Zirconium, Vanadium Or Titanium Containing Patents (Class 420/81)
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Publication number: 20140363694Abstract: A low density high strength steel sheet including 0.15% to 0.25% C, 2.5% to 4% Mn, 0.02% or less P, 0.015% or less S, 6% to 9% Al and 0.01% or less N, the balance being iron and inevitable impurities, wherein 1.7·(Mn—Al)+52.7·C is at least 3 and at most 4.5. A method of producing the low density and high strength steel sheet.Type: ApplicationFiled: February 21, 2012Publication date: December 11, 2014Applicant: TATA STEEL NEDERLAND TECHNOLOGY BVInventors: Cheng Liu, Radhakanta Rana
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Patent number: 8778097Abstract: A low specific gravity and high strength steel sheet includes C of 0.2% to 0.8%, Mn of 2% to 10%, P of 0.02% or less, S of 0.015% or less, Al of 3% to 15%, and N of 0.01% or less. A ratio of Mn/Al is 0.4 to 1.0. Retained austenite in a structure is included in the range of 1% or more. The steel sheet further includes one or two or more elements selected from the group consisting of Si of 0.1% to 2.0%, Cr of 0.1% to 0.3%, Mo of 0.05% to 0.5%, Ni of 0.1% to 2.0%, Cu of 0.1% to 1.0%, B of 0.0005% to 0.003%, Ti of 0.01% to 0.2%, Zr of 0.005% to 0.2%, Nb of 0.005% to 0.2%, W of 0.1% to 1.0%, Sb of 0.005% to 0.2%, and Ca of 0.001% to 0.2%.Type: GrantFiled: October 29, 2008Date of Patent: July 15, 2014Assignee: PoscoInventors: Kwang Geun Chin, Jai Hyun Kwak
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Patent number: 8580190Abstract: An iron-chromium-aluminum alloy having a long service life and exhibiting little change in heat resistance, comprising (as percentages by weight) 4.5 to 6.5% Al, 16 to 24% Cr, 1.0 to 4.0% W, 0.05 to 0.7% Si, 0.001 to 0.5% Mn, 0.02 to 0.1% Y, 0.02 to 0.1% Zr, 0.02 to 0.1% Hf, 0.003 to 0.030% C, 0.002 to 0.03% N, a maximum of 0.01% S, and a maximum of 0.5% Cu, the remainder being iron and the usual steel production-related impurities.Type: GrantFiled: April 2, 2009Date of Patent: November 12, 2013Assignee: Outokumpu VDM GmbHInventor: Heike Hattendorf
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Patent number: 8449845Abstract: In light of the recent analytical technology demanded of fast and accurate measurement of high purity materials, a zirconium crucible is provided for melting an analytical sample and is capable of inhibiting the inclusion of impurities from the crucible by using a high-purity crucible, improving the durability of high-purity zirconium as an expensive crucible material, and increasing the number of times that the zirconium crucible can be used. With this zirconium crucible used for melting an analytical sample in the pretreatment of the analytical sample, the purity excluding gas components is 3N or higher, and the content of carbon as a gas component is 100 mass ppm or less.Type: GrantFiled: August 8, 2008Date of Patent: May 28, 2013Assignee: JX Nippon Mining & Metals CorporationInventors: Yuichiro Shindo, Masahiro Sakaguchi, Mitsuru Yamaguchi
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Patent number: 8153054Abstract: An iron-based high-temperature alloy is disclosed which contains the following chemical composition: 20% by weight Cr; 5 to 6% by weight Al; 4% by weight Ta; 4% by weight Mo; 3 to 4% by weight Re; 0.2% by weight Zr; 0.05% by weight B; 0.1% by weight Y; 0.1% by weight Hf; 0 to 0.05% by weight C; and remainder Fe and unavoidable impurities. The alloy can be produced at low cost and can possess outstanding oxidation resistance and good mechanical properties at temperatures up to 1200° C.Type: GrantFiled: July 24, 2009Date of Patent: April 10, 2012Assignee: Alstom Technology LtdInventors: Mohamed Nazmy, Andreas Künzler, Giuseppe Bandiera, Hanspeter Zinn
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Patent number: 7935883Abstract: A thermoelectric material has a composition expressed by (Fe1-pVp)100-x(Al1-qSiq)x (0.35?p?0.7, 0.01?q?0.7, 20?x?30 atomic %). The thermoelectric material includes a crystal phase having an L21 structure or a crystal phase having a B2 structure as a main phase.Type: GrantFiled: September 4, 2007Date of Patent: May 3, 2011Assignee: Kabushiki Kaisha ToshibaInventors: Shinya Sakurada, Naoki Shutoh
