Solid Component Patents (Class 423/215.5)
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Patent number: 12048956Abstract: A method of recovering fly ash, including a firing step in which raw fly ash powder containing unburned carbon is fired to remove the unburned carbon by burning; measuring the content of unburned carbon in the raw fly ash powder; and obtaining a fine fly ash powder which is a component under a sieve and has a decreased content of unburned carbon as a result of sieve-classifying the raw fly ash powder. The perforation size of the sieve used in the sieve-classifying step is set depending upon the content of unburned carbon in the raw fly ash powder. The sieve has a small perforation size when the content of unburned carbon is large, and the sieve has a large perforation size when the content of unburned carbon is small. The fine fly ash powder, which is the component under the sieve, is recovered through the firing step.Type: GrantFiled: June 4, 2019Date of Patent: July 30, 2024Assignee: TOKUYAMA CORPORATIONInventors: Kohei Omura, Takuya Seki
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Patent number: 11369921Abstract: A contaminated gas stream can be passed through an in-line mixing device, positioned in a duct containing the contaminated gas stream, to form a turbulent contaminated gas stream. One or more of the following is true: (a) a width of the in-line mixing device is no more than about 75% of a width of the duct at the position of the in-line mixing device; (b) a height of the in-line mixing device is no more than about 75% of a height of the duct at the position of the in-line mixing device; and (c) a cross-sectional area of the mixing device normal to a direction of gas flow is no more than about 75% of a cross-sectional area of the duct at the position of the in-line mixing device. An additive can be introduced into the contaminated gas stream to cause the removal of the contaminant by a particulate control device.Type: GrantFiled: May 28, 2019Date of Patent: June 28, 2022Assignee: ADA-ES, Inc.Inventor: Ronald Hanson
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Patent number: 10898851Abstract: Several embodiments of the present technology are directed to the removal of one or more air pollutants using cooling and/or calcium-containing particles. In some embodiments, a method for removing air pollutants comprises flowing a gas stream having calcium-containing particles and one or more of mercury or hydrochloric acid molecules, and cooling the gas stream, thereby causing at least a portion of the calcium-containing particles to adsorb to the mercury and/or hydrochloric acid molecules in the gas stream. The method can further comprise, after cooling the gas stream, filtering the gas stream to remove at least a portion of the calcium-containing particles having adsorbed mercury and hydrochloric acid.Type: GrantFiled: July 6, 2018Date of Patent: January 26, 2021Assignee: Graymont (PA) Inc.Inventors: Harold Wayne Lee, II, Laura L. Kinner, Douglas C. Murdock, Fred Douglas Blackham, John B. Heintzelman
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Patent number: 10705053Abstract: The present disclosure provides an aerosol sensing method. The aerosol sensing method includes steps of providing an entering process, providing a particle collecting process and providing a measuring process. The entering process is to allow an aerosol to enter a chamber of a thermal-piezoresistive oscillator-based aerosol sensor, and a thermal-piezoresistive resonator is disposed in the chamber. The particle collecting process is to allow particulate matters in the aerosol to land on at least one proof-mass of the thermal-piezoresistive resonator when the thermal-piezoresistive resonator is not driven. The measuring process is to use an electrical signal to drive the thermal-piezoresistive resonator and measure a resonant frequency of the thermal-piezoresistive resonator. The particle collecting process and the measuring process are operated in a repetitive cycle for measuring changes of the resonant frequency of the thermal-piezoresistive resonator to measure the particulate matters of the aerosol.Type: GrantFiled: May 3, 2018Date of Patent: July 7, 2020Assignee: NATIONAL TSING HUA UNIVERSITYInventors: Sheng-Shian Li, Ting-Yuan Liu
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Patent number: 10596563Abstract: Methods of preparing a sinter-resistant catalyst include forming a dual coating system. A surface of a particulate catalyst support contacts a first liquid precursor including a metal salt with an element selected from the group consisting of: aluminum (Al), cerium (Ce), zirconium (Zr), titanium (Ti), silicon (Si), magnesium (Mg), zinc (Zn), and combinations thereof. The first liquid precursor precipitates or is adsorbed as an ion on a portion of the surface forming a first coating including a porous metal oxide on the surface. The surface may be contacted with a second liquid precursor including a metal oxide sol including a metal selected from the group consisting of: aluminum (Al), cerium (Ce), zirconium (Zr), iron (Fe), titanium (Ti), silicon (Si), and combinations thereof. A second coating is formed from the second liquid precursor on a portion of the surface to create the sinter-resistant catalyst system.Type: GrantFiled: January 27, 2017Date of Patent: March 24, 2020Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventors: Gongshin Qi, Ming Yang, Ryan J. Day, Xingcheng Xiao, Wei Li
