Abstract: To concentrate metals such as gallium from ore which is extracted from mines or used electronic components while suppressing the quantity of waste liquid generated is difficult. A first solid metal compound which contains a metal selected from a group consisting of gallium, indium, germanium, tellurium, and cesium at a first metal content in a mixture of the first solid metal compound is reduced to form a gaseous metal compound, the gaseous metal compound is oxidized to form a second solid metal compound, and the second solid metal compound is collected at a second metal content which is higher than the first metal content.

Abstract: A method for producing a conversion element is disclosed. In an embodiment, the method includes providing an acidic medium having a pH value of less than 2, adding a conversion material into the acidic medium thereby forming a mixture and adding a silicate solution having a viscosity between 2 to 10 000 poize inclusive to the mixture such that the pH value during the addition of the silicate solution is smaller than 2. The method further includes obtaining a precipitate which contains the conversion material and silicon dioxide as a matrix material, separating the precipitate, washing the precipitate with a washing medium, wherein the washing medium has a pH value of less than 2; and hardening the precipitate thereby forming the conversion element.

Abstract: A process for recovering a metal chloride or mixed metal chloride from a solid waste material comprising recoverable metal containing constituents produced by lead, copper or zinc smelting and refining processes, said process comprising the steps of: (i) heating the solid waste material; (ii) treating the heated material of step (i) with a gaseous chloride to form a gaseous metal chloride containing product; and (iii) treating the gaseous metal chloride containing product of step (ii) to recover the metal chloride or mixed metal chloride. The metal chloride may be further treated to extract the metal itself.

Abstract: The invention provides a preparation process of transition metal boride, comprising the following steps: A) aluminum is put in a reactor, inert gas is fed into the reactor after evacuation, the reactor is heated up to 700 to 800° C. and then added with dry potassium fluoborate or sodium fluoborate, monomer boron and cryolite are generated by rapid stirring and reaction for 4 to 6 hours, and the molten liquid at the upper layer is sucked out and the monomer boron is obtained by means of separation; and B) the obtained monomer boron is added with transition metal for reaction at the temperature from 1800 to 2200° C. in order to generate corresponding transition metal boride.

Abstract: A cyclic preparation method including the following steps: a) boric acid or boric anhydride is added with hydrofluoric acid and then with potassium sulfate for reaction to generate potassium fluoborate; titanium-iron concentrate is added with hydrofluoric acid and then with potassium sulfate for reaction to generate potassium fluotitanate; B) the potassium fluoborate is mixed with the potassium fluotitanate, and the mixture reacts with aluminum to generate titanium boride and potassium cryolite; C) the potassium cryolite is sucked out and then fed into a rotary reaction kettle together with concentrated sulfuric acid, hydrogen fluoride gas as well as potassium sulfate and potassium aluminum sulfate are generated by reaction in the rotary reaction kettle, and the hydrogen fluoride gas is collected and then dissolved in water to obtain hydrofluoric acid aqueous solution; and D) the obtained hydrofluoric acid aqueous solution and potassium sulfate aqueous solution are recycled.

Abstract: A cyclic preparation method for producing titanium boride from intermediate feedstock sodium-based titanium-boron-fluorine salt mixture and producing sodium cryolite as byproduct, which comprises the steps: a) boric acid or boric anhydride is added with hydrofluoric acid and then with sodium carbonate solution for concentration and crystallization to generate sodium fluoborate; titanium-iron concentrate is added with hydrofluoric acid and then with sodium carbonate and sodium hydroxide to obtain sodium fluotitanate; B) the sodium fluoborate is mixed with the sodium fluotitanate, and the mixture reacts with aluminum to generate titanium boride and sodium cryolite; C) the sodium cryolite is sucked out and then fed into a rotary reaction kettle together with concentrated sulfuric acid, hydrogen fluoride gas as well as sodium sulfate and sodium aluminum sulfate are generated by reaction in the rotary reaction kettle, and the hydrogen fluoride gas is collected and then dissolved in water to obtain hydrofluoric aci

Abstract: Ternary and quaternary Chalcopyrite CuInxGa1-xSySe2-y (CIGS, where 0?x and y?1) nanoparticles were synthesized from molecular single source precursors (SSPs) by a one-pot reaction in a high boiling solvent using salt(s) (i.e. NaCl as by-product) as heat transfer agent via conventional convective heating method. The nanoparticles sizes were 1.8 nm to 5.2 nm as reaction temperatures were varied from 150° C. to 190° C. with very high-yield. Tunable nanoparticle size is achieved through manipulation of reaction temperature, reaction time, and precursor concentrations. In addition, the method developed in this study was scalable to achieve ultra-large quantities production of tetragonal and quaternary Chalcopyrite CIGS nanoparticles.

