Abstract: A method for treating a wastewater or a wastewater sludge includes adding performic acid to the wastewater and/or the waster sludge as an odor controlling agent and/or corrosion controlling agent.

Abstract: Tools and techniques for pyroligneous acid production are provided in accordance with various embodiments. For example, a method of pyroligneous acid production is provided. The method may include: introducing a compound that includes at least carbon, oxygen, and hydrogen into a reaction chamber; heating the compound to a temperature of at least 700 degrees Celsius in the reaction chamber such that the compound reacts through a pyrolysis reaction to produce a liquid, where the liquid may include pyroligneous acid; and/or collecting the produced liquid. In some cases, the residence time of the compound may be less than 1,000 seconds. Temperatures above 1,000 degrees Celsius may be utilized in some cases. The produced liquid may be separated into an oil component and a water component that includes the pyroligneous acid. A lighter fraction may be distilled from the water component, where the lighter component includes the pyroligneous acid.

Abstract: The present invention discloses a formaldehyde absorbent and a method for using the same, the chemical composition of the formaldehyde absorbent by weight percentage is, amino acid: 0.1-99.9%; DNA and RNA base 99.9-0.1%. The method comprises the following steps: a. dissolving the formaldehyde absorbent in solvent to form a solution or dissolving the formaldehyde absorbent in solvent and mixing the same onto a solid carrier; b. placing the solution or solid carrier in indoor space that contains formaldehyde; and c. contacting and reacting the formaldehyde-containing air with the solution or the solid carrier and then absorbing the same. The present invention not only achieves not only excellent performance in absorbing hazard gases in the air, but also features low-cost, and further causes no secondary pollution, which therefore creates great social and economical significance in improving quality of human life, safeguarding human health, and protecting environment.

Abstract: Disclosed herein is a process and a plant for recovering ammonia from a mixture including ammonia, acid gas containing H2S and/or CO2 and low-boiling water-soluble organic components. To avoid an enrichment of volatile organic compounds in the acid gas absorber, a partial stream of the liquid phase is withdrawn from an acid gas absorber and processed such that gaseous ammonia with a reduced content of volatile organic components is obtained, which is recirculated into the acid gas absorber.

Abstract: In order to provide a method for the thermal conditioning of an auxiliary material, which, to clean a crude gas stream loaded with an organic pollutant, is configured to be introduced into the crude gas stream and together with the organic pollutant forms a stable system of pollutant and auxiliary material, which can be carried out easily and in a resource-saving manner, it is proposed that the method includes the following steps: feeding the system of pollutant and auxiliary material and a carrier gas stream that has been heated in relation to normal conditions into a thermal conditioning device; chemical conversion of at least a part of the organic pollutant to produce a conditioned auxiliary material; separating the conditioned auxiliary material from the auxiliary material loaded with an organic pollutant by transportation by means of a gas flow; and removing the conditioned auxiliary material from the thermal conditioning device.

Abstract: A process for extracting a target gas component from a gas mixture in an apparatus having a pair of capture and release sections is provided. The pair of capture and release sections includes a sorbent capture section and a sorbent release section, each of the sorbent capture section and sorbent release section having a high surface area medium and a sorbent contained therein. A gas mixture is directed through a flow path, the flow path directing the gas mixture through the sorbent release section followed by the sorbent capture section, wherein the sorbent within the pair of capture and release sections extracts the target gas component and reduces the target gas component in the gas mixture.

Abstract: An absorption medium for removing acid gases from a fluid stream comprises an aqueous solution of a) of at least one metal salt of an aminocarboxylic acid, and b) of at least one acid promoter, wherein the molar ratio of b) to a) is in the range from 0.0005 to 1.0. The acid promoter is selected from mineral acids, carboxylic acids, sulfonic acids, organic phosphonic acids and partial esters thereof. The absorption medium, compared with absorption media based on amino acid salts, has a reduced regeneration energy requirement without significantly reducing the absorption capacity of the solution for acid gases. In a process for removing acid gases from the fluid stream, the fluid stream is brought into contact with the absorption medium.

