Specified Particle Size Used Or Made Patents (Class 423/161)
  • Patent number: 11298682
    Abstract: In a method for capturing carbon, sulfur, and/or nitrogen from a target source, a matrix including activated metal dispersed in a metal activating agent is provided. The target source may be or include a carbon, sulfur, and/or nitrogen target compound. The target source is contacted with the matrix, wherein the activated metal reacts with the target source to produce elemental carbon, elemental sulfur, elemental nitrogen, and/or one or more compounds transformed from the target compound(s). The matrix may be produced by contacting a metal with the metal activating agent, and maintaining contact between the metal and the metal activating agent for a period of time sufficient for metal atoms from the solid metal to disperse in the metal activating agent. The reaction may also produce a metal compound. The activated metal may also be utilized in alkylation and other synthesis processes.
    Type: Grant
    Filed: May 7, 2015
    Date of Patent: April 12, 2022
    Assignee: North Carolina State University
    Inventor: Jerome J. Cuomo
  • Patent number: 11235981
    Abstract: The present invention refers to a process for the preparation of an aqueous solution comprising at least one earth alkali hydrogen carbonate and its uses.
    Type: Grant
    Filed: September 30, 2016
    Date of Patent: February 1, 2022
    Assignee: OMYA INTERNATIONAL AG
    Inventors: Matthias Buri, Samuel Rentsch, Patrick A. C. Gane, René Vinzenz Blum, Martine Poffet
  • Patent number: 11235980
    Abstract: The present invention refers to a process for the preparation of an aqueous solution comprising at least one earth alkali hydrogen carbonate and its uses. The process is carried out in a reactor system that comprises a tank (1) equipped with a stirrer (2) and at least one filtering device (4).
    Type: Grant
    Filed: January 31, 2013
    Date of Patent: February 1, 2022
    Assignee: OMYA INIERNATIONAL AG
    Inventors: Matthias Buri, Samuel Rentsch, Patrick A. C. Gane, René Vinzenz Blum, Martine Poffet
  • Patent number: 11235982
    Abstract: The present invention refers to a process for the preparation of an aqueous solution comprising at least one earth alkali hydrogen carbonate and its uses.
    Type: Grant
    Filed: September 30, 2016
    Date of Patent: February 1, 2022
    Assignee: OMYA INTERNATIONAL AG
    Inventors: Matthias Buri, Samuel Rentsch, Patrick A. C. Gane, René Vinzenz Blum, Martine Poffet
  • Patent number: 10364157
    Abstract: The present invention provides a process for producing high purity hydromagnesite from a source of magnesium chloride. The process involves preparation of a magnesium chloride brine of a specific concentration and reacting with sodium carbonate, while maintaining the reaction at a specific temperature range to form a hydromagnesite precipitate. The product can be calcined to generate high purity magnesium oxide compounds.
    Type: Grant
    Filed: April 10, 2015
    Date of Patent: July 30, 2019
    Assignee: Karnalyte Resources Inc.
    Inventors: Robin Phinney, Jonathon Phinney, Siu Ma
  • Patent number: 9624590
    Abstract: A method recovers an electropositive metal from a metal carbonate. In the method, hydrogen and halogen are combusted to form hydrogen halide. The solid metal carbonate is converted into metal chloride by a gaseous hydrogen halide. In an electrolysis, the metal chloride is decomposed into metal and halogen. The halogen produced in the electrolysis is led out of the electrolysis for combusting. Preferably, the hydrogen halide is produced by combusting the hydrogen and the halogen and the metal carbonate is converted into metal chloride in a fluidized bed reactor. Preferably, lithium is used as the metal.
    Type: Grant
    Filed: June 25, 2013
    Date of Patent: April 18, 2017
    Assignee: SIEMENS AKTIENGESELLSCHAFT
    Inventors: Manfred Baldauf, Guenter Schmid, Dan Taroata
  • Patent number: 9073789
    Abstract: A manufacturing method of a sintered ceramic body mixes barium silicate with aluminum oxide, a glass material, and an additive oxide to prepare a material mixture, molds the material mixture and fires the molded object. The barium silicate is monoclinic and has an average particle diameter in a range of 0.3 ?m to 1 ?m and a specific surface area in a range of 5 m2/g to 20 m2/g. The aluminum oxide has an average particle diameter in a range of 0.4 ?m to 10 ?m, a specific surface area in a range of 0.8 m2/g to 8 m2/g. A volume ratio of the aluminum oxide to the barium silicate is in a range of 10% by volume to 25% by volume.
    Type: Grant
    Filed: September 11, 2013
    Date of Patent: July 7, 2015
    Assignee: NGK Insulators, Ltd.
