Aluminosilicate Other Than Zeolite Patents (Class 423/118.1)
  • Patent number: 10792616
    Abstract: The present disclosure is directed to SCR catalysts, methods for their manufacture, and methods of treating emissions in an exhaust stream with them. The SCR catalysts are produced from pillaring and ion exchanging synthetic phyllosilicates, particularly hydrothermally synthesized phyllosilicates.
    Type: Grant
    Filed: August 12, 2016
    Date of Patent: October 6, 2020
    Assignee: BASF Corporation
    Inventors: Xiaoming Wang, Xiaofan Yang, Meaghan C. McGuire, Geoffrey M. Johnson, John K. Hochmuth
  • Patent number: 10782078
    Abstract: A heat dissipation coating layer contains: a binder and a core-shell heat dissipation filler. The core-shell heat dissipation filler is synthesized in a water bathing process at the temperature within 20° C. to 100° C. The core-shell heat dissipation filler includes a metal core and a shell composed of the mixture of oxide and hydroxide shell. Here the metal core has metal particles, and the shell has a porous structure consisted of a mixture of metal oxide and porous metal hydroxide.
    Type: Grant
    Filed: October 31, 2018
    Date of Patent: September 22, 2020
    Assignee: BGT Materials Limited
    Inventors: Chung-Ping Lai, Kuo-Hsin Chang, Jia-Cing Chen, We-Jei Ke
  • Patent number: 10399859
    Abstract: Described herein are methods and compositions for zeolite synthesis. The methods and compositions involve modifying a colloidal silica sol with a metal compound and in the presence of a structure directing agent, followed by heating to form a zeolite. The methods and compositions result in rapid zeolite formation, even at reduced concentrations of structure directing agent.
    Type: Grant
    Filed: October 26, 2016
    Date of Patent: September 3, 2019
    Assignee: Ecolab USA Inc.
    Inventors: Francois Batllo, Wenyong Lin, Yulia Tataurova, George Salomon, Shiby John
  • Patent number: 9826737
    Abstract: Disclosed is a solid arthropodicide composition comprising by weight (a) from 0.3 to 100% of a particulate component comprising particles of a solid carrier infiltrated with a mixture comprising (i) one or more carboxamide arthropodicides and (ii) a surfactant constituent; (b) from 0 to 50% of a surfactant component having dispersing and wetting properties; and (c) from 0 to 99.7% of one or more additional formulating ingredients. Also disclosed is a propagule contacted with a biologically effective amount of said composition.
    Type: Grant
    Filed: September 5, 2013
    Date of Patent: November 28, 2017
    Assignee: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: Oliver Walter Gutsche, John Henry Green
  • Patent number: 9284456
    Abstract: Superficially porous hybrid particles include hybrid solid cores that each contain an inorganic material and an organic material; and porous hybrid outer shells each include the inorganic and organic materials and having ordered pores, wherein the ordered pores have a median pore size ranges from about 15 to about 1000 ? with a pore size distribution (one standard deviation) of no more than 50% of the median pore size and produce at least one X-ray diffraction peak between 0.01° and 10° of a 2? scan range; wherein the particles have a median size range from about 0.5 ?m to about 100 ?m with a particle size distribution (one standard deviation) of no more than 15% of the median particle size, wherein the inorganic material comprises a metal oxide selected from silica, alumina, titania or zirconia.
    Type: Grant
    Filed: September 13, 2012
    Date of Patent: March 15, 2016
    Assignee: Agilent Technologies, Inc.
    Inventors: Charles Lofton, Ta-Chen Wei, William E Barber, Wu Chen
  • Patent number: 8980784
    Abstract: Silicon-aluminum mixed oxide powder having a weight ratio of (Al2O3/SiO2)ttl in the total primary particle of from 0.003 to 0.05, a weight ratio (Al2O3/SiO2)surface of the primary particles in a surface layer having a thickness of about 5 nm which is less than in the total primary particle and a BET surface area of from 50 to 250 m2/g. It is prepared by igniting one or more silicon compounds selected from the group consisting of CH3SiCl3, (CH3)2SiCl2, (CH3)3SiCl and (n-C3H7)SiCl3, a hydrolysable and oxidizable aluminum compound, at least one fuel gas and air and burning the flame into a reaction chamber, subsequently separating the solid from gaseous materials and subsequently treating the solid with water vapor. The silicon-aluminum mixed oxide powder can be used as catalyst.