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Patent number: 10557390Abstract: A honeycomb filter, including: a honeycomb structure, wherein the honeycomb structure further includes a platinum group element-containing catalyst layer and a trapping layer, the platinum group element-containing catalyst layer is disposed at least on an entire surface of a side of an inner surface of the partition walls surrounding either one of the inflow cells or the outflow cells, the trapping layer does not contain a platinum group element, and the trapping layer is disposed in a range of at least up to 50% with respect to an overall length of the honeycomb structure starting from the outflow end face and is not disposed in a range of at least up to 40% with respect to the overall length starting from the inflow end face, in an extending direction of the cells of the honeycomb structure.Type: GrantFiled: March 18, 2019Date of Patent: February 11, 2020Assignees: NGK Insulators, Ltd., Honda Motor Co., Ltd.Inventors: Fumihiko Yoshioka, Norihiro Wakida, Yoshiaki Hatakeyama, Noritaka Masumitsu
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Patent number: 10233803Abstract: Provided is an exhaust gas purification filter including a substrate comprising a plurality of porous partitions, wherein the partitions form an exhaust gas flow path, a porous catalytic layer is provided on the partitions and the catalytic layer having a thickness of 10 ?m or greater is provided over at least 20% of the total length of the partitions in the lengthwise direction thereof, and the catalytic layer having a thickness of 10 ?m or greater is not present on the partitions 15 mm from an outflow side.Type: GrantFiled: March 29, 2017Date of Patent: March 19, 2019Assignee: Johnson Matthey Public Limited CompanyInventors: Satoshi Sumiya, Daisuke Yokota
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Patent number: 10035126Abstract: A sorbent composition such as for the removal of a contaminant species from a fluid stream, a method for manufacturing a sorbent composition and a method for the treatment of a flue gas stream to remove heavy metals such as mercury (Hg) therefrom. The sorbent composition includes a porous carbonaceous sorbent such as powdered activated carbon (PAC) and a solid particulate additive that functions as a flow-aid to enhance the pneumatic conveyance properties of the sorbent composition. The solid particulate additive may be a flake-like material, for example a phyllosilicate minerals or graphites.Type: GrantFiled: November 4, 2015Date of Patent: July 31, 2018Assignee: ADA Carbon Solutions, LLCInventors: Sarah G. McMurray, Jacqueline Cecil de Peyer, Robert B. Huston, Joseph M. Wong
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Patent number: 10005030Abstract: The flue gas treatment system (1) comprises a reactor (2), a pre-separator (3) downstream of the reactor (2), a separator (4) such as a fabric filter downstream of the pre-separator (3), a humidifier (5) downstream of the separator (4), a supply (7) of a pure fresh reagent into the flue gas (FG) downstream of the pre-separator (3) and upstream of or at the separator (4).Type: GrantFiled: February 3, 2016Date of Patent: June 26, 2018Assignee: GENERAL ELECTRIC TECHNOLOGY GMBHInventor: Robert Råhlin
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Patent number: 9844767Abstract: Disclosed is a catalyst filter, which includes a catalyst support and a nano metallic catalyst sprayed to a surface of the catalyst support. The catalyst filter uses catalyst slurry prepared by using a particulate catalyst, in which a small amount of nano metallic catalyst exhibiting a catalyst performance is sprayed to a surface of the catalyst support, different from an existing patent technique in which catalyst particles are formed and prepared as a support to consume a large amount of catalyst. Therefore, the specific surface area of the catalyst filter is not smaller than the specific surface area of the nano catalyst particles, and thus the catalyst filter may effectively remove and decompose ultra-low concentration gas-state contaminants in an indoor air.Type: GrantFiled: August 3, 2016Date of Patent: December 19, 2017Assignee: Korea Institute of Science and TechnologyInventors: Jongsoo Jurng, Min Su Kim, Eun Seuk Park, Hyoun Duk Jung, Jin Young Kim
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Patent number: 9821272Abstract: A device and a method for reducing carbon monoxide, hydrocarbons, nitrogen oxides and soot particles present in the exhaust gases of diesel engines are provided. The device includes 1) a diesel oxidation catalyst for the oxidation of carbon monoxide, hydrocarbons and nitrogen monoxide; 2) a first unit by means of which ammonia and/or a compound that breaks down to form ammonia can be metered into the exhaust gas that is to be purified; 3) a catalytically activated particulate filter, containing a wall-flow filter substrate comprising a catalytically active material that promotes the selective catalytic reduction of nitrogen oxides to form nitrogen; 4) a second unit by means of which ammonia and/or a compound that breaks down to form ammonia can be metered into the exhaust gas that is to be purified; as well as 5) a catalyst for the selective catalytic reduction of nitrogen oxides to form nitrogen.Type: GrantFiled: November 16, 2012Date of Patent: November 21, 2017Assignee: Deutz AktiengesellschaftInventors: Stephan Schraml, Meike Wittrock, Markus Mueller
