Molybdenum Or Tungsten Containing Patents (Class 420/453)
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Patent number: 9975208Abstract: An alloy for cladding cast iron is disclosed. The alloy may include on a weight basis, about 6.2% to about 9.3% of chromium (Cr), about 3.0% to about 4.5% of iron (Fe), about 1.4% to about 2.15% of silicon (Si), about 0.5% to about 0.8% of boron (B), about 0.1% of carbon (C), and a balance of nickel (Ni) and incidental impurities.Type: GrantFiled: December 15, 2016Date of Patent: May 22, 2018Assignee: Caterpillar Inc.Inventors: Tomasz J. Chojnacki, Deven John Efta, Mark D. Veliz
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Patent number: 9638075Abstract: A nickel-based alloy includes, in weight percent, carbon from about 0.7 to about 2%; manganese up to about 1.5%; silicon up to about 1.5%; chromium from about 25 to about 36%; molybdenum from about 5 to about 12%; tungsten from about 12 to about 20%; cobalt up to about 1.5%; iron from about 3.5 to about 10%; nickel from about 20 to about 55%; and incidental impurities. The alloy is suitable for use in elevated temperature applications such as in valve seta inserts for internal combustion engines.Type: GrantFiled: December 2, 2013Date of Patent: May 2, 2017Assignee: L.E. Jones CompanyInventors: Cong Yue Qiao, Lawrence A. Bowsher, Daniel E. Ward, Scott A. Smith
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Patent number: 9272368Abstract: The present disclosure provides an improved welding process for joining two components of which at least one comprises a brass alloy. In one exemplary embodiment, an intermediate part that includes a metal material different from a brass alloy may be arranged between the components such that it is in contact with the components in marginal regions. The intermediate part may then be heated during the welding process such that it enters into a connection having material continuity with the components in the marginal regions.Type: GrantFiled: July 18, 2013Date of Patent: March 1, 2016Assignee: Emerson Climate Technologies GmbHInventor: Christian Fuhrmann
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Patent number: 8858875Abstract: A Ni based alloy material consists of by mass percent, C?0.03%, Si: 0.01 to 0.5%, Mn: 0.01 to 1.0%, P?0.03%, S?0.01%, Cr: not less than 20% to less than 30%, Ni: more than 40% to not more than 50%, Cu: more than 2.0% to not more than 5.0%, Mo: 4.0 to 10%, Al: 0.005 to 0.5%, W: 0.1 to 10%, N: more than 0.10% to not more than 0.35%, optionally one or more elements selected from Ca?0.01% and Mg?0.01%, with the balance being Fe and impurities, and the formula of “0.5Cu+Mo?6.5” is satisfied. The material has a surface hardness of a Vickers hardness of not less than 350 at 500° C., a corrosion resistance equivalent to that of Ni based alloys having high Mo contents, and excellent erosion resistance in a severe environment.Type: GrantFiled: March 16, 2012Date of Patent: October 14, 2014Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Masaki Ueyama, Masaaki Terunuma
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Publication number: 20140238551Abstract: The disclosure is directed to Ni—P—B alloys bearing Mn and optionally Cr and Mo that are capable of forming a metallic glass, and more particularly metallic glass rods with diameters at least 1 mm and as large as 5 mm or larger. The disclosure is further directed to Ni—Mn—Cr—Mo—P—B alloys capable of demonstrating a good combination of glass forming ability, strength, toughness, bending ductility, and corrosion resistance.Type: ApplicationFiled: February 26, 2014Publication date: August 28, 2014Applicant: Glassimetal Technology, Inc.Inventors: Jong Hyun Na, Michael Floyd, Marios D. Demetriou, William L. Johnson, Glenn Garrett, Maximilien Launey, Danielle Duggins
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Patent number: 8545643Abstract: An alloy designed for use in gas turbine engines which has high strength and a low coefficient of thermal expansion is disclosed. The alloy may contain in weight percent 7% to 9% chromium, 21% to 24% molybdenum, greater than 5% tungsten, up to 3% iron, with a balance being nickel and impurities. The alloy must further satisfy the following compositional relationship: 31.95<R<33.45, where the R value is defined by the equation: R=2.66Al+0.19Co+0.84Cr?0.16Cu+0.39Fe+0.60Mn+Mo+0.69Nb+2.16Si+0.47Ta+1.36Ti+1.07V+0.40W The alloy has better hardness after being age-hardened at 1400° F. (760° C.) if tungsten is present from greater than 5% up to 10% and a preferred density if the alloy contains greater than 5% up to 7% tungsten.Type: GrantFiled: February 17, 2012Date of Patent: October 1, 2013Assignee: Haynes International, Inc.Inventors: Lee Pike, S. Krishna Srivastava
