Abstract: An "in-situ reactor" is provided to facilitate recovery of metals and salts such as potassium, lithium, gold from salt-bearing natural waters, sediments, and rocks by passing a fluid containing such metals and salts through a reactive chemical bed placed at the bottom of a reactor, the metal and salt bearing fluid flowing through the reactive chemical bed to react with the active components to produce a fluid from which the metals and salts can be more easily extracted.

Abstract: A process for making sodium bicarbonate from Nahcolite-rich solutions utilizes solubility suppression with addition of salt. Hot water pumped into a Nahcolite-rich formation, which may contain salt (NaCl) and other impurities in excess of 6% by weight, dissolves the Nahcolite (NaHCO.sub.3) and salt. The dissolved Nahcolite is brought to the surface as a pregnant brine liquor containing Nahcolite, salt, and other impurities, which is then de-gassed under pressure. The pregnant liquor is then mixed with a salt slurry and its temperature reduced to saturate it with salt and force precipitation of Nahcolite out of the pregnant liquor. Carbon dioxide (CO.sub.2) is injected while mixing the pregnant liquor with the salt to facilitate precipitation and conversion of any sodium carbonate (Na.sub.2 C.sub.3) present into sodium bicarbonate (NaHCO.sub.3). The sodium bicarbonate (NaHCO.sub.3) is dewatered and filtered to form a sodium bicarbonate (NaHCO.sub.

Abstract: A process is described for solubilizing lead contained in ores mineralized with sulphidic minerals by in-situ leaching with an acetic acid and acetate containing solution in presence of an oxidant. The in-situ leaching is conducted by means of drillholes in the ore body. In another embodiment the acetic acid and acetate containing solution is percolated through a bed of crushed untreated rock or unconsolidated mineral particles, mill tailings and/or agglomerated or unagglomerated sulphidic lead containing waste material, forming a pile or a layer in an open vat, in presence of an oxidant. Lead is recovered from the pregnant lead acetate containing solution and the solution may subsequently be recycled to further leaching of lead sulphidic minerals or lead sulphide containing particles.

Abstract: Oceanographic mining uses a flexible cover draped over a submarine ore-bearing stratum. The cover serves as a blanket-like structure for application of a leaching substance and isolation of the leachate and stratum from the surrounding water. The leachate infiltrates the stratum and becomes pregnant with intended materials. The leaching solution is subsequently pumped to the surface. The ores are separated from the pregnant leaching solution, enabling the solution to be used again. The cover supports and arranges anchor and sealing tubes and leachate and pregnant liquor tubes. Pumps are mounted on a platform connected to the cover. The cover is deployed by sinking parallel coils and filling peripheral tubes to uncoil and anchor the cover on a sea bed. One cover is spread by tube and is sunk in a controlled manner.

Abstract: The invention provides caverns and methods for producing caverns in bedded salt deposits for the storage of materials that are not solvents for salt. The contemplated salt deposits are of the bedded, non-domed variety, more particularly salt found in layered formations that are sufficiently thick to enable the production of commercially usefully sized caverns completely encompassed by walls of salt of the formation. In a preferred method, a first bore hole is drilled into the salt formation and a cavity for receiving insolubles is leached from the salt formation. Thereafter, at a predetermined distance away from the first bore hole, a second bore hole is drilled towards the salt formation. As this drill approaches the salt, the drill assumes a slant approach and enters the salt and drills through it in a horizontal direction until it intersects the cavity for receiving insolubles.

Abstract: A process for producing valuable sodium-based chemicals from a brine containing sodium carbonate and sodium bicarbonate, such as those containing from about 8% to about 20% total alkali obtained by contacting water with an underground trona formation by heating the brine at about 100.degree. C. to about 140.degree. C. to evaporate water, convert sodium bicarbonate to sodium carbonate and to drive off resulting carbon dioxide, reacting the brine with reduced sodium bicarbonate with an aqueous sodium hydroxide solution in amounts to convert essentially all of the remaining sodium bicarbonate in the brine to sodium carbonate, cooling to about 5.degree. C. to about 25.degree. C. to precipitate sodium carbonate decahydrate crystals, separating the crystals from their mother liquor, melting the separate crystals to form a sodium carbonate solution, heating the solution to from above about 60.degree. C. to below 110.degree. C.

