Abstract: The present disclosure comprises antimicrobial compositions and devices comprising silver compounds that resist heat and light discoloration. In one aspect, the said compounds comprise silver and at least one s-triazine ring or moiety. In another aspect, the antimicrobial compositions are hydrogels that are effective against broad spectrum of common pathogens including MRSA and VRE and are suitable for treating human or animal wounds and burns. The methods of the present disclosure comprise treating medical and non-medical devices and articles with compositions comprising the silver compounds to impart antimicrobial property.

Abstract: A method is disclosed for recovering gold from a gold-containing organic solution containing soluble gold. The method comprises contacting the gold-containing organic solution with an aqueous stripping solution in order to extract gold from the gold-containing organic solution into the aqueous stripping solution. The aqueous stripping solution containing gold is separated from the organic solution. The separated aqueous stripping solution containing gold is contacted with a reducing agent containing sodium metabisulphite, in order to reduce gold from the aqueous stripping solution.

Abstract: A method for inhibiting methane production in naturally occurring or induced reducing conditions, thus subsequently resulting into inhibition of the biomethylation process of the heavy metals is disclosed. The disclosed inhibiting composition blocks 3-hydroxy-3-ethylglutaryl coenzyme A (HMG-CoA) reductase, and 8-hydroxy-5-deazaflavin (coenzyme F420) in the methane production pathway, due to the presence of lovastatin in the red yeast rice. As a result the methanogens are unable to produce enough quantities of methane that will result to the production of methylmetal(loids), which are usually volatile and more toxic than their inorganic counterparts due to increased water solubility and hydrophobicity.

Abstract: Disclosed are methods and compositions for improving metal extraction processes by introducing at least one cationically charged compound selected from a group consisting of amines, particularly quaternary amines such as alkyldimethylbenzylammonium chlorides (ADBAC compounds), polyamines and other suitable cationic organic materials, and mixtures thereof, for neutralizing and/or coagulating excess anionic organic compounds including, for example, flotation reagents, surfactants, polymers, flotation reagent by-products and/or anti-scalant additives found in metal concentrate streams, and thereby reduce the downstream fouling of the activated carbon by these compounds.

Abstract: According to one embodiment, a copper recovery apparatus includes a precipitation tank configured to precipitate copper hydroxide grains in water, a filter aid supplier, a mixing tank configured to mix the filter aid with a water to produce a suspension, a separator provided with a filter, a line configured to supply the suspension to the separator, thereby forming a precoat layer formed of the filter aid on the filter, a separation tank configured to receive the detached matter of the precoat layer discharged together with the detaching water from the separator to magnetically separate copper hydroxide grains and filter aid, a line configure to discharge and recover the detaching water from the separation tank, and a line configured to return the separated filter aid to the filter aid supplier from the separation tank.

Abstract: Disclosed are methods and compositions for improving metal extraction processes by introducing at least one cationically charged compound selected from a group consisting of amines, particularly quaternary amines such as alkyldimethylbenzylammonium chlorides (ADBAC compounds), polyamines and other suitable cationic organic materials, and mixtures thereof, for neutralizing and/or coagulating excess anionic organic compounds including, for example, flotation reagents, surfactants, polymers, flotation reagent by-products and/or anti-scalant additives found in metal concentrate streams, and thereby reduce the downstream fouling of the activated carbon by these compounds.

Abstract: Gold and other metals in dissolved anionic form are removed from cyanide-derived aqueous mining effluent by passage of the effluent through an array of conduits in series connectivity, each conduit containing a stationary permeable bed of a particulate absorbent having selective affinity for dissolved anionic metal species, the flow of said effluent through said array being adjusted to produce sharply defined absorption zones.

Abstract: A method for recovering base metal values from oxide ore is provided, where the ore includes a first group metal selected from nickel, cobalt and copper. The method includes reducing ore particle size to suit the latter unit operation, favoring contact for the metal elements, contacting the ore with ferric or ferrous chloride, hydrated or anhydrous, to produce a mix of ore and iron (II or III) chloride subjecting the mixture of the ore and ferric or ferrous chloride to enough energy to decompose the chlorides into hydrochloric acid and a iron oxides from the second group, forming their respective chlorides, selectively dissolve the produced base metal chlorides, leaving the metal as oxides and in the solid state, and recovering the dissolved base metal values from aqueous solution.

