Titanium Containing Patents (Class 420/126)
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Publication number: 20040035508Abstract: Disclosed are a high strength hot rolled steel plate, preventing a deterioration in bore expandability and ductility involved in an increase in strength to not less than 690 N/mm2 and, despite high strength, providing a high level of bore expandability and a high level of ductility, and a producing process thereof. The steel plate according to the first aspect is a steel plate, comprising a steel comprising, by mass, C: 0.01-0.15%; Si: 0.30-2.00%; Mn: 0.50-3.00%; P ≦0.03%; S ≦0.005%; Ti: 0.01-0.50% and/or Ni: 0.01-0.05%; and the balance consisting of Fe and unavoidable impurities, not less than 80% of all grains being accounted for by grains having a ratio (ds/dl) of minor axis (ds) to major axis (dl) of not less than 0.1, the steel plate having a steel structure comprising not less than 80% of ferrite and the balance consisting of bainite, the steel plate having a strength of not less than 690 N/mm2.Type: ApplicationFiled: June 3, 2003Publication date: February 26, 2004Inventors: Hiroyuki Okada, Toshimitsu Aso, Riki Okamoto
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Patent number: 6669790Abstract: An iron-based casting alloy and a process for making the alloy are provided by combining an iron-carbon-chromium system with primary carbides of vanadium, niobium, titanium, or combinations thereof without any eutectic carbides of vanadium, niobium and titanium. Eutectic chromium carbides (M7C3) are also formed without any primary chromium carbides. Proeutectic austenite can also be formed in the alloy.Type: GrantFiled: May 16, 1997Date of Patent: December 30, 2003Assignee: Climax Research Services, Inc.Inventors: Richard B. Gundlach, Sumita Majumdar
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Patent number: 6669789Abstract: A composition and method of making a high-strength low-alloy hot-rolled steel sheet, strip, or plate bearing titanium as the principal or only microalloy strengthening element. The steel is substantially ferritic and has a microstructure that is at least 20% acicular ferrite. The steel has a minimum yield strength of at least 345 MPa (50 ksi) and even over 621 MPa (90 ksi) adding titanium as the lone microalloy element for strengthening, with elongation of 15% and more. Addition of vanadium, niobium, or a combination thereof can result in yield strengths exceeding 621 MPa (90 ksi). Effective titanium content, being the content of titanium in the steel not in the form of nitrides, oxides, or sulfides, is in the range of 0.01 to 0.12% by weight. The manufacturing process includes continuously casting a thin slab and reducing the slab thickness using thermomechanical controlled processing, including dynamic recrystallization controlled rolling.Type: GrantFiled: August 31, 2001Date of Patent: December 30, 2003Assignee: Nucor CorporationInventors: Daniel Geoffrey Edelman, Steven Leonard Wigman
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Publication number: 20030190251Abstract: A process for enhancing precipitation strengthening in steel and for making a high-strength micro-alloy steel, and a steel made from the process. The process includes the step of deforming the steel containing a suitable precipitate strengthening substance, at a temperature at which the microstructure of the steel is essentially stable and at which those precipitation strengthening particles that form are of a desirable particle size for precipitation strengthening. Deforming the steel introduces dislocations in the crystal structure of the steel, which increases the kinetics of precipitation by increasing the number of precipitation nucleation sites and accelerating the rate of diffusion of the precipitate material. The steel may be deformed by bending or rolling the steel. Preferably the process also includes the step of cooling the steel at a rapid rate so as to minimize the formation of precipitate particles of a larger-than-desired size.Type: ApplicationFiled: April 3, 2002Publication date: October 9, 2003Applicant: IPSCO Enterprises Inc.Inventors: Dengqi Bai, Michael Ambrose Cooke, James Asante, Jonathan Dorricott
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Publication number: 20030178105Abstract: Disclosed is a steel for machine structural use having good machinability and chip-breakability as well as a method of producing the steel. The steel consists essentially of, by wt. %, C: 0.05-0.8%, Si: 0.01-2.0%, Mn: 0.1-3.5%, S: 0.01-0.2%, Al: 0.001-0.020%, Ca: 0.0005-0.02%, O: 0.0005-0.01% and N: 0.001-0.04%, and further, one or both of Ti: 0.002-0.010% and Zr: 0.002-0.025%, the balance being Fe and inevitable impurities. At production of the steel controlled deoxidization is conducted by operation meeting certain conditions so that at least a certain amount of “duplex inclusion” having a specific chemical composition may be formed, and Ti and/or Zr is added to precipitate finely dispersed MnS inclusion particles with nuclei of Ti-oxide and/or Zr-oxide. The finely dispersed MnS inclusions must share a determined part of the total sulfide inclusions.Type: ApplicationFiled: November 27, 2002Publication date: September 25, 2003Inventors: Masakazu Hayashi, Takashi Kano, Kazuhisa Ishida, Yutaka Kurebayashi, Makoto Hobo
