Vacuum Patents (Class 419/60)
  • Patent number: 5733427
    Abstract: A sputtering target formed of a refractory metallic silicide having a composition MSi.sub.x including a mixture composition of an MSi.sub.2 phase in the form of particles (M: at least one refractory metal selected from a group consisting of W, Mo, Ti, Zr, Hf, Ni and Ta), and an Si phase provided as a matrix phase. Interface layers having a predetermined thickness are formed at the interfaces between the MSi.sub.2 phase and the Si phase. The value X in the composition formula MSi.sub.x is set to a range of 2.0 to 4.0, and the thickness of the interface layers formed between the MSi.sub.2 phase and the Si phase, the dispersion of the composition, the density ratio of the target, the electrical resistivity of the Si phase and the surface roughness are set to predetermined values. An uniform high-quality thin film in which a composition distribution is uniform can be manufactured stably by using this target.
    Type: Grant
    Filed: March 30, 1995
    Date of Patent: March 31, 1998
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Michio Satou, Takashi Yamanobe, Mitsuo Kawai, Tatsuzo Kawaguchi, Kazuhiko Mitsuhashi, Toshiaki Mizutani
  • Patent number: 5722037
    Abstract: There is provided a process for producing titanium composite, comprising the steps of: molding titanium powder, titanium alloy powder, or powder comprising titanium into a certain shape by a cold isostatic press or cold press; reacting the shape with hydrocarbon gas at its decomposition temperature or higher, to form TiC therein; and providing the shape with high density by vacuum sintering, hot isostatic pressing, hot forging, hot rolling and/or the combinations thereof. TiC a reinforcing material, is in-situ formed by reacting a cold-pressed body of the powder with hydrocarbon gas and cleaner than the externally added one and distributed more uniformly and finely in the Ti matrix, leading to a significant improvement in wear resistance and high temperature property.
    Type: Grant
    Filed: May 9, 1996
    Date of Patent: February 24, 1998
    Assignee: Korea Institute of Machinery & Materials
    Inventors: Hyung-Sik Chung, Yong-Jin Kim, Byung-Kee Kim, Jian-Qing Jiang
  • Patent number: 5714700
    Abstract: This invention provides a self-lubricating composite material which has excellent strength and oxidation resistnce at a high temperature and can be used in air and in vacuum, and a production method thereof, the composite material is a Cu--Ni--Sn type composite sintered body containing 20 to 70 vol % of mixed particles of graphite and WS.sub.2 as the solid lubricant components and having a porosity of not greater than 25 vol %, and a matrix is a two-phase alloy comprising Cu--Ni alloy particles and an Sn single phase or an Sn--Ni intermetallic compound dispersed uniformly in the grain boundary of the alloy particles and firmly bonding them, and this matrix encompasses the solid lubricant particles. The matrix consists of 5 to 40 wt % of Ni, 4 to 15 wt % of Sn and the balance of Cu and unavoidable impurities as the alloy composition.
    Type: Grant
    Filed: December 18, 1996
    Date of Patent: February 3, 1998
    Assignee: Nippon Steel Corporation
    Inventors: Tokuhiko Nishida, Shoichi Sekiguchi, Toru Ono, Yuko Tsuya
  • Patent number: 5666636
    Abstract: The present invention provides a process for preparing titanium nitride sintered masses having no residual pores and consisting of TiN solid solution particles and Ni solid solution matrix, in which a granulated powder of the following composition:TiN-pMo.sub.2 C-qC-rNi-sMeCwherein:p is 5 to 20 wt %;q is 0 to 1.5 wt %;r is 15 to 30 wt %;s is 0 to 5 wt %;MeC is one or more carbides selected from VC, WC, TaC and NbC;with the proviso that q and s are not 0 wt % simultaneously;is compacted and sintered. The process according to the present invention can provide sintered TiN cermets of high density and a small grain size.
    Type: Grant
    Filed: March 22, 1996
    Date of Patent: September 9, 1997
    Assignee: Korea Institute of Science and Technology
    Inventors: Jong Ku Park, Sung Tae Park
  • Patent number: 5649279
    Abstract: There is disclosed a new process for binder phase enrichment. The process combines binder phase enrichment by dissolution of cubic phase with the requirements that cause formation of stratified layers, resulting in a unique structure. The new structure is characterized by, in comparison with the ones previously known, deeper stratified layers and less maximum binder phase enrichment. The possibility of combining dissolution of the cubic phase with formation of stratified layers offers new possibilities to optimize the properties of tungsten carbide based cemented carbides for cutting tools.The new process offers possibilities to combine the two types of gradients. The dissolution of cubic phase moves the zone with maximum mount of stratified binder phase from the surface to a zone close to and below the dissolution front.