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Publication number: 20100300585Abstract: The invention relates to a hot-rolled ferritic steel sheet, the composition of the steel of which comprises, the contents being expressed by weight: 0.001?C?0.15%, Mn?1%, Si?1.5%, 6%?Al?10%, 0.020%?Ti?0.5%, S?0.050%, P?0.1%, and, optionally, one or more elements chosen from: Cr?1%, Mo?1%, Ni?1%, Nb?0.1%, V?0.2%, B?0.010%, the balance of the composition consisting of iron and inevitable impurities resulting from the smelting, the average ferrite grain size dIV measured on a surface perpendicular to the transverse direction with respect to the rolling being less than 100 microns.Type: ApplicationFiled: April 29, 2008Publication date: December 2, 2010Applicant: ARCELORMITTAL FRANCEInventors: Astrid Perlade, Xavier Garat, Jean-Louis Uriarte, Olivier Bouaziz, Josee Drillet
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Publication number: 20090297387Abstract: A low specific gravity and high strength steel sheet includes C of 0.2% to 0.8%, Mn of 2% to 10%, P of 0.02% or less, S of 0.015% or less, Al of 3% to 15%, and N of 0.01% or less. A ratio of Mn/Al is 0.4 to 1.0. Retained austenite in a structure is included in the range of 1% or more. The steel sheet further includes one or two or more elements selected from the group consisting of Si of 0.1% to 2.0%, Cr of 0.1% to 0.3%, Mo of 0.05% to 0.5%, Ni of 0.1% to 2.0%, Cu of 0.1% to 1.0%, B of 0.0005% to 0.003%, Ti of 0.01% to 0.2%, Zr of 0.005% to 0.2%, Nb of 0.005% to 0.2%, W of 0.1% to 1.0%, Sb of 0.005% to 0.2%, and Ca of 0.001% to 0.2%.Type: ApplicationFiled: October 29, 2008Publication date: December 3, 2009Applicant: POSCOInventors: Kwang Geun Chin, Jai Hyun Kwak
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Publication number: 20080236644Abstract: A thermoelectric material has a composition expressed by (Fe1-pVp)100-x(Al1-qSiq)x (0.35?p?0.7, 0.01?q?0.7, 20?x?30 atomic %). The thermoelectric material includes a crystal phase having an L21 structure or a crystal phase having a B2 structure as a main phase.Type: ApplicationFiled: September 4, 2007Publication date: October 2, 2008Applicant: Kabushiki Kaisha ToshibaInventors: Shinya Sakurada, Naoki Shutoh
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Patent number: 6830676Abstract: A cracking tube includes a lining of a fouling resistant and corrosion resistant iron aluminide alloy. The iron aluminide alloy can include 14-32 wt. % Al, at least 2 vol. % transition metal oxides, 0.003 to 0.020 wt. % B, 0.2 to 2.0 wt. % Mo, 0.05 to 1.0 wt. % Zr, 0.2 to 2.0 wt. % Ti, 0.10 to 1.0 wt. % La, 0.05 to 0.2 wt. % C., balance Fe, and optionally ≦1 wt. % Cr, and the coefficient of thermal expansion of the iron aluminide alloy is substantially the same as the coefficient of thermal expansion over the temperature range of ambient to about 1200° C. of an outer metal layer. A cracking tube utilizing the iron aluminide alloy can be formed from powders of the iron aluminide alloy by consolidation methods including cold isostatic pressing (CIP), hot isostatic pressing (HIP), reaction synthesis, spraying techniques, or co-extrusion with a second material of the cracking tube.Type: GrantFiled: June 11, 2001Date of Patent: December 14, 2004Assignee: Chrysalis Technologies IncorporatedInventor: Seetharama C. Deevi
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Patent number: 6383662Abstract: A high-strength lightweight steel and its use for car parts and facade linings is a purely ferritic steel having, in mass %, more than 5 to 9% Al, less than 0.2% Si, and 0.03 to 0.2% Mn.Type: GrantFiled: May 12, 2000Date of Patent: May 7, 2002Inventor: Georg Frommeyer
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Patent number: 5620651Abstract: The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, .ltoreq.1% Cr and either .gtoreq.0.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element or .gtoreq.0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, .ltoreq.1% oxygen, .ltoreq.3% Cu, balance Fe.Type: GrantFiled: April 20, 1995Date of Patent: April 15, 1997Assignee: Philip Morris IncorporatedInventors: Vinod K. Sikka, Seetharama C. Deevi, Grier S. Fleischhauer, Mohammad R. Hajaligol, A. Clifton Lilly, Jr.