Abstract: Process for disposing of insoluble tailings that remain when solubilizing uncalcined or calcined trona in the process of producing soda ash, in which the tailings are slurried with water or waste solutions of sodium carbonate and/or sodium bicarbonate, adding an alkali metal hydroxide or alkaline earth metal hydroxide in effective amounts up to about 10% by weight of the aqueous slurrying solution, pumping the slurry into a well connected to an underground mined-out cavity with sufficient pressure to prevent build-up of tailings from plugging the bottom of the well opening, dispersing and settling said tailings in the cavity, removing a liquor from said cavity whose concentration of sodium carbonate and/or sodium bicarbonate has been increased and recovering such enriched liquor for use in the manufacture of sodium-containing chemicals such as soda ash.

Abstract: An improved method for stimulating coal degasification wells comprising the use of a coal comminuting solvent to weaken the cleat structure of a coal seam immediately prior to use of high pressure gas in a gas cavitation process. A solvent such as ammonia is injected into the coal seam and allowed to dissolve materials from the cleat structure for a period of time sufficient to weaken that structure. Thereafter, high pressure gas is injected into the coal seam and suddenly released to cause disintegration of coal surrounding the borehole.

Abstract: Process for removing an industrial residue containing sodium sulphate, in which the sodium sulphate in the residue 7 is treated with a calcium salt 12 to precipitate calcium sulphate 13, which is sent to a rock salt deposit 15, from which an aqueous solution of sodium chloride 16 is withdrawn.The process applies to the residues from the desulphurization of fumes by means of sodium bicarbonate.

Abstract: After they have been washed out, cavities (4) in rock salt contain a large quantity of brine (8) at a temperature which is lower than the temperature of the surrounding formation (2). This means that the cavity cannot be sealed quickly because the brine will expand progressively as it heats up. The method of the invention serves to shorten the time period between the end of working the cavity for salt and being able to abandon the cavity finally from about 30 years to about 2 years. The method consists in injecting quantities of a mixture (12) into the cavity (4), the mixture being of greater density than brine (8) and being capable of setting, with equivalent quantities of brine (8) being returned to the surface, and then in keeping the cavity (4) open after it has been completely filled with mixture (12) for as long as it takes the rock salt (2) to creep and fill up the shrinkage voids which appear during setting of the mixture (12), after which the cavity (4) can be sealed.

Abstract: A method of increasing recovery of mineral and metals during in-situ chemical leaching of earth material by injection of a treating fluid which comprises cationic, organic polymers which are made up of long chain hydrocarbon molecules of very great molecular weight (in excess of 1000 and as great as 1,000,000). Maintaining clays in a flocculated state and preventing the formation of colloidal particles improves permeability during chemical leaching of clay bearing earth materials.

Abstract: An apparatus and method are described for penetrating ice. The apparatus comprises: (a) a confined thermochemical reaction chamber having an inlet opening and an outlet opening and containing therein a substantially immobilized first thermochemical reactant, (b) flow means connected to said inlet for delivering an aqueous second thermochemical reactant to said reaction chamber for exothermal reaction with the first reactant, and (c) said outlet opening comprising discharge means for delivering hot thermochemical reaction product including hot aqueous fluid and/or steam into contact with the ice to be melted and penetrated. In an alternative design, the inlet and outlet may be a single opening with a cyclic or oscillating exothermic reaction taking place within the reaction chamber.