Abstract: A method of removing lead sulfide contained in refined molybdenite powder concentrates (major component; MoS2) is provided. More specifically, in order to solve the problems associated with a leaching method using a leaching agent that is employed for conventional hydrometallurgical process, oxygen-free inert gas is circulated in a furnace for pyrometallurgical treatment to evaporate lead sulfide at high temperature, followed by condensing process to recover lead sulfide at low temperature. The method is characterized in that, it can reduce environmental contamination and can easily recover sulfides of valuable metals such as lead, indium, zinc and the like.

Abstract: A method of removing lead sulfide contained in refined molybdenite powder concentrates (major component; MoS2) is provided. More specifically, in order to solve the problems associated with a leaching method using a leaching agent that is employed for conventional hydrometallurgical process, oxygen-free inert gas is circulated in a furnace for pyrometallurgical treatment to evaporate lead sulfide at high temperature, followed by condensing process to recover lead sulfide at low temperature. The method is characterized in that, it can reduce environmental contamination and can easily recover sulfides of valuable metals such as lead, indium, zinc and the like.

Abstract: A method of producing titanium metal from a titanium-containing material includes the steps of producing a solution of M?TiF6 from the titanium-containing material, selectively precipitating M?2TiF6 from the solution by the addition of (M?)aXb and using the selectively precipitated M?2TiF6 to produce titanium. M? is a cation of the type which forms a hexafluorotitanate, M? is selected from ammonium and the alkali metal cations, X is an anion selected from halide, sulphate, nitrite, acetate and nitrate and a and b are 1 or 2.

Abstract: A process for producing alumina particles, comprising vaporizing aluminum chloride to form an aluminum chloride vaporized gas, which optionally contains an inert gas, and oxidizing the vaporized aluminum chloride with an oxidizing gas to produce alumina particles, wherein the aluminum chloride vaporized gas and the oxidizing gas are introduced into a reactor each at an ejecting flow velocity of about 10 m/sec or more, the ratio of the flow velocity of oxidizing gas to the flow velocity of the aluminum chloride vaporized gas is approximately from 0.2 to less than 10, and the amount of oxidizing gas is about 1 or more times the amount of oxidizing gas necessary for stoichiometrically oxidizing aluminum chloride.

Abstract: A process for purifying solid crude aluminum chloride, containing iron impurities, includes the steps of mixing iron with the crude aluminum chloride and reactively subliming and desubliming the mixture.

Abstract: Gallium-containing waste is chlorinated in the presence of gallium trichloride from the beginning. By this procedure, gallium is more efficiently chlorinated and gallium trichloride is more easily separated from other chlorides and recovered.

Abstract: A process for producing a ceramic material which is electrically conductive by reacting titanium dioxide with intercalated graphite under conditions which effect the reduction of the titanium dioxide, said product comprising an electrically conductive, corrosion-resistant, substoichiometric titanium dioxide combined chemically with an intercalant or residue thereof, for example, a metal such as copper or nickel, and the use thereof in thermal, electrical and electro-chemical applications.

Abstract: A process for obtaining essentially cone-shaped aluminum chloride granules free of fines from a gas current containing aluminum chloride, comprising contacting said gas current with a surface whose temperature is below about 70.degree. C. to deposit the aluminum chloride thereon in the form of cone-shaped granules and then heating said surface for a time and at a temperature sufficient to detach said granules from said surface; and the essentially cone-shaped product of such process.

