By Addition Of Material To Coolant Patents (Class 376/306)
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Patent number: 7889828Abstract: A method of suppressing deposition of radionuclides on components of a nuclear power plant comprises forming a ferrite film by contacting a first chemical including iron (II) ions, a second chemical for oxidizing the iron (II) ions to iron (III) ions, and a third chemical for adjusting the pH of a processing solution containing a mixture of the first and second chemicals to be 5.5 to 9.0 with the metal member surface in a time period from a finishing stage in decontamination step of removing contaminants formed on the surface of metal member composing the nuclear power plant, and suppressing deposition of radionuclides on the metal member by the ferrite film.Type: GrantFiled: March 25, 2009Date of Patent: February 15, 2011Assignee: Hitachi-GE Nuclear Energy, Ltd.Inventors: Hideyuki Hosokawa, Makoto Nagase, Kazushige Ishida, Yoichi Wada, Naoshi Usui, Motohiro Aizawa, Motomasa Fuse
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Patent number: 7869557Abstract: The object of this invention is to provide a method for mitigating a stress corrosion cracking of reactor structural material which makes it possible to suppress the rise in the main steam line dose rate without secondary effects such as a rise in the concentration of radioactive cobalt-60, etc. in the reactor water. Hydrogen and a reductive nitrogen compound containing nitrogen having a negative oxidation number (for example, hydrazine) are injected into the core water of boiling water nuclear power plant. By injecting the reductive nitrogen compound containing nitrogen having a negative oxidation number into the core water, the stress corrosion cracking of structural material of reactor can be mitigated without side reactions such as a rise in the concentration of cobalt-60, etc.Type: GrantFiled: January 16, 2009Date of Patent: January 11, 2011Assignee: Hitachi-GE Nuclear Energy, Ltd.Inventors: Kazushige Ishida, Yoichi Wada, Makoto Nagase, Masahiko Tachibana, Masao Endo, Motomasa Fuse, Naoshi Usui, Motohiro Aizawa
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Patent number: 7864914Abstract: The object of this invention is to provide a method for mitigating a stress corrosion cracking of reactor structural material which makes it possible to suppress the rise in the main steam line dose rate without secondary effects such as a rise in the concentration of radioactive cobalt-60, etc. in the reactor water. Hydrogen and a reductive nitrogen compound containing nitrogen having a negative oxidation number (for example, hydrazine) are injected into the core water of boiling water nuclear power plant. By injecting the reductive nitrogen compound containing nitrogen having a negative oxidation number into the core water, the stress corrosion cracking of structural material of reactor can be mitigated without side reactions such as a rise in the concentration of cobalt-60, etc.Type: GrantFiled: February 2, 2009Date of Patent: January 4, 2011Assignee: Hitachi-GE Nuclear Energy, Ltd.Inventors: Kazushige Ishida, Yoichi Wada, Makoto Nagase, Masahiko Tachibana, Masao Endo, Motomasa Fuse, Naoshi Usui, Motohiro Aizawa
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Publication number: 20100329410Abstract: Disclosed is a basket 50 that is located within a basket containment vessel, into which a boric acid solution capable of dissolving a pH adjuster flows, and can allow a pH adjuster solution to flow out by the inflowing boric acid solution. The basket 50 includes a plurality of containment units 71 stacked in a vertical direction with a predetermined first space L1 therebetween. The pH adjuster can be stored in each of the containment units 71. Also disclosed is a pH adjusting device including the basket 50, the basket containment vessel in which the basket 50 can be contained and in which cooling water can be stored, and an overflow pipe that, within the basket containment vessel, allows the pH adjuster solution that is obtained from the pH adjuster dissolved in the cooling water to flow out.Type: ApplicationFiled: April 8, 2009Publication date: December 30, 2010Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.Inventors: Koichi Tanimoto, Masaharu Watabe, Jiro Kasahara
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Patent number: 7844024Abstract: A method of suppressing deposition of radionuclides on components of a nuclear power plant comprises forming a ferrite film by contacting a first chemical including iron (II) ions, a second chemical for oxidizing the iron (II) ions to iron (III) ions, and a third chemical for adjusting the pH of a processing solution containing a mixture of the first and second chemicals to be 5.5 to 9.0 with the metal member surface in a time period from a finishing stage in decontamination step of removing contaminants formed on the surface of metal member composing the nuclear power plant, and suppressing deposition of radionuclides on the metal member by the ferrite film.Type: GrantFiled: February 3, 2009Date of Patent: November 30, 2010Assignee: Hitachi-GE Nuclear Energy, Ltd.Inventors: Hideyuki Hosokawa, Makoto Nagase, Kazushige Ishida, Yoichi Wada, Naoshi Usui, Motohiro Aizawa, Motomasa Fuse