Abstract: In a method for separating rich ore particles from agglomerates which contain said rich ore particles and magnetizable particles attached thereto, especially Fe3O4, in the course of a process for obtaining rich ore from crude ore, in which agglomerates the rich ore particle and the magnetizable particle are bonded by organic molecular chains, the agglomerates are contained in a suspension containing a carrier fluid and are broken up by an input of mechanical energy so that an agent contained in the suspension and decomposing the exposed, hydrophobic molecular chains can act upon the molecular chains. The Fe-containing oxide components are separated from the suspension in a magnetic separation process.

Abstract: An adsorbent contains a carbohydrate having an ether linkage. Alternatively, an adsorbent contains a carbohydrate having a cross-linkage formation produced by a dehydration reaction using a strong acid. In collection of a precious metal using the adsorbent, the adsorbent selectively adsorbs a precious metal dissolved in a solution.

Abstract: Various embodiments provide new methods of rhenium recovery. The methods can include subjecting a metal-bearing solution to an activated carbon bed, and adsorbing rhenium onto the activated carbon. The methods can also include heating a basic aqueous elution solution and eluting the rhenium from the activated carbon with the heated elution solution. The methods can also incorporate an ion exchange as a rhenium recovery apparatus.

Abstract: The oxine ligands 5-chloro-8-hydroxyquiniline and 5-sulfoxyl-8-hydroxyquinoline are covalently bound, using, for example, the Mannich reaction, to a silica gel polyamine composite made from a silanized amorphous silica xerogel and polyallylamine. The resulting modified composites, termed CB-1 (X?Cl) and SB-1 (X?SO3H), respectively, show a clear selectivity for trivalent over divalent ions and selectivity for gallium over aluminum. The compounds of the invention can be applied for the sequestration of metals, such as heavy metals, from contaminated mine tailing leachates.

Abstract: A method for recovering base metal values from oxide ore is provided, where the ore includes a first group metal selected from nickel, cobalt and copper. The method includes reducing ore particle size to suit the latter unit operation, favoring contact for the metal elements, contacting the ore with ferric or ferrous chloride, hydrated or anhydrous, to produce a mix of ore and iron (II or III) chloride subjecting the mixture of the ore and ferric or ferrous chloride to enough energy to decompose the chlorides into hydrochloric acid and a iron oxides from the second group, forming their respective chlorides, selectively dissolve the produced base metal chlorides, leaving the metal as oxides and in the solid state, and recovering the dissolved base metal values from aqueous solution.

Abstract: Various embodiments provide new methods of rhenium recovery. The methods can include subjecting a metal-bearing solution to an activated carbon bed, and adsorbing rhenium onto the activated carbon. The methods can also include heating a basic aqueous elution solution and eluting the rhenium from the activated carbon with the heated elution solution.

Abstract: Multi-layered macromolecules wherein the layers are covalently bonded together and wherein the macromolecules are covalently bonded to solid particulate substrates, methods for the preparation of such compositions, and methods for their uses in a multitude of end use applications ranging from the purification of waste chemical and metal process streams to the separation and identification of proteins, peptides, and oligionucleotides.

Abstract: An adsorbent contains a carbohydrate having an ether linkage. Alternatively, an adsorbent contains a carbohydrate having a cross-linkage formation produced by a dehydration reaction using a strong acid. In collection of a precious metal using the adsorbent, the adsorbent selectively adsorbs a precious metal dissolved in a solution.

Abstract: The oxine ligands 5-chloro-8-hydroxyquiniline and 5-sulfoxyl-8-hydroxyquinoline are covalently bound, using, for example, the Mannich reaction, to a silica gel polyamine composite made from a silanized amorphous silica xerogel and polyallylamine. The resulting modified composites, termed CB-1 (X?Cl) and SB-1 (X?SO3H), respectively, show a clear selectivity for trivalent over divalent ions and selectivity for gallium over aluminum. The compounds of the invention can be applied for the sequestration of metals, such as heavy metals, from contaminated mine tailing leachates.