Abstract: Nahcolite solution mining process comprising drilling at least one well into a Nahcolite bed, circulating hot barren aqueous liquor in a cavity in said Nahcolite bed for a time sufficient to produce a pregnant liquor having an increase in the concentration of NaHCO.sub.3 in the range of from about 3 to about 20% while maintaining Na.sub.2 CO.sub.3 concentration in the range of about 0.25-4%, preferably less than 2.5%, withdrawing said pregnant liquor, cooling said pregnant liquor to preferentially precipitate NaHCO.sub.3 therefrom and to produce a barren liquor, recovering said NaHCO.sub.3, and reheating and re-injecting said barren liquor in said well. The cavity temperature is maintained below about 250.degree. F. and preferably below about 200.degree. F. The barren liquor is injected at a pressure of below about 150 psig. The pregnant liquor is extracted at a temperature in the range of from about 85.degree. F. to about 200.degree. F., and the cystallization occurs at a temperature of about 25.degree.-120.

Abstract: Process for obtaining increased yields of minerals from bedded ore desposits in the absence of natural confining beds, by confining the flow of leach solution to the mineralized zone through operation of wells comprising, (a) injecting ground water into the barren zones above and below the mineralized zone while simultaneously injecting leaching solution into the mineralized zone at a single injection well location, and (b) recovering ground water from barren zones while simultaneously recovering leaching solution from the mineralized zone at a single recovery well location.

Abstract: A composition, useful for dissolving sulfur, which comprises a major amount of a disulfide or polysulfide and a catalyst comprising one or more polyalkyleneoxyamines or polyamines, and methods for using the composition in a system to prevent sulfur-plugging, are disclosed.

Abstract: A method for the electro-thermal and electrochemical underground conversion of coal into oil and by-products comprises the steps of inserting an underground probe into a bore hole until the probe is in close proximity to a coal seam. A mixture of air, steam, an electrolyte and a suitable catalyst is supplied to the probe, and the mixture is then sprayed directly on the coal seam through a passage in a nozzle. The probe is also energized with electricity applied to the nozzle to produce an arc between the coal and the probe, simultaneous with the spraying of the mixture on the coal seam. Heat of the combustion from the arc and the steam combine to produce a pyrolysis, oxidation, and reduction of the coal, thereby converting the coal into a gaseous combination of oil and by-products. The arc can be rotated to increase the tunnel diameter. An apparatus for performing the method is also provided.

Abstract: The present invention relates to a new process of heap leaching and comprises the following steps:(a) preparing the ground to receive the heap;(b) forming the heap;(c) sinking injection wells into the heap;(d) injecting the leaching solution by means of injection wells; and(e) recovering the leaching solution at the base of the heap, or by pumping from wells neighboring those used for injection.

Abstract: A method for enhanced mineral recovery from a subsurface earth formation is disclosed. An outer loop borehole is formed from a vertical shaft. A leaching fluid is injected from the surface to the outer loop borehole to leach away minerals in proximity with the loop.

Abstract: A solvent for sulfur consisting of a dialkyl disulfide which is free of any basic substance. It is obtained from a commercial dialkyl disulfide by treatment with a reagent capable of eliminating or blocking the basic substances, particularly amines, which are customarily present in such a product. This reagent may be an acid.The use of the product, after treatment in this manner, for dissolving sulfur which has deposited in the casings of natural gas wells permits the reuse several times of the dialkyl disulfide employed.

Abstract: A process for the recovery of sulfur from sulfur-bearing ores employing an aqueous leaching solution containing calcium monosulfide, calcium hydrosulfide or mixtures of such calcium sulfide species. The sulfur ore is contacted in an extraction zone with the aqueous leaching solution under conditions to solubilize sulfur from the ore in the form of calcium polysulfide. Preferably, the extraction step is carried out at an elevated temperature. The loaded leaching solution is recovered from the extraction zone and applied to a sulfur-production zone. Here the loaded solution is contacted with hydrogen sulfide under conditions to react the hydrogen sulfide with the calcium polysulfide to produce calcium hydrosulfide and elemental sulfur. The calcium hydrosulfide solution is recycled for use as leaching solution in the sulfur extraction zone.

