Noble Metal Containing Patents (Class 420/444)
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Patent number: 11542575Abstract: Disclosed herein are embodiments of a nickel-based alloy. In particular embodiments, the nickel-based alloy is configured for use in applications involving supercritical fluids. The disclosed nickel-based alloy embodiments are highly resistant to corrosion and exhibit high stability and thus are suited for use in vessels, boilers, piping, and other receptacles that contain or are used with supercritical fluids. Method embodiments of making the nickel-based alloy also are disclosed.Type: GrantFiled: May 10, 2019Date of Patent: January 3, 2023Assignee: Etikrom A.S.Inventors: Benjamin Adam, Julie Tucker
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Patent number: 11268170Abstract: A nickel-based superalloy comprises, in percentages by mass, 4.0 to 5.5% rhenium, 3.5 to 12.5% cobalt, 0.30 to 1.50% molybdenum, 3.5 to 5.5% chromium, 3.5 to 5.5% tungsten, 4.5 to 6.0% aluminum, 0.35 to 1.50% titanium, 8.0 to 10.5% tantalum, 0.15 to 0.30% hafnium, 0.05 to 0.15% silicon, the balance being nickel and unavoidable impurities. A single-crystal blade comprises such an alloy and a turbomachine comprising such a blade.Type: GrantFiled: November 14, 2018Date of Patent: March 8, 2022Assignees: SAFRAN, OFFICE NATIONAL D'ETUDES ET DE RECHERCHES AEROSPATIALESInventors: Jérémy Rame, Virginie Jaquet, Joël Delautre, Jean-Yves Guedou, Pierre Caron, Odile Lavigne, Didier Locq, Mikael Perrut
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Patent number: 11105216Abstract: The component of the turbomachine comprises a body of the component, a bond layer covering a base surface of the body, and a top layer covering the bond layer and made of abradable ceramic material. The base surface of the component has patterned protrusions and, through two covering steps used for forming the bond layer and the top layer, also the top surface of the component has patterned protrusions. The pattern protrusions of the base surface may be obtained in different ways, for example casting, milling, grinding, electric discharge machining or additive manufacturing. The patterned protrusions belong to an abradable seal of the turbomachine, and may be shaped and sized to maintain specified clearances and to reduce flow of a working fluid within turbomachinery equipment and/or it's components.Type: GrantFiled: May 13, 2015Date of Patent: August 31, 2021Assignee: NUOVO PIGNONE SRLInventors: Iacopo Giovannetti, Massimo Giannozzi, Giovanni Salvestrini, Girolamo Tripoli, Marco Boncinelli
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Patent number: 10071813Abstract: A helicopter engine air intake including an anti-icing grid that provides a large bypass flow in event of icing. The air intake includes air intake lips and an anti-icing grid mounted on outer ends of the air intake lips, being interposed in the air flow penetrating into the air intake, at least one air intake lip being formed by a thin metal sheet.Type: GrantFiled: July 26, 2013Date of Patent: September 11, 2018Assignee: SAFRAN HELICOPTER ENGINESInventors: Paul-Etienne Jactat, Nicolas Bulot, Pascal Lebrusq, Thierry Vergez
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Patent number: 9499886Abstract: A Ni-based single crystal superalloy which has the following composition: Co: 4.0 to 9.5 wt %, Cr: 5.1 to 8.0 wt %, Mo: 2.1 to 3.5 wt %, W: 0.0 to 2.9 wt %, Ta: 4.0 to 10.0 wt %, Al: 4.5 to 6.5 wt %, Ti: 0.0 to 1.0 wt %, Hf: 0.08 to 0.5 wt %, Nb: 0.0 to 3.0 wt %, Re: 4.5 to 8.0 wt % and Ru: 0.5 to 6.5 wt % with the remainder including Ni and unavoidable impurities, wherein P1?700 is satisfied in which P1 represents a parameter 1, which is obtained by a formula: P1=137×[W (wt %)]+24×[Cr (wt %)]+46×[Mo (wt %)]?18×[Re (wt %)].Type: GrantFiled: June 18, 2015Date of Patent: November 22, 2016Assignee: IHI CORPORATIONInventors: Akihiro Sato, Kazuyoshi Chikugo, Yasuhiro Aoki, Nobuhito Sekine, Mikiya Arai, Shoju Masaki
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Patent number: 9011764Abstract: A nickel-chromium-cobalt-molybdenum alloy includes (in weight %) Cr 21-23%, Fe 0.05-1.5%, C 0.05-0.08%, Mn?0.5%, Si?0.25%, Co 11-13%, Cu?0.15%, Mo 8.0-10.0%, Ti 0.3-0.5%, Al 0.8-1.3%, P<0.012%, S<0.008%, B>0.002-<0.006%, Nb>0-1%, N?0.015%, Mg?0.025%, Ca?0.01%, V 0.005-0.6%, optionally W in contents between 0.02-max. 2%, Ni rest as well as smelting-related impurities, in the form of tubes, sheets, wire, bars, strips or forgings, wherein the alloy satisfies the following formula: X3=5?50, wherein X ? ? 3 = 100 * X ? ? 1 X ? ? 2 and X1=C+5N and X2=0.5Ti+Nb+0.5 V.Type: GrantFiled: March 15, 2011Date of Patent: April 21, 2015Assignee: VDM Metals GmbHInventors: Jutta Kloewer, Juergen Tewes, Ralf-Udo Husemann
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Patent number: 8968643Abstract: The object of the present invention is to provide an Ni-based single crystal super alloy capable of improving strength by preventing precipitation of a TCP phase at high temperatures. This object is achieved by an Ni-based single crystal super alloy having a composition comprising 5.0-7.0 wt % of Al, 4.0-10.0 wt % of Ta, 1.1-4.5 wt % of Mo, 4.0-10.0 wt % of W, 3.1-8.0 wt % of Re, 0-0.50 wt % of Hf, 2.0-5.0 wt % of Cr, 0-9.9 wt % of Co and 4.1-14.0 wt % of Ru in terms of its weight ratio, with the remainder consisting of Ni and unavoidable impurities. Furthermore, in this Ni-based single crystal super alloy, when lattice constant of matrix is taken to be a1 and lattice constant of precipitation phase is taken to be a2, a2?0.999a1.Type: GrantFiled: October 8, 2010Date of Patent: March 3, 2015Assignees: National Institute for Materials Science, IHI CorporationInventors: Toshiharu Kobayashi, Yutaka Koizumi, Tadaharu Yokokawa, Hiroshi Harada, Yasuhiro Aoki, Mikiya Arai, Shoju Masaki
