Group Iv Or V Transition Metal Containing Patents (Class 420/53)
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Patent number: 12221665Abstract: In the austenitic stainless steel material of the present disclosure, the chemical composition consists of, by mass %, C: 0.100% or less, Si: 1.00% or less, Mn: 5.00% or less, Cr: 15.00 to 22.00%, Ni: 10.00 to 21.00%, Mo: 1.20 to 4.50%, P: 0.050% or less, S: 0.050% or less, Al: 0.100% or less, N: 0.100% or less, and Cu: 0 to 0.70%, with the balance being Fe and impurities, and an austenite grain size No. determined in accordance with ASTM E112 is from 5.0 to less than 8.0, and in a cross section perpendicular to the longitudinal direction of the austenitic stainless steel material, the dislocation cell structure ratio is from 50 to less than 80%, and the number density of precipitates with a long axis of 1.0 ?m or more is 5.0 per 0.2 mm2 or less.Type: GrantFiled: May 29, 2020Date of Patent: February 11, 2025Assignee: NIPPON STEEL CORPORATIONInventors: Misaho Yamamura, Jun Nakamura
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Patent number: 11692232Abstract: High strength precipitation hardening stainless steel alloy is disclosed. The steel alloy has a composition by weight %, about: 30.0% max nickel (Ni), 0.0 to 15.0% cobalt (Co), 25.0% max chromium (Cr), 5.0% max molybdenum (Mo), 5.0% max titanium (Ti), 5.0% max vanadium (V), about 0.5% max lanthanum (La) and/or cerium (Ce), and in balance iron (Fe) and inevitable impurities. The steel alloy provides a unique combination of corrosion resistance, strength and toughness and is a material for aircraft landing gears and structures.Type: GrantFiled: November 25, 2019Date of Patent: July 4, 2023Inventor: Gregory Vartanov
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Patent number: 9368807Abstract: The present invention relates to a fuel cell element having an active core interposed between a first and second conducting plate, wherein at least the first conducting plate is made from an alloy having, in percentages by weight, 24.0 to 27.0% nickel; 13.5 to 16.0% chromium; 1.90 to 2.35% titanium; 1.0 to 1.5% molybdenum; 0.10 to 0.50% vanadium; at most 0.08% carbon; at most 2.0% manganese; at most 1.0% silicon; at most 0.35% aluminum; at most 0.03% sulphur; and at most 0.01% boron, the balance consisting of iron and impurities.Type: GrantFiled: April 19, 2013Date of Patent: June 14, 2016Assignees: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE, APERAM ALLOYS IMPHYInventors: Eric Claude, Richard Bosquet, Gilles Platen, Claude Roussel
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Publication number: 20150093284Abstract: Welding material for welding of superalloys comprising boron with the range of 0.3-0.8 wt. % B, 0.2-0.8 wt. % C, 17-23 wt. % Cr, 0.35-10 wt. % Mo, 0.1-4.15 wt. % Nb with nickel or iron and impurities to balance for weld repair of engine components manufactured of precipitation hardening superalloys with high content of gamma prime phase at an ambient temperature.Type: ApplicationFiled: April 28, 2014Publication date: April 2, 2015Applicant: Liburdi Engineering LimitedInventors: Alexander B. Goncharov, Joseph Liburdi, Paul Lowden
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Publication number: 20150000468Abstract: There is provided a metal powder for powder metallurgy including Zr and Si in a manner such that following conditions of (A) and (B) are satisfied, wherein a remainder thereof includes at least one element selected from the group consisting of Fe, Co and Ni, (A) the mass ratio of a content of Zr to a content of Si is 0.03 to 0.3, and (B) the content of Si is 0.35 to 1.5% by mass.Type: ApplicationFiled: September 17, 2014Publication date: January 1, 2015Inventor: Hidefumi NAKAMURA
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Patent number: 8865060Abstract: An austenitic stainless steel, which consists of by mass percent, C: not more than 0.02%, Si: not more than 1.5%, Mn: not more than 2%, Cr: 17 to 25%, Ni: 9 to 13%, Cu: more than 0.26% not more than 4%, N: 0.06 to 0.35%, sol. Al: 0.008 to 0.03%. One or more elements selected from Nb, Ti, V, TA, Hf, and Zr in controlled amounts can be included with the balance being Fe and impurities. P, S, Sn, As, Zn, Pb and Sb among the impurities are controlled as P: 0.006 to 0.04%, S: 0.0004 to 0.03%, Sn: 0.001 to 0.1%, As: not more than 0.01%, Zn: not more than 0.01%, Pb: not more than 0.01% and Sb: not more than 0.01%. The amounts of S, P, Sn, As, Zn, Pb and Sb and the amounts of Nb, Ta, Zr, Hf, and Ti are further controlled using formulas.Type: GrantFiled: February 8, 2012Date of Patent: October 21, 2014Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Takahiro Osuki, Kazuhiro Ogawa, Hiroyuki Hirata, Yoshitaka Nishiyama
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Patent number: 8741215Abstract: To provide an inexpensive heat-resisting steel for engine valves by causing Fe-based heat-resisting steel to exhibit high temperature strength not inferior to that of Ni-based heat-resisting steel. A heat-resisting steel for engine valves excellent in high temperature strength containing, in % by mass, C: 0.20 to 0.50%, Si: 1.0% or less, Mn: 5.0% or less, P: 0.1 to 0.5%, Ni: 8.0 to 15.0%, Cr: 16.0 to 25.0%, Mo: 2.0 to 5.0%, Cu: 0.5% or less, Nb: 1.0% or less (including 0%), W: 8.0% or less (including 0%), N: 0.02 to 0.2%, B: 0.01% or less, and remnants of Fe and impurities, wherein the heat-resisting steel for engine valves satisfies formulae below: 442P(%)+12Mo(%)+5W(%)+7Nb(%)+328N(%)+171?300??Formula (1) ?38.13P(%)+1.06Mo(%)+0.13W(%)+9.64Nb(%)+13.52N(%)+4.83?0.12??Formula (2).Type: GrantFiled: April 19, 2010Date of Patent: June 3, 2014Assignees: Hitachi Metals, Ltd., Honda Motor Co., Ltd.Inventors: Katsuhiko Ohishi, Takehiro Ohno, Toshihiro Uehara