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Publication number: 20100290577Abstract: A pressurized water nuclear reactor (PWNR) 100 includes a core having a containment shield 105 surrounding a reactor vessel 110 having fuel assemblies that contain fuel rods filled with fuel pellets 115, and control rods 118, and a steam generator 120 thermally coupled to the reactor vessel 110. A flow loop includes the steam generator 120, a turbine 130, and a condenser 135, and a pump 140 for circulating a water-based heat transfer fluid 145 in the loop. The heat transfer fluid 145 includes a plurality of nanoparticles having at least one carbon allotrope or related carbon material dispersed therein, such as diamond nanoparticles.Type: ApplicationFiled: February 22, 2007Publication date: November 18, 2010Applicant: University of Florida Research Foundation, Inc.Inventors: Ronald H. Baney, James S. Tulenko, Kevin W. Powers
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Patent number: 7811392Abstract: It is an object of the present invention to efficiently suppress radionuclide deposition on a reactor component of nuclear power plant. Radionuclide deposition on the surface of a metallic reactor component of nuclear power plant is suppressed by forming a ferrite film on the component, wherein the film is formed, after decontamination for removing radionuclides contaminants from the component surface is completed and before the plant is started up, by contacting a treatment solution which mixes a first agent containing the iron (II) ions, a second agent for oxidizing the iron (II) ions into the iron (III) ions and a third agent for adjusting pH level of a solution to 5.5 to 9.0 in this order with the reactor component surface.Type: GrantFiled: July 14, 2006Date of Patent: October 12, 2010Assignee: Hitachi-GE Nuclear Energy, Ltd.Inventors: Hideyuki Hosokawa, Makoto Nagase, Kazushige Ishida, Youichi Wada, Naoshi Usui, Motohiro Aizawa, Motomasa Fuse
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Publication number: 20100246745Abstract: A method for operating a nuclear reactor may include adding one or more chemicals to water in the reactor prior to reactor shutdown, during reactor shutdown, or prior to and during reactor shutdown. The one or more chemicals may trigger release of one or more radioactive substances from at least one out-of-core surface of the reactor into the reactor water. A method for reducing post-shutdown radiation levels of a nuclear reactor may include adding one or more chemicals to water in the reactor prior to reactor shutdown, during reactor shutdown, or prior to and during reactor shutdown. The one or more chemicals may include, for example, one or more metals, metal ions, metal compounds, metals and metal ions, metals and metal compounds, metal ions and metal compounds, or metals, metal ions, and metal compounds.Type: ApplicationFiled: December 29, 2006Publication date: September 30, 2010Inventors: Samson Hettiarachchi, Juan Alberto Varela, Thomas Pompilio Diaz
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Publication number: 20100246746Abstract: The present invention relates generally to a process for a pressurized water reactor. The pressurized water reactor includes a primary circuit and a reactor core. The process includes adding a sufficient amount of an organic compound to coolant water passing through the primary circuit of the pressurized water reactor. The organic compound includes elements of carbon and hydrogen for producing elemental carbon.Type: ApplicationFiled: March 31, 2009Publication date: September 30, 2010Applicant: Westinghouse Electric Company, LLCInventors: William CONNOR, Rachel DeVito
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Publication number: 20100135450Abstract: Crystal habit modifiers (CHM) are provided to ameliorate deposit-related concerns in nuclear plant systems. The principal targets for utilization of crystal habit modifiers are Pressure Water Reactor (PWR) primary-side fuel rod crud and secondary-side steam generator deposits and Boiling Water Reactor (BWR) coolant system deposits.Type: ApplicationFiled: December 1, 2009Publication date: June 3, 2010Inventors: Keith Paul Fruzzetti, Karen Samie Kim, Robert Douglas Varrin, JR., Charles Marks
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Publication number: 20100080335Abstract: A nuclear power plant is provided including a BWR, a reactor cooling system cooling the BWR, an HWC hydrogen injection system connected to the reactor cooling system and an alcohol injection system connected to the reactor cooling system. Methods for providing methanol and hydrogen are also provided.Type: ApplicationFiled: December 1, 2009Publication date: April 1, 2010Applicant: AREVA NP INC.Inventors: Bernhard Stellwag, Mihai G.M. Pop
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Publication number: 20100074389Abstract: Provided is a replacement basket configured to house a pellet bed through which fluid may pass. The flow direction of the fluid prevents the bed of pellets from fluidizing within the replacement basket. Provided also is a system using the replacement basket and a method of providing pellets in the replacement basket. According to example embodiments, a replacement basket may include a top surface portion, a bottom, and at least one vertical wall with a hole. The hole is configured to allow a flow of fluid to enter the replacement basket. A plenum, below the pellet bed, may allow a flow of fluid to proceed through the pellet bed in a downward direction. A central pipe may be provided in the replacement basket to allow the flow of fluid in the basket to exit the replacement basket.Type: ApplicationFiled: September 25, 2008Publication date: March 25, 2010Inventors: Thomas Alfred Caine, Juan Alberto Varela, Luong Cam Tran
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Patent number: 7676017Abstract: A vacuum actuated and sustained ammonia feed system for the pH adjustment of power plant condensate and boiler feed water is described. This system can provide a safe means of providing anhydrous ammonia for pH adjustment to the condensate/feed water system of a power plant.Type: GrantFiled: April 5, 2006Date of Patent: March 9, 2010Assignee: Southern Company Services, Inc.Inventors: Herman A. Nebrig, Jr., Chad E. McKnight
