Abstract: The disclosure discloses a method for recycling lead paste in a spent lead-acid battery, comprising: (1) pretreating lead paste in a spent lead-acid battery as a raw material under vacuum; mixing the pretreated lead paste with a chlorination reagent to obtain reactants; and heating the reactants under vacuum to carry out a chlorination volatilization reaction, so that lead element in the pretreated lead paste is combined with chlorine element in the chlorination reagent to form lead chloride, which is then volatilized, and after the reaction is completed, chlorination residue and a crude lead chloride product are obtained by condensation and crystallization after volatilization; (2) purifying the crude lead chloride product obtained in the step (1) under vacuum to obtain a refined lead chloride product.

Abstract: A method for the treatment of flue dusts containing arsenic and/or antimony from pyrometallurgical methods, wherein a reducing agent is added to the flue dusts, the flue dusts are heated together with the reducing agent, and volatile components are separated from a slag. The reducing agent is a carbonaceous compound.

Abstract: A technique is provided in which valuable material is recovered from solid recovered material generated during chlorinating process of titanium-containing raw material, and in particular, in which chlorine gas and titanium-containing raw material can be efficiently separated and recovered from the solid recovered material. The method for production of titanium tetrachloride includes: a chlorinating process in which titanium-containing raw material, coke and chlorine are reacted, a recovering process in which chlorine gas, titanium oxide and coke are recovered by treating solid recovered material which is byproduced during the chlorinating process, and a reusing process in which these recovered material are reused as raw material for the chlorinating process.

Abstract: The present invention provides a control valve for a water channel, which comprises of, from top to bottom, a control shaft bolt, a sliding valve disc, a fixing valve disc and a valve base. A valve shell combining with the valve base covers around a lower portion of the control shaft bolt, the sliding valve disc and the fixing valve disc to prevent mentioned components from falling out. The amount and the open/close operation of the two different kinds of water sources can be operated and controlled by a single control valve of the water channel to simplify the complexity in structure. Also it is convenient for a user to control the amount and the open/close operation of two different water sources by a single control valve.

Abstract: A process for producing metal oxide from a metal salt includes supplying a first part of the metal salt to a hydrate drier so as to indirectly heat the first part of the metal salt in the hydrate drier using a heat transfer medium from a first stage of a multi-stage indirect cooler so as to dry the first part of the metal salt in the hydrate drier and so as to control a waste gas temperature of the process. A second part of the metal salt is guided as a partial stream past the hydrate drier. The metal salt is preheated in a first preheating stage and precalcined in a second preheating stage. The metal salt and a fluidizing gas having a temperature of 150° C. or less are supplied to a fluidized bed reactor so as to calcine the metal salt to form a metal oxide product. The metal oxide product is cooled in at least one suspension heat exchanger and then in the multi-stage indirect cooler.

Abstract: A process for producing metal oxide from metal salts includes cleaning a metal salt in a filter. After cleaning, the metal salt is dried in a drying apparatus. Steam is formed in the drying apparatus. The metal salt is preheated in at least one preheating stage. The metal salt is calcined to metal oxide in a fluidized-bed reactor. The metal oxide is cooled. The steam formed in the drying apparatus is recirculated into the filter.

Abstract: A direct reduction process for a metalliferous material includes supplying the metalliferous material, a solid carbonaceous material, an oxygen-containing gas, and a fluidizing gas into a fluidized bed in a vessel and maintaining the fluidized bed in the vessel, at least partially reducing metalliferous material in the vessel, and discharging a product stream that includes the partially reduced metalliferous material from the vessel. The process comprises (a) reducing the metalliferous material in a solid state in a metal-rich zone in the vessel; (b) injecting the oxygen-containing gas into a carbon-rich zone in the vessel with a downward flow in a range of ±40° to the vertical and generating heat by reactions between oxygen and the metalliferous material (including metallized material), the solid carbonaceous material and other oxidizable solids and gases in the fluidized bed, and (c) transferring heat from the carbon-rich zone to the metal-rich zone by movement of solids within the vessel.

