Hydrogen Or Hydrogen Plus Nitrogen (nitrogen Per Se In 57) Patents (Class 419/58)
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Patent number: 9972452Abstract: A rotary switch device includes a fixed contact point part and a movable contact point part. The movable contact point part is rotated on the fixed contact point part so as to connect and disconnect the fixed contact point part and the movable contact point part. The fixed contact point part and the movable contact point part have contact surfaces which are band shapes and to which corrosion-resistant conductive processing is applied. A transient contact region, in which a contact point is moved from one end portion to the other end portion in a predetermined connection-operation angle from a contact start point with respect to the other of the fixed contact point part and the movable contact point part, is provided on each of the contact surfaces.Type: GrantFiled: October 24, 2016Date of Patent: May 15, 2018Assignee: ALPHA CORPORATIONInventor: Takahiro Okada
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Patent number: 8999230Abstract: New net shape strength retaining high temperature alloy parts are formed from fine metallurgical powders by mechanically blending the powders and placing them in die, placing a piston in the die, extending the piston into a driving chamber, filling the chamber with CH4 and air and compressing the powders with the filling pressure. Igniting gas in the chamber drives the piston into the cavity, producing pressures of about 85 to 150 tsi, compacting the powders into a near net shape alloy part, ready for sintering at 2300° C. without shrinking. The alloy parts are Re, Mo—Re, W—Re, Re—Hf—HfC, Re—Ta—Hf—HfC, Re—Mo—Hf—HfC, Mo—Re—Ta, Mo—Re-f-HfC, W—Re—Hf—HfC, W—Re—Ta—Hf—HfC or W—Re—Mo—Hf alloys.Type: GrantFiled: March 30, 2009Date of Patent: April 7, 2015Assignee: Utron Kinetics, LLCInventors: Karthik Nagarathnam, Donald Trostle, Dennis Massey
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Patent number: 8999229Abstract: Disclosed herein is a sintered composition comprising iron; about 0.05 to about 1 wt % molybdenum; about 3 to about 4.5 wt % silicon; about 0.05 to about 0.5 wt % chromium; about 0.011 to about 0.015 wt % magnesium; all weight percents being based on the total weight of the composition; the composition being devoid of carbon except for trace amounts; and wherein the composition is sintered. Disclosed herein too is a method comprising blending a powdered composition that comprises iron; about 0.05 to about 1 wt % molybdenum; about 3 to about 4.5 wt % silicon; about 0.05 to about 0.5 wt % chromium; about 0.011 to about 0.015 wt % magnesium; all weight percents being based on the total weight of the composition; the composition being devoid of carbon except for trace amounts; compacting and sintering the composition.Type: GrantFiled: November 11, 2011Date of Patent: April 7, 2015Assignee: Alpha Sintered Metals, Inc.Inventors: Thomas J. Cornelio, Leonid I. Frayman, Thomas E. Haberberger
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Patent number: 8840833Abstract: A component, such as a SOFC interconnect, and methods of making the component are provided using various chromium powders, including powder particles with a chromium core covered with an iron shell, a pre-alloyed Cr—Fe powder or a chromium powder produced by hydrogen reduction with hydrogen.Type: GrantFiled: November 21, 2011Date of Patent: September 23, 2014Assignee: Bloom Energy CorporationInventors: Martin Janousek, Shivanand I. Majagi
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Patent number: 8465692Abstract: A method for producing a metal article may include: Producing a supply of a composite metal powder by: providing a supply of molybdenum metal powder; providing a supply of a sodium compound; combining the molybdenum metal powder and the sodium compound with a liquid to form a slurry; feeding the slurry into a stream of hot gas; and recovering the composite metal powder; and consolidating the composite metal powder to form the metal article, the metal article comprising a sodium/molybdenum metal matrix. Also disclosed is a metal article produced accordance with this method.Type: GrantFiled: March 2, 2011Date of Patent: June 18, 2013Assignee: Climax Engineered Materials, LLCInventors: Naresh Goel, Carl Cox, Dave Honecker, Eric Smith, Chris Michaluk, Adam DeBoskey, Sunil Chandra Jha
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Patent number: 8083989Abstract: A method for producing a three-dimensional shaped article, including molding by irradiation of an optical beam to powder and by a rotating tool, providing a hollow part in a base pedestal supporting a shaped object, filling the hollow part with powder, forming a powder layer in the upper part of the hollow part and a surrounding region thereof, after a sintering region supporting the shaped object from the underside is formed in a region containing the powder layer, molding three or more supports of the base pedestal and two or more support frames connecting the shaped object, then the molded product and the base pedestal are then reversed in a vertical direction, thereby cutting and removing the sintering region, and molding the bottom part to achieve the object based on the fact that the supporting frames and the shaped object are cut and separated.Type: GrantFiled: November 23, 2009Date of Patent: December 27, 2011Assignee: Matsuura Machinery CorporationInventors: Tsuneji Yamaoka, Kouichi Amaya
