Abstract: A method for extracting secondary metal values from a sulfuric acid leachate is provided. The method includes providing a leachate which contains a primary metal and a plurality of secondary metals, wherein the primary metal is selected from the group consisting of Cu, Li and Ni and is derived from sulfuric acid leaching of an ore; passing the leachate through a first ion exchange resin which is selective to, and releasably binds, the plurality of secondary metals; stripping the plurality of secondary metals from the second or third ion exchange resins, thereby obtaining a first extract; and recovering the secondary metals from the first extract.

Abstract: A microwave-mechanical fluidization mining system and a mining method for metal mines. The microwave-mechanical fluidization mining system comprises a microwave pre-splitting mechanical mining system, a microwave separation system, a high-power microwave focused melting system and a goaf, wherein ore-waste rock mixtures mined by the microwave pre-splitting mechanical mining system are transported to the microwave separation system through a conveyor and an elevator on the microwave pre-splitting mechanical mining system, separated ores are transported to the high-power microwave focused melting system, and separated waste rocks are transported through a conveyor to the goaf for filling. Microwave pre-splitting mechanical mining is adopted instead of a traditional blasting mining method to increase an excavation speed and avoid the influence of blasting on the stability of surrounding rocks.

Abstract: Provided is a method of inhibiting degradation of an extractant by an anhydrous environment avoiding and metal stripping, the method including the steps of: (a) stopping the addition of soda ash (Na2CO3) to an extracting reaction tank; (b) starting solution recirculation and stopping solvent recirculation of a settler; (c) supplying a solvent from a loaded organic tank to a scrubbing reaction tank, in which the scrubbing reaction tank, stripping reaction tank and extracting reaction tank are connected for circulation and operating stirrers of the scrubbing reaction tank, stripping reaction tank and extracting reaction tank; (d) supplying a sulfuric acid solution having a controlled concentration with a diluting solution to the stripping reaction tank; (e) transferring the solvents of the settler, the loaded organic tank and all the pipes to the scrubbing reaction tank; and (f) stopping the step (e) and initiating solvent recirculation.

Abstract: Provided is a method for inhibiting extractant degradation comprising preparing step, extracting step and scrubbing step, the method including: (a) the preparing step of a DSX solvent by adjusting the extractant concentration of the DSX solvent to a specific range; (b) the extracting step of metal included in the feed solution by adjusting the ratio of the organic (solvent) and an aqueous (solution) as a feed solution; (c) the scrubbing step of adjusting the zinc concentration of the solution using zinc sulfate; and (d) stripping step.

Abstract: A novel process for treating pickling acid residue and recovering sulfates and nickel therefrom has been developed. By lowering the pH of a magnesium compound slurry to 4-5.5 with sulfuric acid containing pickling acid residue in the presence of ammonium sulfate, both magnesium sulfate and nickel sulfate are solubilized. Magnesium sulfate and nickel sulfate solution is separated from the solids by filtration and an iron hydroxide and chromium hydroxide residue is obtained as a precipitate. Magnesium sulfate and nickel sulfate are then separated from the solution.

Abstract: Provided is a method for inhibiting extractant degradation in the DSX process through the manganese extraction control, the method comprising: (a) stirring DSX solvent and DSX feed solution, which is a solution containing a valuable metal from which iron has been removed in an agitator, in which soda ash (Na2CO3) is further added to maintain a constant pH; and (b) scrubbing the manganese from the DSX solvent, extracted in step (a).

Abstract: The present invention is related to a polymer membrane for the selective extraction of cobalt (II) ions as well as a method for extracting cobalt (II) ions using said polymer membrane.

Abstract: Systems and methods for basic leaching are provided. In various embodiments, a method is provided comprising leaching a slurry comprising a copper bearing material and an ammonia leach medium, adding copper powder to the slurry, separating the slurry into a pregnant leach solution and solids, and performing a solvent extraction on the pregnant leach solution to produce an loaded aqueous stream.

Abstract: The invention relates to a method for regenerating the extractive potential of an organic hydroxyoxime-based extraction solution used in the recovery of metals by liquid-liquid extraction. The method is two-stage, in which a solid hydroxylamine is used in the reaction stage, and the removal of the undesirable compounds generated in the reaction occurs in the second stage by adsorption purification. The method of the invention is suitable for treatment of degraded oxime metal extractants in various process organic solutions both in aldehyde and ketoxime extractant solutions. The method can also be used to treat a mixture of degraded oxime extractants.