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Patent number: 9815707Abstract: The present invention provides a method of processing discharge gas containing ammonia, hydrogen, nitrogen, and an organic metal compound discharged from the production process of a gallium nitride compound semiconductor. The discharge gas is brought into contact with a cleaning agent prepared by impregnating an alkali metal compound with a metal oxide to remove the organic metal compound from the discharge gas. The discharge gas from which an organic metal compound is removed is brought into contact with an ammonia decomposition catalyst on heating to decompose the ammonia into nitrogen and hydrogen. The discharge gas in which ammonia is decomposed is brought into contact with palladium alloy membrane on heating to recover hydrogen that has penetrated through the palladium alloy membrane.Type: GrantFiled: December 17, 2015Date of Patent: November 14, 2017Assignee: JAPAN PIONICS CO., LTD.Inventors: Kansei Izaki, Masanori Iwaki, Yasusada Miyano, Toshio Akiyama
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Patent number: 9764280Abstract: A method for the reduction and prevention of mercury emissions into the environment from combusted fossil fuels or other off-gases with the use of hypobromite is disclosed. The hypobromite is used for the capture of mercury from the resulting flue gases using a flue gas desulfurization system or scrubber. The method uses hypobromite in conjunction with a scrubber to capture mercury and lower its emission and/or re-emission with stack gases. The method allows the use of coal as a cleaner and environmentally friendlier fuel source as well as capturing mercury from other processing systems.Type: GrantFiled: August 19, 2016Date of Patent: September 19, 2017Assignee: ECOLAB USA INC.Inventors: Nicholas R. Denny, Bruce A. Keiser, David M. Dotzauer, Wayne M. Carlson
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Patent number: 9586169Abstract: A method for manufacturing granules of, e.g., urea or ammonium nitrate, wherein the ejection of submicron dust to the atmosphere is reduced is described. The method contains an arrangement of three scrubbers wherein the gas withdrawn from the granulator is provided to a first scrubber, resulting in the formation of a first purified gas stream, which is provided to a third scrubber, with the operating temperature of the third scrubber being below than of the first scrubber. In preferred embodiments, the process comprises various recycle streams.Type: GrantFiled: February 5, 2014Date of Patent: March 7, 2017Assignee: Green Granulation Technology LimitedInventors: Wei Wang, Mengguang Wang
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Patent number: 9587539Abstract: An exhaust gas after-treatment system for an internal combustion engine, with a particle filter arranged downstream of an internal combustion engine for filtering soot out of the exhaust gas, and with an oxidation catalytic converter arranged upstream of the particle filter and downstream of the internal combustion engine for the oxidation of SO2 into SO3. The SO3 and/or precipitated H2SO4 serves for the oxidation of soot in the particle filter and thus for the regeneration of the particle filter.Type: GrantFiled: April 3, 2015Date of Patent: March 7, 2017Assignee: MAN Diesel & Turbo SEInventor: Andreas Döring
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Patent number: 9486783Abstract: A diesel oxidation catalyst (DOC) system for the treatment of exhaust gas emissions, including oxidation of nitrogen oxides (NO), unburned hydrocarbons (HC), and carbon monoxide (CO) is disclosed. Fresh and hydrothermally aged Zero-PGM (ZPGM) DOC samples are prepared and configured with an alumina-based washcoat on ceramic substrate, overcoat including doped Zirconia support oxide, and impregnation layer of Cu—Mn spinel of selected base metal loadings. Testing of fresh and hydrothermally aged ZPGM DOC system samples including Cu—Mn spinel is developed to evaluate the performance of Cu—Mn spinel active phase in oxidation CO, HC, and NO, as well as production of NO2. Key to improvement in light-off performance and NO oxidation is to have a diesel oxidation catalyst that is substantially PGM-free and available for a plurality of applications in lean burn engine operations.Type: GrantFiled: April 11, 2014Date of Patent: November 8, 2016Assignee: Clean Diesel Technologies, Inc. (CDTI)Inventors: Zahra Nazarpoor, Stephen J. Golden
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Patent number: 9463812Abstract: There is provided a method of filtration for a rail vehicle or other off-highway powered system. The method includes determining a filter load of a primary filtration system to an air intake of an engine. The method also includes determining that the filter load exceeds a specified threshold. Additionally, the method includes deactivating the primary filtration system. The method further includes activating a secondary filtration system to the engine.Type: GrantFiled: May 15, 2014Date of Patent: October 11, 2016Assignee: General Electric CompanyInventors: Suresh Rama Reddy Govindappa, Lamar K Ledbetter
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Ash compositions recovered from coal combustion gases having reduced emissions of HCI and/or mercury
Patent number: 9399597Abstract: The description relates to production of fly ash with properties suitable for use in Portland cement. The fly ash compositions will contain coal ash, water-insoluble copper compositions and metallic mercury adsorbed onto ash particles. In one aspect, the coal ash composition will have a total mercury content of from 0.1 to 2.0 ppm and the water-soluble mercury is less than 20% of the total mercury content. The process entails combusting coal to produce hot combustion gases containing fly ash, CO2, chlorine, and mercury, cooling the combustion gases and introducing into the combustion gases at a temperature of less than 1000° F., preferably within the range of from about 250° to about 900° F., a copper-based chloride remediator (CBCR), and collecting the fly ash which comprises insoluble copper compositions and water insoluble mercury compositions.Type: GrantFiled: August 26, 2014Date of Patent: July 26, 2016Assignee: FUEL TECH, INC.Inventors: Christopher R. Smyrniotis, Kent W. Schulz, Emelito P. Rivera, Ian Saratovsky, Vasudeo S. Gavaskar -