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Patent number: 8926897Abstract: A nickel-base superalloy having excellent oxidation resistance is provided. It is useful as high-temperature members such as turbine blades and turbine vanes for jet engines or gas turbines. The nickel-base superalloy has a composition containing Co: 0.1 to 15% by weight, Cr: 0.1 to 10% by weight, Mo: 0.1 to 4.5% by weight, W: 0.1 to 15% by weight, Al: 2 to 8% by weight, Ta+Nb+Ti: 0 to 16% by weight, Hf: 0 to 5% by weight, Re: 0.1 to 16% by weight, Ru: 0.1 to 16% by weight, Si: 0.2 to 5% by weight and a balance made of Ni and unavoidable impurities.Type: GrantFiled: September 27, 2006Date of Patent: January 6, 2015Assignee: National Institute for Materials ScienceInventors: Hiroshi Harada, Kyoko Kawagishi, Toshiharu Kobayashi, Yutaka Koizumi, Atsushi Sato
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Patent number: 8877122Abstract: A Ni-based single crystal superalloy which has the following composition: Co: 0.0 wt % or more to 15.0 wt % or less, Cr: 4.1 to 8.0 wt %, Mo: 2.1 to 4.5 wt %, W: 0.0 to 3.9 wt %, Ta: 4.0 to 10.0 wt %, Al: 4.5 to 6.5 wt %, Ti: 0.0 to 1.0 wt %, Hf: 0.00 to 0.5 wt %, Nb: 0.0 to 3.0 wt %, Re: 8.1 to 9.9 wt % and Ru: 0.5 to 6.5 wt % with the remainder including Ni and unavoidable impurities. As a result, the Ni-based single crystal superalloy which includes more than 8 wt % of Re in the composition ratio and has excellent specific creep strength and the turbine blade incorporating the Ni-based single crystal superalloy may be made.Type: GrantFiled: April 16, 2010Date of Patent: November 4, 2014Assignee: IHI CorporationInventors: Yasuhiro Aoki, Nobuhito Sekine, Akihiro Sato, Kazuhito Miyata, Kazuyoshi Chikugo
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Patent number: 8852500Abstract: A Ni-base superalloy having a chemical composition comprising Cr: 3.0-5.0 wt %, Co: 5.0-10.0 wt %, Mo: 0.5-3.0 wt %, W: 8.0-10.0 wt %, Ta: 5.0-8.0 wt %, Nb: 3.0 wt % or less, Al: 4.5-6.0 wt %, Ti: 0.1-2.0 wt %, Re: more than 3.0-4.0 wt %, Ru: 0.2-4.0 wt %, Hf: 0.01-0.2 wt %, and the balance being Ni and unavoidable impurities, a method for producing the same, and turbine blade or turbine vane components are disclosed. The Ni-base superalloy has high creep strength and textural stability under high temperature environment, and is excellent in applicability to turbine blade or turbine vane components of large-sized gas turbines.Type: GrantFiled: March 16, 2007Date of Patent: October 7, 2014Assignee: National Institute for Materials ScienceInventors: Yutaka Koizumi, Hiroshi Harada, Tadaharu Yokokawa, Toshiharu Kobayashi
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Patent number: 8771440Abstract: A Ni-based single crystal superalloy according to the invention has, for example, a composition including: 5.0 to 7.0 wt % of Al, 4.0 to 10.0 wt % of Ta, 1.1 to 4.5 wt % of Mo, 4.0 to 10.0 wt % of W, 3.1 to 8.0 wt % of Re, 0.0 to 2.0 wt % of Hf, 2.5 to 8.5 wt % of Cr, 0.0 to 9.9 wt % of Co, 0.0 to 4.0 wt % of Nb, and 1.0 to 14.0 wt % of Ru in terms of weight ratio; and the remainder including Ni and incidental impurities. In addition, the contents of Cr, Hf and Al are preferably set so as to satisfy the equation OP?108. According to the Ni-based single crystal superalloy of the invention, high creep strength can be maintained and the oxidation resistance can be improved.Type: GrantFiled: September 12, 2007Date of Patent: July 8, 2014Assignees: National Institute for Materials Science, IHI CorporationInventors: Akihiro Sato, Hiroshi Harada, Kyoko Kawagishi, Toshiharu Kobayashi, Tadaharu Yokokawa, Yutaka Koizumi, Yasuhiro Aoki, Mikiya Arai, Kazuyoshi Chikugo, Shoju Masaki
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Publication number: 20140130945Abstract: A bulk-glass forming Ni—Cr—Nb—P—B alloy is provided. The alloy includes Ni(100?a?b?c?d)CraTabPcBd, where the atomic percent a is between 3 and 11, the atomic percent b is between 1.75 and 4, the atomic percent c is between 14 and 17.5, and the atomic percent d is between 2.5 and 5. The alloy is capable of forming a metallic glass having a lateral dimension of at least 3 mm.Type: ApplicationFiled: November 15, 2013Publication date: May 15, 2014Applicant: Glassimetal Technology, Inc.Inventors: Jong Hyun Na, Michael Floyd, Marios D. Demetriou, William L. Johnson, Glenn Garrett
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Patent number: 8696980Abstract: A nickel-base superalloy with improved degradation behavior consists essentially of the following chemical composition (details in % by weight): 7.7-8.3 Cr, 5.0-5.25 Co, 2.0-2.1 Mo, 7.8-8.3 W, 5.8-6.1 Ta, 4.9-5.1 Al, 1.3-1.4 Ti, 0.1-0.6 Pt, 0.1-0.5 Nb, 0.11-0.15 Si, 0.11-0.15 Hf, 200-750 ppm C, 50-400 ppm B, and the remainder Ni and production-related impurities.Type: GrantFiled: February 3, 2011Date of Patent: April 15, 2014Assignee: Alstom Technology LtdInventors: Mohamed Nazmy, Claus Paul Gerdes, Andreas Kuenzler
