Boron Containing Patents (Class 420/121)
  • Patent number: 4886710
    Abstract: A mining and construction bit body is composed of a Mn-B steel alloy composition. The alloy content of the composition in percents by weight includes: carbon, 0.33-0.38; manganese, 1.10-1.35; boron, 0.0005 minimum; silicon 0.15-0.30; sulfur, 0.045 maximum; and phosphorus, 0.035 maximum. The composition has a minimum hardenability of 47 Rockwell C at the Jominy 6/16 position and a maximum as-rolled hardness of 22 Rockwell C such that without anneal the composition meets hardenability and machinability requirements that make it useful for fabricating mining and construction bit bodies of all sizes.
    Type: Grant
    Filed: April 16, 1987
    Date of Patent: December 12, 1989
    Assignee: Kennametal Inc.
    Inventor: Mark S. Greenfield
  • Patent number: 4878964
    Abstract: A permanent magnetic alloy essentially consists of 10 to 40% by weight of R, 0.1 to 0.8% by weight of boron, 50 to 300 ppm by weight of oxygen and the balance of iron, where R is at least one component selected from the group consisting of yttrium and the rate-earth elements.An alloy having this composition has a high coercive force .sub.I H.sub.C and a high residual magnetic flux density and therefore has a high maximum energy product.
    Type: Grant
    Filed: September 27, 1988
    Date of Patent: November 7, 1989
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Tetsuhiko Mizoguchi, Koichiro Inomata, Toru Higuchi, Isao Sakai
  • Patent number: 4859254
    Abstract: A permanent magnet according to the present invention is characterized in that it is composed of an alloy comprising mainly of iron, and R (rare earth element including yttrium), cobalt, and boron, wherein the alloy is formed principally of ferromagnetic Fe-rich phase of tetragonal system and includes a nonmagnetic Laves phase. Compared with the prior rare earth-Fe based magnet, it has higher Curie temperature and has excellent magnetic characteristics, especially the temperature characteristics.
    Type: Grant
    Filed: September 10, 1986
    Date of Patent: August 22, 1989
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Tetsuhiko Mizoguchi, Isao Sakai, Hiromi Niu, Koichiro Inomata
  • Patent number: 4859255
    Abstract: A magnetically anisotropic sintered permanent magnet of the FeCoBR system (R is sum of R.sub.1 and R.sub.2) wherein:R.sub.1 is Dy, Tb, Gd, Ho, Er, Tm and/or Yb, andR.sub.2 comprises 80 at % or more of Nd and Pr in R.sub.2, and the balance of other rare earth elements exclusive of R.sub.1,said system consisting essentially of, by atomic percent, 0.05 to 5% of R.sub.1, 12.5 to 20% of R, 4 to 20% of B up to 35% of Co, and the balance being Fe. Additional elements M(Ti, Zr, Hf, Cr, Mn, Ni, Ta, Ge, Sn, Sb, Bi, Mo, Nb, Al, V, W) may be present.
    Type: Grant
    Filed: February 29, 1988
    Date of Patent: August 22, 1989
    Assignee: Sumitomo Special Metals Co., Ltd.
    Inventors: Setsuo Fujimura, Masato Sagawa, Yutaka Matsuura, Hitoshi Yamamoto, Norio Togawa
  • Patent number: 4851058
    Abstract: The hard magnetic properties, including intrinsic coercivity, remanence and energy product of rapidly quenched, rare earth-transition metal alloys has been substantially increased by the addition of suitable amounts of the element boron. The preferred rare earth constituent elements are neodymium and praseodymium, and the preferred transition metal element is iron.
