Abstract: A method for producing a glass article is provided. The method for producing a glass article, the method including preparing a glass to be processed, the glass comprising a glass bulk and a low-refractive surface layer disposed on the glass bulk, and etching away the low-refractive surface layer to form an etched glass, wherein the etching away the low-refractive surface layer comprises: cleaning the low-refractive surface layer with an acid solution; and cleaning the low-refractive surface layer with a base solution after the cleaning it with the acid solution.

Abstract: A traffic cone is provided. The traffic cone includes a triangular base with feet coupled to a bottom side of the triangular base. The traffic cone further includes a cone body having eight surfaces forming an octagonal cone shape coupled to the triangular base, wherein the cone body extends from a top side of the triangular base. Additionally, the traffic cone includes at least one reflective member coupled around a perimeter of the cone body.

Abstract: The present disclosure describes methods of attaching surfaces together. In one aspect, a method includes depositing a first adhesive onto a first surface of a first item, the first adhesive forming a pattern that at least partially surrounds a region of the first surface where there is no first adhesive. A second adhesive is jetted onto the region of the first surface, wherein the second adhesive has a viscosity lower than a viscosity of the first adhesive. The first surface of the first item and a second surface of a second item are brought into contact with one another. The method also includes curing the first and second adhesives. While the methods can be particularly suitable for manufacturing optical light guide elements, the methods also can be used in other contexts and applications as well.

Abstract: The invention discloses a lens, which comprises an outer surface and an inner surface, wherein a pattern outline is printed on the outer surface; and an argon gas layer, a high refractive index layer, a lower refractive index layer and a waterproof layer are evaporated at an area, outside the pattern outline, of the outer surface from inside to outside in turn. By adoption of clear patterns formed on the outer surface by the manufacturing processes and a four-layer vacuum electroplating film evaporated at an area, outside the pattern outline, of the outer surface, the coating does not block the sight and the lens is more beautiful and has the functions of radiation resistance and ultraviolet resistance. The invention also discloses a pattern printing and vacuum electroplating method which has simple and efficient processes and realizes the functions of the coated lens.

Abstract: In one aspect, there is provided a retroreflective film, comprising a retroreflective sub-structure, and a transparent polymeric film, having a surface roughness profile where the Arithmetic Mean Deviation of the Roughness Profile (Ra) ranges from about 0.18 microns to about 1.30 microns and where the Mean Spacing of Local Peaks (R-S) in the printing direction ranges from about 10 microns to about 85 microns, located over and coupled to the retroreflective sub-structure and wherein the polymeric film as a Vicat softening point of about 90° or greater.

Abstract: In one aspect, there is provided a retroreflective film, comprising a retroreflective sub-structure, and a transparent polymeric film, having a surface roughness profile where the Arithmetic Mean Deviation of the Roughness Profile (Ra) ranges from about 0.18 microns to about 1.30 microns and where the Mean Spacing of Local Peaks (R-S) in the printing direction ranges from about 10 microns to about 85 microns, located over and coupled to the retroreflective sub-structure.

Abstract: The invention relates to a method of treatment of a retroreflective sheet with a treatment composition that comprises a fluorinated compound having one or more silyl groups and an auxiliary compound selected from the group consisting of (i) one or more non-fluorinated compounds of an element M selected from Si, Ti, Zr, B, Al, Ge, V, Pb and Sn and (ii) an organic compound having a Si—H group. The invention also relates to compositions comprising (i) a fluorinated compound comprising one or more silyl groups and (ii) an auxiliary compound selected from the group consisting of organic compounds having a Si—H group.

Abstract: The hue variable retroreflective sheet of the present invention includes: a surface layer (1) composed of at least one layer; and a plurality of retroreflective elements (3, 4, 5) that are positioned beneath the surface layer, wherein the retroreflective elements (3, 4, 5) retroreflect incident light toward a light source direction, at least one layer of the surface layer (1) is an optical coherent layer that changes in color depending on a point of view, and in which an optical coherent coloring material with a core material having a surface that is covered with one or more substantially transparent coating layer is dispersed, and mirror-reflects the incident light toward a direction opposite to the light source side, at least one layer of the retroreflective sheet is a colored layer containing a coloring material that colors retroreflected light, and the retroreflected light and the mirror-reflected light provide different hues.

