Alcohol, Arylhydroxide, Or Polyol Patents (Class 423/242.4)
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Patent number: 11499104Abstract: A method is disclosed of purifying a recycled or renewable organic material, wherein the recycled or renewable organic material includes more than 1 ppm silicon as silicon compounds and/or more than 10 ppm phosphorous as phosphorous compounds. The method can include providing a feed of the lipid material; heat treating the organic material in presence of an adsorbent and the filtering organic material and hydrotreating the lipid material in a presence of a hydrotreating catalyst to obtain purified hydrotreated organic material having less than 20% organic material and/or less than 30% of the original phosphorous content of the organic material.Type: GrantFiled: July 19, 2019Date of Patent: November 15, 2022Assignee: NESTE OYJInventors: Blanka Toukoniitty, Ville Paasikallio, Jukka-Pekka Pasanen, Jouni Touronen, Meri Hovi, Antti Pasanen, Salla Likander, Sami Toppinen, Pekka Aalto, Kari Jansson, Marina Lindblad, Mats Käldström, Kaisa Lamminpää
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Patent number: 9611440Abstract: A process for producing dry synthetic natural gas (SNG, Synthetic Natural Gas) from solid or liquid, carbonaceous fuel, substantially consisting of the following process steps: a) gasification of a solid or liquid, carbonaceous fuel to a raw synthesis gas b) cooling of the gas, separation of solids and the gas condensate c) raw gas conversion d) washing of the gas with methanol for separating hydrogen sulfide, carbon dioxide and moisture, wherein the methanol is circulated via a regeneration plant, e) methanation, f) condensation of moisture by means of cooling and/or cold water, g) further drying of the gas by condensation at low temperature by adding methanol to avoid the formation of ice.Type: GrantFiled: October 25, 2013Date of Patent: April 4, 2017Assignee: L'AIR LIQUIDE, SOCIÉTÉ ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCÉDÉS GEORGES CLAUDEInventors: Manfred Meyer, Stefan Walter, Ute Herrlett
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Publication number: 20150001132Abstract: Disclosed herein are scavenging compounds and compositions useful in applications relating to the production, transportation, storage, and separation of crude oil and natural gas. Also disclosed herein are methods of using the compounds and compositions as scavengers, particularly in applications relating to the production, transportation, storage, and separation of crude oil and natural gas.Type: ApplicationFiled: June 25, 2014Publication date: January 1, 2015Inventors: Jennifer L. Sorrells, Nestor U. Soriano, JR.
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Publication number: 20140369916Abstract: Provided is a process for controlling heavy metal (e.g., mercury) emission in S02-containing flue gas, comprising passing a stream of the flue gas (2) through a wet scrubber (1) where it is brought into contact with a liquid absorbent (8) comprising an ionic liquid, an oxidizer (11) and polar protic organic solvent, wherein the amount of said organic solvent is adjusted such that the SO2 absorption is minimized while operating said wet scrubber at a temperature lower than the normal working temperature that would be used in the absence of said solvent. The process may be preceded by an initial stage where a fluoride-containing liquid is used for reducing the amount of sulfur dioxide in the flue gas stream; the sulfur dioxide can be subsequently desorbed from the fluoride-containing liquid upon the addition of a polar solvent.Type: ApplicationFiled: January 31, 2013Publication date: December 18, 2014Applicant: Yissum Research Development Company of the Hebrew University of JerusalemInventors: Yoel Sasson, Tatyana Sachs, Effi Dvash, Zach Barnea
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Patent number: 8858828Abstract: The present disclosure provides a scrubbing composition containing an aqueous solution of 2-(3-aminopropoxy)ethan-1-ol. The scrubbing composition is especially suited for use in removing acid gases, such as carbon dioxide and hydrogen sulfide, from gas streams.Type: GrantFiled: October 18, 2011Date of Patent: October 14, 2014Assignee: Huntsman Petrochemical LLCInventors: Howard P. Klein, Robert A. Grigsby, Jr., Jingjun Zhou, Patrick Holub, Attila Gaspar, Zsolt Gaspar