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Patent number: 8071015Abstract: Disclosed is a process of producing a porous metal body containing a metal component which is likely to be oxidized, by which process the amounts of residual carbon and residual oxygen therein are decreased, and by which the performance of the product porous body can be largely promoted. The process for producing a porous metal body by sintering a material of the porous metal body, which material is obtained by coating a slurry containing a metal powder and an organic binder on an organic porous aggregate, comprises a defatting step of treating the material of the porous metal body at a temperature not higher than 650° C.Type: GrantFiled: March 17, 2009Date of Patent: December 6, 2011Assignee: Taiyo Nippon Sanso CorporationInventors: Tomohiro Wada, Tomoyuki Haneji, Shinichi Takahashi, Kiichi Kanda, Kenichi Watanabe
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Patent number: 7993577Abstract: The invention relates to manufacture of titanium articles from sintered powders. The cost-effective initial powder: 10-50 wt % of titanium powder having ?500 microns in particle size manufactured from underseparated titanium sponge comprising ?2 wt % of chlorine and ?2 wt % of magnesium; 10-90 wt % of a mixture of two hydrogenated powders A and B containing different amount of hydrogen; 0-90 wt % of standard grade refined titanium powder, and/or 5-50 wt % of alloying metal powders. The method includes: mixing powders, compacting the blend to density at least 60% of the theoretical density, crushing titanium hydride powders into fine fragments at pressure of 400-960 MPa, chemical cleaning and refining titanium powders by heating to 300-900° C. and holding for ?30 minutes, heating in vacuum at 1000-1350° C., holding for ?30 minutes, and cooling.Type: GrantFiled: June 11, 2007Date of Patent: August 9, 2011Assignee: Advance Materials Products, Inc.Inventors: Volodymyr A. Duz, Orest M. Ivasishin, Vladimir S. Moxson, Dmitro G. Savvakin, Vladislav V. Telin
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Patent number: 7931855Abstract: A method of reducing the oxygen content of a powder is provided. A canister is prepared with a getter, filled with the powder to be densified, sealed and evacuated. The canister is subjected to a hydrogen atmosphere at an elevated temperature whereby hydrogen diffuses into the canister through the walls thereof. The hydrogen forms moisture when reacted with the oxygen of the powder and the moisture in the reacted with the getter in order to remove oxygen from the powder to the getter. The atmosphere outside the canister is then altered to an inert atmosphere or vacuum, whereby hydrogen diffuses out of the canister. A dense body having a controlled amount of oxygen can thereafter be produced by conventional powder metallurgy techniques.Type: GrantFiled: October 6, 2005Date of Patent: April 26, 2011Inventors: Roger Berglund, Hans Eriksson, Johan Sundstrom, Per Arvidsson
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Patent number: 7740797Abstract: In photo-shaping a target object executed by a photo-shaping machine (10) along with a computing device (1), a first path (P1) is generated as a light beam irradiation path on the basis of contour data of each section sliced at a specified pitch of three-dimensional CAD model data of the target object desired to be formed, and the first parameter data. A second path (P2) is generated as a removal processing path on the basis of the three-dimensional CAD model data, the second parameter data, and removing timing data showing a timing of executing the removal process. Driving programs (P3) are generated for executing the photo-shaping process including the light beam irradiation and the removal process, on the basis of the first path data, second path data and removing timing data, thereby performing the photo-shaping and removal process according to the driving programs.Type: GrantFiled: October 21, 2005Date of Patent: June 22, 2010Assignee: Panasonic Electric Works Co., Ltd.Inventors: Satoshi Abe, Hirokazu Shinkai
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Patent number: 7585458Abstract: A feedstock composition and a method of forming metal articles using powder metallurgy techniques comprise mixing metal powders and a novel aromatic binder system. The composition of the novel feedstock comprises an aromatic binder system and a metal powder. The aromatic binder system comprises an aromatic species and can further comprise lubricants, surfactants, and polymers as additives. The metal powder comprises elemental metals, metal compounds, and metal alloys, particularly for highly-reactive metals. The method of forming metal articles comprises the steps of providing and mixing the metal powder and the aromatic binder system to produce a novel feedstock. The method further comprises processing the novel feedstock into a metal article using a powder metallurgy forming technique. Metal articles formed using the present invention have an increase in carbon and oxygen contents each less than or equal to 0.2 wt % relative to the metal powder used to fabricate the article.Type: GrantFiled: November 17, 2006Date of Patent: September 8, 2009Assignee: Battelle Memorial InstituteInventors: Eric A. Nyberg, Kenneth Scott Weil, Kevin L. Simmons