Abstract: A method of making a polymer coating on a microstructured substrate. The method may be performed by vaporizing a liquid monomer or other pre-polymer composition and condensing the vaporized material onto a microstructured substrate, followed by curing. The resulting article may possess a coating that preserves the underlying microstructural feature profile. Such a profile-preserving polymer coating can be used to change or enhance the surface properties of the microstructured substrate while maintaining the function of the structure.

Abstract: The invention relates to a method of treatment of a retroreflective sheet with a treatment composition that comprises a fluorinated compound having one or more silyl groups and an auxiliary compound selected from the group consisting of (i) one or more non-fluorinated compounds of an element M selected from Si, Ti, Zr, B, Al, Ge, V, Pb and Sn and (ii) an organic compound having a Si—H group. The invention also relates to compositions comprising (i) a fluorinated compound comprising one or more silyl groups and (ii) an auxiliary compound selected from the group consisting of organic compounds having a Si—H group.

Abstract: A method of producing a retro-reflective heat transfer film includes heat-joining a PET release film and a transparent TPU sheet; forming a sticky-adhesive layer or a hot melt adhesive layer on the surface of the transparent TPU sheet; fixing glass beads made of beads with a refractive index of 2.2 to the semi-finished sheet; coating a thin film of transparent resin on the surface of the glass beads, and then forming an aluminum vacuum-coating layer on the coated thin film and forming a reflective resin layer transparent, colored or with graphics on the surface of the aluminum vacuum-coating layer and then producing a transfer sheet by forming a transparent hot melt resin layer on the surface of the reflective resin layer of the semi-finished sheet subject.

Abstract: A film having a high transmittance and matt property is disclosed which has, on a transparent support 1, a hard coat layer 2 incorporated therein particles 4 of a particle size of 1.0 to 10 ?m that is larger than the layer thickness thereof, and a low-refractive-index layer 3 having a refractive index of 1.45 or less and covering said hard coat layer, wherein a haze value is 1.0% or more, and a total transmittance of light is 93.5% or more. The film having a high transmittance can prevent occurrence of unevenness of display due to thermal expansion of a light-tuning film and occurrence of unevenness of brightness peculiar to the light-tuning film.

Abstract: The invention relates to retroreflective articles such as retroreflective sheeting that comprises a core sheet comprising retroreflective elements and a topcoat wherein the topcoat comprises certain water-borne acrylic polymer(s).

Abstract: This invention relates to light transmitting filters comprising: (a) a light absorbing layer of material having a front surface and a back surface, (b) transparent microspheres embedded in the light absorbing layer and contacting the front surface of the light absorbing layer with portions of the microspheres protruding through the back surface of the light absorbing layer for transmitting light through the light absorbing layer, and (c) a conformed layer of optically clear material having a front surface and a back surface wherein the front surface of the conformed layer is in contact with and conforming in shape with the protruding portions of the microspheres, and wherein the back surface of the conformed layer has a textured finish. The invention also relates to methods of making these light transmitting filters.

Abstract: A light reflective film having a multi-layered structure including a light reflective membrane layer on a web. A plurality of transparent spherical glass beads are provided on the light reflective membrane layer. A transparent film layer is provided on the glass beads and is spaced away from the light reflective membrane layer by an air gap. A transparent coating encapsulates all of the component layers to form the light reflective film. The light reflective film is flexible and durable, and effectively reflects light when under water.

Abstract: A composite on the surface of a substrate, and a method for producing the composite are disclosed. The composite includes a first coating, reflective beads, and a clear coating. The method for preparing the composite includes the stepwise application of coating compositions and reflective beads. The composite, which is wear-resistant and retroreflective, is useful as a traffic marking.

