Treatment Of Matte Or Nodule Patents (Class 423/150.4)
  • Patent number: 8916116
    Abstract: The invention provides a process for the leaching of a laterite ore, concentrate, tailings or waste rock for the recovery of value metals, at least one value metal being nickel. The laterite ore or concentrate is subjected to a leaching step with a lixiviant comprising hydrochloric acid to leach nickel from the laterite ore, followed by a liquid/solids separation step. The liquid obtained is subject to solvent extraction with a dialkyl ketone, to obtain a solution rich in iron and a raffinate. Separation of iron from cobalt and nickel is obtained.
    Type: Grant
    Filed: December 12, 2012
    Date of Patent: December 23, 2014
    Assignee: Process Research Ortech inc.
    Inventors: Vaikuntam I. Lakshmanan, Ramamritham Sridhar, Jonathan Chen, M. A. Halim, Robert DeLaat
  • Patent number: 8597601
    Abstract: A process to use ferric sulphate equilibrium to reduce overall acid consumption and iron extraction, the process comprising the steps of: (i) sulphating; (ii) selective pyrolysis and (iii) selective dissolution.
    Type: Grant
    Filed: June 1, 2012
    Date of Patent: December 3, 2013
    Assignee: Vale S.A.
    Inventors: Tiago Valentim Berni, Antonio Clareti Pereira, Flavia Dutra Mendes
  • Patent number: 8287827
    Abstract: Process for the treatment of a lateritic nickel/cobalt ore consisting of a mixture (2) of limonite and saprolite, characterized in that: the mixture (2) in the presence of an iron-precipitating agent is made into a pulp (1), having a solids content of between 10 and 40% by weight; the pulp undergoes a leaching operation (4) with sulphuric acid (5), at a temperature between 70° C. and the boiling point and at atmospheric pressure; and a solid-liquid separation (8) is carried out so as to obtain an iron-containing solid residue (9) and a solution containing nickel and cobalt ions. Process for producing nickel and/or cobalt intermediate concentrates or commercial products using the above process.
    Type: Grant
    Filed: August 22, 2007
    Date of Patent: October 16, 2012
    Assignee: Eramet
    Inventors: Jérôme Agin, Yves Le Quesne, Bertrand Berthomieu
  • Patent number: 8147781
    Abstract: There is provided a method of treating a metalliferrous material, comprising providing a metalliferrous material including at least one target metallic element, solubilising the metalliferrous material so as to effect production of an intermediate product including an operative solution. The operative solution includes a solvent component and a solute component. The solute component includes at least one solute component-based target metallic element and each one of the at least one solute component-based target metallic element corresponds to a one of the at least one target metallic element of the metalliferrous material such that the operative solution includes at least one target metallic element.
    Type: Grant
    Filed: September 9, 2009
    Date of Patent: April 3, 2012
    Assignee: Sheritt International Corporation
    Inventors: Preston Carl Holloway, Michael Joseph Collins, Eugene William Yuzda
  • Publication number: 20110058998
    Abstract: There is provided a method of treating a metalliferrous material, comprising providing a metalliferrous material including at least one target metallic element, solubilising the metalliferrous material so as to effect production of an intermediate product including an operative solution. The operative solution includes a solvent component and a solute component. The solute component includes at least one solute component-based target metallic element and each one of the at least one solute component-based target metallic element corresponds to a one of the at least one target metallic element of the metalliferrous material such that the operative solution includes at least one target metallic element.
    Type: Application
    Filed: September 9, 2009
    Publication date: March 10, 2011
    Applicant: SHERRITT INTERNATIONAL CORPORATION
    Inventors: Michael Joseph COLLINS, Preston Carl HOLLOWAY, Eugene William YUZDA
  • Patent number: 7871584
    Abstract: A process for the recovery of nickel and cobalt from nickel and cobalt containing ores, including the steps of first leaching a laterite ore and/or a partially oxidized sulfide ore with an acid solution to produce a pregnant leach solution containing at least dissolved nickel, cobalt and ferric ions, and subsequently leaching a sulfide ore or concentrate with the pregnant leach solution to produce a product liquor. Alternatively, the laterite ore and/or partially oxidized sulfide ore can be leached in a combined leach with the sulfide ore or concentrate. The ferric ion content in the pregnant leach solution or in the combined leach is sufficient to maintain the oxidation and reduction potential in the sulfide leach high enough to assist in leaching nickel from the sulfide ore or concentrate.
    Type: Grant
    Filed: May 8, 2007
    Date of Patent: January 18, 2011
    Assignee: BHP Billiton SSM Technology Pty. Ltd.