Abstract: A process for treating a finely particulate, in particular metal-containing, charge material: The charge material and a treatment gas, in particular a reduction gas, are introduced into a fluidized bed chamber of a fluidized bed reactor to form a fluidized bed. After at least partial reaction in the fluidized bed, the treatment gas is discharged from the fluidized bed and, outside the fluidized bed, is at least partially reprocessed, preferably oxidized, by an exothermic, chemical reaction with a reactant, preferably with a gaseous and/or liquid oxidizing agent. The thermal energy of this reaction is at least partially introduced into the fluidized bed chamber, in particular into the fluidized bed, or being discharged therefrom to affect the temperature of the particulate material above the bed. Also an apparatus for operating such a fluidized bed includes the chamber, lines into and out of the chamber for gas and material and a cyclone at the chamber for the material.

Abstract: A process for the recovery of metal oxides from a solution containing metallic salts by spray roasting of these solutions. The process is particularly suitable for spray roasting spent pickling acids. The process feeds the solution to a reactor for spray roasting of the droplets in at least two stages, where at least one evaporation stage follows at least one conversion stage to convert the metal salts to metal oxides. The device for implementing the process includes a spray roasting reactor having a first heating zone to evaporate the water and a second heating zone to convert the metal salts to oxides.

Abstract: Cyclical batch processes for halogenation, such as chlorination, of minerals in a fixed bed using a plurality of cycles which include the steps of at least partially evacuating the bed, charging the bed with reactant gas, maintaining the reactant gas in the bed for a predetermined time, and exhausting reaction products under vacuum. Also disclosed is the chlorination of spodumene in its beta crystalline form produced by calcining spodumene in its naturally-occurring alpha crystalline form to preferentially extract lithium as lithium chloride.

Abstract: Methods and apparatuses for separating metal values, such as nickel and nickel compounds, from mineral ores, including lateritic ores are disclosed. The method includes providing a mixture of particles (e.g., crushed and sized ore) that is composed of at least a first group of particles and a second group of particles. Group members have similar chemical composition, while particles belonging to different groups have dissimilar chemical compositions. The mixture of particles is concurrently, or generally concurrently, heated (using microwave/millimeter wave energy) and exposed to a reactant. The wave energy and the reactant act to increase the difference in either the magnetic susceptibility or other separation properties between the first and second group of particles. The mixture of particles is then passed through an appropriate separator to separate the particles of interest. Optional steps are disclosed for purifying selected particles.

Abstract: This invention relates to a method for stabilizing a fluidized bed used in roasting by adjusting the oxygen content of the roasting gas in the bed. The fine-grained material for roasting is fed into the furnace above the fluidized bed and the roasting gas, which causes the fluidizing, is fed into the bottom of the furnace through a grate. In this method, the total amount of oxygen in the roasting gas to be fed and the average total oxygen requirement of the material to be roasted are calculated and the ratio between them regulated so that the oxygen coefficient in the bed is over 1.

Abstract: The specification discloses a process for recovering chlorine from a chlorinator waste. The process involves treating the chlorinator waste with oxygen in a fluidised bed under conditions which promote the conversion of metal chlorides to metal oxides and discourage the oxidation of carbon contained in the waste. Suitable conditions include a bed temperature in a range from 400 to 700° C., a superficial velocity in a range from 0.2 to 1 metre/second and stoichiometric ratio, R, in a range from 0.2 to 1.2.

Abstract: Transition metals may be recovered from a salt-containing mixture containing at least one transition metal compound, salts, and organic compounds by separating from the salt-containing mixture a mixture of the transition metal compound and the salts. This mixture, together with any organic impurities, is introduced into a combustion zone, and the flue gas/salt mixture leaving the combustion zone is quenched with water. The combustion residue, containing the transition metal, is separated from the resulting quench solution, dried, and converted to fresh catalyst.

Abstract: Process for producing Iron carbide wherein, in a first stage, Iron ore is reduced to sponge iron using a reducing gas containing at least 90% hydrogen, on a nitrogen-free basis, to produce a sponge iron having a carbon content of less than 1% wt.; then in a second stage the sponge iron is fluidized at a temperature of 500 to 800° C. with a methane-containing fluidizing gas in a fluidized bed reactor wherein the water content of the gas in the reactor is not more than 1.5% wt., to produce a product wherein at least 85% of the iron content is in the form of Fe3C.