Abstract: The process for purifying a contaminated chloro, bromo or iodo precursor salt of zirconium, hafnium or aluminum by means of providing a molten thermal body of one or more alkali or alkaline earth metal halides and the precursor salt containing impurities, maintaining the body at a temperature sufficient to volatilize the precursor salt away from its impurities while effecting a reducing condition in the body by means of a fluid, mobile reducing agent which is non-reducing of said precursor salt, and isolating the purified volatilized precursor salt from the body. The ultra purified isolated volatilized precursor salt can then be reacted with a fluorinating agent to produce the highly purified fluoride for use in optical fiber grade glass or the like.

Abstract: A process for purifying anhydrous aluminum chloride containing organochlorine impurities, comprising contacting said impure aluminum chloride with a bath containing at least one chloroaluminate for a time sufficient to remove said impurities therefrom and recovering the purified aluminum chloride in the vapor phase of the chloroaluminate bath.

Abstract: Aluminium chloride contaminated with iron chloride is purified by contacting it in vapor form with a bed of particles of aluminium metal interspersed with particles of a chemically inert material. The efficiency of the process may be maintained by acid treating, drying and recycling the bed material. The process may be applied to aluminium chloride produced by the chlorination of a bauxite beneficiate.

Abstract: Metallic constituents, especially heavy metal constituents are removed from dust electrostatically separated from a gas mixture consisting substantially of carbon monoxide and phosphorus in vapor form obtained during the electrothermal production of yellow phosphorus. To this end, the dust is initially calcined with continuous agitation under oxidizing conditions at temperatures of 300.degree. to 800.degree. C.; next, the resulting calcined matter is mixed with carbon and the mixture is treated at temperatures of 950.degree. to 1200.degree. C. under reducing conditions with volatilization of the metallic constituents; and the volatized metallic constituents are ultimately condensed and separated.

Abstract: A process for making alpha alumina particles wherein a Bayer process caustic aluminate solution is treated with both alumina hydrate seed material and alpha alumina promoter particles to precipitate alumina hydrate particles. The precipitated particles are separated from the solution and then dried and calcined to produced alpha alumina particles. Addition of promoter particles in the precipitation step lowers the calcination temperture necessary to produce alpha alumina and results in smaller sized crystallites in the product.

Abstract: The invention is primarily directed to the production of a substantially iron free alumina-silica product and substantially iron free aluminum chloride from bauxites, bauxitic clays and kaolinitic clays wherein the feed material to an agglomeration stage is selected to contain a minimum of about 20% kaolinite mineral. The agglomerates are so formed to produce a product that is preferably at least minus 6 mesh plus 200 mesh and in a subsequent calcination stage the calcined agglomerates have a bulk density of preferably 0.8 to 1.3. In a subsequent differential iron chlorination stage a substantially iron free alumina-silica product is produced and in a subsequent mass chlorination stage substantially iron free aluminum chloride is produced.

Abstract: A mixture of an aluminous ore and a carbon source is dried and calcined in the presence of a sulfur-containing compound. The mixture is then chlorinated to produce crude metal chlorides. Aluminum chloride is condensed and separated from the remaining metal chlorides, combined with sulfur and aluminum powder, and sublimated and desublimated so as to produce substantially pure aluminum chloride.

Abstract: A selective chlorination method of a mixture of simple or complex metallic oxides, comprising at least one of the elements to be used, iron, aluminum, titanium and silicon, as well as the impurities accompanying said elements, said method consisting of a grinding, a calcination, a placing in suspension in a bath of melted salts of the mixture of said metallic oxides and of their impurities and of an introduction of chlorinating agents into said bath maintained at a temperature which assures the volatility of at least one of the metallic chlorides formed; characterized by the fact that, in order to selectively extract the metallic chlorides formed from the bath, specific chlorinating mixtures are introduced into this bath by successive steps, said mixtures having increasing chlorinating power, and the introduction is in a number at the most equal to the usuable elements to be chlorinated.

Abstract: A process for decomposing chlorinated hydrocarbon compounds wherein the compounds are heated to an elevated temperature of about 800.degree. to 1200.degree. C. and reacted with alumina and a reactive carbon source. A preferred operating temperature is about 800.degree. to 900.degree. C. and preferred carbon sources are activated carbon and coked alumina. The process is particularly useful for disposing of chlorinated organic compounds that are generated in the production of metal chlorides by chlorination of a metal oxide in the presence of carbon.