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Publication number: 20140134039Abstract: Austenitic stainless steel is disclosed herein. In the described embodiments, the austenitic stainless steel comprises 16.00 wt % of Chromium to 30.00 wt % of Chromium; 8.00 wt % of Nickel to 27.00 wt % of Nickel; no more than 7.00 wt % of Molybdenum; 0.40 wt % of Nitrogen to 0.70 wt % of Nitrogen, 1.0 wt % of Manganese to 4.00 wt % of Manganese, and less than 0.10 wt % of Carbon, wherein the ratio of the Manganese to the Nitrogen is controlled to less than or equal to 10.0. Austenitic stainless steel based on specified minimum PREN (Pitting Resistance Equivalent Number) values is also disclosed. (1) PRE=wt % Cr+3.3×wt % (Mo)+16 wt % N>=25 for N in range of 0.40-0.70. (2) PRE=wt % Cr+3.3×wt % (Mo+W)+16 wt % N>=27 for N in range of 0.40-0.70 with W present.Type: ApplicationFiled: May 24, 2012Publication date: May 15, 2014Applicant: UNITED PIPELINES ASIA PACIFIC PTE LIMITEDInventor: Cecil Vernon Roscoe
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Patent number: 8696835Abstract: An austenitic stainless steel for use in a hydrogen gas atmosphere comprises, in mass %, C: 0.10% or less, Si: 1.0% or less, Mn: 0.01 to 30%, P: 0.040% or less, S: 0.01% or less, Cr: 15 to 30%, Ni: 5.0 to 30%, Al: 0.10% or less, N: 0.001 to 0.30% with the balance Fe and inevitable impurities. An X-ray (111) integration intensity of a cross section along the direction rectangular to the working direction is five times that in a random direction or less, and the X-ray integration intensity ratio of a cross section along the working direction satisfies I(220)/I(111)?10. The high strength steel can also contain one or more of the groups of Mo and W; V, Nb, Ta, Ti, Zr and Hf; B; Cu and Co; Mg, Ca, La, Ce, Y, Sm, Pr and Nd.Type: GrantFiled: November 24, 2010Date of Patent: April 15, 2014Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Hiroyuki Semba, Masaaki Igarashi, Tomohiko Omura, Mitsuo Miyahara, Kazuhiko Ogawa
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Patent number: 8663549Abstract: To provide an inexpensive heat-resisting steel for engine valves by causing Fe-based heat-resisting steel to exhibit high temperature strength not inferior to that of Ni-based heat-resisting steel. A heat-resisting steel for engine valves excellent in high temperature strength containing, in % by mass, C: 0.20 to 0.50%, Si: 1.0% or less, Mn: 5.0% or less, P: 0.1 to 0.5%, Ni: 8.0 to 15.0%, Cr: 16.0 to 25.0%, Mo: 2.0% or less (including 0%), Cu: 0.5% or less, Nb: 1.0% or less (including 0%), W: 2.0% or less (including 0%), N: 0.02 to 0.30%, B: 0.01% or less, and remnants of Fe and impurities, wherein the heat-resisting steel for engine valves satisfies formulae below: 156.42P(%)+0.91Mo(%)+0.73W(%)?12.27Nb(%)+220.96N(%)+120.59?170??Formula (1) 13.70P(%)?6.97Mo(%)?4.32W(%)?3.29Nb(%)+119.10N(%)+27.75?25??Formula (2).Type: GrantFiled: June 23, 2010Date of Patent: March 4, 2014Assignees: Hitachi Metals, Ltd., Honda Motor Co., Ltd.Inventors: Katsuhiko Ohishi, Akihiro Toji
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Publication number: 20140030134Abstract: A purpose of the present invention is to provide a martensitic stainless steel applicable in environments involving both wet carbon dioxide gas and wet hydrogen sulfide and excellent in weldability, manufacturability, and resistance to strain age hardening. Provided is a martensitic stainless steel having excellent corrosion resistance and resistance to strain age hardening comprising, in percent by mass, 0.02% or less of C, 0.02% or less of N, 0.1 to 0.5% of Si, 0.1 to 0.5% of Mn, 10 to 13% Cr, Ni exceeding 5.0% but 8% or less, 1.5 to 3% of Mo, 0.01 to 0.05% of V, 0.16 to 0.30% of Zr, 0.01 to 0.05% of Ta, and the balance of Fe and unavoidable impurities, wherein the martensitic stainless steel satisfies the condition that the sum of the carbon and the nitrogen exceeds 0.02% but 0.04% or less.Type: ApplicationFiled: April 11, 2011Publication date: January 30, 2014Applicant: NKK TUBESInventors: Shuji Hashizume, Yusuke Minami, Yu Yamamoto
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Patent number: 8506729Abstract: An austenitic stainless steel hot-rolled steel material can be provided which has sea-water resistance and strength superior to conventional steel. Low-temperature toughness can be maintained, which is preferable in a structural member of speedy craft. The steel material can include an austenitic stainless steel hot-rolled steel material which excels in the properties of corrosion resistance, proof stress, and low-temperature toughness. In such austenitic stainless steel hot-rolling steel material, e.g., PI [=Cr+3.3(Mo+0.5W)+16N] ranges from 35 to 40, ? cal [=2.9 (Cr+0.3Si+Mo+0.5W)?2.6 (Ni+0.3Mn+0.25Cu+35C+20N)?18] ranges from ?6 to +2, and a 0.2% proof stress at room temperature is not less than 550 MPa, Charpy impact value measured using a V-notch test piece at ?40° C. is not less than 100 J/cm2, and the pitting potential measured in a deaerated aqueous solution of 10% NaCl at 50° C. (Vc?100) is not less than 500 mV (as it relates to saturated Ag/AgCl).Type: GrantFiled: January 13, 2012Date of Patent: August 13, 2013Assignee: Nippon Steel & Sumikin Stainless Steel CorporationInventors: Yuusuke Oikawa, Shinji Tsuge, Shigeo Fukumoto, Kazuhiro Suetsugu, Ryo Matsuhashi, Hiroshige Inoue