    Inventors: Yunie Izumi, Yoshimasa Kobayashi, Yuji Katsuda
  • Publication number: 20140286842
    Abstract: A method of mineralizing calcium from industrial waste comprising extracting calcium ions from a suspension of calcium rich granular particles and aqueous ammonium chloride to form a calcium-rich first fraction and a heavy second fraction. The heavy second fraction is separated from the first fraction and the calcium-rich first fraction is carbonated with a gas comprising carbon dioxide to form a suspension of precipitated calcium carbonate and aqueous ammonium chloride. The precipitate is separated from the aqueous ammonium chloride by centrifugal means and the separated heavy second fraction comprises an enriched weight percent of iron.
    Type: Application
    Filed: June 3, 2014
    Publication date: September 25, 2014
    Applicant: COREX MATERIALS, INC.
    Inventor: Frank A. KARBARZ
  • Patent number: 8809582
    Abstract: The present invention relates to an economic process for preparing surface-reacted calcium carbonate. The present invention further relates to a surface-reacted calcium carbonate having an increased specific BET surface area, and the use of a process for adjusting the specific BET surface area.
    Type: Grant
    Filed: August 8, 2013
    Date of Patent: August 19, 2014
    Assignee: Omya International AG
    Inventors: Patrick A.C. Gane, Daniel E. Gerard, Joachim Schölkopf
  • Patent number: 8785687
    Abstract: The present invention relates to an economic process for preparing surface-reacted calcium carbonate. The present invention further relates to a surface-reacted calcium carbonate having an increased specific BET surface area, and the use of a process for adjusting the specific BET surface area.
    Type: Grant
    Filed: June 15, 2010
    Date of Patent: July 22, 2014
    Assignee: Omya International AG
    Inventors: Patrick A. C. Gane, Daniel E. Gerard, Joachim Schölkopf
  • Publication number: 20140141246
    Abstract: System for producing precipitated calcium carbonate from calcium carbonate slurry waste; method for calcium carbonate slurry waste recovery, processing and purification and the precipitated calcium carbonate product thereof”. The application defines a system for producing precipitated CaCO3, said system having separation (m1), recovery (m2), processing (m3) and purification (m4) modules; a method for calcium carbonate slurry waste recovery, processing and purification, wherein additives (dispersants) and lime are added to the slurry, said slurry being subjected to the following steps: hydration (20-70% solids), separation using a sieve, acidulation/carbonation using CO2 from the boiler (step wherein phosphoric acid is added along with chelating acidulants such as sulfuric acid, hydrogen peroxide and citric acid), decanting, delaminating, homogenization (with dispersants being added), separation using a sieve, stabilization (pH adjusted to between 8 and 9.5) and drying (1.
    Type: Application
    Filed: December 15, 2011
    Publication date: May 22, 2014
    Applicant: ECOFILL ESPECIALIDADES EM TECNOLOGIA DE TRANSFOMÇÃO DE RESÍDOUS LTDA
    Inventor: Márcio Nunes Da Silva
  • Publication number: 20140044619
    Abstract: A continuous countercurrent flow process for converting FGD gypsum to ammonium sulfate and calcium carbonate including countercurrent flows with internal recycle of liquids to maximize the purity of reaction products while minimizing reaction times, and further include embodiments of the process that provide a yield of both ammonium sulfate and calcium carbonate to be 97 to 100%, and embodiments that provide for processes having a total time of reaction being 8 to 12 minutes, the invention further including processes for removing contaminants from the FGD gypsum employing an acid rinse process and/or a slurry tank reactor process.
    Type: Application
    Filed: August 9, 2013
    Publication date: February 13, 2014
    Inventors: Murray P. Hasinoff, Taylor Pursell, Joseph A. Saiia, Arthur R. Shirley, JR., Keith D. Cochran, Timothy G. Holt
  • Patent number: 8470272
    Abstract: The present invention resides in a process of recovering nickel and cobalt, regenerating the main raw materials, said process including the steps of: granulometric separation; leaching; neutralization; MHP production in only one stage and the pressure crystallization of magnesium sulphite. The process proposes a way to recovery nickel and cobalt from laterite ores through the atmospheric and heap leaching with staged addition of ore—by size separation—and H2SO4, decreasing the nickel losses and simplifying the neutralization circuit and producing a more purified MHP. The present process route is employed for nickel extraction, including the one from high magnesium containing lateritic ores.
    Type: Grant
    Filed: June 1, 2009
    Date of Patent: June 25, 2013
    Assignee: Vale S.A.
    Inventors: Antonio Clareti Pereira, Felipe Hilario Guimaraes, Joao Alberto de Lessa Tude, Lino Rodrigues de Freitas, Tiago Valentim Berni
  • Patent number: 8388915
    Abstract: A method for producing basic magnesium sulfate granules, by heating a water-containing granular composition to a temperature of 50-250° C. to dryness. The granular composition has a water content of 10-60 wt. % and comprises fibrous basic magnesium sulfate particles, magnesium hydroxide in an amount of 5-300 weight parts per 100 weight parts of the fibrous basic magnesium sulfate particles, magnesium sulfate in an amount of 0.1-200 weight parts per 100 weight parts of a total amount of the fibrous basic magnesium sulfate particles and magnesium hydroxide. This method can give basic magnesium sulfate granules having a low bulk density and a high crushing strength.