Abstract: To provide a simple highly-pure Xe retrieval method and device with high retrieval efficiency by functionally removing such elements as water, CO2 and FCs from waste gases from semiconductor production processes, such as the plasma etching, that contain low-concentration Xe. For samples containing xenon and fluorocarbon, this invention is characterized by having at least first adsorption means (A1) filled with synthetic zeolite with pore size of 4A or smaller and aluminum oxide, arranged serially, gas separation means (A2) composed of silicone or polyethylene hollow fiber gas separation membrane modules 4, second adsorption means (A3) filled with either activated carbon, synthetic zeolite with pore size of 5A or larger, molecular sieving carbon with pore size of 5A or larger, or a combination of these, and reaction means (A4) filled with calcium compounds as reactant.

Abstract: A device and a method for producing a fine liquid mist and injecting the said mist into a gas stream to capture and remove very fine particulate pollutants. The pressurized gas stream is passed into a droplet generator (20) into which the liquid is sprayed and atomised into a mist which captures particulates and then into a droplet separator (30) to produce a separated liquid/particulate mixture and a gas stream with a reduced concentration of particulates. The main application is the removal of fine particulates from vehicle exhaust streams. Optionally a degassing stage (90) is provided for the removal of residual gases and vapours. The preferred liquid to form the mist is water.

Abstract: A scrubber for scrubbing at least one pollutant from flue gas includes a first stage configured to provide a chemical oxidant to a stream of flue gas, and a second stage configured to provide a chemical or chemicals to the stream of flue gas, a scrubbing medium recirculation feature configured to continuously recirculate a slurry used in the second stage, and a by-product processing portion configured to remove a by-product from a stream of slurry withdrawn from the scrubber. The by-product includes reaction products of at least one pollutant.

Abstract: Methods and apparatuses are described for contacting an oxidizing solution such as an aqueous hydrogen peroxide composition of hydrogen peroxide and at least one additive that catalyzes the decomposition of the hydrogen peroxide into hydroxyl radicals with an atmospheric effluent containing odorous and/or noxious components. These components are absorbed by the aqueous hydrogen peroxide composition to produce an atmospheric effluent having reduced amounts of the odorous and/or noxious components. Various methods are described for adding the hydrogen peroxide and the decomposition additive.

Abstract: There is provided a method for reducing the content of at least one water soluble volatile organic compound in a gas. The method comprises contacting the gas with an aqueous acidic oxidizing composition comprising H2O2 and a metal catalyst, and submitting the at least one water soluble volatile organic compound and the aqueous acidic oxidizing composition to an UV radiation.

Abstract: The method allows to remove mercaptans contained in a gaseous feed comprising hydrocarbons by carrying out the following stages: a) contacting, in a reactor R1, gaseous feed 1 with a liquid stream 13 comprising olefins, in the presence of a first acid catalyst so that the mercaptans react with the olefins so as to form sulfides, b) discharging an effluent 3 from reactor R1 and separating the effluent into a gas phase and a liquid phase so as to obtain a mercaptan-depleted treated gas 4 and a sulfide-laden liquid, c) separating the sulfide-laden liquid into a first fraction 6 and a second fraction 5, the volume flow rate of first fraction 6 being at least three times higher than the volume flow rate of second fraction 5, d) recycling first fraction 6 to stage a) as a first portion of said liquid stream to be fed into said reactor R1, e) regenerating second fraction 5 by cracking so as to obtain a sulfide-depleted second fraction 2 that is recycled to stage a) as a second portion of said liquid stream.