    Type: Grant
    Filed: September 3, 1982
    Date of Patent: July 25, 1989
    Assignee: General Motors Corporation
    Inventor: John J. Croat
  • Patent number: 4849035
    Abstract: A permanent magnet alloy having at least one light rare earth element, iron and carbon. The alloy has a cellular microstructure of at least two solid phases with a Fe.sub.14 R.sub.2 C.sub.1 magnetically hard, tetragonal major phase surrounded by at least one minor phase. The light rare earth element may be Pr or Nd. At least one heavy rare earth element, such as Dy, may be used. Boron may be included in the alloy. The alloy is produced by casting and heating to form the Fe.sub.14 R.sub.2 (C,B).sub.1 magnetically hard, tetragonal major phase.
    Type: Grant
    Filed: May 9, 1988
    Date of Patent: July 18, 1989
    Assignee: Crucible Materials Corporation
    Inventors: Hans H. Stadelmaier, Nen-Chin Liu
  • Patent number: 4844754
    Abstract: High energy product, magnetically anisotropic permanent magnets are produced by hot working overquenched or fine grained, melt-spun materials comprising iron, neodymium and/or praseodymium, and boron to produce a fully densified, fine grained body that has undergone plastic flow.
    Type: Grant
    Filed: March 17, 1986
    Date of Patent: July 4, 1989
    Assignee: General Motors Corporation
    Inventor: Robert W. Lee
  • Patent number: 4842657
    Abstract: Amorphous alloys containing zirconium as an amorphus forming metal and having the formula X.sub..alpha. Z.sub..gamma. wherein X is at least one of Fe, Co and Ni, .alpha. is 80 to 92 atomic %, Z is zirconium, .gamma. is 8 to 20 atomic % and the sum of .alpha. and .gamma. is 100 atomic %, cause very little variation of properties during aging and embrittlement because they contain no metalloid as the amorphous forming element, and they further have excellent strength, hardness, corrosion resistance and heat resistance and maintain superior magnetic properties which are characteristic of iron group elements.
    Type: Grant
    Filed: December 5, 1980
    Date of Patent: June 27, 1989
    Assignee: Shin-Gijutsu Kaihatsu Jigyodan
    Inventors: Tsuyoshi Masumoto, Kiyoyuki Esashi, Masateru Nose
  • Patent number: 4840684
    Abstract: Isotropic permanent magnet formed of a sintered body having a mean crystal grain size of 1-160 microns and a major phase of tetragonal system comprising, in atomic percent, 10-25% of R wherein R represents at least one of rare-earth elements including Y, 3-23% of B and the balance being Fe. As additional elements M, Al, Ti, V, Cr, Mn, Zv, Hf, Nb, Ta, Mo, Ge, Sb, Sn, Bi, Ni or W may be incorporated.The magnets can be produced through a powder metallurgical process resulting in high magnetic properties, e.g., up to 7 MGOe or higher energy product.
    Type: Grant
    Filed: December 30, 1983
    Date of Patent: June 20, 1989
    Assignee: Sumitomo Special Metals Co, Ltd.
    Inventors: Setsuo Fujimura, Masato Sagawa, Yutaka Matsuura
  • Patent number: 4837109
    Abstract: A method of producing a neodymium-iron-boron permanent magnet alloy having a composition of 25.0-50.0 weight % of neodymium, 0.3-5.0 weight % of boron and balance substantially iron, including the steps of adding metal calcium, calcium hydride or a mixture thereof as a reducing agent to neodymium fluoride, iron and boron (or ferroboron), and further adding thereto at least one of calcium chloride, sodium chloride and potassium chloride as a flux, melting the resulting mixture in an inert gas atmosphere, or in a reducing gas atmosphere or substantially in vacuum at 1,000.degree.-1,300.degree. C., thereby reducing said neodymium fluoride to provide said alloy with as small a calcium content as 0.1 weight % or less. The starting materials may contain dysprosium fluoride and niobium to provide Nd-Dy-Fe-B-Nb alloys containing 0.5-15.0 weight % Dy and 0.05-5.0 weight % Nb. This method makes it possible to produce Nd-Fe-B or Nd-Dy-Fe-B-Nb permanent magnet alloys with as small a calcium content as 0.