Abstract: A method for recovering scandium is provided, which is capable of recovering highly-pure scandium from nickel oxide ore in a simple and efficient manner. The method for recovering scandium according to the present invention includes a scandium elution step S2 of passing a solution containing scandium through an ion exchange resin to obtain an eluted liquid containing scandium from the ion exchange resin, a neutralization step S3 of adding for neutralization a neutralizing agent to the eluted liquid, a solvent extraction step S4 of solvent-extracting the neutralized eluted liquid using an amine-based extracting agent, and a scandium recovering step S5 of obtaining a scandium precipitate from residual liquid separated by the solvent extraction, and then roasting the precipitate to obtain scandium oxide.

Abstract: A method of preparing magnetite particles may include providing a first solution of substantially ferrous sulphate. The first solution may be converted by replacing sulphate ions with chloride ions to produce a second solution of substantially ferrous chloride. The second solution may be oxidized to produce a third solution of substantially iron oxide. A system for purifying a solution of substantially iron oxide may include a solution reservoir, at least one membrane unit, and at least one pump for circulating the solution between the solution reservoir and the membrane unit. The solution may be delivered from the solution reservoir to an inlet of the membrane unit, and/or the solution may be returned from an outlet of the membrane unit to the solution reservoir.

Abstract: This invention relates to a process for the recovery of cobalt ions and tungstic acid and/or its derivatives from aqueous solutions, such as in particular the spent catalytic waters deriving from processes for the oxidative cleavage of vegetable oils. In particular this invention relates to a process for the recovery of cobalt ions and tungstic acid and/or its derivatives which provides for the use of cation-exchange resins.

Abstract: The invention provides a method for extracting transition metals, the method comprising supplying a feedstream containing transition metal, mixing the feedstream with nitric acid for a time and at a concentration sufficient to form an aqueous phase containing the transition metal, combining the aqueous phase with organic extractant phase for a time and at a concentration sufficient to cause the transition metal to reside within the organic extractant phase, and combining the transition metal-containing organic extractant phase with an hydroxamic acid-containing aqueous phase at a concentration and for a time sufficient to cause the transition metal to reside in the hydroxamic acid-containing aqueous phase.

Abstract: This disclosure relates to a process for selectively extracting Fe(III) ions from an aqueous feedstock containing Fe(III) ions and non-ferric ions. The process comprises contacting the feedstock with an organic phase comprising a phosphonium salt or ammonium salt ionic liquid under liquid-liquid extraction conditions for a time sufficient to allow transfer of at least some of the Fe(III) ions from the feedstock to the organic phase to provide an Fe(III) ion laden organic phase and an Fe(III) depleted feedstock, and separating the Fe(III) ion laden organic phase from the Fe(III) depleted feedstock.

Abstract: The invention provides a process for the leaching of a laterite ore or concentrate for the recovery of value metals, at least one value metal being nickel. The laterite ore or concentrate is subjected to a leaching step with a lixiviant comprising hydrochloric acid to leach nickel from the laterite ore. Nickel is extracted with an oxime at a lower pH than other processes for extraction of nickel from solution, especially after separation of iron and cobalt values.

Abstract: A process for the removal of ferric iron as hematite from a nickel solution containing ferric and ferrous ions including the steps of: raising the temperature of the nickel solution to between 90° C. and the boiling point of the solution at atmospheric pressure; raising the pH of the nickel solution to be between 2 and 3; and adding a hematite seed to facilitate hematite precipitation, wherein ferric ions are precipitated as hematite in a predominantly crystalline form.

Abstract: We propose a method for leaching nickel, cobalt and iron from a nickel laterite ore, characterized in that the nickel laterite ore is brought into contact with a solution of sulphuric acid and urea mixture. In this way, there is provided a method for efficient recovery of nickel and cobalt from nickel laterite ores where leaching in sulphuric acid/urea mixture can be completed in about less than 1 hour.