Abstract: A method for treating a fluid to be scrubbed, comprising filling a scrubber with a volume of biodiesel or biomass adequate to cover a sintered permeable membrane in the reaction chamber and a bit more to create a reaction zone in not only a plurality of pores in the membrane with fluid but in a reaction zone above the membrane, then introducing fluid to be scrubbed to the membrane, building up pressure in the reaction chamber, and passing a scrubbed fluid from the reaction zone to an exit port at a rate equal to the rate the fluid to be scrubbed is introduced.

Abstract: A method of treating a gas stream containing silane or other silicon-containing gas is described, in which the gas stream is conveyed to a liquid ring pump or screw-mechanism pump, to which are also supplied an oxidant for oxidising the silicon-containing gas within the pump, and a liquid for forming a liquid ring or intermittent flushing within the pump. A liquid stream containing said liquid and a by-product of the oxidation of the silicon-containing gas is exhaust from the pump.

Abstract: A method for treating gases to be scrubbed, comprising filling a scrubber with a volume of lean liquid adequate to cover a sintered permeable membrane in the reaction chamber and a bit more to create a reaction zone in not only a plurality of pores in the membrane with gases but in a reaction zone above the membrane, then introducing gases to be scrubbed to the membrane, building up pressure in the reaction chamber, and passing scrubbed gas from the reaction zone to an exit port at a rate equal to the rate of gases to be scrubbed are introduced.

Abstract: A system removes ethanol and other organic carbons from fermentation exhaust gases. Structurally, the system includes a first scrubber with top and bottom ends. Further, the system includes a second scrubber with a top end and with a bottom end in fluid communication with the first scrubber's top end. During operation, exhaust gases are introduced into the bottom end of the first scrubber. Further, a light alcohol solvent is flowed down from the top end to the bottom end of the first scrubber. As the solvent contacts the exhaust gases, it absorbs the other organic carbons. Thereafter, the exhaust gases enter the second scrubber's bottom end. At the second scrubber's top end, water is introduced and falls into contact with the exhaust gases, absorbing the ethanol. In this manner, ethanol and other organic carbons are removed from the exhaust gases solely through absorption by solvents.

Abstract: Waste gas/wastewater treatment equipment treats waste gas in a scrubber 18 by using micronanobubble water produced in a micronanobubble reaction vessel 31 as washing water. Waste gas is efficiently cleaned by the substance surface high-velocity cleaning function which micronanobubbles have. The washing water having been used in the waste gas treatment is reused in wastewater treatment in adjustment tank 1, denitrification tank 3 and nitrification tank 11 which constitute a wastewater treatment section. Thus, the micronanobubbles contained in the washing water are utilized in wastewater treatment, so that efficiency of wastewater treatment is enhanced.

Abstract: A scrubber for scrubbing at least one pollutant from flue gas includes a first stage configured to provide a chemical oxidant to a stream of flue gas, and a second stage configured to provide a chemical or chemicals to the stream of flue gas, a scrubbing medium recirculation feature configured to continuously recirculate a slurry used in the second stage, and a by-product processing portion configured to remove a by-product from a stream of slurry withdrawn from the scrubber. The by-product includes reaction products of at least one pollutant.

Abstract: The present invention provides compositions comprising ionic liquids and an amine compound, and methods for using and producing the same. In some embodiments, the compositions of the invention are useful in reducing the amount of impurities in a fluid medium or a solid substrate.

Abstract: Methods and apparatuses are described for contacting an oxidizing solution such as an aqueous hydrogen peroxide composition of hydrogen peroxide and at least one additive that catalyzes the decomposition of the hydrogen peroxide into hydroxyl radicals with an atmospheric effluent containing odorous and/or noxious components. These components are absorbed by the aqueous hydrogen peroxide composition to produce an atmospheric effluent having reduced amounts of the odorous and/or noxious components. Various methods are described for adding the hydrogen peroxide and the decomposition additive.