Abstract: A process for sequentially fracturing a subterranean formation containing desired natural resources in which controlled pulse fracturing (CPF) is combined with hydraulic fracturing in the same wellbore. After multiple radial vertical fractures have been created by CPF, a solidifiable gel material is directed into the created fractures during a subsequent hydraulic fracturing procedure. During this procedure, multiple vertical hydraulic fractures initiate in and propagate away from the CPF created fractures thereby bringing the wellbore into communication with the desired natural resources.

Abstract: Metal values, particularly precious metal values, are recovered from fines on a footwall and in the fissures and cracks therein by passing a solution capable of solubilizing the metal values across the footwall. The metal values are preferably adsorbed on to a suitable support such as activated carbon underground and then the support, having the metal values adsorbed thereon, transported to the surface for further processing.

Abstract: A cyclic solution mining method that uses aqueous sodium hydroxide for recovering valuable alkali values, preferably as soda ash, from subterranean deposits of trona or nahcolite, even when such deposits are NaCl-contaminated. The aqueous sodium hydroxide mining solvent is generated via electrodialysis of a recirculating sodium chloride brine stream. Hydrogen chloride that is also generated in the cell's operation is neutralized with aqueous sodium carbonate, to regenerate sodium chloride brine that is recirculated to the electrodialysis cell as brine feed.

Abstract: A process is provided for recovering valuable metals from geothermal brine comprising introducing donor metallic particles into a geothermal zone which is dominated with hot-pressurized geothermal brine which contains a metal value selected from the group consisting of gold value, silver value, copper value, lead value, tin value and mixtures thereof. The donor metallic particle contains a donor metal selected from the group consisting of iron, zinc, aluminum and mixtures thereof. The process further comprises forming a deposit on the donor metallic particles by replacing at least a part of the donor particle with the metal values, producing a stream of the hot-pressurized geothermal brine containing the donor metallic particles which, in turn, contain the deposit of metal values, and separating the donor metallic particles from the thusly produced stream of hot-pressurized geothermal brine.

Abstract: A method for the recovery of mineral resources, such as metallic minerals, petroleum, etc., from solid materials, such as subsurface earth formations, including; partially burning a hydrogen-containing fuel in the presence of an oxidizing agent under conditions to produce partial oxidation products, such as alcohols, hydrogen peroxide, aldehydes, ketones, etc., terminating the burning to prevent decomposition of the partial oxidation products and contacting the solid materials with the partial oxidation products and contacting the solid materials with the partial oxidation products and an alkaline or acidic material.

Abstract: A method for the in situ leaching of a subterranean mineral (e.g. uranium) deposit which permits the use of downflow ion exchange columns without requiring expensive filtration equipment to remove particulate material and/or sediment from the leach solution. The injection and production wells are gravel packed so that all of the heavier particulate material will be filtered from the leach solution as it flows into the production well. The bed of ion exchange resin in the downflow column is then used to filter the finer sediment from the leach solution as the resin adsorbs the uranium from the leach solution. The barren leach solution from the ion exchange column can be used to makeup fresh leach solution without any further filtration. The loaded resin is removed from the ion exchange columns and is screened to remove the fine sediment. The resin is then eluted and screened again to remove any sediment that may accumulate during elution.

Abstract: Mineral values, particularly uranium, are recovered from subsurface earth formations containing the same, as well as cations which form precipitates with sulfuric acid leach solutions, by injecting into at least one injection well a preliminary acidic solution capable of forming soluble materials with at least one of the precipitate-forming cations, such as calcium and iron cations, passing the preliminary acidic solution through the subsurface formation for a time sufficient to form such soluble materials, withdrawing the preliminary acidic solution containing the solubilized materials from at least one producing well, thereafter, injecting a sulfuric acid leach solution into said injection well, contacting the subsurface formation with the leach solution for a time sufficient to extract significant amounts of mineral values from the formation and produce a pregnant leach solution containing the thus solubilized mineral values and withdrawing the pregnant leach solution from the production well.