Abstract: A method for recovering base metal values from oxide ore is provided, where the ore includes a first group metal selected from iron, magnesium and aluminum and a second group metal selected from nickel, cobalt and copper. The method includes reducing ore particle size to suit the latter unit operations, favoring contact of the metal elements, contacting the ore with ferric or ferrous chloride, hydrated or anhydrous, to produce a mix of ore and iron(II or III) chloride, subjecting the mixture of the ore and ferric or ferrous chloride to enough energy to decompose the chlorides into hydrochloric acid and a iron oxide, contacting the readily-formed hydrochloric acid with the base metal oxides from the second group, forming their respective chlorides, selectively dissolve the produced base metal chlorides, leaving the metals as oxides and in the solid state, and recovering the dissolved base metal values from aqueous solution.

Abstract: Multi-layered macromolecules wherein the layers are covalently bonded together and wherein the macromolecules are covalently bonded to solid particulate substrates, methods for the preparation of such compositions, and methods for their uses in a multitude of end use applications ranging from the purification of waste chemical and metal process streams to the separation and identification of proteins, peptides, and oligionucleotides.

Abstract: In a method for separating rich ore particles from agglomerates which contain said rich ore particles and magnetizable particles attached thereto, especially Fe3O4, in which agglomerates of the rich ore particle and the magnetizable particle are bonded by organic molecular chains, the agglomerates are contained in a suspension containing a carrier fluid and are broken up by an input of mechanical energy so that an agent contained in the suspension and decomposing the exposed, hydrophobic molecular chains can act upon the molecular chains. The Fe-containing oxide components are separated from the suspension in a magnetic separation process.

Abstract: A method for recovering base metal values from oxide ore is provided, where the ore includes a first group metal selected from iron, magnesium and aluminum and a second group metal selected from nickel, cobalt and copper. The method includes reducing ore particle size to suit the latter unit operations, favoring contact of the metal elements, contacting the ore with ferric or ferrous chloride, hydrated or anhydrous, to produce a mix of ore and iron(II or III) chloride, subjecting the mixture of the ore and ferric or ferrous chloride to enough energy to decompose the chlorides into hydrochloric acid and a iron oxide, contacting the readily-formed hydrochloric acid with the base metal oxides from the second group, forming their respective chlorides, selectively dissolve the produced base metal chlorides, leaving the metals as oxides and in the solid state, and recovering the dissolved base metal values from aqueous solution.

Abstract: A process for recovering a precious metal from a sulfidic material comprises the steps of preparing an acidic aqueous halide solution having an oxidation potential sufficient to oxidize the sulfidic material and render the precious metal soluble in the solution, adding the material to the acidic aqueous halide solution so that the sulfidic material is oxidized and the precious metal is solubilized and separating the precious metal from the oxidized sulfidic material. In addition, a process for removing a contaminant from a contaminated sulfidic material comprises the steps of mixing the material in an aqueous solution wherein a multi-valent species of a relatively high oxidation state oxidizes the contaminant to render it soluble in the solution, produces a contaminant refined material, and is reduced to a relatively lower oxidation state; and removing the contaminant from the solution while regenerating the multi-valent species to its relatively high oxidation state.

Abstract: The invention relates to a method for the recovery of gold from a gold-containing chloride solution using activated carbon. The gold-containing solution and the carbon are contacted with each other, after which the gold that has formed as metallic particles on the surface of the carbon is separated from the carbon using physical methods as gold concentrate that contains metallic gold.

Abstract: A nanopore reactive adsorbent composite material, which may be a porous adsorbent comprising a chemically surface face modified gel, has a composition and micro structure, which integrals ion exchange components such as hydroxy apatite.

Abstract: The invention relates to analytical chemistry and technology for processing clay-salt waste (slurries) of potassium-processing factories. The inventive method is based on the analysis of the totality of tested material and consists in annealing the nanoparticles of precious metal (Au, Pt, Pd) organic compounds at a temperature ranging from 600 to 950° C. in the presence of a chloride agent in the form of potassium chlorides (KCl) or sodium chlorides (NaCl) and in producing the acid-soluble compounds of said metals. The sample is exposed to the entire cycle of technological conversion: 1) chloridising roasting; 2) leaching with weak mineral acid solutions; 3) sorption of precious metal compounds on the industrial sorbent AM-2B 4 from the solution obtained after leaching and 4) desorption. A tradeable solution obtained at the end of said cycle is analysed for precious metal content.