    Type: Grant
    Filed: July 10, 1987
    Date of Patent: June 6, 1989
    Assignee: Hitachi Metals, Ltd.
    Inventors: Masaaki Tokunaga, Kimio Uchida, Akitoshi Hiraki
  • Patent number: 4836868
    Abstract: In an R-Fe-B permanent magnet produced by a process including a rapid cooling, a composition of{R.sub.a (Ce.sub.b La.sub.1-b).sub.1-a }x(Fe.sub.1-z Co.sub.z).sub.100-x-y-w B.sub.y M.sub.w(R is at least one rare earth element except for La and Ce but including Y, 5.5.ltoreq.x<12, 2.ltoreq.y<15, 0.ltoreq.z.ltoreq.0.7, 0<w.ltoreq.10, 0.80.ltoreq.a.ltoreq.1.00, 0.ltoreq.b.ltoreq.1, M is Zr, Nb, Mo, Hf, Ta, W, Ti, and/or V) is proposed. The presence of the M element increases a ((BH)max) to a value higher than that of a composition wherein x is higher than 12 and makes the magnet more easily magnetizable.
    Type: Grant
    Filed: April 14, 1987
    Date of Patent: June 6, 1989
    Assignee: TDK Corporation
    Inventors: Kohichi Yajima, Osamu Kohmoto, Tetsuhito Yoneyama
  • Patent number: 4834815
    Abstract: Metallic alloys are disclosed which are at least about 90% amorphous, having enhanced magnetic properties and consist essentially of a composition represented by the formula Fe.sub.a-b Co.sub.b B.sub.c Si.sub.d C.sub.e, wherein "a", "b", "c", "d" and "e" are atomic percentages ranging from about 75 to about 85, about 0.1 to about 0.8, about 12 to about 15, about 2 to about 5 and about 1 to about 3, respectively. Magnetic cores comprising such alloys, including cores having been subjected to a field anneal, are also disclosed.
    Type: Grant
    Filed: October 15, 1987
    Date of Patent: May 30, 1989
    Assignee: Allied-Signal Inc.
    Inventor: Howard H. Lieberman
  • Patent number: 4834814
    Abstract: Metallic glasses having high permeability, low magnetostriction, low coercivity, low ac core loss, low exciting power and high thermal stability are disclosed. The metallic glasses consist essentially of a composition defined by the formula Fe.sub.a M.sub.b B.sub.c Si.sub.d C.sub.e in which "a"-"e" are in atom percent, the sum ("a"+"b"+"c"+"d"+"e") equals 100, M is at least one element selected from the group consisting of Mo, Cr, Ti, Zr, Hf, Nb, Ta, V and W, "a" ranges from about 66 to 81.5, "b" ranges from about 0.5 to 6, "c" ranges from about 10 to 26, "d" ranges from about 1 to 12, "e" ranges from about 0 to 2 and the sum ("c"+"d"+"e") ranges from about 18 to 28, and have been annealed at a temperature, T.sub.a, for a time, t.sub.a, sufficient to induce precipitation of discrete particles therein. Such metallic glasses are suitable for use in tape recorder heads, relay cores, transformers and the like.
    Type: Grant
    Filed: March 7, 1988
    Date of Patent: May 30, 1989
    Assignee: Allied-Signal Inc.
    Inventors: Ryusuke Hasegawa, Gordon E. Fish
  • Patent number: 4829277
    Abstract: A ring magnet for creating a desired magnetic field within the bore of the ring is formed from a plurality of magnetized, magnetically isotropic magnets comprised of RE.sub.2 TM.sub.14 B.sub.1 alloy. The invention has particular application to ring magnets for magnetic resonance imaging devices.