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Patent number: 8765086Abstract: A process for removal of H2S and CO2 from an acid gas stream comprising H2S and CO2, the process comprising the steps of: (a) reacting H2S in the acid gas stream with SO2 to form sulphur vapor and water vapor, thereby obtaining a first off-gas stream comprising CO2, water vapor, sulphur vapor, residual SO2 and residual H2S; (b) converting residual SO2 in the first off-gas stream to H2S in a first off-gas treating reactor, thereby obtaining a second off-gas stream depleted in SO2 and enriched in H2S and CO2 compared to the first off-gas stream; (c) contacting the second off-gas stream with an H2S absorbing liquid, thereby transferring H2S from the gas stream to the H2S absorbing liquid to obtain H2S absorbing liquid enriched in H2S and a third off-gas stream enriched in CO2; (d) removing CO2 from the third off-gas stream by contacting the third off-gas stream with CO2 absorbing liquid in a CO2 absorber, thereby transferring CO2 from the third off-gas stream to the CO2 absorbing liquid to obtain CO2 absorbing lType: GrantFiled: August 29, 2008Date of Patent: July 1, 2014Assignee: Shell Oil CompanyInventors: Theodorus Johannes Brok, Gerardus Petrus Van Der Zwet
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Patent number: 8685236Abstract: A method of removing contaminates from sour water is provided. The method includes producing raw sour water within a syngas production system, and removing the contaminates from the raw sour water using a chemical reaction within a treatment unit to produce treated sour water. The treatment unit is in flow communication with the syngas production system.Type: GrantFiled: August 20, 2009Date of Patent: April 1, 2014Assignee: General Electric CompanyInventor: Gary Daniel Miller
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Patent number: 8664141Abstract: Provided is a silver-supported alumina catalyst for reducing nitrogen oxides using ethanol, which has the drawbacks of the conventional silver-supported alumina catalysts improved, has high performance, is not likely to deteriorate over time, and has excellent initial performance and durability. A catalyst for purifying nitrogen oxides, which purifies nitrogen oxides in exhaust gas using an alcohol as a reducing agent, and contains alumina, aluminum sulfate and silver as main components.Type: GrantFiled: July 29, 2009Date of Patent: March 4, 2014Assignee: Babcock-Hitachi Kabushiki KaishaInventors: Masatoshi Fujisawa, Yasuyoshi Kato
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Patent number: 8641922Abstract: A sorbent for removal of acid gas from hydrocarbon gas includes a mixture of dewatered residue obtained from the distillation of ethanol, and an amine.Type: GrantFiled: October 7, 2011Date of Patent: February 4, 2014Assignee: Intevep, S.A.Inventors: Alfredo Viloria, Rafael Yoll, Yanine Gonzalez, Monica Roman, Jose Biomorgi
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Patent number: 8623308Abstract: The invention provides a process for removing mercaptans from a gas stream comprising natural gas or inert gas and mercaptans, the process comprising the steps of: (a) contacting a first gas stream comprising natural gas or inert gas and mercaptans with a hydrodesulphurization catalyst in the presence of hydrogen in a hydrodesulphurization unit to obtain a second gas stream comprising natural gas or inert gas, which is depleted of mercaptans and enriched in H2S; (b) removing H2S from the second gas stream comprising natural gas or inert gas in a H2S removal unit to obtain a purified gas stream comprising natural gas or inert gas, which is depleted of mercaptans.Type: GrantFiled: August 2, 2005Date of Patent: January 7, 2014Assignee: Shell Oil CompanyInventors: Anders Carlsson, Gijsbert Jan Van Heeringen
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Patent number: 8524184Abstract: A process for the removal of hydrogen sulfide from a gas stream in which the gas stream is first passed through a Claus unit operating at a sub-stoichiometric ratio (H2S:SO2) of greater than 2:1 to produce a tail gas stream comprising less than 2000 vppm SO2. This tail gas stream is then treated to increase the sulfur recovery to at least 99.5% by first directly cooling the tail gas stream by contact with water as a coolant, followed by contacting the gas stream with a circulating stream of a dilute, absorbent solution of a severely sterically hindered secondary aminoether alcohol to further cool the gas stream, and then removing the H2S from the stream using a stronger absorbent solution of a severely sterically hindered secondary aminoether alcohol.Type: GrantFiled: June 29, 2010Date of Patent: September 3, 2013Assignee: ExxonMobil Research and Engineering CompanyInventors: Jagannathan N. Iyengar, David Perry, Robert B. Fedich