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Patent number: 6623691Abstract: The present invention describes an ultra-low carbon bake hardenable galvanized or galvannealed steel product, having a higher yield strength at the temperature of the molten zinc bath while maintaining a low yield strength and excellent bake hardening properties in a skinpassed condition, BH0 being higher than 35 MPa and BH2 higher than 40 MPa (GI) and BH0>20 MPa and BH2>30 MPa (GA), as well as having a superior paint appearance after stamping and painting. The content in the steel composition of the Ti is comprised between 3.42 N and 3.42 N+60 ppm for a fixed nitrogen content (N), and the Nb-content, comprised between 50 ppm and 100 ppm, is fixed so that no substantial precipitation of niobium carbides will occur during the process.Type: GrantFiled: December 22, 2000Date of Patent: September 23, 2003Assignee: Sidmar N.V.Inventors: Sven Vandeputte, Serge Claessens
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Patent number: 6615476Abstract: A method is required in which a plate-like flange member may be firmly secured at the front end of a hollow shaft member through a plastic working treatment by virtue of caulking combination, so as to manufacture a hollow shaft having a flange at one end thereof.Type: GrantFiled: June 26, 2000Date of Patent: September 9, 2003Assignees: Fuji Jukogyo Kabushiki Kaisha, Kubota Iron Works Co., LTDInventors: Shigeaki Yamanaka, Masami Oguri
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Patent number: 6599469Abstract: Disclosed is a non-heat treated steel for soft niriding, which can provide forged parts exhibiting equal to or larger than the limit strain at which cracks occur in straightening by bending and equal to or larger than the fatigue strength when compared with the parts of conventional heat treated steel, such as S48C. The non-heat treated steel for soft nitriding consists essentially of, by weight, C: 0.2-0.6%, Si: 0.05-1.0%, Mn: 0.25-1.0%, S: 0.03-0.2%, Cr: up to 0.2%, sol-Al: up to 0.045%, Ti: 0.002-0.01%, N: 0.005-0.025%, and O: 0.001-0.005%; provided that the conditions, 0.12[Ti%]<[O%]<2.5[Ti%] and 0.04[N%]<[O%]<0.75[N%], are met; the balance being Fe and inevitable impurities; and the structure after hot forging being a mixed structure of ferrite and pearlite.Type: GrantFiled: January 29, 2002Date of Patent: July 29, 2003Assignee: Daido Steel Co., Ltd.Inventors: Kazuhisa Ishida, Koichiro Inoue
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Publication number: 20030138343Abstract: The invention provides a steel for machine structural use, which is excellent in machinability, comprising, in percent by mass, C: 0.1-0.6%, Si: 0.01-2.0%, Mn: 0.2-2.0%, S: 0.005-0.2%, Al: not more than 0.009%, Ti: not less than 0.001% but less than 0.04%, Ca: 0.0001-0.01%, O (oxygen): 0.001-0.01%, and N: not more than 0.Type: ApplicationFiled: November 15, 2002Publication date: July 24, 2003Inventors: Naoki Matsui, Koji Watari, Takayuki Nishi, Toru Kato, Hitoshi Matsumoto, Hiroaki Tahira
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Patent number: 6562207Abstract: Sputter target, method of manufacture of same and sputter coating process using the target as a sputtering source are disclosed. The sputter target comprises an Me/Si multi-phase, consolidated blend wherein the Si component is present in a very small amount of about trace—0.99 mole Si:1 mole Me. Preferably, Me comprises one or more of Ta, Ti, Mo, or W. The targets are made from the requisite powders via HIP consolidation to provide densities of greater than 98 % of the theoretical density. The targets are especially useful in reactive cathodic sputtering systems employing N2 as the reactive gas to form amorphous Me/Si/N layers.Type: GrantFiled: January 14, 2000Date of Patent: May 13, 2003Assignee: Tosoh SMD, Inc.Inventor: Eugene Y. Ivanov
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Publication number: 20030072672Abstract: Disclosed is a free-cutting steel containing Ti- and/or Zr-carbosulfide as inclusion and having good machinability both in turning and drilling. The free-cutting steel consists essentially of, in mass %, C: 0.05-0.80%, Si: 0.01-2.5%, Mn: 0.1-3.5%, Ti+0.52Zr: 0.03-1.2%, S:0.015-0.6% and the balance of Fe and inevitable impurities, and is characterized in that the contents of Ti, Zr and S meet the condition of (Ti+0.52Zr)/S<2. The free-cutting steel may contain, in addition to the above basic alloy composition, Ca: 0.0005-0.02% and/or Mg: 0.0003-0.02%. The latter steel exhibits much more improved machinability.Type: ApplicationFiled: May 31, 2002Publication date: April 17, 2003Inventors: Masakazu Hayaishi, Yutaka Kurebayashi
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Publication number: 20030072673Abstract: Disclosed is a free-cutting steel which exhibits good machinability in turning and small roughness of the turned surfaces, and in which substantially no macro-streak-flaw occurs. The free-cutting steel contains, by weight %, C: 0.03-0.20%, Mn: 0.5-3.0%, P: 0.02-0.40%, S: more than 0.2% up to 1.0%, one or both of Ti and Zr (in case of both, the total amount): 0.01-3.0%, O: 0.0005-0.0050% and Pb: less than 0.01%, the balance being Fe and inevitable impurities. The steel is characterized in that it contains, as the inclusion therein, Ti-based and/or Zr-based carbosulfide compound or compounds. The steel may further contain at least one from the group of Bi: up to 0.4%, Se: up to 0.5% and Te: up to 0.1%.Type: ApplicationFiled: May 31, 2002Publication date: April 17, 2003Inventors: Masakazu Hayaishi, Yutaka Kurebayashi