Patent number: 9381510Abstract: An exhaust gas purifying catalyst comprising a catalyst layer comprising two or more types of inorganic porous particles each having a different particle size, a catalytically active component, and voids, wherein; as a first characteristic, 50% or more by number of all the voids in the catalyst layer satisfies a condition of the following (formula 1); L/2/(?S)1/2?2 . . . (formula 1) wherein S represents a void cross-sectional area, and L represents a void cross-sectional circumference in the (formula 1), and; as a second characteristic, in the void cross-sectional area in the catalyst layer, the average void radius, determined assuming that the void shape is a perfect circle, is 10 ?m to 20 ?m.Type: GrantFiled: September 10, 2014Date of Patent: July 5, 2016Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Hironori Iwakura, Toshiharu Moriya, Yasunori Imada, Yunosuke Nakahara
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Patent number: 9302224Abstract: A system for NOx reduction in combustion gases, especially from diesel engines, incorporates an oxidation catalyst to convert at least a portion of NO to NO2, particulate filter, a source of reductant such as NH3 and an SCR catalyst and methods for operating such a system are disclosed. Considerable improvements in NOx conversion and soot reduction are observed even at relatively low operating temperatures.Type: GrantFiled: September 17, 2014Date of Patent: April 5, 2016Assignees: Daimler AG, HJS Emission Technology GmbH & Co. Ltd., Johnson Matthey Public Limited CompanyInventors: Anders Andreasson, Guy Richard Chandler, Claus Friedrich Goersmann, James Patrick Warren, Georg Hüthwohl
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Patent number: 9206507Abstract: Disclosed are homoleptic diazabutadiene nickel precursors used for the vapor deposition of nickel-containing films. The precursors have the general formula Ni(R-DAD)2, wherein R-DAD stands for substituted 1,4-diazabuta-1,3-diene ligands. The sole presence of the Ni—N bonds was also considered to avoid too high intrusion of other elements, such as carbon, into the nickel-containing films. The flexibility of the Ni—N bond in terms of film deposition also allows using the molecules for nickel, nickel-nitride, nickel-carbonitride, nickel oxide or any other type of nickel-containing films. The nickel-containing film depositions can be carried out by thermal and/or plasma-enhanced CVD, ALD, and pulse CVD or any other type of depositions methods.Type: GrantFiled: September 27, 2012Date of Patent: December 8, 2015Assignees: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude, American Air Liquide, Inc.Inventors: Clément Lansalot-Matras, Julien Gatineau, Benjamin J. Jurcik, Jr.
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Patent number: 9174161Abstract: A device for purifying smoke gases comprising a cylindrical container with a gas inlet at its bottom region and a gas exit for purified gas in its top region, as well as an inlet for washing liquid and an exit for spent washing liquid, wherein the container internally does not include any current baffles so that the gas and liquid can rotate freely, and wherein the container internally has a stirring device of perforated plates, e.g. netting discs, for optimal mixing of gas and fluid. It is also disclosed a process for purifying such smoke gases, wherein such a purification device is used.Type: GrantFiled: May 26, 2008Date of Patent: November 3, 2015Assignee: CO2 Purification ASInventor: Thomas Thomassen
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Patent number: 9114360Abstract: Provided is a process for controlling heavy metal (e.g., mercury) emission in SO2-containing flue gas, comprising passing a stream of the flue gas (2) through a wet scrubber (1) where it is brought into contact with a liquid absorbent (8) comprising an ionic liquid, an oxidizer (11) and polar protic organic solvent, wherein the amount of said organic solvent is adjusted such that the SO2 absorption is minimized while operating said wet scrubber at a temperature lower than the normal working temperature that would be used in the absence of said solvent. The process may be preceded by an initial stage where a fluoride-containing liquid is used for reducing the amount of sulfur dioxide in the flue gas stream; the sulfur dioxide can be subsequently desorbed from the fluoride-containing liquid upon the addition of a polar solvent.Type: GrantFiled: January 31, 2013Date of Patent: August 25, 2015Assignee: YISSUM RESEARCH DEVELOPMENT COMPANY OF THE HEBREW UNIVERSITY OF JERUSALEM LTD.Inventors: Yoel Sasson, Tatyana Sachs, Effi Dvash, Zach Barnea
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Patent number: 8986636Abstract: Embodiments of the invention provide an engine aftertreatment apparatus comprising first and second diesel particulate filters (DPFs), the first DPF being provided upstream of the second DPF, the second DPF being provided with a coating of a second DPF catalyst, the second DPF catalyst being arranged to promote reduction of NOx.Type: GrantFiled: October 1, 2012Date of Patent: March 24, 2015Assignee: Jaguar Land Rover LimitedInventor: Jonathan Hartland