    Type: Grant
    Filed: March 30, 2009
    Date of Patent: March 5, 2013
    Assignee: Ube Material Industries, Ltd.
    Inventors: Shinichi Yamamoto, Takashi Kishimoto
  • Publication number: 20120328497
    Abstract: A method of producing calcium carbonate from a waste sludge containing calcium carbonate and at least one silicate mineral. The method comprises the steps of: (i) incinerating the sludge to an ash in which at least 60% of the calcium carbonate present in the sludge is converted to free calcium oxide which is unreacted with the silicate mineral(s), (ii) optionally slaking the ash to convert at least a portion of the free calcium oxide therein to calcium hydroxide, (iii) treating either the ash from step (i) or the slaked ash from step (ii) with an aqueous solution of a polyhydroxy compound to provide a solution of dissolved calcium hydroxide, (iv) separating insoluble material from the solution of calcium ions obtained in step (iii), (v) dispersing carbon dioxide through the solution obtained from step (iv) so as to produce calcium carbonate, and (vi) separating the calcium carbonate produced in step (v).
    Type: Application
    Filed: June 14, 2012
    Publication date: December 27, 2012
    Inventor: Robert Philip Higgs
  • Patent number: 8012445
    Abstract: A method and apparatus for producing a calcium carbonate product formed of small <100 ?m sized separate calcium carbonate particles. Calcium hydroxide is fed through a disintegration and spraying apparatus (14), operating on the principle of a pin mill, into a gas which contains carbon dioxide for precipitating calcium carbonate particles and which is inside a precipitation reactor (10). The temperature in the precipitation reactor is maintained at <65° C.
    Type: Grant
    Filed: July 5, 2005
    Date of Patent: September 6, 2011
    Assignee: FP-Pigments Oy
    Inventors: Mikko Maijala, Roope Maijala, Bj{hacek over (o)}rn Lax, Jarmo Tolonen, Jeuvo Tjurin
  • Publication number: 20110110832
    Abstract: The present invention resides in a process of recovering nickel and cobalt, regenerating the main raw materials, said process including the steps of: granulometric separation; leaching; neutralization; MHP production in only one stage and the pressure crystallization of magnesium sulphite. The process proposes a way to recovery nickel and cobalt from laterite ores through the atmospheric and heap leaching with staged addition of ore—by size separation—and H2SO4, decreasing the nickel losses and simplifying the neutralization circuit and producing a more purified MHP. The present process route is employed for nickel extraction, including the one from high magnesium containing lateritic ores.
    Type: Application
    Filed: June 1, 2009
    Publication date: May 12, 2011
    Applicant: VALE S.A.
    Inventors: Antonio Clareti Pereira, Felipe Hilario Guimaraes, Joao Alberto de Lessa Tude, Lino Rodrigues de Freitas, Tiago Valentim Berni
  • Patent number: 7704476
    Abstract: The present invention relates to a process and a plant for producing sulfuric acid, in which a starting gas containing sulfur dioxide at least partly reacts with molecular oxygen in at least one contact with at least one contact stage to form sulfur trioxide, and in which the sulfur-trioxide-containing gas produced is introduced into an absorber and converted there to sulfuric acid. To achieve that only small gas volumes must be supplied to the first contact stage, based on the amount of sulfur dioxide used, with at least the same capacity of the plant and by using conventional catalysts, it is proposed in accordance with the invention to supply to the first contact stage a contact gas with a sulfur dioxide content of more than 16 vol-% and with a volumetric ratio of sulfur dioxide to oxygen of more than 2.67:1.
    Type: Grant
    Filed: April 12, 2005
    Date of Patent: April 27, 2010
    Assignee: Outotec OYJ
    Inventors: Karl-Heinz Daum, Hannes Storch, Jan Rieder
  • Patent number: 7595037
    Abstract: Described is a method as well as an apparatus for hydration of a particulate or pulverulent material containing CaO. The method is peculiar in that water is added in a quantity which will ensure that the partial pressure PH2O of the added water as a function of the temperature (° C.) is maintained within the interval defined by the formula (I), where PH2O is the partial pressure of water vapour in atm. and T is the temperature in ° C. Hereby is obtained that the material particles do not lump into agglomerates, and that the particles are hydrated evenly from the outside and inwards so that it is the active surface of the material particles which undergoes hydration in connection with partial hydration. This is due to the fact that the liquid water will not get into contact with the material particles since the water will appear in vapour form within the specified interval.