Abstract: Novel optical devices based on diamondoid-containing materials are disclosed. Materials that may be fabricated from diamondoids included diamondoid nucleated CVD films, diamondoid-containing CVD films, molecular crystals, and polymerized materials. Devices that may be fabricated from the diamondoid-containing materials disclosed herein include solid state dye lasers, semiconductor lasers, light emitting diodes, photodetectors, photoresistors, phototransistors, photovoltaic cells, solar cells, anti-reflection coatings, lenses, mirrors, pressure windows, optical waveguides, and particle and radiation detectors.

Abstract: This invention relates to retroreflective sheeting which has an image, such as an image. More specifically, the image has varying appearance at different angles of view. The retroreflective sheeting has a layer of transparent microsphere lenses, a transparent polymeric spacing layer underlying, contacting, and conforming to the bottom of the lenses, the spacing and conformation of which is critical to the optimal performance of the retroreflective article, a reflective layer having a top surface in contact with the back surface of the spacing layer and a topcoat and/or cover sheet overlying and conforming to the top surfaces of the lenses and having a flat top surface or face. In another embodiment, the retroreflective sheeting includes a pressure sensitive adhesive underlying and in contact with the reflective layer. The retroreflective sheeting has an image whose proportions are determined by a non-conformity of the reflective and spacing layer to the bottom of the lenses.

Abstract: A process for forming a retroreflective layer on a powder coated substrate is provided. The substrate is powder coated and the powder coating is subsequently partially cured. Reflective elements are then partially embedded in the semi-cured powder. The powder is then fully cured to permanently bond the reflective elements with the powder coating. The resultant retroreflective assembly can be used in any application requiring high detectability in poor visibility conditions, such as road signs and the like.

Abstract: Encapsulated-lens retroreflective sheeting is described which contains an improved binder layer. The binder layer is obtained from a film-forming mixture which comprises: (A) a vinyl chloride copolymer, (B) a thermoplastic polyurethane, and (C) an aminoplast resin. Such binder layer exhibits improved adhesion to metallized beads and to a variety of cover films such as acrylic films.

Abstract: This invention relates to retroreflective sheeting which has an image, such as an image. More specifically, the image has varying appearance at different angles of view. The retroreflective sheeting has a layer of transparent microsphere lenses, a transparent polymeric spacing layer underlying, contacting, and conforming to the bottom of the lenses, the spacing and conformation of which is critical to the optimal performance of the retroreflective article, a reflective layer having a top surface in contact with the back surface of the spacing layer and a topcoat and/or cover sheet overlying and conforming to the top surfaces of the lenses and having a flat top surface or face. In another embodiment, the retroreflective sheeting includes a pressure sensitive adhesive underlying and in contact with the reflective layer. The retroreflective sheeting has an image whose proportions are determined by a non-conformity of the reflective and spacing layer to the bottom of the lenses.

Abstract: Retroreflective sheeting (1) comprises a reflective base (2), a transparent film layer (4) which is colored different from the color of reflected light of the reflective base (2) and a pressure-sensitive adhesive layer (3). The transparent film layer (4) is removably provided on the reflective base (2) via the pressure-sensitive adhesive layer (3). Part (4′) of the transparent film layer (4) is to be cut out on use so that the transparent film layer (4) may form a desired image. The peel strength between the transparent film layer (4) and the reflective base (2) is 25 to 400 gf/25 mm. After the transparent film layer (4) is pressed to the reflective base (2) under a pressure of 5 kgf/cm2, the peel strength between the transparent film layer (4) and the reflective base (2) is 700 gf/25 mm or greater.

Abstract: A wheel rim includes a transparent adhesive layer provided on the surface of the wheel rim, a light-reflective particle layer which is substantially free of any superimposed or overlapping particles and which is formed by spreading solely and uniformly dry light-reflective particles on the transparent adhesive layer and contacting directly the particles with the transparent adhesive layer, the particles having dimensions larger than the thickness of the transparent adhesive layer so that some of the dry light-reflective particles which do not contact the transparent adhesive layer can be allowed to fall off the transparent adhesive layer by gravity, and a transparent protective layer provided on the light-reflective particle layer.

Abstract: The articles of the present invention comprise pavement marking articles which are retroreflective under dry and/or wet conditions. The articles comprise a monolayer of exposed-lens optical elements, a spacing layer, and a reflective layer. The present invention also provides a method of making said pavement marking articles.