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Patent number: 8974756Abstract: The disclosure provides an improved means of controlling mercury emissions from coal-fired boiler applications. Specifically, the disclosure comprises a static mixing device placed in the flue gas stream. The static mixing device can enhance dispersion of injected sorbents in the flue gas, resulting in improved mercury capture at a lower sorbent injection rate.Type: GrantFiled: July 25, 2013Date of Patent: March 10, 2015Assignee: ADA-ES, Inc.Inventor: Cameron E. Martin
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Patent number: 8961913Abstract: The present invention relates to a method and a system for cleaning a CO2 rich flue gas stream containing water vapor and NOX prior to CO2 sequestration. The method and system include heating the flue gas stream to a temperature suitable for selective catalytic reduction (SCR) of NOX in a flue gas heater, reducing at least some of the NOX in the heated flue gas stream to N2 by SCR, and removing at least some of the water vapor from the NOX depleted flue gas stream by adsorption in an adsorption drier.Type: GrantFiled: July 30, 2013Date of Patent: February 24, 2015Assignee: ALSTOM Technology LtdInventors: Olaf Stallmann, Gerhard Heinz, Klaus Schnieder
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Publication number: 20150050202Abstract: A method is provided in which a contaminated waste gas, comprising particulates, an acid gas, and mercury, is contacted with a mercury removal agent to remove or cause the removal of mercury from the waste gas and a flue gas conditioning agent to alter at least one of a resistivity and cohesivity of the particulates. At least one of the following statements is true: the flue gas conditioning agent is substantially free of SO3, an amount of mercury removed from the waste gas in the presence of the flue gas conditioning agent is at least the same as an amount of mercury removed from the waste gas in the absence of the flue gas conditioning agent; the flue gas conditioning agent comprises more than about 25 wt.Type: ApplicationFiled: August 15, 2014Publication date: February 19, 2015Inventors: Gregory M. Filippelli, Sharon Sjostrom
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Publication number: 20150041717Abstract: A process for treating steam-saturated crude gases from an entrained flow gasification of fuels before entry into heat exchangers sited upstream of a crude gas converting operation. To avoid solid deposits in an entrance region of the heat exchangers, the crude gas is converted from a saturated into a superheated state by supply of a hot gas to the crude gas. Hot gas contemplated is superheated high pressure steam or recycled superheated converted crude gas.Type: ApplicationFiled: August 11, 2014Publication date: February 12, 2015Inventors: Norbert FISCHER, Manfred JÄNIG, Doris KLOSTERMANN, Andreas MEIßNER, Manfred SCHINGNITZ, Guido SCHULD
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Patent number: 8926926Abstract: A thin layer of low mean-pore-size filter material that permanently accommodates the accumulation of exhaust particulates (as soot or a soot cake) is carried on a porous ceramic support. The supported filter material is closely coupled with the exhaust manifold of the engine, for the purpose of passive regeneration of stored particulates, and removes particulate matter from the exhaust which is directed through the filter layer and ceramic support. The oxygen content of the exhaust oxidizes the particulate matter on the filter material. In a preferred embodiment, a thin layer of the filter material is supported on inlet channel walls of a wall flow-through ceramic filter body to remove the particles from the exhaust. The filter body comprises an upstream exhaust gas flow inlet face with openings to a plurality of inlet channels and a downstream face with a like plurality of openings from outlet channels. The inlet channels are closed at the downstream face and the outlet channels are closed at the inlet face.Type: GrantFiled: November 25, 2009Date of Patent: January 6, 2015Assignee: GM Global Technology Operations LLCInventors: Calvin K. Koch, Paul M. Najt, Kushal Narayanaswamy, David L. Hilden
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Patent number: 8919110Abstract: A filter for filtering particulate matter (PM) from exhaust gas emitted from a positive ignition engine or a compression ignition engine, which filter comprising a porous substrate having inlet surfaces and outlet surfaces, wherein the inlet surfaces are separated from the outlet surfaces by a porous structure containing pores of a first mean pore size, wherein the porous substrate is coated with a washcoat comprising a plurality of solid particles wherein the porous structure of the washcoated porous substrate contains pores of a second mean pore size, and wherein the second mean pore size is less than the first mean pore size.Type: GrantFiled: August 19, 2013Date of Patent: December 30, 2014Assignee: Johnson Matthey Public Limited CompanyInventors: Louise Clare Arnold, Robert James Brisley, Christopher Gough Morgan
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Patent number: 8911611Abstract: A process for obtaining electrolytic manganese from the treated sludge of the exhaust gases of ferroalloy production furnaces for any other industrial waste having magnesium in general, with a significant manganese content, by means of a process consisting of the following phases: sulphation, lixiviation, purification, conditioning and electrolysis, and whereby a manganese sulphate liquor is obtained that is suitable for the already known electrolysis process, which allows obtaining electrolytic manganese.Type: GrantFiled: May 25, 2004Date of Patent: December 16, 2014Assignee: Ferroatlantica, S.L.Inventors: Juan Carlos Sanchez Recio, José Sancho Martinez