Abstract: Methods and apparatuses for separating metal values, such as nickel and nickel compounds, from mineral ores, including lateritic ores are disclosed. The method includes providing a mixture of particles (e.g., crushed and sized ore) that is composed of at least a first group of particles and a second group of particles. Group members have similar chemical composition, while particles belonging to different groups have dissimilar chemical compositions. The mixture of particles is concurrently, or generally concurrently, heated (using microwave/millimeter wave energy) and exposed to a reactant. The wave energy and the reactant act to increase the difference in either the magnetic susceptibility or other separation properties between the first and second group of particles. The mixture of particles is then passed through an appropriate separator to separate the particles of interest. Optional steps are disclosed for purifying selected particles.

Abstract: Methods for inhibiting depletion of mineral values from pregnant lixiviant solutions comprise contacting the requisite metal ore with a preg-robbing inhibition agent (PRIA) comprising (I) alkyl polyglucoside surfactants; (II) imidazoline based amphoteric surfactants; (III) hydroformylation products of lower (C2–C8) alkanes in an organic solvent medium, and (IV) esters and aldehydes.

Abstract: A display device is formed by burying at least part of a light emitting device in an insulating material, wherein a drive electrode for the light emitting device is formed so as to be extracted on a surface of the insulating material. A display unit is produced by two-dimensionally arraying such light emitting devices on a base body. Since the display device is modularized by burying a light emitting device finely formed in an insulating material, to re-shape the light emitting device into a size easy to handle, it is possible to suppress the production cost of the display unit using such display devices, and to ensure a desirable handling performance of the light emitting device; for example, facilitate the carrying of the light emitting device or the mounting thereof on a base body.

Abstract: A method of recovering metal and/or oxide thereof from a slurry is described. The method involves magnetically separating at least a portion of any magnetic impurities from the slurry and then leaching or dissolving at least a portion of any remaining magnetic impurities in a slurry. At least one chelating agent can then be added to the slurry and the solids can be recovered from the slurry by various separation techniques. The methods of the present invention are particularly useful in the recovery of tantalum and/or oxide thereof especially tantalum and/or oxide thereof having a very fine size.

Abstract: Methods and apparatuses for separating metal values, such as nickel and nickel compounds, from mineral ores, including lateritic ores are disclosed. The method includes providing a mixture of particles (e.g., crushed and sized ore) that is composed of at least a first group of particles and a second group of particles. Group members have similar chemical composition, while particles belonging to different groups have dissimilar chemical compositions. The mixture of particles is exposed to microwave/millimeter wave energy in order to differentially heat the first and second group of particles, thereby increasing differences in magnetic susceptibility between the first and second group of particles. The mixture of particles is then passed through a magnetic field gradient, which causes the particles to separate into magnetic and non-magnetic fractions.

Abstract: The method of preparing the porous material incorporating ultrafine metal particles comprises the following steps: (1) preparing surface-protected ultrafine metal particles by reducing metal ions in the presence of molecules such as dodecanethiol molecules; (2) immersing a wet gel in a solution of the ultrafine metal particles, thus forming an ultrafine metal particle/wet gel composite in which the ultrafine metal particles are incorporated in the wet gel; and (3) drying the ultrafine metal particle/wet gel composite to form a porous body.

Abstract: A two-step chemical precipitation process involving hydroxide precipitation and sulfide precipitation combined with “field separation” technology such as magnetic separation, dissolved air flotation, vortex separation or expanded plastics flotation, effectively removes chelated and non-chelated heavy metal precipitates and other fine particles from water. In the first-step, the non-chelated heavy metals are precipitated as hydroxides and removed from the water by a conventional liquid/solids separator such as an inclined plate clarifier to remove a large percentage of the dissolved heavy metals. The cleaned water is then treated in a second precipitation step to remove the residual heavy metals to meet discharge limits. In the second precipitation step, any metal precipitant more effective than hydroxide for metal precipitation can be used.

Abstract: A process for removing precious metals from activated carbon. The activated carbon is contacted with an aqueous solution of methyl ethyl ketoxime and sodium hydroxide.