Abstract: The articles of the present invention comprise pavement marking articles which are retroreflective under dry and/or wet conditions. The articles comprise a monolayer of exposed-lens optical elements, a spacing layer, and a reflective layer. The present invention also provides a method of making said pavement marking articles.

Abstract: This invention relates to retroreflective sheeting which has an image, such as an image. More specifically, the image has varying appearance at different angles of view. The retroreflective sheeting has a layer of transparent microsphere lenses, a transparent polymeric spacing layer underlying, contacting, and conforming to the bottom of the lenses, the spacing and conformation of which is critical to the optimal performance of the retroreflective article, a reflective layer having a top surface in contact with the back surface of the spacing layer and a topcoat and/or cover sheet overlying and conforming to the top surfaces of the lenses and having a flat top surface or face. In another embodiment, the retroreflective sheeting includes a pressure sensitive adhesive underlying and in contact with the reflective layer. The retroreflective sheeting has an image whose proportions are determined by a nonconformity of the reflective and spacing layer to the bottom of the lenses.

Abstract: Disclosed herein are novel electrophoretic displays and materials useful in fabricating such displays. In particular, novel encapsulated displays are disclosed. Particles encapsulated therein are dispersed within a suspending, or electrophoretic, fluid. This fluid may be a mixture of two or more fluids or may be a single fluid. The displays may further comprise particles dispersed in a suspending fluid, wherein the particles contain a liquid. In either case, the suspending fluid may have a density or refractive index substantially matched to that of the particles dispersed therein. Finally, also disclosed herein are electro-osmotic displays. These displays comprise at least one capsule containing either a cellulosic or gel-like internal phase and a liquid phase, or containing two or more immiscible fluids. Application of electric fields to any of the electrophoretic displays described herein affects an optical property of the display.

Abstract: Glass microspheres and rear projection screens containing glass microspheres, which combine a desirable index of refraction (preferably, no greater than about 1.70) and low levels of defects (e.g., bubbles, visible haziness, frostiness, or opacity, substantially nonspherical shapes) upon formation are provided. Also provided is a coating method of placing microspheres on a film for use in a rear projection screen.

Abstract: This invention provides a method of bonding substantially non-fluorinated polymeric material to a fluoropolymer utilizing a bonding composition comprising primary or secondary di- or poly-amine and a melt-processable, substantantially non-fluorinated component. Multi-layer articles and composite constructions, including retroreflective sheeting and fuel line hoses, made of a fluoropolymer layer and a substantially non-fluorinated layer are also provided.

Abstract: Retroreflective sheeting articles 10 that have a retroreflective bead bond layer 15 that contains a polymer that contains linear crystalline segments and that is incorporated into a crosslinked polymeric network.

Abstract: An article of clothing 10 bearing a retroreflective applique 12 that has a binder layer 14 onto which a retroreflective layer 19 is disposed. The retroreflective layer 19 includes a layer of optical elements 16 and a metal reflective layer 18, and the binder layer 14 includes a thermoplastic copolymer that includes units which contain carboxyl groups. A retroreflective applique, which uses such a binder layer in conjunction with aluminum-coated or silver-coated optical elements, demonstrates very good home laundering durability.

Abstract: Aliphatic polyurethane film forming mixtures, image bearing aliphatic polyurethane films, and image bearing retroreflective sheeting having such image bearing films are described. The image-bearing aliphatic polyurethane films of the invention comprise an aliphatic polyurethane film derived from a film-forming mixture comprising (A) an aliphatic polyurethane, and (B) at least one hydroxy-containing imidazoline surfactant represented by the formula ##STR1## wherein R is an aliphatic group containing from about 10 to about 22 carbon atoms and R.sup.