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Patent number: 7524361Abstract: Provided is a hydrogen separation membrane prepared by compression-molding metal microparticles having hydrogen adsorbing properties, wherein the microparticles are composed of 0.5 to 50% by weight of a first metal powder and 50 to 99.5% by weight of a second metal powder having a relatively larger average particle diameter than the first metal powder.Type: GrantFiled: January 12, 2006Date of Patent: April 28, 2009Assignee: Korea Institute of Energy ResearchInventors: Jong-Soo Park, Wang-Lai Yoon, Ho-Tae Lee, Dong-Won Kim, Sung-Ho Cho, Shin-Kun Ryi, Seung-Hoon Choi
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Patent number: 7459108Abstract: The present invention relates to a method for preparing a metallic membrane, more particularly to a method for preparing metallic membranes, which comprises dissolving a transition metal of Period 3 and its alloy particle powder and synthetic polymer in a fixed ratio; radiating or casting to prepare a membrane precursor; oxidizing the synthetic polymer on the membrane precursor under a mixed gaseous atmosphere of nitrogen and hydrogen; and sintering the membrane precursor at a predetermined temperature. The metallic membrane prepared by the process of the present invention has excellent mechanical and chemical properties and enables to maintain a relatively small pore size and high porocity than traditional membranes. Therefore, it is useful for water treatment.Type: GrantFiled: January 24, 2006Date of Patent: December 2, 2008Assignees: Korea Research Institute of Chemical Technology, Samwon Engineering Co., Ltd.Inventors: Kew-Ho Lee, In-Chul Kim, Soo-Min Lee, In-Hwan Choi
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Patent number: 7449144Abstract: A process for manufacturing a sliding contact piece for medium to high current densities including a step of warm premixing of graphite and plastic binder, a step of cold mixing of the resulting premixture with copper, a step of pressing of the resulting main mixture into the sliding contact piece, and finally a step of sintering of it; and so as to improve the operating characteristics of the sliding contact piece, which is free of any environmentally harmful additives, a metal such as zinc, tin, bismuth or an alloy of such metals is added during the premixing of the graphite and plastic binder.Type: GrantFiled: January 17, 2003Date of Patent: November 11, 2008Assignee: Deutsche Carbone AGInventors: Wilhelm Latz, Jürgen Spangenberg, Arwed Uecker
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Patent number: 7384445Abstract: The invention concerns a sintered metal part which has a densified surface and sintered density of at least 7.35 g/cm3 and a core structure distinguished by a pore structure obtained by single pressing to at least 7.35 g/cm3 and single sintering of a mixture of a coarse iron or iron-based powder and optional additives.Type: GrantFiled: April 19, 2005Date of Patent: June 10, 2008Assignee: Höganäs ABInventors: Paul Skoglund, Mikhail Kejzelman, Anders Bergmark
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Publication number: 20070231181Abstract: A method of manufacturing a sintered body includes a first process of forming a metal powder containing carbon into a compact having a predetermined shape and a second process of baking the compact in a hermetically sealed space so as to produce a sintered body. The hermetically sealed space has an atmosphere having a pressure of 60 kPa to 140 kPa and contains a hydrogen gas and an oxygen gas. The sum of partial pressures of the hydrogen gas and the oxygen gas is not more than 3 Pa.Type: ApplicationFiled: March 26, 2007Publication date: October 4, 2007Inventor: Hidefumi Nakamura
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Patent number: 7255830Abstract: To make a three-dimensional object, an optical beam is first irradiated on a predetermined portion of a powder layer to form a sintered layer, which is then covered with a new powder layer. The optical beam is again irradiated on a predetermined portion of the new powder layer to form another sintered layer that has been united with the underlying sintered layer. These processes are repeatedly carried out to form a plurality of sintered layers united together. When the second lower density layer is formed on the first higher density layer, a powder material layer for the lower density layer is formed at a predetermined thickness so as to have a thickness suitable for sintering condition and then the powder material layer is sintered to form the lower density layer.Type: GrantFiled: September 29, 2003Date of Patent: August 14, 2007Assignee: Matsushita Electric Works, Ltd.Inventors: Satoshi Abe, Isao Fuwa, Hirohiko Togeyama, Norio Yoshida, Masataka Takenami, Shuushi Uenaga
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Patent number: 7226492Abstract: Tungsten-based alloy material sintered at a high sintering power that may contain additive elements soluble in the nickel and selected from the group constituted, for example, by rhenium, molybdenum, tantalum, niobium, vanadium or a mixture of these, wherein, after sintering in liquid phase at a temperature of around 1500° C., it has: a two-phased ?-? microstructure that is fully densified, has no porosities or has negligible porosities of a low mean grain size (L?) and a contiguity (C??) that is very low with respect to the size of the tungsten crystals, and a dispersion of micro-oxides with no loss of ductility properties.Type: GrantFiled: September 20, 2002Date of Patent: June 5, 2007Inventors: Pascal Mahot, Guy Nicolas, Marc Voltz