    Type: Grant
    Filed: February 16, 2005
    Date of Patent: September 29, 2009
    Assignee: FLSMIDTH A/S
    Inventors: Jens Peter Hansen, Lars Skaarup Jensen
  • Patent number: 7501110
    Abstract: This patent describes the use of barium sulfate as filler for thermosetting and thermoplastic plastics, elastomers, sealants, adhesives, fillers, varnishes, paints, paper, glass and as substrate for colored pigment formulations as well as for single-layer or multilayer coatings consisting of metal oxides, metal oxide mixtures and/or metal compounds, as a nucleus of crystallization for lead sulfate in the negative electrode paste of lead accumulators and as an X-ray contrast medium, the barium sulfate being produced by a continuous process wherein a barium salt solution and a sulfate solution are simultaneously and continuously brought together in equimolar quantities in a precipitating suspension at a temperature of 30 to 90° C., with constant stirring, the precipitating suspension is withdrawn continuously in a steady volume and the barium sulfate precipitate is filtered, washed and optionally dried, wherein the barium salt solution has a concentration of 0.1 to 0.
    Type: Grant
    Filed: March 11, 2005
    Date of Patent: March 10, 2009
    Assignee: Sachtleben Chemie GmbH
    Inventors: Djamschid Amirzadeh-Asl, Jürgen Bäuml, Udo Selter
  • Publication number: 20080299024
    Abstract: Method for industrial manufacture of pure MgCO3 comprising providing an olivine containing species of rock, to comminute the olivine containing species of rock to increase its surface, to contact the comminuted olivine containing species of rock with water and CO2. The process is conducted in at least two steps, namely a first step (R1) at a first pH where a dissolving reacting as represented by the equation: Mg2SiO4(S)+4H+=2Mg2++SiO2(aq)+2H2O, takes place. Then a precipitation takes place in the second step (R2) at a higher pH as represented by the equations: Mg2++HCO3?=MgCO3(S)+H+, and Mg2++CO32?=MgCO3(S), the presence of HCO3? and H+ ions mainly provided by the reaction between CO2 and water.
    Type: Application
    Filed: November 23, 2006
    Publication date: December 4, 2008
    Applicant: INSTITUTT FOR ENERGITEKNIKK
    Inventors: Oddvar Gorset, Harald Johansen, Jan Kihle, Ingrid Anne Munz, Arne Raaheim
  • Patent number: 7288239
    Abstract: The invention relates to synthesis of nanoparticles, in particular to methods for producing nanoparticles with networks consisting of Z sulphate (Z=magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba) or the binary mixtures thereof). The inventive method consists in synthesising the nanoparticles by crystal growth from an ion Z source and a sulphate ion source in a liquid phase mixture. The invention produces Z sulphate nanoparticles having a small diameter and uniformly dispersible in water or other solvents in a simple way. Co-ordinating solvents like glycerine, glycol ethylene and other polyethylene glycols, polyalcohols or dimethylsulphoxide (DMSO) are used for the synthesis mixture.
    Type: Grant
    Filed: November 19, 2003
    Date of Patent: October 30, 2007
    Assignee: Nanosolutions GmbH
    Inventors: Fernando Ibarra, Christiane Meyer, Stephan Haubold, Thorsten Heidelberg
  • Patent number: 7135157
    Abstract: A process for the preparation of platy precipitated calcium carbonate comprising the steps of providing a suspension of calcium hydroxide, carbonating the suspension of calcium hydroxide, adding a polyacrylate to the suspension prior to the completion of carbonation to precipitate platy calcium carbonate. Also provided are a paper that is filled and a paper that is coated using the platy precipitated calcium carbonate according to the present invention.
    Type: Grant
    Filed: June 6, 2003
    Date of Patent: November 14, 2006
    Assignee: Specialty Minerals (Michigan) Inc.
    Inventor: Harry John Huhn, III
  • Patent number: 7128887
    Abstract: A process for the preparation of platy PCC comprising the steps of providing a suspension of calcium hydroxide, carbonating the suspension of calcium hydroxide, adding a condensed phosphate to the suspension prior to the completion of carbonation to precipitate platy calcium carbonate. A paper that is filled is also provided and a paper that is coated and a polymer that is filled are envisioned that use the platy PCC according to the present invention.
    Type: Grant
    Filed: May 29, 2003
    Date of Patent: October 31, 2006
    Assignee: Specialty Minerals (Michigan) Inc.
    Inventor: Harry John Huhn, III
  • Patent number: 6132696
    Abstract: A method for the manufacture of precipitated calcium carbonate from impure calcium oxide of improved color is disclosed. The method comprises admixing impure calcium oxide with an aqueous solution consisting essentially of a salt of at least one compound selected from the group consisting of organic amines of the formula RNH.sub.2 and alkanolamines of the formula NH.sub.2 (R.sup.1 OH), where R and R.sup.1 are alkyl groups of 1-4 carbon atoms, and hydrochloric or nitric acid. The solution obtained is treated with a reducing agent e.g. sodium hydrosulphite, separated from insoluble matter and then treated with carbon dioxide or the carbonate of the amine or alkanolamine at a temperature of at least 50.degree. C. Preferably, the amine of the salt and of the carbonate are the same, and the salt is used in at least the stoichiometric amount to dissolve the lime.