Abstract: This invention relates to lens type functional retroreflective sheeting having retroreflective regions and visual functionality presenting regions, the retroreflective sheeting comprising:a base sheet consisting of a support comprising a functional resin layer containing a functional pigment having light-storing or fluorescent properties, microspherical lens-embedding regions in which microspherical lenses are densely distributed on the surface of the functional resin layer of the support so as to form a mono-layer, and microspherical lens-free regions in which substantially no microspherical lens is embedded and the functional resin layer is exposed;a transparent protective film disposed above the microspherical lens-bearing surface of the base sheet; andbonds at which said base sheet and said transparent protective film are partly bonded together. This lens type functional retroreflective sheeting not only afford good visibility to viewers positioned in the direction of the light source (e.g.

Abstract: Luminous retroreflective sheetings have a transparent cover layer, an optical layer disposed beneath the cover layer, and a reflective layer. The optical layer includes a first polymer layer and a monolayer of beads at least partially embedded therein. The reflective layer is disposed proximate a focal plane of the monolayer of beads. The monolayer of beads includes transparent beads that, in combination with the reflective layer, retroreflect incident light. The monolayer also includes light-emitting beads that emit light under the influence of an applied voltage or ultraviolet (UV) radiation. Processes for making such sheetings are also disclosed.

Abstract: The present invention discloses lens-type retroreflective sheeting excellent in appearance and having constant thickness and desired retroreflective performance, wherein the transparent microspheres in the retroreflective layer are composed of transparent microspherical lenses (A) having a refractive index of 1.8 or more and transparent microspherical fillers (B) having a refractive index different by at least 5% from the refractive index of the lenses (A).

Abstract: A reflective plate (10) is disclosed, comprising a substrate (1), a retroreflective sheet (2) adhered to the surface of said substrate and having substantially flat base portions (3) covered with said retroreflective sheet (2), the retroreflective sheeting having retroreflective elements and a light transmissive cover layer; and a plurality of projections (4) covered with said retroreflective sheet and present on the corners of regular polygons that are arranged to form a regularly repeated pattern, wherein the arrangement of the projections (4) satisfies the relationship 0.05<h/P<0.60.

Abstract: A retroreflective article utilizing a solventless bead bond composition wherein the bead bond composition includes a urethane/acrylate interpenetrating polymer network in which the urethane polymer is a thermoplastic and the acrylate component is a thermoset. The solventless bead bond is applied as a mixture of diisocyanates, diols, multifunctional acrylates and additives and thermally cured to a rubbery, thermoplastic solid. At this point the bead bond can be softened or molded with the application of heat or stored for a period of time without loss of thermoplasticity. Final retroreflective sheeting constructions which possess superior adhesion to acrylics, toughness and high retroreflectance are achieved by curing the multifunctional acrylates with radiation.

Abstract: The present invention provides a retroreflective sheeting including: optical elements arranged in substantially a monolayer; a spacing layer in which the optical elements are at least partially embedded; a specularly reflecting layer underlying the spacing layer; and a bead bond layer in which the optical elements are at least partially embedded. The bead bond layer includes an aminoplast-crosslinked polymer comprising urethane groups, wherein prior to crosslinking the polymer has a glass transition temperature (Tg) of less than about 0.degree. C.

Abstract: The present invention provides a method for producing retroreflective sheeting useful for marking or the like of signs such as road signs and construction signs; number plates of vehicles such as motorcars and motorcycles; materials for safety such as clothes and life jackets; signboards, etc.

Abstract: A retroreflective element which may be used in pavement markings comprising a core having (a) a central layer having first and second major surfaces and at least one vertical surface, (b) a barrier layer applied to the first major surface, and (c) a barrier layer applied to the second major surface; and a plurality of optical elements embedded in the vertical surface(s) of the central layer.

Abstract: A retroreflective sheeting have a multitude of retroreflective elements that include a layer of optical elements and a reflective element(s) that is positioned functionally behind the optical elements. The retroreflective elements are supported by a polymeric layer, and an adhesive layer positioned below the support layer. The adhesive layer contains a polyurethane crosslinked by at least an isocyanate compound. The polyurethane is polymerized from a component containing a polyol having at least one alkyl side chain in a molecule, and the adhesive has (i) a storage modulus of about 2.times.10.sup.7 to 8.times.10.sup.7 dyne per square centimeter when measured in a tensile mode at a frequency of 35 Hz and 25.degree. C., and (ii) a softening point of about 80.degree. C. to less than 200.degree. C.