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Publication number: 20130224069Abstract: Provided is a hydrochloric acid corrosion resistant alloy For brazing that is provided with corrosion resistance against hydrochloric acid, and when brazing various types of stainless steel, can be used for brazing at practical temperatures (1150° C. or less), and has good joint strength and brazeability to the substrate. The hydrochloric acid corrosion resistant alloy of the present invention contains, in mass percent, 6.0-18.0% Mo, 10.0-25.0% Cr, 0.5-5.0% Si, and 4.5-8.0% P, with the remainder being 40.0-73.0% Ni and unavoidable impurities, and the total of Si and P being 6.5-10.5%. In this case, the alloy may contain 12.0% or less of Cu, 20.0% or less of Co, 15.0% or less of Fe, 8.0% or less of W, 5.0% or less of Mn, and 0.5% or less of the total of C, B, Al, Ti, and Nb.Type: ApplicationFiled: May 26, 2011Publication date: August 29, 2013Applicant: FUKUDA METAL FOIL & POWDER CO., LTDInventors: Katsunori Otobe, Shinichi Nishimura
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Patent number: 8501086Abstract: A Ni based alloy, which consists of by mass percent, C?0.03%, Si: 0.01 to 0.5%, Mn: 0.01 to 1.0%, P?0.03%, S?0.01%, Cr: not less than 20% to less than 30%, Ni: more than 40% to not more than 60%, Cu: more than 2% to not more than 5.0%, Mo: 4.0 to 10%, Al: 0.005 to 0.5% and N: more than 0.02% to not more than 0.3%, with the balance being Fe and impurities, and the expression of “0.5 Cu+Mo?6.5” is satisfied, has excellent corrosion resistance equivalent to that of Ni based alloys having high Mo contents, such as Hastelloy C22 and Hastelloy C276, in severe corrosive environments containing reducing acids, such as hydrochloric acid and sulfuric acid, together with excellent workability. Therefore, it can be suitably used as a low-cost material for various kinds of structural members.Type: GrantFiled: September 23, 2010Date of Patent: August 6, 2013Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Masaki Ueyama, Masaaki Terunuma, Satoshi Matsumoto
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Patent number: 8414828Abstract: A material is presented that exhibits excellent corrosion resistance to supercritical ammonia and is suitable for a supercritical ammonia reactor. An Ni-based corrosion resistant alloy includes from 15% or more to 50% or less by mass of Cr and any one or both of Mo and W, wherein a [(content of Mo)+0.5×(content of W)] is from 1.5% or more to 8.5% or less by mass, a value of 1.8×[% content of Cr]/{[% content of Mo]+0.5×[% content of W]} is from 3.0 or more to 70.0 or less and the balance is Ni and an unavoidable impurity. The alloy may be used to configure a supercritical ammonia reactor or the material is coated on a surface that contacts with a supercritical ammonia fluid. The alloy exhibits excellent corrosion resistance to supercritical ammonia and a mineralizer added the supercritical ammonia. The safety and reliability of an apparatus can be improved, the producing cost can be reduced, the apparatus lifetime can be extended and the running cost can be reduced.Type: GrantFiled: August 22, 2006Date of Patent: April 9, 2013Assignees: Furuya Metal Co., Ltd., Mitsubishi Chemical Corporation, Tokyo Denpa Co., Ltd., Tsuguo Fukuda, The Japan Steel Works, Ltd.Inventors: Yoshihiko Yamamura, Shinya Sato, Shinichi Nishiya
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Patent number: 8394210Abstract: A nickel-base alloy having favorable toughness and thermal fatigue resistance comprises, in weight percentages based on total alloy weight: 9 to 12 chromium; 25 to 35 iron; 1 to 3 molybdenum; 3.0 to 5.5 niobium; 0.2 to 2.0 aluminum; 0.3 to 3.0 titanium; less than 0.10 carbon; no more than 0.01 boron; nickel; and incidental impurities. Also disclosed are die casting dies, other tooling, and other articles of manufacture made from or comprising the nickel-base alloy.Type: GrantFiled: May 5, 2011Date of Patent: March 12, 2013Assignee: ATI Properties, Inc.Inventors: Wei-Di Cao, Richard L. Kennedy, Michael M. Antony, John W. Smythe
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Patent number: 8313591Abstract: An austenitic heat resistant alloy, which contains, by mass percent, C?0.15%, Si?2%, Mn?3%, Ni: 40 to 80%, Cr: 15 to 40%, W and Mo: 1 to 15% in total content, Ti?3%, Al?3%, N?0.03%, O?0.03%, with the balance being Fe and impurities, and among the impurities P?0.04%, S?0.03%, Sn?0.1%, As?0.01%, Zn?0.01%, Pb?0.01% and Sb?0.01%, and satisfies the conditions [P1=S+{(P+Sn)/2}+{(As+Zn+Pb+Sb)/5}?0.050], [0.2?P2=Ti+2Al?7.5?10×P1], [P2?9.0?100×O] and [N?0.002×P2+0.019] can prevent both the liquation crack in the HAZ and the brittle crack in the HAZ and also can prevent defects due to welding fabricability, which occur during welding fabrication, and moreover has excellent creep strength at high temperatures. Therefore, the alloy can be used suitably as a material for constructing high temperature machines and equipment, such as power generating boilers, plants for the chemical industry and so on.Type: GrantFiled: December 24, 2009Date of Patent: November 20, 2012Assignee: Sumitomo Metal Industries, Ltd.Inventors: Hiroyuki Hirata, Atsuro Iseda, Hirokazu Okada, Hiroyuki Semba, Kaori Kawano, Osamu Miyahara