Abstract: An earth battery which includes a first electrode which is a veined material located in the earth, a second electrode electrically connected to the surface of the earth and disposed in a hole which extends from the surface of the earth into the first electrode, an electrolyte disposed in the hole and in contact with the first and second electrodes, and means for electrically connecting the first electrode to the surface of the earth. A seam of coal is preferred as the first electrode. A method of mining metals located in the earth using the earth battery and a method of drilling holes in the earth are also disclosed.

Abstract: In accordance with the present invention, mineral values are recovered from subsurface earth formations containing the same as well as calcium-containing materials by injecting into at least one injection well an aqueous sulfuric acid leach solution adapted to extract such mineral values from the subsurface formation and containing a solubility increasing agent, such as sodium chloride, adapted to significantly increase the solubility of calcium sulfates in water, in an amount sufficient to thus increase the solubility of calcium sulfates in water, contacting the subsurface earth formation with the leach solution for a time sufficient to extract significant amounts of mineral values from the formation and produce a pregnant leach solution containing the thus extracted mineral values and to thus solubilized significant amounts of calcium sulfates and withdrawing the pregnant leach solution from at least one producing well.

Abstract: Mineral values, particularly uranium, are recovered in situ from a heterogeneous subsurface earth formation containing the mineral values, which formation comprises zones of both high and low permeability, including injecting a plurality of separate slugs of leach solution adapted to solvate the mineral values into at least one injection well in communication with all zones of the formation, injecting a slug of a gas which is essentially insoluble in the leach solution between each two successive volumes of leach solution and withdrawing the pregnant leach solution, containing mineral values, from at least one production well in communication with all zones of the formation. The method can be further improved by injecting a mobility modifier, adapted to decrease the mobility of the leach solution, at the trailing end and/or leading end of the leach solution which is in contact with a slug of the gas. In a preferred embodiment, the mineral values contain significant amounts of uranium.

Abstract: In a process for the uniform distribution of a two phase gas/liquid or liquid/liquid mixture comprising delivering a first stream of said mixture to a point, and dividing the first stream at the point into at least two streams, the improvement comprising creating a turbulent environment in the first stream just prior to the point at which the first stream is divided into at least two streams.

Abstract: This invention relates to a process for reducing to environmentally acceptable levels the amount of soluble or mobile contaminants in formations that have been subjected to in situ leaching to recover mineral values therefrom. The present process is also applicable to surface milling operations. In accordance with the present invention, an aqueous solution containing orthophosphates is introduced into the formation to immobilize contaminants by forming a relatively stable precipitate. For example, radionuclides such as uranium, thorium or radium form stable precipitates with orthophosphates.When the formation fluids contain a high concentration of carbonates, the formation fluids are treated to reduce the carbonates concentration to levels which do not substantially interfere with the phosphate precipitation of contaminants.

Abstract: This invention is a process for comminuting run-of-mine crushed coal by contacting the coal with an aqueous methanol solution for a time sufficient to comminute a substantial portion of the coal to a predetermined particle size. Another aspect of this invention is a process for slurry mining coal which comprises contacting the coal in-situ with an aqueous methanol solution for a time sufficient to comminute a portion of the coal and to form a slurry, and then conveying the slurry to a receiving vessel where the comminuted coal is recovered. Still another aspect of this invention, is to transport the comminuted coal having a desired particle size in slurry form using an aqueous methanol solution as the slurry medium wherein there is further comminution of the coal to improve its burning characteristics.

Abstract: The present invention is directed to heap leach processes for leaching metal values from ore. The heap is constructed with a plurality of cellular heaps formed by loading ore onto an impermeable pad having a raised berm network thereon to separate the pad surface into a plurality of reservoirs. Leach solution percolating through the ore is collected in the respective reservoirs. Additional cellular heaps may be subsequently built overlying the original cellular heaps with an impermeable barrier being placed between stacked cellular heaps to prevent overleaching of underlying cellular heaps. The effluent leach solution from the overlying cellular heap is routed to the underlying reservoir from where it is withdrawn. Use of berms on the surface of the individual cellular heaps permits pooling of leach solution thereon for enhanced leaching. An earthen dam around the heap eliminates ore sides to the heap and insulates the heap during cold weather.