Abstract: Spindle-shaped magnetic metal particles containing iron as a main component of the present invention, have an average major axis diameter (L) of 0.05 to 0.15 &mgr;m; a coercive force of 111.4 to 143.2 kA/m; a Co content of from 0.5 to less than 5 atm % based on whole Fe; a crystallite size of from 150 to less than 170 Å; a ratio of Al to Co from 1.0:1 to less than 2.0:1; a specific surface area (S) represented by the formula: S≦−160×L+65; an oxidation stability (&Dgr;&sgr;s) of saturation magnetization of not more than 5.0%; and an ignition temperature of not less than 140° C. The spindle-shaped magnetic metal particles containing iron as a main component, exhibit an adequate coercive force, and are excellent in dispersibility, oxidation stability and coercive force distribution despite fine particles, especially notwithstanding the particles have an average major axis diameter as small as 0.05 to 0.15 &mgr;m.

Abstract: An end product containing iron carbide (Fe3C) is produced from an intermediate product consisting of granular, directly reduced iron. Said intermediate product is supplied by an iron ore reduction plant and is fed to a carburization reactor. Liquid hydrocarbons are conveyed to the carburization reactor at temperatures of 500 to 900° C., at least part of the granular, directly reduced iron being subjected to a swirling movement. The end product removed from the carburization reactor consists of 5 to 90 wt. % Fe3C. A fluidization gas containing methane and hydrogen can be added to the carburization reactor in addition to the hydrocarbons.

Abstract: Spindle-shaped magnetic metal particles containing iron as a main component, having an average major axis diameter (L) of 0.05 to 0.15 &mgr;m; a coercive force of 111.4 to 159.2 kA/m; a Co content of from 5 to less than 15 atm % based on whole Fe; a crystallite size of from 150 to less than 170 Å; a ratio of Al to Co from 0.3:1 to less than 2.0:1; a specific surface area (S) represented by the formula: S≦−160×L+65; an oxidation stability (&Dgr;&sgr;s) of saturation magnetization of not more than 4.5%; and an ignition temperature of not less than 145° C. The spindle-shaped magnetic metal particles containing iron as a main component, exhibit an adequate coercive force, and are excellent in dispersibility, oxidation stability and coercive force distribution despite fine particles, especially notwithstanding the particles have an average major axis diameter as small as 0.05 to 0.15 &mgr;m.

Abstract: A process for producing chlorine and iron oxide from iron chloride (which may be generated as a by-product of the direct chlorination of titaniferous ores) comprises the steps of converting ferrous chloride to ferric chloride by reaction with chlorine, separating the solids from the gaseous products, reacting the gaseous ferric chloride with oxygen, condensing unreacted ferric chloride onto iron oxide particles, separating the gaseous products from the iron oxide particles and recycling the iron oxide particles to the oxidation or condensation step.

Abstract: A process for adjusting a circulating fluidized bed, wherein a part of the carrier gas is recovered, mixed with a propellant and returned to the fluidized bed as a carrier gas.

Abstract: Iron carbide (Fe 3 C) is produced from granulated j sponge iron which has a maximum carbon content of 2 wt. % and is supplied from an iron ore reducing plant. The sponge iron is swirled with a gas containing carbon and a maximum 1.5 vol. % water in a fluidized bed reactor at temperatures ranging, from 500 to 800° C. A product is extracted from the reactor. The total iron content of said product is fixed at a minimum of 80 wt. % Fe 3 C. Preferably, methane or a gas containing methane is fed into the fluidized bed reactor as a gas containing carbon. A waste gas can be extracted from the top area of the fluidized bed reactor and hydrogen can be separated therefrom and at least partially directed into the reducing plant.

Abstract: The present invention is concerned with a method for the pre-reduction of laterite fines in a reactor, preferably a fluidized bed, with reducing gases generated in situ by adding a reducing agent such as a carbonaceous material in the fluidized bed chamber, fluidizing the bed with an oxidizing gas and maintaining the reactor at a temperature sufficiently high to partially combust the coal and generate a reducing atmosphere. The reactor bed discharge calcine product has a carbon content of about 0.1%, and the composite reactor product has a carbon content lower than 2.0%.

Abstract: A method of reducing the iron content of starting material containing calcium, silicon and oxygen, and iron in the form of a ferrite and/or oxide, for example a steel slag, includes the steps of heating the starting material to a temperature of at least 800° C. and preferably between 900° C. and 1150° C. inclusive, in the presence of a reductant such as carbon monoxide and in the presence of a siliceous material with which non-ferrous oxides released during the reduction form high melting point compounds, to produce a magnetic form of iron, and removing at least some of the magnetic form of iron to produce a product, which may be used as a raw material in the cement industry.