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Publication number: 20100027731Abstract: The oxidizing chemistry environment of BWR reactor water is a key factor promoting intergranular stress corrosion cracking of stainless steel and nickel based alloys used in reactor coolant system piping and vessel internals. This is typically mitigated during power operation with hydrogen injection. However, this method is only effective when the reactors are at power. Accordingly, this invention proposes a method of reducing electrochemical corrosion potential during the start-up phase of BWR reactors. The method includes the steps of providing a mitigation additive adapted to reduce electrochemical corrosion of a BWR reactor; and injecting the mitigation additive into the BWR reactor at a predetermined location prior to hydrogen injection coming online.Type: ApplicationFiled: July 13, 2009Publication date: February 4, 2010Applicant: Electric Power Research Institute, Inc.Inventors: Christopher John Wood, Susan Elaine Garcia
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Publication number: 20100020915Abstract: Environmentally protective Method of treating an aqueous radioactive fluid (AF) in a nuclear reactor cycle or radwaste system to selectively capture or remove radioactive isotopes in a reduced quantitative package to minimize radwaste generated and revitalize neutron absorption capacity of nuclear reactor coolant by separately carrying away boron constituents, when B10 is later added.Type: ApplicationFiled: October 8, 2009Publication date: January 28, 2010Applicant: DIVERSIFIED TECHNOLOGIES SERVICES, INC.Inventors: Larry E. Beets, Charles E. Jensen, Dennis A. Brunsell
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Publication number: 20090316852Abstract: A method for suppressing deposit of radionuclide onto structure member composing a nuclear power plant, comprising the steps of: bringing film formation liquid including iron (II) ions and either of zinc (II) ions and nickel (II) ions into contact with a surface of the structure member; and forming either of a ferrite film including the zinc and a ferrite film including the nickel on the surface of the structure member.Type: ApplicationFiled: June 6, 2008Publication date: December 24, 2009Inventors: Hideyuki Hosokawa, Makoto Nagase, Satoshi Morisawa, Motoaki Sakashita, Katsuo Yokota
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Publication number: 20090225928Abstract: The object of this invention is to provide a method for mitigating a stress corrosion cracking of reactor structural material which makes it possible to suppress the rise in the main steam line dose rate without secondary effects such as a rise in the concentration of radioactive cobalt-60, etc. in the reactor water. Hydrogen and a reductive nitrogen compound containing nitrogen having a negative oxidation number (for example, hydrazine) are injected into the core water of boiling water nuclear power plant. By injecting the reductive nitrogen compound containing nitrogen having a negative oxidation number into the core water, the stress corrosion cracking of structural material of reactor can be mitigated without side reactions such as a rise in the concentration of cobalt-60, etc.Type: ApplicationFiled: January 16, 2009Publication date: September 10, 2009Inventors: Kazushige ISHIDA, Yoichi Wada, Makoto Nagase, Masahiko Tachibana, Masao Endo, Motomasa Fuse, Naoshi Usui, Motohiro Aizawa
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Publication number: 20080292042Abstract: The object of this invention is to provide a method for mitigating a stress corrosion cracking of reactor structural material which makes it possible to suppress the rise in the main steam line dose rate without secondary effects such as a rise in the concentration of radioactive cobalt-60, etc. in the reactor water. Hydrogen and a reductive nitrogen compound containing nitrogen having a negative oxidation number (for example, hydrazine) are injected into the core water of boiling water nuclear power plant. By injecting the reductive nitrogen compound containing nitrogen having a negative oxidation number into the core water, the stress corrosion cracking of structural material of reactor can be mitigated without side reactions such as a rise in the concentration of cobalt-60, etc.Type: ApplicationFiled: June 18, 2008Publication date: November 27, 2008Inventors: Kazushige Ishida, Yoichi Wada, Makoto Nagase, Masahiko Tachibana, Masao Endo, Motomasa Fuse, Naoshi Usui, Motohiro Aizawa
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Patent number: 7449101Abstract: In a method of reducing corrosion of a metal material, a substance such as semiconductor for generating an electric current by thermal excitation is coated or adhered on a metal material surface, to be exposed to a water having a high temperature of 150° C. or more, of a boiler and ducts or pipes, to which hot water heated by the boiler contacts, of a thermal electric power plant or a nuclear reactor structural material or ducts or pipes surrounding the reactor in a nuclear power plant.Type: GrantFiled: February 5, 2003Date of Patent: November 11, 2008Assignees: Kabushiki Kaisha Toshiba, The Tokyo Electric Power Company, Incorporated, Ishikawajima - Harima Heavy Industries Co., Ltd.Inventors: Masato Okamura, Yukio Henmi, Nagayoshi Ichikawa, Tetsuo Oosato, Seiji Yamamoto, Kazuo Murakami, Kenji Yamazaki, Junichi Takagi, Tadasu Yotsuyanagi, Shunichi Suzuki, Kenro Takamori, Mitsuru Sambongi, Yuichi Fukaya, Takasi Hirano