Abstract: Disclosed herein is a method for easily and efficiently removing manganese from an aqueous acidic solution of sulfuric acid containing cobalt and manganese at low cast to obtain a high-purity cobalt sulfate aqueous solution usable as a raw material for lithium ion secondary batteries. The high-purity cobalt sulfate aqueous solution is obtained by mixing an aqueous acidic solution of sulfuric acid containing cobalt and manganese (aqueous phase) with an acidic organic extractant (organic phase) while adjusting the pH of the aqueous acidic solution of sulfuric acid to a value in a range between 2 and 4 with a pH adjuster such as sodium hydroxide to extract manganese into the organic phase. The acidic organic extractant to be used is preferably diluted so that the concentration of di-2-ethylhexyl phosphate is 10 to 30 vol %.

Abstract: A crystallization system for producing sodium aluminum fluoride cryolite from hydrofluoric acid waste includes a crystallization reaction tank, a sodium aluminate tank, a high concentration hydrofluoric acid waste tank, a pH value/fluoride detecting section, a dehydrator, a low concentration hydrofluoric acid waste tank, and a control device. The crystallization reaction tank includes a dispersing plate and the control plate to control the flow rate and liquid form of the sodium aluminate and the hydrofluoric acid waste. The loop-like pH value/fluoride detecting section is in communication with the reaction tank to detect the pH value/fluoride concentration of the water sample which is the aqueous mixture of sodium aluminate and hydrofluoric acid waste. Therefore, the crystallization system is capable of controlling factors affecting the cryolite purity during the operation process, and consequently, the crystallization system can produce cryolite whose purity is good enough for recycling.

Abstract: A method for recovering rare earth compounds, vanadium and nickel from waste vanadium-nickel catalysts, comprising steps of: acid leaching, by soaking waste vanadium-nickel catalysts into a sulfuric acid solution and obtaining a mixture containing alumina silica slag; sedimentation, by filtering out the alumina silica slag from the mixture to obtain a filtrate, and then adding a salt into the filtrate to precipitate rare earth double salts followed by isolating a sediment of rare earth double salts and a liquid solution via filtration; and extraction, by providing and adding an alkali into the sediment of rare earth double salts followed by further soaking the rare earth double salts in an acid solution to precipitate rare earth oxalate or rare earth carbonate, and adding an oxidizer into the liquid solution to adjust the pH value thereof and then extracting vanadium and nickel from the liquid solution via an ion-exchange resin.

Abstract: The present invention refers to a method being easy to recover metals including nickel and aluminum from waste aluminum catalysts, thereby entirely promoting the recovering rate. Said method comprises: preparing and roasting a waste aluminum catalyst with sodium salts, and then obtaining a first solution comprising vanadium and molybdenum, and a dreg comprising nickel and aluminum through leaching and filtrating; collecting and mixing the dreg with alkali powders to obtain a mixture of the dreg and alkali powders, roasting the mixture at 300 to 1000° C. with aluminum in the dreg reacting with hydroxyl generated from the roasting of mixture and further generating aluminum hydroxide, and then obtaining a second solution comprising aluminum and a concentrate having nickel through another leaching and filtrating; and recovering aluminum from the second solution and recovering nickel from the concentrate.

Abstract: Provided herein are processes for recovering molybdenum and/or other value metals (e.g., uranium) present in aqueous solutions from a large range of concentrations: from ppm to grams per liter via a solvent extraction process by extracting the molybdenum and/or other value metal from the aqueous solution by contacting it with an organic phase solution containing a phosphinic acid, stripping the molybdenum and/or other value metal from the organic phase solution by contacting it with an aqueous phase strip solution containing an inorganic compound and having a ?1.0 M concentration of free ammonia, and recovering the molybdenum and/or other value metal by separating it from the aqueous phase strip solution. When the molybdenum and/or other value metal are present only in low concentration, the processes can include an organic phase recycle step and/or an aqueous phase strip recycle step in order to concentrate the metal prior to recover.

Abstract: Provided are methods method of recovering metal from an aqueous solution, the method comprising contacting an aqueous solution containing at least two metals selected from molybdenum, cobalt, nickel, zinc and iron with an organic solvent and an oxime-containing reagent composition at a predetermined pH, the predetermined pH selected to provide a high first metal extraction and a low second metal extraction; and separating the first metal from the solution.