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Publication number: 20030063996Abstract: The present invention relates to a high strength hot rolled steel sheet containing 0.15% or less C, 0.02 to 0.35% Ti, and 0.05 to 0.7% Mo by weight percentage and consisting essentially of a matrix of ferrite structure single phase and fine precipitates with a grain size of smaller than 10 nm dispersed in the matrix, for example, a high strength hot rolled steel sheet which consists essentially of 0.06% or less C, 0.5% or less Si, 0.5 to 2.0% Mn, 0.06% or less P, 0.005% or less S, 0.1% or less Al, 0.006% or less N, 0.02 to 0.10% Ti, 0.05 to 0.6% Mo by weight percentage, and the balance being Fe, wherein fine precipitates with a grain size of smaller than 10 nm are dispersed in a matrix of ferrite structure single phase at a number per unit volume of 5×104/&mgr;m3 or higher. This steel sheet, which has tensile strength of not lower than 550 MPa, high elongation and excellent stretch flangeability, is suitable for intricately shaped automotive chassis parts such as a suspension arm.Type: ApplicationFiled: March 28, 2002Publication date: April 3, 2003Applicant: NKK CORPORATIONInventors: Yoshimasa Funakawa, Tsuyoshi Shiozaki, Kunikazu Tomita, Takanobu Saito, Hiroshi Nakata, Kaoru Sato, Minoru Suwa, Tetsuo Yawamoto, Yasuhiro Murao, Eiji Maeda
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Patent number: 6540846Abstract: Disclosed herein is a high-strength hot-rolled steel sheet superior in stretch-flanging properties and fatigue properties which comprises (in mass %) 0.01-0.10% C, less than 2% Si (including 0%), 0.5-2% Mn, less than 0.08% P (including 0%), less than 0.01% S (including 0%), less than 0.01% N (including 0%), 0.01-0.1% Al, and at least one of 0.1-0.5% Ti and less than 0.8% Nb (including 0%), with the granular bainitic structure accounting for more than 80% (by area) in its sectional metallographic structure. Disclosed also herein is a process for producing said steel sheet.Type: GrantFiled: February 27, 2001Date of Patent: April 1, 2003Assignee: Kabushiki Kaisha Kobe Seiko ShoInventors: Takahiro Kashima, Shunichi Hashimoto
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Patent number: 6524726Abstract: Disclosed is a cold-rolled steel sheet excellent in formability, panel shapeability and dent-resistance, comprising 0.005 to 0.015% by weight of C, 0.01 to 0.2% by weight of Si, 0.2 to 1.5% by weight of Mn, 0.01 to 0.07% by weight of P, 0.006 to 0.015% by weight of S, 0.01 to 0.08% by weight of sol. Al, not higher than 0.004% by weight of N (N≦0.004%), not higher than 0.003% by weight of O (O≦0.003%), 0.04 to 0.23% by weight of Nb, 1.0≦(Nb %×12)/(C %×93)≦3.0, and a balance of Fe and unavoidable impurities, said cold-rolled steel sheet meeting the relationship given below: exp(&egr;)×(5.29×exp(&egr;)−4.19)≦&sgr;/&sgr;0.2≦exp(&egr;)×(5.64×exp(&egr;)−4.49) where 0.002<&egr;≧0.096, &egr; represents a true strain, &sgr;0.2 represents a 0.2% proof stress, and &sgr; represents a true stress relative to &egr;.Type: GrantFiled: December 23, 1999Date of Patent: February 25, 2003Assignee: NKK CorporationInventors: Fusato Kitano, Masaya Morita, Yoshihiro Hosoya, Takeshi Fujita, Tadashi Inoue, Masahiro Iwabuchi, Takeo Ishii
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Publication number: 20030034100Abstract: Steel strapping and a method of manufacturing steel strapping are disclosed. The steel strapping has the following composition in wt % and a microstructure including a matrix of recovery-annealed cold worked ferrite containing martensite and carbides dispersed through the matrix. 1 C: up to 0.2 Mn: up to 2.0 Si: 0.2-0.4 Ti: 0.025-0.045 V: 0.05-0.07 Cr: up to 0.25 Ni: up to 0.30 Mo: up to 0.10 N: up to 0.005 Cu: up to 0.20 Al: up to 0.08 Nb: up to 0.005 P: up to 0.035 S: up to 0.020 Balance iron and incidental impurities.Type: ApplicationFiled: August 2, 2001Publication date: February 20, 2003Inventors: Jeffery W. Doonan, Peter Ivan Unicomb, Robert K. Armstrong
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Patent number: 6511553Abstract: The present invention provides a steel for steel sheets excellent in workability and showing significantly decreased formation of surface defects, and a method of deoxidizing molten steel for the steel for steel sheets which prevents nozzle clogging during continuous-casting the molten steel. That is, the steel for steel sheets excellent in workability, comprises, based on weight, 0.0001 to 0.0030% of C, up to 0.03% of Si, 0.05 to 0.30% of Mn, up to 0.015% of P, 0.001 to 0.015% of S, up to 0.008% of Al, 0.02 to 0.08% of Ti, 0.0005 to 0.0020% of Ca, 0.0005 to 0.01% of N, optionally containing at least one of 0.001 to 0.02 wt % of Nb and 0.0001 to 0.0010 wt % of B, and the balance of Fe and unavoidable impurities.Type: GrantFiled: October 15, 1999Date of Patent: January 28, 2003Assignee: Nippon Steel CorporationInventors: Junji Nakashima, Takashi Sawai, Mitsuo Uchimura, Wataru Yamada, Shigenori Tanaka, Yasuharu Sakuma, Akinobu Murasato
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Patent number: 6391124Abstract: A non-heat treated soft-nitrided steel part respective contents of C, Si, Mn, P, Cr, Ti, V, N, Al, Pb, S and Ca of which are in specific ranges and which satisfies the following formulas (1) to (3). This part can be produced in a process of hot working, machining and soft-nitriding without any prior heat treatment, and has superior properties such as high fatigue strength and wear resistance. Fn1=−141.5(C %)−19.6(Mn %)+1280(N %)+95.6≦60 (1) Fn2=−103.8(C %)+59.1(Mn %)+850.4(N %)+360.9≧350 (2) Fn3=−13.4(C %)−3.45(Mn %)+112.7(N %)+13.Type: GrantFiled: October 30, 2000Date of Patent: May 21, 2002Assignees: Sumitomo Metals (Kokura) Ltd., Honda Giken Kogyo Kabushiki KaishaInventors: Hitoshi Matsumoto, Yoshihiko Kamada, Mitsuo Uno, Masato Kurita, Seiichi Koike, Mitsuo Takashima