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Patent number: 8430075Abstract: A superaustenitic stainless steel comprises in weight %, 0.15 to 0.9% C, 0.2 to 1.3% Si, 0 to 0.45% Mn, 32.5 to 37.5% Cr, 13.5 to 17.5% Ni, 3.2 to 5.5% Mo, 0 to 2% Nb, 0 to 0.5% B, 0 to 2% Zr and 30 to 51% Fe. In a preferred embodiment, the superaustenitic stainless steel consists essentially of, in weight %, 0.5 to 0.9% C, 0.2 to 0.5% Si, 0.2 to 0.4% Mn, 33.0 to 35.0% Cr, 15.5 to 17.5% Ni, 4.0 to 4.5% Mo, 0.7 to 0.9% Nb, 0.07 to 0.13% B, 0 to 0.05% Zr and 40 to 46% Fe. The superaustenitic stainless steel is useful for valve seat inserts for internal combustion engines such as diesel or natural gas engines.Type: GrantFiled: December 16, 2008Date of Patent: April 30, 2013Assignee: L.E. Jones CompanyInventors: Cong Yue Qiao, Todd Trudeau
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Publication number: 20120321478Abstract: This invention provides a precipitate hardening stainless steel having excellent structure stability, strength, toughness, and corrosion resistance, which requires no sub-zero treating and thus is excellent in terms of productivity, and a long blade for a steam turbine using the same. The following are provided: a precipitate hardening stainless steel, which comprises C at 0.05 mass % or less, N at 0.05 mass % or less, Cr at 10.0 mass % to 14.0 mass %, Ni at 8.5 mass % to 11.5 mass %, Mo at 0.5 mass % to 3.0 mass %, Ti at 1.5 mass % to 2.0 mass %, Al at 0.25 mass % to 1.00 mass %, Si at 0.5 mass % or less, and Mn at 1.0 mass % or less, and the balance is composed of Fe and inevitable impurities; and a long blade for a steam turbine composed of the precipitate hardening stainless steel.Type: ApplicationFiled: June 13, 2012Publication date: December 20, 2012Inventors: Shinji OIKAWA, Hideo YODA, Masahiko ARAI, Hiroyuki DOI
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Patent number: 8318083Abstract: The present invention addresses the need for new austenitic steel compositions with higher creep strength and higher upper temperatures. The new austenitic steel compositions retain desirable phases, such as austenite, M23C6, and MC in its microstructure to higher temperatures. The present invention also discloses a methodology for the development of new austenitic steel compositions with higher creep strength and higher upper temperatures.Type: GrantFiled: July 20, 2010Date of Patent: November 27, 2012Assignee: UT-Battelle, LLCInventors: Roman I Pankiw, Govindarajan Muralidharan, Vinod Kumar Sikka, Philip J. Maziasz
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Publication number: 20120237389Abstract: An austenitic steel not susceptible to relaxation cracking, with composition comprising, in percentages by weight: 0.019% ?C ?0.030%, 0.5% ?Mn ?2%, 0.1% ?Si ?0.75%, Al >0.25%, 18% ?Cr ?25%, 12% ?Ni ?20%, 1.5% ?Mo ?3%, 0.001 % <B ?0.008%, 0.25% ?V ?0.35%, 0.23% ?N ?0.27%, the balance being iron and unavoidable impurities wherein: Ni(eq.) ?1.11 Cr(eq.) ?8.24, wherein: Cr(eq)=Cr+Mo+1.5 Si+5V+3AI+0.02, Ni(eq)=Ni+30C+x(N?0.045)+0.87 wherein: x=30 for N?0.2, x=22 for 0.2<N?0.25, x=20 for 0.25<N?0.35.Type: ApplicationFiled: July 20, 2010Publication date: September 20, 2012Applicants: ArcelorMittal Investigacion y Desarrollo SL, Netherlands Org. for Applied Sci. Research (TNO), Centro Sviluppo Materiali S.P.A.Inventors: Bernard Bonnefois, Amelie Fanica, Lionel Coudreuse, Tassa Oriana, Johannes Cornelis Van Wortel
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Publication number: 20120171070Abstract: A alloy and a process of forming a alloy are disclosed. The alloy has a predetermined grain boundary morphology. The alloy includes by weight greater than about 0.06 percent carbon, up to about 0.0015 percent sulfur, less than about 16 percent chromium, between about 39 percent and about 44 percent nickel, between about 2.5 percent and about 3.3 percent niobium, between about 1.4 percent and about 2 percent titanium, up to about 0.5 percent aluminum, up to about 0.006 percent boron, up to about 0.3 percent copper, up to about 0.006 percent nitrogen, and greater than about 0.5 percent molybdenum.Type: ApplicationFiled: January 3, 2011Publication date: July 5, 2012Applicant: GENERAL ELECTRIC COMPANYInventors: Ganjiang FENG, George A. GOLLER, Raymond Joseph STONITSCH, Jason R. PAROLINI, Shan LIU
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Patent number: 8105447Abstract: An austenitic stainless steel hot-rolled steel material can be provided which has sea-water resistance and strength superior to conventional steel. Low-temperature toughness can be maintained, which is preferable in a structural member of speedy craft. The steel material can include an austenitic stainless steel hot-rolled steel material which excels in the properties of corrosion resistance, proof stress, and low-temperature toughness. In such austenitic stainless steel hot-rolling steel material, e.g., PI [=Cr+3.3(Mo+0.5W)+16N] ranges from 35 to 40, ? cal [=2.9(Cr+0.3Si+Mo+0.5W)?2.6(Ni+0.3Mn+0.25Cu+35C+20N)?18] ranges from ?6 to +2, and a 0.2% proof stress at room temperature is not less than 550 MPa, Charpy impact value measured using a V-notch test piece at ?40° C. is not less than 100 J/cm2, and the pitting potential measured in a deaerated aqueous solution of 10% NaCl at 50° C. (Vc?100) is not less than 500 mV (as it relates to saturated Ag/AgCl).Type: GrantFiled: February 23, 2009Date of Patent: January 31, 2012Assignee: Nippon Steel & Sumikin Stainless Steel CorporationInventors: Yuusuke Oikawa, Shinji Tsuge, Shigeo Fukumoto, Kazuhiro Suetsugu, Ryo Matsuhashi, Hiroshige Inoue