Abstract: A process for the production of a high grade nickel product including the steps of: a) providing at least one heap of a nickeliferous lateritic ore and leaching that heap with a suitable lixiviant, preferably sulfuric acid solution, to produce a nickel rich pregnant leach solution (PLS); b) subjecting the PLS to an impurity removal step to precipitate ferric iron, and preferably partially precipitate aluminium and chromium as hydroxides; and c) recovering a high grade nickel product from the PLS preferably by either nickel ion exchange, solvent extraction, electrowinning, conventional multi-stage neutralization, pyrohydrolysis or sulfidation.

Abstract: The invention provides a process for the leaching of a laterite ore, concentrate, tailings or waste rock for the recovery of value metals, at least one value metal being nickel. The laterite ore or concentrate is subjected to a leaching step with a lixiviant comprising hydrochloric acid to leach nickel from the laterite ore, followed by a liquid/solids separation step. The liquid obtained is subject to solvent extraction with a dialkyl ketone, to obtain a solution rich in iron and a raffinate. Separation of iron from cobalt and nickel is obtained.

Abstract: Method for production of metallic cobalt from the raffinate from solvent extraction of nickel’.

Abstract: Provided is a method for producing cobalt sulfate, wherein, on the occasion of separating an acidic solution containing calcium, magnesium and sodium as impurities from a cobalt chloride solution by solvent extraction, when a diluent is added to the extractant to be used to dilute the extractant by 10% to 30% by volume; in Step 1, the operational pH is maintained in the range of 4.0 to 5.0 and the liquid volume ratio of organic phase/liquid phase is maintained in the range of 5.0 to 7.0; in Step 2, the operational pH is maintained in the range of 4.0 to 4.5 and the liquid volume ratio of organic phase/liquid phase is maintained in the range of 5.0 to 10.0; and in Step 3, the pH is maintained in the range of 0.5 to 1.0.

Abstract: The objective of the present invention is to selectively extract cobalt from an acidic solution containing a high concentration of manganese. This cobalt extraction method extracts cobalt from an acidic solution containing manganese and cobalt by subjecting the acidic solution to solvent extraction by means of a valuable metal extraction agent comprising an amide derivative represented by general formula (I). The valuable metal extraction agent is represented by the general formula. In the formula: R1 and R2 each represent the same or different alkyl group; R3 represents a hydrogen atom or an alkyl group; and R4 represents a hydrogen atom or any given group aside from an amino group bonded to the ? carbon as an amino acid. Preferably, the general formula has a glycine unit, a histidine unit, a lysine unit, an aspartic acid unit, or an N-methylglycine unit. Preferably, the pH of the acidic solution is 3.5-5.5 inclusive.

Abstract: Provided is a production method for obtaining high purity nickel sulfate having low levels of impurities, particularly low levels of magnesium and chloride, by adjusting the concentration of an extractant and the pH concentration at the time of treatment in a process of obtaining a nickel sulfate solution having a high nickel concentration by solvent extraction using an acidic organic extractant.

Abstract: A method for concentrating metal chlorides in and separating same from an iron(III) chloride-containing hydrochloric acid solution is described, wherein iron is precipitated from the solution as iron oxide, preferably haematite and filtered off in a filtration device, and the now further concentrated non-hydrolysable metal chlorides are removed from at least a part of the hydrochloric acid filtrate.

Abstract: Disclosed herein is a method for easily and efficiently removing manganese from an aqueous acidic solution of sulfuric acid containing cobalt and manganese at low cast to obtain a high-purity cobalt sulfate aqueous solution usable as a raw material for lithium ion secondary batteries. The high-purity cobalt sulfate aqueous solution is obtained by mixing an aqueous acidic solution of sulfuric acid containing cobalt and manganese (aqueous phase) with an acidic organic extractant (organic phase) while adjusting the pH of the aqueous acidic solution of sulfuric acid to a value in a range between 2 and 4 with a pH adjuster such as sodium hydroxide to extract manganese into the organic phase. The acidic organic extractant to be used is preferably diluted so that the concentration of di-2-ethylhexyl phosphate is 10 to 30 vol %.

Abstract: The invention provides a process for the leaching of a laterite ore or concentrate for the recovery of value metals, at least one value metal being nickel. The laterite ore or concentrate is subjected to a leaching step with a lixiviant comprising hydrochloric acid to leach nickel from the laterite ore. Nickel is extracted with an oxime at a lower pH than other processes for extraction of nickel from solution, especially after separation of iron and cobalt values.

