Utilizing Liquid As Reactant Patents (Class 423/238)
-
Patent number: 10443472Abstract: An extruded honeycomb catalyst for nitrogen oxide reduction according to the selective catalytic reduction (SCR) method in exhaust gases from motor vehicles includes an extruded active carrier in honeycomb form having a first SCR catalytically active component and with a plurality of channels through which the exhaust gas flows during operation, and a washcoat coating having a second SCR catalytically active component being applied to the extruded body, wherein the first SCR catalytically active component and the second SCR catalytically active component are each independently one of: (i) vanadium catalyst with vanadium as catalytically active component; (ii) mixed-oxide catalyst with one or more oxides, in particular those of transition metals or lanthanides as catalytically active component; and (iii) an Fe- or a Cu-zeolite catalyst.Type: GrantFiled: October 20, 2017Date of Patent: October 15, 2019Assignee: Johnson Matthey Public Limited CompanyInventors: Guy Richard Chandler, Neil Robert Collins, Ralf Dotzel, Joerg Muench, Paul Richard Phillips, Gudmund Smedler, Andrew Peter Walker
-
Patent number: 10005021Abstract: A system for recovering ammonia from a gas stream is provided. The system includes a regenerator and a carbon dioxide wash station.Type: GrantFiled: December 22, 2016Date of Patent: June 26, 2018Assignee: GENERAL ELECTRIC TECHNOLOGY GMBHInventors: Sanjay Kumar Dube, Stephen Alan Bedell
-
Patent number: 9665763Abstract: Some methods may involve determining whether an object is positioned on or near a portion of a fingerprint sensor system. If an object is positioned on or near the portion of the fingerprint sensor system, an acoustic impedance of at least a portion of the object may be determined. Based at least in part on the acoustic impedance, it may be determined whether the object is a finger.Type: GrantFiled: August 31, 2014Date of Patent: May 30, 2017Assignee: QUALCOMM IncorporatedInventors: Eliza Yingzi Du, Ming Yu Chen, Esra Vural, Kwokleung Chan, Suryaprakash Ganti, John Keith Schneider, David William Burns
-
Patent number: 8984863Abstract: Provided is an ammonia injection device (10) installed at an exhaust gas duct through which an exhaust gas generated in a gas turbine flows, and configured to inject ammonia into the exhaust gas at an upstream side of a denitration catalyst configured to perform denitration processing in a flowing direction of the exhaust gas, the device including a plurality of ammonia injection pipes (11) disposed in parallel each other in a surface which traverses the exhaust gas duct. A plurality of nozzle pipes (12) configured to eject the ammonia from the ammonia injection pipes in an arrangement direction of the plurality of ammonia injection pipes are installed at the ammonia injection pipe in a longitudinal direction of the ammonia injection pipes. Diffuser panels (13) extending toward a downstream side in a flowing direction of the exhaust gas at both sides in a longitudinal direction of the ammonia injection pipes with respect to the nozzle pipes are formed at the nozzle pipes.Type: GrantFiled: November 1, 2011Date of Patent: March 24, 2015Assignee: IHI CorporationInventors: Akinori Yukimura, Masafumi Kawai, Yoshiyuki Yamane
-
Patent number: 8980204Abstract: A process for the clean-up of a crude syngas stream having widely varying composition and particulate load. The process includes quenching the crude syngas stream with a liquid stream to cool the syngas stream and remove particulates, tars and heavier hydrocarbon compounds. The process further includes co-scrubbing the syngas stream to remove both HCl and NH3 from the syngas stream, removing particulate matter from the syngas stream, and removing sulfur from the syngas stream. A syngas treatment system is also disclosed.Type: GrantFiled: May 24, 2011Date of Patent: March 17, 2015Assignee: Air Products and Chemicals, Inc.Inventors: Gowri Krishnamurthy, Charles Roland Higdon, III, Christine Peck Kretz, Carmine Richard Gagliardi, Kevin M. Duffy, Kuo-Kuang Hsu
-
Patent number: 8961915Abstract: A method for removing ammonia from a gas stream divides the gas steam into a plurality of separate gas streams and sprays a dilute acid solution into the streams. The acid solution is aqueous sulfuric acid and ammonium sulfate is produced. A device is used to divide the gas stream, the device having a plurality of conduits in fluid communication with a plenum. Spray nozzles are located in each conduit to spray the acid solution into the gas streams. The device creates less than 10 Pa back pressure to the gas stream.Type: GrantFiled: September 25, 2013Date of Patent: February 24, 2015Assignee: Ohio State Innovation FoundationInventors: Lingying Zhao, Lara Jane S. Hadlocon, Roderick Manuzon
-
Patent number: 8920759Abstract: One embodiment includes an oxidation catalyst assembly formed by applying a washcoat of platinum and a NOx storage material to a portion of a substrate material.Type: GrantFiled: March 2, 2009Date of Patent: December 30, 2014Assignee: GM Global Technology Operations LLCInventors: Jong H. Lee, David B. Brown, Michael J. Paratore, Jr., Yongsheng He