    Type: Grant
    Filed: November 20, 1986
    Date of Patent: May 9, 1989
    Assignee: General Motors Corporation
    Inventors: Daniel W. Stahura, Robert R. Lown
  • Patent number: 4802931
    Abstract: Magnetically hard compositions having high values of coercivity, remanence and energy product contain rare earth elements, transition metal elements and boron in suitable proportions. The preferred rare earth elements are neodymium and praseodymium, and the preferred transition metal element is iron. The magnetic alloys have characteristic very finely crystalline microstructures.
    Type: Grant
    Filed: October 26, 1983
    Date of Patent: February 7, 1989
    Assignee: General Motors Corporation
    Inventor: John J. Croat
  • Patent number: 4792368
    Abstract: Magnetic materials comprising Fe, B, R (rare earth elements) and Co having a major phase of Fe-Co-B-R intermetallic compound(s) of tetragonal system, and sintered anisotropic permanent magnets consisting essentially of, by atomic percent, 8-30% R (at least one of rare earth elements inclusive of Y), 2-28% B, no less than 50% Co, and the balance being Fe with impurities. Those may contain additional elements M (Ti, Ni, Bi, V, Nb, Ta, Cr, Mo, W, Mn, Al, Sb, Ge, Sn, Zr, Hf) providing Fe-Co-B-R-M type materials and magnets.
    Type: Grant
    Filed: July 25, 1983
    Date of Patent: December 20, 1988
    Assignee: Sumitomo Special Metals Co., Ltd.
    Inventors: Masato Sagawa, Setsuo Fujimura, Yutaka Matsuura
  • Patent number: 4789521
    Abstract: A rare-earth element permanent magnet alloy characterized by good magnetic alignment and high energy product, said magnet consisting essentially of, in atomic percent, at least one rare earth element didymium, mischmetal, neodymium and thorium 12 to 20, boron 4 to 14 and balance iron.
    Type: Grant
    Filed: June 20, 1986
    Date of Patent: December 6, 1988
    Assignee: Crucible Materials Corporation
    Inventors: Kalathur S. V. L. Narasimhan, Bao-Min Ma
  • Patent number: 4784922
    Abstract: The present invention provides corrosion resistance clad steels comprising a steel core and a cladding of a corrosion resistance metallic material tightly covering the circumference of the core, the interface between the core and cladding being metallurgically bonded. As the core materials, steel bars for concrete reinforcement including PC steel bars; or materials for sections (e.g., angles or channels) may be appropriately selected depending on the intended use. The foregoing steel materials is produced by a method comprising the steps of arranging the corrosion resistance metallic cladding member over the entire surface of the circumference of the steel core member and hot rolling to form an intimate metallurgical bonding at the interface between both members, thereby forming the foregoing clad steel material. The material may be formed into deformed steel bars.
    Type: Grant
    Filed: October 3, 1986
    Date of Patent: November 15, 1988
    Assignee: Mitsubishi Steel Mfg. Co., Ltd.
    Inventor: Tsuneo Yoshimura
  • Patent number: 4773950
    Abstract: A magnetically anisotropic sintered permanent magnet of the FeBR system in which R is sum of R.sub.1 and R.sub.2 wherein:R.sub.1 is Dy, Tb, Gd, Ho, Er, Tm and/or Yb, andR.sub.2 comprises 80 at % or more of Nd and Pr in R.sub.2 and the balance of at least one of other rare earth elements exclusive of R.sub.1,said system comprising by atomic percent, 0.05 to 5% of R.sub.1, 12.5 to 20% of R, 4 to 20% of B, and the balance being Fe with impurities. Additional elements M(Ti, Zr, Hf, Cr, Mn, Ni, Ta, Ge, Sn, Sb, Bi, Mo, Nb, Al, V, W,) may be present.
    Type: Grant
    Filed: September 15, 1983
    Date of Patent: September 27, 1988
    Assignee: Sumitomo Special Metals Co., Ltd.