    Type: Grant
    Filed: February 3, 2012
    Date of Patent: March 17, 2015
    Assignee: Evonik Degussa GmbH
    Inventors: Christian Schulze Isfort, Horst-Werner Zanthoff, Thomas Quandt, Christian Boeing
  • Patent number: 8967383
    Abstract: The present disclosure teaches improved processes to produce high-brightness kaolins at high yields from various natural sources of crude kaolin. In some embodiments, a process for treating mined kaolin comprises: blunging kaolin material with water at high shear to form a slurry; introducing the slurry to one or more beneficiation units for flocculation of titania (e.g., anatase) and titania-associated impurities (e.g., iron); introducing a sodium silicate composition, or precursors thereof, to the beneficiation units, wherein the sodium silicate composition is characterized by a Na2O/SiO2 ratio selected from about 0.25 to about 2.5; and recovering a suspension comprising at least 70% of the kaolin clay. The selected sodium silicate composition enhances flocculation of the titania while maintaining dispersion of the kaolin clay in the slurry. One or more chemical leaching reactions generate a treated kaolin that is characterized by a brightness of about 90 or higher.
    Type: Grant
    Filed: October 16, 2013
    Date of Patent: March 3, 2015
    Assignee: KaMin, LLC
    Inventors: Deqiang Ma, Charles Allen Newsome, Aubrey Clay Smith, John Taylor, Richard Douglas Carter
  • Publication number: 20140301921
    Abstract: Amine-aldehyde resins are disclosed for removing a wide variety of solids and/or ionic species from the liquids in which they are suspended and/or dissolved. These resins are especially useful as froth flotation depressants, for example in the beneficiation of value materials (e.g., bitumen, coal, or kaolin clay) to remove impurities such as sand. The resins are also useful for treating aqueous liquid suspensions to remove solid particulates, as well as for removing metallic ions in the purification of water.
    Type: Application
    Filed: June 23, 2014
    Publication date: October 9, 2014
    Inventors: James T. Wright, John B. Hines, Lisa M. Arthur, Carl R. White, Kurt D. Gabrielson, Michael J. Cousin
  • Patent number: 8685283
    Abstract: Micelle-templated superficially porous particles having a solid core and an outer porous shell with ordered pore structures and a narrow particle size distribution, such as about ±5% (one sigma), and a high specific surface area of about 5 to about 1000 m2/g.
    Type: Grant
    Filed: August 29, 2008
    Date of Patent: April 1, 2014
    Assignee: Agilent Technologies, Inc.
    Inventors: Ta-Chen Wei, Wu Chen, William E. Barber
  • Patent number: 8545776
    Abstract: The invention provides a method of inhibiting the accumulation of DSP scale in the liquor circuit of Bayer process equipment. The method includes adding one or more particular silane based small molecules to the liquor fluid circuit. These scale inhibitors reduce DSP scale formation and thereby increase fluid throughput, increase the amount of time Bayer process equipment can be operational and reduce the need for expensive and dangerous acid washes of Bayer process equipment. As a result, the invention provides a significant reduction in the total cost of operating a Bayer process.
    Type: Grant
    Filed: September 25, 2009
    Date of Patent: October 1, 2013
    Assignee: Nalco Company
    Inventors: Timothy La, Ji Cui, John D. Kildea, David H. Slinkman
  • Patent number: 8529851
    Abstract: New process for obtaining lithium aluminosilicate-based (LAS) ceramic materials having a near-zero and negative thermal expansion coefficient within a temperature range of (?150° C. to 450° C.). These materials are applicable to the manufacture of components that require a high level of dimensional stability.
    Type: Grant
    Filed: November 27, 2009
    Date of Patent: September 10, 2013
    Assignee: Consejo Superior de Investigaciones Científicas (CSIC)
    Inventors: Ramón Torrecillas San Millán, Adolfo Fernández Valdés, Olga García Moreno
  • Patent number: 8501142
    Abstract: This disclosure relates to carbonizing and activating carbonaceous material.