    Type: Grant
    Filed: November 17, 1994
    Date of Patent: July 15, 1997
    Assignee: Sandvik AB
    Inventors: Per Gustafson, Leif Akesson, Ake Ostlund
  • Patent number: 5640666
    Abstract: A method of producing a composite powder by providing particles of (I) tungsten, niobium, zirconium, titanium or mixtures thereof, (II) silicon and (III) carbon in a proportion relative to each other so as to possess an overall chemical composition in that segment of the ternary diagram of FIGS. 2(a), 2(b), 2(c) and 2(d) designated A, and subjecting the particles to a mechanical alloying process under conditions and for a time sufficient to produce the composite powder. Also disclosed is a method of forming a substantially oxygen-free composition of matter comprising a matrix substance of WSi.sub.2, NbSi.sub.2, ZrSi.sub.2, TiSi.sub.2 or alloys thereof having SiC dispersed therein, the method comprising consolidating the above-described composite powder. Also disclosed is a method of forming oxidation- and wear-resistant coatings by subjecting the composite powder whose composition lies in segment A to a metallurgical process such as plasma spraying.
    Type: Grant
    Filed: October 2, 1995
    Date of Patent: June 17, 1997
    Assignee: University of Florida
    Inventors: S. Jayashankar, Michael J. Kaufman
  • Patent number: 5637816
    Abstract: A metal matrix composite comprising an iron aluminide binder phase and a ceramic particulate phase such as titanium diboride, zirconium diboride, titanium carbide and tungsten carbide is made by heating a mixture of iron aluminide powder and particulates of one of the ceramics such as titanium diboride, zirconium diboride, titanium carbide and tungsten carbide in a alumina crucible at about 1450.degree. C. for about 15 minutes in an evacuated furnace and cooling the mixture to room temperature. The ceramic particulates comprise greater than 40 volume percent to about 99 volume percent of the metal matrix composite.
    Type: Grant
    Filed: August 22, 1995
    Date of Patent: June 10, 1997
    Assignee: Lockheed Martin Energy Systems, Inc.
    Inventor: Joachim H. Schneibel
  • Patent number: 5623725
    Abstract: Process for producing very pure platinum materials dispersion-reinforced with Y.sub.2 O.sub.3 and having high strength and extensibility, even in the temperature range >800.degree. C., from platinum powder by mechanical alloying, which comprises the process stepspreparing platinum powder of high purity and low particle size of from 2 to 10 .mu.m,introducing and dispersing Y.sub.2 O.sub.3 particles >1 .mu.m in the platinum powder by milling in a platinum vessel using milling media of zirconium oxide,degassing the milled product under a vacuum of better than 10.sup.-3 mbar and with an increase in temperature to at least 1200.degree. C. in a platinum capsule for a period of up to 48 hours,gastight welding of the evacuated capsule and hot isostatic pressing at 1350.degree. C.
    Type: Grant
    Filed: May 16, 1995
    Date of Patent: April 22, 1997
    Assignee: Schott Glaswerke
    Inventors: Joachim Disam, Gerhard Jangg, Johannes Zbiral, Gerhard Schreier, Christian Edtmaier
  • Patent number: 5607780
    Abstract: Disclosed are a target material for magneto-optical recording medium having a structure formed by sintering of an RE-TM phase (A) having a composition with an RE content higher than that of the composition of an intermetallic compound represented by the chemical formula TM.sub.2 RE, and a TM-RE phase (B) having a composition with an RE content equal to or lower than that of the composition of an intermetallic compound represented by the chemical formula TM.sub.2 E, wherein RE denotes at least one rare earth element selected from the group of elements consisting of Nd, Gd, Tb, Dy, Ho and Er, and TM denotes at least one element selected from the group of metals of the iron group which consists of Fe, Co and Ni; and a process for producing the same.
    Type: Grant
    Filed: May 20, 1994
    Date of Patent: March 4, 1997
    Assignee: Hitachi Metals, Ltd.
    Inventors: Kaoru Masuda, Takashi Meguro
  • Patent number: 5580516
    Abstract: A powder of tantalum, niobium, or an alloy thereof, having an oxygen content less than about 300 ppm, and the production thereof without exposure to a temperature greater than about 0.7 T.sub.H. A powder metallurgy formed product of tantalum, niobium, or an alloy thereof, having an oxygen content less than about 300 ppm, and the production thereof without exposure to a temperature greater than about 0.7 T.sub.H.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: December 3, 1996
    Assignee: Cabot Corporation
    Inventor: Prabhat Kumar
  • Patent number: 5574954
    Abstract: A composite, a sintered product of the composite, and a process for producing products from this composite. The composite has a very high volummetric proportion of TiC, and its remainder of a matrix. The TiC constitutes at least 70% by volume and as much as 95% by volume of the ultimate product. The process includes making a green body which can be handled and is thereafter pre-sintered to form a pre-form. The pre-form is oversized relative to the ultimate product. It is sintered and machined, again oversize. Then it is again sintered and subjected to hot isostatic compression, to assume at least a close approximation to the pre-determined dimension of the product. It is characterized by its light weight, resistance to erosion, and resistance to chemical attack.
    Type: Grant
    Filed: June 4, 1992
    Date of Patent: November 12, 1996
    Assignee: Alloy Technology International, Inc.
    Inventor: Jayanti M. Panchal
  • Patent number: 5552109
    Abstract: This invention relates to a process of forming a sintered article of powder metal comprising blending graphite and lubricant with a pre-alloyed iron based powder, pressing said blended mixture to shape in a single compaction stage sintering said article, and then high temperature sintering said article in a reducing atmosphere to produce a sintered article having a density greater than 7.4 g/cc.