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Publication number: 20080219396Abstract: A nuclear power plant with an improved cooling system using nanoparticles in solid or fluid form to improve heat transfer and reduce corrosion is provided. The nanoparticles are delivered to a closed cooling circuit such as a CCWS. Methods for providing the nanoparticles are also provided.Type: ApplicationFiled: March 6, 2007Publication date: September 11, 2008Applicant: AREVA NPInventors: Mihai G.M. Pop, Brian Glenn Lockamon
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Publication number: 20080181351Abstract: A formic acid aqueous solution that contains Fe (II) ions is produced by dissolving metal iron in a formic acid aqueous solution. Nitrogen is supplied from a nitrogen supply device to a chemical liquid tank and then discharged from a discharge line to reduce the dissolved oxygen concentration in the aqueous solution. The chemical liquid tank is filled with the formic acid aqueous solution sealed with nitrogen, and transferred from a factory to a nuclear reactor building designated as radiation-controlled areas. Inside the nuclear reactor building the chemical liquid tank is installed in a film deposition apparatus connected to a reactor water recirculation pipeline. The formic acid aqueous is supplied from the chemical liquid tank to the inside of the reactor water recirculation pipeline, and then a ferrite film is formed on the inner surface of the reactor water recirculation pipeline.Type: ApplicationFiled: June 26, 2007Publication date: July 31, 2008Inventors: Hideyuki Hosokawa, Makoto Nagase, Satoshi Morisawa, Motoaki Sakashita, Katsuo Yokota
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Patent number: 7346140Abstract: A photocatalytic substance having the properties of an n-type semiconductor is deposited on a surface of a metal base made of a stainless steel or Inconel. When necessary, the hydrogen concentration of the reactor water is increased. A current produced by the photocatalytic substance when the same is irradiated with light or radioactive rays in a nuclear reactor flows through the metal base to reduce corrosion current. When necessary, the photocatalytic substance is provided on its surface with at least one of Pt, Rh, Ru and Pd.Type: GrantFiled: June 27, 2005Date of Patent: March 18, 2008Assignee: Kabushiki Kaisha ToshibaInventors: Nagayoshi Ichikawa, Yukio Hemmi, Tetsuo Oosato, Junichi Takagi, Kenji Yamazaki
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Publication number: 20070289368Abstract: In a method of monitoring deposition of a noble metal in an intergranular stress corrosion crack (IGSCC) in a metal reactor shroud wall of a nuclear reactor, a metal sample may be placed at a location within near an inner surface of the metal reactor shroud wall. The sample may be submerged below a water line in the reactor and includes at least one thermal fatigue crack. The sample is maintained at the location for a given duration, and a given amount of the noble metal is added into the reactor water while the sample is maintained at the location. The sample is then removed. In an example, a surface crevice deposition monitor for a reactor includes a flow conditioner arranged between a top guide clamp and an anchor clamp, and at least one sample holder connected between the top guide clamp and flow conditioner.Type: ApplicationFiled: June 16, 2006Publication date: December 20, 2007Inventors: Russell Seeman, Thomas Alfred Caine, Thanh Tu
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Patent number: 7264770Abstract: A method for mitigating stress corrosion cracking of a component exposed to a high temperature water in a high temperature water system is provided. The method comprises the steps of lowering corrosion potential conditions to a desired low corrosion potential in the high temperature water environment; and introducing a first material comprising zinc into the high temperature water environment, such that the desired low corrosion potential facilitates transport of the first material into cracks in a structure communicative with the high temperature water environment.Type: GrantFiled: May 2, 2005Date of Patent: September 4, 2007Assignee: General Electric CompanyInventors: Peter Louis Andresen, Young-Jin Kim, Sam Hettiarachchi, Thomas Pompilio Diaz, Thomas Martin Angeliu, Martin Mathew Morra
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Patent number: 7147823Abstract: A method for cooling a heat source, a method for preventing chemical interaction between a vessel and a cooling composition therein, and a cooling system. The method for cooling employs a containment vessel with an oxidizable interior wall. The interior wall is oxidized to form an oxide barrier layer thereon, the cooling composition is monitored for excess oxidizing agent, and a reducing agent is provided to eliminate excess oxidation. The method for preventing chemical interaction between a vessel and a cooling composition involves introducing a sufficient quantity of a reactant which is reactive with the vessel in order to produce a barrier layer therein that is non-reactive with the cooling composition. The cooling system includes a containment vessel with oxidizing agent and reducing agent delivery conveyances and a monitor of oxidation and reduction states so that proper maintenance of a vessel wall oxidation layer occurs.Type: GrantFiled: April 15, 2002Date of Patent: December 12, 2006Assignee: Battelle Energy Alliance, LLCInventor: Eric P. Loewen