    Type: Grant
    Filed: October 4, 2007
    Date of Patent: August 6, 2013
    Assignee: British American Tobacco (Investments) Limited
    Inventors: Stephen Robert Tennison, Jonathan Robert Tunbridge, Roger Nicholas Place, Andrew John Blackburn, Alan Mark Giles
  • Patent number: 8268269
    Abstract: As population density increases, the transportation of hazardous chemicals, including acids and disinfectants, lead to an increased incidence of spills while the consequences of spills become more serious. While solutions of halide acids, hypohalites and halites are safer disinfectants for transportation, handling, storage and use than traditional gaseous chlorine, the manufacturing cost of these disinfectants has here-to-fore limited their use. Economical processes are presented for the manufacture of O2, halogen oxides, halide acids, hypohalites, and halates; as well as polynucleate metal compounds, metal hydroxides and calcium sulfate hydrate (gypsum). The instant invention presents methods and processes that incorporate the use of sulfur. This is while environmental regulators, such as the US EPA, require an increased removal of sulfur from hydrocarbon fuels, thereby creating an abundance of sulfur, such that the refining industry is in need of a way to dispose of said abundance of sulfur.
    Type: Grant
    Filed: July 23, 2007
    Date of Patent: September 18, 2012
    Inventors: Richard Alan Haase, John Smaardyk
  • Publication number: 20120003328
    Abstract: Provided are a modified Na-montmorillonite and a preparation method thereof, wherein the content of Na+ in the modified sodium-montmorillonite, calculated as Na2O, is not less than 2.0%. The modified Na-montmorillonite has more reasonable microstructure, higher performance, and better quality. Also provided are a method for preparing a modified nanometered Na-montmorillonite from the modified Na-montmorillonite, and the modified nanometered Na-montmorillonite obtained by the method. Also provided are uses and a pharmaceutical composition of the modified Na-montmorillonite or modified nanometered Na-montmorillonite.
    Type: Application
    Filed: January 8, 2010
    Publication date: January 5, 2012
    Inventors: Haihui Zheng, Guanglie Lv, Zhiguo Xia, Nian Xu, Sheng Le, Zhongchao Ma, Yufeng Chi, Wenbo Chen, Jixin Chen
  • Patent number: 8029752
    Abstract: The invention provides a method of controlling silica in the liquor circuit of the Bayer process. The method involves addition of a promoter material to enhance the precipitation of DSP and includes adding one or more silica dispersion materials or dry silica forms to those parts of the circuit where precipitation of DSP and removal of silica from solution is desirable; for example the desilication stage of a Bayer process plant. The removal of DSP from solution reduces silica concentration in the liquor and thereby enables better control of process issues such as silica contamination in alumina product and DSP formation in later stages of the process where precipitation as scale onto vessel walls and equipment is problematical. As a result, the invention provides a significant reduction in the total cost of operating a Bayer process.
    Type: Grant
    Filed: April 6, 2009
    Date of Patent: October 4, 2011
    Assignee: Nalco Company
    Inventors: Timothy La, Ji Cui, John D. Kildea, David H Slinkman, Kim Richard Coleman
  • Patent number: 7976799
    Abstract: The present invention relates to the use of lithium salts and/or magnesium salts for the precipitation of aluminum oxides present in aqueous media.
    Type: Grant
    Filed: February 24, 2010
    Date of Patent: July 12, 2011
    Assignee: Areva Federal Services, LLC
    Inventor: Donald Geniesse
  • Patent number: 7968067
    Abstract: The present invention relates to the use of lithium salts and/or magnesium salts for the precipitation of aluminum oxides present in aqueous media.