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Patent number: 8097098Abstract: The invention concerns martensitic stainless steel, characterized in that its composition in weight percentages is as follows: 9%=Cr=13%; 1.5%=Mo=3%; 8%=Ni=14%; 1%=Al=2%; 0.5%=Ti=1.5% with AI+Ti=2.25%; traces=Co=2%; traces=W=1% with Mo+(W/2)=3%; traces=P=0.02%; traces=S=0.0050%; traces=N=0.0060%; traces=C=0.025%; traces=Cu=0.5%; traces=Mn=3%; traces=Si=0.25%; traces=O=0.0050%; and is such that: Ms (° C.)=1302 42 Cr 63 Ni 30 Mo+20AI-15W-33Mn-28Si-30Cu-13Co+10 Ti=50Cr eq/Ni eq=1.05 with Cr eq (%)=Cr+2Si+Mo+1.5 Ti+5.5 AI+0.6W Ni eq (%)=2Ni+0.5 Mn+3O C+25 N+Co+0.3 Cu. The invention also concerns a method for making a mechanical part using said steel, and the resulting part.Type: GrantFiled: June 26, 2006Date of Patent: January 17, 2012Assignee: Aubert & DuvalInventor: Jacques Montagnon
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Publication number: 20120003116Abstract: An austenitic stainless steel, which consists of by mass %, C?0.02%, Si: 0.01 to 0.50%, Mn: 0.01 to 2.0%, Cr: 24 to 26%, Ni: 19 to 22%, Mo: more than 0.10% to less than 0.50%, N: more than 0.04% to not more than 0.15%, and one or two elements selected from Nb?0.30% and V?0.40%, with the balance being Fe and impurities, and among the impurities P?0.030%, S?0.002% and Sn?0.015%, and satisfies [2.5?36Nb+53V+15N?25.0] and [S+{(P+Sn)/2??5.76×10?4×(36Nb+53V+15N)+0.0267] has excellent corrosion resistance, in particular, excellent intergranular corrosion resistance, and further has excellent crack insusceptibility in a weld heat affected zone. This austenitic stainless steel is a particularly excellent material as structural members for a nuclear power plant.Type: ApplicationFiled: September 15, 2011Publication date: January 5, 2012Applicant: SUMITOMO METAL INDUSTRIES, LTD.Inventors: Takahiro OSUKI, Kiyoko Takeda, Tetsuo Yokoyama
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Publication number: 20110314965Abstract: There is provided a metal powder for powder metallurgy including Zr and Si in a manner such that following conditions of (A) and (B) are satisfied, wherein a remainder thereof includes at least one element selected from the group consisting of Fe, Co and Ni, (A) the mass ratio of a content of Zr to a content of Si is 0.03 to 0.3, and (B) the content of Si is 0.35 to 1.5% by mass.Type: ApplicationFiled: May 24, 2011Publication date: December 29, 2011Applicant: SEIKO EPSON CORPORATIONInventor: Hidefumi NAKAMURA
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Patent number: 8071020Abstract: A high strength Cr—Ni alloy material excellent in hot workability and stress corrosion cracking resistance, and seamless pipe for oil well application which consists of, by mass percent, C: 0.05% or less, Si: 0.05 to 1.0%, Mn: 0.01% or more and less than 3.0%, P: 0.05% or less, S: 0.005% or less, Cu: 0.01 to 4%, Ni: 25% or more and less than 35%, Cr: 20 to 30%, Mo: 0.01% or more and less than 4.0%, N: 0.10 to 0.30%, Al: 0.03 to 0.30%, O (oxygen): 0.01% or less, and REM (rare earth metal): 0.01 to 0.20% with the balance being Fe and impurities, and also satisfies the conditions in the following formula (1). N×P/REM?0.40??formula (1) where P, N, and REM in the formula (1) respectively denote the contents (mass %) of P, N, and REM. The high strength Cr—Ni alloy material may further contain one or more types of W, Ti, Nb, Zr, V, Ca, and Mg, instead of part of Fe.Type: GrantFiled: June 16, 2009Date of Patent: December 6, 2011Assignee: Sumitomo Metal Industries, Ltd.Inventors: Yohei Otome, Masaaki Igarashi, Hisashi Amaya, Hirokazu Okada
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Patent number: 8003045Abstract: A cast, austenitic steel composed essentially of, expressed in weight percent of the total composition, about 0.4 to about 0.7 C, about 20 to about 30 Cr, about 20 to about 30 Ni, about 0.5 to about 1 Mn, about 0.6 to about 2 Si, about 0.05 to about 1 Nb, about 0.05 to about 1 W, about 0.05 to about 1.0 Mo, balance Fe, the steel being essentially free of Ti and Co, the steel characterized by at least one microstructural component selected from the group consisting of MC, M23C6, and M(C, N).Type: GrantFiled: June 4, 2010Date of Patent: August 23, 2011Assignee: UT-Battelle, LLCInventors: Govindarajan Muralidharan, Vinod Kumar Sikka, Philip J. Maziasz, Roman I. Pankiw
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Patent number: 7959854Abstract: A heat resistant alloy comprising, in % by weight, over 0.6% to not more than 0.9% of C, up to 2.5% of Si, up to 3.0% of Mn, 20 to 28% of Cr, 8 to 55% of Ni, 0.01 to 0.8% of Ti and 0.05 to 1.5% of Nb, the balance being Fe and inevitable impurities, the value of (Ti+Nb)/C being 0.12 to 0.29 in atomic % ratio. When the alloy further contains up to 0.5% of Zr, the value of (Ti+Nb+Zr)/C is 0.12 to 0.29 in atomic % ratio. When the alloy is heated at a temperature of at least about 800 degrees C., a fine Ti—Nb—Cr carbide or Ti—Nb—Zr—Cr carbide precipitates within grains to thereby retard creep deformation and give an improved creep rupture strength. The alloy is therefore suitable as a material for hydrogen production reforming tubes.Type: GrantFiled: October 30, 2006Date of Patent: June 14, 2011Assignee: Kubota CorporationInventors: Makoto Takahashi, Kunihide Hashimoto, Makoto Hineno