    Type: Grant
    Filed: June 29, 1995
    Date of Patent: September 3, 1996
    Inventors: Rohith Shivanath, Peter Jones, Danny T. D. Thieu
  • Patent number: 5523170
    Abstract: An article with a high temperature superalloy body having a directionally oriented microsuucture and a structural discontinuity, such as a crack, or surface erosion or wear portion, is repaired, to provide a repaired article, using a mixture of Ni base ahoy powders. One powder includes a careful balance of the temperature depressants Si and B. In the one powder, Si is included in the range of about 0.05-2.2 wt. % to provide about 0.02-1.3 wt. % Si in a repaired portion as bonded with the article. In that same powder, B is include in the range of about 0.2-1.2 wt. % to provide about 0.08-0.7 wt. % in that repaired portion. In the repair method, the repaired portion can be provided, when shorter brazing times are used, with improved mechanical properties by diffusing the brazed alloy and aging the repaired structure in the range of about 1600.degree.-1700.degree. F. for a time in the range of about 1-16 hours.
    Type: Grant
    Filed: December 28, 1994
    Date of Patent: June 4, 1996
    Assignee: General Electric Company
    Inventors: David E. Budinger, Jim D. Reeves, Robert A. Anderson
  • Patent number: 5516483
    Abstract: A process of forming a sintered article for powder metal comprising blending carbon and ferro alloys and lubricant with compressible elemental iron powder, pressing said blended mixture to form sintering said article, and then high temperature sintering said article in a reducing atmosphere to produce a sintered article having a high density from a single compression.
    Type: Grant
    Filed: February 8, 1994
    Date of Patent: May 14, 1996
    Assignee: Stackpole Limited
    Inventors: Rohith Shivanath, Peter Jones, Danny T. D. Thieu
  • Patent number: 5512236
    Abstract: A process of coining sintered articles of powder metal comprising: blending carbon, ferro manganese, and lubricant with compressible elemental iron powder, pressing the blended mixture to form the articles, high temperature sintering of the articles in a reducing atmosphere and then coining the sintered articles to final shape so as to narrow the tolerance variability of coined articles and substantially eliminate secondary operations.
    Type: Grant
    Filed: August 25, 1994
    Date of Patent: April 30, 1996
    Assignee: Stackpole Limited
    Inventors: Peter Jones, Roger Lawcock
  • Patent number: 5508000
    Abstract: According to the present invention, silicide grains are coupled with each other in a linked manner so as to provide a metal silicide phase, and grains forming a Si phase are dispersed in the gaps of the metal silicide phase discontinuously so as to provide a mixed structure of a sputtering target of high density and containing carbon at a rate less than 100 ppm. Because of the high density and high strength of the target, generation of particles at the time of sputtering can be reduced, and because of the reduced content of carbon, mixing of carbon in a thin film formed by the sputtering can be prevented.
    Type: Grant
    Filed: November 21, 1994
    Date of Patent: April 16, 1996
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Michio Satou, Takasi Yamanobe, Mituo Kawai, Tooru Komatu, Hiromi Shizu, Noriaki Yagi
  • Patent number: 5470527
    Abstract: A sputtering target that consists essentially of a continuous matrix of Ti-W phase, Ti phase having a particle diameter of 50 .mu.m or less distributed in the matrix, and a W phase having a particle diameter of 20 .mu.m or less also distributed in the matrix. Preferably the target contains aluminum in the range of 1 ppm or less. The target has high density and a low impurity content, which reduces the generation of particles from the target when it is used for sputtering. A method of manufacturing the sputtering target is also disclosed.
    Type: Grant
    Filed: September 12, 1994
    Date of Patent: November 28, 1995
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Takashi Yamanobe, Michio Satou, Takashi Ishigami, Minoru Obata, Mituo Kawai, Noriaki Yagi, Toshihiro Maki, Shigeru Ando
  • Patent number: 5456878
    Abstract: In a producing process of a sintered porous anode body of valve-metal for a solid-state electrolytic capacitor, molded pieces of the powder of valve-metal is sintered at a high temperature and at a lowered pressure in an atmosphere of an inert gas supplied at a fixed flow rate. Thanks to the usage of the inert gas, partial pressures of impurity elements can be suppressed and a gas emitted from the molded pieces in the sintering process can be washed out. Consequently, there is obtained a solid-state electrolytic capacitor in which the lead wire of the anode body is not easily bent down and which has a reduced leakage current and an increased withstand voltage.
    Type: Grant
    Filed: December 2, 1991
    Date of Patent: October 10, 1995
    Assignee: NEC Corporation
    Inventors: Hirokazu Tadokoro, Arihiro Goto
  • Patent number: 5455001
    Abstract: A method for manufacturing an intermetallic compound comprises (a) preparing a powder, (b) canning said powder in a tube, (c) executing a first heat treatment to said tube-canned powder, and (d) treating said tube-canned powder for obtaining an intermetallic compound. This invention offers a simple, efficient, and inexpensive method for producing an intermetallic compound possessing excellent mechanical properties.