    Inventors: Setsuo Fujimura, Masato Sagawa, Yutaka Matsuura, Hitoshi Yamamoto, Norio Togawa
  • Patent number: 4770702
    Abstract: A rare earth-iron-boron alloy powder which consists essentially of:12.5 to 20 at % R wherein R.sub.1 is 0.05 to 5 at %, 4 to 20 at % B, and 60 to 83.5 at % Fe,wherein R.sub.1 is at least one heavy rare earth element selected from the group consisting of Gd, Tb, Dy, Ho, Er, Tm and Yb, 80 to 100 at % of R.sub.2 consists of Nd and/or Pr, the balance in the R.sub.2 being at least one element selected from the group consisting of rare earth elements including Y and except for R.sub.1, and R=R.sub.1 =R.sub.2 by atomic %, wherein a major phase of at least 80 vol % of the entire alloy coinsists of a tetragonal structure, and wherein oxygen does not exceed 10,000 ppm, carbon does not exceed 1000 ppm and calcium does not exceed 2000 ppm. The alloy powder is produced by directly reducing a mixture comprising rare earth oxide, iron and other ingredients or oxide thereof with a reducing agent Ca and CaCl.sub.2, putting the reduced product into water, then treating with water. Up to 35 at % Co may be substituted for Fe.
    Type: Grant
    Filed: January 20, 1988
    Date of Patent: September 13, 1988
    Assignee: Sumitomo Special Metals Co., Ltd.
    Inventors: Naoyuki Ishigaki, Takaki Hamada, Setsuo Fujimura
  • Patent number: 4770723
    Abstract: Magnetic materials comprising Fe, B and R (rare earth elements) having a major phase of Fe--B--R intermetallic compound(s) of tetragonal system, and sintered anisotropic permanent magnets consisting essentially of, by atomic percent, 8-30% R (at least one of rare earth elements inclusive of Y), 2-28% B and the balance being Fe with impurities. Those may contain additional elements M (Ti, Ni, Bi, V, Nb, Ta, Cr, Mo, W, Mn, Al, Sb, Ge, Sn, Zr, Hf) providing Fe--B--R--M type materials and magnets.
    Type: Grant
    Filed: February 10, 1987
    Date of Patent: September 13, 1988
    Assignee: Sumitomo Special Metals Co., Ltd.
    Inventors: Masato Sagawa, Setsuo Fujimura, Yutaka Matsuura
  • Patent number: 4769063
    Abstract: A rare earth alloy for producing permanent magnet comprised of: 15-65 atomic % R.sub.1, 35-83 atomic % Fe, and 0-15 atomic % B, where R.sub.1 represents at least one of heavy rare earth elements Gd, Tb, Dy, Ho, Er, Tm and Yb. This alloy is produced by reducing a mixture of correspoding rare earth oxides, Fe, and a boron containing material by Ca, contacting the reduced mass with water, and treating the resultant slurry with water. Using this alloy, Fe-B-R base magnets wherein R.sub.1 is substituted for part of R (R representing lanthanide and/or Y) having a high performance are produced with a reduced cost.
    Type: Grant
    Filed: February 26, 1986
    Date of Patent: September 6, 1988
    Assignee: Sumitomo Special Metals Co., Ltd.
    Inventors: Naoyuki Ishigaki, Takaki Hamada, Setsuo Fujimura
  • Patent number: 4767450
    Abstract: A rare earth-iron-boron alloy powder which consists essentially of:12.5 to 20 at % R wherein R.sub.1 is 0.05 to 5 at %, 4 to 20 at % B, and 60 to 83.5 at % Fe,wherein R.sub.1 is at least one heavy rare earth element selected from the group consisting of Gd, Tb, Dy, Ho, Er, Tm, and Yb, 80 to 100 at % of R.sub.2 consists of Nd and/or Pr, the balance in the R.sub.2 being at least one element selected from the group consisting of rare earth elements including Y and except for R.sub.1, and R=R.sub.1 +R.sub.2 by atomic %, wherein a major phase of at least 80 vol % of the entire alloy coinsists of a tetragonal structure, and wherein oxygen does not exceed 10,000 ppm, carbon does not exceed 1000 ppm and calcium does not exceed 2000 ppm. The alloy powder is produced by directly reducing a mixture comprising rare earth oxide, iron and other ingredients or oxide thereof with a reducing agent Ca and CaCl.sub.2, putting the reduced product into water, then treating with water. Up to 35 at % Co may be substituted for Fe.