Abstract: In the fluidized bed chlorination of oxidic materials, for example minerals such as bauxite, tantalite, columbite, wolframite or scheelite, the separation of metal values giving vaporous chlorides at the reaction temperature is enhanced by maintaining a zone substantially free of chlorine in the fluidized bed, for example a zone at least 0.25 m in depth measured from the expanded bed surface. A high aspect ratio bed and counter current movement of the bed matter and the chlorine within the bed are preferably used.

Abstract: The purification of aluminum chloride, with the crude aluminum chloride normally being obtained through a process of carbo-chlorination of metallic ores, in particularly aluminum bearing ores, to make the metallic chlorides, in particular aluminum chloride. In the present invention, if the crude aluminum chloride does not contain traces of sulfur, the crude aluminum chloride is blended with elemental sulfur or an equivalent sulfur containing compound and simultaneously elemental aluminum powder or an equivalent aluminum containing compound in the solid state is added to the crude aluminum chloride. This blend is kept at 180.degree. C. at one atmosphere of pressure and is fed into a screw-type sublimer wherein the substantially pure aluminum chloride undergoes sublimation in the presence of elemental nitrogen as a purging agent and under constant agitation. The sublimed aluminum chloride is streamed into a reaction ground bed containing aluminum granules at approximately 250.degree. C.

Abstract: Carbonaceous pyropolymers possessing recurring units containing at least carbon and hydrogen atoms may be obtained from compositions of matter comprising carbonaceous pyropolymers possessing recurring units containing at least carbon and hydrogen atoms composited on an inorganic metal oxide support or substrate by treating the composition of matter with a chloride-containing compound at an elevated temperature in the range of from about 400.degree. to about 1000.degree. C. in the vapor phase. The resulting metal chloride such as aluminum chloride is continuously removed from the composite, leaving only the carbonaceous pyropolymer.

Abstract: Alkali and alkaline earth metal chlorides contained in a residue of a chlorination process of a feed material of bauxite or clay associated with coal are removed by the addition of sulfuric acid which causes their conversion to their sulfate form, and the simultaneous production of hydrochloric acid. The residue, which has been rendered environmentally acceptable, can be disposed of readily, for example, to an ash pond or disposal area for flue gas desulfurization sludges. The hydrochloric acid is then recycled to the chlorination process. The hydrochloric acid may be utilized, for example, as a binder of the feed material, to prechloridize the feed material or as a portion of the leach solution when the chlorination process is a hydrochloric acid leach.

Abstract: At least a single stage chlorination system for the production of a substantially iron-free alumina-silica product from Bauxites, Bauxitic Clays and Clays wherein at least one chlorination agent is selected from the group consisting of Cl.sub.2, HCl and COCl.sub.2 and at least one chlorination agent from the group consisting of AlCl.sub.3 and SiCl.sub.4.

Abstract: At least a two stage chlorination system for the production of aluminum trichloride and aluminum monochloride wherein in the gas stream containing the highest percentages of aluminum chloride produced CO.sub.2 is present and the said gas stream is passed through a charcoal or devolatilized coke bed in a preferred temperature range of about 1000.degree. C. to 1600.degree. C. to convert the said CO.sub.2 to CO and cycling at least part of the said CO produced to at least the second chlorination stage.

Abstract: At least a two-stage chlorination system for the production of a substantially iron-free alumina-silica product from Bauxites and Clays wherein in a preferred embodiment of the invention the chlorination agent is selected from the group consisting of Cl.sub.2, HCl and COCl.sub.2 in the first chlorination stage and wherein in the second chlorination stage the chlorination agent is selected from the group consisting of AlCl.sub.3 and SiCl.sub.4.

Abstract: At least a single stage chlorination system for the production of a substantially iron-free alumina-silica product from Bauxites, Bauxitic Clays and Clays wherein at least one chlorination agent is selected from the group consisting of Cl.sub.2, COCl.sub.2, AlCl.sub.2, AlCl, SiCl.sub.4 and SiCl.sub.2 and wherein the said chlorination agent is a limited percentage of the total gas stream.