Abstract: A method for reducing or substantially eliminating oxides of nitrogen from an effluent gas stream, that includes providing a source of ultraviolet radiation with a precise wavelength, adding ammonia or an ammonia based reagent to the effluent stream, upstream of the ultraviolet radiation source, controllably operating the ultraviolet radiation source to irradiate the effluent stream flowing in the duct and substantially reducing or eliminating oxides of nitrogen by promotion a reaction of ammonia with the oxides of nitrogen to produce N2 and H2O, and also thereby destroying any surplus ammonia. This process can also be modified to oxidize carbon monoxide and VOC's to CO2 and H2O.

Abstract: A method and apparatus (22) for treating culinary gaseous effluents (Eg) carried in an air extraction duct of a kitchen, the apparatus includes: a unit (24) for storing in liquid form a nucleophilic active product (Pa), or odour destroyer, able to fix foul-smelling molecules in the form of inert salts, a nebulizing and diffusing unit (26) which vaporizes or sublimates the active product (Pa) coming from the storage unit, and which diffuses the vaporized or sublimated active product (Pa) in an extraction duct (18), at ambient temperature, so as to minimize the discharge of foul-smelling molecules at the outlet of the extraction duct. A plant including this apparatus is also disclosed.

Abstract: The gaseous feed flowing in through line 1 is contacted in contacting zone ZA with a liquid solvent flowing in through line 2. The solvent comprises between 0.001% and 100% by weight of a liquid olefin. Contacting in zone ZA is carried out in the presence of an acid catalyst. The purified gaseous feed is discharged from zone ZA through line 3. The sulfide-laden solvent is discharged through line 4, then regenerated in unit RE. The regenerated solvent is recycled through lines 7 and 2 to zone ZA.

Abstract: A multiple-field precipitator, flue-gas treating device, in accordance with the principles of the invention, includes a first section having a dual-function, sensible-cooling heat exchanger/electrostatic precipitator, a second section having a wet electrostatic precipitator, and a middle section fluidly connecting the first and second sections. In the first section, the exchanger/precipitator sensibly cools the flue gas and collects most of the dust from the flue gas. In the middle section, the dust-reduced flue gas is combined with an alkaline material, thereby forming reaction products. These reaction products and several other pollutants are captured by the wet electrostatic precipitator, in the form of a pollutant-laden liquid. The pollutant-laden liquid is directed to a series of heat exchangers and settling tanks, where various pollutants such as SOx, metals, NOx, and chlorides are removed in different stages.

Abstract: A process is presented for separating and removing acid gases or base gases from a feed gas by use of a gas permeable membrane and a permeate comprising a treatment solution. The treatment solution in the permeate is caustic or acidic and reacts with the base or acid gases respectively to form salts so as to facilitate their removal from the feed gas. The acid gas in an acid feed gas may include HCN, H2S, CO2, COS and/or NOx. The base gas in a base feed gas may include NH3. In another aspect of the present invention, an apparatus for treating a feed gas containing an acid or a base gas comprises a feed gas passage; a treatment solution container containing a treatment solution; and a gas permeable membrane.

Abstract: A process and an apparatus for treating exhaust gases, comprising an aeration stirring tank (5) employing an aqueous alkaline liquid, and, as a posterior stage, a gas-liquid contact device (7) and/or a packed column (11). The apparatus can remove at the posterior stage harmful gases that the aeration stirring tank fails to remove, for example, water-soluble organic compounds such as ethanol, halogenated silicon compounds such as SiCl4, and halogen gases such as F2 and Cl2. The process and apparatus are particularly suitable for purifying exhaust gases discharged from a semiconductor production device.

Abstract: Methods and apparatus are described which utilize an aqueous hydrogen peroxide composition of hydrogen peroxide and at least one additive which serves to catalyze the rapid decomposition of the hydrogen peroxide into hydroxyl radicals. When contacted with an atmospheric effluent containing odor and/or noxious components, the hydroxyl radicals formed oxidize the odor and noxious components to non-odor offensive, environmentally acceptable by-product.

