Abstract: Methods and systems for preparing metallic alloys comprising volatile materials such as phosphorus suitable for bulk metallic glasses are described. The methods variously involve carrying out alloying at temperatures and pressures that minimize or counteract sublimation of the volatile species.

Abstract: Identifying a stable phase of a binary alloy comprising a solute element and a solvent element. In one example, at least two thermodynamic parameters associated with grain growth and phase separation of the binary alloy are determined, and the stable phase of the binary alloy is identified based on the first thermodynamic parameter and the second thermodynamic parameter, wherein the stable phase is one of a stable nanocrystalline phase, a metastable nanocrystalline phase, and a non-nanocrystalline phase.

Abstract: Described herein is a mercury sample that has an isotopic composition that differs from the naturally occurring distribution of isotopes. In various configurations of an isotopically tailored mercury sample, the fraction of one or more isotopes is increased or decreased with respect to the natural fraction(s). A example of a lighting device comprises an envelope, a buffer gas enclosed within the envelope, a isotopically tailored sample of mercury vapor, and a current injection mechanism configured to excite the mercury vapor to emit light. In various configurations, the lighting device emits radiation at a wavelength of 254 nm and/or at a wavelength of 185 nm. In various configurations, the lighting device envelope includes a fluorescent coating that is excited by ultraviolet (UV) light emitted by the mercury vapor. In various configurations, the lighting device provides improved efficiency as compared to lamps employing mercury with a naturally occurring isotope distribution.

Abstract: Energy-saving lamps contain a gas filling of mercury vapour and argon in a gas discharge bulb. Amalgam spheres are used for filling the gas discharge bulb with mercury. A tin amalgam having a high proportion by weight of mercury in the range from 30 to 70% by weight is proposed. Owing to the high mercury content, the amalgam spheres have liquid amalgam phases on the surface. Coating of the spheres with a tin or tin alloy powder converts the liquid amalgam phases on the surface into a solid amalgam having a high tin content. This prevents conglutination of the amalgam spheres during storage and processing.

Abstract: The invention relates to a composite material formed by millimeter-scale particles of magnetic material A and a conductive liquid B. The material is characterized in that the material A is chosen from magnetic compounds and magnetic alloys and is in the form of particles, the mean size of which is between 0.1 and 2 mm, and in that the support fluid B is a conductive fluid chosen from metals, metal alloys and salts that are liquid at temperatures below the Curie temperature of the material A, or from mixtures thereof.

Abstract: The invention relates to a composite material formed by microparticles of magnetic material A and a conductive liquid B. The material is characterized in that the material A is chosen from magnetic compounds and magnetic alloys and is in the form of particles, the mean size of which is between 1 and 10 ?m, and in that the support fluid B is a conductive fluid chosen from metals, metal alloys and salts that are liquid at temperatures below the Curie temperature of the material A, or from mixtures thereof.

Abstract: A method includes releasing mercury in devices requiring mercury, in particular fluorescent lamps. The method includes the use of manganese-mercury compositions.

Abstract: The subject of the present invention is a method of preparation of a monolithic hydrated alumina by the oxidation of aluminium or an aluminium alloy in the presence of a mercury amalgam that contains at least one noble metal, such as silver. This hydrated alumina serves inter alia as base product in methods of preparation of amorphous or crystalline aluminas, or of aluminates, which themselves serve as base products for methods of preparation of composite materials based on oxides, on metals, on carbon products and/or on polymers. Application of the said products obtained by the said methods in many fields, such as catalysis, thermal and acoustic insulation, magnetism, waste storage, and preparation of radioelement transmutation targets.

Abstract: A method includes releasing mercury in devices requiring mercury, in particular fluorescent lamps. The method includes the use of manganese-mercury compositions.

Abstract: A process for the formation of shaped Group III-V semiconductor nanocrystals comprises contacting the semiconductor nanocrystal precursors with a liquid media comprising a binary mixture of phosphorus-containing organic surfactants capable of promoting the growth of either spherical semiconductor nanocrystals or rod-like semiconductor nanocrystals, whereby the shape of the semiconductor nanocrystals formed in said binary mixture of surfactants is controlled by adjusting the ratio of the surfactants in the binary mixture.