Abstract: A method for recovering gold from gold-loaded fine carbon residue from a coarse carbon gold recovery process is disclosed. The gold-loaded fine carbon residue is mixed with activated coarse carbon and an aqueous solution of a transfer reagent to form a slurry. In the slurry the reagent promotes transfer of gold from the fine carbon to the coarse carbon. After allowing time for the transfer, gold-loaded coarse carbon is separated from the slurry. Gold can then be recovered from the separated coarse carbon, for example by cyanide leaching followed by electrowinning. More gold can be recovered by adding further coarse carbon and repeating the transfer of gold to that coarse carbon. In one example 66% of gold was transferred from the fine carbon to the coarse carbon in one transfer cycle. About 89% and 96% of gold can be recovered after respectively second and third transfer cycles.

Abstract: A powerful reducing agent such as hydrazine monohydrate is added to the standard eluent solutions such as NsOH-NaCN with or without alcohol. The kinetics of elution of gold or of silver are thus markedly enhanced.

Abstract: Magnetic porous inorganic siliceous materials having a particle size of about 1 to about 200 microns useful as solid supports in various chromatography, immunoassays, synthesis and other separation and purification procedures is disclosed.

Abstract: A process is provided for the removal of fluoride from a metal sulphate solution, such as a zinc sulphate solution, which presents an option for the disposal of waste treatment sludge from the aluminum anodizing industry. The fluoride is removed from metal sulphate solution by mixing the sludge with the solution for a predetermined period of time and then performing a solid/liquid separation.

Abstract: A process for selectively removing metal values which may include catalytic values from a mixture containing same, wherein a magnetic particle is contacted with a liquid solvent which selectively dissolves the metal values to absorb the liquid solvent onto the magnetic particle. Thereafter the solvent-containing magnetic particles are contacted with a mixture containing the heavy metal values to transfer metal values into the solvent carried by the magnetic particles, and then magnetically separating the magnetic particles. Ion exchange resins may be used for selective solvents.

Abstract: A pulp with ph=9.5 to 11.5, resin, and cyanide KCN is fed to a reaction zone. KCN is in a concentration of CN.sup.- ions in the liquid phase of the pulp from about 0.1 to about 10 g/l, which is maintained constant. The sorbent is in an amount providing its concentration 1 to 1.5% of the reaction zone volume. The leaching procedure produces a sorbent with impurities and rich in gold and silver, and a cyanic pulp depleted of gold and silver. Then, the sorbent rich in gold and silver is separated from the cyanic pulp. The saturated sorbent with impurities is processed in the desorption zone in two stages by passing therethrough a sulfuric acid solution of thiourea, the volume of the solution comprising 10 to 15 volumes of said sorbent. The sulfuric acid solution of thiourea is in an amount of 30% to 50% of said solution volume. A sulfuric acid solution of thiourea rich in gold and silver and a sorbent depleted of gold, silver and impurities is obtained.

Abstract: Increased efficiency of extraction of silver and gold from ore materials thereof containing active carbonaceous material is obtained by conducting the extraction in two stages. In a first stage a portion of the silver and of the gold when present is extracted in a cyanide leach solution. The leached solids residue is contacted with activated carbon so that the silver and the gold when present are adsorbed on the activated carbon at elevated temperature (most preferably at about 35.degree. C. to about 100.degree. C.). In a modification, a slurry of the ore material is treated with cyanide and the precious metal adsorbed directly from the cyanided slurry with activated carbon at elevated temperature up to about 70.degree. C.

Abstract: A process for removing heavy metals from a silver nitrate solution is disclosed. The process comprises the step of bringing said silver nitrate solution into contact with activated alumina having a surface acidity of at least 8 and an average pore diameter of not more than 50 .ANG..

Abstract: Hydrophilic hydrogels capable of a high degree of water imbibition are contacted with aqueous feedstocks containing metal and metal anion values to collect the water and dissolved or suspended values or materials. The term metals includes the free base and precious metals, alloys, salts (including their solvated and complex precious metal ions) and compounds, including base metal anions, and mixtures of the above which are soluble or insoluble in water. The feeds can be ores, industrial or other wastes. After contact, the hydrated hydrogel can be partially dehydrated and separated from the aqueous feedstock. The material values can be recovered by using a strong oxidant to destroy the hydrogel. The aqueous feedstock can be recycled or further purified.