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Publication number: 20120267420Abstract: A class of nickel based alloys having a fine grain structure resistant to stress corrosion cracking, and methods of alloy design to produce further alloys within the class are presented. The alloys act as suitable welding materials in similar applications to that of Alloy 622. The fine-grained structure of these novel alloys may also be advantageous for other reasons as well such as wear, impact, abrasion, corrosion, etc. These alloys have similar phases to Alloy 622 in that they are composed primarily of austenitic nickel, however the phase morphology is a much finer grained structure opposed to the long dendritic grains common to Alloy 622 when it is subject to cooling rates from a liquid state inherent to the welding process.Type: ApplicationFiled: March 23, 2012Publication date: October 25, 2012Inventor: Justin Lee Cheney
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Publication number: 20120213660Abstract: An alloy designed for use in gas turbine engines which has high strength and a low coefficient of thermal expansion is disclosed. The alloy may contain in weight percent 7% to 9% chromium, 21% to 24% molybdenum, greater than 5% tungsten, up to 3% iron, with a balance being nickel and impurities. The alloy must further satisfy the following compositional relationship: 31.95<R<33.45, where the R value is defined by the equation: R=2.66Al+0.19Co+0.84Cr?0.16Cu+0.39Fe+0.60Mn+Mo+0.69Nb+2.16Si+0.47Ta+1.36Ti+1.07V+0.40W The alloy has better hardness after being age-hardened at 1400° F. (760° C.) if tungsten is present from greater than 5% up to 10% and a preferred density if the alloy contains greater than 5% up to 7% tungsten.Type: ApplicationFiled: February 17, 2012Publication date: August 23, 2012Applicant: HAYNES INTERNATIONAL, INC.Inventors: Lee Pike, S. Krishna Srivastava
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Patent number: 8187725Abstract: A nickel, chromium, iron alloy and method for use in producing weld deposits and weldments formed therefrom. The alloy comprises, in weight percent, about 28.5 to 31.0% chromium; about 0 to 16% iron; less than about 1.0% manganese; about 2.1 to 4.0% niobium plus tantalum; 1.0 to 6.5% molybdenum; less than 0.50% silicon; 0.01 to 0.35% titanium; 0 to 0.25% aluminum; less than 1.0% copper; less than 1.0% tungsten; less than 0.5% cobalt; less than about 0.10% zirconium; less than about 0.01% sulfur; less than 0.01% boron; less than 0.03% carbon; less than about 0.02% phosphorous; 0.002 to 0.015% magnesium plus calcium; and balance nickel and incidental impurities. The method includes the steps of forming a welding electrode from the above alloy composition and melting the electrode to form a weld deposit. A preferred weldment may be in the form of a tubesheet of a nuclear reactor.Type: GrantFiled: July 19, 2007Date of Patent: May 29, 2012Assignees: Huntington Alloys Corporation, Areva NP Inc.Inventors: Samuel D. Kiser, Brian A. Baker, David E. Waskey
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Publication number: 20120058004Abstract: Providing a metal mold repair method and a metal mold repair paste agent which are capable of repairing cracks with simple work. A repair paste agent containing components that become an alloy is directly applied to a surface of a metal mold having a crack so as to cover the crack part, subsequently a surface of the repair paste agent is coated with an oxidation inhibitor and the repair paste agent is made to penetrate the inside of the crack by heating and becomes an alloy, thereby filling up the crack.Type: ApplicationFiled: March 3, 2011Publication date: March 8, 2012Inventors: Michiharu HASEGAWA, Noriyuki Miyazaki, Masafumi Nakamura, Naoji Yamamoto, Kazuo Ueda
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Patent number: 7985304Abstract: A nickel-base alloy having favorable toughness and thermal fatigue resistance comprises, in weight percentages based on total alloy weight: 9 to 20 chromium; 25 to 35 iron; 1 to 3 molybdenum; 3.0 to 5.5 niobium; 0.2 to 2.0 aluminum; 0.3 to 3.0 titanium; less than 0.10 carbon; no more than 0.01 boron; nickel; and incidental impurities. Also disclosed are die casting dies, other tooling, and other articles of manufacture made from or comprising the nickel-base alloy.Type: GrantFiled: April 19, 2007Date of Patent: July 26, 2011Assignee: ATI Properties, Inc.Inventors: Wei-Di Cao, Richard L. Kennedy, Michael M. Antony, John W. Smythe
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Patent number: 7959854Abstract: A heat resistant alloy comprising, in % by weight, over 0.6% to not more than 0.9% of C, up to 2.5% of Si, up to 3.0% of Mn, 20 to 28% of Cr, 8 to 55% of Ni, 0.01 to 0.8% of Ti and 0.05 to 1.5% of Nb, the balance being Fe and inevitable impurities, the value of (Ti+Nb)/C being 0.12 to 0.29 in atomic % ratio. When the alloy further contains up to 0.5% of Zr, the value of (Ti+Nb+Zr)/C is 0.12 to 0.29 in atomic % ratio. When the alloy is heated at a temperature of at least about 800 degrees C., a fine Ti—Nb—Cr carbide or Ti—Nb—Zr—Cr carbide precipitates within grains to thereby retard creep deformation and give an improved creep rupture strength. The alloy is therefore suitable as a material for hydrogen production reforming tubes.Type: GrantFiled: October 30, 2006Date of Patent: June 14, 2011Assignee: Kubota CorporationInventors: Makoto Takahashi, Kunihide Hashimoto, Makoto Hineno