    Type: Grant
    Filed: July 7, 1994
    Date of Patent: October 3, 1995
    Assignee: National Science Council
    Inventor: Chen-Ti Hu
  • Patent number: 5445789
    Abstract: A plunger charged as an electrode is received in a trough charged as a counter-electrode in order to heat material in the trough above the annealing temperature of metal material or the sintering temperature of ceramic-material. The trough and plunger are situated in a vacuum chamber separated from a condenser and pump stand by a valve. The plunger can be retracted into a cover of the chamber by a hydraulic drive on the cover. The cover, drive, and plunger are removable from the lower part of the chamber as a unit.
    Type: Grant
    Filed: March 16, 1994
    Date of Patent: August 29, 1995
    Assignee: Leybold Durferrit GmbH
    Inventors: Erwin Wanetzky, Franz Hugo
  • Patent number: 5441695
    Abstract: The invention relates to a process for the manufacture by sintering of a titanium part, characterized in that is consists of:(a) mixing a titanium hydride powder with a temporary binding agent,(b) injecting the mixture obtained into a mold to obtain a part in the desired shape,(c) removing the binding agent,(d) heating the part in a hydrogen atmosphere up to the desired sintering temperature,(e) replacing the hydrogen atmosphere by a vacuum or a non-reactive atmosphere once the sintering temperature has been reached, and(f) cooling the part in a non-reactive gas atmosphere.
    Type: Grant
    Filed: July 22, 1994
    Date of Patent: August 15, 1995
    Assignee: Asulab S.A.
    Inventor: Thomas Gladden
  • Patent number: 5441694
    Abstract: In a method for preparing a high .alpha.-type silicon nitride powder by adding to and mixing with metallic silicon powder a copper catalyst and nitriding the mixture in a non-oxidizing gas atmosphere containing nitrogen or ammonia at 1,000.degree. to 1,500.degree. C., the amount of copper catalyst is limited to from 0.05 % to less than 0.5 % by weight of copper based on the weight of the metallic silicon. There is obtained silicon nitride powder of high purity at low cost and high efficiency since the copper catalyst can be efficiently removed from the silicon nitride powder through conventional acid treatment.
    Type: Grant
    Filed: June 10, 1994
    Date of Patent: August 15, 1995
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Masanori Fukuhira, Hirofumi Fukuoka, Yoshiharu Konya, Masaki Watanabe
  • Patent number: 5437834
    Abstract: A porous living body repairing member obtained by compression-molding a metal fiber material into a desired shape, sintering the fiber mesh body or thereafter, and imparting a compressive stress of not more than 4.00 to 40.0 MPa to provide a porous living body repairing member having a compressive elasticity of not more than 2000 MPa and a permanent deformation of not more than 1% under a stress below a compressive yield stress.The compressive yield stress becomes approximately equal to the above compressive stress, and almost complete elasticity of a permanent deformation rate of not more than 0.1% is shown with respect to a compressive stress below this compressive yield stress. Accordingly, even when the porous living body repairing member is used at a high compressive load site such as man's lumbar body, permanent deformation hardly occurs.
    Type: Grant
    Filed: October 7, 1993
    Date of Patent: August 1, 1995
    Assignee: Kyocera Corporation
    Inventors: Hideaki Okimatsu, Yasunori Tamura
  • Patent number: 5429793
    Abstract: A process for producing metal oxide dispersion-strengthened anodes for use in fuel cells in which a metal alloy powder comprising at least one metal powder and at least one metal oxide forming phase is formed into a "green" cohesive structure. The "green" cohesive structure is heated in a sintering furnace resulting in simultaneous sintering and internal oxidizing of the oxide forming phase within the "green" cohesive structure, forming an oxide dispersion-strengthened structure. To promote simultaneous sintering of the "green" cohesive structure and internal oxidation of the oxide forming phase within the "green" cohesive structure, an oxidizing agent is disposed within the "green" cohesive structure or is applied to the exterior of the cohesive structure.
    Type: Grant
    Filed: May 17, 1994
    Date of Patent: July 4, 1995
    Assignee: Institute of Gas Technology
    Inventors: Estela T. Ong, Nellie Burton-Gorman
  • Patent number: 5418071
    Abstract: In the present invention, metal silicide grains form an interlinked structure of a metal silicide phase, and Si grains which form a Si phase are discontinuously dispersed between the metal silicide phase to provide a sputtering target having a high density two-phased structure and having an aluminum content of 1 ppm or less. Because of the high density and high strength of the target, the generation of particles from the target during sputtering is reduced, and due to the reduced carbon content of the target, the mixing of carbon into the thin film during sputtering can be prevented.