    Type: Grant
    Filed: November 25, 1985
    Date of Patent: August 30, 1988
    Assignee: Sumitomo Special Metals Co., Ltd.
    Inventors: Naoyuki Ishigaki, Takaki Hamada, Setsuo Fujimura
  • Patent number: 4767474
    Abstract: Isotropic permanet magnet formed of a sintered body having a mean crystal grain size of 1-130 microns and a major phase of tetragonal system comprising, in atomic percent, 10-25% of R wherein R represents at least one of rare-earth elements including Y, 3-23% of B, no more than 50% of Co and the balance being Fe. As additional elements M, Al, Ti, V, Cr, Mn, Zr, Hf, Nb, Ta, Mo, Ge, Sb, Sn, Bi, Ni or W may be incorporated.The magnets can be produced through a powder meallurgical process resulting in high magnetic properties, e.g., up to 7 MGOe or higher energy product.
    Type: Grant
    Filed: December 30, 1983
    Date of Patent: August 30, 1988
    Assignee: Sumitomo Special Metals Co., Ltd.
    Inventors: Setsuo Fujimura, Masato Sagawa, Yutaka Matsuura
  • Patent number: 4765848
    Abstract: In the rare earth-iron-boron permanent magnet, Ce and La decrease the magnetic properties when used alone but synergistically enhance iHc when used in combination.The composition provided by the present invention is generally expressed by [(Ce.sub.x La.sub.1-x).sub.y R.sub.1-y ].sub.z [(Fe.sub.1-u-w Co.sub.w M.sub.u).sub.1-v B.sub.v ].sub.1-z with a proviso of 0.4.ltoreq.x.ltoreq.0.9, 0.2<y.ltoreq.1.0, 0.05.ltoreq.z.ltoreq.0.3, 0.01.ltoreq.v.ltoreq.0.3, 0.ltoreq.u.ltoreq.0.2, 0.ltoreq.w.ltoreq.0.5, and M is at least one element selected from the group consisting of Al, Ti, V, Cr, Mn, Zr, Hf, Nb, Ta, Mo, Ge, Sb, Sn, Bi, Ni, W, Cu, and Ag.
    Type: Grant
    Filed: December 27, 1985
    Date of Patent: August 23, 1988
    Assignee: Kaneo Mohri
    Inventors: Kaneo Mohri, Jiro Yamasaki
  • Patent number: 4756775
    Abstract: Magnetically hard compositions having high values of coercivity, remanence and energy product contain rare earth elements, transition metal elements and boron in suitable proportions. The preferred rare earth elements are neodymium and praseodymium, and the preferred transition metal element is iron. The magnetic alloys have characteristic very finely crystalline microstructures.
    Type: Grant
    Filed: October 26, 1983
    Date of Patent: July 12, 1988
    Assignee: General Motors Corporation
    Inventor: John J. Croat
  • Patent number: 4743513
    Abstract: Wear-resistant materials and articles, wherein an amorphous material having a hardness of greater than about 1600 VHN is utilized to protect wear-susceptible portions of substrates or is itself made into a wear-resistant article. Amorphous materials having hardnesses greater than about 1600 VHN are found to have surprisingly great wear resistance and can be used to prepare wear-resistant articles. Particularly satisfactory results have been obtained with metal-metalloid systems such as W--Ru--B, Re--Mo--B, Mo--Ru--B, and Co--Nb--B materials.
    Type: Grant
    Filed: June 10, 1983
    Date of Patent: May 10, 1988
    Assignee: Dresser Industries, Inc.