Abstract: The invention provides an iron sulfide characterized in that it comprises FeS.sub.2, Fe.sub.1-x S, Fe.sub.3 O.sub.4 and FeSO.sub.4, and that the secondary particles thereof, have a 50% volume-cumulative particle diameter of from 20 to 300 .mu.m. The invention also provides a process for producing an iron sulfide comprising the steps of introducing (a) ferrous sulfate monohydrate having a d.sub.50 of from 20 to 300 .mu.m and (b) not less than stoichiometric amount of at least one sulfur compound selected from elemental sulfur and hydrogen sulfide into the fluidized bed of a furnace and then fluidizing, burning, and reacting the ingredients at a temperature of from 350 to less than 630.degree. C., a superficial velocity of 0.1 m/sec or higher, and a pressure of 1 atm or higher using air as a fluidizing gas.

Abstract: Pyritic ores are heated with microwave energy in a fluidized bed to a temperature in the range of approximately 573 degrees Kelvin to 823 degrees Kelvin with a controlled amount of oxygen to promote the oxidation of the pyritic ores according to the reaction: 2FeS.sub.2 +3/2 O.sub.2 .fwdarw.Fe.sub.2 O.sub.3 +4S, thereby preventing the production of sulphur dioxide.

Abstract: A process and an apparatus for the production of iron oxides having low chloride ion content comprising charging of a free HCl containing iron chloride solution into a spray roaster with a feeding device and a spray boom for charging the iron chloride containing solution into a reaction chamber heated by combustion gases thermally decomposing the solution into iron oxide, HCl gas and reaction gases a discharging device for the iron oxide and a cooling zone between the burner's focal plane and the discharging device cooling of iron oxide granules to temperatures at less than 450.degree. C. reducing the concentration of HCl gas to less than 10 volume percent charging the layer of iron oxide granules onto a conveyor plate charged with hot steam and feeding the exhaust gases into the central combustion duct of the spray roaster. The resulting iron oxide has a residual chloride ion content of less than 500 ppm Cl.sup.- and a specific surface area in excess of 3.5 m.sup.3 /g.

Abstract: This invention describes a method of reprocessing zinc- and iron oxide-containing residual material. Zinc- and iron oxide-containing dust and/or sludge is granulated with water, granules and carbonaceous material are fed to a circulating fluidized bed system, the gas-solids suspension circulated in the circulating fluidized bed system is fed to a second fluidized bed reactor, the solids discharged from the second fluidized bed reactor are recycled to the reactor of the circulating fluidized bed system, 50 to 75% by volume of the oxygen required to gasify the carbonaceous material are fed as fluidizing gas to the reactor of the circulating fluidized bed system and 25 to 50% by volume of said required oxygen are fed as a fluidizing gas and secondary gas to the second fluidized bed reactor, iron oxide-containing material is discharged from the reactor of the circulating fluidized bed system and zinc-containing material is discharged with the exhaust gas from the circulating fluidized bed system.

Abstract: In a continuous process for reacting particulate ore with a liquid reagent in a counter-current vertical column the improvement comprising:(a) providing an upper and lower chamber for the vertical column;(b) maintaining sufficient upward flow of liquid reagent in The upper chamber so that the particulate ore is wetted and deaerated, at least some fine particles thereof are carried overhead for removal, and the remainder thereof settle and enter the lower chamber; and(c) maintaining sufficient fluidization and retention time in the lower chamber so that the desired amount of reaction with the ore takes place, at least some of the fine ore particles which are generated from the reaction process and/or which are introduced with the particulate ore are entrained and carried upward for removal, and the reacted particulate ore exits the lower chamber.

Abstract: In a fluidized bed process having a bed of fluidized particulate material which is susceptible to having at least some of the particulate material being entrained in the gases exiting the bed, the entrainment is reduced by introducing the particulate material into the process, in the substantial absence of a gas which transports the particulate material, at one or more points which are below the surface of the bed of fluidized particulate material.

Abstract: A method for producing high-purity iron oxide which comprises pulverizing iron ore into powder having an average particle diameter of 20-150 .mu.m, removing fine particles from the powder, and subjecting the powder to wet magnetic separation in a magnetic field of 1000-15000 gauss for the removal of impurities. The iron oxide powder may undergo the secondary steps of pulverization and classification, which are performed by the combination of a wet grinding means and a wet cyclone, and drying and calcination.