Abstract: In a treatment of carnallitic ores by treatment with a decomposition-brine containing amounts of MgCl.sub.2, KCl and NaCl suitable for precipitating artificial sylvinite in a solution of MgCl.sub.2 saturated in KCl and NaCl, the improvement of adding to said decomposition-brine a collector, e.g., a fatty amine acetate, for the flotation of KCl and a source of gas, preferably a gas-liberating additive such as H.sub.2 O.sub.2, so as to contact newly formed crystal nucleii of KCl selectively with said collector and to contact bubbles of said gas with said collector so as to form a froth enriched in KCl simultaneously with the decomposition of said carnallite, the process being particularly useful for treatment of underground carnallitic ore whereby the froth and brine are withdrawn at the surface, separated, and the brine, after make-up additions, is recycled to the ore formation.

Abstract: An oxygenated lixiviant is transported down an injection pipe into the leach zone at the bottom of an injection pipe, the lixiviant leaches the ore and the pregnant lixiviant containing metal compounds is recovered through a recovery pipe. The metal compounds are separated from the lixiviant and the lixiviant is regenerated, reoxygenated and recycled. The pressure of the lixiviant at the downstream end of the injection pipe is substantially equal to the pressure of the lixiviant at the upstream end thereby permitting maximum oxygenation without any degassing.

Abstract: Separate deposits of trona or nahcolite ore are solution mined with two solvents, aqueous sodium hydroxide and aqueous hydrogen chloride. Aqueous sodium carbonate solution is withdrawn from the region of the NaOH-treated ore deposit, for recovery of soda ash. Aqueous sodium chloride brine is withdrawn from the region of the HCl-treated ore deposit and introduced to an electrodialysis cell to regenerate the two solvents and thereby continue the solution mining cycle.

Abstract: The present invention provides an improved process for the in-situ recovery of mineral values, particularly uranium, from subterranean deposits that exhibit heterogeneous permeabilities in the formation zones. Aqueous solutions of thickening agents or viscosity building agents are utilized to control the mobility of the leaching solutions as they traverse the subterranean formation to solubilize the mineral values therein.

Abstract: A method of recovering boric acid from a subterranean deposit of colemanite ore by solution mining, comprises:supplying a leach solution comprising hydrochloric acid to the subterranean deposit via an injection well in communication therewith, whereby colemanite ore is dissolved and an aqueous pregnant solution of boric acid and calcium chloride is formed in the deposit;withdrawing the pregnant solution of boric acid and calcium chloride from said deposit via a production well in communication therewith;separating boric acid from the withdrawn solution;adding sulfuric acid to the resultant concentrated solution from which boric acid has been separated, whereby hydrochloric acid is regenerated therein and CaSO.sub.4.2H.sub.2 O is formed;separating CaSO.sub.4.2H.sub.2 O from the resultant solution containing regenerated hydrochloric acid thereby forming a regenerated leach solution; andrecycling the regenerated leach solution to the subterranean deposit of colemanite via an injection well.

Abstract: Uranium and other base metals are leached from their ores with aqueous solutions containing bicarbonate ions that have been generated or reconstituted by converting other non-bicarbonate anions into bicarbonate ions. The conversion is most conveniently effected by contacting solutions containing SO.sub.4.sup.= and Cl.sup.- ions with a basic anion exchange resin so that the SO.sub.4.sup.= and Cl.sup.- ions are converted into or exchanged for HCO.sub.3.sup.- ions. CO.sub.2 may be dissolved in the solution so it is present during the exchange. The resin is preferably in bicarbonate form prior to contact and CO.sub.2 partial pressure is adjusted so that the resin is not fouled by depositing metal precipitates. In-situ uranium mining is conducted by circulating such solutions through the ore deposit. Oxidizing agents are included in the injected lixiviant.