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Patent number: 8500866Abstract: Upon cooling to 15 to 45° C., a process for the treatment of raw product gas generated by pressure gasification of solid fuels comprises the removal of HCN and NH3 in a preliminary stage, of H2S and COS and possibly other sulfur-containing compounds in a first stage and of CO2 in a second stage by physisorption with cold oxygenate, and the pure product gas is supplied to the direct reduction of iron ore as reduction gas and/or as fuel gas. An improvement of the process consists in that recycle gas loaded with CO2 and steam, which is branched off from the circuit of the recycle gas of the direct reduction of iron ore, is admixed to the desulfurized product gas upon removal of the steam contained therein.Type: GrantFiled: May 23, 2008Date of Patent: August 6, 2013Assignee: Lurgi Clean Coal Technology (Proprietary) LimitedInventor: Gerhard Schmitt
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Patent number: 8444943Abstract: Apparatus and methods for recovering sulfur from acid gases. Acid gases containing relatively high amounts of carbonyl sulfide and/or one or more types of mercaptans can be treated in a sulfur recovery system employing an acid gas enrichment zone and a tail gas treatment zone, where partially-loaded sulfur absorbing solvent from the tail gas treatment zone is employed for sulfur absorption in the acid gas enrichment zone. Off-gas from the acid gas enrichment zone can be combined and hydrogenated with a sulfur recovery unit tail gas thereby increasing the total amount of sulfur recovery from the initial acid gas.Type: GrantFiled: April 30, 2010Date of Patent: May 21, 2013Assignee: Black & Veatch CorporationInventor: Justin A. Lamar
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Patent number: 8435471Abstract: A wet flue gas desulfurization process uses byproduct polyester streams such as those from the production of PLA and/or PGA consisting of hydroxy acids and other organic acids to catalyse the solubilization of calcium from limestone and to further catalyse the reaction of calcium with SO2 for desulfurization and thereby provide significant improvement in process efficiency.Type: GrantFiled: October 22, 2009Date of Patent: May 7, 2013Assignee: 2R Environmental Systems, LLCInventors: Barry Hugghins, Joseph Daniel Cook
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Patent number: 8404900Abstract: An absorbent for separating acidic gases is disclosed. The absorbent or an absorbent composition for separating acidic gases has more than 3 kinds of compounds along with Chemical Formula 1 and 2, and has ability of rapid carbon dioxide elimination, excellent absorption ability, and less energy consumption for regenerating an absorbent due to easy desorption of carbon dioxide.Type: GrantFiled: October 27, 2009Date of Patent: March 26, 2013Assignee: Korea Electric Power CorporationInventors: Jun-Han Kim, Jae-Goo Shim, Kyung-Ryong Jang, Ji-Hyun Lee
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Patent number: 8318117Abstract: Absorption medium for acid gases comprising an oligoamine (A) of the general formula (I) and a primary or secondary alkanolamine (B) of the general formula (II) in which the weight ratio of oligoamine (A) to the primary or secondary alkanolamine (B) is 0.2 to 4, and also the process for removing acid gases from a gas stream by contacting the gas stream at a pressure of 0.05 to 10 MPa abs with an aqueous solution brought to and maintained at a temperature of 20 to 80° C. of said absorption medium.Type: GrantFiled: June 9, 2009Date of Patent: November 27, 2012Assignee: BASF SEInventors: Ute Lichtfers, Robin Thiele, Susanna Voges, Georg Sieder, Oliver Spuhl, Hugo Rafael Garcia Andarcia
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Publication number: 20120248372Abstract: Systems containing imidazoles or blends of imidazoles and amines are described herein. Methods of their preparation and use are also described herein. The methods of using the systems include the reduction of volatile compounds from gas streams and liquid streams.Type: ApplicationFiled: March 27, 2012Publication date: October 4, 2012Applicant: BOARD OF TRUSTEES OF THE UNIVERSITY OF ALABAMAInventor: Jason E. Bara