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Patent number: 6383308Abstract: To provide a torsion bar for the use of a seat belt retractor which can be manufactured without a spheroidizing annealing process. A torsion bar to be used as a load limiter in a seat belt retractor is characterized in that the torsion bar is made of steel of which the carbon content is 0.04% or less.Type: GrantFiled: July 3, 2000Date of Patent: May 7, 2002Assignee: Takata CorporationInventors: Muneo Nishizawa, Yasushi Kanamori, Joji Mishina
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Publication number: 20020036035Abstract: A high-strength hot-rolled steel sheet superior in stretch flange formability which comprises C (0.01-0.10 mass %), Si (no more than 1.0 mass %), Mn (no more than 2.5 mass %), P (no more than 0.08 mass %), S (no more than 0.005 mass %), Al (0.015-0.050 mass %), and Ti (0.10-0.30 mass %), with the remainder being substantially Fe, said hot-rolled steel sheet having a structure composed mainly of ferrite in which the unit grain is surrounded by grains such that adjacent grains differ in orientation more than 15°, said unit grain having an average particle diameter (d) no larger than 5 &mgr;m. This steel sheet is produced by the steps of heating, rolling, cooling, and coiling under the following conditions. Heating temperature: 1150-1300° C.; reduction in rolling at 900-840° C.: no less than 70%; cooling rate: no less than 60° C./s; and coiling temperature: 300-500° C. or 600-750° C.Type: ApplicationFiled: July 23, 2001Publication date: March 28, 2002Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)Inventors: Takahiro Kashima, Shunichi Hashimoto
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Patent number: 6361624Abstract: A method of producing a fully stabilized extra low carbon porcelain enameling steel having excellent formability and fish scaling resistance as well as superior enamel adherence. The method includes hot rolling a slab to strip, the slab having a composition consisting essentially of in weight percent: 0.005 max. C, 0.35 max. Mn, 0.015 max. P, 0.015 max. S, 0.015 max. Si, 0.025 to 0.055 Al, 0.006 to 0.015 N, 0.03 to 0.06 Ti, 0.02 to 0.05 Cb, up to 0.03 Sb, the balance Fe and inevitable impurities. The hot rolled strip is cold rolled at least 65% and box annealed until a cold spot temperature within the range of 610 to 705 degrees C. is reached. The invention includes the product made according to the process.Type: GrantFiled: September 11, 2000Date of Patent: March 26, 2002Assignee: USX CorporationInventor: George Franklin Altemus
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Patent number: 6344093Abstract: A high tensile strength steel product for high heat input welding having excellent toughness in the heat-affected zone and having a tensile strength of at least 490 MPa contains, in terms of percent by weight, from about 0.05% to about 0.18% of C, 0.6% or less of Si, from about 0.80% to about 1.80% of Mn, 0.005% or less of Al, 0.030% or less of P, 0.004% or less of S, 0.005% or less of Nb, from about 0.04% to about 0.15% of V, from about 0.0050% to about 0.00150% of N, and from about 0.010% to about 0.050% of Ti, the ratio of the Ti content to the Al content, Ti/Al, satisfying 5.0 or more, and further contains at least one of from about 0.0010% to about 0.0100% of Ca and from about 0.0010% to about 0.0100% of REM, and the balance being Fe and incidental impurities.Type: GrantFiled: May 9, 2000Date of Patent: February 5, 2002Assignee: Kawasaki Steel CorporationInventors: Akio Ohmori, Fumimaru Kawabata, Keniti Amano
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Publication number: 20020005234Abstract: The present invention describes an ultra-low carbon bake hardenable galvanized or galvannealed steel product, having a higher yield strength at the temperature of the molten zinc bath while maintaining a low yield strength and excellent bake hardening properties in a skinpassed condition, BH0 being higher than 35 MPa and BH2 higher than 40 MPa (GI) and BH0>20 MPa and BH2>30 MPa (GA), as well as having a superior paint appearance after stamping and painting. The content in the steel composition of the Ti is comprised between 3,42 N and 3,42 N+60 ppm for a fixed nitrogen content (N), and the Nb-content, comprised between 50 ppm and 100 ppm, is fixed so that no substantial precipitation of niobium carbides will occur during the process.Type: ApplicationFiled: December 22, 2000Publication date: January 17, 2002Inventors: Sven Vandeputte, Serge Claessens
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Patent number: 6290784Abstract: A hot rolled steel sheet comprises ultrafine ferrite grains as a main phase and fine second phase particles. The ferrite grains have an average grain size of not less than 2 &mgr;m but less than 4 &mgr;m. The second phase has an average particle size of not more than 8 &mgr;m and in not less than 80% of the second phase, the spacing of the second phase particle with the closest second phase particle is not less than the second phase particle size. The steel sheet has an ultrafine grain structure, superior mechanical characteristics, reduced anisotropy in its mechanical characteristics and high formability. A process for producing the steel sheet is also disclosed.Type: GrantFiled: October 26, 1999Date of Patent: September 18, 2001Assignee: Kawasaki Steel CorporationInventors: Eiko Yasuhara, Akio Tosaka, Osamu Furukimi
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Patent number: 6287395Abstract: A high-energy weldable soft magnetic steel with high toughness in the heat-affected zone of weld joints, high specific electric resistance to reduce eddy currents, aging resistance and weathering resistance comprises 0.65 to <1.0% chromium, >1.0 to 2.0% silicon, 0.25 to 0.55% copper, 0.003 to 0.008% nitrogen, 0.15 to <0.6% manganese, 0.02 to 0.07% aluminumsolu., 0.01 to 0.02% titanium, 0 to 0.15% carbon, 0 to 0.045% phosphorus, the balance iron and unavoidable impurities.Type: GrantFiled: February 5, 1999Date of Patent: September 11, 2001Assignee: Thyssen Stahl AGInventors: Udo Schriever, Hans-Joachim Tschersich