    Inventors: Houyuan Liu, Alexey Duarte, Wolf Meihack
  • Patent number: 7799296
    Abstract: A method for converting nickel into a nickel salt solution. Nickel is dissolved and reacted in an oxygen-enriched acidic solution to produce a nickel salt solution as illustrated in the following chemical equation, wherein X is a conjugate base: Ni+H2X+½O2->NiX+H2O.
    Type: Grant
    Filed: November 8, 2005
    Date of Patent: September 21, 2010
    Assignee: Ovonic Battery Company, Inc.
    Inventors: Michael A. Fetcenko, Cristian Fierro, Avram Zallen, Tim Hicks
  • Patent number: 7601314
    Abstract: A process for the recovery of nickel and/or cobalt from an impure nickel, cobalt or mixed nickel/cobalt material including the steps of: a) providing a nickel, cobalt or mixed nickel/cobalt material; and b) contacting the nickel, cobalt or mixed nickel/cobalt material with a feed ammoniacal ammonium carbonate solution and a reductant in a leach step.
    Type: Grant
    Filed: April 8, 2004
    Date of Patent: October 13, 2009
    Assignee: BHP Billiton SSM Technology Pty Ltd
    Inventors: Peter Allan Anderson, Mark Fisher, John Ernest Fittock, Victoria Margaret Hultgren, Erin Maree Jones, Robert Bruce Messenger, Adam Sean Moroney
  • Patent number: 7563421
    Abstract: A hydrometallurgical process based on pressure leaching at elevated temperature for recovering nickel from nickel oxide ores, characterized by a simplified and efficient process as a whole, realizing a simplified leaching stage, reduced neutralizer consumption and precipitate production in the neutralization stage, and efficient use of recycled water. The hydrometallurgical process of the present invention, comprising a leaching stage which stirs the slurried ore in the presence of sulfuric acid at 220 to 280° C.
    Type: Grant
    Filed: May 10, 2005
    Date of Patent: July 21, 2009
    Assignee: Sumitomo Metal Mining Co., Ltd.
    Inventors: Hiroshi Kobayashi, Hirofumi Shouji, Masaki Imamura, Yoshitomo Ozaki, Naoyuki Tsuchida
  • Patent number: 7534407
    Abstract: A process for recovering nickel from a solid feed material containing nickel in the form of millerite is disclosed. The process includes treating a slurry of the solid feed material and a process solution so that all or at least part of the nickel in the millerite forms an acid leachable solid form. The process also includes pressure acid leaching the treated slurry and leaching nickel in solids in the slurry into solution. Finally, the process includes recovering nickel from solution.
    Type: Grant
    Filed: November 21, 2006
    Date of Patent: May 19, 2009
    Assignee: WMC Resources Limited
    Inventors: Natalia Streltsova, Domenic Furfaro
  • Patent number: 7416711
    Abstract: An atmospheric leach process in the recovery of nickel and cobalt from lateritic ores, said processing including the steps of: a) separating the lateritic ore into a low magnesium containing ore fraction, and a high magnesium containing ore fraction by selective mining or post mining classification; b) separately slurrying the separated ore fractions; c) leaching the low magnesium containing ore fraction with concentrated sulphuric acid as a primary leach step; and d) introducing the high magnesium content ore slurry following substantial completion of the primary leach step and precipitating iron as goethite or another low sulphate containing form of iron oxide or iron hydroxide, wherein sulphuric acid released during iron precipitation is used to leach the high magnesium ore fraction as a secondary leach step.
    Type: Grant
    Filed: March 14, 2003
    Date of Patent: August 26, 2008
    Assignee: QNI Technology Pty. Ltd.
    Inventors: Houyuan Liu, James D. Gillaspie, Coralie Adele Lewis, David Neudorf, Steven Barnett
  • Patent number: 7387767
    Abstract: A process for recovering nickel and cobalt values from nickel- and cobalt-containing laterite ores as an enriched mixed nickel and cobalt sulphide intermediate and for producing nickel and cobalt metal from the nickel and cobalt sulphide intermediate. The laterite ore is leached as a slurry in a pressure acid leach containing an excess of aqueous sulphuric acid at high pressure and temperature, excess free acid in the leach slurry is partially neutralized to a range of 5 to 10 g/L residual free H2SO4 and washed to yield a nickel- and cobalt-containing product liquor, the product liquor is subjected to a reductant to reduce any Cr(VI) in solution to Cr(III), the reduced product liquor is neutralized to precipitate ferric iron and silicon at a pH of about 3.5 to 4.0, and the neutralized and reduced product liquor is contacted with hydrogen sulphide gas to precipitate nickel and cobalt sulphides.