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Patent number: 8889090Abstract: There are provided methods capable of easily and efficiently recovering and recycling ammonia from exhaust gas containing a small amount of ammonia, the exhaust gas being exhausted from a production process of a gallium nitride compound semiconductor. The method of recovering ammonia includes filtering exhaust gas containing ammonia, hydrogen, nitrogen, and a solid compound with a filter to remove the solid compound from the exhaust gas; pressurizing and cooling the filtered exhaust gas with a heat pump to liquefy ammonia contained in the filtered exhaust gas; and separating liquefied ammonia from hydrogen and nitrogen to recover liquefied ammonia. The method of recycling ammonia includes evaporating recovered liquid ammonia; mixing the evaporated ammonia with another crude ammonia to obtain mixed gas; purifying the mixed gas; and supplying the purified gas to the production process of a gallium nitride compound semiconductor.Type: GrantFiled: May 24, 2013Date of Patent: November 18, 2014Assignee: Japan Pionics Co., Ltd.Inventors: Kansei Izaki, Masanori Iwaki, Toshio Akiyama
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Patent number: 8883103Abstract: A method for treating exhaust from an engine. The method includes activating an exhaust ionizer in receipt of the exhaust when temperature of a catalyst of a selective catalytic converter, which is in communication with the exhaust ionizer so as to receive exhaust from the exhaust ionizer, is equal to or above an effective temperature. The method further includes deactivating or maintaining the exhaust ionizer in a deactivated state when temperature of the catalyst is below the effective temperature.Type: GrantFiled: January 16, 2014Date of Patent: November 11, 2014Assignees: DENSO International America, Inc., Denso CorporationInventors: Edward Szczepanski, Nicholas Polcyn
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Patent number: 8871164Abstract: SOx removal equipment for reducing sulfur oxides from flue gas from a boiler, a cooler which is provided on the downstream side of the SOx removal equipment, for reducing the sulfur oxides from the flue gas and for decreasing a gas temperature, CO2 recovery equipment including: an absorber for bringing CO2 in the flue gas into contact with a CO2 absorption liquid so as to be reduced; and a regenerator for causing the CO2 absorption liquid to emit CO2 so as to recover CO2 and regenerate the CO2 absorption liquid, and a wet type electric dust collector for reducing a mist generation material which is a generation source of mist that is generated in the absorber of the CO2 recovery equipment before introducing the flue gas to the CO2 recovery equipment, are included.Type: GrantFiled: May 31, 2011Date of Patent: October 28, 2014Assignee: Mitsubushi Heavy Industries, Ltd.Inventors: Tatsuto Nagayasu, Takashi Kamijo, Masayuki Inui, Tsuyoshi Oishi, Hiromitsu Nagayasu, Hiroshi Tanaka, Takuya Hirata, Tatsuya Tsujiuchi, Susumu Okino, Naoyuki Kamiyama, Seiji Yoshihara
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Patent number: 8865097Abstract: A flue-gas purification system includes a flue-gas cycling system, a reactor, and an absorbent adding system having at least a catalytic absorbent, wherein the catalytic absorbent is being gasified for reacting with the flue-gas in the reactor in a homogenous gas-gas phase reacting manner. Therefore, the purification system has fast reaction rate between the pollutants of the flue-gas and the catalytic absorbent, which is preferably ammonia, to efficiently remove pollutants, so as to effectively purify the flue-gas.Type: GrantFiled: August 5, 2013Date of Patent: October 21, 2014Inventors: Baoquan Zhang, Xiaoqing Zhang
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Patent number: 8828339Abstract: A CO shift catalyst according to the present invention is one that reforms carbon monoxide (CO) in gas. The CO shift catalyst includes: active ingredients including one of molybdenum (Mo) and iron (Fe) as a main ingredient and one of nickel (Ni) and ruthenium (Ru) as an accessory ingredient; and one or at least two oxides of titanium (Ti), zirconium (Zr), and cerium (Ce) as a carrier supporting the active ingredients. The CO shift catalyst can be used for a CO shift reactor 20 that converts CO in gasified gas 12 produced in a gasifier 11 into CO2.Type: GrantFiled: February 24, 2011Date of Patent: September 9, 2014Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Toshinobu Yasutake, Masanao Yonemura, Tetsuya Imai
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Patent number: 8808652Abstract: A selective catalytic reduction system and method for reducing nitrogen oxide (NOx) emissions comprising a boiler producing flue gas emissions, a particulate control device receiving flue gas emissions from the boiler, a selective catalytic reduction unit (SCR) receiving flue gas emissions from the particulate control device and reducing nitrogen oxide (NOx) emissions, and a heat exchanger located downstream of the selective catalytic reduction unit (SCR) for removing heat from the flue gas for preheating at least one of boiler feed water and combustion air for the boiler.Type: GrantFiled: June 14, 2013Date of Patent: August 19, 2014Assignee: 2E Environmental, LLCInventor: Robert Ellery