    Type: Grant
    Filed: February 4, 1993
    Date of Patent: May 23, 1995
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Michio Satou, Takashi Yamanobe, Takashi Ishigami, Mituo Kawai, Noriaki Yagi, Toshihiro Maki, Minoru Obata, Shigeru Ando
  • Patent number: 5409518
    Abstract: A sintered titanium alloy is composed of a titanium matrix or titanium alloy matrix and hard particles dispersed in the matrix, the sintered titanium alloy comprises: 4-8 mass % of aluminum (Al); 2-6 mass % of vanadium (V); 0.15-0.8 mass % of oxygen (O); at least one element selected from the group consisting of 0.2-9 mass % of boron (B), 0.5-3 mass % of at least one of molybdenum (Mo), tungsten (W), tantalum (Ta), zirconium (Zr), niobium (Nb), and hafnium (Hf), 0.05-2 mass % of at least one of Ia Group elements, IIa Group elements, and IIIa Group elements, 0.05-0.5 mass % of at least one of halogens; with the balance being titanium (Ti) and inevitable impurities.
    Type: Grant
    Filed: November 8, 1991
    Date of Patent: April 25, 1995
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Takashi Saito, Tadahiko Furuta
  • Patent number: 5403542
    Abstract: Method of manufacturing a sintered carbonitride alloy comprising wet milling powders of forming binder phase containing Co, Ni and mixture thereof and powder forming hard constituents of nitrides and carbonitrides with Ti as the main component to a mixture with desired composition; compacting said mixture to form compact; heating the compact at 100-300 C. in oxygen or air and subjecting said compact in multiple heating steps to effect sintering.
    Type: Grant
    Filed: February 10, 1994
    Date of Patent: April 4, 1995
    Assignee: Sandvik AB
    Inventors: Gerold Weinl, Rolf G. Oskarsson, Per Gustafsson
  • Patent number: 5403374
    Abstract: A watch exterior part is formed of cemented carbide or stellite alloy, and has a three-dimensionally curved as-sintered surface or a small hole with an as-sintered interior peripheral surface, or has a three-dimensionally curved polished surface obtained by polishing an as-sintered surface. The watch exterior part is manufactured by a method in which organic binder is milled into a material powder, and a molded body obtained by injection molding is subjected to a binder removing process and then sintered. By the manufacturing method, a watch exterior part formed of cemented carbide or stellite alloy has a high strength and a complicated configuration such as a three-dimensional curved surface and a small hole, without applying secondary machining operations such as discharge operations.
    Type: Grant
    Filed: May 28, 1992
    Date of Patent: April 4, 1995
    Assignees: Sumitomo Electric Industries, Ltd., Namiki Precision Jewel Co., Ltd.
    Inventors: Nobuyuki Kitagawa, Toshio Nomura, Yoichi Yaguchi, Hidehiro Uchiumi, Naoko Iwashimizu
  • Patent number: 5387272
    Abstract: The present invention provides an Al-Si based sintered alloy of high strength and high ductility, a method for production thereof and use thereof. The alloy comprises 1-45% of Si, 0.1-20% of an element of Group IIIa, 0.01-5% of at least one element of Groups IVa and Va, the balance of substantially Al. This alloy can further contain at least one of 0.01-5% of Cu, 0.01-5% of Mg, 2.0% or less of Fe, 1.5% or less of Mn and 1.5% or less of Co and the oxygen content is reduced to 0.15% or less by sintering under vacuum. The present invention is applied to automobile parts such as a piston and scroll compressors. The alloy has a tensile strength of about 40 kg/mm.sup.2 or higher and an elongation of 1.5% or more at 150.degree. C.
    Type: Grant
    Filed: April 8, 1992
    Date of Patent: February 7, 1995
    Assignees: Hitachi, Ltd., Hitachi Powdered Metals Company, Limited
    Inventors: Yasuo Kamitsuma, Yusaku Nakagawa, Mitsuo Chigasaki, Tadashi Iizuka, Kooichi Inaba, Keiichi Nakamura, Masaki Minabe, Tsuyoshi Kagaya
  • Patent number: 5342573
    Abstract: A method of producing a tungsten heavy alloy product according to a powder metallurgical procedure utilizing the injection molding technique which enables production of tungsten heavy alloy products having high dimensional accuracy and complex configuration and yet having high physical strength and toughness in high productivity and at low cost. A powder mixture of tungsten powder and nickel powder, iron powder or copper powder is mixed with an organic binder and they are kneaded together. The kneaded mixture is injection molded into a predetermined shape, and thereafter the binder is removed from the molded product. Subsequently, the molded product is sintered in a temperature range of from the melting point of the bond phase of nickel, iron or copper to +50.degree. C. relative to the melting point.
    Type: Grant
    Filed: August 20, 1992
    Date of Patent: August 30, 1994
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Yoshinari Amano, Masahiro Omati, Junzo Matsumura
  • Patent number: 5330704
    Abstract: Powder composed of particles of a rapidly solidified dispersion strengthened aluminum base alloy is compacted into billet form. The billet is vacuum autoclaved at a temperature ranging from 350.degree. C. to the alloy's incipient melting temperature and formed into a substantially fully dense wrought product. Gas content of the alloy is decreased and powder degassing steps are eliminated. The dispersion strengthened aluminum wrought product is produced in an economical and efficient manner.
    Type: Grant
    Filed: February 4, 1991
    Date of Patent: July 19, 1994
    Assignee: AlliedSignal Inc.