Abstract: Various embodiments provide a method comprising leaching a cobalt bearing material to form a slurry, filtering the slurry to yield solids and a cobalt bearing liquid phase, and forwarding the solids to a second leaching operation.

Abstract: Various embodiments provide a method comprising leaching a cobalt bearing material to form a slurry, filtering the slurry to yield solids and a cobalt bearing liquid phase, performing a solution extraction of the cobalt bearing liquid phase to yield a purified cobalt bearing liquid phase, precipitating cobalt gypsum by adding lime to a first portion of the purified cobalt bearing liquid phase, and recycling the cobalt gypsum to the leaching.

Abstract: The present invention relates generally to a process for controlled leaching and sequential recovery of two or more metals from metal-bearing materials. In one exemplary embodiment, recovery of metals from a leached metal-bearing material is controlled and improved by providing a high grade pregnant leach solution (“HGPLS”) and a low grade pregnant leach solution (“LGPLS”) to a single solution extraction plant comprising at least two solution extractor units, at least two stripping units, and, optionally, at least one wash stage.

Abstract: A process is described for the recovery of nickel and/or cobalt from laterite or partially oxidized lateritic ores having a substantial proportion of the iron present in the ferrous state. The process includes providing a laterite or partially oxidized laterite ore wherein a substantial proportion of the iron present in the ore is in the ferrous state; acid leaching the ore to provide a product leach solution containing at least ferrous iron, nickel and cobalt together with acid soluble impurities; and recovering the nickel and cobalt from the product leach solution with a selective ion exchange resin in an ion exchange process leaving the ferrous iron and other acid soluble impurities in the raffinate.

Abstract: A solid composition comprises: MnO2; and a compound represented by the general formula (I) wherein: R is a polymer; each Y is independently a hydrogen or a negative charge; Z is either hydrogen or is not present; each n is independently 1, 2, 3, 4, 5 or 6; wherein the MnO2 is bound to the compound of formula (I) so as to coat the surface thereof. Such a composition may be used for the separation of polyvalent metal species, such as Mo, from one or more accompanying impurities.

Abstract: Provided is a method for producing ferronickel from a nickel sulfide or a mixed sulfide containing nickel and cobalt, obtained by hydrometallurgy of nickel oxide ore or obtained from scraps or products in process. The method for producing a ferronickel raw material is to form the ferronickel raw material from a nickel sulfide or a mixed sulfide containing nickel sulfide and cobalt sulfide, wherein treatments are performed through the following steps: (1) redissolution step, (2) deferrization step, (3) solvent extraction step, (4) hydroxylation step, (5) roasting step, and (6) washing and calcining step.

Abstract: The invention provides hydrometallurgical processes by which dissolved nickel may be removed from water at ambient temperature and low system pressure.

Abstract: The present invention relates to a method for preparing magnetite nanoparticles from low-grade iron ore using solvent extraction and magnetite nanoparticles prepared by the same. According to the method for magnetite nanoparticles from low-grade iron ore of the present invention, it is possible to prepare high-purity magnetite nanoparticles having a purity of 99% or higher by solvent extraction using low-grade iron ore as a starting material, and thus it is possible to reduce the processing cost and the amount of energy used, thus supplying a high-efficiency magnetite nanoparticle adsorbent, which can be industrially applied to wastewater treatment or desalination plant, in large quantities at low cost. In particular, it is possible to effectively treat livestock wastewater, heavy metal wastewater, oil discharged into rivers, etc. at low cost, thus significantly contributing to the prevention of environmental pollution.

Abstract: A method for extracting cobalt from copper raffinate. First, a supply of raffinate containing at least cobalt, copper, ferric iron and nickel, is provided. The raffinate is pretreated by one or all of raising the raffinate pH level; removing solids; and, reducing ferric iron to ferrous iron. Substantially all copper is removed using first ion exchange resin selective for copper. A second ion exchange resin selective for both cobalt and nickel is used to remove the cobalt and nickel. Cobalt and nickel are separately eluted from the second ion exchange resin.