-
Patent number: 8821822Abstract: Disclosed herein is a process and a plant for recovering ammonia from a mixture including ammonia, acid gas containing H2S and/or CO2 and low-boiling water-soluble organic components. To avoid an enrichment of volatile organic compounds in the acid gas absorber, a partial stream of the liquid phase is withdrawn from an acid gas absorber and processed such that gaseous ammonia with a reduced content of volatile organic components is obtained, which is recirculated into the acid gas absorber.Type: GrantFiled: November 13, 2009Date of Patent: September 2, 2014Assignee: Lurgi GmbHInventors: Gert Ungar, Matthias Linicus
-
Publication number: 20140205524Abstract: A process for extracting a target gas component from a gas mixture in an apparatus having a pair of capture and release sections is provided. The pair of capture and release sections includes a sorbent capture section and a sorbent release section, each of the sorbent capture section and sorbent release section having a high surface area medium and a sorbent contained therein. A gas mixture is directed through a flow path, the flow path directing the gas mixture through the sorbent release section followed by the sorbent capture section, wherein the sorbent within the pair of capture and release sections extracts the target gas component and reduces the target gas component in the gas mixture.Type: ApplicationFiled: January 24, 2013Publication date: July 24, 2014Inventor: David Sevier
-
Patent number: 8758485Abstract: A process for the recovery of ammonia contained in a gaseous stream is described, said process comprising the following phases: (a) subjecting the gaseous stream containing ammonia to a washing (S) with an aqueous washing solution (5a) having a pH lower than 7.0, with the formation of a purified gaseous stream (6) and an aqueous solution (7) containing an ammonium salt; (b) subjecting the aqueous solution containing the ammonium salt coming from phase (a) to a distillation process (MD) with a hydrophobic microporous membrane at a temperature ranging from 50 to 250° C. and a pressure ranging from 50 KPa to 4 MPa absolute with the formation of a regenerated washing solution (16) and a gaseous stream (18) comprising NH3 and H2O; (c) recycling said generated washing solution to phase (a). The equipment for carrying out the above process is also described.Type: GrantFiled: January 11, 2010Date of Patent: June 24, 2014Assignee: Saipem S.p.A.Inventors: Paolo Casara, Alessandro Gianazza, Ivano Miracca
-
Publication number: 20140086813Abstract: The invention relates to a process for the removal of NO and NO2 from an oxygen-containing gas stream, which comprises a scrubbing step in which the gas stream is brought into contact with an ammonia-containing scrubbing solution, NO is oxidized to form NO2 by means of the oxygen present at a pressure of at least 2 bar and temperatures of from 15° C. to 60° C. and at least part of the NO2 present in the gas stream is converted by means of the ammonia-containing scrubbing solution into ammonium nitrite and a downstream decomposition step in which the ammonium nitrite present in the scrubbing solution is thermally decomposed into elemental nitrogen and water, where the decomposition step is carried out at temperatures of from 121° C. to 190° C. and a pressure of from 2 to 40 bar. The invention likewise relates to a plant for operation of the process of the invention.Type: ApplicationFiled: April 12, 2012Publication date: March 27, 2014Applicant: LINDE AKTIENGESELLSCHAFTInventors: Nicole Schodel, Hans-Jorg Zander, Florian Winkler, Roland Ritter
-
Patent number: 8591848Abstract: Disclosed is a system which enables the efficient utilization of urea for selective catalytic reduction (SCR) of NOx by gasifying it and feeding it to a plurality of selective catalytic reduction units associated with a plurality of gas turbines. The invention enables feeding a gasified product of the urea with the ability to fully control separate SCR units without excessive reagent usage or loss of pollution control effectiveness. Controllers determine the amount of reagent required for each turbine to control NOx emissions and then mixes the gasified urea with the correct amount of carrier gas for efficient operation of each separate SCR unit despite the demand variation between the turbines. In this manner the gasification unit can be properly controlled to provide urea on demand without the need for storing large inventories of ammonia-containing gasses to correct for fluctuations in demand.Type: GrantFiled: November 6, 2008Date of Patent: November 26, 2013Assignee: Fuel Tech, Inc.Inventors: William H. Sun, Paul G. Carmignani, John M. Boyle
-
