andre Klein
  • Patent number: RE28826
    Abstract: A mold for forming plastic foam parts in which an injection-molded plastic member forms a molding surface of the foam molding cavity against which foam plastic is adapted to be molded. The plastic member is preferably injection molded in a metal molding die from either polyethylene or polypropylene so that its molding surface is the reverse of the exterior surface of the plastic part to be foam molded therein. Vent passages and sealing beads may be integrally formed with the injection-molded member.
    Type: Grant
    Filed: April 25, 1975
    Date of Patent: May 25, 1976
    Inventor: Michael Ladney, Jr.
  • Patent number: RE29265
    Abstract: Plastic molding machine, primarily adapted for generating and molding a closed-cell foam plastic material. The foam is generated by introducing a gas inert to the plastic material into a granular mixture of same so that the gas is thoroughly intermixed among the granular particles. The gas is then held under pressure while the granular particles are reduced to a flowable material, said pressure being sufficient to assure that the gas will not be expelled therefrom during the plasticization process. In one preferred embodiment, gas is mixed into the granular plastic in a hopper and held therein under pressure as said granular material is fed into a screw and plasticized thereby.The plastic material is then conducted at a relatively low pressure, such as that generated by the extrusion machine used for plasticizing the material, through a branched system past a check valve in each branch of said system, to an injection assembly.
    Type: Grant
    Filed: March 22, 1976
    Date of Patent: June 14, 1977
    Assignee: Ex-Cell-O Corporation
    Inventor: James W. Hendry
  • Patent number: T984007
    Abstract: a jig-saw puzzle comprises interfitting pieces (1, 2, 3, 4) which when fitted together side-by-side form a three-dimensional upper surface simulating for example hills and valleys. Each piece is formed of a molded open or closed cell thermoplastics foamed core 7 sandwiched between upper and lower thermoplastics skins 8a and 8b. A printed sheet 9 is stuck on to the upper skin 8a. The skins 8a and 9a may be made from any conventional moldable thermoplastics. A preferred thermoplastics is a copolymer of propylene with from 5 to 20% by weight of ethylene made by injecting ethylene into the final stages of an otherwise propylene homopolymerization. The core may be made of the same or different plastics as the skins. Polyurethane is a preferred core material. The printed sheet, which may be paper or fabric, may be stuck on to the upper sheet with adhesive or by penetration or fusing of the skin material into the sheet during molding of the pieces.
    Type: Grant
    Filed: July 26, 1978
    Date of Patent: July 3, 1979
    Assignee: Imperial Chemical Industries Limited
    Inventor: John C. Richardson