Abstract: A retroreflective article comprising a monolayer of microspheres partially embedded in and protruding from a binder layer and specular reflector underlying the microspheres, wherein the monolayer of microspheres comprises a mixture of a first class of microspheres having a first refractive index and a second class of microspheres having a second refractive index wherein the second refractive index is higher than the first refractive index. As a result, the sheeting exhibits superior observation angle angularity.

Abstract: Encapsulated retroreflective element comprising a retroreflective assembly made up of a transparent optical body and a reflective member and essentially completely encapsulated within a dense, substantially transparent oxide coating. Also a method for making such retroreflective elements and articles and compositions comprising such retroreflective elements.

Abstract: High brightness durable retro-reflecting microspheres for retro-reflection and related uses (and a novel method of forming the same) is provided embodying a retro-reflective vitreous glass microsphere encapsulated in a hardened clear non-vitreous metal-oxide ceramic shell of substantially the same index of fraction as the microsphere.

Abstract: This invention relates to glass microsphere (bead) coated articles having an upper surface comprising a layer of low refractive index transparent glass microspheres such as those made from recycled ordinary glass. The articles of the invention have an extremely smooth tactile feel and a low friction surface even though they can be prepared from glass microspheres intermixed with abrasive irregularly shaped glass particles. The invention also relates to the method making the bead coated articles of the invention and transfer articles that can be used to make the bead coated articles of the invention.

Abstract: An all-optical flip-flop device is achieved by employing two optical amplifiers arranged so that they together operate in only one of two stable states at a given time. In a first stable state of operation, the first optical amplifier behaves as a laser having a first predetermined characteristic wavelength. The arrangement is switched to a second stable state of operation in which the second optical amplifier behaves as a laser having a second characteristic wavelength, where the first and second characteristic wavelengths are at least nominally different, when an optical signal pulse is received at the input of the first optical amplifier. The arrangement is switched back to the first stable state when an optical signal pulse is received at the input of the second optical amplifier.

Abstract: Retroreflective sheeting having an aliphatic polyurethane topcoat is described. The aliphatic polyurethane topcoat is obtainable from a mixture comprising (A) an aliphatic polyurethane derived from an aliphatic polyisocyanate and a polyester polyol prepared from a mixture comprising (A-1) a dicarboxylic acid component comprising isophthalic acid as the major dicarboxylic acid; and (A-2) a polyol component; and (B) cellulose acetate butyrate. The mixture also may contain (C) at least one non-reactive solvent, and optionally, (D) one or more surfactants including, for example, hydroxy-containing non-silicone surfactants.

Abstract: A retroreflective article (100, 200, 300) includes a monolayer of retroreflective elements (120, 220, 320), a binder layer (110, 210, 310), and a compound comprising an aromatic bidentate moiety. The retroreflective elements (120, 220, 320) are partially embedded in the binder layer (110, 210, 310), and the compound is chemically associated with the retroreflective elements (120, 220, 320) to provide extraordinary laundering durability to the retroreflective article (100, 200, 300).

Abstract: Retroreflective appliques comprising a monolayer of retroreflective elements partially embedded in and protruding from the front surface of a binder layer and an optional layer of adhesive on the rear surface of the binder layer, wherein the binder layer, the adhesive layer, or both contain a metal-azo dye to camouflage the color of any exposed portions of said binder layer. Appliques comprising micropheres with aluminum reflectors as retroreflective elements and a black metal-azo dye in the binder layer will exhibit a pleasing silver appearance even after portions of the binder layer have been visibly exposed due to degradation of the aluminum reflectors, typically as a result of subjecting the applique to harsh laundering conditions.

Abstract: Glass microspheres and rear projection screens containing glass microspheres, which combine a desirable index of refraction (preferably, no greater than about 1.70) and low levels of defects (e.g., bubbles, visible haziness, frostiness, or opacity, substantially nonspherical shapes) upon formation are provided. Also provided is a coating method of placing microspheres on a film for use in a rear projection screen.