Patent number: 8470274Abstract: A method for feeding reducing agent or reducing agent precursor into exhaust systems of mobile internal combustion engines and an exhaust system are preferably used for internal combustion engines with high nitrogen oxide compound emissions. A feed time is established. An exhaust parameter and/or necessary quantity of reducing agent is determined and a feed state of the reducing agent is defined. The reducing agent is treated if the feed state does not correspond to a stored state. The reducing agent feed to the exhaust system takes place last. The steps are repeated multiple times. This permits reducing agent to be fed into an exhaust system in a state suitable for the exhaust temperature, so that complete conversion of reducing agent takes place and selectively catalytic reduction is also ensured. This reduces the quantity of electrical energy necessary for converting reducing agent. A motor vehicle having the system is also provided.Type: GrantFiled: September 27, 2011Date of Patent: June 25, 2013Assignee: EMITEC Gesellschaft fuer Emissionstechnologie mbHInventors: Wolfgang Maus, Rolf Brück
-
Patent number: 8466315Abstract: A urea granulation process and the apparatus suitable for operating that process integrates a method for reducing ammonia emissions from a urea granulation plant which is emitted by a urea production process by scrubbing the off-gas and recovering the scrubber bleed and integrating it into the granulation process so that ammonium salts are completely contained by the process.Type: GrantFiled: November 6, 2009Date of Patent: June 18, 2013Assignee: UHDE Fertilizer Technology B.V.Inventors: Paul Niehues, Harald Franzrahe, Matthias Potthoff, Roland Monstrey
-
Patent number: 8454916Abstract: A dosing control system for a vehicle includes a current storage module, an adaption triggering module, and an adaption ending module. The current storage module estimates an amount of ammonia stored by a selective catalytic reduction (SCR) catalyst. The adaptation triggering module triggers a reduction of the amount of ammonia stored by the SCR catalyst to zero when a first amount of nitrogen oxides (NOx) measured by a first NOx sensor located downstream of the SCR catalyst is greater than a predicted value of the first amount of NOx. The adaptation ending module selectively ends the reduction and enables injection of dosing agent based on a comparison of the first amount of NOx with a second amount of NOx upstream of the SCR catalyst.Type: GrantFiled: June 18, 2010Date of Patent: June 4, 2013Inventors: James M. Perrin, Rebecca J. Darr, Paul Jasinkiewicz, Jason Daniel Mullins, Kyle E. Crawford
-
Patent number: 8367025Abstract: The disclosure provides methods and systems for sequestering and/or reducing carbon dioxide present in an industrial effluent fluid stream containing carbon dioxide. A scrubbing material comprising a first component, a second component (distinct from the first component), and preferably water, is contacted with the effluent fluid stream. The first component comprises a source of calcium oxide and a source of alkali metal ions. The second component comprises a slag having one or more reactive silicate compounds. Methods of reducing carbon dioxide from exhaust generated by combustion sources, lime and/or cement kilns, iron and/or steel furnaces, and the like are provided. Carbon dioxide emission abatement systems are also disclosed. Methods of recycling industrial byproducts are further provided.Type: GrantFiled: January 23, 2012Date of Patent: February 5, 2013Assignee: C-Quest Technologies LLCInventor: Douglas C. Comrie
-
Patent number: 8303849Abstract: A method of HCN removal from syngas including treating a hot syngas stream for conversion to chemical products by removing various components from the hot syngas stream by: passing the hot syngas stream to a scrubber; adding aldehyde to a circulating scrubber water; capturing ammonia and HCN in the circulating scrubber water and condensing water from the hot syngas stream into the circulating scrubber water; withdrawing a scrubber waste water effluent from the scrubber comprising absorbed ammonia, ammonium, and absorbed HCN, and glycol nitriles, formed from the reaction of the aldehydes with HCN, from the scrubber; withdrawing a treated syngas stream effluent from the scrubber having a reduced concentration of ammonia and HCN; and, passing at least a portion of the scrubber waste water effluent stream to a biological treatment zone for the removal of ammonia, absorbed HCN, and glycol nitriles.Type: GrantFiled: November 9, 2010Date of Patent: November 6, 2012Assignee: Coskata, Inc.Inventor: Robert Hickey
-
Patent number: 8293201Abstract: A process for the recovery of ammonia contained in a gaseous purging stream produced in a synthesis process of urea.Type: GrantFiled: November 14, 2008Date of Patent: October 23, 2012Assignee: Saipem S.p.A.Inventors: Paolo Casara, Alessandro Gianazza, Ivano Miracca, Giuseppe Merelli, Gustavo Capannelli, Aldo Bottino
-