Abstract: The invention relates to a method for utilizing silicon tetrachloride formed as a by-product of the chlorination of aluminium- and silicon-containing minerals. More particularly, the invention relates to a process for the preparation of aluminium trichloride and silicon dioxide by chlorination of alumina with silicon tetrachloride. According to the invention alumina or a material essentially consisting of alumina is reacted with silicon tetrachloride as a single chlorinating agent at a temperature exceeding 400.degree. C., unreacted silicon tetrachloride is separated from the aluminium trichloride formed and is recycled into the chlorination step, silicon dioxide is isolated from the solid residue essentially consisting of the unreacted alumina and silicon dioxide, unreacted alumina is recycled into the chlorination step and aluminium trichlorine obtained is continuously eliminated.

Abstract: A method is disclosed for preventing the condensation of aluminum chloride (AlCl.sub.3) in a fractional distillation column which is operated to separate a fraction which does not include AlCl.sub.3 from a mixture containing AlCl.sub.3 and other metal chlorides and which is operated at temperatures which include the sublimation or melting points of AlCl.sub.3 at the operating pressure of the column. According to this method, titanium tetrachloride (TiCl.sub.4) is maintained in the column in an amount at least as great, by weight, as the amount of AlCl.sub.3 contained in the mixture.

Abstract: In a process for purifying aluminum chloride made by the high temperature chlorination of an aluminum value containing material by distilling the aluminum chloride in a still, and separating the aluminum chloride the improvement comprising adding sufficient alkali chloride to the aluminum chloride as to provide an aluminum chloride/alkali chloride mixture having a conductivity sufficient to permit internal electrical resistance heating of the still when an electric current is applied across the still mixture.

Abstract: A method for producing alumina from a material containing alumina values via a chlorination step which process comprises the steps of:(A) dehydrating the material, if necessary, at a temperature of between about 500 and about 1300.degree. K.;(B) chlorinating the product of step (A) in the presence of chlorine and carbon at a temperature below about 1200.degree. K. and under conditions which provide chlorination of a majority of the iron present in the clay without substantial chlorination of titania values which may be present therein with concommittant formation of an iron chloride cloud above the surface of the chlorination reaction mixture;(C) introducing oxygen into the iron chloride cloud under conditions to cause oxidation of a majority of the iron chloride contained in the cloud;(D) chlorinating the non-gaseous product of step (B) in the presence of chlorine and carbon at a temperature above about 1300.degree. K.

Abstract: There is described a method for producing alumina from a material containing alumina values via a chlorination step which process comprises the steps of:(A) dehydrating the material, if necessary, at a temperature of between about 500 and about 1300.degree. K;(B) chlorinating the product of step (A) in the presence of chlorine and carbon at a temperature below about 1200.degree. K and under conditions which provide chlorination of a majority of the iron present in the clay without substantial chlorination of titania values which may be present therein with concommittant formation of an iron chloride cloud above the surface of the chlorination reaction mixture;(C) introducing oxygen into the iron chloride cloud under conditions to cause oxidation of a majority of the iron chloride contained in the cloud;(D) chlorinating the non-gaseous product of step (B) in the presence of chlorine and carbon at a temperature above about 1300.degree.

Abstract: A two stage process is described for chlorinating aluminum value containing materials such as bauxite, clay, fly ash, etc. The process comprises the steps of:(A) dehydrating the material, if necessary, at a temperature of between about 500.degree. and about 1300.degree. K.;(B) chlorinating the product of step (A) in the presence of chlorine and carbon at a temperature below about 1200.degree. K. and under conditions which provide chlorination of a majority of the iron present in the clay without substantial chlorination of titania values which may be present therein with concommittant formation of an iron chloride cloud above the surface of the chlorination reaction mixture;(C) introducing oxygen into the iron chloride cloud under conditions to cause oxidation of a majority of the iron chloride contained in the cloud; and(D) chlorinating the non-gaseous product of step (B) in the presence of chlorine and carbon at a temperature above about 1300.degree. K.