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Patent number: 8795616Abstract: A system and method of using a double-effect-reactor to dispose incinerated flue gas and improve cement yields. The double-effect-reactor features an incinerated reaction chamber and a gas-solid suspension mixing chamber. The system includes the double-effect-reactor, a high temperature dust-arrester, a system for recovery of thermal energy and dust removal, a triple valve, and an independent chimney. Also disclosed is a method in which combines the double-effect-reactor with a cement production system.Type: GrantFiled: December 26, 2011Date of Patent: August 5, 2014Assignee: Satarem Technologies LimitedInventor: Ching Chiu Leung
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Patent number: 8770497Abstract: Device for distributing a fluid in a controlled manner, in particular for distributing a gas loaded with particles, the device comprising a pipe (1) provided with at least one inlet orifice (2) and with a series of outlet orifices (3) spread along the pipe (1) and cut in the side wall of this pipe, characterized in that at least one section (4) of the wall, located downstream of at least one outlet orifice and limited by a section (5) of the edge of this orifice, has a shape such that this section of the edge of this orifice is positioned inside the pipe so that, when the device is in service, the flow direction of the fluid exiting this orifice and travelling along said wall section is controlled by the shape of the latter section.Type: GrantFiled: October 30, 2009Date of Patent: July 8, 2014Assignee: Solvay (Societe Anonyme)Inventors: Thierry Cartage, Olivier Jacques F. J. G. Bodson, Marc Thijssen
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Patent number: 8765089Abstract: A process for reducing nitrogen oxides and halogenated organic compounds in an incineration plant having at least one combustion chamber. The process comprises separating out fly ash using a dust collector. Water is added to and hydrochloric acid separated out in a first acid-operated scrubber. Water and ammonia are added so as to separate out sulphur dioxide in a second neutral or slightly acid-operated scrubber so as to form ammonium sulphite, a portion of the ammonium sulphite thereby reacts with oxygen so as to form an aqueous ammonium sulphate/ammonium sulphite solution. The aqueous ammonium sulphate/ammonium sulphite solution is introduced into an oxygen-containing smoke gas downstream of a secondary gas introduction area so as to decompose the ammonium sulphate and ammonium sulphite so as to form ammonia and sulphur dioxide.Type: GrantFiled: March 8, 2007Date of Patent: July 1, 2014Assignee: Forschungszentrum Karlsruhe GmbHInventor: Hans Hunsinger
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Patent number: 8741243Abstract: Sorbent bodies comprising activated carbon, processes for making them, and methods of using them. The sorbent bodies can be used to remove toxic elements from a fluid, such as from a gas stream. For instance, the sorbent bodies may be used to remove elemental mercury or mercury in an oxidized state from a coal combustion flue gas.Type: GrantFiled: May 13, 2008Date of Patent: June 3, 2014Assignee: Corning IncorporatedInventors: Kishor Purushottam Gadkaree, Benedict Yorke Johnson, Pei Qiong Kuang, Anbo Liu, Youchun Shi
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Patent number: 8734741Abstract: A method for removing contaminants from a gas stream by feeding the gas stream into a scrubber that can use seawater as the scrubbing medium. The gas stream is first scrubbed with the seawater and then mixed with ozone to remove the contaminants. Nitrogen oxides that are present in the gas stream are converted to nitric acid/nitrates and these are recovered via condensate or coalesced mist for neutralization. The treated gas stream is then exhausted to the atmosphere.Type: GrantFiled: April 25, 2013Date of Patent: May 27, 2014Assignee: Linde AktiengesellschaftInventor: Naresh J. Suchak
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Patent number: 8734747Abstract: A method for treating exhaust gas is provided, which includes measuring SO3 concentration in the exhaust gas which contains at least SO2 and SO3 by using an SO3 gas analyzer; injecting fine particles into the exhaust gas after the step of measuring; cooling the exhaust gas after the step of injection, by recovering heat from the exhaust gas; collecting fly ash from the cooled exhaust gas; and removing at least SO2 from the exhaust gas after the step of collecting by absorbing the SO2 with an absorbing solution. In addition, an apparatus for treating exhaust gas is provided, which includes an SO3 gas analyzer; a fine particles injector; a heat exchanger; an electrostatic precipitator; an absorption tower; and a fine particle feed controller.Type: GrantFiled: September 20, 2012Date of Patent: May 27, 2014Assignee: Mitsubishi Heavy Industries, Ltd.Inventor: Satoru Sugita
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Patent number: 8722002Abstract: A method of recycling captured agglomerated soot captured by and collected from a diesel emission control after-treatment (DECAT) system, the method comprising collecting captured agglomerated diesel soot (CADS) as a feedstock, loading the CADS into a controlled thermochemical conversion (TCC) process reactor, employing time-phased heat and pressure in the controlled TCC process reactor until the CADS sufficiently decompose to reclaim solids, liquid fuels and gases, piping pyrolysis oils (tars) and vapors produced in the controlled TCC process reactor to chambers, cooling and condensing the pyrolysis oils and vapors into a liquid form, and recirculating a pyrolysis gas produced in the controlled TCC process reactor for use as a source of heat and power.Type: GrantFiled: September 5, 2012Date of Patent: May 13, 2014Assignee: Dearborn Financial, Inc.Inventor: Michael B. Rohlfs