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Patent number: 7922969Abstract: The corrosion-resistant nickel-base alloy combines thermal stability with corrosion resistance and mechanical strength. The alloy contains balanced proportions of nickel, molybdenum, chromium, and iron with an effective amount of yttrium to stabilize grain boundaries against unwanted reactions, which might degrade corrosion resistance, and an effective amount of boron to maintain an acceptable level of ductility. The alloy may contain minor amounts of additives or impurities, such as silicon, manganese, and aluminum. The alloy may contain between about 25-45% molybdenum, 2-6% chromium, 2-4% iron, 0.01-0.03% boron, 0.005-0.015% yttrium, and up to a maximum of 1% manganese, silicon, and aluminum, respectively, by weight, the balance being nickel. It is preferred that the combined ratio of molybdenum, chromium, and iron to nickel be in the range of about 25% to 45%.Type: GrantFiled: June 28, 2007Date of Patent: April 12, 2011Assignee: King Fahd University of Petroleum and MineralsInventor: Hani M. Tawancy
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Publication number: 20110058977Abstract: A Ni based cast alloy consisting essentially of C: 0.01 to 0.2% by weight, Si: 0.5 to 4.0% by weight, Cr: 14 to 22% by weight, Mo+W: 4.0 to 10% by weight, B: 0.001 to 0.02% by weight, Co: up to 10% by weight, Al: up to 0.5% by weight, Ti: up to 0.5% by weight, Nb: up to 5.0% by weight, Fe: up to 10% by weight, the balance being Ni and incidental impurities, wherein a ?? phase precipitates in a matrix phase thereof.Type: ApplicationFiled: August 27, 2010Publication date: March 10, 2011Inventors: Jun Sato, Shinya Imano, Hiroyuki Doi
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Patent number: 7879460Abstract: Disclosed is a welding wire for joining cast iron and stainless steel, having a composition of 0.03 wt % or less of C, 2.0˜3.0 wt % of Si, 12.0˜14.0 wt % of Mn, 7.0˜9.0 wt % of Cr, 45.0˜47.0 wt % of Ni, 0.5˜0.8 wt % of Nb, and 2.0˜3.0 wt % of Mo, with a balance of Fe. Using the welding wire, a weld zone which has no hot cracks and is sound and good can be obtained.Type: GrantFiled: November 25, 2008Date of Patent: February 1, 2011Assignee: Hyundai Motor CompanyInventor: Jae Gyu Jung
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Publication number: 20100272597Abstract: Disclosed herein is a nickel based alloy comprising, in weight percentage: carbon from about 0.5 to about 1.5; chromium from about 25 to about 35; tungsten from about 12 to about 18; iron from about 3.5 to about 8.5; molybdenum from about 1 to about 8; manganese up to about 0.50; silicon up to about 1.0; and the balance nickel and incidental impurities. The alloy is suitable for valve seat insert applications in internal combustion engines.Type: ApplicationFiled: April 24, 2009Publication date: October 28, 2010Applicant: L. E. Jones CompanyInventors: Cong Yue Qiao, Daniel W. Bancroft
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Patent number: 7785532Abstract: A nickel-molybdenum-chromium alloy, capable of withstanding both strong oxidizing and strong reducing 2.5% hydrochloric acid solutions at 121° C., contains 20.0 to 23.5 wt. % molybdenum and 13.0 to 16.5 wt. % chromium with the balance being nickel plus impurities and residuals of elements used for control of oxygen and sulfur.Type: GrantFiled: May 14, 2007Date of Patent: August 31, 2010Assignee: Haynes International, Inc.Inventor: Paul Crook
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Patent number: 7731895Abstract: An austenitic stainless steel improved in creep strength, creep ductility, weldability and also hot workability. The steel, consisting of, by mass %, C: 0.05-0.15%, Si: not more than 2%, Mn: 0.1-3%, P: 0.05-0.30%, S: not more than 0.03%, Cr: 15-28%, Ni: 8-55%, Cu: 0-3.0%, Ti: 0.05-0.6%, REM: 0.001-0.5%, sol. Al: 0.001-0.1%, N: not more than 0.03%, and the balance being Fe and incidental impurities. This steel may contain one or more of Mo, W, B, Nb, V, Co, Zr, Hf, Ta, Mg and Ca. It is preferable that REM is Nd.Type: GrantFiled: October 3, 2007Date of Patent: June 8, 2010Assignee: Sumitomo Metal Industries, Ltd.Inventors: Hirokazu Okada, Masaaki Igarashi, Kazuhiro Ogawa, Yasutaka Noguchi
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Patent number: 7662740Abstract: A fuel cell catalyst comprising platinum, chromium, and copper, nickel or a combination thereof. In one or more embodiments, the concentration of platinum is less than 50 atomic percent, and/or the concentration of chromium is less than 30 atomic percent, and/or the concentration of copper, nickel, or a combination thereof is at least 35 atomic percent.Type: GrantFiled: June 3, 2004Date of Patent: February 16, 2010Assignees: Symyx Technologies, Inc., Honda Giken Kogyo Kabushiki KaishaInventors: Konstantinos Chondroudis, Alexander Gorer, Martin Devenney, Ting He, Hiroyuki Oyanagi, Daniel M. Giaquinta, Kenta Urata, Hiroichi Fukuda, Qun Fan, Peter Strasser, Keith James Cendak, Jennifer N. Cendak, legal representative