    Type: Grant
    Filed: June 5, 1998
    Date of Patent: October 17, 2000
    Assignee: Goldcorp Inc.
    Inventors: Alvin Lee Porter, William Joseph Wilson
  • Patent number: 6099814
    Abstract: In the method for the humid treatment of effluents containing a compound selected from the group consisting of H.sub.2 SO.sub.4, free SO.sub.2, SO.sub.3.sup.-, or SO.sub.4.sup.= and having a pH lower than 5, the effluents are reacted with a basic compound. Particles selected from the group consisting of CaCO.sub.3.MgCO.sub.3, MgCO.sub.3 and a mixture of these, are used for treating the said effluents, the said particles having a particle size such that at least 95% of the particles selected from the group consisting of CaCO.sub.3.MgCO.sub.3 and MgCO.sub.3 have a particle size smaller than 75 .mu.m. After treatment magnesium sulfate in the form of a solution or brine is recovered.
    Type: Grant
    Filed: May 28, 1997
    Date of Patent: August 8, 2000
    Assignee: Lloist Recherche et Developpement S.A.
    Inventors: Henri Rene Langelin, Simon Colombier
  • Patent number: 5567665
    Abstract: A process is provided for preparing a shape-shifted catalyst component comprising (1) contacting a dihydrocarbyloxide magnesium compound with carbon dioxide in the presence of a slurrying agent to form a slurry of a carboxylated dihydrocarbyloxide magnesium compound; (2) adding a filler to the slurry either before or after the carboxylation of step (1); (3) spray drying the slurry of step (2) to evaporate the slurrying agent and to produce solid particles of the carboxylated dihydrocarbyloxide magnesium compound incorporating the filler; and, optionally, (4) heating the solid particles to remove carbon dioxide to produce a shape-shifted dihydrocarbyloxide magnesium compound component. A catalyst system using the component and a polymerization process employing the catalyst system are also provided.
    Type: Grant
    Filed: May 23, 1995
    Date of Patent: October 22, 1996
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Burkhard E. Wagner, Daniel P. Zilker, Jr., Robert J. Jorgensen
  • Patent number: 5304382
    Abstract: Ferritin analogs comprising an apoferritin protein shell and a core substantially devoid of ferrihydrite, e.g. of inorganic composition such as aluminum hydroxide or organic composition such as acetaminophen. The protein shell can be removed from ferritin analog to produce spherules having a substantially monomodal nominal diameter between about 45 and 100 Angstroms.
    Type: Grant
    Filed: March 26, 1992
    Date of Patent: April 19, 1994
    Assignee: Monsanto Company
    Inventor: Bruce F. Monzyk
  • Patent number: 5286285
    Abstract: A finely powdery magnesium hydroxide especially suitable as a flame-retardant filler for plastic compounds, in which the particles are provided optionally with a thin coating of a surfactant. The grain size of the magnesium hydroxide, measured by laser diffraction, is below 10 .mu.m. The median value of the grain size is greater than 0.8 .mu.m, and the maximum of the median value of the grain size is 3 .mu.m. The contents of water-soluble ionic impurities, viz. Ca.sup.++, Na.sup.+, K.sup.+, SO.sub.4 --, Cl.sup.-, of the magnesium hydroxide are below the following limits (in parts by weight): Ca.sup.++ <1000 ppm, Na.sup.+ <20 ppm, K.sup.+ <20 ppm, SO.sub.4 --<1500 ppm, Cl.sup.- <1000 ppm. The contents of Mn, Cu and Ni are below the following limits (in parts by weight): MnO<100 ppm, NiO<100 ppm, CuO<10 ppm.
    Type: Grant
    Filed: June 4, 1993
    Date of Patent: February 15, 1994
    Assignee: Veitscher Magnesitwerke-Actien-Gesellschaft
    Inventors: Andreas Meier, Michael Grill
  • Patent number: 5112584
    Abstract: Method for production of magnesium chloride, to be used for production of magnesium, by leaching of magnesite in hydrochloric acid. A two-stage leaching process is used where in a first reactor magnesite lumps are dissolved in hydrochloric acid. The magnesium chloride containing solution is led to a second reactor, where finely ground magnesite or hydrochloric acid is added to obtain approximate equivalence between magnesium and chlorine. To precipitate the impurities an excess of magnesium oxide or magnesium hydroxide is added in one or several purification stages.
    Type: Grant
    Filed: April 17, 1990
    Date of Patent: May 12, 1992
    Assignee: Norsk Hydro a.s.
    Inventors: Glor T. Mejdell, Hanne M. Baumann, Kjell W. Tveten
  • Patent number: 4978516
    Abstract: A process for improving a purity and/or whiteness degree of a talc powder is disclosed. A talc powder with a particle size of about 0.8 mm or less containing impurities such as asbestos, etc. is treated with a phosphoric acid agent under heating at from 70.degree. to 250.degree. C. to remove impurities such as asbestos, etc. by utilizing the difference in the rate of dissolution as between the talc and the impurities. The phosphoric acid agent is one selected from the group consisting of phosphoric acid, pyrophosphoric acid, sodium phosphate, ammonium phosphate, calcium phosphate, sodium tripolyphosphate, sodium pyrophosphate, sodium hexametaphosphate and mixtures thereof. Thus, asbestos, which is considered to be carcinogenic, can be effectively removed from talc.