Abstract: The present invention refers to a direct purification process of a nickel laterite leaching effluent including adjusting a pH of a leaching solution, employing an ion exchange resin to adsorb nickel and copper selectively over ferric or ferrous iron, and recovering nickel.

Abstract: A method for recovering nickel from sulfuric acid aqueous solution, for recovering nickel in an effectively utilizable form as a raw material of nickel industry material, by separating efficiently impurity elements of iron, aluminum, manganese, etc., from the sulfuric acid aqueous solution containing nickel and cobalt, and the impurity elements, iron, aluminum, manganese, etc.

Abstract: The present application relates to novel gel-type or macroporous picolylamine resins which are based on at least one monovinylaromatic compound and at least one polyvinylaromatic compound and/or a (meth)acrylic compound and contain tertiary nitrogen atoms in structures of the general formula (I) as functional group, where R1 is an optionally substituted radical from the group consisting of picolyl, methylquinoline and methylpiperidine, R2 is —CH2—S—CH2COOR3 or —CH2—S—C1-C4-alkyl or —CH2—S—CH2CH(NH2)COOR3 or —CH2—S—CH2—CH(OH)—CH2(OH) or or derivatives thereof or —C?S(NH2), R3 is a radical from the group consisting of H, Na and K, m is an integer from 1 to 4, n and p are each, independently of one another, a number in the range from 0.1 to 1.9 and the sum of n and p is 2 and M is the polymer matrix, a process for preparing them and their uses, in particular the use in hydrometallurgy and electroplating.

Abstract: The present application relates to novel monodisperse, gel-type or macroporous picolylamine resins which are based on at least one monovinylaromatic compound and at least one polyvinylaromatic compound and/or a (meth)acrylic compound and contain tertiary nitrogen atoms in structures of the general formula (I) as functional group, where R1 is an optionally substituted radical from the group consisting of picolyl, methylquinoline and methylpiperidine, R2 is a radical —(CH2)q—COOR3, R3 is a radical from the group consisting of H, Na and K, m is an integer from 1 to 4, n and p are each, independently of one another, a number in the range from 0.1 to 1.9 and the sum of n and p is 2, q is an integer from 1 to 5 and M is the polymer matrix, a process for preparing them and their uses, in particular the use in hydrometallurgy and electroplating.

Abstract: Provided are methods using a ketoxime in metal extraction. One aspect of the invention relates to a method for the recovery of metal from a metal-containing aqueous solution at an elevated temperature using a ketoxime. Another aspect relates to a method of separating iron/copper using a specific ketoxime. Aldoximes may also be added to the reagent compositions used in these methods.

Abstract: The present disclosure relates to a process and system for recovery of one or more metal values using solution extraction techniques and to a system for metal value recovery. In an exemplary embodiment, the solution extraction system comprises a first solution extraction circuit and a second solution extraction circuit. A first metal-bearing solution is provided to the first and second circuit, and a second metal-bearing solution is provided to the first circuit. The first circuit produces a first rich electrolyte solution, which can be forwarded to primary metal value recovery, and a low-grade raffinate, which is forwarded to secondary metal value recovery. The second circuit produces a second rich electrolyte solution, which is also forwarded to primary metal value recovery. The first and second solution extraction circuits have independent organic phases and each circuit can operate independently of the other circuit.

Abstract: Reagent compositions, methods for their manufacture and methods of their use are described. In particular, provided are reagent compositions comprising an aldoxime and ketoxime with an alkyl substituent. Also provided are methods of metal recovery using these reagent compositions.

Abstract: The invention provides a process for the leaching of a laterite ore, concentrate, tailings or waste rock for the recovery of value metals, at least one value metal being nickel. The laterite ore or concentrate is subjected to a leaching step with a lixiviant comprising hydrochloric acid to leach nickel from the laterite ore, followed by a liquid/solids separation step. The liquid obtained is subject to solvent extraction with a dialkyl ketone, to obtain a solution rich in iron and a raffinate. Separation of iron from cobalt and nickel is obtained.

Abstract: Provided are methods using ketoximes and/or aldoximes, including 3-methyl-5-alkylsalicylaldoxime and/or 3-methyl-5-alkyl-2-hydroxyacetophenone oxime, in reagent compositions for metal extraction/isolation. One such method is of extracting a metal from an aqueous ammoniacal solution. Metals that can be extracted include nickel, zinc and copper.