Abstract: The present invention relates to an alloy comprising a first element A, a second element B, a third element C, and a fourth element D. In the alloy, first element A and second element B are present as a binary compound AB, and third element C and fourth element D are present as a binary compound CD. In addition, the alloy is substantially free from binary compounds AD, BC, AC, and BD. These alloys can be characterized as semiconducting, quasi-binary, single phase alloys having the formula (AB)x(CD)1−x, where x is between 0 and 1 and where A, B, C, and D are different. The present invention also relates to a method of producing an alloy. The method includes providing a first binary material AB and providing a second binary material CD. The first binary material AB and the second binary material CD are contacted under conditions effective to mix the first binary material AB and the second binary material CD without decomposing either the first binary material AB or the second binary material CD.

Abstract: A process for the formation of shaped Group II-VI semiconductor nanocrystals comprises contacting the semiconductor nanocrystal precursors with a liquid media comprising a binary mixture of phosphorus-containing organic surfactants capable of promoting the growth of either spherical semiconductor nanocrystals or rod-like semiconductor nanocrystals, whereby the shape of the semiconductor nanocrystals formed in said binary mixture of surfactants is controlled by adjusting the ratio of the surfactants in the binary mixture.

Abstract: The present invention concerns totally solid amalgamating compositions particularly useful in the preparation of dental amalgams for filling cavities and similar dental applications, comprising one or more solid amalgamating alloys, metals and/or intermetallic compounds or combinations thereof, amalgam forming compositions containing such totally solid amalgamating compositions, methods for producing dental amalgams with such totally solid amalgamating compositions or amalgam forming compositions containing them, and denial amalgams produced thereby.

Abstract: A modified amalgam composition forming an adhesive bond with tooth structure treated with a dental adhesive. The modified amalgam can be prepared by admixing particulate additives into conventional amalgam alloy powder to form a modified alloy powder and then triturating the modified alloy powder with mercury. The modified amalgam when applied to a prepared tooth cavity that has been precoated with an acrylate- or methacrylate-functional dental adhesive results in an adhesive bond between the modified amalgam and coated tooth structure. Preferred particulate additives for the amalgam alloy powder are acrylate- or methacrylate-functional polymers, metal salts of acrylates or methacrylates, nonmetallic fillers, oxidizing agents and reducing agents.

Abstract: Working fluid for absorption heat pumps operating at very high temperature, particularly 200.degree. to 1000.degree. C., said working fluid being a mixture of at least two constituents, characterized in that the working fluid is constituted by a mixture of at least two chemical elements, whereof the first called the "solvent" is much more volatile than the others called "solutes" at the temperature of the mixture, the nature and proportions of each of the chemical elements in the mixture being chosen in such a way that the Vapour pressure of the mixture is significantly below that of the first, more volatile chemical element throughout the operating cycle of the working fluid in the pump.These chemical elements can in particular be metals such as mercury or sodium, or metalloids such as sulphur.

Abstract: A method and apparatus for preparing cast composite materials of nonmetallic particles in a metallic matrix, wherein particles are mixed into a molten metallic alloy to wet the molten metal to the particles, and the particles and metal are sheared past each other to promote wetting of the particles by the metal. The mixing occurs while minimizing the introduction of gas into the mixture, and while minimizing the retention of gas at the particle-liquid interface. Mixing is done at a maximum temperature whereat the particles do not substantially chemically degrade in the molten metal during the time required for processing, and casting is done at a temperature sufficiently high that there is no solid metal present in the melt. Mixing is preferably accomplished with a dispersing impeller, or a dispersing impeller used with a sweeping impeller.

Abstract: A unique class of bonding alloys and methods for their use are provided which enable the user to electrically join superconductive materials to themselves, to normal conductive materials, or to semi-conductors. The bonding alloys have enhanced wetting properties and a melting point less than 100.degree. C. in all instances. The bonding alloys are unusual and advantageous in that they create an intimate, direct, mechanical and electrical contact between the superconductive material and any other electrical conductor while minimizing mechanical and chemical stresses and avoiding alterations to the superconductive material itself.

Abstract: A solid, thin sheet of an amalgam is formed by first mixing together a liquid metal and one or more powdered metals to form the amalgam in liquid form. The liquid amalgam is then spread out over a surface to form a thin layer of the liquid amalgam. The temperature of the thin layer of amalgam is then reduced to below the melting temperature of the liquid metal in the amalgam to form a solid sheet of the amalgam. The solid thin sheet of amalgam can then be removed from the surface. The solid thin sheet of amalgam can be stored at the lower temperature until it is desired to use the amalgam.