Abstract: Heavy metal compounds, particularly vanadium pentoxide, are recovered from petroleum coke by combusting the coke under conditions constraining the temperatures to within the range 680.degree. C. to 1400.degree. C., collecting the ash which is then subjected to a known process for the extraction of the metallic compounds.Whilst the combustion process may be achieved in a fluidised bed furnace, higher recovery rates are likely to be achieved utilising a tubular furnace chamber inclined at 10.degree. to horizontal. dried petroleum coke, ground to fine powder (ASTM 75 micron, or less) is entrained into a primary air flow injected tangentially into the chamber through ports together with secondary air sufficient to maintain an oxidising atmosphere. Molten slag is deposted on the chamber wall by centrifugal action and drained from the chamber to fall on a rotating steel drum immersed in a water trough. A scraper removes the slag from the drug as flakes which are removed from the water trough using a screw conveyor.

Abstract: A process for the recovery of nickel catalyst metal from a top portion of a fluidized bed consists essentially of the steps of providing a sludge material including spent catalyst including recoverable catalyst metal in the form of particles which are finely divided, and an organic material consisting essentially of fat, the organic material being combustible or otherwise degradable under conditions attainable by fluidized bed techniques; feeding the sludge material into a base portion of a fluidized bed including a bed of inert carrier material; converting the organic material to waste gases in the fluidized bed; maintaining the fluidized bed under conditions which cause the particles of recoverable catalyst metal to rise to a top portion of the fluidized bed, the recoverable catalyst metal comprising particles having an average particle size of less than 50 microns; removing the particles of recoverable catalyst metal and the waste gases from the top portion of the fluidized bed; and separating the particle

Abstract: A novel design for a fluidized bed reactor is provided. The fluidized bed reactor includes a baffle system to ensure the proper residence time of the feed materials. The fluidized bed reactor also provides a novel method for reducing the negative effects of thermal expansion in the reactor.

Abstract: Disclosed is a process to effect a reduction to a desired, constant degree as exactly as possible and to achieve a low surplus of carbon. The reduction by treatment with carbonaceous reducing agents is effected in such a manner that fine-grained solids, which contain higher metal oxides, are calcined at 800.degree. to 1100.degree. C. with hot gases in which the solids are suspended. The calcined solids are reduced at a temperature in the range of from 800.degree. to 1100.degree. C. to form low metal oxides in a stationary fluidized bed, which is supplied with carbonaceous reducing agents and oxygen-containing gases. The carbonaceous reducing agents are supplied to the stationary fluidized bed at such a rate so as to reduce the higher metal oxides to low metal oxides, while maintaining the reduction temperature in the stationary fluidized bed and insuring that the discharged matter has the desired carbon content.

Abstract: Chlorine may be recovered from residues from the fluidized bed chlorination of iron-containing metalliferous oxidic materials, such as ilmenite, bauxite, chromite, wolframite, scheelite, tantalite or columbite, the residues containing condensed iron chloride and blow-over bed solids, by heating the residue to revolatalize the iron chloride and reacting it with oxygen. The quantity of iron chloride in the oxidic material is controlled relative to the quantity of blow-over carbon so that the quantity of carbon is sufficient on combustion to provide the required heat but is insufficient to cause undue dilution of the chlorine produced by virtue of its combustion products. Chlorine of a concentration suitable for direct recycle to a chlorination process, e.g. of 30% to 50% volume concentration is produced.

Abstract: This invention relates to the development of a viable metallurgical process capable of treating low grade concentrates, bulk concentrates, dirty concentrates, or ore directly for the recovery of non-ferrous metals such as zinc, lead, copper, and precious metals and accordingly is significant to the development of massive fine grained sulphide ore bodies found throughout the world. The process involves the consecutive steps of sulphatizing roasting in a fluidized bed reactor, a two stage leach, metal recovery from solution by conventional processes such as electrowinning and precipitation, and recycling of residue wash waters and leach liquors containing high concentrations of iron and minor impurity elements to the roaster or a spray dryer for thermal decomposition. Simple and efficient rejection of iron from the circuit to residue as stable hematite is the net result of the recirculation and thermal decomposition.