    Inventor: David M. Scruggs
  • Patent number: 4721538
    Abstract: A rare-earth element permanent magnet alloy characterized by good magnetic alignment and high energy product, said magnet consisting essentially of, in atomic percent, at least one rare earth element didymium, mischmetal, neodymium and thorium 12 to 20, boron 4 to 14 and balance iron.
    Type: Grant
    Filed: June 20, 1986
    Date of Patent: January 26, 1988
    Assignee: Crucible Materials Corporation
    Inventors: Kalathur S. V. L. Narasimhan, Bao-Min Ma
  • Patent number: 4678522
    Abstract: A cold rolled boron steel sheet having excellent stretchability, deep drawability, and second workability and method for producing the same, which comprises the steps of hot rolling a steel containing not more than 0.05% C by weight and, P and N in the relation of P+5N.ltoreq.0.0175% by weight at a temperature of 850.degree. C. or more, cold rolling the hot rolled steel strip at a reduction of not less than 50%, and subjecting the cold rolled steel strip to continuous annealing at a temperature between the recrystallization temperature and the A.sub.3 point.
    Type: Grant
    Filed: August 7, 1986
    Date of Patent: July 7, 1987
    Assignee: Nippon Steel Corporation
    Inventors: Tsuyoshi Kawano, Shiroh Sanagi, Koe Nakajima
  • Patent number: 4668310
    Abstract: Amorphous alloys having high strength, high hardness, high crystallization temperature, high saturation magnetic induction, low coercive force, high magnetic permeability and particularly low deterioration of magnetic properties with lapse of time, have a composition formula ofT.sub.a X.sub.b Z.sub.c or T.sub.a' X.sub.b' Z.sub.c' M.sub.d,whereinT is at least one of Fe, Co and Ni,X is at least one of Zr, Ti, Hf and Y,Z is at least one of B, C, Si, Al, Ge, Bi, S and P,a is 70-98 atomic %,b is not more than 30 atomic %,c is not more than 15 atomic %,sum of a, b and c is 100 atomic %,M is at least one Mo, Cr, W, V, Nb, Ta, Cu, Mn, Zn, Sb, Sn, Be, Mg, Pd, Pt, Ru, Os, Rh, Ir, Ce, La, Pr, Nd, Sm, Eu, Gd, Tb and Dy,a' is 70-98 atomic %,b' is not more than 30 atomic %,c' is not more than 15 atomic %,d is not more than 20 atomic %, andsum of a', b', c' and d is 100 atomic %.
    Type: Grant
    Filed: March 14, 1983
    Date of Patent: May 26, 1987
    Assignees: Hitachi Metals, Ltd., Hitachi, Ltd.
    Inventors: Mitsuhiro Kudo, Shinji Takayama, Yoshizo Sawada, Yasunobu Ogata
  • Patent number: 4664724
    Abstract: A permanent magnetic alloy essentially consists of 10 to 40% by weight of R, 0.1 to 8% by weight of boron, 50 to 300 ppm by weight of oxygen and the balance of iron, where R is at least one component selected from the group consisting of yttrium and the rare-earth elements.An alloy having this composition has a high coercive force .sub.I H.sub.C and a high residual magnetic flux density and therefore has a high maximum energy product.
    Type: Grant
    Filed: September 9, 1985
    Date of Patent: May 12, 1987
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Tetsuhiko Mizoguchi, Koichiro Inomata, Toru Higuchi, Isao Sakai
  • Patent number: 4661174
    Abstract: In the production of non-oriented electrical steel sheets, it has been attempted to decrease the watt loss, e.g., by adding Sn to silicon steels, but in such a case the relationship between the watt loss and the magnetic flux density falls within the curves 1 and 1' in FIG. 1. The addition of boron is therefore unsatisfactory for meeting the recent demand for improving the magnetic properties of a non-oriented electrical steel sheet over those indicated by the curve 3.In the present invention, the combined addition of Sn and B and/or sol. Al results in the development of (110) and (100) textures, which are desirable for the magnetic properties.A non-oriented electrical steel sheet according to the present invention consists of:at most 0.015% carbon,0.3% to 2.0% silicon,0.02% to 0.20% tin,and optionally1.0% to 1.5% manganese,and(a) 0.005% to 0.10% acid-soluble aluminium,at most 0.007% nitrogen,at most 0.005% boron,the weight ratio of the boron content/nitrogen content being from 0.5 to 1.