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Patent number: 8696979Abstract: A Ni-base superalloy having a chemical composition comprising Al: 4.5-7.0 wt %, Ta+Nb+Ti: 0.1-4.0 wt %, with Ta being less than 4.0 wt %, Mo: 1.0-8.0 wt %, W: 0.0-10.0 wt %, Re: 2.0-8.0 wt %, Hf: 0.0-1.0 wt %, Cr: 2.0-10.0 wt %, Co: 0.0-15.0 wt %, Ru: 0.0-5.0 wt %, and the balance being Ni and unavoidable impurities, and a method for producing the same are disclosed. The Ni-base superalloy has excellent creep property at high temperature and is suitable for use as a member at high temperature under high stress.Type: GrantFiled: March 16, 2007Date of Patent: April 15, 2014Assignee: National Institute for Materials ScienceInventors: Tadaharu Yokokawa, Yutaka Koizumi, Hiroshi Harada, Toshiharu Kobayashi
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Publication number: 20140076467Abstract: Nickel based alloys capable of forming bulk metallic glass are provided. The alloys include Ni—Cr—Si—B compositions, with additions of P and Mo, and are capable of forming a metallic glass rod having a diameter of at least 1 mm. In one example of the present disclosure, the Ni—Cr—Mo—Si—B—P composition includes about 4.5 to 5 atomic percent of Cr, about 0.5 to 1 atomic percent of Mo, about 5.75 atomic percent of Si, about 11.75 atomic percent of B, about 5 atomic percent of P, and the balance is Ni, and wherein the critical metallic glass rod diameter is between 2.5 and 3 mm and the notch toughness between 55 and 65 MPa m1/2.Type: ApplicationFiled: September 17, 2013Publication date: March 20, 2014Applicant: Glassimetal Technology Inc.Inventors: Jong Hyun Na, Michael Floyd, Glenn Garrett, Marios D. Demetriou, William L. Johnson
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Patent number: 8641963Abstract: The present disclosure relates to an improved low-cost metallic coating to be deposited on gas turbine engine components. The metallic coating consists of 1.0 to 18 wt % cobalt, 3.0 to 18 wt % chromium, 5.0 to 15 wt % aluminum, 0.01 to wt % yttrium, 0.01 to 0.6 wt % hafnium, 0.0 to 0.3 wt % silicon, 0.0 to 1.0 wt % zirconium, 0.0 to 10 wt % tantalum, 0.0 to 9.0 wt % tungsten, 0.0 to 10 wt % molybdenum, 0.0 to 43.0 wt % platinum, and the balance nickel.Type: GrantFiled: July 8, 2008Date of Patent: February 4, 2014Assignee: United Technologies CorporationInventors: Brian S. Tryon, David A. Litton, Russell A. Beers
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Publication number: 20130315659Abstract: A braze alloy composition is disclosed, containing nickel, about 5% to about 40% of at least one refractory metal selected from niobium, tantalum, or molybdenum; about 2% to about 32% chromium; and about 0.5% to about 10% of at least one active metal element. An electrochemical cell that includes two components joined to each other by such a braze composition is also described. A method for joining components such as those within an electrochemical cell is also described. The method includes the step of introducing a braze alloy composition between a first component and a second component to be joined, to form a brazing structure. In many instances, one component is formed of a ceramic, while the other is formed of a metal or metal alloy.Type: ApplicationFiled: September 27, 2012Publication date: November 28, 2013Applicant: General Electric CompanyInventors: Sundeep Kumar, Raghavendra Rao Adharapurapu, Mohamed Rahmane
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Patent number: 8491837Abstract: A Ni-based brazing composition at least containing, in mass %, 1.0% or more and 1.3% or less of B, 4.0% or more and 6.0% or less of Si, and the balance consisting of Ni and unavoidable impurities, wherein the brazing composition forms wherein the brazing composition forms dispersed phase containing B or Si in a metal texture after the brazing, and a maximum length of the dispersed phase is 30 ?m or less.Type: GrantFiled: September 2, 2008Date of Patent: July 23, 2013Assignee: IHI CorporationInventors: Naoki Oiwa, Sadao Nishikiori, Tsukasa Wakabayashi, Junji Tsuji
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Publication number: 20130095346Abstract: A Ni-based superalloy component includes a bond coat layer having a chemical composition not allowing interdiffusion to occur on a Ni-base superalloy substrate, and by allowing the bond coat layer to have Pt and/or Ir content equal to or higher than 0.2% but not exceeding 15% by mass, generation of an SRZ, which occurs at an interface between the Ni-base superalloy substrate and the bond coat layer in a high-temperature oxidizing atmosphere, can be suppressed, and at the same time adhesion at the interface between a ceramic thermal barrier coat layer and the bond coat layer is improved. Thus, a long-life Ni-based superalloy component with suppressed elemental interdiffusion between the Ni-base superalloy substrate and the bond coat layer even at temperatures exceeding 1100° C. is provided.Type: ApplicationFiled: April 14, 2011Publication date: April 18, 2013Applicant: NATIONAL INSTITUTE FOR MATERIALS SCIENCEInventors: Rudder Wu, Kyoko Kawagishi, Kazuhide Matsumoto, Hiroshi Harada