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Patent number: 5618491Abstract: Disclosed is a stud for a boiler or other high temperature application, such as a furnace. The stud is made of an iron aluminum alloy which comprises about 81 to 91 wt. % iron, about 8 to 13 wt. % aluminum, about 0.01 to 0.3 wt. % carbon, and zero to about 3 wt. % of a refractory metal and/or zero to about 1.5 wt. % zirconium. The studs are welded to a surface of a component of the boiler or furnace by arc or resistance welding. The aluminum of the iron aluminum alloy imparts good oxidation and sulfidation resistance to the studs. The alloy also has a good electrical resistance which makes the alloy especially useful for arc or resistance welding. The aluminum content acts as a getter to eliminate gas porosity in the resulting welds. The present invention is particularly useful for making boiler heat exchange surfaces or refractory covered surfaces wherein the studs function as refractory anchors.Type: GrantFiled: February 22, 1996Date of Patent: April 8, 1997Assignee: TRW, Inc.Inventors: Mohan Kurup, Clark Champney
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Patent number: 5595706Abstract: The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have a disordered body centered cubic structure and improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, 4 to 9.5% Al, 0.2-2.0% Ti, 0.5-2% Mo, 0.1 to 0.8% Zr, 0.01-0.5% C, balance Fe.Type: GrantFiled: December 29, 1994Date of Patent: January 21, 1997Assignee: Philip Morris IncorporatedInventors: Vinod K. Sikka, Seetharama C. Deevi, Grier S. Fleischhauer, Mohammad R. Hajaligol, A. Clifton Lilly, Jr.
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Patent number: 5545373Abstract: This invention relates to improved corrosion-resistant iron-aluminide intermetallic alloys. The alloys of this invention comprise, in atomic percent, from about 30% to about 40% aluminum alloyed with from about 0.1% to about 0.5% carbon, no more than about 0.04% boron such that the atomic weight ratio of boron to carbon in the alloy is in the range of from about 0.01:1 to about 0.08:1, from about 0.01 to about 3.5% of one or more transition metals selected from Group IVB, VB, and VIB elements and the balance iron wherein the alloy exhibits improved resistance to hot cracking during welding.Type: GrantFiled: September 6, 1994Date of Patent: August 13, 1996Assignee: Martin Marietta Energy Systems, Inc.Inventors: Philip J. Maziasz, Gene M. Goodwin, Chain T. Liu
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Patent number: 5425821Abstract: The present invention resides in a method for making an internal combustion engine intake valve. An iron aluminum alloy, in the form of a coil or bar stock, is provided. The alloy comprises 76.05 to 90.15 weight percent iron, 9 to 13.3 weight percent aluminum, 0.05 to 0.35 weight percent carbon, and 0.5 to 3 weight percent of a refractory metal, and/or 0.3 to 1.5 weight percent of titanium in combination with, or in place of, the refractory metal. The coil or bar stock is extruded to a poppet valve preform configuration at a heading temperature in the range of 800.degree. to 2,000.degree. F. and a true strain of about 0.5 to 2.2. The preform configuration is then headed to a pre-machined configuration while maintaining the head of such preform at an effective heading temperature up to 2,200.degree. F. said heading being carried out at a true strain of about 1.4 to 2.3.Type: GrantFiled: May 13, 1994Date of Patent: June 20, 1995Assignee: TRW Inc.Inventors: Mohan Kurup, Roger R. Wills, Mark S. Scherer
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Patent number: 5411702Abstract: The iron-aluminum alloy comprises the following constituents in atom percent:______________________________________ 12-18 aluminum 0.1-10 chromium 0.1-2 niobium 0.1-2 silicon 0.1-5 boron 0.01-2 titanium 100-500 ppm carbon 50-200 ppm zirconium remainder iron. ______________________________________This alloy is distinguished by high thermal-shock resistance and, at temperatures of 800.degree. C., still has comparatively good mechanical properties. The alloy can be used advantageously in components such as, for example, casings of gas turbines, which, with comparatively low mechanical loading, are subject to frequent thermal cycling.Type: GrantFiled: December 28, 1993Date of Patent: May 2, 1995Assignee: ABB Management AGInventors: Mohamed Nazmy, Corrado Noseda, Markus Staubli