    Type: Grant
    Filed: May 25, 1984
    Date of Patent: April 28, 1987
    Assignee: Nippon Steel Corporation
    Inventors: Kunisuke Miyoshi, Yoshiaki Shimoyama, Takeshi Kubota
  • Patent number: 4659378
    Abstract: Electrical contacts to or mechanical connections between components and provided by using a thin layer of an alloy consisting of metals and metalloids. Such a layer shows excellent adhesion to glass or semiconductor substrates.
    Type: Grant
    Filed: June 22, 1984
    Date of Patent: April 21, 1987
    Assignee: International Standard Electric Corporation
    Inventors: Hans Volz, Peter Kersten
  • Patent number: 4623408
    Abstract: Nitrogen-containing amorphous alloys having a combination of superior properties which are highly valuable and desirable for ferromagnetic materials or superconducting materials are produced by sputtering metallic materials and nitrogen compounds containing semi-metal or semiconducting metal, such as boron or silicon, without requiring the use of nitrogen gas. The produced alloy has a novel structure, represented by the formula:MxLyNz(wherein M is at least one metal or alloy; L is at least one semimetal or semiconducting element; and x, y and z are fractional atomic percentages totaling 100 (i.e., x+y+z=100) and the value of y+z being 10 or more and the respective values of x, y, z being not zero).
    Type: Grant
    Filed: January 16, 1985
    Date of Patent: November 18, 1986
    Assignees: Hideaki Karamon, Research Development Corporation of Japan
    Inventors: Hideaki Karamon, Keiichi Ogawa
  • Patent number: 4623387
    Abstract: Amorphous alloys containing zirconium as an amorphous forming metal and having teh formula X.sub..alpha. Z.sub..gamma. wherein X is at least one of Fe, Co and Ni, .alpha. is 80 to 92 atomic %, Z is zirconium, .gamma. is 8 to 20 atomic % and the sum of .alpha. and .gamma. is 100 atomic %, cause little variation of properties during aging and embrittlement because they contain no metalloid as the amorphous forming element, and they further have excellent strength, hardness, corrosion resistance and heat resistance and maintain superior magnetic properties which are characteristic of iron group elements.
    Type: Grant
    Filed: February 5, 1985
    Date of Patent: November 18, 1986
    Assignee: Shin-Gijutsu Kaihatsu Jigyodan
    Inventors: Tsuyoshi Masumoto, Kiyoyuki Esashi, Masateru Nose
  • Patent number: 4617052
    Abstract: A process for preparing a mother alloy for making a Fe-B-Si base amorphous metal is described, comprising the steps of:providing a molten metal containing an iron source and ferrosilicon;adding to the molten metal a mineral ore containing a boron oxide;reducing a predetermined amount of the boron oxide in the molten metal by the reducing action of carbon or silicon that is initially present in the metal or externally added together with the mineral ore, thereby dissolving said boron oxide as elemental boron in the molten metal;removing the carbon or aluminum by supplying an oxidant; andadjusting the contents of boron and silicon in the molten metal to be within a desired composition range.
    Type: Grant
    Filed: August 30, 1985
    Date of Patent: October 14, 1986
    Assignee: The Japan Steel Works Ltd.
    Inventors: Tomoo Takenouchi, Yoshiaki Ichinomiya, Yoshiyuki Iwanami