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Patent number: 7901519Abstract: A precipitation hardenable martensitic stainless steel that includes, in percent by weight, 11.0 to 12.5 percent chromium, 1.0 to 2.5 percent molybdenum, 0.15 to 0.5 percent titanium, 0.7 to 1.5 percent aluminum, 0.5 to 2.5 percent copper, 9.0 to 11.0 percent nickel, up to 0.02 percent carbon, up to 2.0 percent tungsten, and up to 0.001 percent boron. Articles formed from the stainless steel and methods of forming the same are also disclosed.Type: GrantFiled: December 10, 2003Date of Patent: March 8, 2011Assignee: ATI Properties, Inc.Inventor: Wei-Di Cao
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Patent number: 7879159Abstract: A precipitation-hardened stainless maraging steel which exhibits a combination of strength, toughness, and corrosion resistance comprises by weight about: 8 to 15% chromium (Cr), 2 to 15% cobalt (Co), 7 to 14% nickel (Ni), and up to about 0.7% aluminum (Al), less than about 0.4% copper (Cu), 0.5 to 2.6% molybdenum (Mo), 0.4 to less than about 0.75% titanium (Ti), up to about 0.5% tungsten (W), and up to about 120 wppm carbon (C), the balance essentially iron (Fe) and incidental elements and impurities, characterized in that the alloy has predominantly lath martensite microstructure essentially without topologically close packed intermetallic phases and strengthened primarily by a dispersion of intermetallic particles primarily of the eta-Ni3Ti phase and wherein the titanium and carbon (Ti) and (C) levels are controlled such that C can be dissolved during a homogenization step and subsequently precipitated during forging to provide a grain-pinnning dispersion.Type: GrantFiled: January 25, 2006Date of Patent: February 1, 2011Assignee: QuesTek Innovations, LLCInventors: James Wright, Jin-Won Jung
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Patent number: 7842141Abstract: A steel composition contains: 0.05% or less of C; 0.5% or less of Si; 0.20% to 1.80% of Mn; 0.03% or less of P; 0.005% or less of S; 14.0% to 18.0% of Cr; 5.0% to 8.0% of Ni; 1.5% to 3.5% of Mo; 0.5% to 3.5% of Cu; 0.05% or less of Al; 0.20% or less of V; 0.01% to 0.15% of N; and 0.006% or less of O on a mass basis, and satisfies the following expressions: Cr+0.65Ni+0.6Mo+0.55Cu?20C?18.5 and Cr+Mo+0.3Si?43.5C?0.4Mn?Ni?0.3Cu?9N?11 (where Cr, Ni, Mo, Cu, C, Si, Mn, and N represent their respective contents (mass %)). After such a steel pipe material is formed into a steel pipe, the steel pipe is quenched by cooling after heating to a temperature of the AC3 transformation point or more and tempered at a temperature of the AC1 transformation point or less.Type: GrantFiled: April 2, 2009Date of Patent: November 30, 2010Assignee: JFE Steel CorporationInventors: Mitsuo Kimura, Takanori Tamari, Takaaki Toyooka
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Patent number: 7815848Abstract: A corrosion resistant alloy is provided which includes, in percent by weight: (a) 16 to 24% Ni; (b) 18 to 26% Cr; (c) 1.5 to 3.5% Mo; (d) 0.5 to 1.5% Si; (e) 0.001 to 1.5% Nb; (f) 0.0005 to 0.5% Zr; (g) 0.01 to 0.6% N; (h) 0.001 to 0.2% Al; (j) less than 0.2% Ti; and (k) less than 1% Mn, trace impurities, and the balance Fe. Articles, such as flexible automotive exhaust couplings, including the present alloys are also provided.Type: GrantFiled: April 23, 2007Date of Patent: October 19, 2010Assignee: Huntington Alloys CorporationInventors: James Roy Crum, Nathan Charles Eisinger, Stephen Mark Gosnay, Gaylord Darrell Smith
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Publication number: 20100196799Abstract: The present invention relates to the use of the A286 alloy grade for the manufacture of a sheet, optionally surfaced, making it possible to obtain a conducting plate of mono polar or bipolar type for a fuel cell element. The invention also relates to this optional surface treatment process, which comprises a cold-rolling step followed by a continuous annealing step in an oxidizing atmosphere and by an acid pickling step.Type: ApplicationFiled: June 19, 2007Publication date: August 5, 2010Applicants: L'Air Liquide Societe Anonyme Pour L'Etude et L'Exploration DesProcedes George Claude, Arcelormittal-Stainless & Nickel Alloys, Alfa Laval Corporate ABInventors: Eric Claude, Richard Bousquet, Gilles Platen, Claude Roussel
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Patent number: 7754142Abstract: A high-carbon austenitic iron-base alloy with good corrosion and wear resistance, particularly useful for valve seat insert applications when corrosion resistance is required, comprises about 1.8-3.5 wt % carbon, about 12-24 wt % chromium, about 0.5-4 wt % silicon, about 12-25 wt % nickel, about 2-12 wt % molybdenum and tungsten combined, about 0.05-4 wt % niobium and vanadium combined, about 0-1 wt % titanium, about 0.01-0.2 wt % aluminum, about 0.05-3 wt % copper, and less than 1.5 wt % manganese, with the balance being iron and a small amount of impurities.Type: GrantFiled: April 13, 2007Date of Patent: July 13, 2010Assignee: Winsert, Inc.Inventor: Xuecheng Liang
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Patent number: 7749432Abstract: A cast, austenitic steel composed essentially of, expressed in weight percent of the total composition, about 0.4 to about 0.7 C, about 20 to about 30 Cr, about 20 to about 30 Ni, about 0.5 to about 1 Mn, about 0.6 to about 2 Si, about 0.05 to about 1 Nb, about 0.05 to about 1 W, about 0.05 to about 1.0 Mo, balance Fe, the steel being essentially free of Ti and Co, the steel characterized by at least one microstructural component selected from the group consisting of MC, M23C6, and M(C, N).Type: GrantFiled: January 19, 2005Date of Patent: July 6, 2010Assignee: UT-Battelle, LLCInventors: Govindarajan Muralidharan, Vinod Kumar Sikka, Philip J. Maziasz, Roman I. Pankiw