Abstract: Metal chlorides such as aluminum chloride (AlCl.sub.3) are separated from a mixture containing metal chlorides including AlCl.sub.3 and ferric chloride (FeCl.sub.3). In order to effect this separation, the mixture is subjected to a fractional distillation process utilizing an array of distillation columns. According to this process, the mixture is introduced into a first distillation column which is operated at temperatures and pressures sufficient to separate FeCl.sub.3 from the mixture while avoiding the formation of a solid solution of FeCl.sub.3 and AlCl.sub.3 within the column. At least one additional distillation column is then employed to separate metal chlorides from the remaining mixture from the first column.

Abstract: A method for producing aluminum chloride suitable for direct introduction into an aluminum chloride reduction cell by treatment of the gas stream emerging from an aluminum value source chlorination process comprising the steps of:1. reducing and condensing iron chloride in one or more iron chloride condensation stages;2. absorbing the aluminum chloride contained in the gas stream under high temperature conditions with an alkali chloride or alkali chloride mixture to form an ionic alkali chloride-aluminum chloride complex; and3. selectively condensing the chlorides from the product by step (2) to produce a purified aluminum chloride-alkali chloride complex suitable for direct introduction into an aluminum chloride reduction cell.

Abstract: A method for purifying with respect to iron, aluminum chloride produced via the chlorination of aluminum bearing ores or materials which also contain iron. The process comprising the steps of:1. chlorinating the aluminum value containing material in a manner which produces a gaseous product containing both ferric chloride and aluminum chloride;2. oxidizing at least a portion of the ferric chloride to particulate iron oxide;3. removing the iron oxide from the gaseous product;4. reducing any remaining ferric chloride to ferrous chloride, using reduced iron oxide, e.g. iron powder;5. condensing the ferrous chloride along with at least about 10% of the available aluminum chloride to assure removal of substantially all iron chloride; and6. condensing the remaining about 80% of the available aluminum chloride as pure product.

Abstract: This invention relates to the recovery of molybdenum, vanadium, and aluminum, as well as of cobalt and nickel, from the residues of hydrodesulfurization catalysts.PRIOR ARTMolybdenum-containing catalysts are used in the petroleum industry for the hydrodesulfurization of hydrocarbons. The hydrodesulfurization treatment consists in contacting petroleum or a petroleum fraction with hydrogen in the presence of a catalyst so as to remove the sulfur as gaseous hydrogen sulfide. The catalysts used for said purpose generally comprise a support material made of alumina containing, as active components, either molybdenum and cobalt or molybdenum and nickel. Sometimes catalysts in which the support consists of silica in place of alumina are also used.The active components, i.e. molybdenum, cobalt and/or nickel, are present as oxides in the fresh catalysts. The percentages of active components are variable. In most cases, these percentages are of about 10-15% for molybdenum oxide (MoO.sub.

Abstract: The efficiency of a given reactor for the conversion of aluminum oxide bearing starting material by means of reducing and chlorinating gases or of carbon coated aluminum oxide bearing starting material by means of chlorinating gases in a solid/gas fluidized bed to yield aluminum chloride is improved by the addition of an inert, solid dilution agent to the bed. Whereas, as a result of the chemical reaction, the average particle size and bulk density of the reagent decreases in a batch process, and in a continuous process an equilibrium value is reached, the average particle size and the bulk density of the inert material remains unchanged. An initial average particle size of 60-80 microns proved successful; quartz, corundum, magnesium oxide of similar particle size and bulk density was added as dilution agent, and a gas flow rate of 2 to 30 cm/sec was attained along with quantitative conversion of the gaseous reagent.

Abstract: The process is based on the series of halide-forming affinities. The oxides are passed through a series of zones equal in number to the plurality of halides or mixtures which are to be produced. A halide of an element of lower halide-forming affinity is fed counter-current to the oxides. The halide supply is in stoichiometric equivalent to the total content of halide to be extracted. The oxide of the said fed element is also extracted.