    Inventor: Paul S. Gilman
  • Patent number: 5310520
    Abstract: Discrete powder particles of copper 14 and INVAR 12 are mixed together in a container 16 and packed into a powder metal article. This article is hot vacuum degassed and vacuum sealed and then heated to temperature well below the sintering temperature of copper or INVAR. Immediately after heating the article, it is subjected to a high pressure, high strain force such as extrusion through a die thereby yielding a fully dense, strong composite material 10 with excellent combined thermal expansion and conductivity properties.
    Type: Grant
    Filed: January 29, 1993
    Date of Patent: May 10, 1994
    Assignee: Texas Instruments Incorporated
    Inventors: Sunil C. Jha, James A. Forster, Henry F. Breit
  • Patent number: 5277717
    Abstract: A rapidly solidified, low density aluminum base alloy consists essentially of the formula Al.sub.bal Li.sub.a Cu.sub.b Mg.sub.c Zr.sub.d wherein "a" ranges from about 2.2 to 2.5 wt %, "b" ranges from about 0.8 to 1.2 wt %, "c" ranges from about 0.4 to 0.6 wt % and "d" ranges from about 0.4 to 0.8 wt %, the balance being aluminum plus incidental impurities. The alloy is especially suited to be consolidated to produce a strong, tough, low density aircraft landing wheel.
    Type: Grant
    Filed: August 4, 1992
    Date of Patent: January 11, 1994
    Assignee: AlliedSignal Inc.
    Inventors: Jerry C. LaSalle, Santosh K. Das
  • Patent number: 5275782
    Abstract: A housing for a semiconductor device is improved to avoid thermal distortions. The housing is formed of an Al-Si compound material and includes a housing member having a space for holding the semiconductor device. Occlusion gas contained in the Al-Si compound material is removed so that at least any nitrogen gas remaining in occlusion after degassing is 0.1 percent by weight or less. Since the housing member substantially does not contain occlusion gas, the housing is not subject to thermal distortion even though the housing is exposed to heat in operation.
    Type: Grant
    Filed: June 7, 1991
    Date of Patent: January 4, 1994
    Inventors: Mitsuo Osada, Yugaku Abe, Tetsuya Hayoshi
  • Patent number: 5269830
    Abstract: A process for synthesizing intermetallic compounds from elemental powders. The elemental powders are initially combined in a ratio which approximates the stoichiometric composition of the intermetallic compound. The mixed powders are then formed into a compact which is heat treated at a controlled rate of heating such that an exothermic reaction between the elements is initiated. The heat treatment may be performed under controlled conditions ranging from a vacuum (pressureless sintering) to compression (hot pressing) to produce a desired densification of the intermetallic compound. In a preferred form of the invention, elemental powders of Fe and Al are combined to form aluminide compounds of Fe.sub.3 Al and FeAl.
    Type: Grant
    Filed: October 26, 1990
    Date of Patent: December 14, 1993
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Barry H. Rabin, Richard N. Wright
  • Patent number: 5217541
    Abstract: A permanent magnet essentially consisting of in weight percent, 60% to 68% at least one transition element by weight, 30% to 38% at least one rare earth element by weight, 0.1% to 1.5% nitrogen by weight, and 0.8% to 1.5% boron by weight is disclosed. A method for producing the permanent magnet containing at least one rear element, at least one rare earth element, nitrogen and boron includes melting, cooling, milling, magnetizing, and compacting the transition element, the rare earth element and boron to form a green compact, and then sintering the green compact in nitrogen atmosphere having a constant partial pressure for 1 to several hours to form the permanent magnet.
    Type: Grant
    Filed: August 26, 1991
    Date of Patent: June 8, 1993
    Assignee: High End Metals Corp.
    Inventors: Tsung-Shune Chin, Shiang-Jiun Heh, Ken-Der Lin
  • Patent number: 5207821
    Abstract: Disclosed is a sintered alloy composition and method of manufacturing the same, the sintered alloy composition having a multi-phase structure, comprising: a first phase composed of aluminum and copper; and a second phase being dispersed in the first phase and composed of molybdenum, chromium, silicon and cobalt. This alloy composition has excellent abrasion and corrosion resistance, preferably to be used for making machine parts such as valve seats for engines.
    Type: Grant
    Filed: July 9, 1991
    Date of Patent: May 4, 1993
    Assignees: Hitachi Powdered Metals Co., Ltd., Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Yutaka Ikenoue, Keitaro Suzuki, Yoshimasa Aoki, Hideo Urata, Koji Koishikawa, Makoto Tsuji
  • Patent number: 5174952
    Abstract: A process for the powder-metallurgical production of a workpiece by filling a binder-free and solvent-free, dry metal powder or ceramic powder into a mold, precompacting the powder by tapping and presintering it for 1/2 hour to 1 hour at 0.65 to 0.85 times the absolute melting temperature without significant shrinkage, adjacent powder particles being joined merely at their contact points by necking to give a skeletal formed body. The formed body is taken out of the mold and finish-sintered at at least 0.9 times the absolute melting temperature for at least 1 hour without additional support by a mold. Advantageously, the sintered body is additionally hot-isostatically pressed containerless in order to reach at least 98% of the theoretical density.
    Type: Grant
    Filed: September 6, 1990
    Date of Patent: December 29, 1992
    Assignee: Asea Brown Boveri Ltd.