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Publication number: 20100154939Abstract: By focusing on the non-diffusible hydrogen that causes hydrogen embrittlement of austenitic stainless steel, the present invention provides an austenitic stainless steel in which the non-diffusible hydrogen is removed by maintaining the austenitic stainless steel in a vacuum of 0.2 Pa or less and heating at a heating temperature of 200° C. to 500° C. for 460 hours or less to remove the hydrogen (H) contained therein to a level of 0.00007 mass % (0.7 mass ppm) or less.Type: ApplicationFiled: January 15, 2010Publication date: June 24, 2010Applicant: NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGYInventors: Yukitaka MURAKAMI, Saburo MATSUOKA, Yoji MINE, Toshihiko KANEZAKI
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Publication number: 20100147247Abstract: A superaustenitic stainless steel comprises in weight %, 0.15 to 0.9% C, 0.2 to 1.3% Si, 0 to 0.45% Mn, 32.5 to 37.5% Cr, 13.5 to 17.5% Ni, 3.2 to 5.5% Mo, 0 to 2% Nb, 0 to 0.5% B, 0 to 2% Zr and 30 to 51% Fe. In a preferred embodiment, the superaustenitic stainless steel consists essentially of, in weight %, 0.5 to 0.9% C, 0.2 to 0.5% Si, 0.2 to 0.4% Mn, 33.0 to 35.0% Cr, 15.5 to 17.5% Ni, 4.0 to 4.5% Mo, 0.7 to 0.9% Nb, 0.07 to 0.13% B, 0 to 0.05% Zr and 40 to 46% Fe. The superaustenitic stainless steel is useful for valve seat inserts for internal combustion engines such as diesel or natural gas engines.Type: ApplicationFiled: December 16, 2008Publication date: June 17, 2010Applicant: L. E. Jones CompanyInventors: CONG YUE QIAO, Todd Trudeau
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Patent number: 7731895Abstract: An austenitic stainless steel improved in creep strength, creep ductility, weldability and also hot workability. The steel, consisting of, by mass %, C: 0.05-0.15%, Si: not more than 2%, Mn: 0.1-3%, P: 0.05-0.30%, S: not more than 0.03%, Cr: 15-28%, Ni: 8-55%, Cu: 0-3.0%, Ti: 0.05-0.6%, REM: 0.001-0.5%, sol. Al: 0.001-0.1%, N: not more than 0.03%, and the balance being Fe and incidental impurities. This steel may contain one or more of Mo, W, B, Nb, V, Co, Zr, Hf, Ta, Mg and Ca. It is preferable that REM is Nd.Type: GrantFiled: October 3, 2007Date of Patent: June 8, 2010Assignee: Sumitomo Metal Industries, Ltd.Inventors: Hirokazu Okada, Masaaki Igarashi, Kazuhiro Ogawa, Yasutaka Noguchi
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Patent number: 7708842Abstract: A metal gasket formed from a suitable iron-nickel chromium alloy includes at least one embossment that exhibits essentially full functional recovery at temperatures exceeding 1000° F. and including in the range of 1100° F. to 1600° F. or more and which is made from sheet material that is work hardened and strengthened by cold rolling, or a combination of cold rolling and precipitation hardening, without any post embossment heat treating that would act to further harden the material. Suitable iron-nickel-chromium alloys include those comprising, by weight, greater than 18% nickel; greater than 14% chrome and 0.1-10% of at least one element selected from the group consisting of Mo, Ti, V, Al, Co, Nb, Ta and Cu, with the balance being substantially Fe, wherein the gasket sheet alloy has a deformed microstructure.Type: GrantFiled: July 3, 2007Date of Patent: May 4, 2010Assignee: Federal-Mogul World Wide, Inc.Inventor: Thomas Zurfluh
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Publication number: 20100074791Abstract: A ferrous abrasion resistant sliding material capable of improving seizing resistance, abrasion resistance and heat crack resistance is provided. The ferrous abrasion resistant sliding material has a martensite parent phase which forms a solid solution with carbon of 0.15 to 0.5 wt %, and the martensite parent phase contains one or more types of each special carbide of Cr, Mo, W and V dispersed therein in a total content of 10 to 50% by volume.Type: ApplicationFiled: November 30, 2009Publication date: March 25, 2010Inventor: Takemori Takayama
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Publication number: 20100054983Abstract: An austenitic stainless steel, which comprises by mass %, C<0.04%, Si?1.5%, Mn?2%, Cr: 15 to 25%, Ni: 6 to 30%, N: 0.02 to 0.35%, sol. Al?0.03% and further contains one or more elements selected from Nb?0.5%, Ti?0.4%, V?0.4%, Ta?0.2%, Hf?0.2% and Zr?0.2%, with the balance being Fe and impurities, and among the impurities P?0.04%, S?0.03%, Sn?0.1%, As?0.01%, Zn?0.01%, Pb?0.01% and Sb?0.01%, and satisfy the conditions F1=S+{(P+Sn)/2}+{(As+Zn+Pb+Sb)/5}?0.0075 and 0.05?F2=Nb+Ta+Zr+Hf+2Ti+(V/10)?1.7?9×F1 has not only excellent liquation cracking resistance in the HAZ on the occasion of welding and excellent embrittling cracking resistance in the HAZ during a long period of use at high temperatures but also excellent polythionic acid SCC resistance and high temperature strength.Type: ApplicationFiled: August 28, 2009Publication date: March 4, 2010Inventors: Takahiro OSUKI, Kazuhiro OGAWA, Hiroyuki HIRATA, Yoshitaka NISHIYAMA