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Patent number: 7172725Abstract: In W—Cu alloy having a homogeneous micro-structure and a fabrication method thereof, the method includes forming mixed powders by mixing tungsten powders with W—Cu composite powders; forming a compact by pressurizing-forming the mixed powders; forming a skeleton by sintering the compact; and contacting copper to the skeleton and performing infiltration. W—Cu alloy having a homogeneous structure fabricated by the present invention shows better performance by being used as a material for high voltage electric contact of a contact braker, a material for heat sink of an IC semiconductor and a shaped charge liner.Type: GrantFiled: November 28, 2003Date of Patent: February 6, 2007Assignee: Agency For Defense DevelopmentInventors: Moon-Hee Hong, Ja-Ho Choi, Seoung Lee, Eun-Pyo Kim, Sung-Ho Lee, Joon-Woong Noh
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Patent number: 6958084Abstract: A sintered material and a method for the production thereof is described. The material comprises an alloy selected from one of the groups having a composition comprising in weight %: either Cr 5-30/Mo 0-15/Ni 0-25/W 0-15/C 0-5/Si 0-5/Fe 0-5/Mn 0-5/others 10 max/Co balance, or Cr 10-20/Mo 0-15/Co 0-20/W 0-5/Fe 0-20/Al 0-5/Ti 0-5/others 15 max/Ni balance; said alloy having incorporated therein from 3-15 weight % of Sn; and optionally from 1-6 weight % of a solid lubricant material.Type: GrantFiled: June 25, 2002Date of Patent: October 25, 2005Assignee: Federal-Mogul Sintered Products LimitedInventors: Iain Robert Whitaker, Richard Jameson Pavey
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Patent number: 6723280Abstract: A method of providing a resistance to oxidation of Nickel at high temperatures by combining Ni powder with five percent Pt resinate, and heating the same to a temperature of 500° C. to 1300° C. Electro-conductive components serving as electrodes and the like comprise a Ni/Pt powder subjected to temperatures of between 500° C. and the respective melting points of Ni and Pt.Type: GrantFiled: January 15, 2002Date of Patent: April 20, 2004Assignee: Vishay Vitramon IncorporatedInventor: Vito A. Coppola
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Patent number: 6719946Abstract: An anode support formed of a three-dimensional interconnected porous nickel plaque fabricated by sintering a bed of pure metallic nickel powder particles.Type: GrantFiled: December 20, 2001Date of Patent: April 13, 2004Assignee: FuelCell Energy, Inc.Inventors: Chao-yi Yuh, Jian Li
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Patent number: 6679933Abstract: A copper graphite composite material suitable for use in applications such as brushes, switches and contact materials for rail systems and other industrial devices. The composite comprises a copper network matrix having a plurality of pores containing graphite. The composite may have an IACS value of at least 40% which may even be higher than 70% and a density value of at least 6.0 g/cm3. The method for preparation of the composite comprises mixing graphite and copper powder under non-oxidising conditions, compacting the mixture and sintering under non-oxidising conditions.Type: GrantFiled: September 7, 2001Date of Patent: January 20, 2004Assignees: Victorian Rail TrackInventors: Da Hai He, Rafael R. Manory, Norman J. Grady, Harry Sinkis, Clim Pacheco
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Patent number: 6669898Abstract: A process for preparation of molded articles, such as golf club heads, by metal injection molding and the resulting product.Type: GrantFiled: June 6, 2002Date of Patent: December 30, 2003Assignee: RA Brands, L.L.C.Inventors: Stephen H Gressel, Matthew M Marley, Maryann Wright
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Publication number: 20030211002Abstract: A process for preparing a sintered article of a compacted iron-based metallurgical powder. The green compact is sintered at a closely held predetermined temperature in order to achieve desired density and dimensional stability.Type: ApplicationFiled: January 15, 2003Publication date: November 13, 2003Inventors: Alphonso Grau, Gregory Lavallee, Sylvain Allard
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Patent number: 6641779Abstract: A valve seat made of an Fe-based sintered alloy excellent in wear resistance and having a reduced counterpart valve attack property is disclosed, which comprises a base comprising 15-40% by weight of Cu, 0.3-12% by weight of Ni and 0.0005-3.0% by weight of C, and further comprising 0.1-10% by weight of Co and 0.1-10% by weight of Cr when necessary, with the balance being Fe and inevitable impurities, the base having a structure which comprises an Fe-based alloy phase 1 composed of Fe as a main component combined by a Cu-based alloy phase 2 composed of Cu as a main component, wherein hard particles phase 3 having MHV of 500-1700 is dispersed in the base. The Fe-based alloy phase 1 is an Fe alloy phase which comprises Ni, Cu and C with Fe having more than 50% by weight, while the Cu-based alloy phase 2 is a Cu alloy phase which comprises Ni, Fe and C with Cu having more than 50% by weight.Type: GrantFiled: November 15, 2001Date of Patent: November 4, 2003Assignee: Mitsubishi Materials CorporationInventors: Kinya Kawase, Koichiro Morimoto