Abstract: Method and apparatus for isolating, decomposing, and fixing the organic hazardous substances in a stable manner using chemical techniques and isolating and decomposing the organic hazardous substances from various waste mixtures. The temperature treatment is preferably kept within room temperature range of between 0-30° C. The detoxification of the organic hazardous substances avoids secondary pollution of the environment when the treated materials are released in the soil, atmosphere, or in groundwater.

Abstract: Malodorous gases such as amines, organosulfur compounds, hydrogen sulfide, styrene and aldehydes are economically and efficiently treated at ambient temperature and pressure by a catalytic absorption and oxidation process comprising: (a) bringing the malodorous gases into contact with a scrubbing water containing a heterogeneous catalyst to absorb the malodorous components catalytically, and (b) subjecting the resulting solution containing the malodorous components to a catalytic oxidation by contacting it with an oxidizing agent such as hydrogen peroxide, ozone, oxygen, air, nitrogen oxides, and NaOCl in the presence of the catalyst at a temperature ranging from 0 to 100 □ under an ambient pressure, the heterogeneous catalyst comprising an active metal element selected from alkali, alkaline earth and transition metals, and an oxide support material.

Abstract: The invention relates to a process for the selective recovery of olefins from a mixture of gases by: a) bringing a gaseous mixture having olefins and hydrogen into contact with silver nitrate solution whereby the olefins are absorbed into the silver nitrate solution as a complex; b) separating the solution having complexed olefins from the non-absorbed gases; c) depressurising and heating the olefin complex solution from (b) so as to release the olefins from the complex and regenerate the silver nitrate solution; d) passing the regenerated silver nitrate solution through a bed containing silver oxide so as to maintain the pH value of the silver nitrate at between 3 and 6; and e) recycling the silver nitrate solution regenerated in (d) to step (a).

Abstract: The claimed invention relates to a process for preparing an aqueous formaldehyde solution comprising absorbing a formaldehyde-loaded gas stream, in an absorption zone, in an aqueous solution comprising from 0.000% to 0.01% by weight of a Bronsted base, based on the formaldehyde absorbed. The produced aqueous formaldehyde solution comprises: a) from 10 to 75% by weight of formaldehyde, b) from 0 to 500 ppm by weight of tetroxane, c) from 50 to 400 ppm by weight of formic acid, based on the formaldehyde absorbed, and d) from 0.2 to 5.0% by weight of methanol, based on the formaldehyde absorbed.

Abstract: The invention provides an improved point-of-use PFC/HFC abatement process involving an electrochemical route to abatement. PFCs/HFCs are treated with a relatively strong chemical reducing agent, typically an alkali such as lithium, potassium, or sodium, in a system that promotes ionization of the alkali, e.g., by inclusion of ammonia or other compound that promotes dissolution of the alkali to ions. The electrochemical potential arising from the ionization process provides sufficient energy to extract the fluorine atoms from the PFCs/HFCs. The system also contains a weak acid proton donor to provide a hydrogenation source. The weak acid is believed to displace the reaction equilibrium by protonation, to allow the reaction to proceed at a sufficient rate.

Abstract: The invention relates to a process for the selective recovery of olefins from a mixture of gases by: a) bringing a gaseous mixture having olefins and hydrogen into contact with silver nitrate solution whereby the olefins are absorbed into the silver nitrate solution as a complex; b) separating the solution having complexed olefins from the non-absorbed gases; c) depressurising and heating the olefin complex solution from (b) so as to release the olefins from the complex and regenerate the silver nitrate solution; d) passing the regenerated silver nitrate solution through a bed containing silver oxide so as to maintain the pH value of the silver nitrate at between 3 and 6; and e) recycling the silver nitrate solution regenerated in (d) to step (a).

Abstract: Methods and apparatus are described which utilize an aqueous hydrogen peroxide composition of hydrogen peroxide and at least one additive which serves to catalyze the rapid decomposition of the hydrogen peroxide into hydroxyl radicals. When contacted with an atmospheric effluent containing odor and/or noxious components, the hydroxyl radicals formed oxidize the odor and noxious components to non-odor offensive, environmentally acceptable by-product.