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Patent number: 8366838Abstract: A single crystal alloy for high AN2 applications has a composition consisting essentially of from 4.0 to 10 wt % chromium, from 1.0 to 2.5 wt % molybdenum, up to 5.0 wt % tungsten, from 3.0 to 8.0 wt % tantalum, from 5.5 to 6.25 wt % aluminum, from 6.0 to 17 wt % cobalt, up to 0.2 wt % hafnium, from 4.0 to 6.0 wt % rhenium, from 1.0 to 3.0 wt % ruthenium, and the balance nickel. Further, these single crystal alloys have a total tungsten and molybdenum content in the range of from 1.0 to 7.5 wt %, preferably from 2.0 to 7.0 wt %, a total refractory element content in the range of from 9.0 to 24.5 wt %, preferably from 13 to 22 wt %, a ratio of rhenium to a total refractory element content in the range of from 0.16 to 0.67, preferably from 0.20 to 0.45, a density in the range of from 0.300 to 0.325 lb/in3, and a specific creep strength in the range from 106×103 to 124×103 inches.Type: GrantFiled: December 9, 2009Date of Patent: February 5, 2013Assignee: United Technologies CorporationInventors: Venkatarama K. Seetharaman, Alan D. Cetel
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Patent number: 8334056Abstract: An alloy including: about 10 at % to about 30 at % of a Pt-group metal; less than about 23 at % Al; about 0.5 at % to about 2 at % of at least one reactive element selected from Hf, Y, La, Ce and Zr, and combinations thereof; a superalloy substrate constituent selected from the group consisting of Cr, Co, Mo, Ta, Re and combinations thereof; and Ni; wherein the Pt-group metal, Al, the reactive element and the superalloy substrate constituent are present in the alloy in a concentration to the extent that the alloy has a solely ??-Ni3Al phase constitution.Type: GrantFiled: September 2, 2011Date of Patent: December 18, 2012Assignee: Iowa State University Research Foundation, Inc.Inventors: Brian M. Gleeson, Daniel J. Sordelet, Wen Wang
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Publication number: 20120237391Abstract: The present invention provides Ni-base single crystal superalloy with good high-temperature property, particularly long creep life and excellent resistance to creep deformation, by adjusting content of Al and Ti that form a gamma prime (??), a major hardening phase of the Ni-base single crystal superalloy. The Ni-base single crystal superalloy comprise Co: 11.5˜13.5%, Cr: 3.0˜5.0%, Mo: 0.7˜2.0%, W: 8.5˜10.5%, Al: 3.5˜5.5%, Ti: 2.5˜4.5%, Ta: 6.0˜8.0%, Re: 2.0˜4.0%, Ru: 0.1˜2.0% in Weight %, and the rest is Ni and other inevitable impurities. And composition ratio of Al/Ti is 0.7˜2.2. In addition, the superalloy has a mixed structure of the ? matrix and ?? particles.Type: ApplicationFiled: March 14, 2012Publication date: September 20, 2012Applicant: KOREA INSTITUTE OF MACHINERY & MATERIALSInventors: Hyun Uk Hong, Chang Yong Jo, In Soo Kim, Baig Gyu Choi
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Patent number: 8241560Abstract: A single crystal nickel base superalloy consists essentially of, in weight %, about 6.4% to about 6.8% Cr, about 9.3% to about 10.0% Co, above 6.7% to about 8.5% Ta, about 5.45% to about 5.75% Al, about 6.2% to about 6.6% W, about 0.5% to about 0.7% Mo, about 0.8% to about 1.2% Ti, about 2.8% to about 3.2% Re, up to about 0.12% Hf, about 0.01% to about 0.08% by weight C, up to about 0.10% B, and balance Ni and incidental impurities. The superalloy provides improved alloy cleanliness and castability while providing improved high temperature mechanical properties such as stress rupture life.Type: GrantFiled: April 28, 2003Date of Patent: August 14, 2012Assignee: Howmet CorporationInventors: John Corrigan, Michael G. Launsbach, John R. Mihalisin
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Publication number: 20120034098Abstract: A Ni-based single crystal superalloy which has the following composition: Co: 0.0 wt % or more to 15.0 wt % or less, Cr: 4.1 to 8.0 wt %, Mo: 2.1 to 4.5 wt %, W: 0.0 to 3.9 wt %, Ta: 4.0 to 10.0 wt %, Al: 4.5 to 6.5 wt %, Ti: 0.0 to 1.0 wt %, Hf: 0.00 to 0.5 wt %, Nb: 0.0 to 3.0 wt %, Re: 8.1 to 9.9 wt % and Ru: 0.5 to 6.5 wt % with the remainder including Ni and unavoidable impurities. As a result, the Ni-based single crystal superalloy which includes more than 8 wt % of Re in the composition ratio and has excellent specific creep strength and the turbine blade incorporating the Ni-based single crystal superalloy may be made.Type: ApplicationFiled: April 16, 2010Publication date: February 9, 2012Inventors: Yasuhiro Aoki, Nobuhito Sekine, Akihiro Sato, Kazuhito Miyata, Kazuyoshi Chikugo
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Publication number: 20110256018Abstract: A Ni-based single crystal superalloy with good resistance to creep deformation and creep life at a high temperature is formed by adjusting the quantity of relatively inexpensive alloy elements while minimizing the quantity of expensive alloy elements. The Ni-based single crystal superalloy with good creep properties comprises Co: 11.5˜13.5%, Cr: 3.0˜5.0%, Mo: 0.7˜2.0%, W: 8.5˜10.5%, Al: 4.5˜6.5%, Ti: 0.5˜2.0%, Ta: 6.0˜8.0%, Re: 2.0˜4.0%, Ru: 0.1˜2.0% in Weight %, with the rest of the superalloy comprising Ni and other inevitable impurities. In addition, the superalloy has a mixed structure of the ? matrix and ?? particles.Type: ApplicationFiled: July 30, 2010Publication date: October 20, 2011Applicant: KOREA INSTITUTE OF MACHINERY & MATERIALSInventors: Baig Gyu Choi, Chang Yong Jo, In Soo Kim, Young Keun Ahn, Young Soo Yoo, Hi Won Jeong, Seong Moon Seo, Hyun Uk Hong