    Type: Grant
    Filed: April 14, 2010
    Date of Patent: June 28, 2011
    Assignee: Areva Federal Services, LLC
    Inventor: Donald Geniesse
  • Patent number: 7767281
    Abstract: The present invention relates to an inkjet recording element showing good dye keeping in time and then good image stability. Said element comprises a support and at least one ink-receiving layer, said ink-receiving layer comprising at least allophane-type amorphous spherical or ring-shaped aluminosilicate particles, said aluminosilicate particles having been submitted to an acidic treatment. Said particles can be natural allophane, purified or not, or allophane obtained by synthesis.
    Type: Grant
    Filed: January 19, 2005
    Date of Patent: August 3, 2010
    Assignee: Eastman Kodak Company
    Inventors: Oliver A. Caillault, Stephanie V. Desrousseaux, Gerard A. Friour, Jean M. Guilment, Olivier J. Poncelet
  • Publication number: 20100189613
    Abstract: The present invention relates to the use of lithium salts and/or magnesium salts for the precipitation of aluminum oxides present in aqueous media.
    Type: Application
    Filed: April 14, 2010
    Publication date: July 29, 2010
    Applicant: AREVA FEDERAL SERVICES LLC
    Inventor: Donald GENIESSE
  • Patent number: 7666505
    Abstract: A synthetic microsphere having a low alkali metal oxide content and methods of forming the microsphere and its components are provided. The synthetic microsphere is substantially chemically inert and thus a suitable replacement for natural cenospheres, particularly in caustic environments such as cementitious mixtures. The synthetic microsphere can be made from an agglomerate precursor that includes an aluminosilicate material, such as fly ash, a blowing agent such as sugar, carbon black, and silicon carbide, and a binding agent. The synthetic microsphere is produced when the precursor is fired at a pre-determined temperature profile so as to form either solid or hollow synthetic microspheres depending on the processing conditions and/or components used.
    Type: Grant
    Filed: August 25, 2003
    Date of Patent: February 23, 2010
    Assignee: James Hardie Technology Limited
    Inventors: Amlan Datta, Hamid Hojaji, David L. Melmeth, James A. McFarlane, Thinh Pham, Noel E. Thompson, Huagang Zhang
  • Patent number: 7270704
    Abstract: The inventive method for producing refractory high-strength spherical granules consists in separately presintering kaolin and bauxite in a rotational furnace, jointly sintering said components in order to produce a charging material, granulating, drying and screening said charging material, sintering said granules in the rotational furnace and screening the sintered granules. Said sintered kaoline is produced by sintering at a temperature ranging from 1400 to 1500 DEG C so far as a water absorption of 5% is attained for kaoline containing 40-45 mass % and a free quartz in a quantity equal to or greater than 60 mass %. The Al2O3:SiO2 ratio in the charging material is equal to 1:1 at the following charging material component ratio: 36-67 mass % sintered kaolin and the rest being sintered bauxite.
    Type: Grant
    Filed: November 8, 2005
    Date of Patent: September 18, 2007
    Assignee: Otkrytoe Aktsionernoe Obschestvo “Borovichsky Kombinat Ogneuporov”
    Inventors: Vladimir Anatolievich Mozhzherin, Viktor Pavlovich Migal, Vyacheslav Yakovlevich Sakulin, Alexandr Nikolaevich Novikov, Galina Nikolaevna Salagina, Evgeny Arkadievich Schtern, Vladimir Vasilievich Skurikhin, Vyacheslav Vladimirovich Bulin, Lyubov Vladimirovna Mordanova, Boris Abramovich Simanovsky, Oleg Mikhailovich Rosanov
  • Publication number: 20070189944
    Abstract: The present invention relates to microparticles, particularly spherical silica microparticles, which may be useful in liquid chromatography. Specifically, the microparticles include a solid core and an outer porous shell surrounding and irreversibly joined to the core. The shell is composed of a plurality of colloidal nanoparticles, which are applied using an electrostatic multi-multilayering method. The resulting microparticles have a small particle diameter, such as about 1 ?m to 3.5 ?m, a high particle density, such as about 1.2 g/cc to 1.9 g/cc, and a high surface area, such as about 50 m2/g to 165 m2/g. These microparticles can be used to form packed beds and liquid chromatographic columns, which are more efficient and rugged than conventional liquid chromatographic columns.