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Publication number: 20100028716Abstract: Brazing alloy with a composition consisting essentially of FeaNiRestCrbMocCudSieBfPg, wherein 0 atomic %<=a<=50 atomic %; 5 atomic %<=b<=18 atomic %; 0.2 atomic %<c<=3 atomic %; 4 atomic %<=e<=15 atomic %; 4 atomic %<=f<=15 atomic %; 0 atomic %<=g<=6 atomic %; rest Ni, and wherein if 0 atomic %<a<=50 atomic %; then 0.5 atomic %<=d<3 atomic % and if a=0, then 0.5 atomic %<=d<=5 atomic %.Type: ApplicationFiled: August 1, 2007Publication date: February 4, 2010Inventors: Dieter Nuetzel, Thomas Hartmann
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Publication number: 20090280024Abstract: The invention intends to provide a material that exhibits excellent corrosion resistance to supercritical ammonia and is suitable for a supercritical ammonia reactor. An Ni-based corrosion resistant alloy includes from 15% or more to 50% or less by mass of Cr and any one or both of Mo and W, wherein a [(content of Mo)+0.5×(content of W)] is from 1.5% or more to 8.5% or less by mass, a value of 1.8×[% content of Cr]/{[% content of Mo]+0.5×[% content of W]} is from 3.0 or more to 70.0 or less and the balance is Ni and an unavoidable impurity. Preferably, content of Fe is less than 3% by mass, and content of C is less than 0.05% by mass. The alloy is used to configure a supercritical ammonia reactor or the material is coated on a surface that contacts with a supercritical ammonia fluid. The alloy exhibits excellent corrosion resistance to supercritical ammonia and a mineralizer added the supercritical ammonia.Type: ApplicationFiled: August 22, 2006Publication date: November 12, 2009Applicant: Solvolthermal Crystal Growth Technology Research AllianceInventors: Yoshihiko Yamamura, Shinya Sato, Shinichi Nishiya
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Patent number: 7562807Abstract: Accordingly, the present invention provides a weld filler composition for joining different alloy steel pieces with substantially different chromium content, such as joining low alloy ferritic steel to high alloy ferritic steel, low alloy ferritic steel to austenitic stainless steel, or high alloy ferritic steel to austenitic stainless steel, and a method using the same. In one embodiment, the present invention provides a composition for a weld filler comprising nickel, iron, and chromium, which collectively comprise at least 50% by weight of the weld filler; niobium, carbon, manganese, molybdenum, and silicon, which collectively comprise no more than 50% by weight of the weld filler, and a niobium to carbon ratio of approximately 20 or less.Type: GrantFiled: May 5, 2004Date of Patent: July 21, 2009Assignee: Electric Power Research InstituteInventors: Kent K. Coleman, David Wayne Gandy, Ramaswamy Viswanathan, William F. Newell, Jr.
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Patent number: 7498087Abstract: Vapor turbine operating with geothermal vapors containing corrosive agents such as chlorides and/or sulfides in particular. The turbine comprises a series of rotor blades made of a nickel alloy containing a quantity of nickel ranging from 55% to 59% by weight to avoid the washing of the geothermal vapors, maintaining a high useful life of the series of rotor blades and vapor turbine.Type: GrantFiled: December 20, 2005Date of Patent: March 3, 2009Assignee: Nuovo Pignone S.p.A.Inventors: Carlo Cortese, Paolo Bendinelli, Marco De Iaco, Lorenzo Cosi, Marco Anselmi
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Publication number: 20080206089Abstract: The present application relates to an alloy for use at high temperature. The invention is characterized in that the alloy consists principally of Ni, Cr and Fe and in that the alloy has a principal composition such that the levels of the elements Fe, Si, C, Nb and Mo lie within the following intervals, given in percentage by weight: Fe 5-13 Si 1-3 C <0.1 Nb <0.2 Mo <1.0 and in that Ni comprises the balance, while its level does not exceed 69% and in that the level of Cr is greater than Cr=15% and in that it is less than the lower of the two values Cr=5*Si?2.5*Fe +42.Type: ApplicationFiled: June 16, 2006Publication date: August 28, 2008Applicant: SANDVIK INTELLECTUAL PROPERTY ABInventor: Rikard Norling
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Patent number: 7118636Abstract: An Fe—Ni—Cr alloy formulated to contain a strengthening phase that is able to maintain a fine grain structure during forging and high temperature processing of the alloy. The alloy contains a sufficient amount of titanium, zirconium, carbon and nitrogen so that fine titanium and zirconium carbonitride precipitates formed thereby are near their solubility limit in the alloy when molten. In the production of an article from such an alloy by thermomechanical processing, a dispersion of the fine titanium and zirconium carbonitride precipitates form during solidification of the melt and remain present during subsequent elevated processing steps to prohibit austenitic grain growth.Type: GrantFiled: April 14, 2003Date of Patent: October 10, 2006Assignee: General Electric CompanyInventors: Jianqiang Chen, Jon Conrad Schaeffer, Anjilivelil Kuruvilla