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Publication number: 20030190250Abstract: A method for manufacturing a sintered compact includes the steps of preparing an alloy powder having a composition represented by Expression 1: RTW (where, R is at least one kind of rare earth metal, T is at least one kind of transition metal, and w defines a relation of 1<w<4), sintering the alloy powder in a vacuum atmosphere or an atmosphere containing gas with a molecular weight of 30 or less, and processing the alloy powder by a hot isostatic pressing. The sintered compact has a high density, and reduces deteriorations in its sintered compact properties such as magnetostrictive properties in an air atmosphere at high-temperatures.Type: ApplicationFiled: February 27, 2003Publication date: October 9, 2003Inventors: Teruo Mori, Takeshi Nomura, Seigo Tokoro, Naomichi Umehara
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Patent number: 6595821Abstract: A high-quality and high-reliability rotary anode target for X-ray tubes, of which the mechanical strength at high temperatures is increased and which is applicable not only to low-speed rotation (at least 3,000 rpm) but also even to high-speed rotation at high temperatures, and also a method for producing it. The rotary anode has a two-layered structure to be formed by laminating an Mo alloy substrate that comprises from 0.2% by weight to 1.5% by weight of TiC with the balance of substantially Mo, and an X-ray generating layer of a W—Re alloy that overlies the substrate.Type: GrantFiled: April 20, 2001Date of Patent: July 22, 2003Assignee: Tokyo Tungsten Co., Ltd.Inventors: Masayuki Itoh, Koji Asahi, Mitsuo Osada, Yoshinari Amano, Tomohiro Takida
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Publication number: 20010014568Abstract: Provided are a high-quality and high-reliability rotary anode target for X-ray tubes, of which the mechanical strength at high temperatures is increased and which is applicable not only to low-speed rotation (at least 3,000 rpm) but also even to high-speed rotation at high temperatures, and also a method for producing it. The rotary anode has a two-layered structure to be formed by laminating an Mo alloy substrate that comprises from 0.2% by weight to 1.5% by weight of TiC with the balance of substantially Mo, and an X-ray generating layer of a W—Re alloy that overlies the substrate.Type: ApplicationFiled: April 20, 2001Publication date: August 16, 2001Inventors: Masayuki Itoh, Koji Asahi, Mitsuo Osada, Yoshinari Amano, Tomohiro Takida
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Patent number: 6238454Abstract: Heat-dissipating microcircuit substrate, having coefficients of thermal expansion adjusted to match the materials of the microcircuit mounted thereupon, are manufactured by powder metallurgy using carbides resulting from the combination of various types of carbons and wetting agents.Type: GrantFiled: March 18, 1997Date of Patent: May 29, 2001Inventors: Frank J. Polese, Glen B. Engle, Vladimir Ocheretyansky
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Patent number: 6132486Abstract: A process of forming a multi-phase sintered article of powdered metal comprising: blending a mixture of copper powder, aluminum powder, iron powder, and nickel, each in their free states, with a lubricant, compacting the blended mixture into a die cavity, forming the article, and high temperature sintering the article in a reducing atmosphere comprised of 100% dissociated ammonia so as to produce the multi-phase sintered article of powdered metal; and the multi-phase sintered article of powdered metal formed thereby.Type: GrantFiled: November 9, 1998Date of Patent: October 17, 2000Assignee: Symmco, Inc.Inventor: James N. Dixon
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Patent number: 6074454Abstract: The invention relates to bullets having increased frangibility (or which can be easily fragmented) and to materials and processes for the manufacture of such bullets. The bullets of the present invention are typically made from copper or copper alloy powders (including brass, bronze and dispersion strengthened copper) which are pressed and then sintered under conditions so as to obtain bullets with the desired level of frangibility. In preferred embodiments of the invention, the bullets also contain several additives that increase or decrease their frangibility.Type: GrantFiled: July 11, 1996Date of Patent: June 13, 2000Assignee: Delta Frangible Ammunition, LLCInventors: John T. Abrams, Anil V. Nadkarni, Roy Kelly
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Patent number: 6071469Abstract: There is disclosed a method of sintering cemented carbide bodies including heating said bodies to the sintering temperature in a suitable atmosphere and cooling. If said cooling at least to below 1200.degree. C. is performed in a hydrogen atmosphere of pressure 0.4-0.9 bar and >0.1 bar noble gas, preferably argon cemented carbide bodies with no surface layer of binder phase are obtained. This is an advantage when said bodies are to be coated with wear resistant layers by the use of CVD-, MTCVD- or PVD-technique.Type: GrantFiled: May 6, 1999Date of Patent: June 6, 2000Assignee: Sandvik ABInventors: Barbro Rohlin, Margareta P.ang.lsson, Leif kesson