    Type: Grant
    Filed: July 25, 1989
    Date of Patent: December 18, 1990
    Assignee: Asada Mill Co., Ltd.
    Inventors: Osamu Yamada, Kozo Shinohara
  • Patent number: 4968498
    Abstract: Process for the manufacture of a mixed metal oxide powder, in which at least one metal alcoholate is hydrolyzed in the presence of at least one metal oxide or hydroxide and of an acidic organic compound containing more than 6 carbon atoms in the molecule. The process is applicable to the production of barium titanate powders.
    Type: Grant
    Filed: June 15, 1988
    Date of Patent: November 6, 1990
    Assignee: Solvay & Cie (Societe Anonyme)
    Inventors: Henri Wautier, Luc Lerot
  • Patent number: 4944928
    Abstract: A process for the preparation of pure magnesium oxide, especially suitable for the preparation of refractory products, from magnesium silicate and magnesium hydrosilicate materials such as olivine, serpentine, garnierite, or the like, the starting material being decomposed (digested) with hydrochloric acid, the residues being separated from the decomposition slurry and the sesquioxides to be regarded as contaminants and other contaminants being precipitated from the crude brine thus obtained by the addition of crude serpentine as a pH increasing substance, the precipitates being separated and the magnesium chloride solution thus obtained being subjected to thermal decomposition, particularly by spray calcination, whereby magnesium oxide is obtained and hydrogen chloride is recovered.
    Type: Grant
    Filed: February 27, 1989
    Date of Patent: July 31, 1990
    Assignee: Veitscher Magnestiwerke-Actien-Gesellschaft
    Inventors: Michael Grill, Gerhard Graf
  • Patent number: 4664888
    Abstract: A rough cut catalyst/vapor separator for fluid catalyst cracking risers which is located at the outlet of a riser and causes the oil-catalyst mixture to undergo a tight, 180 degree downward turn. The centrifugal separator is equivalent to one-half a turn inside a cyclone and causes most of the catalyst to move to the wall. Most of the oil vapors are squeezed out away from the wall. At the end of the separator is a shave-off scoop positioned to divide a predominantly catalyst phase from a predominantly oil phase. The shave-off scoops conduct the catalyst phase away from the center of the vessel and deposit it near the vessel wall where its downward flow is continued under the action of gravity. The oil vapor phase continue its downward flow for a while but then must undergo a 180 degree turn and flow upward to exit the vessel through a series of conventional cyclone separators. The second 180 degree turn of the oil vapors help separate catalyst which is not caught by the shave-off scoop.
    Type: Grant
    Filed: June 27, 1985
    Date of Patent: May 12, 1987
    Assignee: Texaco Inc.
    Inventor: Leonce F. Castagnos, Jr.
  • Patent number: 4591495
    Abstract: In a system using the double absorption process for sulphuric acid manufacture, a single acid circulation system and a single cooler are employed. Acid from the exit of the air drying tower and final absorber tower are mixed in a common reservoir, while acid from intermediate absorber tower is discharged to a separate reservoir. Acid from the common reservoir is split between the intermediate and final absorber towers and product line. Acid from the separate reservoir is cooled and split between the drying tower and intermediate absorber tower. The circulation arrangement reduces the cooling to one relatively high temperature location and simplifies acid strength and level control. Only half of the bulk of the circulating acid has to be cooled and the effect of seasonal fluctuating temperatures in the drying tower is minimized.
    Type: Grant
    Filed: August 29, 1985
    Date of Patent: May 27, 1986
    Assignee: C-I-L Inc.
    Inventor: Gordon M. Cameron
  • Patent number: 4548794
    Abstract: According to the present invention, processes are provided for recovery of nickel, cobalt and like metal values from laterite ores wherein the ores are separated into high and low magnesium containing fractions, the low magnesium fraction is leached with sulfuric acid at elevated temperatures and pressure to solubilize the metal values. The pregnant liquor resulting from the high pressure which also contains solubilized Fe, Al and acid is then contacted with a low magnesium fraction of the ore in a low pressure leach under conditions such that at least some of the acid is neutralized and substantially all of the solubilized Fe and Al is removed as hematite and alunite precipitate.In one embodiment, the pregnant liquor from the high pressure leach and the high magnesium fraction are contacted at atmospheric pressure and a temperature of about 80.degree. C. prior to low pressure leaching. In other embodiments, various process streams are separated by size and otherwise, and recycled to within the processes.