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Patent number: 6217675Abstract: Cold rolled steel sheets having improved bake hardenability is provided. Specifically, the present invention relates to a cold rolled steel sheet, with improved bake hardenability, comprising an ultra low carbon steel containing titanium and/or niobium, wherein the relationship between the contents of carbon and molybdenum in solid solution being regulated in a specified range, and a cold rolled steel sheet, with improved bake hardenability, which further contains a specified amount of boron in addition to the above constituents.Type: GrantFiled: February 28, 2000Date of Patent: April 17, 2001Assignee: Nippon Steel CorporationInventors: Hirokazu Taniguchi, Kazumasa Yamazaki, Koichi Goto
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Patent number: 6210496Abstract: A cold rolled steel sheet having high strength and high formability and having excellent crushing performance can include 0.05-0.40 mass % of C, 1.0-3.0 mass % of Si, 0.6-3.0 mass % of Mn, 0.02-1.5 mass % of Cr, 0.010-0.20 mass % of P and 0.01-0.3 mass % of Al, with the remainder consisting essentially of Fe. The steel sheet includes a ferrite major phase and a minor phase consisting of martensite, acicular ferrite and retained austenite. The cold rolled steel sheet can be used in automobiles.Type: GrantFiled: February 12, 1999Date of Patent: April 3, 2001Assignee: Kawasaki Steel CorporationInventors: Syusaku Takagi, Kazuya Miura, Osamu Furukimi, Kei Sakata, Takashi Obara
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Patent number: 6203630Abstract: A steel product contains, by mass %, C: 0.45 to 0.60%, Si: 0.01 to 0.15%, Mn: 0.20 to 0.60%, S: 0.012% or lower, Al: 0.015 to 0.040%, Ti: 0.005 to 0.050%, B: 0.0005 to 0.0050%, N: 0.010% or lower, O: 0.0010% or lower, and balance being Fe and unavoidable impurities. Limitations are provided to allowable maximum sizes per each sort of contained non-metallic inclusions and the number per unit area thereof. This steel may contains one kind or two kinds or more of Cr: 1.00% or lower, Mo: 0.50% or lower and Ni: 1.50 or lower.Type: GrantFiled: July 13, 2000Date of Patent: March 20, 2001Assignee: Daido Tokushuko Kabushiki KaishaInventors: Yasushi Matsumura, Yutaka Kurebayashi, Sadayuki Nakamura
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Patent number: 6187117Abstract: A method of making a weathering grade steel plate includes the steps of establishing a minimum yield strength:plate thickness target from one of 50 KSI:up to 4″, 65 KSI:up to 1.5″, and 70 KSI:up to 1.25″. A modified weathering grade alloy composition is cast into a slab employing effective levels of manganese, carbon, niobium, vanadium, nitrogen, and titanium. The cast slab is heated and rough rolled to an intermediate gauge plate. The intermediate gauge plate is controlled rolled and subjected to one of air cooling or accelerated cooling depending on the minimum yield strength and thickness target. With the controlled alloy chemistry, rolling and cooling, the final gauge plate exhibits discontinuous yielding and can be used for applications requiring a 70 KSI minimum yield strength in plate thicknesses up to 1.25″, a 65 KSI minimum yield strength in plate thickness up to 1.50″ and a 50 KSI minimum yield strength for plates as thick as 4″.Type: GrantFiled: January 20, 1999Date of Patent: February 13, 2001Assignees: Bethlehem Steel Corporation, Pohang Iron & Steel Co., Ltd.Inventors: Yulin Shen, Richard L. Bodnar, Jang-Yong Yoo, Wung-Yong Choo
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Patent number: 6149862Abstract: An alloy and alloy product has about 1.3% to 1.7% by weight concentration of silicon, along with iron, alloying elements, and inevitable impurities and exhibits improved resistance to hydrogen embrittlement and sulfide stress cracking in an intensive hydrogen-charged medium wherein H from the medium acts as an alloying element. The alloy is characterized by an Fe--Si--H system wherein Fe is a donor element with respect to Si and Si is an acceptor element with respect to Fe. Further, the alloying elements are Fe--Si noninteractive elements with respect to Fe and Si, such that the presence of the alloying elements are not donor or acceptor elements with respect to Fe or Si. In several alloy compositions, the alloy has between about 1.38% to 1.63% weight Si. The alloy may further include between about 0.10% to 0.25% weight of C. In one particular alloy, the alloy composition includes about 0.18% of C; although, in one alloy product, an alloy is used having about 0.16% to 0.24% weight of C.Type: GrantFiled: May 18, 1999Date of Patent: November 21, 2000Assignee: The Atri Group Ltd.Inventors: Naum I. Gliklad, Avgust B. Kuslitskiy, Leonid A. Kuslitskiy
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Patent number: 6083455Abstract: The present invention relates to manufacturing methods of nitrided steel parts, having high tensile strength, high fatigue strength, and excellent bending roughness, through nitriding without thermal refining, to thus-manufactured steel parts, and to steel products for nitriding, and steels for nitriding having a specific chemical composition, serving as steel stock for the manufacture of such steel parts. The chemical composition is as follows: C: over 0.20 to 0.60%, Si: 0.05 to 1.0%, Mn: 0.20 to 1.50%, P: 0.08% or less, S: 0.005 to 0.10%, Cu: 0.30% or less, Ni: 0.30% or less, Cr: 0.30% or less, Mo: 0.30% or less, V: 0.20% or less, Nb: 0.05% or less, Ti: 0.003 to 0.03%, Al: 0.08% or less, Ca: 0.005% or less, Pb: 0.30% or less, N: 0.008 to 0.030%, and the balance of Fe and unavoidable impurities. Steel products preferably have the ferrite-pearlite microstructure having a ferrite percentage of not less than 10%.Type: GrantFiled: January 5, 1998Date of Patent: July 4, 2000Assignee: Sumitomo Metal Industries, Ltd.Inventors: Masato Kurita, Koji Watari, Toru Kato, Harunori Kakimi, Mitsuo Uno, Masanori Sakamoto, Yoshihiko Kamada