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Patent number: 8715600Abstract: A circulating dry scrubber flue gas desulfurization system is disclosed. Hydrated lime is injected into the flue gas upstream of the CDS vessel. The flue gas then passes through a baghouse, where solids are captured. At least a portion of the solids are recycled. The recycle path runs from the baghouse to a splitter, where the solids are divided between the injection points. No distribution box is needed, which permits lowering the height and/or restructuring the location of many components of the system, reducing costs as well as improving or maintaining removal of combustion byproducts from the flue gas.Type: GrantFiled: May 16, 2013Date of Patent: May 6, 2014Assignee: Babcock & Wilcox Power Generation Group, Inc.Inventor: Jeb W Gayheart
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Patent number: 8679431Abstract: An air pollution control system comprises a SOx removal equipment for reducing sulfur oxides from flue gas from a boiler, a cooler for reducing the sulfur oxides that remain in the flue gas and for decreasing a gas temperature, CO2 recovery equipment including an absorber for bringing CO2 in the flue gas into contact with a CO2 absorption liquid so as to be reduced, a regenerator for causing the CO2 absorption liquid to emit CO2 so as to recover CO2 and regenerate the CO2 absorption liquid, a heat exchanger which for decreasing a temperature of the flue gas, and calcium carbonate spraying equipment for spraying calcium carbonate between the heat exchanger and an electric dust collector, wherein a mist generation material in the flue gas is converted from a gas state to a mist state to arrest and reduce the mist generation material in the mist state using calcium carbonate.Type: GrantFiled: May 31, 2011Date of Patent: March 25, 2014Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Tatsuto Nagayasu, Takashi Kamijo, Masayuki Inui, Tsuyoshi Oishi, Hiromitsu Nagayasu, Hiroshi Tanaka, Takuya Hirata, Tatsuya Tsujiuchi, Susumu Okino, Naoyuki Kamiyama, Seiji Yoshihara
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Patent number: 8668889Abstract: SOx removal equipment for reducing sulfur oxides from flue gas from a boiler, a cooler which is provided on the downstream side of the SOx removal equipment, for reducing the sulfur oxides from the flue gas and for decreasing a gas temperature, CO2 recovery equipment which includes an absorber for bringing CO2 in the flue gas into contact with a CO2 absorption liquid so as to be reduced and a regenerator for causing the CO2 absorption liquid to emit CO2 so as to recover CO2 and regenerate the CO2 absorption liquid, and dissolved salt spraying equipment for reducing a mist generation material which is a generation source of mist that is generated in the absorber of the CO2 recovery equipment before introducing the flue gas to the CO2 recovery equipment, are included.Type: GrantFiled: May 31, 2011Date of Patent: March 11, 2014Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Tatsuto Nagayasu, Takashi Kamijo, Masayuki Inui, Tsuyoshi Oishi, Hiromitsu Nagayasu, Hiroshi Tanaka, Takuya Hirata, Tatsuya Tsujiuchi, Susumu Okino, Naoyuki Kamiyama, Seiji Yoshihara
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Patent number: 8623304Abstract: In accordance with the present invention, there is provide and device and method to facilitate the treatment of chlorine bypass dust while preventing increases in chemical cost and concentrations of heavy metals in clinker, and ensuring stability in quality of cement, and to treat chlorine bypass exhaust gas while avoiding coating troubles in a cement kiln etc., and preventing heat losses in a preheater etc., without degradation of clinker production amount.Type: GrantFiled: August 4, 2011Date of Patent: January 7, 2014Assignee: Taiheiyo Cement CorporationInventors: Shinichiro Saito, Junichi Terasaki
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Patent number: 8580979Abstract: Humic Acid is extracted and then can be used to treat flue gas and fly ash from the combustion of coal or municipal waste. The resulting product may be used as a soil ameliorant.Type: GrantFiled: January 21, 2013Date of Patent: November 12, 2013Assignee: Organocat, LLCInventor: Alexander Shulgin
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Patent number: 8580214Abstract: Methods of treating mercury contaminated gas comprising: introducing a hydrogen halide selected from HBr and HI into a mercury contaminated gas stream containing a quantity of particulate matter at an introduction rate sufficient to create a concentration of at least 0.1 ppmvd; wherein greater than 50% of all particulate matter in the mercury contaminated gas stream is a native particulate matter; contacting a quantity of active bromine with the native particulate matter; creating a doped particulate matter; coating a filtration media with the doped particulate matter; and passing a portion of the mercury contaminated gas stream through the doped particulate matter on the filtration media and other related methods are disclosed herein.Type: GrantFiled: February 1, 2012Date of Patent: November 12, 2013Assignee: Shaw Environmental & Infrastructure, Inc.Inventors: Randall P. Moore, Kevin Jackson, Stephen Baloga, Bobby I. T. Chen, Berani A. C. Halley, John Edel