Abstract: A stack emission control system utilized to remove organic contaminants as water-soluble solids from air collected from the vicinity of a polyurethane foam line assembly prior to the exhaust of the air into the surrounding atmosphere is described. A conventional packed tower scrubber is utilized containing an inert material as packing and pH-adjusted water as the wash fluid. The pH-adjusted water serves to remove essentially all of the organic contaminants as water-soluble solids from the air prior to exhaust of the air. The contaminant water-soluble solids are then readily separable from the pH-adjusted water by post-treatment to allow for the separate disposal of the essentially contaminant-free water and the contaminant solids.

Abstract: A method for removing high boiling point volatile organic compounds from an exhaust gas and an apparatus for performing such operation are described. In the method, a wet scrubber is provided which is equipped with a spent water reservoir at the bottom of the scrubber for collecting spent water that contains the volatile organic compounds dissolved in water used to wash the exhaust gas. An ozone gas at a preset concentration is then flown into the spent water to oxidize the dissolved volatile organic compounds contained in the water. The exhaust gas after being washed in the wet scrubber can be released to the atmosphere together with carbon dioxide generated in the oxidation reaction. In the apparatus, an ozone detector is further provided on the exhaust gas outlet in the wet scrubber chamber to verify a content of ozone in the released exhaust gas which is an indication that all the volatile organic compounds have been oxidized in the spent water reservoir.

Abstract: Disclosed is a process for the treatment of a plant fluid effluent containing odor compounds including an alkyl mercaptan or an alkyl thiol, an amine compound, ammonia, hydrogen sulfide and mixtures thereof by contacting the plant effluent in either a counterflow or cocurrent flow process. In the process, the effluent is contacted with an aqueous solution comprising a peroxyacid compound and one or more essential oils. When contacted with the peroxyacid, odor compounds in the effluent are oxidized and converted from the gaseous phase into a chemically modified highly aqueous soluble phase in the aqueous treatment. In this way, odor removal from the gas is preferred and odor compounds are efficiently transferred into the aqueous treatment solution. The use of such a process produces a significant improvement in odor quality index as measured by a conventional process using an expert panel when compared to conventional treatment methods.

Abstract: An integrated process for vent gas treatment for the abatement of volatile emissions is disclosed. The vent gas comprises dioxygen, carbon monoxide, hydrocarbons and other organic compounds comprising one or more alkyl halide compound of 1 to 5 carbon atoms. In the preferred embodiment, the vent gas is heated and mixed with an amount of combustible fluid. Then the mixture is directed to a catalytic oxidation reactor having a suitable oxidation catalyst disposed therein, wherein the mixture is catalytically oxidized. The effluent from the catalytic oxidation reactor is directed to heat the incoming vent gas and subsequently to a scrubber wherein the effluent is scrubbed of soluble compounds and the resultant treated gas stream is vented. Importantly, the amount of combustible fluid supplied to the vent gas stream is controlled so at to provide sufficient reactants for the catalytic oxidation to maintain reaction temperatures from 200° C. and 600° C.

Abstract: Disclosed is a method of eliminating the odor from a malodorous gas, where the odor is due to the presence of a C10 to C18 fatty acid in the gas. An aqueous solution containing at least a stoichiometric amount of a base that reacts with said C10 to C18 fatty acid to produce a salt is sprayed into the gas.

Abstract: Substances to be processed and a hydrogen peroxide aqueous solution are enclosed in a process vessel, and a the process vessel is enclosed in an autoclave together with water. Oxidation processing of the substances is performed by changing the state in the autoclave and the process vessel to a supercritical state which is realized by heating an outer wall of the autoclave with a heater. Further, even if the substances leak from the process vessel, by oxidizing the leaking substances in the autoclave the leaking of the substances to the outside of an oxidation processing apparatus is prevented.