Publication number: 20120195816Abstract: The present disclosure relates to a gas cleaning A process for cleaning a gas stream containing carbon dioxide and sulfur dioxide, including removal of carbon dioxide from the gas stream in a carbon dioxide removal stage; the process comprising a) removing, in a sulfur removal stage, sulfur dioxide from the gas stream by bringing the gas stream into direct contact with a liquid comprising ammonia, to absorb into the liquid sulfur dioxide from the gas stream such that the gas stream is depleted in sulfur dioxide; b) cooling, in a gas cooling stage, the gas stream such that a cooled gas stream is formed; c) removing, in the carbon dioxide removal stage, carbon dioxide from the cooled gas stream depleted in sulfur dioxide by bringing the gas stream into contact with ammoniated liquid to absorb into the liquid carbon dioxide from the gas stream such that the gas stream is depleted in carbon dioxide and enriched in ammonia; d) removing, in an ammonia removal stage, ammonia from the gas stream depleted in carbon diType: ApplicationFiled: February 1, 2011Publication date: August 2, 2012Inventors: Sanjay Kumar Dube, David James Muraskin
-
Patent number: 8206470Abstract: In one embodiment, a fluid mixture composition is used at least in part as a fuel for engine-powered transportation vehicles, the mixture comprising an initial concentration of an ammonia-like reductant component and an initial concentration of an ammonia-like carrier component. The mixture may also include an optional third hydrocarbon component, e.g., gasoline or diesel fuel, with modified properties when compared to conventional gasolines or diesel fuels. The mixture is separated into a first and a second stream, with the majority of the first stream being used as a fuel for the engine and at least a first portion of the second stream being injected into the engine exhaust gases to reduce NOx emissions. A second portion of the second stream is aspirated into the engine and a lean air/fuel ratio may be used to improve fuel efficiency.Type: GrantFiled: July 31, 2006Date of Patent: June 26, 2012Inventor: William O. Jacobson
-
Publication number: 20120137744Abstract: An acid-impregnated activated carbon matrix is formed from a carbonaceous material by the addition of a mineral acid, and may be used to chemisorb ammonia from a gas stream. The ammonia reacts with the acid to form a fertilizer salt. The spent matrix may be used as a fertilizer, or the fertilizer salt may be elutriated from the matrix.Type: ApplicationFiled: February 3, 2012Publication date: June 7, 2012Applicant: CARBON SOLUTIONS INC.Inventors: Richard L. Johnson, R. Eugene Kuzub, Jin Kwon Tak
-
Publication number: 20120128560Abstract: A process for the clean-up of a crude syngas stream having widely varying composition and particulate load. The process includes quenching the crude syngas stream with a liquid stream to cool the syngas stream and remove particulates, tars and heavier hydrocarbon compounds. The process further includes co-scrubbing the syngas stream to remove both HCl and NH3 from the syngas stream, removing particulate matter from the syngas stream, and removing sulfur from the syngas stream. A syngas treatment system is also disclosed.Type: ApplicationFiled: May 24, 2011Publication date: May 24, 2012Applicant: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Gowri Krishnamurthy, Charles Roland Higdon, III, Christine Peck Kretz, Carmine Richard Gagliardi, Kevin M. Duffy, Kuo-Kuang Hsu
-
Patent number: 8155509Abstract: A device and method for providing a gaseous substance mixture which includes at least one reducing agent and/or at least one reducing agent precursor, includes a reservoir for an aqueous solution which includes at least one reducing agent precursor that can be flow connected to an evaporator chamber, and a device for dosing the aqueous solution in the evaporator chamber. A device can heat the evaporator chamber to a temperature higher than or equal to a critical temperature, in which the aqueous solution is at least partially evaporated. The device and method enable reducing agent to be provided for selective catalytic reduction of nitrogen oxides in the exhaust of an internal combustion engine. Preferably, an evaporator unit is configured as the evaporator chamber and a hydrolysis catalytic converter is disposed outside the exhaust system. As a result, the size of the hydrolysis catalytic converter is reduced, allowing compact construction.Type: GrantFiled: November 17, 2008Date of Patent: April 10, 2012Assignee: Emitec Gesellschaft fuer Emissionstechnologie mbHInventors: Rolf Brück, Marc Brugger, Thomas Härig, Peter Hirth, Ulf Klein
-
Patent number: 8105558Abstract: The disclosure provides methods and systems for sequestering and/or reducing carbon dioxide present in an industrial effluent fluid stream containing carbon dioxide. A scrubbing material comprising a first component, a second component (distinct from the first component), and preferably water, is contacted with the effluent fluid stream. The first component comprises a source of calcium oxide and a source of alkali metal ions. The second component comprises a slag having one or more reactive silicate compounds. Methods of reducing carbon dioxide from exhaust generated by combustion sources, lime and/or cement kilns, iron and/or steel furnaces, and the like are provided. Carbon dioxide emission abatement systems are also disclosed. Methods of recycling industrial byproducts are further provided.Type: GrantFiled: February 11, 2011Date of Patent: January 31, 2012Assignee: C-Quest Technologies, LLCInventor: Douglas C. Comrie