    Inventors: Peter Jongenburger, Christoph Tonnes, Clemens Verpoort
  • Patent number: 5156805
    Abstract: A ferritic alloy with a wear resistive oxide scale is obtained through the steps of pressing a ferritic alloy powder containing aluminum into a powder compact of a desired configuration, sintering the powder compact in a non-oxidizing atmosphere to provide a resulting sintered product, and heat-treating the sintered product in an oxidizing gas atmosphere in order to precipitate in the surface thereof alumina in the form of an alumina scale as the wear resistive oxide scale which is responsible for improved surface hardness or wear resistance. Due to the inherent porous nature of the sintered product, the oxidizing gas can readily penetrate deep into the surface of sintered product to facilitate the oxidization of the product surface into the alumina scale, in addition to that the oxidization depth can be controlled such as by the density of the product, which makes it possible to readily control the thickness of the alumina scale.
    Type: Grant
    Filed: July 25, 1991
    Date of Patent: October 20, 1992
    Assignee: Matsushita Electric Works, Ltd.
    Inventors: Junji Imai, Shuji Yamada, Tadashi Hamada, Hajime Kojima, Masao Tanahashi
  • Patent number: 5152829
    Abstract: A rapidly solidified aluminum base alloy consists essentially of the formula Al.sub.bal Fe.sub.a Si.sub.b X.sub.c, wherein X is at least one element selected from the group consisting of W,Ta,Nb, "a" ranges from 3.0 to 7.1 at %, "b" ranges from 1.0 to 3.0 at %, "c" ranges from 0.25 to 1.25 at % and the balance is aluminum plus incidental impurities, with the provisos that the ratio [Fe+X]:Si ranges from about 2.33:1 to 3.33:1 and that the ratio Fe:X ranges from about 16:1 to 5:1. The alloy exhibits high strength, ductility and fracture toughness and is especially suited for use in high temperature structural applications such as gas turbine engines, missiles, airframes and landing wheels.
    Type: Grant
    Filed: June 3, 1991
    Date of Patent: October 6, 1992
    Assignee: Allied-Signal Inc.
    Inventors: David J. Skinner, Michael S. Zedalis
  • Patent number: 5152828
    Abstract: The present invention relates to a method of producing a mold material used for obtaining a mold for casting metals such as Zn, Al and the like or molding resins. In the method, the short fibers having an aspect ratio of 30 to 300 and obtained by cutting ferritic stainless steel long fibers having a width of 100 .mu.m or less, ferritic stainless steel powder and at least one of Cu powder and Cu alloy powder are used as raw materials. The raw materials are blended to obtain a material mixture which is then compressed under pressure in a Cold Isostatic Press process. The thus obtained compressed product is sintered in a vacuum atmosphere. The sintered material is held in an atmosphere of nitrogen gas or decomposed ammonia gas so that 0.3 to 1.2 wt % of nitrogen is added to the stainless steel in the sintered material. The thus obtained mold material has a hardness of HMV 250 to 500.
    Type: Grant
    Filed: October 8, 1991
    Date of Patent: October 6, 1992
    Assignee: Sintokogio Ltd.
    Inventor: Tatsuhiko Katoh
  • Patent number: 5151247
    Abstract: The present invention is a method for densifying powder metallurgical parts to 100% theoretical density. The method comprises applying a high pressure of 0.1-100 MPa during sintering in a high pressure furnace at a temperature before which the liquid phase is formed and maintaining this pressure during the rest of the sintering cycle until the furnace has cooled to almost room temperature. The method achieves rapid, complete closure of the porosity which results in parts with close dimensional tolerances and practically no warpage.
    Type: Grant
    Filed: November 1, 1991
    Date of Patent: September 29, 1992
    Assignee: Sandvik AB
    Inventors: Bengt O. Haglund, Bengt N. During
  • Patent number: 5149496
    Abstract: A magnesium based metal matrix composite is made from rapidly solidified magnesium alloy powder and SiC particulate using liquid suspension coprocessing or mechanical alloying. The composite is suitable for consolidation into bulk shapes having, in combination, high strength, high stiffness, low density, low coefficient of thermal expansion, and high hardness. The composite is suited for uses in such applications as space and missile guidance and navigation and control system precision components where low density, very high specific stiffness and long term dimensional and environmental stability are principal performance criteria.
    Type: Grant
    Filed: January 27, 1992
    Date of Patent: September 22, 1992
    Assignee: Allied-Signal Inc.
    Inventors: Santosh K. Das, Chin-Fong Chang, Derek Raybould
  • Patent number: 5147601
    Abstract: A composition comprising a powder of iron and nickel and a binder (e.g. wax) is injection molded. The powder contains 0.5 to 10% by weight of nickel and has an average particle diameter not exceeding 45 microns. The binder is removed from the molded product. The molded product is sintered, and the sintered product is cooled to room temperature slowly at a rate of 2.degree. C. to 50.degree. C. per minute. The sintered product is of an iron-nickel alloy, has a high density and a high level of soft ferromagnetic properties, and may be complicated in shape.