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Patent number: 6001149Abstract: A contact material, a shaped article or contact piece and a process for producing a shaped article from a contact material based on silver, include forming a powder mixture from silver and a metal oxide, and metallurgically processing the powder to form the shaped article with the metal oxide being reduced to metal. Since metal oxide powders are obtainable with a very much smaller particle size than metal powders, it is possible to obtain a contact material with a mean particle size of the metal incorporated as an active component of less than 1 .mu.m. Such a contact material has particularly favorable switching properties as a result of the fine particle size.Type: GrantFiled: July 27, 1998Date of Patent: December 14, 1999Assignee: Siemens AktiengesellschaftInventors: Franz Hauner, Gunter Tiefel
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Patent number: 5993731Abstract: The process for producing net shape or near net shape metal parts is improved by sintering a compact in a reducing atmosphere where the compact contains a metal and chemically-bound oxygen in the form of a metal oxide, for example, and the chemically-bound oxygen is in an amount sufficient to improve the sintering of the compact. Improved sintering is facilitated when the metal oxide forms a metal/metal oxide eutectic during reduction of the chemically-bound oxygen in a reducing atmosphere during the sintering process. The compact can contain a metal oxide and a solution compound to produce an alloy part, provided the chemically-bound oxygen is present in an amount sufficient to improve sintering. In a preferred embodiment, the compact also contains a reinforcement compound and is sintered to make a metal matrix composite. The resultant density of the near net shape metal parts made by the improved sintering process is preferably about 97% or more of the theoretical density.Type: GrantFiled: November 7, 1997Date of Patent: November 30, 1999Assignee: Brush Wellman, Inc.Inventors: David E. Jech, Juan L. Sepulveda, Anthony B. Traversone
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Patent number: 5993730Abstract: One or more organic or inorganic metal salts or compounds of at least one of the groups IV, V and VI of the periodic system, particularly V, Cr, Mo and W, optionally together with one or more organic iron group metal salts, are dissolved in at least one polar solvent and complex bound with at least one complex former comprising functional groups in the form of OH or NR.sub.3, (R=H or alkyl). Hard constituent powder and optionally soluble carbon source are added to the solution. The solvent is evaporated and the remaining powder is heat treated in an inert and/or reducing atmosphere. As a result, coated hard constituent powder is obtained, which after addition of a pressing agent and optionally with other coated hard constituent powders and/or carbon to obtain the desired composition, can be compacted and sintered according to standard practice.Type: GrantFiled: October 13, 1998Date of Patent: November 30, 1999Assignee: Sandvik ABInventors: Mats Waldenstrom, Rolf Svensson
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Patent number: 5989493Abstract: A molding compound consisting of the nickel superalloy Hastelloy X is used to form net-shape or near net-shape articles. The compound, containing atomized Hastelloy X powder having an average particle size less than about 20 .mu.m, is mixed with a liquid carrier, a gel forming binder and processing additives and molded at relatively low pressures in a conventional injection molding machine. A critical air debinding step prior to sintering results in high densification of the article, which has mechanical properties comparable to cast or wrought processed material.Type: GrantFiled: August 28, 1998Date of Patent: November 23, 1999Assignee: AlliedSignal Inc.Inventors: Jerry C. La Salle, Bryan C. Sherman
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Patent number: 5985208Abstract: A debinding and sintering method is employed to produce consolidated net shape articles from metal powders including 17-4PH stainless steel alloy by metal injection molding using an agar based aqueous binder. The debinding and sintering step can be combined into one cycle to economically produce components for the consumer and aerospace industries.Type: GrantFiled: August 27, 1998Date of Patent: November 16, 1999Assignee: AlliedSignal Inc.Inventors: Michael Sean Zedalis, Bryan C. Sherman, Jerry C. La Salle
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Patent number: 5976458Abstract: The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, .ltoreq.1% Cr and either .gtoreq.0.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element or .gtoreq.0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, .ltoreq.1% oxygen, .ltoreq.3% Cu, balance Fe.Type: GrantFiled: January 3, 1996Date of Patent: November 2, 1999Assignee: Philip Morris IncorporatedInventors: Vinod K. Sikka, Seetharama C. Deevi, Grier S. Fleischhauer, Mohammad R. Hajaligol, A. Clifton Lilly, Jr.