-
Publication number: 20120009108Abstract: Combined removal of both ammonia from an ammonia-containing waste gas and nitrogen oxides from a nitrogen oxide-containing waste gas in a combined ammonia/urea synthesis plant is accomplished by mixing the gases and employing one or both of selective non-catalytic reduction at a temperature of 850° C. to 1100° C. or selective catalytic reduction at a temperature of 150° C. to 550° C., in which the ammonia and the nitrogen oxides react with one another to give nitrogen and water, the ammonia-containing waste gas derived from a low-pressure and/or atmospheric absorber of the urea synthesis plant, and the nitrogen oxide-containing waste gas derived from a flue gas duct of a primary reformer of the ammonia synthesis plant, both the ammonia and the nitrogen oxides of the mixed waste gas flows being depleted simultaneously during the same process step.Type: ApplicationFiled: March 12, 2010Publication date: January 12, 2012Applicant: UHDE GMBHInventors: Ivo Mueller, Joachim Johanning
-
Patent number: 8092771Abstract: The present invention provides a process for producing a nitrogen-containing carbon material, comprising a first step of subjecting azulmic acid to a first heat treatment in an oxygen-containing gas atmosphere, thereby preparing a heat-treated product, and a second step of subjecting the heat-treated product to a second heat treatment in an inert gas atmosphere.Type: GrantFiled: March 27, 2008Date of Patent: January 10, 2012Assignee: Asahi Kasei Chemicals CorporationInventor: Hidenori Hinago
-
Publication number: 20110289846Abstract: A process is provided where a waste stream is directed to an evaporator that produces a vapor having volatile compounds. The vapor including the volatile compounds is directed through a vapor scrubber that contacts the volatile compounds with a scratching solution. The scrubbing solution reacts with the gaseous volatile compounds in the vapor such that the volatile compounds pass from a vapor state into the scrubbing solution and form volatile compounds in the liquid scrubbing solution. The scrubbing solution is collected and recycled.Type: ApplicationFiled: May 25, 2010Publication date: December 1, 2011Applicant: HPD, LLCInventors: William A. Shaw, Mitchell Adam Edwards, Jeffrey Dean Brosdal
-
Publication number: 20110280779Abstract: Process for scrubbing out ammonia nitrogen and/or ammonium nitrogen and/or urea nitrogen from exhaust gases enriched with these nitrogen compounds in plants for producing ammonia or urea, wherein the nitrogen compounds first form with a hypochlorite-containing solution in a scrubber an intermediate which under acidic or neutral reaction conditions is reacted to form elemental nitrogen and salt, and the reaction of the nitrogen compounds to form elemental nitrogen and salt proceeds in a pH range of 4 to 6.Type: ApplicationFiled: November 27, 2009Publication date: November 17, 2011Applicant: UHDE GMBHInventors: Helmut Gehrke, Dennis Lippmann
-
Patent number: 8029753Abstract: An ammonia contact scrubber system (10) for removing ammonia from a fuel stream for a fuel cell (16) includes a contact scrubber (12) having a scrubber fuel inlet (14) and a scrubber fuel exhaust (20) for directing flow of the fuel stream through support material (24) within the scrubber (12) and into the fuel cell (16). An acid circulating loop (26) has an acid holding tank (28) holding a liquid acid solution (30), an acid feed line (32) secured in fluid communication between the holding tank (28) and a scrubber acid inlet (36) of the contact scrubber (12), an acid return (38) for returning the acid solution from the scrubber (12) to the acid holding tank (28), and an acid circulation pump (42) for pumping the acid solution (30) through the acid circulating loop (26) and through the support material (24) within the scrubber (12).Type: GrantFiled: December 20, 2006Date of Patent: October 4, 2011Inventor: Richard D Breault
-
Publication number: 20110229394Abstract: A process for the granulation of urea with a scrubbing system includes several waste streams for removal of dust and ammonia from the off-gas of a urea granulation unit. A urea granulator, a granulator scrubber dust stage, a granulator scrubber acid stage, product coolers, a product cooler scrubber dust stage, an evaporation unit, and a condenser unit are included in the system. A first stream of fresh air is sent into the urea granulator, whereby dust- and ammonia-laden air is drawn off from the granulator and conveyed into a granulator scrubber dust stage, followed by a granulator scrubber acid stage and ammonia is scrubbed from that air by the generation of an ammonium salt. A second stream of fresh air is used for cooling the product drawn off from the urea granulator in product coolers. The cooling air is thus heated up and conveyed to a product cooler scrubber dust stage.Type: ApplicationFiled: November 6, 2009Publication date: September 22, 2011Applicant: UHDE FERTILIZER TECHOLOGY B.V.Inventors: Paul Niehues, Harald Franzrahe, Matthias Potthoff, Roland Monstrey