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Patent number: 6863990Abstract: Enhancing wear and corrosion resistance of an industrial component by depositing a Ni-based alloy coating having a thickness of at least about 50 microns onto a surface of the industrial component by high velocity oxyfuel propulsion of a Ni-based alloy powder containing a) Cr, b) from about 15 to about 25 wt % Mo, c) no more than about 1 wt % Fe, and d) no more than about 1 wt % elements having an atomic number greater than 42. A Ni-based alloy powder for HVOF deposition containing a) Cr, b) from about 15 to about 25 wt % Mo, c) no more than about 1 wt % Fe, and d) no more than about 1 wt % elements having an atomic number greater than 42. A Ni-based coating on an industrial component having enhanced corrosion and wear resistance.Type: GrantFiled: May 2, 2003Date of Patent: March 8, 2005Assignee: Deloro Stellite Holdings CorporationInventors: James B. C. Wu, Matthew X. Yao
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Patent number: 6818077Abstract: A nickel-based superalloy containing 12.0 to 16.0% by weight of Cr, 4.0 to 9.0% by weight of Co, 3.4 to 4.6% by weight of Al, 0.5 to 1.6% by weight of Nb, 0.05 to 0.16% by weight of C, 0.005 to 0.025% by weight of B, and at least one of Ti, Ta and Mo. Amounts of Ti, Ta and Mo are ones calculated by the equations (1) and (2), wherein TiEq is 4.0 to 6.0 and MoEq is 5.0 to 8.0. TiEq=Ti % by weight+0.5153×Nb % by weight+0.2647×Ta % by weight (1) MoEq−Mo % by weight+0.5217×W % by weight+0.5303×Ta % by weight+1.Type: GrantFiled: May 6, 2003Date of Patent: November 16, 2004Assignee: Hitachi, Ltd.Inventors: Akira Yoshinari, Hideki Tamaki, Hiroyuki Doi
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Patent number: 6782943Abstract: A fouling reducing device for the tubes of a tubular heat exchanger of the type that contains at least one turbulence-generating element lodged inside one of the tubes of the exchanger. The fouling reducing device is a turbulence-generating element made of a metallic alloy with a nickel content that is greater than 50% by weight, and further made of at least one metal chosen from among chrome and molybdenum. The turbulence-generating element has an improved resistance to corrosion when in contact with a hydrocarbon, such as crude oil.Type: GrantFiled: January 29, 2002Date of Patent: August 31, 2004Assignee: Elf Antar FranceInventor: Claude Baudelet
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Patent number: 6776728Abstract: A weight member for a golf club head is made of a WFeNi alloy by a precision casting process. The WFeNi alloy includes wt 15%-40% of iron, wt 30%-60% of nickel, wt 15%-30% of tungsten, wt 1.5%-10.0% of chromium, and wt 0.5%-5.0% of molybdenum. Chromium improves the rust-resisting property of the weight member. Molybdenum reduces the risk of cracks in the weight member during welding. Uniformity of shining finishing of the weight member can be improved by controlling a mixture ratio of nickel to tungsten. Manganese, copper, vanadium, and niobium may be added to improve the mechanical properties of the weight member.Type: GrantFiled: July 3, 2003Date of Patent: August 17, 2004Assignee: Nelson Precision Casting Co., Ltd.Inventors: Chan-Tung Chen, Yan-Zheng Su
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Patent number: 6764646Abstract: A nickel-chromium-molybdenum-copper alloy that is resistant to sulfuric acid and wet process phosphoric acid contains in weight percent 30.0 to 35.0% chromium, 5.0 to 7.6% molybdenum, 1.6 to 2.9% copper, up to 1.0% manganese, up to 0.4% aluminum, up to 0.6% silicon, up to 0.06% carbon, up to 0.13% nitrogen, up to 5.1% iron, up to 5.0% cobalt, with the balance nickel plus impurities.Type: GrantFiled: June 13, 2002Date of Patent: July 20, 2004Assignee: Haynes International, Inc.Inventors: Paul Crook, Martin L. Caruso
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Patent number: 6758764Abstract: A weight member for a golf club head is made of a WFeNi alloy by a precision casting process. The WFeNi alloy includes nickel 30-60 wt %, tungsten 15-30 wt %, chromium 1.5-10.0 wt %, and iron that is the remaining portion. Chromium improves the rust resisting property of the weight member and lengthens the life of the weight member. Uniformity of shining finishing of the weight member can be improved by controlling a mixture ratio of nickel to tungsten. Silicon may be added to improve the flowability of the molten metal. Manganese, copper, vanadium, and niobium may be added to improve the mechanical properties of the weight member.Type: GrantFiled: July 3, 2003Date of Patent: July 6, 2004Assignee: Nelson Precision Casting Co., Ltd.Inventors: Chan-Tung Chen, Yan-Zheng Su