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Publication number: 20110223084Abstract: This invention relates to sulfur functionalized ionic liquid compounds that are useful in methods of carbon dioxide or sulfur dioxide removal to which they may be applied.Type: ApplicationFiled: March 10, 2011Publication date: September 15, 2011Applicant: E. I. DU PONT DE NEMOURS AND COMPANYInventor: MARK A. SCIALDONE
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Patent number: 7951355Abstract: A process for producing a purified synthesis gas stream from a contaminated feed synthesis gas stream is disclosed. A part of the feed synthesis gas stream is subjected to a water gas shift step. The water gas shift step is used in combination with bulk contaminant removal followed by polishing to thereby remove the contaminants from the synthesis gas stream so as to provide the purified synthesis gas stream having a desired low level of contaminants.Type: GrantFiled: December 6, 2007Date of Patent: May 31, 2011Assignee: Shell Oil CompanyInventors: Jan Lodewijk Maria Dierickx, Maarten Hesselink, Cornelis Jacobus Smit
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Publication number: 20110104030Abstract: Novel solvent composition for selective removal of COS from a gas stream containing same, said composition comprising a) at least one polyalkylene glycol alkyl ether of the formula R1O-(Alk-O)n—R2??(I) or 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone or a mixture of N-formylmorpholine and N-acetylmorpholine wherein R1 is an alkyl group having from 1 to 6 carbon atoms; R2 is hydrogen or an alkyl group having from 1 to 4 carbon atoms; Alk is an alkylene group, branched or unbranched, having from 2 to 4 carbon atoms, and n is from 1 to 10; and b) at least one alkanolamine compound of the formula R3NHR4OR6??(II) or at least one piperazine compound of formula wherein R3 is hydrogen, an alkyl group having from 1 to 6 carbon atoms, or the R4OH group; R4 is a branched or unbranched alkylene group having from 1 to 6 carbon atoms; R5, independently in each occurrence, is hydrogen or an hydroxyalkyl group having from 1 to 4 carbon atoms; and R6 is hydrogen, an alkyl grType: ApplicationFiled: August 16, 2010Publication date: May 5, 2011Applicant: DOW GLOBAL TECHNOLOGIES INC.Inventors: Craig N. Schubert, Arnold C. Ashcraft
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Publication number: 20100003177Abstract: Apparatus comprising an absorber device provided with a plurality of sequentially adjacent sections for flowing a gas stream therethrough. A conduit infrastructure comprising a section configured to ingress, communicate with and egress from each section of the absorber device, and a recovery and regeneration section, is configured with a plurality of heat exchange and cooling equipment. A process wherein a liquid solvent provided with at least one chemical compound selected for reacting with the selected gaseous component, is counter-flowed against and commingled with the gas stream. The liquid solvent temperature is controllably manipulated between each section of the column to provide: (a) thermodynamic-driven mass transfer at the front end of the absorber device, and (b) kinetic-driven mass transfer at the back end of the absorber device. The heat generated during the recovery of the gaseous component from the absorption liquid solvent system is recovered for use in regenerating solvent system.Type: ApplicationFiled: March 23, 2007Publication date: January 7, 2010Applicant: THE UNIVERSITY OF REGINAInventors: Adisorn Aroonwilas, Amornvadee Veawab
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Patent number: 7604788Abstract: The invention provides a process for the removal of polysulfanes from gas streams formed during H2S synthesis.Type: GrantFiled: October 26, 2007Date of Patent: October 20, 2009Assignee: Evonik Degussa GmbHInventors: Alexander Möller, Wolfgang Böck, Wolfgang Taugner, Harald Heinzel, Stephan Rautenberg
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Publication number: 20090081093Abstract: The disclosure provides methods and systems for sequestering and/or reducing sulfur oxides, nitrogen oxides and/or carbon dioxide present in industrial effluent fluid streams. A solid particulate material comprising a slag component, a binder component (distinct from the slag component), and optionally water is formed and then contacted with the effluent fluid stream to reduce at least one of the sulfur oxides, nitrogen oxides, and/or carbon dioxide. The contacting of the effluent stream may occur in a packed bed reactor with the solid dry particulate material. Methods of reducing pollutants from exhaust generated by combustion sources, lime and/or cement kilns, iron and/or steel furnaces, and the like are provided.Type: ApplicationFiled: September 18, 2008Publication date: March 26, 2009Inventor: Douglas C. Comrie