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Patent number: 6968028Abstract: A nuclear power station includes a feedwater/steam circuit having a condensate-purification device and a feedwater pump connected upstream of a reactor pressure vessel. A branch line has a gas-injection device for introducing hydrogen into a coolant to ensure especially low maintenance and repair costs of the gas-injection device and an especially homogeneous distribution of hydrogen produced in the gas-injection device. The branch line branches off from the feedwater/steam circuit directly downstream of the condensate-purification device and discharges into the feedwater/steam circuit directly upstream of the feedwater pump.Type: GrantFiled: September 13, 2000Date of Patent: November 22, 2005Assignee: Framatome ANP GmbHInventor: Anwer Puthawala
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Patent number: 6944254Abstract: A reactor coolant system of a pressurized water nuclear reactor with fuel assemblies in the core is simultaneously shutdown and decontaminated in less than 90 hours after the shutdown is initiated. A LOMI or Can-Derem decontamination reagent is added to reactor coolant to reduce iron and nickel in oxidized coatings before removing dissolved hydrogen and reducing the gamma emitting activity of the reactor coolant.Type: GrantFiled: July 30, 2003Date of Patent: September 13, 2005Assignee: Westinghouse Electric Co., LLCInventors: Joseph W. Kormuth, William A. Byers, Richard D. Reid, George P. Sabol
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Patent number: 6937686Abstract: Method for controlling the level of iron in feedwater of a BWR wherein an iron-containing sacrificial electrode in placed contact with the feed water dissolution of the electrode is induced at a rate which provides a desired level of iron in the feedwater.Type: GrantFiled: September 30, 2002Date of Patent: August 30, 2005Assignee: General Electric CompanyInventors: Robert James Law, David Phillip Siegewarth
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Patent number: 6928134Abstract: An apparatus admits gas into the primary coolant of a pressurized water nuclear reactor having a coolant loop for a liquid coolant, in particular water, to which hydrogen is to be added. The coolant loop preferably includes a volume control tank for the coolant as well as at least one high-pressure pump which admits coolant that has been extracted from the coolant loop back into the coolant loop again. An admission point for the hydrogen is located in a suction line on the suction side of the high-pressure pump. A measurement line on the pressure side of the high-pressure pump communicates with the volume control tank or with a dewatering system. A device for measuring the hydrogen content in the coolant is incorporated into the measurement line. The measuring device is connected through a control device to a control valve, with which the delivery of hydrogen to the admission point can be controlled. The gas admission apparatus assures a definite, precisely maintained hydrogen content in the coolant.Type: GrantFiled: March 30, 1998Date of Patent: August 9, 2005Assignee: Framatome ANP GmbHInventors: Anwer Puthawala, Helmut Stünkel
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Patent number: 6898259Abstract: The corrosion of a component in a water-guiding loop of a nuclear facility is reduced. A protective layer is produced with a sol-gel process. Prior to the sol application, water that wettens the component is removed from the conduction system and the component is optionally dried in a separate step. After the sol-gel process has been carried out, the conduction system is again filled with water. A liquid sol film that is produced on the component is dried, especially by means of hot air. A component in the primary system of a boiling water reactor can especially be coated with a highly corrosion-resistant zirconium oxide protective layer according to the sol-gel process.Type: GrantFiled: September 23, 2002Date of Patent: May 24, 2005Assignee: Framatome ANP GmbHInventors: Bernhard Stellwag, Patricia Vaz
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Patent number: 6891912Abstract: A reactor core (104) includes fuel assemblies (202) arranged in a loading pattern (1100) in response to corresponding power levels of the fuel assemblies (202). A crud deposition model (412) is used to predict crud deposition on the fuel assemblies (202) and fuel pins (300) within the fuel assemblies (202). The prediction of crud deposition enables generation of the loading pattern (1100) and design of lattice structures (1600) for the fuel assemblies (202) that results in the reduction of total crud deposition in the reactor core (104) and causes a substantially uniform crud deposition on the fuel assemblies (202) of the reactor core (104).Type: GrantFiled: March 26, 2003Date of Patent: May 10, 2005Assignee: Pinnacle West Capital CorporationInventors: Yovan D. Lukic, Jeffrey S. Schmidt
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Patent number: 6885721Abstract: The present invention relates to a method for inhibiting stress corrosion cracking occurring on steam generator tubes in the secondary side of nuclear power plants and an inhibitor therefor. The method comprises supplying lanthanum boride as an inhibitor for stress corrosion cracking into the secondary feed water of the nuclear power plants. The method according to the present invention improves the resistance of stress corrosion cracking ten times or higher than no inhibitor, and five times or higher than the conventional inhibitor. In particular, the method according to the present invention shows a superior inhibiting effect in the lead-contaminated environment such that the complete inhibition of stress corrosion cracking can be achieved. As thus, the method can reduce the unexpected stop of operating nuclear power plants caused by the stress corrosion cracking on steam generator tubes, thereby reducing the cost required for maintaining and repairing the tubes.Type: GrantFiled: March 19, 2002Date of Patent: April 26, 2005Assignees: Korea Atomic Energy Research Institute, Korea Hydro & Nuclear Power Co., Ltd.Inventors: Do Haeng Hur, Joung Soo Kim