-
Publication number: 20110142740Abstract: The method and system relate to reducing the content of hazardous chemicals when handling malodorous gases emanating from a pulp mill and before burning said malodorous gases in final incineration equipment in oxygen excess environment in order to oxidize the sulphur compounds. The flow of malodorous gases is transported to final incineration (C2) by using liquid ring pumps. The hazardous chemical, preferably ammonia, is bound or dissolved in the liquid used in the liquid ring pump. A part of the liquid used in the liquid ring pump is bled off to final destruction different than the final incineration equipment in oxygen excess environment.Type: ApplicationFiled: August 11, 2008Publication date: June 16, 2011Applicant: METSO POWER ABInventors: Robert Lundahl, Sofia Blomstrom
-
Patent number: 7927513Abstract: A method for the high removal of ammonia, COS and HCN from syngas (along with some polishing of particulates) in a cost effective and environmentally benign and sustainable fashion, with the need for little to no chemical addition by using a combination of water based gas scrubbing, HCN scrubbing and biological processing steps.Type: GrantFiled: October 27, 2009Date of Patent: April 19, 2011Assignee: Coskata, Inc.Inventor: Robert Hickey
-
Patent number: 7910078Abstract: The present invention relates to a method for removing carbon dioxide (CO2) from a gas stream. Particularly, the present invention relates to a method for removing CO2 from a gas stream by a liquid absorbent having an amino alcohol derived from 4-amino-2-butanol. In comparison to conventional amines, the amino alcohols of the present invention have been found to provide a higher CO2 absorption capacity and a higher cyclic capacity for CO2 removal.Type: GrantFiled: August 23, 2007Date of Patent: March 22, 2011Assignee: University of ReginaInventors: Paitoon Tontiwachwuthikul, Andrew G. H. Wee, Raphael Idem, Kreangkrai Maneeintr, Gao-jun Fan, Amornvadee Veawab, Amr Henni, Adisorn Aroonwilas, Amit Chakma
-
Patent number: 7906086Abstract: The disclosure provides methods and systems for sequestering and/or reducing carbon dioxide present in an industrial effluent fluid stream containing carbon dioxide. A scrubbing material comprising a first component, a second component (distinct from the first component), and preferably water, is contacted with the effluent fluid stream. The first component comprises a source of calcium oxide and a source of alkali metal ions. The second component comprises a slag having one or more reactive silicate compounds. Methods of reducing carbon dioxide from exhaust generated by combustion sources, lime and/or cement kilns, iron and/or steel furnaces, and the like are provided. Carbon dioxide emission abatement systems are also disclosed. Methods of recycling industrial byproducts are further provided.Type: GrantFiled: March 8, 2007Date of Patent: March 15, 2011Inventor: Douglas C. Comrie
-
Patent number: 7875089Abstract: A hydrogen generation apparatus employs a thermocatalytic reactor (60) formed of a top plate (62), a bottom plate (66), and a reactor core (64) disposed between the top an bottom plates. The reactor core has a reaction surface (64a) and a combustion surface (64b), each surface having a raised periphery defining opposing ends (61a and 61b) and opposing sides (63a and 63b). The reaction surface (64a) and the top plate (62) together define a reaction chamber and the combustion surface (64b) and the bottom plate (66) together define a combustion chamber. The reaction core (64) has a first set of a plurality of spaced apart, substantially straight radiating fins (76a) extending from the reaction surface (64a) and a second set of a plurality of spaced part, substantially straight radiating fins (76b) extending from the combustion surface (64b).Type: GrantFiled: March 4, 2002Date of Patent: January 25, 2011Assignee: Intelligent Energy, Inc.Inventors: Michael Roy Powell, Charles J. Call
-
Patent number: 7867462Abstract: A method and system for controlling emissions with ammonia recovery and fly ash beneficiation in accordance with the present invention includes introducing ammonia to react with at least a portion of sulfur trioxides in an exhaust emission and result in at least one or more ammoniated compounds. At a least a portion of fly ash particles and the ammoniated compounds in the exhaust emission are precipitated and at least the precipitated fly ash particles are beneficiated. At least a portion of the beneficiated fly ash particles which are heated are mixed with the precipitated ammoniated compounds to recover at least a portion of the ammonia. The recovered ammonia is reused in introducing ammonia to react with at least a portion of sulfur trioxides.Type: GrantFiled: September 25, 2006Date of Patent: January 11, 2011Assignee: PMI Ash Technologies, LLCInventor: Joseph W. Cochran