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Publication number: 20090047201Abstract: The invention provides a process for removing mercaptans from a gas stream comprising natural gas or inert gas and mercaptans, the process comprising the steps of: (a) contacting a first gas stream comprising natural gas or inert gas and mercaptans with a hydrodesulphurisation catalyst in the presence of hydrogen in a hydrodesulphurisation unit to obtain a second gas stream comprising natural gas or inert gas, which is depleted of mercaptans and enriched in H2S; (b) removing H2S from the second gas stream comprising natural gas or inert gas in a H2S removal unit to obtain a purified gas stream comprising natural gas or inert gas, which is depleted of mercaptans.Type: ApplicationFiled: August 2, 2005Publication date: February 19, 2009Inventors: Anders Carlsson, Gijsbert Jan Van Heeringen
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Patent number: 7459134Abstract: The combustion fume flowing in through line 1 is decarbonated by contacting with a solvent in column C2. The solvent laden with carbon dioxide is regenerated in zone R. The purified fume discharged through line 9 comprises part of the solvent. The method allows to extract the solvent contained in the purified fume. The purified fume is contacted in zone ZA with a non-aqueous ionic liquid of general formula Q+ A?; Q+ designates an ammonium, phosphonium and/or sulfonium cation, and A? an anion likely to form a liquid salt. The solvent-depleted purified fume is discharged through line 17. The solvent-laden ionic liquid is regenerated by heating in evaporation device DE. The solvent separated from the ionic liquid in device DE is recycled.Type: GrantFiled: January 23, 2006Date of Patent: December 2, 2008Inventors: Renaud Cadours, Fabrice Lecomte, Lionel Magna, Cécile Barrere-Tricca
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Publication number: 20080175778Abstract: The invention provides a process for the removal of polysulfanes from gas streams formed during H2S synthesis.Type: ApplicationFiled: October 26, 2007Publication date: July 24, 2008Applicant: Evonik Degussa GmbHInventors: Alexander Moller, Wolfgang Bock, Wolfgang Taugner, Harald Heinzel, Stephan Rautenberg
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Patent number: 7000382Abstract: A method of partially oxidizing an alcohol to an aldehyde or ketone comprises contacting a gas containing the alcohol with a solid catalyst containing molybdenum, preferably in a +6 oxidation state, and having a surface area of 10 m2/g or higher, preferably 100 m2/g or higher. The molybdenum is supported on a high surface area carrier. The alcohol is a primary or secondary alcohol and preferably contains from 1 to 6 carbon atoms. In a preferred embodiment, the alcohol is ethanol. NOx emissions from an internal combustion engine can be lowered by combining the product of partial oxidation with the exhaust stream before passing the exhaust mixture through a lean NOx catalyst.Type: GrantFiled: July 2, 2003Date of Patent: February 21, 2006Assignee: General Motors CorporationInventors: Jong-Hwan Lee, Steven J. Schmieg, Se H. Oh
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Patent number: 6663841Abstract: A method for removing or scavenging hydrogen sulfide (H2S) and/or mercaptans from supercritical and/or liquid carbon dioxide (CO2) using triazine scavenging agents is described. Preferred triazines are hexahydrotriazines.Type: GrantFiled: April 18, 2002Date of Patent: December 16, 2003Assignee: Baker Hughes IncorporatedInventors: Tauseef Salma, Doug Elledge, Paula Kolb, Scot Haines
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Patent number: 6652821Abstract: The present invention provides a purifying agent having an effect of removing or decomposing toxic substances contained in flue gas or incinerated ash. The purifying agent of the present invention contains one or more kinds of salts selected from alkali metal silicates, fluoride ion, hydrogencarbonate ion, and water-soluble alcohols or derivatives thereof.Type: GrantFiled: October 18, 2000Date of Patent: November 25, 2003Inventors: Yasuo Fukutani, Yoshiyuki Futahashi, Yukio Wada, Eiichiro Nakayama, Kikuko Fukutani, Masami Kojima, Kosuke Wada, Masayoshi Uchida, Shunji Suzuki, Naoya Fujii