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Patent number: 5993570Abstract: A high strength, high toughness, low carbon/low manganese steel is provided that is further resistant to stepwise cracking and sulfide stress cracking. The steel can be produced by conventional or thin slab casting techniques using normal speeds, with low manganese segregation levels. The steels are excellent candidates for linepipe applications in severe sour gas service.Type: GrantFiled: June 20, 1997Date of Patent: November 30, 1999Assignee: American Cast Iron Pipe CompanyInventor: John Malcolm Gray
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Patent number: 5985053Abstract: A steel having excellent HAZ toughness can be used for ships, buildings, pressure containers, linepipes, and so forth. The steel is of a Ti--Mg--O system steel containing at least 40 pcs/mm.sup.2 of oxide and composite oxide particles of Ti and Mg having a size of 0.001 to 5.0 .mu.m. A steel having excellent HAZ toughness can be produced, and the safety of structures using this steel can be remarkably improved.Type: GrantFiled: December 4, 1997Date of Patent: November 16, 1999Assignee: Nippon Steel CorporationInventors: Takuya Hara, Hitoshi Asahi, Hiroshi Tamehiro, Ryuji Uemori, Naoki Saito
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Patent number: 5954896Abstract: According to the present invention, an ultra low carbon steel with Nb, Ti, or Nb-Ti added thereto is used as a material, and (% S as MnS)/(total S content) is regulated to not more than 0.2 with (% C as carbosulfide)/(total C content) being regulating to not more than 0.7, thereby efficiently precipitating carbosulfide in a .gamma. temperature region during hot rolling and thus reducing the amount of C in solid solution to ensure the homogeneity of the material over the whole length of a coil and to markedly improve the workability.Type: GrantFiled: October 18, 1996Date of Patent: September 21, 1999Assignee: Nippon Steel CorporationInventors: Kazuo Koyama, Masayoshi Suehiro, Naoki Yoshinaga, Natsuko Hashimoto
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Patent number: 5919415Abstract: The invention relates to a steel and to a process for the manufacture of a steel component formed by cold plastic deformation.Type: GrantFiled: December 31, 1997Date of Patent: July 6, 1999Assignee: AscometalInventor: Claude Pichard
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Patent number: 5897967Abstract: A galvannealed steel sheet suited for use in automobiles, and a manufacturing method thereof. The steel sheet has tensile strength of 340 MPa or higher and paint bake hardenability of 10 MPa or higher, and excellent resistance to powdering when press formed, and excellent resistance to chipping in cold regions. The base metal of the galvannealed steel sheet consists essentially of C: 0.004-0.008%, Si: 2.5.times.P (%)-0.20%, Mn: 0.10-0.40%, P: 0.017-0.045%, sol. Al: 0.003-0.08%, Ti: 0.002-0.015%, Nb: 0.010-0.030 %, wherein Ti (%)+Nb (%): 0.012-0.035%. A steel sheet of the chemical composition described above is hot-dip galvanized, heated up to a Fe--Zn alloying temperature at a heating velocity of 20.degree. C./sec or higher, and upon completion of the Fe--Zn alloying process, cooled down from the Fe--Zn alloying temperature at a cooling velocity of 10.degree. C./sec or higher.Type: GrantFiled: July 16, 1997Date of Patent: April 27, 1999Assignee: Sumitomo Metal Industries, Ltd.Inventors: Masahiko Hori, Toshio Nakamori, Yoshiaki Nakazawa, Yasuyuki Tanno
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Patent number: 5853903Abstract: A cold-rolled steel sheet or a zinc or zinc alloy layer coated steel sheet containing 0.0010 to 0.01 wt % of C and having a steel composition containing one or two kinds of 0.005 to 0.08 wt % of Nb and 0.01 to 0.07 wt % of Ti in the ranges given by {(12/93)Nb+(12/48)Ti*} .gtoreq.0.0005, 0.ltoreq.C-{(12/93)Nb+(12/48)Ti*}.ltoreq.0.0015, and Ti*=Ti-{(48/32)S+(48/14)N } , in which a bake hardenability BH f the steel sheet at 170.degree. C..times.20 min after 2% tensile prestrain is 10 to 35 MPa and the BH (MPa) and a yield strength YP (MPa) of the steel sheet satisfy the ranges given by BH.gtoreq.exp(-0.115.multidot.YP+23.0) and 0.67.multidot.BH+160.ltoreq.YP.ltoreq.-0.8.multidot.BH+280.Type: GrantFiled: April 28, 1997Date of Patent: December 29, 1998Assignee: NKK CorporationInventors: Yoshihiro Hosoya, Fusato Kitano, Yasunobu Nagataki
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Patent number: 5820819Abstract: The present invention has an object to provide a steel for a chimney or a gas duct, which is excellent in pitting resistance and rust adhesion in a corrosive environment caused by combustion waste gas in a plant in which the combustion of natural gas occurs. Pitting resistance and rust adhesion are remarkably improved in the steel of the present invention which steel is prepared by using a 5% Cr steel as the base, while reducing an impurity sulfur to not more than 0.010 wt. %, adding titanium within a range of 0.005 to 0.05 wt. %, and further adding nickel alone within a range of 1.0 to 2.5 wt. %, or adding molybdenum alone within a range of 0.10 to 1.0 wt. %, or adding in combination therewith trace amount of copper or molybdenum within a range of 0.10 to 1.0 wt. %.Type: GrantFiled: August 20, 1996Date of Patent: October 13, 1998Assignees: Nippon Steel Corporation, Mitsubishi Jukogyo Kabushiki KaishaInventors: Koji Tanabe, Hidesato Mabuchi, Yukio Tomita, Akira Usami, Katsutoshi Hashima, Hiroshi Kondo, Ryuichiro Ebara, Yoshikazu Yamada, Kazuhide Yamauchi, Masuo Matsumoto