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Patent number: 5328527Abstract: The present invention resides in a method for making an internal combustion engine intake valve. An iron aluminum alloy, in the form of a coil or bar stock, is provided. The alloy comprises 76.05 to 90.15 weight percent iron, 9 to 13.3 weight percent aluminum, 0.05 to 0.35 weight percent carbon, and 0.5 to 3 weight percent of a refractory metal, and/or 0.3 to 1.5 weight percent of titanium in combination with, or in place of, the refractory metal. The coil or bar stock is extruded to a poppet valve preform configuration at a heading temperature in the range of 800.degree. to 2,000.degree. F. and a true strain of about 0.5 to 2.2. The preform configuration is then headed to a pre-machined configuration while maintaining the head of such preform at an effective heading temperature up to 2,200.degree. F., said heading being carried out at a true strain of about 1.4 to 2.3.Type: GrantFiled: December 15, 1992Date of Patent: July 12, 1994Assignee: TRW Inc.Inventors: Mohan Kurup, Roger R. Wills, Mark S. Scherer
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Patent number: 5320802Abstract: The specification discloses a corrosion-resistant intermetallic alloy comprising, in atomic percent, an FeAl iron aluminide containing from about 30 to about 40% aluminum alloyed with from about 0.01 to 0.4% zirconium and from 0.01 to about 0.8% boron. The alloy exhibits considerably improved room temperature ductility for enhanced usefulness in structural applications. The high temperature strength and fabricability is improved by alloying with molybdenum, carbon, chromium and vanadium.Type: GrantFiled: May 15, 1992Date of Patent: June 14, 1994Assignee: Martin Marietta Energy Systems, Inc.Inventors: Chain T. Liu, Claudette G. McKamey, Peter F. Tortorelli, Stan A. David
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Patent number: 5085829Abstract: An oxidation-resistant Fe-Cr-Al steel, having superior workability, oxidation resistance at high temperature and corrosion resistance, has a composition which contains: up to but not more than about 0.05 wt % of C; about 0.1 to about 1.0 wt % of Si; up to but not more than about 1.0 wt % of Mn; from about 3.0 to 7.5 wt % of Cr; from about 4.5 to 6.5 wt % of Al; up to but not more than about 0.05 wt % of N; one or more elements selected from about the group consisting of 1), from about 0.01 wt % to 0.3 wt % of Zr, 2), from 0.01 wt % to 0.3 wt % of Ti, and 3), from about 0.001 wt % to 0.2 wt %, expressed as a total, of Y, La, Ce, Pr, Nd and Hf; and the balance sustantially Fe and incidental inclusions.Type: GrantFiled: December 21, 1990Date of Patent: February 4, 1992Assignee: Kawasaki Steel CorporationInventors: Kazuhide Ishii, Tatsuo Kawasaki
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Patent number: 4988488Abstract: The present invention is directed to a chemical air separation process using a molten salt solution of alkali metal nitrate and nitrite wherein the materials of construction of the containment for the process are chosen from intermetallic alloys of nickel and/or iron aluminide wherein the aluminum content is 28 atomic percent or greater to impart enhanced corrosion resistance.Type: GrantFiled: October 19, 1989Date of Patent: January 29, 1991Assignee: Air Products and Chemicals, Inc.Inventor: Doohee Kang
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Patent number: 4961903Abstract: An improved iron aluminide alloy of the DO.sub.3 type that has increased room temperature ductility and improved high elevated temperature strength. The alloy system further is resistant to corrosive attack in the environments of advanced energy corrosion systems such as those using fossil fuels. The resultant alloy is relatively inexpensive as contrasted to nickel based and high nickel steels currently utilized for structural components. The alloy system consists essentially of 26-30 at. % aluminum, 0.5-10 at. % chromium, 0.02-0.3 at. % boron plus carbon, up to 2 at. % molybdenum, up to 1 at. % niobium, up to 0.5 at. % zirconium, up to 0.1 at. % yttrium, up to 0.5 at. % vanadium and the balance iron.Type: GrantFiled: March 7, 1989Date of Patent: October 9, 1990Assignee: Martin Marietta Energy Systems, Inc.Inventors: Claudette G. McKamey, Chain T. Liu