Abstract: Compositions of matter are disclosed comprising nitrogen containing hydrocarbons which are modified with at least one of the elements selected from the group consisting of sulfur, phosphorus an arsenic, with the modified hydrocarbons being covalently bonded to trialkoxysilane. These modified hydrocarbons are further covalently bonded to a solid inorganic support such as silica to form a solid complexing agent. The complexing agents are particularly useful in a process of removing and/or concentrating certain ions, such as noble metal ions and other transition metal ions, from solutions thereof admixed with other ions by forming a complex of the desired ion(s) with the complexing agent. The solution preferably flow through a column packed with the complexing agent to form the complex of the desired ion(s).

Abstract: The invention has compositions of matter and process aspects.The compositions of matter aspects relate to a class of new organic compounds, viz., intermediates which are sulfur and nitrogen containing hydrocarbons covalently bonded to trialkoxysilane and those intermediates covalently bonded to a solid inorganic support such as silica.The process aspect comprises two processes, viz., (1) a process for making the new class of compounds, and (2) the process of removing and/or concentrating certain ions such as noble metal ions and other transition metal ions, from solutions thereof admixed with other ions which may be present in much higher concentrations by forming a complex of the desired ion(s) with a compound as stated, e.g., by flowing the solution through a column packed with the compound, breaking the complex, e.g., by flowing a receiving liquid through the column to remove the desired ion(s) in solution in the receiving liquid and recovering the desired ion(s) from the receiving liquid.

Abstract: A method for reducing the amount of anionic metal-ligand complex in a solution comprises: (a) contacting the solution with a substance selected from: a compound having the formula: A.sub.w B.sub.x (OH).sub.y C.sub.z.nH.sub.2 O, wherein A represents a divalent metal cation, B represents a trivalent metal cation, C represents a mono- to tetravalent anion, and w, x, y, z and n satisfy the following: 0.ltoreq. z.ltoreq.x.ltoreq.4.ltoreq.w.ltoreq.1/2y and 12.gtoreq.n.gtoreq.1/2(w-x); a calcined product of said compound and mixtures thereof; and (b) separating the substance from the solution. A method for removing substantially all metal-cyanide, -thiocyanate, -thiosulfate, -citrate and/or -EDTA complex from a solution containing one or more of said complexes is also disclosed.

Abstract: A method of treating a waste solution resulting from the processing of a photographic material with a working solution is disclosed, wherein at least part of said waste solution is absorbed by a resin capable of absorbing at least 50 times its own weight of a liquid.

Abstract: A method for sorbing metal values from a slurry containing the same is disclosed. The slurry is advanced through a plurality of vessels arranged in series while countercurrently directing a sorbent through the vessels. Metal values are sorbed from the slurry in each of the vessels by mixing the pulp to achieve homogeneity with the pulp being maintained at a predetermined level in the vessel. A portion of the homogeneous pulp is directed into an interstage screening system disposed within the vessel and at least partially submerged beneath the predetermined pulp level, whereby the sorbent is separated from the slurry. The separated sorbent is primarily returned to the vessel while a portion of the sorbent is removed from the interstage screening system.

Abstract: Gold in a very dilute water solution is carbon filtered to capture the gold by adsorption; the gold in the filter is then recovered from the carbon by means of a highly-efficient non-explosive low-alcohol water-based eluant including a strong base and an elevated level of sodium or potassium cyanide.

Abstract: Heap leaching of gold/silver ores with an aqueous alkali cyanide solution containing a surfactant hydrolyzable at the pH of the solution, the surfactant being present in an amount sufficient to increase the rate of metal value recovery without adversely affecting the carbon efficiency in the subsequent step of separating the metal cyanide value from the pregnant leach solution by absorption on carbon columns.

Abstract: The present invention involves the isolation or leaching of noble metals from materials containing noble metals, e.g. ores, by treating the noble metal- containing materials with a cyclic thiourea derivative under acid pH conditions. Removal is effected by adsorption onto charcoal or by an ion exchanger, for example. Preferred cyclic thioureas are N,N'-ethylenethiourea and N,N'-propylenethiourea and the acid pH conditions may be achieved by sulfuric acid or hydrochloric acid solutions containing 0.01 to 2.0% by weight of the cyclic thiourea.