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Publication number: 20110194972Abstract: A nickel-base superalloy with improved degradation behavior consists essentially of the following chemical composition (details in % by weight): 7.7-8.3 Cr, 5.0-5.25 Co, 2.0-2.1 Mo, 7.8-8.3 W, 5.8-6.1 Ta, 4.9-5.1 Al, 1.3-1.4 Ti, 0.1-0.6 Pt, 0.1-0.5 Nb, 0.11-0.15 Si, 0.11-0.15 Hf, 200-750 ppm C, 50-400 ppm B, and the remainder Ni and production-related impurities.Type: ApplicationFiled: February 3, 2011Publication date: August 11, 2011Applicant: ALSTOM TECHNOLOGY LTDInventors: Mohamed Nazmy, Claus Paul Gerdes, Andreas Kuenzler
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Publication number: 20110171057Abstract: The object of the present invention is to provide an Ni-based single crystal super alloy capable of improving strength by preventing precipitation of a TCP phase at high temperatures. This object is achieved by an Ni-based single crystal super alloy having a composition comprising 5.0-7.0 wt % of Al, 4.0-10.0 wt % of Ta, 1.1-4.5 wt % of Mo, 4.0-10.0 wt % of W, 3.1-8.0 wt % of Re, 0-0.50 wt % of Hf, 2.0-5.0 wt % of Cr, 0-9.9 wt % of Co and 4.1-14.0 wt % of Ru in terms of its weight ratio, with the remainder consisting of Ni and unavoidable impurities. Furthermore, in this Ni-based single crystal super alloy, when lattice constant of matrix is taken to be a1 and lattice constant of precipitation phase is taken to be a2, a2?0.999a1.Type: ApplicationFiled: October 8, 2010Publication date: July 14, 2011Inventors: Toshiharu KOBAYASHI, Yutaka KOIZUMI, Tadaharu YOKOKAWA, Hiroshi HARADA, Yasuhiro AOKI, Mikiya ARAI, Shoju MASAKI
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Patent number: 7910512Abstract: To provide a production process of an electrode catalyst for fuel cell whose initial voltage is high and whose endurance characteristics, especially, whose voltage drop being caused by high-potential application is less. A production process according to the present invention of an electrode catalyst for fuel cell is characterized in that: it includes: a dispersing step of dispersing a conductive support in a solution; a loading step of dropping a platinum-salt solution, a base-metal-salt solution and an iridium-salt solution to the resulting dispersion liquid, thereby loading respective metallic salts on the conductive support as hydroxides under an alkaline condition; and an alloying step of heating the conductive support with metallic hydroxides loaded in a reducing atmosphere to reduce them, thereby alloying them.Type: GrantFiled: September 26, 2008Date of Patent: March 22, 2011Assignee: Cataler CorporationInventors: Hiroaki Takahashi, Sozaburo Ohashi, Tetsuo Kawamura, Yousuke Horiuchi, Toshiharu Tabata, Tomoaki Terada, Takahiro Nagata, Susumu Enomoto
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Patent number: 7871247Abstract: A high modulus component, such as an aircraft engine turbine blade, is formed from a base metal that has a high modulus crystallographic orientation that is aligned with the primary, i.e. radial, direction of the turbine blade. The base metal is Ni, Fe, Ti, Co, Al, Nb, or Mo based alloy. Alignment of a high modulus direction of the base metal with the primary direction provides enhanced high cycle fatigue life.Type: GrantFiled: August 17, 2007Date of Patent: January 18, 2011Assignee: United Technologies CorporationInventors: Dilip M. Shah, Alan D. Cetel, Alan W. Stoner, William P. Allen
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Publication number: 20100297472Abstract: A metallic coating for protecting a substrate from high temperature oxidation and hot corrosion environments comprising about 2.5 to about 13.5 wt. % cobalt, about 12 to about 27 wt. % chromium, about 5 to about 7 wt. % aluminum, about 0.0 to about 1.0 wt. % yttrium, about 0.0 to about 1.0 wt. % hafnium, about 1.0 to about 3.0 wt. % silicon, about 0.0 to about 4.5 wt. % tantalum, about 0.0 to about 6.5 wt. % tungsten, about 0.0 to about 2.0 wt. % rhenium, about 0.0 to about 1.0 wt. % molybdenum and the balance nickel.Type: ApplicationFiled: May 22, 2009Publication date: November 25, 2010Applicant: UNITED TECHNOLOGIES CORPORATIONInventors: Michael Minor, Paul M. Pellet, Michael L. Miller, Brian S. Tryon
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Publication number: 20100226779Abstract: A Ni-base superalloy having a chemical composition comprising Cr: 3.0-5.0 wt %, Co: 5.0-10.0 wt %, Mo: 0.5-3.0 wt %, W: 8.0-10.0 wt %, Ta: 5.0-8.0 wt %, Nb: 3.0 wt % or less, Al: 4.5-6.0 wt %, Ti: 0.1-2.0 wt %, Re: more than 3.0-4.0 wt %, Ru: 0.2-4.0 wt %, Hf: 0.01-0.2 wt %, and the balance being Ni and unavoidable impurities, a method for producing the same, and turbine blade or turbine vane components are disclosed. The Ni-base superalloy has high creep strength and textural stability under high temperature environment, and is excellent in applicability to turbine blade or turbine vane components of large-sized gas turbines.Type: ApplicationFiled: March 16, 2007Publication date: September 9, 2010Inventors: Yutaka Koizumi, Hiroshi Harada, Tadaharu Yokokawa, Toshiharu Kobayashi