    Type: Grant
    Filed: April 7, 2005
    Date of Patent: June 17, 2008
    Assignee: Dynatec Corporation
    Inventors: Finlay Campbell, Michael Collins, Ian Masters, Lyle Trytten
  • Patent number: 6692710
    Abstract: The present invention provides methods for the isolation and production of magnesium products from leaching of laterite material with acid. A magnesium compound is formed by downstream treatment of a leach stream after at least one of nickel or cobalt have been brought into solution. Magnesite is then obtained by adding at least one of alkali metal or alkaline earth metal carbonate to the leach stream. The magnesite may be converted into magnesium chloride by adding an acid, such as HCL.
    Type: Grant
    Filed: March 22, 2001
    Date of Patent: February 17, 2004
    Assignee: Crew Development Corporation
    Inventor: Brian J. Ballou
  • Patent number: 6680035
    Abstract: A hydrometallurgical process is provided for leaching nickeliferous laterite ores at temperatures below the boiling point of the pulp and at atmospheric pressure. The high iron fraction of the laterite, referred to as limonite, is first contacted with concentrated sulfuric acid to partially or completely dissolve the iron and nickel into solution. A reducing agent is used to keep the redox potential in solution below 1000 mV to enhance cobalt dissolution and more advantageously between 1000 and 900 mV to avoid reduction of ferric iron. Further mixing of the leach slurry in the presence of sodium, potassium, or ammonium allows formation of iron jarosite at ambient pressure. The resulting acid from iron hydrolysis is neutralized with the low iron fraction of the laterite ore (saprolite), thereby dissolving nickel into solution. The resulting final leach slurry can then be treated with conventional methods to recover nickel and cobalt from solution.
    Type: Grant
    Filed: May 24, 2001
    Date of Patent: January 20, 2004
    Assignee: BHP Minerals International Inc.
    Inventors: J. Carlos Arroyo, David A. Neudorf
  • Patent number: 6582494
    Abstract: A process for recovering nickel and copper from a concentrate which includes the steps of subjecting the concentrate to a treatment phase to produce a first leach solution which contains predominantly copper and a second leach solution which contains predominantly nickel, subjecting the first leach solution to a process for copper recovery which includes a solvent extraction step to produce a raffinate which is high in sulphuric acid, recycling at least a portion of the raffinate to the aforementioned treatment phase and subjecting the second leach solution to a process for nickel.
    Type: Grant
    Filed: July 19, 2002
    Date of Patent: June 24, 2003
    Assignee: Billiton Intellectual Property, B.V.
    Inventors: David William Dew, Deborah Maxine Miller
  • Patent number: 6461577
    Abstract: A method of leaching sulphidic material that contains metals and arsenic under oxidising conditions and with the aid of microorganisms is characterised by mixing the material with an acid aqueous solution to form a pulp, and in that the material is leached in a first leaching stage at a pH of below 2 and at a temperature that ranges from room temperature to about 55° C. in the presence of an active quantity of microorganisms of the mesophilic and/or moderately thermophilic type, wherewith the major part of the arsenic content of the material and possibly also part of its metal content is/are leached-out and the arsenic leached from said material is oxidised successively to a pentavalent state.
    Type: Grant
    Filed: April 18, 2000
    Date of Patent: October 8, 2002
    Assignee: Boliden Mineral AB
    Inventors: Börje Lindström, Åke Sandström, Jan-Eric Sundkvist
  • Patent number: 6383460
    Abstract: A process for the recovery of nickel and/or cobalt values from a concentrate containing nickel or cobalt hydroxide comprises the steps of subjecting the concentrate to a leaching stage with an ammonium solution to produce a leach solution containing nickel and/or cobalt values and a residue. The nickel concentration in the leach solution is controlled to a maximum value of about 3 to 25 g/l, preferably 8 to 15 g/l and more preferably 10 g/l.
    Type: Grant
    Filed: November 27, 1998
    Date of Patent: May 7, 2002
    Assignee: Cominco Engineering Services Ltd.
    Inventor: David L. Jones
  • Patent number: 6379637
    Abstract: The present invention provides an atmospheric acid leaching process for leaching nickel and cobalt from highly-serpentinized saprolitic fractions of nickel laterite deposits that are generally too low in nickel to support economical extraction of their nickel contents by pyrometallurgical processing except under special circumstances, and generally too high in magnesium to be suitable for processing by modern high pressure acid leaching processes employed for treating predominantly limonitic nickel laterites. The process involves leaching the highly-serpentinized saprolitic portion of the nickel laterite ore profile in strong sulphuric acid solutions at atmospheric pressure and temperatures between 80° C. and 100° C., essentially autogenously, to extract at least 90% of its contained nickel content and a large proportion of its cobalt content after leaching reaction times of about one hour or less.