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Patent number: 5686194Abstract: A laminated steel sheet for dry forming drawn and ironed cans wherein the steel sheet comprises a steel containing iron, carbon, manganese, aluminum, silicon, phosphorus, sulfur and optionally titanium and/or niobium and wherein the steel sheet is electrolytically chromium-coated and covered on both sides with a 10-50 .mu.m thick thermoplastic resin layer. The sheet sheet has a crystal grain size of 8-30 .mu.m, a surface roughness of 0.05-0.6 .mu.m and a thickness of 0.15-0.3 mm.Type: GrantFiled: September 7, 1994Date of Patent: November 11, 1997Assignee: Toyo Kohan Co., Ltd.Inventors: Keiichi Shimizu, Humio Kunishige, Junichi Tanabe, Atsuo Tanaka
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Patent number: 5356493Abstract: Blister-resistant steel sheet consists essentially of 0.0005 to 0.003 wt. % C, 0.10 to 2.2 wt. % Mn, 0.6 wt. % or less Si, 0.07 wt. % or less P, 0.025 wt. % or less S, 0.02 to 0.06 wt. % of sol. Al, 0.0035 wt. % or less N, 0.003 wt. % or less O, [(48/14)N+(48/32)S+4.times.(48/12)C] wt. % or less Ti and the balance being Fe and inevitable impurities; and smaller one of either Ti (wt. %) or [(48/14)N+(48/32)S] (wt. %) being [0.002 t.sup.2 +0.003] or more, where t is a thickness (mm) of the steel sheet. Method for producing blister-resistant steel sheet comprises preparing a cold rolled steel sheet having the composition of described above, and continuously annealing or continuous hot dip galvanizing by heating the steel sheet from room temperature to 650.degree.-720.degree. C. at a rate of 20.degree. C. sec or more and further to the soaking temperature above recrystallization temperature at a rate of 1.degree.-5.degree. C./sec.Type: GrantFiled: July 1, 1993Date of Patent: October 18, 1994Assignee: NKK CorporationInventors: Seishi Tsuyama, Yoshihiro Hosoya, Shuji Kanetoh, Daijiro Koyanagi, Hiromi Nakamura, Satoshi Kohira
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Patent number: 5326527Abstract: A fully killed steel has a composition of from about 0.005 to about 0.020 percent titanium and from about 0.004 to about 0.015 percent nitrogen, with the mole ratio of titanium to nitrogen being less than about 3.42. One grade of this steel exhibiting a 42 KSI minimum yield strength has from about 0.15 to about 0.27 percent carbon and from 0 to about 0.04 percent vanadium. Another grade exhibiting a 50 KSI minimum yield strength has from about 0.05 to about 0.27 percent carbon and at least about 0.02 percent vanadium. The balance of each steel is iron and other elements. Copper may optionally be provided for strength and corrosion resistance. The steel is prepared by continuous casting and hot rolling, without any quenching and tempering required to achieve the desired properties.Type: GrantFiled: September 8, 1992Date of Patent: July 5, 1994Assignee: Bethlehem Steel CorporationInventors: Richard L. Bodnar, Steven S. Hansen
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Patent number: 5284529Abstract: An abrasion-resistant steel consists essentially of 0.05 to 0.45 wt. % C, 0.1 to 1 wt. % Si, 0.1 to 2 wt. % Mn, 0.05 to 1.5 wt. % Ti and the balance being Fe and inevitable impurities, the steel includes at least 200 of precipitates of 1 .mu.m or more in particle size per 1 mm.sup.2 and the precipitates contains Ti.In addition to the above basic elements, at least one element selected from the group consisting of 0.1 to 2 wt. % Cu, 0.1 to 10 wt. % Ni, 0.1 to 3 wt. % Cr, 0.1 to 3 wt. % Mo and 0.0003 to 0.01 wt. % B is added to steel or at least one element selected from the group consisting of 0.005 to 1 wt. % Nb and 0.01 to 1 wt. % V is added to steel.Type: GrantFiled: February 26, 1993Date of Patent: February 8, 1994Assignee: NKK CorporationInventors: Nobuo Shikanai, Yasunobu Kunisada, Tetsuya Sanpei, Kazunori Yako, Kenji Hirabe
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Patent number: 5236521Abstract: An abrasion resistant steel consisting essentially of 0.05 to 0.45 wt. % C, 0.1 to 1 wt. % Si, 0.1 to 2 wt. % Mn, 0.3 to 1.5 wt. % Ti, at most 0.005 wt. % N and the balance Fe as the basic elements contributing to the enhancement of the abrasion resistance property, without excessively increasing the hardness of the steel. In addition to the basic elements, at least one element selected from the group consisting of 0.1 to 2 wt. % Cu, 0.1 to 10 wt. % Ni, 0.1 to 3 wt. % Cr, 0.1 to 3 wt. % Mo and 0.0003 to 0.01 wt. % B may be added to enhance the quenching hardenability of the steel, and 0.01 to 0.5 wt. % V may be added to enhance the precipitation hardenability of the steel.Type: GrantFiled: June 15, 1992Date of Patent: August 17, 1993Assignee: NKK CorporationInventors: Nobuo Shikanai, Tetsuya Sanpei, Kazunori Yako, Kenji Hirabe, Yasunobu Kunisada