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Patent number: 7651575Abstract: An Fe—Ni-based alloy that has improved wear resistance at high temperature over Ni-based superalloys is provided. The alloy is particularly useful for manufacturing engine exhaust valves and other high temperature engine components subjected to corrosion, wear and oxidation.Type: GrantFiled: June 27, 2007Date of Patent: January 26, 2010Assignee: Eaton CorporationInventors: Maria K. Sawford, Shubhayu Sinharoy, Sundaram L. Narasimhan, Alojz Kajinic, Andrzej L. Wojcieszynski, Jeryl K. Wright
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Publication number: 20090098319Abstract: A heat resistant alloy comprising, in % by weight, over 0.6% to not more than 0.9% of C, up to 2.5% of Si, up to 3.0% of Mn, 20 to 28% of Cr, 8 to 55% of Ni, 0.01 to 0.8% of Ti and 0.05 to 1.5% of Nb, the balance being Fe and inevitable impurities, the value of (Ti+Nb)/C being 0.12 to 0.29 in atomic % ratio. When the alloy further contains up to 0.5% of Zr, the value of (Ti+Nb+Zr)/C is 0.12 to 0.29 in atomic % ratio. When the alloy is heated at a temperature of at least about 800 degrees C., a fine Ti—Nb—Cr carbide or Ti—Nb—Zr—Cr carbide precipitates within grains to thereby retard creep deformation and give an improved creep rupture strength. The alloy is therefore suitable as a material for hydrogen production reforming tubes.Type: ApplicationFiled: October 30, 2006Publication date: April 16, 2009Applicant: KUBOTA CORPORATIONInventors: Makoto Takahashi, Kunihide Hashimoto, Makoto Hineno
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Publication number: 20090081069Abstract: An austenitic stainless steel, which comprises by mass percent, C: not more than 0.10%, Si: 0.01 to 1.0%, Mn: 0.01 to 2%, Cr: 16 to 18%, Ni: more than 10% to less than 14%, Mo: more than 2.0% to not more than 3.0%, N: 0.03 to 0.10%, one or more elements selected from V, Nb and Ti satisfying the following formulas (1) and (2), 0.0013?(V/51)+(Nb/93)+(Ti/48)?0.0025??(1), {(C/12)+(N/14)}?{(V/51)+(Nb/93)+(Ti/48)}?0.0058??(2), wherein each element symbol in the formulas (1) and (2) represents the content (by mass %) of the element concerned, with the balance being Fe and impurities, wherein the content of P is not more than 0.04% and the content of S is not more than 0.003% among the impurities, has excellent corrosion resistance, in particular, excellent intergranular corrosion resistance. The preferable contents of Nb and Ti are not more than 0.030% and not more than 0.050%, respectively.Type: ApplicationFiled: November 25, 2008Publication date: March 26, 2009Inventors: Kiyoko Takeda, Masayuki Sagara, Masaaki Terunuma
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Publication number: 20080304996Abstract: An austenitic stainless steel HTUPS alloy includes, in weight percent: 15 to 30 Ni; 10 to 15 Cr; 2 to 5 Al; 0.6 to 5 total of at least one of Nb and Ta; no more than 0.3 of combined Ti+V; up to 3 Mo; up to 3 Co; up to 1 W; up to 0.5 Cu; up to 4 Mn; up to 1 Si; 0.05 to 0.15 C; up to 0.15 B; up to 0.05 P; up to 1 total of at least one of Y, La, Ce, Hf, and Zr; less than 0.05 N; and base Fe, wherein the weight percent Fe is greater than the weight percent Ni wherein said alloy forms an external continuous scale comprising alumina, nanometer scale sized particles distributed throughout the microstructure, said particles comprising at least one composition selected from the group consisting of NbC and TaC, and a stable essentially single phase fcc austenitic matrix microstructure, said austenitic matrix being essentially delta-ferrite-free and essentially BCC-phase-free.Type: ApplicationFiled: April 16, 2008Publication date: December 11, 2008Applicant: UT-BATTELLE, LLCInventors: Michael P. Brady, Michael L. Santella, Yukinori Yamamoto, Chain-tsuan Liu
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Patent number: 7455811Abstract: An iron based brazing material for joining objects by brazing represents an alloy, which apart from iron contains approximately 9-30% Cr, approximately 0-8% Mn, approximately 0-25% Ni, 0-1% N, a maximum of 7% Mo, less than about 6% Si, approximately 0-2% B and/or about 0-15% P, all stated in weight percent, which addition of Si, P, and B in combination or separately lowers the liquidus temperature, that is the temperature at which the brazing material is completely melted. A brazed product is manufactured by brazing of iron based objects with an iron based brazing material which is alloyed with a liquidus lowering element as Si, P and B.Type: GrantFiled: June 3, 2002Date of Patent: November 25, 2008Assignee: Alfa Laval Corporate ABInventor: Per Erik Sjodin
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Publication number: 20080008617Abstract: An Fe—Ni-based alloy that has improved wear resistance at high temperature over Ni-based superalloys is provided. The alloy is particularly useful for manufacturing engine exhaust valves and other high temperature engine components subjected to corrosion, wear and oxidation.Type: ApplicationFiled: June 27, 2007Publication date: January 10, 2008Inventors: Maria K. Sawford, Shubhayu Sinharoy, Sundaram L. Narasimhan, Alojz Kajinic, Andrzej L. Wojcieszynski, Jeryl K. Wright
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Publication number: 20070258844Abstract: A corrosion resistant alloy is provided which includes, in percent by weight: (a) 16 to 24% Ni; (b) 18 to 26% Cr; (c) 1.5 to 3.5% Mo; (d) 0.5 to 1.5% Si; (e) 0.001 to 1.5% Nb; (f) 0.0005 to 0.5% Zr; (g) 0.01 to 0.6% N; (h) 0.001 to 0.2% Al; (j) less than 0.2% Ti; and (k) less than 1% Mn, trace impurities, and the balance Fe. Articles, such as flexible automotive exhaust couplings, including the present alloys are also provided.Type: ApplicationFiled: April 23, 2007Publication date: November 8, 2007Applicant: Huntington Alloys CorporationInventors: James Roy Crum, Nathan Charles Eisinger, Stephen Mark Gosnay, Gaylord Darrell Smith