    Type: Application
    Filed: February 13, 2007
    Publication date: August 16, 2007
    Inventors: Joseph J. Kirkland, Timothy J. Langlois
  • Patent number: 6627165
    Abstract: A process for upgrading of titaniferous material containing silica, including pretreating the titaniferous material by alkaline leaching to precipitate the silica as an aluminosilicate which is amenable to further leaching. Subsequently, the pretreated titaniferous material is leached under acid conditions, causing the silica to enter solution under conditions such that the silica is not hydrolysed or precipitated as a silicate.
    Type: Grant
    Filed: June 28, 2001
    Date of Patent: September 30, 2003
    Assignee: Technological Resources PTY LTD
    Inventors: Ross Alexander McClelland, Michael John Hollitt
  • Patent number: 6528028
    Abstract: A process in which alumina is extracted from bauxite with an aqueous alkali solution, and a desilication product is precipitated such that the product is not contained in a bauxite residue and does not form a complex. The desilication product is mixed with a calcium compound, and the mixture is calcined, to thereby solubilize and recover an alkali component of the product. In addition, an alkali component is removed from a residue (a solid product), and the residue is effectively used as a resource.
    Type: Grant
    Filed: December 28, 2000
    Date of Patent: March 4, 2003
    Assignee: Showa Denko K.K.
    Inventors: Yoshiyuki Takenaka, Yasuo Kawai, Isao Ishikawa
  • Publication number: 20020158373
    Abstract: A method of making a cristobalite-free, mullite grain capable of withstanding reaction with molten aluminum, comprising the steps of: producing a clay slurry comprised of water and kaolin clay of a specific particle size; mixing a water insoluble barium or strontium containing compound into the clay slurry in an amount wherein the barium or strontium containing compound content of the slurry is equal to about 8% by weight of the kaolin clay in the slurry; removing sufficient water from the slurry to form a material having an pelletizable consistency; forming the material into pellets; heating the pellets by continuously moving them through a furnace having a zone, wherein the material is exposed to temperatures of at least 2,650° F. (1,455° C.) for at least 30 minutes.
    Type: Application
    Filed: April 15, 2002
    Publication date: October 31, 2002
    Applicant: North American Refractories Co.
    Inventors: H. David Prior, Daniel F. Fura
  • Patent number: 6309615
    Abstract: A process for the removal of reactive silica from a feedstock to the digestion step of the Bayer process for the manufacture of alumina, in which (a) the feedstock is contacted with a caustic liquor under process conditions which result in dissolving and stabilizing at least 50% of the silica into solution at a level of at least 3 gpL and without significant precipitation from solution of dissolved silica, (b) the silica bearing liquor is separated from solid residue of step (a) under conditions which do not promote significant precipitation of the silica; and (c) aluminosilicates are precipitated from the separated silica bearing liquor from step (b), to form a solid aluminosilicate product which is free of a majority of all other components of the feedstock.
    Type: Grant
    Filed: October 15, 1999
    Date of Patent: October 30, 2001
    Assignee: Comalco Aluminum Limited
    Inventors: Michael John Hollitt, Anthony John Crisp, Warren Scott Staker, Gerard Marcus Roe, Darren Paul Rodda
  • Patent number: 6241893
    Abstract: An amorphous potassium aluminosilicate filtration media which may be mixed with activated carbon filters water to remove oxygen, chlorines, hardness, alkalinity, ammonia, hydrogen, hydrogen sulfide, sodium sulfite and other contaminants. The particular sodium aluminosilicate is a porous amorphous material formed under ultraviolet light or sunlight to produce pore sizes of 60 Å to 250 Å at ambient temperatures (20° C.-35° C.) and low relative humidity (5%-20%). The media is initially formed as a microporous primarily amorphous gel containing Na2O, Al2O3, SiO2 and H2O. The sodium therein is displaced by potassium, whereby the filter removes impurities from water without introducing sodium. The potassium aluminosilicate may be a second stage filter to a first stage filter composed of a strong base anion media charged with potassium carbonate and/or bicarbonate.
    Type: Grant
    Filed: March 18, 1997
    Date of Patent: June 5, 2001
    Inventor: Ehud Levy