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Patent number: 6752883Abstract: A free-cutting Ni-base heat-resistant alloy excellent in the high-temperature strength and corrosion resistance was proposed. The alloy contains Ni as a major component, 0.01 to 0.3 wt % of C and 14 to 35 wt % of Cr, and further contains at least one element selected from Ti, Zr and Hf in a total amount of 0.1 to 6 wt %, and S in an amount of 0.015 to 0.5 wt %. The alloy has dispersed in the matrix thereof a machinability improving compound phase, where such phase contains any one of Ti, Zr and Hf as a major constituent of the metal elements, essentially contains C and either S or Se as a binding component for such metal elements. The alloy also satisfies the relations of WTi+0.53WZr+0.27WHf>2WC+0.75WS and WC>0.37WS, where WTi represents Ti content (wt %), WZr represents Zr content (wt %), WHf represents Hf content (wt %), WC represents C content (wt %) and WS represents S content (wt %).Type: GrantFiled: May 31, 2002Date of Patent: June 22, 2004Assignees: Dokuritsu Gyousei Houjin Sangyo Gijutsu Sougo Kenkyusho, Daido Tokushuko Kabushiki Kaisha, Tohoku Tokushuko Kabushiki KaishaInventors: Kiyohito Ishida, Katsunari Oikawa, Shigeki Ueta, Toshiharu Noda, Takashi Ebata
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Patent number: 6740291Abstract: A nickel-chromium-molybdenum alloy that is thermally stable and resistant to wet process phosphoric acid and chloride induced localized attack contains in weight percent 31.0 to 34.5% chromium, 7.0 to 10.0% molybdenum, up to 0.2% nitrogen, up to 3.0% iron, up to 1.0% manganese, up to 0.4% aluminum, up to 0.75% silicon, up to 0.1% carbon with the balance nickel plus impurities.Type: GrantFiled: May 15, 2002Date of Patent: May 25, 2004Assignee: Haynes International, Inc.Inventor: Paul Crook
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Patent number: 6730180Abstract: The present invention is drawn to new classes of advanced neutron absorbing structural materials for use in spent nuclear fuel applications requiring structural strength, weldability, and long term corrosion resistance. Particularly, an austenitic stainless steel alloy containing gadolinium and less than 5% of a ferrite content is disclosed. Additionally, a nickel-based alloy containing gadolinium and greater than 50% nickel is also disclosed.Type: GrantFiled: September 26, 2001Date of Patent: May 4, 2004Assignee: Bechtel BWXT Idaho, LLCInventors: Ronald E. Mizia, Eric L. Shaber, John N. DuPont, Charles V. Robino, David B. Williams
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Publication number: 20030180175Abstract: To provide a corrosion-resisting and wear resisting alloy including cobalt, nickel or iron as a base used for a sliding part or a valve seat for a machine, and restraining erosion and corrosion caused by eutectic carbide constituting the alloy in an atmosphere with dissolved oxygen.Type: ApplicationFiled: March 13, 2003Publication date: September 25, 2003Applicants: Hitachi, Ltd., Hitachi Kyowa Engineering Co., Ltd.Inventors: Yoshihisa Kiyotoki, Yoshiteru Chiba, Shin Kumagai, Yasuhiro Ogawa, Akira Sakamoto, Hiroyuki Shinohara
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Publication number: 20030070733Abstract: A single step heat treatment for Ni—Cr—Mo alloys containing from 12% to 19% chromium and from 18% to 23% molybdenum provides higher yield strength, high tensile strength and other mechanical properties comparable to those observed in similar alloys age-hardened according to current practices. This treatment is done over a total time of at least 24 hours and preferably less than 50 hours. However, the treatment works for only those alloys having alloying elements present in amounts according to an equation here disclosed.Type: ApplicationFiled: June 28, 2001Publication date: April 17, 2003Inventors: Lee M. Pike, Dwaine L. Klarstrom
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Publication number: 20030049155Abstract: A two step heat treatment for Ni—Cr—Mo alloys containing from 12% to 23.5% chromium provides higher yield strength, high tensile strength and other mechanical properties comparable to those observed in similar alloys age-hardened according to current practices. This treatment is done over a total time of not more than 50 hours. However, the treatment works for only those alloys having alloying elements present in amounts according to an equation here disclosed.Type: ApplicationFiled: June 28, 2001Publication date: March 13, 2003Inventors: Lee M. Pike, Dwaine L. Klarstrom, Michael F. Rothman
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Patent number: 6503345Abstract: High molybdenum, corrosion-resistant alloys are provided with greatly increased thermal stability by controlling the atom concentrations to be NiaMobXcYdZe, where: a is between about 73 and 77 atom percent b is between about 18 and 23 atom percent X is one or more required substitutional alloying elements selected from Groups VI, VII and VIII of the Periodic Table and c does not exceed about 5 atom percent for any one element, Y is one or more optional substitutional alloying elements which may be present and d does not exceed about one atom percent for any one element, Z is one or more interstitial elements and e is as low as possible, not exceeding about 0.2 atom percent in total; and the sum of c and d is between about 2.5 and 7.5 atom percent.Type: GrantFiled: July 1, 1994Date of Patent: January 7, 2003Assignee: Haynes International, Inc.Inventor: Dwaine L. Klarstrom