Abstract: The object of the invention is to provide a process for the recovery of iron and nickel from low iron content laterite ores.Said process comprises subjecting the ore to a carburizing step in the presence of a reducing agent and carbon supplying agent to convert the iron to iron carbide, followed by smelting the residue or product of the carburizing step to produce a ferronickel product.An alternative embodiment is the recovery of the iron and nickel from the product of the carburizing step by magnetic separation.

Abstract: The object of the invention is to provide a process for the recovery of iron and zinc from steel making flue dust.The process comprises subjecting the flue dust to a carbiding step in a fluid bed in the presence of a reducing agent and a carbon supplying agent to break down the zinc ferrite structure and convert the iron to iron carbide, followed by heating the residue or product of the carbiding step to recover zinc by evaporization.The iron carbide produced may be introduced into a steel making furnace for the production of steel.An alternative procedure is the recovery of iron carbide and zinc by magnetic separation from the gangue after the carbiding step and before separation of zinc from iron carbide.

Abstract: The invention provides a process for thermally decomposing salts, containing mainly ferrous sulfate wherein said feed material is contacted in a single suspension-type exchanger with exhaust gases formed by reaction of the oxygen-containing gases in the fluidized bed reactor, the fluidizing gas and at least a partial stream of the secondary gas stream are heated by an indirect heat exchange in a fuel-heated heat exchanger, and the quantity of oxygen introduced via which consists of the fluidizing gas and the secondary gas, is controlled in dependence on the quantity of fuel in order to receive an exhaust gas from the suspension-type exchanger with a free oxygen content of 1-6% by volume and a temperature of 300.degree.-450.degree. C.

Abstract: A process for processing a sulfur-containing heavy oil, which comprises:in a first zone, catalytically cracking a sulfur-containing heavy oil in the presence of fluidized catalyst particles containing about 30 to 60 wt % Fe to thereby convert the heavy oil to a light oil, deposit sulfur-containing coke on the catalyst particles, and partially fixing the decomposed sulfur compounds with the reduced iron contained in the catalyst particles as iron sulfide;in a second zone, contacting the catalyst from the first zone with an oxygen containing gas in an amount less than that theoretically required to thereby partially combust the coke on the catalyst, reduce the iron in the catalyst, and fix the sulfur compounds contained in the coke as iron sulfide; andin a third zone, contacting the reduced catalyst from the second zone with steam in a fluidized manner to produce hydrogen and hydrogen sulfide and to convert the reduced iron and iron sulfide in the catalyst to iron oxides, with the iron oxide-containing catalyst

Abstract: The invention relates to a method of recovering the chlorine values from iron chloride obtained from the chlorination of an aluminous material containing iron oxide, such as bauxite. The method involves partially dechlorinating ferric chloride in the presence of a reducing agent to form products comprising ferrous chloride and a chloride compound derived from the reducing agent and oxidizing ferrous chloride at a temperature of about 300.degree. C. to 1200.degree. C. to form products comprising ferric chloride and ferric oxide. The ferric chloride is recycled and the chlorine values are recovered as the chloride of the reducing agent which is suitable for recycle to the aluminous chlorination stage or has other industrial utility.

Abstract: The invention relates to the recovery of chlorine values as ferric chloride from iron chloride dust which is obtained as a by-product from the chlorination of a titaniferous material containing more than 5% by weight iron oxide, such as ilmenite. The method comprises heating the iron chloride dust to a temperature above 275.degree. C. in the presence of chlorine and iron oxide and recovering the ferric chloride volatilized from the iron chloride dust together with the ferric chloride obtained from ferrous chloride present in the iron chloride dust by reaction with the chlorine and ferric chloride obtained from other metal chloride contaminants by reaction with the iron oxide.

Abstract: A process for producing a cracked distillate and hydrogen from a heavy oil which comprises cracking the heavy oil in the presence of laterite or a laterite-containing catalyst while simultaneously depositing coke on said laterite or laterite-containing catalysts, reducing the laterite or laterite-containing catalyst on which the coke is deposited, and forming a hydrogen-rich gas by contacting the reduced laterite or laterite-containing catalyst with steam.