    Type: Grant
    Filed: July 22, 1983
    Date of Patent: October 22, 1985
    Assignee: California Nickel Corporation
    Inventors: E. Harris Lowenhaupt, John E. Litz, Dennis L. Howe
  • Patent number: 4541994
    Abstract: According to the present invention, Ni- and Co-rich, low Mg fines may be advantageously separated from the coarse fractions of lateritic ores by atmospheric or low pressure leaching. In particular, the process of the present invention comprises contacting a lateritic ore or ore fraction at temperatures from about 20.degree. C. to about 200.degree. C. and pressures from about atmospheric to about 200 psig with an aqueous acid solution to form a leach liquor, a leach residue and a fines fraction. The fines fraction which can be separated from the residue with the leach liquor by conventional means such as cycloning is found to be richer in Ni and Co and lower than the remainder of the residue.
    Type: Grant
    Filed: July 22, 1983
    Date of Patent: September 17, 1985
    Assignee: California Nickel Corporation
    Inventors: E. Harris Lowenhaupt, John E. Litz, Dennis L. Howe
  • Patent number: 4512958
    Abstract: A method of recovering molybdenum oxide as in U.S. Pat. No. 4,379,127 wherein, however, the temperature in the autoclave and the pressure therein are controlled within narrow ranges by increasing the suspension density of the molybdenum sulfide suspension fed to the autoclave upon a fall in temperature and by adding water to the slurry of molybdenum sulfide concentrate formed before introduction into the autoclave upon an increase in temperature.
    Type: Grant
    Filed: October 28, 1983
    Date of Patent: April 23, 1985
    Assignee: GfE Gesellschaft fur Elektrometallurgie mbH
    Inventors: Gunter Bauer, Joachim Eckert
  • Patent number: 4488978
    Abstract: A process for the manufacture of calcium acetate pellets suitable for surface deicing, which comprises slow addition of water to dried calcium acetate or to calcium acetate freshly prepared from reaction of hydrated or unslaked lime with concentrated acetic acid, in an agitated vessel designed to produce pellets. Pellets are dried to a critical residual water level to avoid their embrittlement. The relative amount of water used in the pelletizing process is highly critical, and depends upon the source of calcium acetate as well as the amount of magnesium ion in the pellet formulation.
    Type: Grant
    Filed: February 10, 1983
    Date of Patent: December 18, 1984
    Inventor: Alan B. Gancy
  • Patent number: 4379127
    Abstract: A method of recovering molybdenum oxide by oxidation of a molybdenum sulfide concentrate contaminated with impurities wherein the concentrate in an average particle size in the range of 20 to 90 microns is suspended to form an aqueous suspension which is oxidized at elevated temperature and an elevated oxygen partial pressure in an autoclave. The suspension withdrawn from the autoclave is subjected to filtration to remove the molybdenum oxide from the primary filtrate containing sulfuric acid and this filtrate is neutralized with lime to form calcium sulfate which is then removed from the suspension to provide a second filtrate. According to the invention, only this second filtrate is recirculated at a rate such that the suspension density in the oxidation stage is between 100 to 150 g of solids per liter and this suspension density is maintained in the oxidation stage by the recirculation.
    Type: Grant
    Filed: October 5, 1981
    Date of Patent: April 5, 1983
    Assignee: GfE Gesellschaft fur Elektrometallurgie mbH
    Inventors: Gunter Bauer, Joachim Eckert
  • Patent number: 4152397
    Abstract: Magnesium-bearing phosphate rock in small grain size is converted into phosphoric acid so that no by-products, which are difficult to dispose of are produced. The crushed rock is mixed with water and subsequently acidified with nitric acid, the reaction product being filtered and washed before the neutralization point is reached. The wet and filtered rock is treated with nitric acid to form phosphoric acid and a slurry of calcium nitrate tetrahydrate. The previously formed filtrate is mixed with the calcium nitrate tetrahydrate slurry and this mixture is reacted with ammonia and carbonic acid to form ammonium nitrate, magnesium carbonate and calcium carbonate, which are then separated into an ammonium nitrate solution and a mixture of magnesium and calcium carbonates.
    Type: Grant
    Filed: June 2, 1978
    Date of Patent: May 1, 1979
    Assignee: UHDE GmbH
    Inventors: Friedrich Wolstein, Wilhelm Wengeler, Ferdinand Holtmeier
  • Patent number: 4137293
    Abstract: Gypsum and magnetite which are both coarse and of good quality can simultaneously be produced by introducing calcium carbonate into an aqueous solution containing ferrous sulfate while an oxidizing gas is blown, and then carrying out a neutralizing and oxidizing operation at a pH of 5-6 and a temperature of 60-80.degree. C, and can be separately recovered by magnetic separation.
    Type: Grant
    Filed: December 16, 1977
    Date of Patent: January 30, 1979
    Assignee: Ishihara Sangyo Kaisha, Ltd.