-
Patent number: 7867300Abstract: The present disclosure provides teachings relating to ammonia-based hydrogen generation apparatus and associated methods of use. Exemplary methods and apparatus comprise a thermocatalytic hydrogen generation reactor which includes a reaction chamber containing a catalyst-coated substrate, and a combustion chamber containing a catalyst-coated substrate. Exemplary catalyst-coated substrates include, but are not limited to, metal foam, monolith, mesh, ceramic foam or ceramic monolith.Type: GrantFiled: April 18, 2005Date of Patent: January 11, 2011Assignee: Intelligent Energy, Inc.Inventors: Anand Chellappa, Michael Roy Powell
-
Patent number: 7846240Abstract: A method and system for reducing an amount of ammonia in a flue gas stream. The system 100 includes: a wash vessel 180 for receiving an ammonia-containing flue gas stream 170, the wash vessel 180 including a first absorption stage 181a and a second absorption stage 181b, each of the first absorption stage 181a and the second absorption stage 181b having a mass transfer device 184; and a liquid 187 introduced to the wash vessel 180, the liquid 187 for absorbing ammonia from the ammonia-containing flue gas stream 170 thereby forming an ammonia-rich liquid 192 and a reduced ammonia containing flue gas stream 190 exiting the wash vessel 180.Type: GrantFiled: September 9, 2009Date of Patent: December 7, 2010Assignee: ALSTOM Technology LtdInventors: Eli Gal, Indira Jayaweera
-
Publication number: 20100290965Abstract: Combustion flue gas containing NOX and SOX is treated to remove NOX in a multistep system in which NOX is reduced in the flue gas stream via selective catalytic reduction or selective non-catalytic reduction with ammonia or an ammonia-forming compound, followed treatment with hydrogen peroxide to remove residual ammonia and, optionally, treatment with an alkali reagent to reduce residual NOX in the flue gas stream. The NOX-depleted flue gas stream may also be subjected to a desulfurization treatment for removal of SOX.Type: ApplicationFiled: May 12, 2010Publication date: November 18, 2010Applicant: FMC CORPORATIONInventors: Henry A. Pfeffer, David E. Smith
-
Patent number: 7815879Abstract: Methods and apparatuses are described for contacting an oxidizing solution such as an aqueous hydrogen peroxide composition of hydrogen peroxide and at least one additive that catalyzes the decomposition of the hydrogen peroxide into hydroxyl radicals with an atmospheric effluent containing odorous and/or noxious components. These components are absorbed by the aqueous hydrogen peroxide composition to produce an atmospheric effluent having reduced amounts of the odorous and/or noxious components. Various methods are described for adding the hydrogen peroxide and the decomposition additive.Type: GrantFiled: June 4, 2009Date of Patent: October 19, 2010Assignee: Steen Research, LLCInventors: Stephen R. Temple, Michael J. Stoltz
-
Patent number: 7803337Abstract: A method for treating a fluid to be scrubbed, comprising filling a scrubber with a volume of biodiesel or biomass adequate to cover a sintered permeable membrane in the reaction chamber and a bit more to create a reaction zone in not only a plurality of pores in the membrane with fluid but in a reaction zone above the membrane, then introducing fluid to be scrubbed to the membrane, building up pressure in the reaction chamber, and passing a scrubbed fluid from the reaction zone to an exit port at a rate equal to the rate the fluid to be scrubbed is introduced.Type: GrantFiled: June 25, 2009Date of Patent: September 28, 2010Assignee: Vapor Point, LLCInventors: Jefferey St. Amant, Kenneth R. Matheson
-
Patent number: 7780934Abstract: A process is described that removes by chemical oxidation the excess ammonia (NH3) gas from flue gases that have been subjected to selective catalytic reduction (SCR) and selective non-catalytic reduction (SNCR) of oxides of nitrogen (NOx) by ammonia injection. Methods for the removal of residual ammonia from flue gases prior to fouling air pre-heaters or deposition on fly ash are discussed.Type: GrantFiled: September 6, 2005Date of Patent: August 24, 2010Assignee: Headwaters IncorporatedInventor: Rafic Y. Minkara
-
Patent number: 7740816Abstract: A method for treating gases to be scrubbed, comprising filling a scrubber with a volume of lean liquid adequate to cover a sintered permeable membrane in the reaction chamber and a bit more to create a reaction zone in not only a plurality of pores in the membrane with gases but in a reaction zone above the membrane, then introducing gases to be scrubbed to the membrane, building up pressure in the reaction chamber, and passing scrubbed gas from the reaction zone to an exit port at a rate equal to the rate of gases to be scrubbed are introduced.Type: GrantFiled: February 4, 2009Date of Patent: June 22, 2010Assignee: Vapor Point, LLCInventors: Jefferey St. Amant, Kenneth R. Matheson
-