Abstract: In the subsurface solution mining of mineral values, especially uranium, in situ, magnesium bicarbonate leaching solution is used instead of sodium, potassium and ammonium carbonate and bicarbonates. The magnesium bicarbonate solution is formed by combining carbon dioxide with magnesium oxide and water. The magnesium bicarbonate lixivant has four major advantages over prior art sodium, potassium and ammonium bicarbonates.

Abstract: A process is described for improving yields and leaching rates of mineral values in highly reducing uranium-bearing formations, while minimizing deleterious environmental impact, by injecting an oxidant such as gaseous air or O.sub.2 into the formation prior to leaching. The preoxidation may be enhanced by the presence of CO.sub.2 gas in the pre-leaching oxidant. The process is particularly suitable for systems employing a CO.sub.2 /O.sub.2 lixiviant. The presence of sulfate ion further improves the leaching rate of such a system.

Abstract: A method is provided for mining deep tar sand deposits which minimizes energy losses and surface subsidance due to cavity collapse. A well is sunk through the overburden and tar sands deposit into the bedrock below the deposit; the well is sealed and pressurized with steam and inert gas. Hot aqueous fluid is directed against the deposit to melt the tar and form a tar-sand-water slurry which is passed to a surface recovery plant. Pressure is maintained in the well sufficiently high to hold the overburden. Energy losses are minimized by maintaining the pressure both in the well and the surface plant above the boiling point of the water at the temperature used, which may be as high as 450.degree. F. or more, subsidence is prevented by keeping at least a 10 foot thick ceiling of tar sands throughout the operation, and by backfilling the well with an aqueous slurry of sand after mining operations are complete, before releasing pressure on the well.

Abstract: Leached formations having residual soluble uranium minerals therein are restored by treating the formation under alkaline conditions with a source of phosphate ion whereby insoluble uranium phosphate compounds are formed thereby lowering the residual soluble uranium levels below that existing prior to restoration and the formation, and preferably to levels below about 5 milligrams per liter.

Abstract: The present invention relates to a process for the recovery of uranium and other minerals from uranium ore where at least part of the uranium is present as refractory uranium-mineral complexes, comprising subjecting the uranium ore to mild oxidative carbonate leach fluid to dissolve and remove readily soluble uranium minerals, subsequently subjecting the uranium ore to an oxidative chemically severe leaching system to dissolve and remove the refractory uranium-mineral complexes, and separating and recovering the uranium and other mineral species in the leachate fluids. The process may be applied to in-situ uranium leaching operations or to surface leaching operations.

Abstract: A method of solution mining wherein a lixiviant containing both leaching and oxidizing agents is injected into the subsurface orebody. The composition of the lixiviant is changed by reducing the level of oxidizing agent to zero so that soluble species continue to be removed from the subsurface environment. This reduces the uranium level of the ground water acquifier after termination of the lixiviant injection.

Abstract: The present invention relates to a method for improving the recovery of mineral values from ore bodies subjected to in-situ leaching by controlling the flow behavior of the leaching solution. Foam is introduced into the higher permeability zones of the ore body to act as a diverting agent forcing the leaching fluids into the lower permeability previously non-contacted areas resulting in increased mineral values recovery.

Abstract: A method of solution mining a bed of soluble ore disposed in a sloping subterranean strata disposed beneath an insoluble stratum by developing contemporaneous multiple cavities through the same borehole.

Abstract: Uranium can be extracted from its ores at a pH of 2.5 to 5.5 using sulfuric acid, hydrogen peroxide, trace of iron and a sulfate. The extraction process is applicable to both tank leaching of conventionally mined ores and in situ leaching.

Abstract: This is a method to connect two or more drill holes, such as drill holes at distances of 2,000 to 5,000 feet or more apart, for the purpose of producing soluble ores, such as sylvanite or carnallite, from thick, deep ore bodies or from thin, shallow ore bodies. The drill holes are connected utilizing a signal-sending device in an initial drill hole and a sigal-receiving device in a subsequent drill hole. A fluid is injected down one of the holes forcing the effluent from the other hole thus forming a mined-out corridor between the two holes. This procedure can then be repeated with subsequent, offset drill holes.