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Patent number: 5970307Abstract: A sintering method for a W--Ni--Mn type heavy alloy, including controlling the deoxidization of tungsten and nickel under an inert atmosphere, changing to a hydrogen atmosphere at above a temperature at which manganese is deoxidized and simultaneously deoxidizing tungsten, nickel and manganese, and sintering by raising the temperature, resulting in the fabrication of a sintered heavy alloy having a 100% relative theoretical density.Type: GrantFiled: April 30, 1997Date of Patent: October 19, 1999Assignee: Agency for Defense DevelopmentInventors: Moon Hee Hong, Woon Hyung Baek, Joon Woong Noh, Heung Sub Song, Seong Lee, Eun Pyo Kim
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Patent number: 5956559Abstract: A method for producing an irregular tungsten/matrix interface in tungsten based heavy alloy is disclosed. The method involves a cyclic heat treatment and resintering at above liquidus temperature for tungsten heavy alloys consisting of 80 to 98 weight % tungsten and remainder of matrix phase. The sintered specimens are cyclically heat treated at above 1000.degree. C. and resintered at liquidus temperature of the matrix phase for one minute to 4 hours at a constant temperature.Type: GrantFiled: February 27, 1998Date of Patent: September 21, 1999Assignee: Agency for Defense DevelopmentInventors: Heung Sub Song, Eun Pyo Kim, Seong Lee, Joon Woong Noh, Moon Hee Hong, Woon Hyung Baek
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Patent number: 5907760Abstract: A fabrication method for a molybdenum disilicide sintered body in which a molybdenum disilicide powder having excellent oxidation resistance is sintered in a low-temperature sintering method and compacted at a low temperature and under no pressure, includes carrying out a milling on a molybdenum disilicide powder at a low temperature, providing a diffusion path required to sinter the molybdenum disilicide on which a milling is performed, and sintering the resultant powder under the atmosphere of hydrogen or argon gas.Type: GrantFiled: March 31, 1997Date of Patent: May 25, 1999Assignee: Korea Institute of Science and TechnologyInventors: Ju Choi, Young Do Kim, Myoung Ki Yoo, Seung Ick Lee
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Patent number: 5905936Abstract: Generally rough sphere-shaped work pieces made of fragile material are ground into more uniform spheres. The rough spheres are fed into a holding plate having a channel cut into the bottom side of the plate with a width slightly larger than the largest diameter of the rough spheres. A movable abrasive surface is positioned adjacent to the bottom side of the holding plate. As the rough spheres move through the holding plate which can be vibrated, they move in contact with each other and with the abrasive surface. The finally formed spheres leave the plate where they are collected. It is a further embodiment green spheres which are treated in a sintering process with hydrogen gas have tungsten oxide particles applied to the surface of the spheres prior to and during sintering so that the particles remain separated and apart.Type: GrantFiled: August 6, 1997Date of Patent: May 18, 1999Assignee: Teledyne Wah ChangInventors: Lloyd Fenwick, Darryl Amick, Gary McDowell, Robert Nichols
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Patent number: 5897962Abstract: A method of making flowable tungsten/copper composite powder by milling an aqueous slurry of a mixture of the desired weight ratio of tungsten powder and copper oxide powder and, optionally, a small amount of cobalt powder, spray-drying the slurry to form spherical, flowable agglomerates, and reducing the agglomerates in a hydrogen atmosphere.Type: GrantFiled: July 13, 1995Date of Patent: April 27, 1999Assignee: Osram Sylvania Inc.Inventors: David L. Houck, Nelson Kopatz, Muktesh Paliwal, Sanjay Sampath