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Patent number: 6482275Abstract: A nickel based alloy is provided which includes, in weight percentage, carbon from about 2 to about 3; chromium from about 30 to about 40; tungsten from about 12 to about 18; iron from about 3.5 to about 8.5; molybdenum from about 1 to about 8; manganese up to about 0.5; silicon up to about 1.0; and the balance nickel and incidental impurities. The alloy is useful for internal combustion engine valve seat inserts and the like.Type: GrantFiled: July 27, 2000Date of Patent: November 19, 2002Assignee: L. E. Jones CompanyInventor: Cong Yue Qiao
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Patent number: 6447716Abstract: Nickel-based alloy useful for welding, welding method, and welding electrode.Type: GrantFiled: December 1, 1999Date of Patent: September 10, 2002Assignees: Ugine-Savoie Imphy, Sprint Metal-Societe de Production Internationale de TrefilesInventors: Ricardo Cozar, Albert Bruyere, Bernard Bonnefois
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Patent number: 6242112Abstract: As tube material in waste incineration it has been found advantageous to use a composite tube wherein an inner tube component of a carbon steel or a low-alloy Cr—Mo-steel is metallurgically bonded to an outer tube component of Ni—Cr—Mo—Nb—Fe-alloy with an austenitic structure. The composite tube is fabricated by spraying finely distributed metal drops of the outer component onto the inner component in melt condition. After solidifying, the composite tube is then fabricated by joint extrusion.Type: GrantFiled: May 6, 1999Date of Patent: June 5, 2001Assignee: Sandvik ABInventors: Urban Forsberg, Anders Wilson
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Patent number: 6200690Abstract: A nickel-chromium-based brazing alloy has a composition consisting essentially of about 9.5 to about 16.5 atom percent chromium, 0 to about 5 atom percent iron, about 10 to about 15 atom percent silicon, about 6 to less than 7 atom percent boron, and 0 to about 5 atom percent molybdenum, the balance being essentially nickel and incidental impurities. The alloy is especially suited for use as a brazing filler metal for joining stainless steel and/or superalloy at temperatures above 1100 degree(s) C. Such a filler metal has a thickness ranging from about 65 to 100 micrometers and a width ranging from 100 to 250 millimeters and more. Honeycomb structures and thin corrugated fin/plate structures particularly suited for use in manufacture of plate-type heat exchangers formed at least in part from stainless steels and/or superalloys are brazed using a unique process. The process is characterized by a long holding time at brazing temperature, and combines brazing and diffusion annealing in one technological step.Type: GrantFiled: August 29, 1997Date of Patent: March 13, 2001Assignee: AlliedSignal Inc.Inventor: Anatol Rabinkin
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Patent number: 6200688Abstract: A wear resistant alloy is provided having a composition by weight of 1.0-2.5 C, 1.5-4.5 Si, 8.0-20.0 Cr, 9.0-20.0 W and/or Mo, 0.5-2.0 Nb, 20.0-40.0 Fe, and the balance being Ni (>25.0). This alloy provides excellent wear resistance and good hot hardness with relatively low cost compared to prior art nickel base alloys. The alloy has particular use as a valve seat insert materials in diesel fuel internal combustion engines.Type: GrantFiled: April 20, 1998Date of Patent: March 13, 2001Assignee: Winsert, Inc.Inventors: Xuecheng Liang, Gary R. Strong
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Patent number: 6187115Abstract: A material in powder or wire form on a nickel basis for the production of a coating with a high level of resistance to corrosion and wear by means of a thermal coating process is of the following composition (in percent by weight): C 0.005-1.0; Cr 10.0-26.0; Mo 8.0-20.0; Fe 0.1-10.0; Si 3.0-7.0; B 1.0-4.0; Cu 0.1-5.0; Ni Balance. The material in powder form can be alloyed and sprayed out of the melt or agglomerated out of different alloyed and non-alloyed metal powders. The coating material can also be used in the form of a filling wire or an alloyed and cast bar material.Type: GrantFiled: September 28, 1999Date of Patent: February 13, 2001Assignee: Castolin S.A.Inventors: Ingo Kretschmer, Peter Heimgartner, Gary Robert Heath
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Patent number: 6027583Abstract: A material in powder or wire form on a nickel basis for the production of a coating with a high level of resistance to corrosion and wear by means of a thermal coating process is of the following composition (in percent by weight):______________________________________ C 0.005-1.0; Cr 10.0-26.0; Mo 8.0-20.0; Fe 0.1-10.0; Si 3.0-7.0; B 1.0-4.0; Cu 0.1-5.0; Ni Balance. ______________________________________The material in powder form can be alloyed and sprayed out of the melt or agglomerated out of different alloyed and non-alloyed metal powders. The coating material can also be used in the form of a filling wire or an alloyed and cast bar material.Type: GrantFiled: June 24, 1997Date of Patent: February 22, 2000Assignee: Castolin S.A.Inventors: Ingo Kretschmer, Peter Heimgartner, Gary Robert Heath