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Publication number: 20100143182Abstract: A Ni-based single crystal superalloy according to the invention has, for example, a composition including: 5.0 to 7.0 wt % of Al, 4.0 to 10.0 wt % of Ta, 1.1 to 4.5 wt % of Mo, 4.0 to 10.0 wt % of W, 3.1 to 8.0 wt % of Re, 0.0 to 2.0 wt % of Hf, 2.5 to 8.5 wt % of Cr, 0.0 to 9.9 wt % of Co, 0.0 to 4.0 wt % of Nb, and 1.0 to 14.0 wt % of Ru in terms of weight ratio; and the remainder including Ni and incidental impurities. In addition, the contents of Cr, Hf and Al are preferably set so as to satisfy the equation OP?108. According to the Ni-based single crystal superalloy of the invention, high creep strength can be maintained and the oxidation resistance can be improved.Type: ApplicationFiled: September 12, 2007Publication date: June 10, 2010Inventors: Akihiro Sato, Hiroshi Harada, Kyoko Kawagishi, Toshiharu Kobayashi, Tadaharu Yokokawa, Yutaka Koizumi, Yasuhiro Aoki, Mikiya Arai, Kazuyoshi Chikugo, Shoju Masaki
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Patent number: 7704332Abstract: A single crystal alloy for high AN2 applications has a composition consisting essentially of from 4.0 to 10 wt % chromium, from 1.0 to 2.5 wt % molybdenum, up to 5.0 wt % tungsten, from 3.0 to 8.0 wt % tantalum, from 5.5 to 6.25 wt % aluminum, from 6.0 to 17 wt % cobalt, up to 0.2 wt % hafnium, from 4.0 to 6.0 wt % rhenium, from 1.0 to 3.0 wt % ruthenium, and the balance nickel. Further, these single crystal alloys have a total tungsten and molybdenum content in the range of from 1.0 to 7.5 wt %, preferably from 2.0 to 7.0 wt %, a total refractory element content in the range of from 9.0 to 24.5 wt %, preferably from 13 to 22 wt %, a ratio of rhenium to a total refractory element content in the range of from 0.16 to 0.67, preferably from 0.20 to 0.45, a density in the range of from 0.300 to 0.325 lb/in3, and a specific creep strength in the range from 106×103 to 124×103 inches.Type: GrantFiled: December 13, 2006Date of Patent: April 27, 2010Assignee: United Technologies CorporationInventors: Venkatarama K. Seetharaman, Alan D. Cetel
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Publication number: 20100092302Abstract: A Ni-based single crystal superalloy which has the following composition: Co: 0.0 wt % or more to 15.0 wt % or less, Cr: 4.1 to 8.0 wt %, Mo: 2.1 to 6.5 wt %, W: 0.0 to 3.9 wt %, Ta: 4.0 to 10.0 wt %, Al: 4.5 to 6.5 wt %, Ti: 0.0 to 1.0 wt %, Hf: 0.00 to 0.5 wt %, Nb: 0.0 to 3.0 wt %, Re: 3.0 to 8.0 wt % and Ru: 0.5 to 6.5 wt % with the remainder including Ni and unavoidable impurities, wherein P1?700 is satisfied in which P1 represents a parameter 1, which is obtained by a formula: P1=137×[W (wt %)]+24×[Cr (wt %)]+46×[Mo (wt %)]?18×[Re (wt %)]. The Ni-based single crystal superalloy has excellent specific creep strength.Type: ApplicationFiled: March 11, 2008Publication date: April 15, 2010Inventors: Akihiro Sato, Kazuyoshi Chikugo, Yasuhiro Aoki, Nobuhito Sekine, Mikiya Arai, Shoju Masaki
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Publication number: 20100086411Abstract: A single crystal alloy for high AN2 applications has a composition consisting essentially of from 4.0 to 10 wt % chromium, from 1.0 to 2.5 wt % molybdenum, up to 5.0 wt % tungsten, from 3.0 to 8.0 wt % tantalum, from 5.5 to 6.25 wt % aluminum, from 6.0 to 17 wt % cobalt, up to 0.2 wt % hafnium, from 4.0 to 6.0 wt % rhenium, from 1.0 to 3.0 wt % ruthenium, and the balance nickel. Further, these single crystal alloys have a total tungsten and molybdenum content in the range of from 1.0 to 7.5 wt %, preferably from 2.0 to 7.0 wt %, a total refractory element content in the range of from 9.0 to 24.5 wt %, preferably from 13 to 22 wt %, a ratio of rhenium to a total refractory element content in the range of from 0.16 to 0.67, preferably from 0.20 to 0.45, a density in the range of from 0.300 to 0.325 lb/in3, and a specific creep strength in the range from 106×103 to 124×103 inches.Type: ApplicationFiled: December 9, 2009Publication date: April 8, 2010Applicant: UNITED TECHNOLOGIES CORPORATIONInventors: Venkatarama K. Seetharaman, Alan D. Cetel
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Patent number: 7662740Abstract: A fuel cell catalyst comprising platinum, chromium, and copper, nickel or a combination thereof. In one or more embodiments, the concentration of platinum is less than 50 atomic percent, and/or the concentration of chromium is less than 30 atomic percent, and/or the concentration of copper, nickel, or a combination thereof is at least 35 atomic percent.Type: GrantFiled: June 3, 2004Date of Patent: February 16, 2010Assignees: Symyx Technologies, Inc., Honda Giken Kogyo Kabushiki KaishaInventors: Konstantinos Chondroudis, Alexander Gorer, Martin Devenney, Ting He, Hiroyuki Oyanagi, Daniel M. Giaquinta, Kenta Urata, Hiroichi Fukuda, Qun Fan, Peter Strasser, Keith James Cendak, Jennifer N. Cendak, legal representative
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Publication number: 20090317287Abstract: Single crystal nickel-based superalloy compositions, single crystal nickel-based superalloy components, and methods of fabricating such components are provided. In an embodiment, by way of example only, a single crystal nickel-based superalloy composition consists essentially of, in weight percent from about 3.8 to about 4.2 percent chromium, from about 10.0 to about 10.5 percent cobalt, from about 1.8 to about 2.2 percent molybdenum, from about 4.8 to about 5.2 percent tungsten, from about 5.8 to about 6.2 percent rhenium, from about 5.5 to about 5.8 percent aluminum, from about 5.8 to about 6.2 percent tantalum, from about 3.8 to about 4.2 percent ruthenium, from about 0.13 to about 0.17 percent hafnium, and a balance of nickel.Type: ApplicationFiled: June 24, 2008Publication date: December 24, 2009Applicant: HONEYWELL INTERNATIONAL INC.Inventor: Yiping Hu