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Patent number: 6873672Abstract: The method involves measuring hydrogen permeation in the tubes by mass spectrometry, wherein the tube is inserted into a high or ultrahigh vacuum device in which a mass spectrometer and a total pressure gauge are located. H2 or H2 and inert gas mixtures are circulated inside the tube at the required partial pressure. The tube is then heated and the appearance of H2 outside the tube is observed. The flow thereof inside the tube and emergence time, called permeation time, are determined based on permeation curves. The emergence time of the first microcrack is also determined.Type: GrantFiled: March 13, 2003Date of Patent: March 29, 2005Assignees: Consejo Superior de Investigaciones Cientificas, IberdrolaInventors: José Luis Sacedón Adelantado, Eduardo Santamera Gago, Marcos DÃaz Muñoz, José Serafin Moya Corral, Elisa Román GarcÃa, Angel Samuel Pérez RamÃrez, Begoña RemartÃnez Zato
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Patent number: 6856665Abstract: A method for controlling water quality in a nuclear reactor comprises a first and second steps. The first step is to make an amount of iron, which is carried into the nuclear reactor and corrosively eluted from structural material within the nuclear reactor into reactor water, at least twice as much as any one of an amount of nickel, which is carried into the nuclear reactor, and an amount of nickel, which is generated in the nuclear reactor. The second step is to limit an upper limit of concentration value of iron in system water supplied into the nuclear reactor to up to 0.10 ppb.Type: GrantFiled: September 28, 2001Date of Patent: February 15, 2005Assignee: Kabushiki Kaisha ToshibaInventors: Yukio Hemmi, Kenji Yamazaki, Hajime Hirasawa
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Patent number: 6810100Abstract: Oxygen is mixed with heater drain water of power plant which contains fine particles of iron oxides such that the concentration of the dissolved oxygen in the heater drain water after the mixing of oxygen is in a range from 1 &mgr;g/liter to 20 &mgr;g/liter. The obtained heater drain water after oxygen mixing is filtered through a filter such as a hollow fiber filter to remove fine particles of iron oxides.Type: GrantFiled: November 12, 2002Date of Patent: October 26, 2004Assignee: Organo CorporationInventors: Shinichi Ohashi, Toshio Morita
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Patent number: 6793883Abstract: A method and system for reducing stress corrosion cracking in a hot water system, such as a nuclear reactor, by reducing the electrochemical corrosion potential of components exposed to high temperature water within the structure. The method includes the steps of: providing a reducing species to the high temperature water; and providing a plurality of noble metal nanoparticles having a mean particle size of up to about 100 nm to the high temperature water during operation of the hot water system. The catalytic nanoparticles, which may contain at least one noble metal, form a colloidal suspension in the high temperature water and provide a catalytic surface on which a reducing species reacts with least one oxidizing species present in the high temperature water. The concentration of the oxidizing species is reduced by reaction with the reducing species on the catalytic surface, thereby reducing the electrochemical corrosion potential of the component.Type: GrantFiled: July 5, 2001Date of Patent: September 21, 2004Assignee: General Electric CompanyInventors: Peter Louis Andresen, Thomas Martin Angeliu, Young Jin Kim, Thomas Pompilio Diaz, Samson Hettiarachchi
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Patent number: 6724854Abstract: A method for mitigating stress corrosion cracking in high temperature water includes introducing catalytic nanoparticles and dielectric nanoparticles to the high temperature water in an amount effective to reduce a electrochemical corrosion potential of the high temperature water.Type: GrantFiled: June 16, 2003Date of Patent: April 20, 2004Assignee: General Electric CompanyInventors: Young-Jin Kim, Thomas Martin Angeliu, Peter Louis Andresen
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Patent number: 6714618Abstract: Method for controlling the amount of metal atoms deposited into an oxide layer present on a metal surface, which metal atoms increase the corrosion resistance of metal when present in the oxide film, wherein the metal surface is submerged in water at a selected temperature within the range of about to 200° to 550° F.; and a solution of a compound containing the metal which increases the corrosion resistance of the metal surface when present in the oxide film is injected into the water. The compound decomposes at the selected temperature to release atoms of the metal which incorporate in the oxide film at a desired loading.Type: GrantFiled: November 20, 1998Date of Patent: March 30, 2004Assignee: General Electric CompanyInventors: Samson Hettiarachchi, Robert J. Law, David P. Siegwarth, Thomas P. Diaz, Robert L. Cowan