Abstract: The present invention relates to a preform of a solid body of an amalgam. The amalgam is a mixture of a metal which is liquid at room temperature and at least one powdered metal. The preform is formed by mixing together the ingredients of the amalgam and pouring the amalgam into a caity in a mold. The mold and amalgam is then cooled to a temperature below the melting temperature of the liquid metal in the amalgam. The preform is then removed from the mold. The preform can be stored at the low temperature until it is desired to use it to bond two bodies together. The preform can be used to bond two bodies together, such as the cover plate and housing of a microelectronic device package, by placing the preform between the two bodies. The bodies are mechanically scrubbed and clamped together with the preform therebetween and heated to a temperature at which the preform melts and the amalgam reacts to bond to the two bodies.

Abstract: Mercury is mixed with an inorganic powder resulting in a permanent bonding of the mercury to the powder in a solid form. Thereafter the amalgam may be easily, safely, and legally deposited in a landfill. Suggested powders include copper, zinc, nickel, and sulphur in a ratio of powder to mercury of substantially 3:1. The mixture is followed by compound agitation.

Abstract: Process for the preparation of a polycrystalline alloy for producing monocrystals by passage in a solvent zone.The compound is completely melted by heating it to a temperature above its melting point and for a time sufficient for the homogenization of the liquid. This is followed by a cooling of the liquid by bringing it to a temperature below the melting point thereof. The sudden rise of the temperature occurring at the end of the superfusion of the liquid is monitored and the mixture then undergoes sudden tempering bringing about the instantaneous solidification of the entity in the form of a homogeneous polycrystalline ingot.

Abstract: A high pressure sodium vapor lamp for operation at a sodium vapor pressure of at least 60 Torr and in which the start-up interval of variation of lamp operating voltage is reduced by charging the lamp with a ternary amalgam of mercury, sodium and a third metal selected from the group consisting of indium, gallium and tin. The atomic proportion of the third metal exceeds that of the mercury but does not exceed that of the sodium in the amalgam, and the atomic proportion of sodium is at least twice but not over four times that of the mercury.

Abstract: An alloy for use in production of electromagnetic radiation detectors comprises (Hg,Cd,Zn,)Te for producing crystals with dislocation densities less than about 10.sup.4 cm.sup.-2. The elements are combined in accordance with the formula (Hg.sub.1-x-y Cd.sub.x Zn.sub.y)Te where x is about 10 to about 90 and y is about 0.6 to about 5.0 mole percent.

Abstract: Controllable doping of HgCdTe in concentrations low enough to be useful for electronic devices is accomplished by dissolving the desired dopant in mercury at or below the solubility limit. The mercury is then diluted with pure mercury, to lower the dopant concentration to that which will produce the desired impurity concentration in the end product. The doped mercury is then compounded according to conventional methods, to produce reproducibly doped HgCdTe of uniform composition.

Abstract: Mercury filter for collecting low concentration mercury vapor in gas. Filter has an absorber having a collecting surface of a material that amalgamates readily with mercury, the surface having a reactive tarnish produced by exposure of the plates to available iodine. The absorber can have spaced collecting members with the gas passing about the collecting members. Optionally at least one of the collecting members is at a higher electrical potential difference than the remaining member, which potential difference is insufficient for the filter to act as an electrostatic precipitator so as to reduce attraction of dust. An optional electrically insulating porous matrix can extend between the collecting members and should have sufficient porosity to permit air to flow relatively freely between the collecting members.

Abstract: Substantially pure, free flowing, sodium amalgam particles of predetermined composition and controlled particle size are prepared for use as vaporizable fill for high pressure discharge lamp devices, whereby accurately measurable quantities of the sodium amalgam may be introduced into the lamp devices. A process for producing the substantially pure amalgam particles of accurately controlled size includes heating a mixture of sodium and mercury to form a melt, passing the melt through a vibrating discharge nozzle and subjecting the droplets so formed to an inert cooling fluid maintained at a temperature below the solidification point of the amalgam. An apparatus for producing the amalgam particles comprises a vessel to contain an alkali metal amalgam melt, a vibrating discharge nozzle adapted to form the melt into uniformly sized droplets, and a column of inert cooling fluid maintained at a low temperature at which the melt droplets are solidified.