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Publication number: 20090175756Abstract: A noble alloy comprising at least 25 wt. % palladium; from 15 to 30 wt. % chromium; at least 5 wt. % molybdenum and/or tungsten; and a principal balance of nickel is provided. Dental products and methods of manufacturing dental products using such a nickel-chromium base noble alloy are also provided.Type: ApplicationFiled: October 3, 2008Publication date: July 9, 2009Inventors: Arun Prasad, Paul J. Cascone
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Patent number: 7473326Abstract: A Ni-base directionally solidified superalloy and a Ni-base single-crystal superalloy, which have superior creep strength at a high temperature, consists essentially of from 5.0 percent by weight to 7.0 percent by weight of Al, from 4.0 percent by weight to 16.0 percent by weight of Ta+Nb+Ti, from 1.0 percent by weight to 4.5 percent by weight of Mo, from 4.0 percent by weight to 8.0 percent by weight of W, from 3.0 percent by weight to 8.0 percent by weight of Re, 2.0 percent by weight or less of Hf, 10.0 percent by weight or less of Cr, 15.0 percent by weight or less of Co, from 1.0 percent by weight to 4.0 percent by weight of Ru, 0.2 percent by weight or less of C, 0.03 percent by weight or less of B, and Ni and inescapable impurities as a balance. The superalloys can be used for a turbine blade, a turbine vane and the like of a jet engine, an industrial gas turbine and the like.Type: GrantFiled: March 27, 2003Date of Patent: January 6, 2009Assignees: National Institute for Materials Science, Ishikawajima-Harima Heavy Industries Co., Ltd.Inventors: Toshiharu Kobayashi, Yutaka Koizumi, Tadaharu Yokokawa, Hiroshi Harada, Yasuhiro Aoki, Shouju Masaki
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Publication number: 20080101981Abstract: The invention concerns a Ni based alloy suitable for single crystalline, directionally solidified or polycrystalline components to be used at high temperatures. The alloy is a ??/? alloy and consists of different alloying elements within defined ranges. Among other defined ranges of elements, the alloy contains Pd in a significant amount sufficient to provide the alloy with an improved resistance against hydrogen embrittlement. The invention also concerns a component designed for use as a component in a high temperature environment. Furthermore, the invention concerns a gas turbine arrangement. Moreover, the invention concerns the use of Pd for providing an alloy with improved resistance against hydrogen embrittlement.Type: ApplicationFiled: December 21, 2005Publication date: May 1, 2008Inventors: Douglas James Arrell, Magnus Hasselqvist
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Patent number: 7338259Abstract: A high modulus component, such as an aircraft engine turbine blade, is formed from a base metal that has a high modulus crystallographic orientation that is aligned with the primary, i.e. radial, direction of the turbine blade. The base metal is Ni, Fe, Ti, Co, Al, Nb, or Mo based alloy. Alignment of a high modulus direction of the base metal with the primary direction provides enhanced high cycle fatigue life.Type: GrantFiled: March 2, 2004Date of Patent: March 4, 2008Assignee: United Technologies CorporationInventors: Dilip M. Shah, Alan D. Cetel, Alan W. Stoner, William P. Allen
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Patent number: 7316850Abstract: There is provided a method for depositing a modified MCrAlY coating on a turbine blade tip. The method utilizes laser deposition techniques to provide a metallurgical bond between a turbine blade substrate, such as a superalloy substrate, and the modified MCrAlY composition. Further the modified MCrAlY coating has sufficient thickness such that a post-welding grinding operation to size the turbine blade to a desired dimension will not remove the modified MCrAlY coating entirely. The modified MCrAlY coating thus remains on the finished turbine blade tip after grinding.Type: GrantFiled: March 2, 2004Date of Patent: January 8, 2008Assignee: Honeywell International Inc.Inventors: Yiping Hu, William F. Hehmann
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Patent number: 7306682Abstract: An object of this invention is to provide a single-crystal nickel-based superalloy having high creep rupture strength at high temperatures and excel at corrosion resistance and oxidation resistance at high temperatures. Single-crystal nickel-based superalloys with high temperature strength, hot corrosion resistance and oxidation resistance comprising by weight, 3.0 to 7.0% Cr, 9.5 to 15.0% Co, 4.5 to 8.0% W, 3.3 to 6.0% Re, 4.0 to 8.0% Ta, 0.8 to 2.0% Ti, 4.5 to 6.5% Al, 0.01 to 0.2% Hf, less than 0.5% Mo, 0.01% or less C, 0.005% or less B, 0.01% or less Zr, 0.005% or less O, 0.005% or less N, and balance substantially Ni.Type: GrantFiled: August 10, 2004Date of Patent: December 11, 2007Assignees: Hitachi, Ltd., The Kansai Electric Power Co., Inc., Masahiko Morinaga, Yoshinori MurataInventors: Akira Yoshinari, Ryokichi Hashizume, Masahiko Morinaga, Yoshinori Murata
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Publication number: 20070272332Abstract: A nickel base repair alloy comprises a blend of about 40 to 60 wt % of a first nickel based braze alloy containing boron, about 15 to 35 wt % of a first nickel based filler material, and the remainder consisting of a blend of a second nickel based filler material and a low melting eutectic braze nickel based alloy.Type: ApplicationFiled: May 24, 2006Publication date: November 29, 2007Inventors: Beth Kwiatkowki Abriles, Norman Pietruska, John H. Hyde