    Type: Grant
    Filed: March 30, 1992
    Date of Patent: September 15, 1992
    Assignee: Sumitomo Metal Mining Co., Ltd.
    Inventors: Akihito Ohtsuka, Yoshio Kijima
  • Patent number: 5145503
    Abstract: In a process for producing a high strength structural member by sintering a starting powder material, a powder mixture of a basic powder and an additional powder is used as the starting powder material. The basic powder is comprised of at least one of an amorphous single-phase alloy powder and at least one kind of a mixed-phase alloy powder which contains a crystalline phase and an amorphous phase and has a crystalline phase volume fraction C (Vf) less than 30%, and the additional powder is comprised of a mixed-phase alloy powder containing a crystalline phase and an amorphous phase and having a crystalline phase volume fraction C (Vf) of at least 30% to less than 80%. The relationship between the minimum volume fraction Pm (Vf) of the additional powder in the starting powder material and the crystalline phase volume fraction C (Vf) in the additional powder is established such that Pm (Vf)=-0.7 C (Vf)+61. This ensures that a structural member having a high strength and a high toughness can be produced.
    Type: Grant
    Filed: May 31, 1991
    Date of Patent: September 8, 1992
    Assignee: Honda Giken Kogyo Kabushiki Kaisha
    Inventor: Hiroyuki Horimura
  • Patent number: 5122326
    Abstract: The present invention is a method of removing binder material which is non-sublimable at room temperature and pressures greater than 1 Torr from a binder and particulate mixture. The binder and particulate mixture is formed into a shaped article and placed in a closed furnace. The closed furnace is then adjusted to a pressure and temperature sufficient to effect transformation of the binder material from a solid to a vapor and diffusion of the binder material as a vapor through, and from, the binder and particulate mixture without formation of a liquid phase of binder material on the binder and particulate mixture surface. The shaped article is held under these processing conditions until substantially all of the binder material transforms to its vapor state and diffuses through, and from, the mixture into the closed furnace. The binder material vapor is then evacuated from the furnace through conventional means.
    Type: Grant
    Filed: March 2, 1987
    Date of Patent: June 16, 1992
    Assignee: Vacuum Industries Inc.
    Inventors: Martha L. Jackson, Elliot Thompson
  • Patent number: 5098469
    Abstract: A powder metallurgy process for producing near-net shape, near-theoretical density structures of multiphase nickel, aluminum and/or titanium intermetallic alloys is provided by employing pressureless sintering techniques. The process consists of blending a brittle aluminide master alloy powder with ductile nickel powder, so as to achieve the desired composition. Then, after cold compaction of the powdered mixture, the compact is liquid phase sintered. The four step liquid phase sintering process is intended to ensure maximum degassing, eliminate surface nickel oxide, homogenize the alloy, and complete densification of the alloy by liquid phase sintering.
    Type: Grant
    Filed: September 12, 1991
    Date of Patent: March 24, 1992
    Assignee: General Motors Corporation
    Inventor: Vadim Rezhets
  • Patent number: 5098649
    Abstract: A rare earth metal-iron group metal target for a magneto-optical disk is produced by mixing power (a) produced by the rapid quenching treatment of an alloy composed of at least one rare earth metal and at least one iron group metal in a composition range which permits the formation of an eutectic structure, with powder (b) from at least one iron group metal in an amount necessary for meeting the composition requirements of the target; and subjecting the resulting mixture to pressure sintering in vacuum or in an inert gas atmosphere at a temperature lower than a liquid phase-appearing temperature of the mixture to produce a rare earth metal-iron group metal intermetallic bonding layer betwen the particles.
    Type: Grant
    Filed: June 26, 1990
    Date of Patent: March 24, 1992
    Assignee: Hitachi Metals, Ltd.
    Inventors: Shunichiro Matsumoto, Tsutomu Inui, Rokuo Ichiyasu, Yoshitaka Chiba
  • Patent number: 5077002
    Abstract: Process for shaping any desired metallic and/or ceramic component, in which a dry powder is filled loosely into a ceramic mold, which elastically/plastically yields or cracks and breaks under the influence of shrinkage stresses during sintering, and is sintered. Variants for the mold: thin, resilient shells made of Al.sub.2 O.sub.3, SiO.sub.2 or MgO; special glass which cracks in a network-like manner; a mold having predetermined breaking points, ceramic shell disintegrating into fragments; flexible green ceramic sheeting; green ceramic composition with shrinkage during sintering.
    Type: Grant
    Filed: March 12, 1991
    Date of Patent: December 31, 1991
    Assignee: Asea Brown Boveri Ltd.
    Inventor: Reinhard Fried
  • Patent number: RE34180
    Abstract: Cemented carbide substrates having substantially A or B type porosity and a binder enriched layer near its surface are described. A refractory oxide, nitride, boride, and/or carbide coating is deposited on the binder enriched surface of the substrate. Binder enrichment is achieved by incorporating Group IVB or VB transition elements. These elements can be added as the metal, the metal hydride, nitride or carbonitride.
    Type: Grant
    Filed: September 9, 1988
    Date of Patent: February 16, 1993
    Assignee: Kennametal Inc.
    Inventors: Bela J. Nemeth, deceased, George P. Grab