    Inventors: Koichi Nagata, Kokichi Miyazawa, Takeshi Sato, Masashi Tsuchimoto, Junichi Kawashima
  • Patent number: 4132759
    Abstract: In the process for the production of chlorine and alkali metal hydroxide by electrolysis according to the amalgam process using calcium- and/or sulphate containing crude salt, the calcium and/or sulphate contents introduced into the brine circuit by the crude salt are removed from the brine by precipitation of the double salt Na.sub.2 SO.sub.4 . CaSO.sub.4. Small particles of glauberite may be introduced to the brine to initiate and accellerate precipitation.
    Type: Grant
    Filed: February 28, 1978
    Date of Patent: January 2, 1979
    Assignee: Bayer Aktiengesellschaft
    Inventor: Rolf Schafer
  • Patent number: 4049866
    Abstract: A filler for a mica-free joint compound, comprising by-product gypsum having a mean particle size between about 11 and about 12 microns, a percentage by weight of particles smaller than 1 micron of between about 5 and about 6.5, and a packed dry bulk volume no greater than about 93 cc. per 100 grams.
    Type: Grant
    Filed: March 4, 1976
    Date of Patent: September 20, 1977
    Assignee: United States Gypsum Company
    Inventors: Marvin K. Lane, Winton C. Anderson
  • Patent number: 4038365
    Abstract: Brine from a conventional treatment process is pre-filtered prior to the electrolysis of same by a method which includes the steps of: (a) heating the brine, (b) adding sodium carbonate thereto, (c) stirring the solution, (d) allowing the solution to settle, and (e) passing the solution through an absolute membrane filter. The filter "polishes" the brine feed by removing the high hardness ions.
    Type: Grant
    Filed: December 3, 1975
    Date of Patent: July 26, 1977
    Assignee: BASF Wyandotte Corporation
    Inventors: Arvind S. Patil, Shyam D. Argade, Stephen M. Collins
  • Patent number: 4006215
    Abstract: Sulfate solutions containing at least one valuable metal from the group: Fe, Ni and Co, particularly solutions resulting from the leaching of lateritic ores or concentrates, are treated to recover the valuable metal. The latter is precipitated by treating the solution with magnesium hydroxide. The resulting magnesium-containing solution is treated with lime under controlled conditions to precipitate relatively fine particles of magnesium hydroxide and relatively coarse particles of gypsum. The difference in particle size is relied on to separate the magnesium hydroxide (for recycling) from the gypsum (which is calcined to regenerate lime).
    Type: Grant
    Filed: September 26, 1975
    Date of Patent: February 1, 1977
    Assignee: The International Nickel Company, Inc.
    Inventors: Rotrou Alan Hall, William Edward Jones, Kohur Nagaraja Subramanian
  • Patent number: 3980753
    Abstract: Magnesia of very high purity is produced industrially from a magnesite waste material wherein impurities are present in such amounts that the weight ratio of the precipitable hydroxide ions, calculated as the sum of Fe.sub.2 O.sub.3 + Al.sub.2 O.sub.3 + Cr.sub.2 O.sub.3 + Mn.sub.3 O.sub.4 to the sum of SiO.sub.2 + TiO.sub.2 + B.sub.2 O.sub.3, is at least 1 : 3. The starting material is dissolved in hydrochloric acid of 15-32% concentration, the impurities are precipitated by adjusting the pH of the acidic solution to 4 - 9, and the purified magnesium chloride solution is thermally decomposed into magnesia and hydrochloric acid gas, the latter being recycled to form the hydrochloric acid of the stated concentration for dissolving the starting material.
    Type: Grant
    Filed: November 29, 1974
    Date of Patent: September 14, 1976
    Assignee: Veitscher Magnesitwerke-Aktiengesellschaft
    Inventors: Michael Grill, Georg Bouvier
  • Patent number: 3975283
    Abstract: A gelling agent is added to a brine containing magnesium chloride to convert the brine into a gel which is spray dried to produce dried magnesium chloride comprising substantially solid discrete particles of magnesium chloride having bulk densities in the range from about 12 to 45 pounds per cubic foot.
    Type: Grant
    Filed: March 21, 1975
    Date of Patent: August 17, 1976
    Assignee: NL Industries, Inc.
    Inventors: David G. Braithwaite, William P. Hettinger, Jr.
  • Patent number: 3953573
    Abstract: Minute amounts of boron present in naturally occurring brines found in oceans, inland seas, salt lakes and the like are removed by treating the brine with a solid, finely divided lignite.
    Type: Grant
    Filed: February 21, 1975
    Date of Patent: April 27, 1976
    Assignee: N L Industries, Inc.
    Inventors: Edward O. Kazimir, Donald J. Weintritt
  • Patent number: 3932578
    Abstract: A molded material comprising CaCO.sub.3 and/or MgCO.sub.3 is made and used as a reaction bed through which carbonated water is run to make mineral water.
    Type: Grant
    Filed: July 13, 1973
    Date of Patent: January 13, 1976
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Atsushi Nishino, Hiroshi Kumano, Kazunori Sonetaka