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Patent number: 7273662Abstract: An alloy including a Pt-group metal, Ni and Al in relative concentration to provide a ?-Ni+??-Ni3Al phase constitution, and a coating including the alloy.Type: GrantFiled: May 16, 2003Date of Patent: September 25, 2007Assignee: Iowa State University Research Foundation, Inc.Inventors: Brian Gleeson, Daniel Sordelet, Wen Wang
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Patent number: 7169241Abstract: A Ni-based alloy hardened with the ?? phase, which is able to exhibit not only superior strength at high temperatures, but also excellent hot corrosion resistance and oxidation resistance at high temperatures in spite of containing no Re or reducing the amount of Re. The Ni-based superalloy contains, by weight, C: 0.01 to 0.5%, B: 0.01 to 0.04%, Hf: 0.1 to 2.5%, Co: 0.8 to 15%, Ta: more than 0% but less than 8.5%, Cr: 1.5 to 16%, Mo: more than 0% but less than 1.0%, W: 5 to 14%, Ti: 0.1 to 4.75%, Al: 2.5 to 7%, Nb: more than 0% but less than 4%, V: 0 to less than 1.0%, Zr: 0 to less than 0.1%, Re: 0 to less than 9%, at least one of platinum group elements: 0 to less than 0.5% in total, at least one of rare earth elements: 0 to less than 0.1% in total, and the rest being Ni except for unavoidable impurities.Type: GrantFiled: March 19, 2004Date of Patent: January 30, 2007Assignee: Hitachi, Ltd.Inventors: Hideki Tamaki, Akira Yoshinari, Akira Okayama, Tsuyoshi Takano, Hiroyuki Doi
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Patent number: 7115175Abstract: The present invention relates to an improved single crystal nickel base superalloy and a process for making same. The single crystal nickel base superalloy has a composition comprising 3 to 12 wt % chromium, up to 3 wt % molybdenum, 3 to 10 wt % tungsten, up to 5 wt % rhenium, 6 to 12 wt % tantalum, 4 to 7 wt % aluminum, up to 15 wt % cobalt, up to 0.05 wt % carbon, up to 0.02 wt % boron, up to 0.1 wt % zirconium, up to 0.8 wt % hafnium, up to 2.0 wt % niobium, up to 1.0 wt % vanadium, up to 0.7 wt % titanium, up to 10 wt % of at least one element selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium, platinum, and mixtures thereof, and the balance essentially nickel. The single crystal nickel base superalloy has a microstructure which is pore-free and eutectic ?–?? free and which has a gamma prime morphology with a bimodal ?? distribution.Type: GrantFiled: July 19, 2004Date of Patent: October 3, 2006Assignee: United Technologies CorporationInventors: Daniel P. DeLuca, Charles M. Biondo
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Patent number: 6966956Abstract: A Ni-based single crystal super alloy capable of improving strength by preventing precipitation of a TCP phase at high temperatures may be obtained by a Ni-based single crystal super alloy having a composition consisting of 5.0-7.0 wt % Al, 4.0-8.0 wt % Ta, 2.9-4.5 wt % Mo, 4.0-8.0 wt % W, 3.0-6.0 wt % Re, 0.01-0.50 wt % Hf, 2.0-5.0 wt % Cr, 0.1-15.0 wt % Co and 1.0-4.0 wt % Ru in terms of its weight ratio, with the remainder consisting of Ni and unavoidable impurities. Preferably, the composition of Co in the Ni-based single crystal super alloy is limited to 0.1-9.5 wt %.Type: GrantFiled: July 26, 2004Date of Patent: November 22, 2005Assignees: National Institute for Materials Science, Ishikawajima-Harima Heavy Industries Co., Ltd.Inventors: Yutaka Koizumi, Toshiharu Kobayashi, Tadaharu Yokokawa, Hiroshi Harada, Yasuhiro Aoki, Mikiya Arai, Shoju Masaki, Ryoji Kakiuchi, Kazuyoshi Chikugo
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Patent number: 6905559Abstract: A composition of matter is about 1 to about 3 percent rhenium, from about 6 to about 9 percent aluminum, from 0 to about 0.5 percent titanium, from about 4 to about 6 percent tantalum, from about 12.5 to about 15 percent chromium, from about 3 to about 10 percent cobalt, from about 2 to about 5 percent tungsten, from 0 to about 0.2 percent hafnium, from 0 to about 1 percent silicon, from 0 to about 0.25 percent molybdenum, from 0 to about 0.25 percent niobium, balance nickel and minor elements. The composition is preferably made into a substantially single crystal article, such as a component of a gas turbine engine.Type: GrantFiled: December 6, 2002Date of Patent: June 14, 2005Assignee: General Electric CompanyInventors: Kevin Swayne O'Hara, William Scott Walston, Charles Gitahi Mukira, Melvin Robert Jackson
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Publication number: 20040213693Abstract: A single crystal nickel base superalloy consists essentially of, in weight %, about 6.4% to about 6.8% Cr, about 9.3% to about 10.0% Co, above 6.7% to about 8.5% Ta, about 5.45% to about 5.75% Al, about 6.2% to about 6.6% W, about 0.5% to about 0.7% Mo, about 0.8% to about 1.2% Ti, about 2.8% to about 3.2% Re, up to about 0.12% Hf, about 0.01% to about 0.08% by weight C, up to about 0.10% B, and balance Ni and incidental impurities. The superalloy provides improved alloy cleanliness and castability while providing improved high temperature mechanical properties such as stress rupture life.Type: ApplicationFiled: April 28, 2003Publication date: October 28, 2004Inventors: John Corrigan, Michael G. Launsbach, John R. Mihalisin