Abstract: In a reactor for cracking heavy hydrocarbon oil through a fluidized bed of particles of natural ores, coke-like materials are deposited on a top of the reactor or pipe inside surfaces of a transfer line from the reactor to a scrubber. To effectively scour out the deposited coke-like materials, particles of natural ores having a mean diameter of a few hundred .mu.m is made to be contained in an effluent gas from the top of reactor, passing through the transfer line at a concentration of 1 to 40 g/m.sup.3. The particles of natural ores have a good effect of scouring out the deposited coke-like materials and can keep the transfer line efficiently clean even with a small amount of the particles of natural ores, decreasing a pressure drop in the transfer line.

Abstract: Nickeliferous sulfidic materials containing at least one other metal selected from the group consisting of cobalt, copper and iron are leached with an at least 3 N hydrochloric acid solution to produce a pregnant nickel chloride solution. The pregnant nickel chloride solution is treated with a liquid organic extractant to extract the other metals. The nickel chloride raffinate is concentrated with respect to nickel chloride, and the concentrated nickel chloride solution is heated to at least about 750.degree. C. to hydrolyze the nickel chloride to a refined nickel oxide product and a hydrogen chloride-containing gaseous effluent which is recycled to the concentration step and then through water to regenerate the leaching solution.

Abstract: A process for beneficiating titaniferous ores to a product having a lower percentage content of silicates, and other inerts comprising, at temperatures of 900.degree.-1100.degree. C., passing chlorine through a bed comprising (a) a first fraction of particulate titaniferous ore having about 90% of large particles, (b) a second fraction having about 90% small particles and (c) carbon in an amount equal to 10-30%, by weight, of the total titaniferous ore present, and removing freed silicates and inerts and by-product iron chloride thereby consuming (b) with the titanium dioxide values present in (b) being substituted for iron oxide values present in (a). The beneficiated ore is useful as an intermediate for preparing titanium dioxide pigments.

Abstract: A process for the chlorination of a material containing iron and titanium chemically combined with oxygen, comprising feeding the material to be chlorinated, in particulate solid form, into a reaction bed of solids containing ferrous chloride, and reacting it within that bed, at a temperature below the melting point of ferrous chloride, with a controlled amount of chlorine in the presence of sulphur in free or combined form, to produce solid ferrous chloride, titanium chloride, which is volatile at a temperature of operation, and sulphur dioxide, as the principal products of the process.

Abstract: Exothermic reaction of a fluid stream is carried out with recycle and addition of hot reacted fluid to the colder feed fluid stream, so as to raise the feed fluid stream to operable reaction temperatures and produce optimum reaction rate. The addition of hot reacted fluid is carried out by reactor-internal ejector-effected aspiration of a portion of the hot reacted fluid discharged from the reaction zone into the cold feed fluid. The resulting combined fluid stream is passed to the reaction zone. The balance of the hot reacted fluid not aspirated into the cold feed fluid is passed to product recovery or utilization. The invention is especially applicable to exothermic catalytic reactions.

Abstract: An improved process for preparing a metallic sulphate in a reaction zone from mixing of the corresponding metallic sulphide concentrates with ammonium sulphate and heating. Heating preferably includes directly contacting the mixture with products of combustion of a heating fuel at temperatures between about 150.degree. C and about 480.degree. C. The products of combustion may be diluted with a gas, and the metallic sulphate of the corresponding metallic sulphide may be initially mixed with the mixture to inhibit the development of semi-fluid conditions in the reaction of the metallic sulphide concentrates with ammonium sulphate.

Abstract: A process for the direct production of steel from particulate iron oxides or concentrates including two major steps in which in Step (1) the iron oxides are converted to iron carbide and in Step (2) steel is produced directly from the carbide in the basic oxygen furnace or the electric furnace. In the production of the carbide the oxides are reduced and carburized in a single operation using a mixture of hydrogen as a reducing agent and carbon bearing substances such as propane primarily as carburizing agents. Iron carbide thus produced is introduced as all or part of the charge into a basic oxygen furnace to produce steel directly without the blast furnace step. In order to make the steel making process auto-thermal, heat is supplied either by using the hot iron carbide from Step (1) or preheating the iron carbide or by including sufficient fuel in the iron carbide to supply the required heat by combustion.

Abstract: Disclosed is a resin composition comprising a copolymer [I] having a number average molecular weight of at least 15,000, which comprises at least 30 mole % of the following recurring units [A]: ##STR1## and a compound [II] having a number average molecular weight of at least 1,000, which is comprised of perfluoroalkylether recurring units [D]. This resin composition is used as a cladding of a core-clad optical fiber.