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Patent number: 4861548Abstract: A non-magnetic steel composition suitable for use in various steel and concrete structures, particularly magnetic floating high-speed railways, nuclear fusion facilities and marine structures and appliances where non-magnetic property is required. The steel composition containsC: not more than 1.0%Si: not more than 0.25%Mn: not more than 2.0%Al: more than 20.0 to 37.3%Cr: more than 1.0 to 5.5%P: not more than 0.015%S: not more than 0.005%and may further contain at least one of Ti, V, Nb, W, Mo, and B in an amount ranging from 0.01 to 0.5%, in total, for the elements other than B and in an amount ranging from 0.0001 to 0.005% for B, and at least one of Cu and Ni in an amount ranging from 0.1 to 5.5%, in total.Type: GrantFiled: January 6, 1988Date of Patent: August 29, 1989Assignee: Nippon Steel CorporationInventors: Haruo Shimada, Yoshiaki Sakakibara
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Patent number: 4844865Abstract: A non-magnetic steel material suitable for use in various steel and concrete structures such as magnetic floating high-speed railways, nuclear fusion facilities and marine structrures and appliances where non-magnetic properties are required. The steel composition contain (by weight):C: not more than 1.0%Si: not more than 0.25%Mn: not more than 2.0%Al: more than 20.0 to 37.3%P: not more than 0.015%S: not more than 0.005%Cr: more than 5.5 to 15.0%and may further contain at least one of Ti, V, Nb, W, Co, Mo and B in an amount ranging from 0.01 to 0.5% for the elements other than B, and in an amount ranging from 0.0001 to 0.005% for B, and at least one of Cu and Ni in an amount ranging from 0.1 to 5.5%.Type: GrantFiled: November 25, 1987Date of Patent: July 4, 1989Assignee: Nippon Steel CorporationInventors: Haruo Shimada, Yoshiaki Sakakibara
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Patent number: 4836981Abstract: Concrete reinforcing steel bars or wires useful for reinforcing concrete structures, such as concrete structures built on seashores and marine concrete structures, and concrete bridges, which are exposed to sea salt particles and sea-water splashes, and very excellent in preventing deteriorations or decays of these concrete structures. The steel bars or wires have the following composition,C: not more than 1.0%Si: not more than 0.25%Mn: not more than 2.0%Al: 10.0 to 20.0%CR: 0.5 to 5.5%P: not more than 0.015%S: not more than 0.005%Balance: iron and unavoidable impurities.The steel bars or wires may further contain at least one element selected from Ti, V, Nb, W, Mo or B in such amounts that the total weight range for elements other than B is 0.01 to 0.5% and in amounts ranging from 0.0001 to 0.0005% for B. The bar or wire also may optionally contain Cu and/or Ni in total amounts ranging from 0.1 to 5.5%.Type: GrantFiled: January 25, 1988Date of Patent: June 6, 1989Assignee: Nippon Steel CorporationInventors: Haruo Shimada, Yoshiaki Sakakibara
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Patent number: 4780276Abstract: About ten weight percent nickel is added to a Fe-base alloy which has a ferrite microstructure to improve the high temperature castability and crack resistance while about 0.2 weight percent zirconium is added for improved high temperature cyclic oxidation and corrosion resistance. The basic material is a high temperature FeCrAl heater alloy, and the addition provides a material suitable for burner rig nozzles.Type: GrantFiled: October 14, 1987Date of Patent: October 25, 1988Assignee: The Unites States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Charles A. Barrett, William H. Holt
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Patent number: 4684505Abstract: A high temperature alloy displaying excellent elevated temperature properties as well as low strategic metals content. Based on the iron/aluminum system, the alloy contains about 10 to 19% aluminum, 2 to 8% titanium, from about 0.5 to 10% molybdenium, from 0.1 to 1% hafnium and the balance substantially iron.Type: GrantFiled: June 11, 1985Date of Patent: August 4, 1987Assignee: Howmet Turbine Components CorporationInventors: John R. Brinegar, William R. Freeman