Patent number: 7682425Abstract: The invention relates to a method for removing ammonia and dust from a waste gas that occurs during the production of fertilizers, preferably urea, in which method the waste gas is introduced into a first washer, and a cooling gas is introduced into the one washer and an aqueous solution is introduced into the other washer, whereby both the waste gas and the cooling gas pass through at least one mist collector before exiting from the washer, in each instance, is supposed to be developed further in such a manner that the waste gas pollution can be clearly reduced. This is accomplished in that the additional water is first introduced into a fine-washing area of the first washer, delimited by the mist collector on the top and by a liquid-impermeable partition bottom at the bottom, and sprayed onto the at least one mist collector, and the aqueous solution that forms in the fine-washing area is subsequently passed into the second washer.Type: GrantFiled: September 4, 2004Date of Patent: March 23, 2010Assignee: Uhde GmbHInventors: Paul Niehues, Harald Franzrahe
-
Method for purifying exhaust of waste gas using atomized fluid droplets combined with turbulent flow
Patent number: 7655200Abstract: A method for purifying exhaust of waste gas using atomized fluid droplets combined with turbulent flow, including the following steps: a). atomizing the absorption or reacting fluids to microsized droplets; b). enabling waste gas to pass through the aforementioned absorption or reacting fluids and creating a turbulent flow to thoroughly react the waste gas with the droplets; c). reacting of harmful substances in the waste gas with droplets of the absorption or reacting fluids; d). implementing demisting treatment of the waste gas flow; e). discharging the treated waste gas. The aforementioned steps of the present invention enable the purification of waste gas without the need for packing, and achieve high removal efficiency and low energy consumption.Type: GrantFiled: February 14, 2006Date of Patent: February 2, 2010Inventors: Wen-Hao Lin, Pi-Chung Hsiao -
Patent number: 7575732Abstract: Processes for selectively removing sulfur-containing compounds from a gas are described herein. The processes generally include contacting a first gas including carbon dioxide and hydrogen sulfide with a scrub solution including ammonium bisulfite and ammonium sulfite in a first contact zone to produce a first contact zone effluent liquid including ammonium thiosulfate and a first contact zone overhead gas in which the concentration of hydrogen sulfide is substantially reduced.Type: GrantFiled: May 5, 2008Date of Patent: August 18, 2009Assignee: Thiosolv, LLC.Inventors: Mark C. Anderson, Michael F. Ray, Ronald Shafer
-
Patent number: 7550123Abstract: Methods and apparatuses are described for contacting an oxidizing solution such as an aqueous hydrogen peroxide composition of hydrogen peroxide and at least one additive that catalyzes the decomposition of the hydrogen peroxide into hydroxyl radicals with an atmospheric effluent containing odorous and/or noxious components. These components are absorbed by the aqueous hydrogen peroxide composition to produce an atmospheric effluent having reduced amounts of the odorous and/or noxious components. Various methods are described for adding the hydrogen peroxide and the decomposition additive.Type: GrantFiled: May 26, 2006Date of Patent: June 23, 2009Assignee: Steen Research, LLCInventors: Stephen R. Temple, Michael J. Stoltz
-
Patent number: 7537744Abstract: An improved process for ammonia recovery is provided for the recovery of substantially pure ammonia for use in industrial processes. In this improved method, specific raw materials and/or specific materials of construction are used. Overall efficiency and operational cost savings are increased as a result of the process of the present invention.Type: GrantFiled: April 2, 2002Date of Patent: May 26, 2009Assignee: Rohm and Haas CompanyInventors: Abraham Benderly, Keith Frederick Briegel, Michael Stanley DeCourcy, Ronald Eugene Myers
-
Publication number: 20090104099Abstract: The present invention relates to an apparatus comprising a co-current absorbing unit, a countercurrent absorbing unit, at least one absorbing liquid reservoir, and at least one liquid transferring means. The invention also relates to a method of absorbing a reactive gas and a method of preparing a solution by contacting a reactive gas to a solvent and allowing the reactive gas to react with the solvent.Type: ApplicationFiled: October 10, 2008Publication date: April 23, 2009Inventors: Patrick H. Au-Yeung, Dennis W. Jewell, John G. Pendergast, JR.
-
Publication number: 20090081094Abstract: A method and an installation is provided for the purification of gas, in particular synthesis gas, from the gasification of sewage sludge. Scrubbing hydrogen sulfide and ammonia is performed successively from the gas in two gas scrubbers.Type: ApplicationFiled: August 19, 2008Publication date: March 26, 2009Inventors: Michael Gaiffi, Christian Burgbacher, Marcel Huber, Christian Roschitz, Markus Kleinhappl