Abstract: A process for recovering aluminum from clays associated with coal or bauxite containing iron, siliceous material and titanium which comprises: (a) chlorinating the clay or bauxite in an oxidizing atmosphere to selectively chlorinate and vaporize iron chloride from the remaining chlorides, (b) chlorinating the residue from step (a) in a reducing atmosphere or carbon monoxide and vaporizing the chlorides of aluminum, silicon, titanium, and the residual iron, (c) separating and recovering the formed vaporized chlorides by selective condensation. Silicon tetrachloride may be added to step (b) to suppress the chlorination of silicon. If the clay contains alkali or alkaline earth metals, then the residue of step (b) is treated with sulfuric acid to convert the soluble chlorides, e.g., gypsum, to sulfates and to regenerate a chloridizing and binder solution for pelletizing the clay or bauxite.

Abstract: A continuous process for recovering substantially pure aluminum chloride from chlorination products of aluminum ore. The chlorination products are contacted with a first selective solvent to dissolve a substantial portion of the aluminum chloride and some ferric chloride. The solvent is separated from the chlorides which then are treated to produce a ferric chloride-rich stream and an aluminum chloride-rich stream in which the aluminum chloride to ferric chloride ratio is higher than the ratio prior to solvent separation. The aluminum chloride-rich stream is contacted with a second solvent to dissolve any ferric chloride present and saturate the solution with aluminum chloride. Aluminum chloride in excess of that soluble in the second solvent separates as a substantially pure solid phase. The solution is separated from solid phase and recycled in process to recover additional aluminum chloride.

Abstract: A process for the removal of iron and titanium minerals from aluminum bearing materials in at least one chlorination stage by the use of an excess of aluminum trichloride as at least the major chlorinating agent for the contained iron and titanium minerals, condensing the excess aluminum trichloride to recover the aluminum trichloride in an impure form, and recycling the impure aluminum trichloride to the chlorination stage together with additional aluminum trichloride or starvation amounts of chlorine, or alternately additional amounts of aluminum trichloride and starvation amounts of chlorine.

Abstract: The invention relates to a method of recovering the chlorine values from iron chloride obtained from the chlorination of an aluminous material containing iron oxide, such as bauxite. The method involves partially dechlorinating ferric chloride in the presence of a reducing agent to form products comprising ferrous chloride and a chloride compound derived from the reducing agent and oxidizing ferrous chloride at a temperature of about 300.degree. C. to 1200.degree. C. to form products comprising ferric chloride and ferric oxide. The ferric chloride is recycled and the chlorine values are recovered as the chloride of the reducing agent which is suitable for recycle to the aluminous chlorination stage or has other industrial utility.

Abstract: A process for the selective removal of iron from a ferruginous ore which comprises feeding the dried heated ore into a countercurrent reactor comprising a sulphidizing zone, an intermediate zone and a chlorination zone, through which zones the ore moves in sequence and wherein(a) in the sulphidizing zone, a reductant is introduced and the iron values present in the ore react selectively with sulphur and/or volatile sulphur-containing compounds in the presence of the reductant to form iron sulphides;(b) in the intermediate zone, volatile ferric chloride formed in the chlorinating zone is introduced and reacts with the sulphidized ore to convert the iron sulphides into ferrous chloride and reform the sulphur and/or volatile sulphur containing compounds;(c) in the chlorination zone, chlorine is introduced and converts the ferrous chloride formed in the intermediate zone into volatile ferric chloride;(d) the volatile iron chlorides and the upgraded host oxide are separately removed from the chlorination zone; and

Abstract: The invention comprises a process for the manufacture of metal chlorides by the double-decomposition reaction between a metal chlorinating agent and a metal oxide having greater affinity for chlorine than does the oxide of the metal chloride, and in the presence of small amounts of boron chloride or functionally equivalent boron compounds that increase the rate and degree of completion of the reaction.A major application of this invention is for the making by the chlorination of clay of aluminum chloride and alumina intermediates for the manufacture of aluminum metal.SiCl.sub.4 is formed in the carbo-chlorination of clay or other aluminous-siliceous ores. The SiCl.sub.4 by this invention is catalyzed with BCl.sub.3 and reacted with calcined clay to produce AlCl.sub.3 and SiO.sub.2. The practical use of SiCl.sub.4 to make AlCl.sub.3 thus eliminates the previous costly burden of waste SiCl.sub.4 production.