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Patent number: 7014720Abstract: The present invention provides an austenitic stainless steel tube with a uniform fine grained structure of regular grains, which is not changed to a coarse structure and the steam oxidation resistance is maintained even if the tube is subjected to a high temperature reheating during welding and high temperature bending working. The austenitic stainless steel tube consists of, by mass %, C: 0.03–0.12%, Si: 0.1–0.9%, Mn: 0.1–2%, Cr: 15–22%, Ni: 8–15%, Ti: 0.002–0.05%, Nb: 0.3–1.5%, sol. Al: 0.0005–0.03%, N: 0.005–0.2% and O (oxygen): 0.001–0.008%, and the balance Fe and impurities, the austenitic stainless steel tube having austenitic grain size number of 7 or more and a mixed grain ratio of preferably 10% or less.Type: GrantFiled: March 5, 2003Date of Patent: March 21, 2006Assignee: Sumitomo Metal Industries, Ltd.Inventor: Atsuro Iseda
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Publication number: 20040156737Abstract: An austenitic stainless steel comprises, by weight, 9 to 23% chromium, 30 to 35% nickel, 1 to 6% molybdenum, 0 to 0.03% titanium, 0.15% to 0.6% aluminum, up to 0.1% carbon, 1 to 1.5% manganese, 0 to less than 0.8% silicon, 0.25 to 0.6% niobium and iron. Embodiments of austenitic stainless steels according to the present invention exhibit enhanced resistance to corrosion. Thus, the stainless steels of the present invention may find broad application as, for example, automotive components and, more particularly, as automotive exhaust system flexible connectors and other components, as well as in other applications in which corrosion resistance is desired.Type: ApplicationFiled: February 6, 2003Publication date: August 12, 2004Inventor: James M. Rakowski
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Patent number: 6562293Abstract: An article of equipment intended to be submerged in molten zinc and low percentage aluminum/zinc melts, said article containing an alloy material comprised of carbon, chromium, nickel, tungsten, molybdenum, vanadium, niobium (columbium), cobalt, boron, iron and/or zirconium, wherein vanadium is present in an amount sufficient to limit the &ggr;-region.Type: GrantFiled: November 6, 2000Date of Patent: May 13, 2003Assignee: Alphatech, Inc.Inventor: Jorge A. Morando
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Patent number: 6494789Abstract: A golf club head comprises a ball-hitting face made of a steel alloy containing maximum amounts of 0.03% of C by weight, 0.2% of Si by weight, 0.2% of Mn by weight, 0.2% of P by weight, 0.02% of S by weight, 10.5-11.0% of Cr by weight, 1.8-2.2% of Mo by weight, 9.5-10.5% of Ni by weight, 0.9-1.2% of Ti by weight, 0.5% of Al by weight, 0.1% of Cu by weight, 0.3% of Nb by weight, 0.3% of B by weight, 0.01% of N by weight, 0.1% of V by weight, 0.1% of W by weight, and the rest being Fe. The steel alloy is made by a metallurgical method involving two vacuum melting processes. The texture of the steel alloy is mainly formed of martensite.Type: GrantFiled: February 26, 2001Date of Patent: December 17, 2002Inventor: Archer C. C. Chen
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Patent number: 6485679Abstract: A heat resistant austenitic stainless steel with high strength at elevated temperatures, good steam oxidation resistance, good fire side corrosion resistance, and a sufficient structural stability, suitable for use in boilers operating at high temperatures has a composition (by weight) of. 0.04 to 0.10% carbon (C), not more than 0.4% silicon (Si), not more than 0.6% manganese (MN), 20 to 27% chromium (Cr), 22.5 to 32% nickel (Ni), not more than 0.5% molybdenum (Mo), 0,20 to 0.60% niobium (Nb), 0.4 to 4.0% tungsten (W), 0.10 to 0.30% nitrogen (N), 0.002 to 0.008% boron (B), less than 0.05% aluminium (Al), at least one of the elements Mg and Ca in amounts less than 0.010% Mg and less than 0.010% Ca, and the balance being iron and inevitable impuities.Type: GrantFiled: February 16, 2000Date of Patent: November 26, 2002Assignee: Sandvik ABInventors: Ann Sundström, Goucai Chai
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Patent number: 6352670Abstract: An austenitic stainless steel comprising, by weight, 17 to 23% chromium, 19 to 23% nickel, 1 to 6% molybdenum. The addition of molybdenum to the iron-base alloys of the invention increases their resistance to corrosion. The austenitic stainless steel may consisting essentially of, by weight, 17 to 23% chromium, 19 to 23% nickel, 1 to 6% molybdenum, 0 to 0.1% carbon, 0 to 1.5% manganese, 0 to 0.05% phosphorus, 0 to 0.02% sulfur, 0 to 1.0% silicon, 0.15 to 0.6% titanium, 0.15 to 0.6% aluminum, 0 to 0.75% copper, iron, and incidental impurities. Austenitic stainless steels according to the present invention exhibit enhanced resistance corrosion by salt at a broad temperature range up to at least 1500° F. Thus, the stainless steel of the present invention would find broad application as, for example, automotive components and, more particularly, as automotive exhaust system components and flexible connectors, as well as in other applications in which corrosion resistance is desired.Type: GrantFiled: August 18, 2000Date of Patent: March 5, 2002Assignee: ATI Properties, Inc.Inventor: James M. Rakowski