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Patent number: 5892164Abstract: Fine powders of iron with less than 5% by weight graphite, copper, and an organic binder can be formed into shapes having a green density of up to about 7.4 g/cc and sintered in a hydrogen containing atmosphere to yield parts having minimum variations in physical properties. Incorporation of small quantities of copper, e.g. 1% or less by weight, negates variations in physical properties of sintered parts that were subjected to variations in the hydrogen content of the sintering atmosphere.Type: GrantFiled: April 17, 1998Date of Patent: April 6, 1999Assignee: Air Products and Chemicals, Inc.Inventors: Diwakar Garg, Kerry Renard Berger, James Garfield Marsden
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Patent number: 5887242Abstract: A method of making a hard constituent powder coated with at least one iron group metal, Me, by dissolving and complex binding at least one of Me.sub.n (NO.sub.3).sub.m and Me.sub.n (SO.sub.4).sub.m and other similar Me.sub.n --X.sub.m compounds containing X-groups with low or no carbon content, preferably Me-nitrates, solely or together with one or more metal salts of at least one iron group metal containing organic groups in at least one polar solvent with at least one complex former comprising functional groups in the form of OH or NR.sub.3, (R=H or alkyl). Hard constituent powder is added to the solution. The solvent is evaporated and remaining powder is heat treated in an inert and/or reducing atmosphere. As a result, coated hard constituent powder is obtained which after addition of a pressing agent can be compacted and sintered according to standard practice.Type: GrantFiled: September 25, 1996Date of Patent: March 23, 1999Assignee: Sandvik ABInventors: Mats Nygren, Gunnar Westin, .ANG.sa Ekstrand
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Patent number: 5860055Abstract: In a process for producing granular material in which at least one hard material phase is mixed with a metal powder and a binder and granulated, no premixing of the hard material phase and the metal powder takes place before mixing with the binder and the binder has a viscosity of from 20 to 200 cm.sup.3 /10 min, preferably from 30 to 100 cm.sup.3 /10 min, in accordance with DIN 53735 at 195.degree. C. and a load of 2.16 kg.Type: GrantFiled: March 24, 1997Date of Patent: January 12, 1999Assignee: BASF AktiengesellschaftInventors: Werner Hesse, Knut Bittler
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Patent number: 5845189Abstract: The secondary emission characteristics of a microchannel plate of the type fabricated of lead oxide glass and activated by a hydrogen gas bake is stabilized by treating with another gas, such as hydrogen sulfide, at an elevated temperature.Type: GrantFiled: December 20, 1973Date of Patent: December 1, 1998Assignee: Litton Systems, Inc.Inventor: Bernard Caesar Einstein
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Patent number: 5842108Abstract: A method for producing high density and ultrafine W/Cu bulk material by a mechano-chemical process is disclosed. In the method of this invention, metal salts as start materials are spray-dried and prepare W--Cu precursor powder having uniformly-dispersed tungsten and copper components. The W--Cu precursor powder in turn is subjected to a desalting and milling process, thus preparing W--Cu oxide composite powder. Thereafter, the W--Cu oxide composite powder may be formed into a formed green body prior to reducing and sintering under hydrogen atmosphere.Type: GrantFiled: August 13, 1997Date of Patent: November 24, 1998Assignee: Korea Institute of Machinery & MaterialsInventors: Byoung-Kee Kim, Gil-Geun Lee, Gook-Hyun Ha, Dong-Won Lee
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Patent number: 5828941Abstract: A new class of low chop contact materials based on Ag-chromium carbide and Ag--Cr compositions have an essentially 100% dense, porosity free microstructure. These materials combine the advantageous properties of Ag--WC and Cu--Cr contacts without their disadvantages. A method of making this new class of low chop contact materials includes the steps of cold pressing a mixture of Ag and chromium or chromium carbide to form an unsintered blank and the elevated temperature infiltration of silver into the unsintered blank to obtain an essentially 100% dense, porosity free microstructure.Type: GrantFiled: August 8, 1996Date of Patent: October 27, 1998Assignee: Eaton CorporationInventors: Graham A. Whitlow, William R. Lovic, Paul G. Slade