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Patent number: 5133815Abstract: Cold-rolled steel sheets or hot-dip galvanized steel sheets for deep drawing which have excellent resistance to cold-work embrittlement, containing, all by mass, 0.01% or less C, 0.2% or less Si, 0.05-1.0% Mn, 0.10% or less P, 0.02% or less S, 0.005-0.08% sol.Al, and 0.006% or less N, containing Ti (%) and/or NB (%) solely or in combination within the range in which a relationship between the effective amount of Ti (hereinafter referred to as Ti*) defined by the following formula (1) and the amounts of Nb and C satisfies the following formula (2), and further containing 0.003% or less B when required.Ti*=total Ti-{(48/32).times.S+(48/14).times.N}TM (1)1.ltoreq.(Ti*/48+Nb/93)/(C/12).ltoreq.4.5 (2)And the balance of Fe and inevitable impurities, the steel sheets have a concentration gradient as a result of carburizing.Type: GrantFiled: March 1, 1991Date of Patent: July 28, 1992Assignee: Kabushiki Kaisha Kobe Seiko ShoInventors: Shunichi Hashimoto, Tatsuya Asai, Mitsuru Kitamura
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Patent number: 4985090Abstract: A non-ageing low-alloy hot-rolled strip-form formable steel has a carbon content of between 0.02 and 0.10 wt. % and a thickness of between 0.5 and 5.0 mm. In order to bind N so as to achieve a non-ageing steel, while permitting direct entry of the steel to rolling from casting, the contents of titanium, nitrogen and sulphur in wt. % satisfy the conditions:Ti.gtoreq.2.28 NTi.ltoreq.3.43 N+1.5 Sand the steel is free from titanium carbide and niobium carbide and contains nitrogen in an amount of less than 0.007 wt. %.Type: GrantFiled: June 8, 1990Date of Patent: January 15, 1991Assignee: Hoogovens Groep B.V.Inventors: Erik B. Van Perlstein, Huibert W. den Hartog
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Patent number: 4919885Abstract: The invention relates to a structural steel having high resistance to intergranular stress operation cracking, more particularly in nitrate solutions and good welding properties (in % by mass):0.01 to 0.04% carbonup to 0.012% nitrogen0.08 to 0.22% titanium with Ti equal or greater than 3.5 (C+N)0.2 to 2.5% manganese2.0 to 5.5% chromium0.01 to 0.10% aluminiumup to 0.5% siliconup to 1.0% nickelup to 0.02% phosphorusup to 0.02% sulphurthe residue being iron and unavoidable impurities.Type: GrantFiled: September 28, 1988Date of Patent: April 24, 1990Assignee: Thyssen Stahl AGInventors: Lutz Meyer, Ludwig Hachtel, Gunter Robusch
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Patent number: 4842816Abstract: A steel composition particularly suitable for the manufacture of electric resistance welded pipes for use in most hostile environments and able to display excellent sour resistance and high toughness. The aluminum content of the steel composition is reduced to not more than 0.005%, while from 0.006 to 0.2% in total of one or both of titanium and zirconium is used instead for steel containing 0.0005 to 0.008% Ca. The steel, apart from iron and unavoidable impurities further contains:0.01 to 0.35% C0.02 to 0.5% Si0.1 to 1.8% Mnnot more than 0.015% P, andnot more than 0.003% SCu, Ni, Cr, Mo, Nb and V may be added in appropriate amounts to enhance the steel performance.Type: GrantFiled: July 27, 1987Date of Patent: June 27, 1989Assignee: Nippon Steel CorporationInventors: Akihiro Miyasaka, Hiroyo Haga, Takeshi Terasawa
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Patent number: 4838963Abstract: The invention relates to a micro-alloyed pearlitic steels contain 0.20 to 0.50% C, 0.40 to 1.0% Si, 0,80 to 1,80% Mn, 0.008 to 0.2% S, 0 to 0.7% Cr, 0 to 0.1% Al, 0 to 0.04% N, 0.01 to 0.05% Ti, remainder iron and impurities resulting from the melting process, with mixed sulphides (manganese, titanium carbonitrides, and the like) precipitated on the grain boundaries. The steel may preferably contain an additional content of up to 0.20% V and/or up to 0.10% Nb.Type: GrantFiled: July 6, 1987Date of Patent: June 13, 1989Assignee: Thyssen Edelstahlwerke AGInventors: Bernd Huchtemann, Serosh Engineer, Volker Schuler
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Patent number: 4784922Abstract: The present invention provides corrosion resistance clad steels comprising a steel core and a cladding of a corrosion resistance metallic material tightly covering the circumference of the core, the interface between the core and cladding being metallurgically bonded. As the core materials, steel bars for concrete reinforcement including PC steel bars; or materials for sections (e.g., angles or channels) may be appropriately selected depending on the intended use. The foregoing steel materials is produced by a method comprising the steps of arranging the corrosion resistance metallic cladding member over the entire surface of the circumference of the steel core member and hot rolling to form an intimate metallurgical bonding at the interface between both members, thereby forming the foregoing clad steel material. The material may be formed into deformed steel bars.Type: GrantFiled: October 3, 1986Date of Patent: November 15, 1988Assignee: Mitsubishi Steel Mfg. Co., Ltd.Inventor: Tsuneo Yoshimura
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Patent number: RE33022Abstract: A ferromagnetic amorphous alloy having a composition represented by (Co.sub.x Ni.sub.y Fe.sub.z).sub.a M.sub.b G.sub.c, wherein M is Cr, Mo and/or W, G is Zr, Hf and/or Ti and x,y,z and a, b, c are selected to meet the conditions of x=1-y-z, 0.ltoreq.y.ltoreq.0.2, 0.ltoreq.z.ltoreq.0.7, a=1-b-c, 0.ltoreq.b.ltoreq.0.05 and 0.05.ltoreq.c.ltoreq.0.2 This amorphous alloy has a superior magnetic characteristic and a high thermal stability.Type: GrantFiled: November 5, 1987Date of Patent: August 15, 1989Assignees: Hitachi, Ltd., Hitachi Metals, Ltd., Research Development Corp. of JapanInventors: Shinji Takayama, Yasuo Tsukuda, Kazuo Shiiki, Shigekazu Otomo, Mitsuhiro Kudo, Yasunobu Ogata, Yoshizo Sawada