    Type: Grant
    Filed: October 31, 2000
    Date of Patent: April 30, 2002
    Inventor: Walter Curlook
  • Patent number: 6379636
    Abstract: A process is provided for the leaching of both the “limonite” (Fe approx. ≧25% and Mg approx. ≧6%) and “saprolite” (Fe approx. ≦20% and Mg approx. ≧10%) fractions of typical nickel and cobalt bearing laterite ore. The low magnesium fraction of the laterite ore is leached with sulfuric acid at high pressure and temperature to solubilize the metal values while precipitating most of the solubilized iron as hematite or other iron compounds and a portion of the dissolved aluminum as alunite or other aluminum compounds. After reducing the pressure of the leach slurry to approximately atmospheric pressure, the pregnant leach slurry or solution is contacted with the high magnesium fraction of the ore to solubilize most of the nickel contained in the high-magnesium ore fraction while dissolving only a small portion of the iron content of the high magnesium ore fraction.
    Type: Grant
    Filed: November 3, 1999
    Date of Patent: April 30, 2002
    Assignee: BHP Minerals International, Inc.
    Inventors: J. Carlos Arroyo, James D. Gillaspie, David A. Neudorf, Erik M. Weenink
  • Publication number: 20020012621
    Abstract: A process for the recovery of nickel and/or cobalt values from a concentrate containing nickel or cobalt hydroxide comprises the steps of subjecting the concentrate to a leaching stage with an ammonium solution to produce a leach solution containing nickel and/or cobalt values and a residue. The nickel concentration in the leach solution is controlled to a maximum value of about 3 to 25 g/l, preferably 8 to 15 g/l and more preferably 10 g/l.
    Type: Application
    Filed: November 27, 1998
    Publication date: January 31, 2002
    Inventor: DAVID L. JONES
  • Publication number: 20020006370
    Abstract: A process is provided for the leaching of both the “limonite” (Fe approx. ≧25% and Mg approx. ≦6%) and “saprolite” (Fe approx. <20% and Mg approx. ≧10%) fractions of typical nickel and cobalt bearing laterite ore. The low magnesium fraction of the laterite ore is leached with sulfuric acid at high pressure and temperature to solubilize the metal values while precipitating most of the solubilized iron as hematite or other iron compounds and a portion of the dissolved aluminum as alunite or other aluminum compounds. After reducing the pressure of the leach slurry to approximately atmospheric pressure, the pregnant leach slurry or solution is contacted with the high magnesium fraction of the ore to solubilize most of the nickel contained in the high-magnesium ore fraction while dissolving only a small portion of the iron content of the high magnesium ore fraction.
    Type: Application
    Filed: November 3, 1999
    Publication date: January 17, 2002
    Inventors: J. CARLOS ARROYO, JAMES D. GILLASPIE, DAVID A. NEUDORF, ERIK M. WEENINK
  • Patent number: 6261527
    Abstract: A process is provided for leaching nickeliferous laterite ores by hydrometallurgical methods at temperatures below the boiling point of the pulp and at atmospheric pressure from which high overall nickel and cobalt extractions are obtained. The high iron fraction of the laterite, referred to as limonite, is first contacted with a concentrated mineral acid to partially or completely dissolve the iron and nickel in solution. During this process, a reducing agent is used to keep the redox potential in solution below 1000 mV to enhance cobalt dissolution and more advantageously between 1000 and 900 mV to avoid reduction of ferric iron. Further mixing of the leach slurry in the presence of sodium, potassium, or ammonium will allow the formation of iron jarosite at ambient pressure. The resulting acid from iron hydrolysis is neutralized with the low iron fraction of the laterite ore (saprolite) dissolving nickel into solution.
    Type: Grant
    Filed: November 3, 1999
    Date of Patent: July 17, 2001
    Assignee: BHP Minerals International Inc.
    Inventors: J. Carlos Arroyo, David A. Neudorf
  • Patent number: 6206951
    Abstract: The invention relates to a method for leaching sulfidic nickel matte and particularly copper rich nickel matte, as well as for leaching said matte together with a metallic copper and/or copper-nickel matte. The leach of nickel matte is carried out as pressure leach in one or several stages by means of copper sulfate.
    Type: Grant
    Filed: March 12, 1999
    Date of Patent: March 27, 2001
    Inventor: Sigmund Fugleberg