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Patent number: 6697449Abstract: Method for controlling the amount of metal atoms deposited into an oxide layer present on a metal surface, which metal atoms increase the corrosion resistance of metal when present in the oxide film, wherein the metal surface is submerged in water at a selected temperature within the range of about to 200° to 550° F.; and a solution of a compound containing the metal which increases the corrosion resistance of the metal surface when present in the oxide film is injected into the water. The compound decomposes at the selected temperature to release atoms of the metal which incorporate in the oxide film at a desired loading.Type: GrantFiled: April 10, 2002Date of Patent: February 24, 2004Assignee: General Electric CompanyInventors: Samson Hettiarachchi, Robert J. Law, David P. Siegwarth, Thomas P. Diaz, Robert L. Cowan
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Patent number: 6633623Abstract: A jet pump for a nuclear reactor includes a riser and an inlet mixer having a set of nozzles and a mixing section for receiving coolant flow from the nozzles and suction flow from an annular space between the reactor vessel and the shroud core. To minimize or eliminate electrostatic deposition of charged particulates carried by the coolant on interior wall surface of the inlet-mixer of the jet pump, and also to inhibit stress corrosion cracking, the interior wall surfaces of the nozzles and mixing section are coated with a ceramic oxide such as TiO2 and Ta2O5 to thicknesses of about 0.5-1.5 microns.Type: GrantFiled: November 29, 2000Date of Patent: October 14, 2003Assignee: General Electric CompanyInventors: Catherine P. Dulka, John F. Ackerman, David W. Sandusky, Mark O. Lenz, Leland L. Lantz, Michael B. McMahan, Glen Arthur MacMillan
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Patent number: 6606368Abstract: In a nuclear power plant, by injecting an amount of hydrogen small enough not to increase a radiation dose rate of the main steam system, ECP of metallic component materials composing a nuclear reactor can be decreased to suppress the potential of occurrence of IGSCC, and the control can be easily performed, and the operating cost can be suppressed to increase. Occurrence of intergranular stress corrosion cracking in metallic component materials in contact with reactor cooling water is suppressed by injecting zirconium hydroxide and hydrogen into the reactor cooling water to decrease the electrochemical corrosion potential of the metallic component materials.Type: GrantFiled: April 23, 2001Date of Patent: August 12, 2003Assignees: Hitachi, Ltd., The Tokyo Electric Power Company, IncorporatedInventors: Yoshiyuki Takamori, Masanori Sakai, Yamato Asakura, Masato Nakamura, Hideyuki Hosokawa, Nagao Suzuki, Kouji Hayashi
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Patent number: 6556642Abstract: The present invention relates to a method for inhibiting stress corrosion cracking occurring on steam generator tubes in the secondary side of nuclear power plants and an inhibitor therefor. The method comprises supplying cerium boride as an inhibitor for stress corrosion cracking into the secondary feed water of the nuclear power plants. The method according to the present invention improves resistance of stress corrosion cracking three times or higher than no inhibitor, and two times or higher than the conventional inhibitor. In particular, the method according to the present invention shows a superior inhibiting effect in the lead-contaminated environment such that the complete inhibition of stress corrosion cracking can be achieved. As thus, the method can reduce the unexpected stop of operating nuclear power plants caused by the stress corrosion cracking on steam generator tubes, thereby reducing the cost required for maintaining and repairing the tubes.Type: GrantFiled: October 23, 2001Date of Patent: April 29, 2003Assignees: Korea Atomic Energy Research Institute, Korea Electric Power CorporationInventors: Do Haeng Hur, Joung Soo Kim
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Patent number: 6549603Abstract: To suppress a decrease of thickness due to corrosion of structural members and to achieve a removal of radionuclides with good efficiency in a nuclear power plant, oxidation decontamination is first conducted. An aqueous potassium permanganate solution is supplied from a circulation line to a reactor pressure vessel, which is a stainless steel structural member, and a reactor water cleanup system piping and a drain piping, which are carbon steel structural members. These structural members are oxidation-decontaminated by the action of potassium permanganate. Then the above-mentioned structural members are reduction-decontaminated by using an aqueous oxalic acid solution. The aqueous oxalic acid solution contains hydrazine.Type: GrantFiled: September 8, 2000Date of Patent: April 15, 2003Assignees: Hitachi, Ltd., Kurita Engineering Co., Ltd.Inventors: Kazushige Ishida, Kazumi Anazawa, Yoshiyuki Takamori, Naohito Uetake, Makoto Nagase, Hiroo Yoshikawa, Tadashi Tamagawa
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Publication number: 20020191731Abstract: Method for controlling the introduction of zinc to a nuclear power reactor to control radiation build-up wherein zinc ions are introduced into the reactor water to counteract loss of zinc within the reactor system. In the process, the rate of introduction of zinc ions into the reactor water is balanced with the rate at which zinc ions are lost from the reactor.Type: ApplicationFiled: May 28, 2002Publication date: December 19, 2002Applicant: General Electric CompanyInventor: William J. Marble
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Publication number: 20020181644Abstract: Method for controlling the amount of metal atoms deposited into an oxide layer present on a metal surface, which metal atoms increase the corrosion resistance of metal when present in the oxide film, wherein the metal surface is submerged in water at a selected temperature within the range of about to 200° to 550° F.; and a solution of a compound containing the metal which increases the corrosion resistance of the metal surface when present in the oxide film is injected into the water.Type: ApplicationFiled: April 10, 2002Publication date: December 5, 2002Applicant: General Electric CompanyInventors: Samson Hettiarachchi, Robert J. Law, David P. Siegwarth, Thomas P. Diaz, Robert L. Cowan
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Patent number: 6488782Abstract: Method for reducing in situ the electrochemical corrosion potential and susceptibility to stress corrosion cracking of a nickel-base alloy and boiling water nuclear reactor components formed therefrom when in contact with high temperature water. The method comprises the steps of: adding a metal hydride to the high temperature water; dissociating the metal hydride in the high temperature water to form a metal and at least one hydrogen ion; and reducing the concentration of the oxidizing species by reacting the hydrogen ions with an oxidizing species, thereby reducing in situ the electrochemical corrosion potential of the nickel-base alloy. The method may further include the steps of reacting the metal with oxygen present in the high temperature water to form an insoluble oxide and incorporating the metal into the surface of the nickel-base alloy, thereby reducing the electrical conductivity of the surface of the nickel-base alloy.Type: GrantFiled: January 29, 2001Date of Patent: December 3, 2002Assignee: General Electric CompanyInventors: Young Jin Kim, Peter Louis Andresen
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Patent number: 6473480Abstract: A non-steady state computer model of water in a Boiling Water Reactor (BWR) primary water flow circuit is used to represent the water chemistry and noble metal loading during, for example, an in situ noble metal application process. The modeling software is provided on a laptop or portable computer for real-time use in the field at different reactor sites. After inputting data representing the initial state of reactor water chemistry and operating conditions of the reactor, the model determines the water chemistry, pH, conductivity and noble metal loading throughout the BWR primary water flow circuit, including selected sample locations, as a function of time. Results are used to determine whether technical specifications on conductivity or other chemistry-related parameters will be exceeded during the noble metal application process. Values of rate constants used for modeling noble metal reactions may be changed on site at the reactor during the application process.Type: GrantFiled: December 12, 2000Date of Patent: October 29, 2002Assignee: General Electric CompanyInventors: Richard M. Kruger, Robert J. Law
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Publication number: 20020150195Abstract: The present invention relates to a method for inhibiting stress corrosion cracking occurring on steam generator tubes in the secondary side of nuclear power plants and an inhibitor therefor. The method comprises supplying lanthanum boride as an inhibitor for stress corrosion cracking into the secondary feed water of the nuclear power plants. The method according to the present invention improves the resistance of stress corrosion cracking ten times or higher than no inhibitor, and five times or higher than the conventional inhibitor. In particular, the method according to the present invention shows a superior inhibiting effect in the lead-contaminated environment such that the complete inhibition of stress corrosion cracking can be achieved. As thus, the method can reduce the unexpected stop of operating nuclear power plants caused by the stress corrosion cracking on steam generator tubes, thereby reducing the cost required for maintaining and repairing the tubes.Type: ApplicationFiled: March 19, 2002Publication date: October 17, 2002Inventors: Do Haeng Hur, Joung Soo Kim
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Publication number: 20020136345Abstract: The present invention relates to a method for inhibiting stress corrosion cracking occurring on steam generator tubes in the secondary side of nuclear power plants and an inhibitor therefor. The method comprises supplying cerium boride as an inhibitor for stress corrosion cracking into the secondary feed water of the nuclear power plants. The method according to the present invention improves resistance of stress corrosion cracking three times or higher than no inhibitor, and two times or higher than the conventional inhibitor. In particular, the method according to the present invention shows a superior inhibiting effect in the lead-contaminated environment such that the complete inhibition of stress corrosion cracking can be achieved. As thus, the method can reduce the unexpected stop of operating nuclear power plants caused by the stress corrosion cracking on steam generator tubes, thereby reducing the cost required for maintaining and repairing the tubes.Type: ApplicationFiled: October 23, 2001Publication date: September 26, 2002Inventors: Do Haeng Hur, Joung Soo Kim
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Publication number: 20020118787Abstract: Method for controlling erosion and cracking in a metal component of a nuclear reactor, particularly in the highly concentrated primary and secondary systems of a PWR, comprising creating a catalytic surface on the component; and generating a stoichiometric excess of reductant the water of the reactor to reduce the oxidant concentration at the surface to substantially zero.Type: ApplicationFiled: May 1, 2002Publication date: August 29, 2002Applicant: General Electric Company.Inventors: Peter L. Andresen, Young Jin Kim, Robert L. Cowan, Robert J. Law, Samson Hettiarachchi